CN117357435A - 油包水型化妆品 - Google Patents
油包水型化妆品 Download PDFInfo
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- CN117357435A CN117357435A CN202310746601.6A CN202310746601A CN117357435A CN 117357435 A CN117357435 A CN 117357435A CN 202310746601 A CN202310746601 A CN 202310746601A CN 117357435 A CN117357435 A CN 117357435A
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- Prior art keywords
- water
- oil
- mass
- cosmetic
- component
- Prior art date
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 97
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002734 clay mineral Substances 0.000 claims abstract description 10
- 235000001968 nicotinic acid Nutrition 0.000 claims abstract description 10
- 239000011664 nicotinic acid Substances 0.000 claims abstract description 10
- 229960003512 nicotinic acid Drugs 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000008346 aqueous phase Substances 0.000 claims abstract description 7
- -1 Methacryloxyethyl Chemical group 0.000 claims description 39
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 7
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 6
- KVYGGMBOZFWZBQ-UHFFFAOYSA-N benzyl nicotinate Chemical compound C=1C=CN=CC=1C(=O)OCC1=CC=CC=C1 KVYGGMBOZFWZBQ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 235000005152 nicotinamide Nutrition 0.000 claims description 5
- 239000011570 nicotinamide Substances 0.000 claims description 5
- 229960003966 nicotinamide Drugs 0.000 claims description 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 150000003839 salts Chemical group 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229920000945 Amylopectin Polymers 0.000 claims description 3
- DVHSOAIRLNJAJP-UHFFFAOYSA-N CCC(C)OOC(=O)c1cccnc1 Chemical compound CCC(C)OOC(=O)c1cccnc1 DVHSOAIRLNJAJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- MSCCTZZBYHQMQJ-AZAGJHQNSA-N Tocopheryl nicotinate Chemical compound C([C@@](OC1=C(C)C=2C)(C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)CC1=C(C)C=2OC(=O)C1=CC=CN=C1 MSCCTZZBYHQMQJ-AZAGJHQNSA-N 0.000 claims description 3
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 3
