CN208136018U - Light electrolysis cooperative photocatalysis Fenton process waste water treatment system - Google Patents

Light electrolysis cooperative photocatalysis Fenton process waste water treatment system Download PDF

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Publication number
CN208136018U
CN208136018U CN201820242005.9U CN201820242005U CN208136018U CN 208136018 U CN208136018 U CN 208136018U CN 201820242005 U CN201820242005 U CN 201820242005U CN 208136018 U CN208136018 U CN 208136018U
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China
Prior art keywords
photocatalysis
waste water
pond
treatment system
water treatment
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Expired - Fee Related
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CN201820242005.9U
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Chinese (zh)
Inventor
夏彬彬
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Xiamen Hong Xin Great Yu Environmental Protection Technology Co Ltd
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Xiamen Hong Xin Great Yu Environmental Protection Technology Co Ltd
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Abstract

A kind of light electrolysis cooperative photocatalysis Fenton process waste water treatment system, including:Photocatalysis Fenton pond;Ferrous ion supply equipment, the ferrous ion supply equipment supply ferrous ion to photocatalysis Fenton pond by conduit;Hydrogen peroxide supply equipment, the hydrogen peroxide supply equipment supply hydrogen peroxide to photocatalysis Fenton pond by conduit;Photocatalysis generator, the photocatalysis generator supply gas to photocatalysis Fenton pond by gas-guide tube, and the gas includes hydroxyl radical free radical;Micro cell has iron carbon mixed packing layer in the micro cell;The water outlet of the micro cell connects the water inlet in photocatalysis Fenton pond by pipeline.The system improves high concentration wastewater treatment effect, while reducing the dosing cost of high concentration wastewater treatment process.

