CN1173487A - Method for extracting amino acid needed by human body and amino acid products series - Google Patents
Method for extracting amino acid needed by human body and amino acid products series Download PDFInfo
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Abstract
A process for extracting amino acide needed by human body from the protein of animal or plant includes hydrolysis, filtering, solvent extracting and settling, and features that according to different kinds and contents of amino acids in raw material, different hydrolysis steps (acidic or alkaline one) and solvents are used, and the pH values and temp for each steps such as neutralization, concentration, filtering, settling and refining are controlled. The compound amino acid or 19 single-component amino acids can be obtained, which can be used to produce flavourings or health-care food.
Description
The present invention relates to belong to A23J 1/00 B01D 11/00 class, a kind of extracting method that can extract amino acid needed by human body fully and with the series product of amino acid preparation to containing the solvent-extracted method of protein material.
Amino acid production method in the past has chemical synthesis and fermentation method, and amino acid separation has settling process and absorption method.Though chemical synthesis can obtain single amino acid, kind is incomplete, complex process, and cost is higher, and the product purity instability.The fermentation method productive rate is very low, kind is incomplete yet.With settling process and absorption method amino acid separation several kinds being arranged also, also is that yield is very low; The resin column size is huge, and strength of solution spy is low, give to concentrate to cause very big difficulty, and cost is very high, and general yield only about 30% can not be used.
The amino acid whose producer of domestic production mainly adopts fermentative Production L-glutamic acid, Methionin, hydrolysis hair to produce Gelucystine at present.Above-mentioned a few seed amino acid all is the kind that market does not lack, price is unstable, economic benefit is very low.And market well sold and in short supply, cost an arm and a leg, the very significant amino acid of economic benefit is as L-leucine, L-Isoleucine, L-arginine, L-phenylalanine, L-Histidine, L-methionine(Met), L-Xie Ansuan, L-Serine, L-tryptophane, then domestic none family produces.After particularly Gelucystine producer only extracts a kind of catchpenny Gelucystine, just the mother liquor that contains 16 seed amino acids is drained as waste material.It's a pity most that wherein very high, the expensive Serine of content, arginine, Xie Ansuan etc. also drain with waste liquid.
To above-mentioned amino acid, China is in great demand, industry such as pharmacy, food particularly, and most indispensable amino acids all are from external import with a large amount of foreign exchanges.Once directly used hydrolysis method to produce aminoacids complex, as transfusion, but because this hydrolyzate, has the effect of paying often because of the not thorough and residual peptide chain of hydrolysis in the past.Moreover the amino acid compatibility of hydrolysis method is also unreasonable.
The purpose of this invention is to provide that a kind of technology is simple, cost is low, extract the method for the full composition of amino acid needed by human body in driven, the vegetable-protein, and the health care amino acid products series made from L amino acid and drug matching.
It is to make raw material with animal and plant protein that this human body needs amino acid whose extracting method, adopts hydrolysis, filtration, solvent extraction, settling process respectively, it is characterized in that different according to amino acid contained kind of various animal and plant albumen and amount, prepares burden by proportioning; Hydrolysis method is handled raw material, uses organic solvent 1,2 extractions, and is neutralizing, concentrates, filters, making with extra care in each link and control pH value, temperature etc.This method can once get reasonable aminoacids complex of compatibility or oligomict 19 seed amino acids, with other components compatibility, makes seasonings and health beverage series again.
Aminoacids complex production once had the direct applied history of hydrolysate, can not untie because of the peptide chain that contains in the hydrolyzate, and effect is bad, and this method is eliminated.The inventive method is held various amino acid whose proportionings from compounding links, and thoroughly unties the titanium chain in hydrolytic process, adopts methods such as homemade solvent extraction, pickling, sedimentation, has made needed by human body compatibility reasonable amino acid and oligomict amino acid.This method all is that wide, economic market has been opened up in amino acid whose production on raw material, technology, has the incomparable value of technology in the past.It utilizes the waste material of oil plant factory, slaughterhouse, pharmaceutical factory, Gelucystine factory to be raw material, the cost of extraction liquid and technology is also low, do not produce refuse, free from environmental pollution, and the value of its product can be the hundred times of cost, and its social benefit is to provide better quality products at good values for China's pharmacy industry, grocery trade and people's lives.