- 229920000800 acrylic rubber Polymers 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- 229950004580 benzyl nicotinate Drugs 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- OWMBTIRJFMGPAC-UHFFFAOYSA-N dimethylamino 2-methylprop-2-enoate Chemical compound CN(C)OC(=O)C(C)=C OWMBTIRJFMGPAC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 229920000120 polyethyl acrylate Polymers 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 230000000475 sunscreen effect Effects 0.000 claims description 3
- 239000000516 sunscreening agent Substances 0.000 claims description 3
- 229950009883 tocopheryl nicotinate Drugs 0.000 claims description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 abstract description 10
- 239000003921 oil Substances 0.000 description 61
- 230000000694 effects Effects 0.000 description 13
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 10
- 239000012071 phase Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical class [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 5
- 229910000271 hectorite Inorganic materials 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- OIQXFRANQVWXJF-QBFSEMIESA-N (2z)-2-benzylidene-4,7,7-trimethylbicyclo[2.2.1]heptan-3-one Chemical class CC1(C)C2CCC1(C)C(=O)\C2=C/C1=CC=CC=C1 OIQXFRANQVWXJF-QBFSEMIESA-N 0.000 description 3
- JGUMTYWKIBJSTN-UHFFFAOYSA-N 2-ethylhexyl 4-[[4,6-bis[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 JGUMTYWKIBJSTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000010696 ester oil Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- ISDGWTZFJKFKMO-UHFFFAOYSA-N 2-phenyl-1,3-dioxane-4,6-dione Chemical class O1C(=O)CC(=O)OC1C1=CC=CC=C1 ISDGWTZFJKFKMO-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-M 4-aminobenzoate Chemical compound NC1=CC=C(C([O-])=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical class NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 description 2
- 229940121363 anti-inflammatory agent Drugs 0.000 description 2
- 239000002260 anti-inflammatory agent Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 2
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- YZUUTMGDONTGTN-UHFFFAOYSA-N nonaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCO YZUUTMGDONTGTN-UHFFFAOYSA-N 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 229960001679 octinoxate Drugs 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 229960001173 oxybenzone Drugs 0.000 description 2
- 239000004447 silicone coating Substances 0.000 description 2
