CN117363317A - High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module - Google Patents

High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module Download PDF

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Publication number
CN117363317A
CN117363317A CN202311224389.3A CN202311224389A CN117363317A CN 117363317 A CN117363317 A CN 117363317A CN 202311224389 A CN202311224389 A CN 202311224389A CN 117363317 A CN117363317 A CN 117363317A
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CN
China
Prior art keywords
adhesive film
photovoltaic
light
photovoltaic module
glass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311224389.3A
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Chinese (zh)
Inventor
苏维燕
初文静
林俊良
林金锡
林金汉
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Changzhou Almaden Co Ltd
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Changzhou Almaden Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou Almaden Co Ltd filed Critical Changzhou Almaden Co Ltd
Priority to CN202311224389.3A priority Critical patent/CN117363317A/en
Publication of CN117363317A publication Critical patent/CN117363317A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00Adhesives based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/22Presence of unspecified polymer

Abstract

The invention discloses a high-light-transmission photovoltaic packaging adhesive film and a high-light-transmission photovoltaic module; the photovoltaic packaging adhesive film comprises: the coating comprises a matrix adhesive film and a spherical structure dispersing agent doped in the matrix adhesive film; the refractive index of the dispersing agent is 1.6-1.8, and the volume doping concentration is 0.04-0.12%; the adhesive film is used for laminating and assembling a high-light-transmission photovoltaic module, and the overall haze of the adhesive film and the glass in the photovoltaic module after lamination is 35-60%, and the overall light transmittance is 75-88%. The high light transmission photovoltaic module includes: the front glass, the photovoltaic packaging adhesive film layer, the solar cell layer, the adhesive film layer and the back glass are sequentially stacked. According to the invention, the diffusion particles with the spherical structure are dispersed in the matrix adhesive film, so that the scattering performance and the light transmittance of the adhesive film are improved, the interface reflection between the adhesive film and the glass and the battery piece is reduced, the optimal matching of the light rays of the glass/adhesive film/the battery piece is better realized, the intensity of the light rays incident to the battery piece is improved, and the current and the output power of the battery are improved.