Embodiment:
The extracting method of amino acid needed by human body, equipment used comprise reactor, polyethylene reaction tower, test tank, pressure, flow instrument, pump; Raw material comprises protein-contg animal and plant tankage; Technology comprises hydrolysis, concentrates, sedimentation, filter wash, extraction, filtration, it is characterized in that: by going out finished product amino acid profiles requirement, according to the amino acid contained kind difference of various animal and plant albumen, prepare burden by proportioning; In two reactors, prepare burden respectively: add batching 1 (corn, peanut meal siccative) in the still 1, use H
2SO
4The weak acid hydrolysis, 1-4N, 130-200 ℃, 8-10h thoroughly unties until the titanium chain, sees the silkworm excrement hydrolysising experiment.Add batching 2 (blood meal, dregs of beans, shellfish meat) in the still 2, use the weak base hydrolysis, 1-4N, more than 130 ℃, 12-20h, filtration respectively, filter residue makes fuel; Get filtrate A and B.Neutralizer AB transfers PH7, filtering CaSO
4C liquid, get portion C liquid decolouring, concentrate, crystallization, refining the rational aminoacids complex dry powder of compatibility.Be used for human transfusion or pharmacy.
Another part C liquid with extract Gelucystine waste liquid (containing silk, arginine 18-24kg/T) and mix, add a small amount of raw material hydrolyzed solution accent PH=2.70, advance tower 1, extraction, C liquid with organic solvent 1 counter current contact and go out to become D liquid from tower bottom flow.Solvent 1 is gone into tower 2 and F liquid (pickle solution that contains NaCl) counter current contact, and from recovered overhead, F liquid returns the F jar; Solvent 1 advances tower 3 and 2N HCl counter current contact, and solvent recuperation gets amino acid E liquid, contains Xie Ansuan, methionine(Met), phenylalanine, leucine, Isoleucine, and yield can reach 98%.
D liquid is transferred PH7.0 and solvent 1 counter current contact to advance tower 4, extraction, D liquid and is returned the D jar.Solvent 1 adds an amount of NaCl at tower 5 usefulness 0.1-4N HCl and selects and wash, and washing lotion is gone into jar, and solvent advances tower 6 with 2N HCl again, and solvent recuperation contains arginic solution and goes out from tower bottom flow, refining arginine, and yield can reach 98%, and purity can reach 99%.
D liquid advances tower 7 with solvent 1 again, and D liquid goes out back the D jar from tower bottom flow, and solvent 1 and 0.1-2N HCl liquid are in tower 8 counter current contact, washing lotion is gone into the F flow container, and solvent 1 reenters tower 9, solvent recuperation with 2N HCl liquid, the solution that must contain Histidine decolours, makes with extra care, gets purity and reaches 99% Histidine, yield 98%.
D liquid is transferred PH2-5, advances tower 10 with solvent 1, and D liquid returns the D jar, and solvent 1 advances tower 11 with the washing lotion adverse current of PH8-10, solvent recuperation, the tryptophane of purity 98.5%, yield 97-98%.
D liquid is transferred PH7, concentrate Be ' 28, cool off, leave standstill, crystallization, filter, leach G liquid, ethanol refining Serine, purity 99%, yield 90-95%.
E liquid and solvent 1 advance tower 12, get water H liquid, contain Xie Ansuan and methionine(Met); Solvent 1 advances tower 13 with washing lotion 0.5-2.5N, and acid solution liquid advances the F flow container, and solvent and 2N HCl advance tower 14, solvent recuperation gets water L, contains leucine, Isoleucine, phenylalanine, L liquid is transferred PH7-11, or PH10, advance tower 15 with solvent 2, get water M, contain leucine and Isoleucine, solvent 2 advances tower 16 with 2N HCl, gets phenylalanine, purity 98.5%, yield 97%.
M liquid and solvent 1 advance tower 17, get the water Isoleucine; Wash out leucine with 2N HCl liquid, purity all can reach 99%, yield 98%.
H liquid is contracted to doing,, methionine(Met) can be separated with Xie Ansuan with dehydrated alcohol filter wash repeatedly, refining with ethanol respectively again, reclaim ethanol and get dry powder.
G liquid is transferred PH3, concentrates, leaves standstill 20h in 30 ℃, filter tyrosine.Filtrate is transferred PH8, concentrate, leave standstill, filter in 30 ℃, L-glutamic acid.Filtrate transfers PH7 to leave standstill 4h again, 30 ℃, leach Gelucystine.Filtrate is transferred PH3.8 again, reconcentration Be ' 28-30, in 20 ℃ leach Methionin.Filtrate is transferred PH2.7, concentrates, is left standstill, 10 ℃ of filtrations, glycine and L-Ala.Filtrate is transferred PH7, be concentrated into dried, Threonine and proline(Pro) mixed crystal, get proline(Pro) and Threonine with the ethanol filter wash again; Also can be concentrated into Be ' 28-30, filtrate is washed with dehydrated alcohol again.Filtrate is continued to employ, and can extract cow-bezoar ammonia when adding shellfish meat raw material.Contain proline(Pro) ethanol-recovery ethanol and get proline(Pro), so far separate fully.