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- HEOCBCNFKCOKBX-RELGSGGGSA-N (1s,2e,4r)-4,7,7-trimethyl-2-[(4-methylphenyl)methylidene]bicyclo[2.2.1]heptan-3-one Chemical compound C1=CC(C)=CC=C1\C=C/1C(=O)[C@]2(C)CC[C@H]\1C2(C)C HEOCBCNFKCOKBX-RELGSGGGSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- NWGAAWUUGRXXSC-UHFFFAOYSA-N 1-(2-hydroxypropoxy)propan-2-yl 2-hydroxybenzoate Chemical compound CC(O)COCC(C)OC(=O)C1=CC=CC=C1O NWGAAWUUGRXXSC-UHFFFAOYSA-N 0.000 description 1
- DHGBAFGZLVRESL-UHFFFAOYSA-N 14-methylpentadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C DHGBAFGZLVRESL-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- MEZZCSHVIGVWFI-UHFFFAOYSA-N 2,2'-Dihydroxy-4-methoxybenzophenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MEZZCSHVIGVWFI-UHFFFAOYSA-N 0.000 description 1
- GHEZBHAGHAJHIT-UHFFFAOYSA-N 2,2-dihydroxyethyl-di(docosyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[NH+](CC(O)O)CCCCCCCCCCCCCCCCCCCCCC GHEZBHAGHAJHIT-UHFFFAOYSA-N 0.000 description 1
- FUTGDWNFCMWSJT-UHFFFAOYSA-N 2,3-bis(14-methylpentadecanoyloxy)propyl 14-methylpentadecanoate Chemical compound CC(C)CCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCC(C)C FUTGDWNFCMWSJT-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- XCQFTFZCTGZCNP-UHFFFAOYSA-N 2-(2-ethylhexanoyloxy)ethyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCOC(=O)C(CC)CCCC XCQFTFZCTGZCNP-UHFFFAOYSA-N 0.000 description 1
- ALBXRBNFWICCSC-UHFFFAOYSA-N 2-(5,5-dimethyl-1,1-diphenylhex-1-en-3-ylidene)propanedioic acid Chemical compound C=1C=CC=CC=1C(=CC(CC(C)(C)C)=C(C(O)=O)C(O)=O)C1=CC=CC=C1 ALBXRBNFWICCSC-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- LFNCNUJTQZONPX-UHFFFAOYSA-N 2-[1-[4-amino-2-(2-methylpropyl)phenyl]-3-methylbutylidene]propanedioic acid;1,3,5-triazine Chemical compound C1=NC=NC=N1.CC(C)CC(=C(C(O)=O)C(O)=O)C1=CC=C(N)C=C1CC(C)C LFNCNUJTQZONPX-UHFFFAOYSA-N 0.000 description 1
- AYUKNFXLSTVUAB-UHFFFAOYSA-N 2-[2-[2-(2,2-dimethylpropanoyloxy)propoxy]propoxy]propyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC(C)COC(C)COC(C)COC(=O)C(C)(C)C AYUKNFXLSTVUAB-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- JVXJFNLEXLGQIO-UHFFFAOYSA-N 2-hexyldecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC JVXJFNLEXLGQIO-UHFFFAOYSA-N 0.000 description 1
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 description 1