Description

High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module
Technical Field
The invention relates to the technical field of photovoltaics, in particular to a high-light-transmission photovoltaic packaging adhesive film and a high-light-transmission photovoltaic module.
Background
Conventional photovoltaic modules are composed of glass/encapsulant film/battery sheet/encapsulant film/glass stacks. Sunlight passes through the glass and the packaging adhesive film, reaches the battery piece to perform photoelectric conversion, and is converted into electric energy by the light energy, the absorption and the loss of the sunlight in the photovoltaic module are greatly related to the packaging adhesive film, the refractive index of the packaging adhesive film is generally between 1.46 and 1.49, certain difference exists between the refractive index of the packaging adhesive film and the refractive index of the glass, and the packaging adhesive film cannot efficiently utilize incident light due to higher reflection at the interface of the glass and the battery piece, so that the photovoltaic module has low utilization rate of the sunlight and low power output of module power generation.
Therefore, in order to avoid the limitation of the packaging adhesive film on further improving the photoelectric conversion efficiency of the photovoltaic module, the scattering property of the packaging adhesive film needs to be improved to realize the optical matching of the glass/packaging adhesive film/the battery piece and reduce the photovoltaic packaging loss. The light utilization rate of the battery piece is related to the conversion efficiency of the battery piece and the optical characteristics of glass and a glue film at the front end of the battery piece, and the light utilization rate needs to be improved by adjusting the scattering characteristics of the glue film; however, the higher the light transmittance of the adhesive film, the higher the light utilization rate of the battery piece after the packaging is not necessarily; the higher the haze of the film, the less the light trapping effect of the film is necessarily the best. This requires maximizing the light utilization of the packaged battery sheet by balancing the light transmittance and haze of the adhesive film.
Disclosure of Invention
The invention aims to provide a high-light-transmission photovoltaic packaging adhesive film, which balances the relation between the light transmittance and the haze of the adhesive film, so that the photovoltaic packaging adhesive film can realize the maximization of the light utilization rate of a battery piece after being used for assembling a photovoltaic module.
The invention is realized by the following technical scheme:
the utility model provides a high printing opacity's photovoltaic packaging glued membrane, its characterized in that, this photovoltaic packaging glued membrane includes: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
the refractive index of the spherical structure dispersing agent is 1.6-1.8; the volume concentration of the spherical structure diffusant doping is 0.04-0.12%;
the photovoltaic packaging adhesive film is used for laminating and assembling a high-light-transmission photovoltaic module, and the overall haze of the photovoltaic packaging adhesive film and the glass in the photovoltaic module after being pressed is 35-60%; the overall light transmittance of the photovoltaic packaging adhesive film and the photovoltaic module after the glass is pressed is 75-88%.
Specifically, in order to optimize and improve the photoelectric conversion efficiency of the photovoltaic module, the light absorptivity of the packaging adhesive film material should be as low as possible, and the light transmittance should be as high as possible; therefore, the invention provides the high-light-transmission photovoltaic packaging adhesive film, which improves the scattering performance of the packaging adhesive film, improves the light transmittance, reduces the interface reflection between the packaging adhesive film and the glass and the battery piece, better realizes the optimized matching of the light rays of the glass/front-layer packaging material/the battery piece, improves the intensity of the light rays incident to the battery piece, and improves the battery current and the output power by dispersing the diffusion particles with the spherical structure in the matrix adhesive film.
Further, a high-light-transmittance photovoltaic packaging adhesive film: the particle size of the spherical structure dispersing agent is selected to be 100-500 nm.
Further, a high-light-transmittance photovoltaic packaging adhesive film: the spherical structure dispersing agent is selected from one or a mixture of more of zinc silicate, aluminum oxide and magnesium oxide.
Furthermore, a high-light-transmission photovoltaic packaging adhesive film: the spherical structure dispersing agent is magnesium oxide.
The high-light-transmission photovoltaic module is characterized by adopting the high-light-transmission photovoltaic packaging adhesive film.
Further, a high light transmission photovoltaic module: the photovoltaic module comprises front glass, a photovoltaic packaging adhesive film layer, a solar cell layer, an adhesive film layer and back glass which are sequentially stacked.
Further, a high light transmission photovoltaic module: the whole haze of the front glass and the photovoltaic packaging adhesive film layer after lamination is 35-60%, and the light transmittance is 75-88%.
Further, a high light transmission photovoltaic module: the thickness of the photovoltaic packaging adhesive film layer is 450-550 mu m.
The invention has the beneficial effects that:
according to the invention, the haze of the obtained photovoltaic packaging adhesive film is adjusted by strictly controlling the refractive index (1.6-1.8) and the doping concentration (0.04-0.12% of volume concentration) of the doped dispersing agent particles, so that the light utilization rate of the battery piece in the component after the adhesive film is packaged is greatly increased, and the photoelectric conversion efficiency of the photovoltaic component is maximally realized.
The invention realizes the balance of the light transmittance and the haze of the glass and the front layer packaging material (namely the photovoltaic packaging adhesive film) through the concentration and the type of the doped dispersing agent, thereby ensuring that the light utilization rate of the battery piece is high. The photovoltaic packaging adhesive film has the scattering characteristics of high light transmittance and low reflectivity, and can effectively improve the light utilization rate of the packaged battery piece.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are needed in the description of the embodiments will be briefly described below, it being obvious that the drawings in the following description are only some embodiments of the present invention, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
Fig. 1 is a schematic layer diagram of a high light transmittance photovoltaic module provided by the present invention.
The marks in the figure: 1 front glass, 2 photovoltaic packaging adhesive film layers, 3 solar cell layers, 4 adhesive film layers and 5 back glass.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are only some, but not all embodiments of the invention. The following description of at least one exemplary embodiment is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
In the description of the present invention, it should be understood that the terms "upper," "lower," "left," "right," "top," "bottom," and the like indicate orientations or positional relationships, merely to facilitate describing the present invention and simplify the description, and do not indicate or imply that the devices or elements being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be construed as limiting the invention. Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may include one or more of the feature, either explicitly or implicitly. Moreover, the terms "first," "second," and the like, are used for distinguishing between similar objects and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used may be interchanged where appropriate such that the embodiments of the invention described herein may be implemented in sequences other than those illustrated or otherwise described herein.