Solvent 1 used in the aforesaid method is an organic extractant, and its prescription is:
Di (isooctyl) phosphate 35-85%
Aviation kerosene 55-5%
Octanol 10%
Used solvent 2 is the solvent that contains the aromatic hydrocarbons of doped quaternary ammonium salt 10-30%.
Used F liquid is the pickle solution that contains NaCL.
With the aminoacids complex of aforesaid method extraction separation, the amino acid needed by human body of various single-components can modulate amino acid products series such as seasonings, drink.
The prescription of amino acid soy sauce is: aminoacids complex 4-6% Folium Bambosae extract 0.5-1%
Health care salt 11-15% Potenlini 0.5-1%
Maltose 10-15% phytic acid 0.5-1%
Sorbyl alcohol 1-5% glycerol 0.5%
All the other are pure water for white sugar 1%
Health care salt is the sodium-free salt that contains potassium, magnesium, calcium salt, and ephrosis and hyperpietic are had health-care effect.
The sterilization of Folium Bambosae extract, favorable anti-corrosion effect, and, also have anti-inflammatory, antitumous effect to nontoxic pair of effect of human body.
Containing amino acid whose diabetic subject's beverage formula is: get the aminoacids complex of making by claim 1 method and make 20% solution, and pears, preferred peace fruit pears, Chinese pear, sorb, the 500g infusion is got juice and is got 400ml; Herbal medicine: add sorbyl alcohol 5g in the smooth slender acanthopanax 30g of genseng 500g coptis root 10g lotus-seed kernel 20g Grosvenor Momordica 80g Wu Chia Pee 30g Poria cocos 40g Fructus Corni 80g gynostemma pentaphylla 30g Chinese yam 40g Chinese cassia tree 30g root bark of tree peony 20g root of herbaceous peony 30g shrimp Radix Angelicae Sinensis 30g Wu taro 10g Asian puccoon 20g shizandra berry 30g pollen 50g Ligusticum wallichii 20g the root of straight ladybell 90g fennel 30g mulberry fruit 20g water drug-decocting concentrating liquid, get soup 1000ml;
Preparation: pear juice concentrated solution 480ml, amino acid solution 480ml, soup 40ml mixes, and gets the 1000ml beverage.
The prescription of quick-acting amino acid sports beveragess: g/1000mL
The compositing acid solution 10%800-900ml that contains amino sour 9g/L of Radix Asparagi and arginine 15g/L
Stevia extract-containing liquid 20-60ml triglyceride 10-30ml Yelkin TTS 20-60g
The various vitamin A of citric acid 6-10g sorbyl alcohol 5g, B, C, D, E and mineral calcium, zinc, iron,
Each is a small amount of for potassium; Radix Et Caulis Acanthopanacis Senticosi, Radix Panacis Quinquefolii, Fructus Hippophae, each 10-50g decocting of Grosvenor Momordica are got juice 10-30ml.
Amino acid man oral liquid prescription: g/100mL
Arginine 10g aspartic acid 2g herbal medicine: genseng, the tuber of multiflower knotweed, Herba Epimedii, slender acanthopanax, Nandina domestica, each 10-15g decocting boiling down of Radix Rehmanniae Preparata contract and get juice 10-15g pears alcohol 0.5g, add a small amount of Sucus Glycyrrhizae, glucose is sweeting agent, and all the other are water.
During the rational aminoacids complex dry powder of the inventive method system compatibility (amino acid transfusion prescription), by national standard, error 〉=20%, g/L:
Jiangsu side, Beijing side, Jiangsu side, Beijing side isoleucine 2.10 3.9 leucines 2.85 5.3 valines 2.30 4.3 methionine 2.70 3.0 arginine 8.47 3.3 phenylalanines 2.50 5.5 tryptophans 1.05 1.0 propylhomoserins 2.36 2.4 cysteines 0.54 1.4 glycine 7.80 2.1 tyrosine 0.398 0.5 proline 7.0 8.1 lysines 4.21 3.9 alanine 13.0 3.0 serines 7.0 7.5 glutamic acid 5.50 9.0 asparatates 4.1 sorbierites 50 magnesium sulfate 370mg calcium chloride 368mg potassium chloride 375mg
Above-mentioned weak acid, basic hydrolysis technology can also produce the effect of untiing the titanium chain, test with silkworm excrement separately: carry out test for protein before the hydrolysis, do not find albumen; Obtain several a small amount of amino acid after the hydrolysis.These several seed amino acids can not constitutive protein, the unfolded just titanium chain of this explanation.