- ORWUQAQITKSSRZ-UHFFFAOYSA-N 2-hydroxyethyl 4-[bis[2-(2-hydroxyethoxy)ethyl]amino]benzoate Chemical compound OCCOCCN(CCOCCO)C1=CC=C(C(=O)OCCO)C=C1 ORWUQAQITKSSRZ-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical class C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- WMJBVALTYVXGHW-UHFFFAOYSA-N 3,3-diphenylprop-2-enoic acid Chemical class C=1C=CC=CC=1C(=CC(=O)O)C1=CC=CC=C1 WMJBVALTYVXGHW-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- FVISNFQJDGADOF-UHFFFAOYSA-N 3-methylbutyl 2-methoxy-3-phenylprop-2-enoate Chemical compound CC(C)CCOC(=O)C(OC)=CC1=CC=CC=C1 FVISNFQJDGADOF-UHFFFAOYSA-N 0.000 description 1
- ZQXRINMCMHCYBD-UHFFFAOYSA-N 4-(2-ethylhexoxy)-4-oxobutanoic acid Chemical compound CCCCC(CC)COC(=O)CCC(O)=O ZQXRINMCMHCYBD-UHFFFAOYSA-N 0.000 description 1
- KKJKXQYVUVWWJP-JLHYYAGUSA-N 4-[(e)-(4,7,7-trimethyl-3-oxo-2-bicyclo[2.2.1]heptanylidene)methyl]benzenesulfonic acid Chemical compound CC1(C)C2CCC1(C)C(=O)\C2=C\C1=CC=C(S(O)(=O)=O)C=C1 KKJKXQYVUVWWJP-JLHYYAGUSA-N 0.000 description 1
- CWMKYMMWCJOQFO-UHFFFAOYSA-N 4-[1-[2-[[2-[1-(2H-benzotriazol-4-yl)butyl]-6-methoxy-3,4,5-trimethylphenyl]methyl]-3-methoxy-4,5,6-trimethylphenyl]butyl]-2H-benzotriazole Chemical compound C(C1=C(C(=C(C(=C1C(CCC)C1=CC=CC=2NN=NC=21)C)C)C)OC)C1=C(C(=C(C(=C1C(CCC)C1=CC=CC=2NN=NC=21)C)C)C)OC CWMKYMMWCJOQFO-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- IZHYHVKUSSKSAF-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCCCN(C)CC1=CC=CC=C1.Cl Chemical compound CCCCCCCCCCCCCCCCCCCCN(C)CC1=CC=CC=C1.Cl IZHYHVKUSSKSAF-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
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Classifications
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- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
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Abstract
[课题]提供使用性及分散稳定性优异的油包水型化妆品。[解决手段]一种化妆品,其包含(A)极性油、(B)(B1)HLB为5以下的有机硅表面活性剂或(B2)有机改性粘土矿物、(C)烟酸或其衍生物、(D)油溶性被膜形成剂及(E)水。该化妆品所含的(A)成分的含有率为0.8质量%以上,水相的比率为60质量%以上(均以化妆品的总质量为基准)。
Description
技术领域
本发明涉及高配合极性油的油包水型乳化化妆品。
背景技术
对于直接涂布于皮肤的化妆品,期望在涂布时对皮肤给予水润感、滋润感、细腻感等愉快的使用感。为了实现这样的使用感,对各种方法进行了研究,已知在化妆品中使用感会根据乳化技术而变化,对最适宜的乳化技术进行了研究。在这样的研究中获知,油包水型化妆品中,水相的比率高者在能够给予水润感方面优异。
还已知,对于实现这样的水相的比率高的水包油型化妆品而言,使用有机硅表面活性剂、有机改性粘土矿物等分散剂是有效的。对于这样的分散剂,研究了与各种油分进行组合,对于油分,也研究了将多种成分组合。在此,根据本发明人们的研究获知,作为构成油分的成分,当极性油的含量增多时,化妆品的分散稳定性有时会变得不充分。因此,对于水相比率高的水包油型化妆品而言,大量添加极性油是困难的。极性油中包括提供在涂布时改善皮肤光泽的美容效果、赋予防紫外线效果的效果的物质,期望以高含有率包含极性油从而得到这样的效果、并且具有高分散稳定性的水相比高的油包水型化妆品。
现有技术文献
专利文献
专利文献1:国际专利公开第2020/247441号
发明内容