Description

Light electrolysis cooperative photocatalysis Fenton process waste water treatment system
Technical field
The utility model relates to environment protection field more particularly to a kind of light electrolysis cooperative photocatalysis Fenton process wastewater treatment systems System.
Background technique
High-concentration waste water is the waste water based on organic pollutant.High-concentration waste water is mostly by the row such as papermaking, leather and food Industry is discharged, in the waste water that these industries generate, containing organic matters such as a large amount of carbohydrate, fat, albumen and celluloses, easily Water Eutrophication is caused, if direct emission, serious pollution is will cause, endangers bigger.
Traditional high concentration wastewater treatment method includes biological treatment, physico-chemical process and chemical method etc..These method difficulties drop High-concentration waste water is solved, has no idea to meet higher and higher environmental requirement, therefore, it is necessary to technological innovations.
Utility model content
The utility model solves the problems, such as to be to provide a kind of light electrolysis cooperative photocatalysis Fenton process waste water treatment system, with more The processing to high-concentration waste water is realized well.
To solve the above problems, the utility model provides a kind of light electrolysis cooperative photocatalysis Fenton process wastewater treatment system System, including:Photocatalysis Fenton pond;Ferrous ion supply equipment, the ferrous ion supply equipment are urged by conduit to the light Change Fenton pond and supplies ferrous ion;Hydrogen peroxide supply equipment, the hydrogen peroxide supply equipment are urged by conduit to the light Change Fenton pond and supplies hydrogen peroxide;Photocatalysis generator, the photocatalysis generator pass through gas-guide tube to the photocatalysis Fenton Gas is supplied in pond, and the gas includes hydroxyl radical free radical;Micro cell has iron carbon mixed packing in the micro cell Layer;The water outlet of the micro cell connects the water inlet in photocatalysis Fenton pond by pipeline.
Optionally, the micro cell bottom is also connected into aeration tube, and the aeration tube is located at the end in the micro cell Portion connects aeration head.
Optionally, the aeration head is located at the center of the micro cell bottom, and the aeration head includes multiple solarization air caps.
Optionally, the iron carbon mixed packing layer includes multiple elementary layer structures, and each elementary layer structure can Individually disassembly.
Optionally, there is copper powder or lead powder in each elementary layer structure.
Optionally, the photocatalysis Fenton bottom of pond portion also has water distributor.
Optionally, the part that the gas-guide tube is located at photocatalysis Fenton pond has multiple apertures, and the aperture is located at Above the water distributor.
Optionally, the photocatalysis generator includes anode, cathode, fluorescent tube and catalyst layer.
Optionally, the fluorescent tube is UV lamp pipe.
Optionally, there is the first dosing on the conduit between the ferrous ion supply equipment and photocatalysis Fenton pond Pump;There is the second dosing pump on conduit between the hydrogen peroxide supply equipment and photocatalysis Fenton pond.
In one technical solution of the utility model, micro cell is set in systems, using micro-electrolysis reaction, reaches The high concentration wastewater treatment in one stage.After micro cell, photocatalysis Fenton pond is set.The hydroxyl generated by photochemical catalytic oxidation Base free radical (is generated by photocatalysis generator), further strengthens the oxidability in treatment process, improves high-concentration waste water Treatment effect, while reducing the dosing cost of high concentration wastewater treatment process.Due to being in micro cell backend arrangement photocatalysis Light Fenton's reaction pond, improves the biodegradability of waste water, improves the treatment effeciency of removing heavy metals and coloration.
Detailed description of the invention
Fig. 1 is light electrolysis cooperative photocatalysis Fenton process waste water treatment system schematic diagram provided by the embodiment of the utility model.
Specific embodiment
The processing system of existing high-concentration waste water has much room for improvement.For this purpose, the utility model provides a kind of new high-concentration waste Water electrolysis system, i.e. light electrolysis cooperative photocatalysis Fenton process waste water treatment system, to solve above-mentioned deficiency.
More clearly to indicate, the utility model is described in detail with reference to the accompanying drawing.
The utility model embodiment provides a kind of light electrolysis cooperative photocatalysis Fenton process waste water treatment system, including:Micro- electricity Solve pond 110, photocatalysis Fenton pond 120, ferrous ion supply equipment 170, hydrogen peroxide supply equipment 180 and photocatalysis generator 160.Wherein, ferrous ion supply equipment 170 supplies ferrous ion to photocatalysis Fenton pond 120 by conduit (not marking).It crosses Hydrogen oxide supply equipment 180 supplies hydrogen peroxide to photocatalysis Fenton pond 120 by conduit (not marking).Photocatalysis generator 160 supply gas to photocatalysis Fenton pond 120 by gas-guide tube 165, and the gas includes hydroxyl radical free radical (OH).Photocatalysis Fenton pond 120 has water inlet 121 and water outlet 122.There is water inlet 111, water outlet 112 and iron carbon in micro cell 110 Mixed packing layer 113.The water outlet 112 of micro cell 110 connects the water inlet in photocatalysis Fenton pond 120 by pipeline 140 121。
In the present embodiment, 110 bottom of micro cell is also connected into aeration tube 130, and aeration tube 130 is located in micro cell 110 End connect aeration head 131.And the center that aeration head 131 is located at 110 bottom of micro cell is set, aeration head 131 includes more A solarization air cap (not marking).
In the present embodiment, iron carbon mixed packing layer 113 includes multiple elementary layer structures (not marking), each unit Layer structure can be dismantled individually.For example, four elementary layer structures are shown in Fig. 1, and in use, this four units Layer structure can disassemble one by one, convenient individually to be replaced and adjusted.
In the present embodiment, copper powder (not shown) or lead powder (not shown) can have in each elementary layer structure.Increase Add copper powder or lead powder, is currently to promote the release of iron ion to increase potential difference.