Example 1
A high light transmission photovoltaic packaging adhesive film, comprising: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
wherein: the spherical structure dispersing agent is magnesium oxide (MgO); the volume concentration of the spherical structure diffusant doping is 0.05%; the particle size of the spherical structure diffusant doping is 200nm.
The preparation method of the high-light-transmittance photovoltaic packaging adhesive film in the embodiment 1 comprises the following steps:
(1) Uniformly mixing 0.96g of magnesium oxide with 500.0g of matrix adhesive film;
(2) Adding the mixed materials into a double-screw extruder, heating to 260 ℃, extruding at 45.0MPa, and casting to form a film to obtain a high-light-transmission photovoltaic packaging film; wherein: the casting speed was 2.0m/min.
The high-transmittance photovoltaic packaging adhesive film of the above embodiment 1 is used for assembling a high-transmittance photovoltaic module, as shown in fig. 1, and the module comprises: the front glass 1, the photovoltaic packaging adhesive film layer 2, the solar cell layer 3, the adhesive film layer 4 and the back glass 5 are sequentially stacked; wherein: the front glass 1 is made of ultra-white glass, the thickness of the photovoltaic packaging adhesive film layer 2 is 500 mu m, and the back glass 5 is made of float glass. The above laminated structure was placed in a laminator, vacuum-pulled at 145 ℃ for 6 minutes, followed by lamination at 75KPa for 10 minutes to obtain a high light transmission photovoltaic module.
Example 2
A high light transmission photovoltaic packaging adhesive film, comprising: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
wherein: the spherical structure dispersing agent is zinc silicate (ZnSiO) 3 ) The method comprises the steps of carrying out a first treatment on the surface of the The volume concentration of the spherical structure diffusant doping is 0.09%; the particle size of the spherical structure diffusant doping is 100nm.
The high light transmittance photovoltaic packaging film of example 2 was produced by the method of example 1.
The high-transmittance photovoltaic packaging adhesive film of the above embodiment 2 is used for assembling a high-transmittance photovoltaic module, which comprises: the front glass 1, the photovoltaic packaging adhesive film layer 2, the solar cell layer 3, the adhesive film layer 4 and the back glass 5 are sequentially stacked; wherein: the front glass 1 is made of ultra-white glass, the thickness of the photovoltaic packaging adhesive film layer 2 is 450 mu m, and the back glass 5 is made of float glass. The above laminated structure was placed in a laminator, vacuum-pulled at 145 ℃ for 6 minutes, followed by lamination at 75KPa for 10 minutes to obtain a high light transmission photovoltaic module.
Example 3
A high light transmission photovoltaic packaging adhesive film, comprising: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
wherein: the spherical structure dispersing agent is alumina (Al) 2 O 3 ) The method comprises the steps of carrying out a first treatment on the surface of the The volume concentration of the spherical structure diffusant doping is 0.12%; the particle size of the spherical structure diffusant doping is 500nm.
The high light transmittance photovoltaic packaging film of example 3 was produced by the method of example 1.
The high-transmittance photovoltaic packaging adhesive film of the above embodiment 3 is used for assembling a high-transmittance photovoltaic module, which comprises: the front glass 1, the photovoltaic packaging adhesive film layer 2, the solar cell layer 3, the adhesive film layer 4 and the back glass 5 are sequentially stacked; wherein: the front glass 1 is made of ultra-white glass, the thickness of the photovoltaic packaging adhesive film layer 2 is 550 mu m, and the back glass 5 is made of float glass. The above laminated structure was placed in a laminator, vacuum-pulled at 145 ℃ for 6 minutes, followed by lamination at 75KPa for 10 minutes to obtain a high light transmission photovoltaic module.
Comparative example 1
Comparative example 1 differs from example 1 in that: the base film of comparative example 1 was not doped with a diffusing agent, and the rest was the same as in example 1. Referring to example 1, the adhesive film of comparative example 1 was used to assemble a photovoltaic module.
Comparative example 2
A photovoltaic packaging adhesive film, comprising: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
wherein: the spherical structure dispersing agent is magnesium oxide (MgO); the volume concentration of the spherical structure diffusant doping is 0.209%; the particle size of the spherical structure diffusant doping is 200nm. Referring to example 1, the photovoltaic package of comparative example 2 was used to assemble a photovoltaic module.
Comparative example 2 differs from example 1 in that: the diffuser doping amount in comparative example 2 was much higher than that in example 1, with the remaining conditions being the same.
And (3) testing:
the photovoltaic modules of examples 1 to 3 and comparative examples 1 to 2 were subjected to reflection intensity, light transmittance, and haze test (haze refers to the total haze of the front glass 1 and the photovoltaic packaging film layer 2), and the test results are shown in the following table. Wherein: the reflection intensity test process is as follows: the illumination intensity is 1.0W/m from the front glass 1 2 And then the intensity of the reflected light is tested at the front glass 1.
Diffusing agent type and volume concentration Reflection intensity Transmittance of light Haze degree
Example 1 MgO、0.05% 0.135cd/m 2 88% 36%
Example 2 ZnSiO 3 、0.09% 0.136cd/m 2 80% 50%
Example 3 Al 2 O 3 、0.12% 0.141cd/m 2 75% 55%
Comparative example 1 None, 0 0.144cd/m 2 91% <1
Comparative example 2 MgO、0.209% 0.152cd/m 2 61% 70%
From the test results of example 1 and comparative example 1 in the above table, it can be seen that: according to the invention, the base adhesive film is doped with the dispersing agent with the spherical structure, so that the adhesive film has certain haze, the reduction of the reflection intensity of the photovoltaic module (the reduction of the reflection intensity is about 6.3%), and the strict regulation and control of the type and the concentration of the doped dispersing agent ensure that the light transmittance of the module is greatly reduced while the reflection intensity of the photovoltaic module is reduced, and the light utilization rate of the module is effectively improved.
From the test results of example 1 and comparative example 2, it can be seen that: if the doping concentration of the dispersing agent is increased, the haze of the component is larger, so that the reflection intensity of the component is obviously increased, the light transmittance is reduced greatly, and the light utilization rate of the component is severely restricted.
According to the invention, the diffusion particles with spherical structures are doped in the matrix adhesive film, and the types and doping concentration of the air conditioner diffusion agent are strict, so that the scattering performance of the obtained photovoltaic packaging adhesive film is effectively improved, the light transmittance is improved, the interface reflection between the packaging adhesive film and the glass and the battery piece is reduced, the optimal matching of the light rays of the glass/front-layer packaging material/the battery piece is better realized, the intensity of the light rays incident into the battery piece is improved, and the battery current and the output power are improved
The above-described preferred embodiments of the present invention are only for illustrating the present invention, and are not to be construed as limiting the present invention. Obvious changes and modifications of the invention, which are introduced by the technical solution of the present invention, are still within the scope of the present invention.