本发明想要提供能够实现水相比高的油包水型化妆品的优异使用感、例如水润感、并且还能够实现高分散稳定性的油包水型化妆品。
根据本发明,提供以下的化妆品。
[1]一种油包水型化妆品,其包含:
(A)极性油、
(B)(B1)HLB为5以下的有机硅表面活性剂或(B2)有机改性粘土矿物、
(C)烟酸或其衍生物、
(D)油溶性被膜形成剂、及
(E)水,
以前述油包水型化妆品的总质量为基准,(A)成分的含量为0.8质量%以上,水相的比率为60质量%以上。
[2]根据[1]所述的油包水型化妆品,其中,(B1)成分为聚醚改性有机硅。
[3]根据[1]或[2]所述的油包水型化妆品,其中,(B1)成分为下述通式(b1)所示的质均分子量为30000以上的聚醚改性有机硅,
[式中,A为选自由甲基、苯基及通式-C3H6O(C2H4O)p(C3H6O)qR’所示的聚氧亚烷基组成的组中的基团,
R为甲基或苯基,
m为50~1000的整数,
n为1~40的整数,
重复单元(SiR2O)和(SiRAO)任选无规地排列或形成嵌段,并且
聚醚改性有机硅中的聚氧亚烷基的含有率为40重量%以上。
式-C3H6O(C2H4O)p(C3H6O)qR’中,
R’为选自由氢原子、酰基及碳数1~4的烷基组成的组中的基团,
p为5~50的整数,
q为5~50的整数,
重复单元(C2H4O)和(C3H6O)任选无规地排列或形成嵌段。]。
[4]根据[1]~[3]中任一项所述的油包水型化妆品,其中,(B2)成分为具有三层结构的胶体水合硅酸铝。
[5]根据[1]~[4]中任一项所述的油包水型化妆品,其中,(B2)成分为用季铵盐型阳离子表面活性剂将下述通式(a2)所示的粘土矿物改性而得的物质,
(X,Y)2-3(Si,Al)4O10(OH)2Z1/3·xH2O(b2)
(式中,
X=Al、Fe(III)、Mn(III)或Cr(III),
Y=Mg、Fe(II)、Ni,Zn或Li,
Z=K、Na或Ca,
x为整数。)。
[6]根据[1]~[5]中任一项所述的化妆品,其中,(C)成分为选自由烟酸、
烟酰胺、
烟酸苄酯、
生育酚烟酸酯、及
烟酸β-丁氧基酯组成的组中的物质。
[7]根据[1]~[6]中任一项所述的油包水型化妆品,其中,(D)成分为选自由三甲基硅烷氧基硅酸酯、
二甲基氨基甲基丙烯酸酯季盐、
乙烯基吡咯烷酮/甲基丙烯酸-N,N-二甲基-乙基铵基乙基盐共聚物(anti-nioethyl copolymer salt)、
有机硅/聚醚系聚氨酯树脂、
甲基丙烯酰氧基乙基羧基甜菜碱/甲基丙烯酸烷基酯共聚物、
糊精、
(乙烯基吡咯烷酮/VA)共聚物、
丙烯酸烷基酯共聚物铵、
聚乙烯醇、
聚丙烯酸乙酯、
丙烯酸烷基酯/辛基丙烯酰胺共聚物、
丙烯酸(酯)类/丙基聚三甲基硅氧烷甲基丙烯酸酯共聚物、
聚乙酸乙烯酯、
丙烯酸(酯)类/聚二甲基硅氧烷共聚物、
三甲基硅烷氧基甲硅烷基氨基甲酰支链淀粉(polyether grafted acrylicsilicone)、
聚醚接枝丙烯酸有机硅、及
氟改性有机硅树脂组成的组中的物质。
[8]根据[1]~[7]中任一项所述的油包水型化妆品,其中,(A)成分为紫外线吸收剂。
[9]根据[1]~[8]中任一项所述的油包水型化妆品,其中,以前述油包水型化妆品的总质量为基准,
(A)成分的含有率为2~20质量%、
(B)成分的含有率为0.5~7质量%、
(C)成分的含有率为2~10质量%、及
(D)成分的含有率为1~20质量%。
[10]根据[1]~[9]中任一项所述的油包水型化妆品,其为防晒用化妆品。
根据本发明,可以提供能够同时满足由具有高水相比而带来的优异使用感、由极性油带来的各种功能、和优异的分散稳定性的油包水型化妆品。
具体实施方式
本发明的油包水型化妆品(以下,有时简称为“化妆品”)包含:
(A)极性油、
(B)特定的分散剂、
(C)烟酸或其衍生物、
(D)油溶性被膜形成剂、及
(E)水。
对本发明的化妆品中所含的各成分说明如下所述。
(A)极性油
本发明的化妆品包含极性油(以下有时称为“(A)成分”)。本发明中,极性油是指具有极性基团、即亲水性基团的物质。该极性油可根据化妆品所需要的功能从通常用于化妆品领域、医药领域、食品领域等极性油中任意选择。极性油优选这些中的IOB值为0.05~0.80者。IOB值是Inorganic/Organic Balance(无机性/有机性比)的简称,是表现无机性值相对于有机性值的比率的值,是表示有机化合物的极性程度的指标。IOB值具体而言,以IOB值=无机性值/有机性值来表示。在此,关于“无机性值”、“有机性值”,例如,如对分子中1个碳原子设定“有机性值”为20、对分子中1个羟基设定“无机性值”为100这样设定与各种原子或官能团对应的“无机性值”、“有机性值”,通过累计有机化合物中的所有原子和官能团的“无机性值”、“有机性值”,可以算出该有机化合物的IOB值。
本发明中,极性油可以使用能够对化妆品赋予功能者。具体而言,可以利用在使用化妆品时对皮肤赋予光泽、颜色、质感或能够赋予紫外线吸收效果、对皮肤的保护膜形成效果等的极性油。
作为极性油,可列举酯油、高级脂肪酸、高级醇及蜡等。这些中,优选使用酯油。另外,极性油中紫外线吸收效果高者通常被称为紫外线吸收剂,在本发明的化妆品中,可以为了赋予保护皮肤免受紫外线伤害的功能而使用。