Existing light electrolysis system be mostly using fixed iron carbon bed process, and iron carbon bed it is hardened be one very Troubling problem, because it is easy blocking.And in the present embodiment, it is different from traditional light electrolysis system, iron carbon is mixed It closes filler layer 113 and is designed to the multiple elementary layer structures individually dismantled, is i.e. each of the at this time elementary layer knot Structure is the unit that can be split and replace.
In the present embodiment, iron carbon mixed packing layer 113, which has, decomposes organic macromolecule ability, and hydrogen peroxide is generally also added (not shown), acid waste water are reacted with iron therein, can generate ferrous ion, and ferrous ion enters photocatalysis Fenton with water body In pond 120, then with hydrogen peroxide formation Fenton reagent, the Fenton's reaction accordingly carried out can generate hydroxyl radical free radical, hydroxyl free Base has extremely strong oxidation susceptibility, and most larger molecular organics difficult to degrade can degrade to form small organic molecule etc.. It follows that in the micro cell 110 of system provided in this embodiment in front, iron ion can react for ferrous ion, these Ferrous ion with corresponding water body from micro cell 110 enter photocatalysis Fenton pond 120.Therefore, in photocatalysis Fenton pond 120 In, it is possible to reduce the additional amount of ferrous ion has saved cost to save the supply of ferrous ion.
In the present embodiment, 120 bottom of photocatalysis Fenton pond also has water distributor 150.
In the present embodiment, the part that gas-guide tube 165 is located at photocatalysis Fenton pond 120 has multiple apertures (not marking), institute It states aperture and is located at 150 top of water distributor.
In the present embodiment, photocatalysis generator 160 includes anode 161, cathode 162, fluorescent tube 163 and catalyst layer 164.Its In, fluorescent tube 163 is UV (ultraviolet) fluorescent tube.Catalyst layer 164 can be rutile titania TiO2
In the present embodiment, have the on the conduit between ferrous ion supply equipment 170 and photocatalysis Fenton pond 120 One dosing pump 171.There is the second dosing on the conduit between hydrogen peroxide supply equipment 180 and photocatalysis Fenton pond 120 Pump 181.First dosing pump 171 and the second dosing pump 181 can be controlled separately the additional amount of ferrous ion and hydrogen peroxide.
In the micro cell 110 of the present embodiment, there is iron carbon mixed packing layer 113 therefore will do it the micro- electricity of iron carbon Solution.Iron-carbon micro-electrolysis be based on the cell reaction in electrochemistry, when by iron and it is carbon-impregnated enter electrolyte solution (high-concentration waste water itself For a kind of electrolyte solution) in when, due to the difference in Electrode Potential between iron and carbon there are 1.2V, thus will form countless micro- electricity Cell system constitutes an electric field in its action space, and the nascent state ferrous ion that anode reaction generates has stronger reduction Ability can make chromophoric group the nitro (- NO of certain organic matters2), nitroso (- NO) be reduced into amido (- NH2), another amido class has The biodegradability of machine object is also apparently higher than nitro type organic.The ferrous ion of nascent state can also make certain unsaturated chromophores Group is (such as:Carboxyl-COOH;Azo group-N=N-) double bond open, so that chromophoric group is destroyed and is removed coloration, and then keep part difficult Degradation is cyclic annular and long-chain organic matter resolves into the small organic molecule of easily biological-degradable and improves biodegradability.In addition, divalent and Ferric ion is good flocculant, especially newborn ferrous ion, has higher absorption-flocculation activity.It adjusts The pH of waste water can make iron ion become the flocculent deposit of hydroxide, the molecule of suspension or colloidal attitude in absorption effluent and Organic polymer, can further decrease the coloration of waste water, while removing some organic pollutants matter is purified waste water.
In the micro cell 110 of the present embodiment, iron ion can act on hydroxyl and form the hydrogen-oxygen with coagulation Change ferrous, there is a natural attraction between the sexes for the particle with faint negative electrical charge in ferrous hydroxide and pollutant, formed more stable flocculate ( It is iron cement) and remove.
In the photocatalysis Fenton pond 120 of the present embodiment, the reaction carried out includes Fenton's reaction.Fenton's reaction be usually with The wastewater treatment method of Fenton reagent progress chemical oxidation.Fenton reagent is one mixed by hydrogen peroxide and ferrous ion The kind very strong oxidant of oxidability.Its oxidation mechanism mainly (general pH in acid condition<3.5) ferrous ion, is utilized As the catalyst of hydrogen peroxide, generating has very Strong oxdiative electrical property and the very high hydroxyl radical free radical of reactivity, hydroxyl free Base generates organic free radical with hardly degraded organic substance in aqueous solution and is allowed to structure destruction, final oxygenolysis.It is ferrous simultaneously from Son is oxidized to iron ion and generates coagulating sedimentation, and large amount of organic is condensed and is removed.Fenton oxidation method, which can be handled effectively, to be contained The waste water of organic matters such as nitrobenzene, acrylonitrile-butadiene-styrene copolymer (ABS) and for waste water decoloration and except dislike It is smelly.
And the present embodiment is that photocatalysis oxidation technique is added on the basis of Fenton's reaction pond, and it is fragrant to become a kind of photocatalysis Pond 120.The hydroxyl radical free radical (being generated by photocatalysis generator 160) generated by photochemical catalytic oxidation, further strengthens place Oxidability during reason improves high concentration wastewater treatment effect, at the same reduce the dosing of high concentration wastewater treatment process at This.
The present embodiment improves the biodegradability of waste water in 110 backend arrangement photocatalysis light Fenton's reaction pond of micro cell, Improve the treatment effeciency of removing heavy metals and coloration.
Although the utility model discloses as above, the utility model is not limited to this.Anyone skilled in the art, It does not depart from the spirit and scope of the utility model, can make various changes or modifications, therefore the protection scope of the utility model It should be defined by the scope defined by the claims..