Claims (8)

1. The utility model provides a high printing opacity's photovoltaic packaging glued membrane which characterized in that, this photovoltaic packaging glued membrane includes: the substrate adhesive film and the spherical structure dispersing agent are doped in the substrate adhesive film, so that a photovoltaic packaging adhesive film with a certain haze is formed;
the refractive index of the spherical structure dispersing agent is 1.6-1.8; the volume concentration of the spherical structure diffusant doping is 0.04-0.12%;
the photovoltaic packaging adhesive film is used for laminating and assembling a high-light-transmission photovoltaic module, and the overall haze of the photovoltaic packaging adhesive film and the glass in the photovoltaic module after being pressed is 35-60%; the overall light transmittance of the photovoltaic packaging adhesive film and the photovoltaic module after the glass is pressed is 75-88%.
2. The high light transmittance photovoltaic packaging film according to claim 1, wherein the particle size of the spherical structure diffusing agent is selected to be 100-500 nm.
3. The high light transmittance photovoltaic packaging adhesive film according to claim 1, wherein the spherical structure diffusing agent is selected from one or more of zinc silicate, aluminum oxide and magnesium oxide.
4. The high-transmittance photovoltaic packaging adhesive film according to claim 3, wherein the spherical structure diffusing agent is magnesium oxide.
5. A high light transmission photovoltaic module, characterized in that the photovoltaic module adopts the high light transmission photovoltaic packaging adhesive film according to any one of claims 1 to 4.
6. The high-transmittance photovoltaic module according to claim 5, wherein the photovoltaic module comprises a front glass (1), a photovoltaic packaging adhesive film layer (2), a solar cell layer (3), an adhesive film layer (4) and a back glass (5) which are sequentially stacked.
7. The high-transmittance photovoltaic module according to claim 6, wherein the total haze after the front glass (1) and the photovoltaic packaging film layer (2) are pressed together is 35-60%, and the transmittance is 75-88%.
8. The high light transmission photovoltaic module according to claim 6, wherein the thickness of the photovoltaic packaging film layer (2) is 450-550 μm.
CN202311224389.3A 2023-09-21 2023-09-21 High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module Pending CN117363317A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311224389.3A CN117363317A (en) 2023-09-21 2023-09-21 High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311224389.3A CN117363317A (en) 2023-09-21 2023-09-21 High-light-transmission photovoltaic packaging adhesive film and high-light-transmission photovoltaic module

Publications (1)

Publication Number Publication Date
CN117363317A true CN117363317A (en) 2024-01-09

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