作为酯油的具体例,可列举二新戊酸三丙二醇酯、异壬酸异壬酯、肉豆蔻酸异丙酯、辛酸十六烷基酯、肉豆蔻酸辛基十二烷基酯、棕榈酸异丙酯、硬脂酸丁酯、月桂酸己酯、肉豆蔻酸肉豆蔻酯、油酸癸酯、二甲基辛酸己基癸酯、十六烷基乳酸酯、十四烷基乳酸酯、乙酰化羊毛脂、异鲸蜡醇硬脂酸酯、异鲸蜡醇异硬脂酸酯、胆甾醇12-羟基硬脂酸酯、鲸蜡醇乙基己酸酯、乙二醇二(2-乙基己酸)酯、二季戊四醇脂肪酸酯、单异硬脂酸-N-烷基二醇酯、新戊二醇二癸酸酯、二异硬脂醇苹果酸酯、甘油二(2-庚基十一烷酸)酯、三羟甲基丙烷三(2-乙基己酸)酯、三羟甲基丙烷三异硬脂酸酯、季戊四醇四(2-乙基己酸)酯、三异辛酸甘油酯(2-乙基己酸三甘油酯)、三辛酸甘油酯、三异棕榈酸甘油酯、三羟甲基丙烷三异硬脂酸酯、十六烷基-2-乙基己酸酯、棕榈酸2-乙基己酯、甘油三肉豆蔻酸酯、甘油三(2-庚基十一烷酸)酯、蓖麻油脂肪酸甲酯、油酸油酯、乙酰甘油酯、棕榈酸2-庚基十一烷基酯、己二酸二异丁酯、N-月桂酰基-L-谷氨酸-2-辛基十二烷基酯、二(2-庚基十一烷醇)己二酸酯、月桂酸乙酯、癸二酸二(2-乙基己基)酯、肉豆蔻酸2-己基癸酯、棕榈酸2-己基癸酯、己二酸2-己基癸酯、癸二酸二异丙酯、琥珀酸2-乙基己酯、柠檬酸三乙酯等。
作为紫外线吸收剂,没有特别限定,可广泛列举通常用于化妆品的紫外线吸收剂。可以例示出例如:
(a1)对氨基苯甲酸(PABA)乙酯、二羟丙基PABA乙酯、二甲基PABA乙基己酯、甘油PABA酯、PEG-25-PABA、二乙氨羟苯甲酰基苯甲酸己酯等苯甲酸衍生物;
(a2)胡莫柳酯、水杨酸乙基己酯(水杨酸辛酯)、水杨酸二丙二醇酯、TEA水杨酸盐等水杨酸衍生物;
(a2)甲氧基肉桂酸辛酯、甲氧基肉桂酸乙基己酯、甲氧基肉桂酸异丙酯、甲氧基肉桂酸异戊酯、西诺沙酯、甲氧基肉桂酸DEA盐、甲基肉桂酸二异丙酯、甘油乙基己酸酯二甲氧基肉桂酸酯、二(2-乙基己基)-4’-甲氧基亚苄基丙二酸酯等肉桂酸衍生物;
(a2)4-叔丁基-4’-甲氧基二苯甲酰甲烷等二苯甲酰甲烷衍生物;
(a2)奥克立林等β,β-二苯基丙烯酸酯衍生物;
(a2)二苯甲酮-1、二苯甲酮-2、二苯甲酮-3或羟苯甲酮、二苯甲酮-4、二苯甲酮-5、二苯甲酮-6、二苯甲酮-8、二苯甲酮-9、二苯甲酮-12等二苯甲酮衍生物;
(a2)3-亚苄基樟脑、4-甲基亚苄基樟脑、亚苄基樟脑磺酸、甲基硫酸樟脑苄烷铵、对苯二亚甲基二樟脑磺酸、聚丙烯酰氨甲基亚苄基樟脑等亚苄基樟脑衍生物;
(a2)苯基苯并咪唑磺酸、苯基二苯并咪唑四磺酸酯二钠等苯基苯并咪唑衍生物;
(a2)双乙基己氧苯酚甲氧苯基三嗪、乙基己基三嗪酮(例如“Uvinul T150”;BASF公司)、二乙基己基丁酰胺基三嗪酮、2,4,6-三(二异丁基-4’-氨基亚苄基丙二酸酯)-均三嗪、2,4,6-三[4-(2-乙基己基氧基羰基)苯胺基]-1,3,5-三嗪等三嗪衍生物;
(a2)甲酚曲唑三硅氧烷、亚甲基双(苯并三唑基四甲基丁基酚)等苯并三唑衍生物;
(a2)薄荷醇邻氨基苯甲酸酯等邻氨基苯甲酸衍生物;
(a2)二甲氧亚苄基二氧代咪唑烷基丙酸乙基己酯等咪唑啉衍生物;
(a2)具有亚苄基丙二酸酯官能团的聚有机硅氧烷等亚苄基丙二酸酯衍生物;
(a2)1,1-二羧基(2,2’-二甲基丙基)-4,4-二苯基丁二烯等4,4-二芳基丁二烯衍生物等。
本发明中,极性油可以从这些中任意选择使用。另外,可以将2种以上极性油组合使用。例示的极性油中也存在在常温下为粉末状态等固体形状者,也可以通过溶解于其它极性油中而使用。并且,本发明的化妆品优选包含紫外线吸收剂作为极性油。含有紫外线吸收剂作为极性油的本发明的化妆品优选作为防晒用化妆品。
关于本发明的化妆品中的(A)成分的含有率,为了充分发挥极性油的美容效果、防紫外线效果,以较高的含量进行配合。具体而言,以化妆品的总质量为基准,(A)成分的含有率为0.8质量%以上,优选为2~20质量%,更优选为3~15质量%。极性油的含有率低时,通过极性油而实现的功能有时无法充分发挥,因此需要注意。
(B)特定的分散剂
本发明的化妆品包含特定的分散剂(以下有时称为“(B)成分”)。该(B)成分为(B1)HLB为5以下的有机硅表面活性剂或(B2)有机改性粘土矿物中的任意者。通过使用这些特定的分散剂,可以实现优异的使用性。
(B1)HLB为5以下的有机硅表面活性剂
本发明的化妆品中的(B1)成分为有机硅表面活性剂,其HLB值为5以下,优选在2~5的范围内。本发明中的(B1)成分是在分子内具有有机硅结构(疏水性部分)和亲水性部分的非离子性的表面活性剂。
本发明的化妆品中可使用的有机硅表面活性剂没有特别限定,有例如用聚醚基、聚甘油基改性的有机硅系表面活性剂,其中优选用聚醚基改性的有机硅、即聚醚改性有机硅。
聚醚系有机硅已知有各种,本发明中特别优选使用的是下述通式(b1)所示者。
[式中,A为选自由甲基、苯基及通式-C3H6O(C2H4O)p(C3H6O)qR’所示的聚氧亚烷基组成的组中的基团,
R为甲基或苯基,
m为50~1000的整数,
n为1~40的整数,
重复单元(SiR2O)和(SiRAO)任选无规地排列或形成嵌段,并且
聚醚改性有机硅中的聚氧亚烷基的含有率为40重量%以上,
通式-C3H6O(C2H4O)p(C3H6O)qR’中,
R’为选自由氢原子、酰基及碳数1~4的烷基组成的组中的基团,
p为5~50的整数,
q为5~50的整数,
重复单元(C2H4O)和(C3H6O)任选无规地排列或形成嵌段。]
这样的聚醚改性有机硅的分子量无需进行限定,优选质均分子量为30000以上的聚醚改性有机硅。
除此之外,作为聚醚改性有机硅,还可以使用:
聚(氧亚乙基·氧亚丙基)甲基聚硅氧烷共聚物、
聚氧亚乙基甲基聚硅氧烷共聚物、
有机硅链支链型甲基聚硅氧烷共聚物、
烷基链支链型聚氧亚乙基甲基聚硅氧烷共聚物、
烷基链·有机硅链支链型聚氧亚乙基甲基聚硅氧烷共聚物、
交联型聚氧亚乙基甲基聚硅氧烷、
含有烷基的交联型聚氧亚乙基甲基聚硅氧烷等。