Claims (10)

1. a kind of light electrolysis cooperative photocatalysis Fenton process waste water treatment system, including:
Photocatalysis Fenton pond;
Ferrous ion supply equipment, the ferrous ion supply equipment by conduit to the supply of photocatalysis Fenton pond it is ferrous from Son;
Hydrogen peroxide supply equipment, the hydrogen peroxide supply equipment supply peroxidating to photocatalysis Fenton pond by conduit Hydrogen;
Photocatalysis generator, the photocatalysis generator supply gas, the gas to photocatalysis Fenton pond by gas-guide tube Body includes hydroxyl radical free radical;
It is characterized in that, further including:
Micro cell has iron carbon mixed packing layer in the micro cell;The water outlet of the micro cell passes through pipeline Connect the water inlet in photocatalysis Fenton pond.
2. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 1, which is characterized in that described micro- Electrolysis bottom of pond portion is also connected into aeration tube, and the aeration tube is located at the connection of the end in micro cell aeration head.
3. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 2, which is characterized in that the exposure Gas head is located at the center of the micro cell bottom, and the aeration head includes multiple solarization air caps.
4. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 1, which is characterized in that the iron Carbon mixed packing layer includes multiple elementary layer structures, and each elementary layer structure can be dismantled individually.
5. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 4, which is characterized in that Mei Gesuo Stating has copper powder or lead powder in elementary layer structure.
6. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 1, which is characterized in that the light Catalysis Fenton bottom of pond portion also has water distributor.
7. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 6, which is characterized in that described to lead The part that tracheae is located at photocatalysis Fenton pond has multiple apertures, and the aperture is located above the water distributor.
8. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 1, which is characterized in that the light Catalytic reactor includes anode, cathode, fluorescent tube and catalyst layer.
9. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 8, which is characterized in that the lamp Pipe is UV lamp pipe.
10. light electrolysis cooperative photocatalysis Fenton process waste water treatment system according to claim 1, which is characterized in that described There is the first dosing pump on conduit between ferrous ion supply equipment and photocatalysis Fenton pond;The hydrogen peroxide supply There is the second dosing pump on conduit between equipment and photocatalysis Fenton pond.
CN201820242005.9U 2018-02-09 2018-02-09 Light electrolysis cooperative photocatalysis Fenton process waste water treatment system Expired - Fee Related CN208136018U (en)

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CN201820242005.9U CN208136018U (en) 2018-02-09 2018-02-09 Light electrolysis cooperative photocatalysis Fenton process waste water treatment system

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Application Number Priority Date Filing Date Title
CN201820242005.9U CN208136018U (en) 2018-02-09 2018-02-09 Light electrolysis cooperative photocatalysis Fenton process waste water treatment system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862177A (en) * 2019-12-16 2020-03-06 河南永煤碳纤维有限公司 Treatment method and treatment system for acrylonitrile-containing wastewater
CN112979013A (en) * 2021-03-08 2021-06-18 重庆迪笙宏环保科技有限公司 Low-emission system for organic synthetic wastewater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110862177A (en) * 2019-12-16 2020-03-06 河南永煤碳纤维有限公司 Treatment method and treatment system for acrylonitrile-containing wastewater
CN112979013A (en) * 2021-03-08 2021-06-18 重庆迪笙宏环保科技有限公司 Low-emission system for organic synthetic wastewater

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