另外,作为用聚甘油基改性的聚甘油改性有机硅,也可以使用:
支链型聚甘油改性有机硅、
交联型聚甘油改性有机硅、
含有烷基的交联型聚甘油改性有机硅、
烷基支链型聚甘油改性有机硅等。
作为更具体的例子,可列举:
PEG-9聚二甲基硅氧乙基聚二甲基硅氧烷、
月桂基PEG-9聚二甲基硅氧乙基聚二甲基硅氧烷、
鲸蜡基PEG/PPG-10/1聚二甲基硅氧烷、
PEG-9甲基醚聚二甲基硅氧烷、
PEG-10聚二甲基硅氧烷、
PEG-3聚二甲基硅氧烷等,但是不限于这些。
(B2)有机改性粘土矿物
本发明的化妆品中的(B2)成分为有机改性粘土矿物。(B2)成分例如为具有三层结构的胶体水合硅酸铝中的一种,可列举用季铵盐型阳离子表面活性剂将以下的式(b2)所示的粘土矿物改性而得的物质。
(X,Y)2-3(Si,Al)4O10(OH)2Z1/3·nH2O(b2)
式中、
X为Al、Fe(III)、Mn(III)或Cr(III)、
Y为Mg、Fe(II)、Ni,Zn或Li、且
Z为K、Na或Ca。
这里使用的季铵盐型阳离子表面活性剂为以下所示的物质。
式中、
Ri为碳数10~22的烷基或苄基、
Rii为甲基或碳数10~22的烷基、
Riii及Riv分别独立地为碳数1~3的烷基或羟基烷基、
X为卤素原子或甲基硫酸盐残基。
作为这样的季铵盐型阳离子表面活性剂,可列举例如十二烷基三甲基氯化铵、肉豆蔻基三甲基氯化铵、鲸蜡基三甲基氯化铵、硬脂基三甲基氯化铵、二十烷基三甲基氯化铵、山嵛基三甲基氯化铵、肉豆蔻基二甲基乙基氯化铵、鲸蜡基二甲基乙基氯化铵、硬脂基二甲基乙基氯化铵、二十烷基二甲基乙基氯化铵、山嵛基二甲基乙基氯化铵、肉豆蔻基二乙基甲基氯化铵、鲸蜡基二乙基甲基氯化铵、硬脂基二乙基甲基氯化铵、二十烷基二乙基甲基氯化铵、山嵛基二乙基甲基氯化铵、苄基二甲基肉豆蔻基氯化铵、苄基二甲基鲸蜡基氯化铵、苄基二甲基硬脂基氯化铵、苄基二甲基山嵛基氯化铵、苄基甲基乙基鲸蜡基氯化铵、苄基甲基乙基硬脂基氯化铵、二山嵛基二羟乙基氯化铵、及相应的溴化物等,还可列举二棕榈基丙基乙基甲基硫酸铵等。在实施本发明时,任意选择这些之中的一种或两种以上。
(B2)成分优选选自由二硬脂二甲铵锂蒙脱石、季铵盐-18水辉石、司拉氯铵水辉石、及二硬脂基二甲基氯化铵处理硅酸铝镁组成的组。作为市售品,可列举BENTONE27(苄基二甲基硬脂基氯化铵处理水辉石、Elementis Japan公司制)及BENTONE38(二硬脂基二甲基氯化铵处理水辉石、Elementis Japan公司制)。(B)成分除了可以使用分散于分散介质中者以外,也可以使用粉末状态者。
本发明的化妆品中,(B)成分的含有率可根据目的任意选择,以化妆品的总质量为基准,优选为0.5~7质量%,更优选为0.7~5质量%。
(C)烟酸或其衍生物
本发明的化妆品包含烟酸或其衍生物(以下,有时简称为“(C)成分”)。本发明中,通过将该(C)成分与后述油溶性被膜形成剂组合使用,从而改良分散稳定性。烟酸衍生物是作为对化妆品赋予美白效果的成分而众所周知的物质,除了这样的效果以外还有助于分散稳定性,这是意料之外的。
(C)成分可以从用于化妆品用途、医药用途的物质中任意选择使用,例如,优选选自由烟酸、
烟酰胺、
烟酸苄酯、
生育酚烟酸酯、及
烟酸β-丁氧基酯组成的组。
本发明的化妆品中,(C)成分的含有率可根据目的任意选择,以化妆品的总质量为基准优选为2质量%,更优选为3质量%。另一方面,上限没有特别限定,即使过度提高含有率也难以得到与添加量成正比的效果。因此,烟酸或其衍生物的含有率相对于化妆品的总质量优选为10质量%以下,特别优选为8质量%以下。
(D)油溶性被膜形成剂
本发明的化妆品包含油溶性被膜形成剂(以下,有时简称为“(D)成分”)。油溶性被膜形成剂在化妆品中包含于油相,具有如下效果:将化妆品涂布于皮肤后,形成覆盖皮肤的被膜,发挥使化妆品在皮肤上维持的效果,改良所谓的持妆性。
作为(D)成分,只要是通常用于化妆品中的物质就没有特别限定。作为具体例,可列举:
三甲基硅烷氧基硅酸酯、
二甲基氨基甲基丙烯酸酯季盐、
乙烯基吡咯烷酮/甲基丙烯酸-N,N-二甲基-乙基铵基乙基盐共聚物、
有机硅/聚醚系聚氨酯树脂、
甲基丙烯酰氧基乙基羧基甜菜碱/甲基丙烯酸烷基酯共聚物、
糊精、
(乙烯基吡咯烷酮/VA)共聚物、
丙烯酸烷基酯共聚物铵、
聚乙烯醇、
聚丙烯酸乙酯、
丙烯酸烷基酯/辛基丙烯酰胺共聚物、
丙烯酸(酯)类/丙基聚三甲基硅氧烷甲基丙烯酸酯共聚物、
聚乙酸乙烯酯、
丙烯酸(酯)类/聚二甲基硅氧烷共聚物、
三甲基硅烷氧基甲硅烷基氨基甲酰支链淀粉、
聚醚接枝丙烯酸有机硅、及
氟改性有机硅树脂等。
其中,从持妆的观点出发,优选有机硅被膜形成剂,作为有机硅被膜形成剂,可优选列举:
三甲基硅烷氧基硅酸酯/聚二甲基硅氧烷醇交联聚合物、
有机硅树脂胶、
三甲基硅烷氧基硅酸酯、
有机硅化支链淀粉、
丙烯酸(酯)类/聚二甲基硅氧烷共聚物、
倍半硅氧烷系等。(D)成分可以仅使用1种,也可以将2种以上适当组合使用。
本发明的化妆品中,(D)成分的含有率可根据目的任意选择,以化妆品的总质量为基准,优选为1~20质量%,更优选为5~15质量%,进一步期望为6~12质量%。通过提高(D)成分的含有率可提高持妆性,另一方面,通过使(D)成分的含有率为一定以下,可以改良化妆品的延展性。
(E)水
本发明的组合物除了上述成分以外还包含水。作为水,可以使用用于化妆品、准药品等中的水,例如,可以使用纯化水、离子交换水、自来水等。
本发明的化妆品的水相比率高,以化妆品的总质量为基准的水相比率为60质量%以上,优选为65质量%以上,进一步优选为70质量%以上。本发明中,水是构成这样的水相的物质,水相由水和水以外的水溶性成分例如低级醇等构成。因此,水的含有率以化妆品的总质量为基准,一般为30质量%以上,优选为35~70质量%,更优选为40~65质量%。
(F)其它成分
另外,本发明的化妆品可以包含上述以外的其它成分。例如,可包含非极性油、(B1)成分以外的表面活性剂、香料、水溶性紫外线吸收剂、粉末、保湿剂、亲油性增稠剂、低级醇(碳数小于6)、抗氧化剂、消炎剂、美白剂、各种提取物、激活剂、血液循环促进剂、抗脂溢剂、抗炎剂、水溶性皮膜形成剂、及氨基酸或肽等。
需要说明的是,为了改良分散稳定性,通常使用增稠剂等,这一点是已知的。但是,根据本发明人们的研究获知,有使用感因为配合油凝胶化剂而受损的倾向。因此,本发明的化妆品优选不含油凝胶化剂。
本发明的化妆品可以通过任意方法制造。可以采用配合各成分并搅拌混合的方法;混合水溶性成分而形成水相成分,将其配合到油相成分中后使其分散的方法等各种方法。
本发明的化妆品的形态没有特别限定,从分散稳定性优异的角度出发,优选制成各种液状化妆品且设为可以直接应用于皮肤的形态。此时的粘度优选为1000~70000mPa·s,更优选为2500~55000mPa·s,更优选为3000~45000mPa·s。通过使粘度在这样的范围内,涂布时容易涂开,可以得到优异的使用感。
实施例
以下列举实施例进一步具体地说明本发明,但是本发明不因此而受到限定。需要说明的是,只要没有特别声明,则含有率表示相对于化妆品总质量的质量%。
制造下述表1所示的组成的油包水型乳化化妆品,对以下的项目进行评价。它们的结果也一并示于表1。
[使用性]
对于各试样,请3名专业小组成员评价将各化妆品涂布于皮肤时的使用感,由其平均值按照以下基准来确定评价。
A:很水润
B:水润
C:稍粘腻
D:粘腻
[室温时稳定性、高温时稳定性]
将各试样在室温下保存,确认粘度随着时间经过如何变化。
A:粘度几乎不降低
B:粘度稍稍降低
C:粘度降低
[表1-1]
表1-1
[表1-2]
表1-2
由得到的结果可知,虽然几乎不含极性油的参考例的化妆品的稳定性优异,但是极性油含量增加的比较例的各化妆品的经时稳定性受损。即,可知为了引出极性油的效果而单纯增加极性油含量的方式并不合适。并且可知,本发明的化妆品发挥了极性油的功能,且分散稳定性也优异。
Claims (10)
1.一种油包水型化妆品,其包含:
(A)极性油、
(B)(B1)HLB为5以下的有机硅表面活性剂或(B2)有机改性粘土矿物、
(C)烟酸或其衍生物、
(D)油溶性被膜形成剂、及
(E)水,
以所述油包水型化妆品的总质量为基准,(A)成分的含量为0.8质量%以上,水相的比率为60质量%以上。
2.根据权利要求1所述的油包水型化妆品,其中,(B1)成分为聚醚改性有机硅。
3.根据权利要求1或2所述的油包水型化妆品,其中,(B1)成分为下述通式(b1)所示的质均分子量为30000以上的聚醚改性有机硅,
式中,A为选自由甲基、苯基及通式-C3H6O(C2H4O)p(C3H6O)qR’所示的聚氧亚烷基组成的组中的基团,
R为甲基或苯基,
m为50~1000的整数,
n为1~40的整数,
重复单元(SiR2O)和(SiRAO)任选无规地排列或形成嵌段,并且
聚醚改性有机硅中的聚氧亚烷基的含有率为40重量%以上,
式-C3H6O(C2H4O)p(C3H6O)qR’中,
R’为选自由氢原子、酰基及碳数1~4的烷基组成的组中的基团,
p为5~50的整数,
q为5~50的整数,
重复单元(C2H4O)和(C3H6O)任选无规地排列或形成嵌段。
4.根据权利要求1或2所述的油包水型化妆品,其中,(B2)成分为具有三层结构的胶体水合硅酸铝。
5.根据权利要求1或2所述的油包水型化妆品,其中,(B2)成分为用季铵盐型阳离子表面活性剂将下述通式(a2)所示的粘土矿物改性而得的物质,(X,Y)2-3(Si,Al)4O10(OH)2Z1/3·xH2O(b2)
式中,
X=Al、Fe(III)、Mn(III)或Cr(III),
Y=Mg、Fe(II)、Ni,Zn或Li,
Z=K、Na或Ca,
x为整数。
6.根据权利要求1或2所述的化妆品,其中,(C)成分为选自由烟酸、烟酰胺、
烟酸苄酯、
生育酚烟酸酯、及
烟酸β-丁氧基酯组成的组中的物质。
7.根据权利要求1或2所述的油包水型化妆品,其中,
(D)成分为选自由三甲基硅烷氧基硅酸酯、
二甲基氨基甲基丙烯酸酯季盐、
乙烯基吡咯烷酮/甲基丙烯酸-N,N-二甲基-乙基铵基乙基盐共聚物、
有机硅/聚醚系聚氨酯树脂、
甲基丙烯酰氧基乙基羧基甜菜碱/甲基丙烯酸烷基酯共聚物、
糊精、
(乙烯基吡咯烷酮/VA)共聚物、
丙烯酸烷基酯共聚物铵、
聚乙烯醇、
聚丙烯酸乙酯、
丙烯酸烷基酯/辛基丙烯酰胺共聚物、
丙烯酸(酯)类/丙基聚三甲基硅氧烷甲基丙烯酸酯共聚物、
聚乙酸乙烯酯、
丙烯酸(酯)类/聚二甲基硅氧烷共聚物、
三甲基硅烷氧基甲硅烷基氨基甲酰支链淀粉、
聚醚接枝丙烯酸有机硅、及
氟改性有机硅树脂组成的组中的物质。
8.根据权利要求1或2所述的油包水型化妆品,其中,(A)成分为紫外线吸收剂。
9.根据权利要求1或2所述的油包水型化妆品,其中,以所述油包水型化妆品的总质量为基准,
(A)成分的含有率为2~20质量%,
(B)成分的含有率为0.5~7质量%,
(C)成分的含有率为2~10质量%,及
(D)成分的含有率为1~20质量%。
10.根据权利要求1或2所述的油包水型化妆品,其为防晒用化妆品。
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