Attached: experimental results show that of titanium chain opened in the silkworm excrement hydrolysis
Claims (6)
1, a kind of extracting method of amino acid needed by human body, equipment used comprise reactor, polyethylene reaction tower, test tank, pressure, flow instrument, pump; Raw material comprises protein-contg animal and plant tankage; Technology comprises hydrolysis, concentrates, sedimentation, filter wash, extraction, filtration, and it is characterized in that: various amino acid whose content are by going out finished product amino acid profiles requirement batching in the check material protein; Batching 1 corn, peanut meal siccative in the still 1, the weak acid hydrolysis, 1-4N, 8-10h until the titanium chain thoroughly untie → mistake →
Filter to such an extent that liquid A → filter residue is made batching 2 blood meals, dregs of beans, shellfish meat in the fuel still 2, weak base hydrolysis 1-4N, 12-20h → filter → liquid B neutralizer AB, PH7 for 130-200 ℃
130-200 ℃ of slag → fuel
With organic solvent 1 counter current contact advance tower 1 → extraction → solvent 1 go into tower 2 and F liquid counter current contact →
→ concentrated → cooling → filter → filtrate concentrates → transfers PH5 → crystallisation by cooling → filter → ethanol and makes with extra care → get tryptophane
Serine is made with extra care → got to slag slag D liquid accent PH6.5-7.5 → concentrate → leave standstill → filter → ethanol
G liquid
Filtration when G liquid is transferred PH3 → filtration → accent PH8 when leaving standstill → keeping 30 ℃ → concentrate → leave standstill → 30 ℃ →
Get tyrosine and get L-glutamic acid accent PH7 → 30 ℃ filtration → concentrated → cooling → 0-10 ℃ filtration → accent PH3.8 → concentrated → 20 ℃ of filtration → filtrates
↓ ↓ ↓
Gelucystine aspartic acid Methionin is transferred → 10 ℃ of filtration → accent PH7 of PH2.7 → concentrate → be concentrated into Be ' 30 → filtration → filter residue dehydrated alcohol filter wash,
↓
Glycine, L-Ala filtrate are continued to employ → must be contained proline(Pro) ethanol → recovery ethanol and gets proline(Pro), so far separate fully.
2, amino acid needed by human body extracting method according to claim 1 is characterized in that described
A. solvent 1 is an organic extractant, and its prescription is:
Di (isooctyl) phosphate 35-85%
Aviation kerosene 55-5%
Octanol 10%
B. solvent 2 is for containing the aromatic solvent of doped quaternary ammonium salt 10-30%;
C.F liquid is the pickle solution that contains NaCL.
3, amino acid needed by human body series product comprise the L type amino acid of various single components it is characterized in that the prescription of amino acid soy sauce is: aminoacids complex 4-6% Folium Bambosae extract 0.5-1%
Health care salt 11-15% Potenlini 0.5-1%
Maltose 10-15% phytic acid 0.5-1%
Sorbyl alcohol 1-5% glycerol 0.5%
All the other are pure water for white sugar 1%
Health care salt is the inorganic salt that contain potassium, magnesium, calcium salt.
4, amino acid products series according to claim 3, the L type amino acid that comprises various single components, it is characterized in that diabetic subject's beverage formula is: get the aminoacids complex of making by claim 1 method and make 20% solution, pears, preferred peace fruit pears, Chinese pear, sorb, 500g infusion; Herbal medicine: add sorbyl alcohol 5g in the smooth slender acanthopanax 30g of genseng 500g coptis root 10g lotus-seed kernel 20g Grosvenor Momordica 80g Wu Chia Pee 30g Poria cocos 40g Fructus Corni 80g gynostemma pentaphylla 30g Chinese yam 40g Chinese cassia tree 30g root bark of tree peony 20g root of herbaceous peony 30g shrimp Radix Angelicae Sinensis 30g Wu taro 10g Asian puccoon 20g shizandra berry 30g pollen 50g Ligusticum wallichii 20g the root of straight ladybell 90g fennel 30g mulberry fruit 20g water drug-decocting concentrating liquid, get juice 1000ml preparation: pear juice concentrated solution 480ml, amino acid solution 480ml, soup 40ml mixes, and gets the 1000ml beverage.
5, amino acid products series according to claim 3 comprises the L type amino acid of making by claim 1 method, it is characterized in that quick-acting amino acid sports beverages prescriptions: g/1000mL
Compositing acid solution 10%800-900ml, honey 20-60ml, triglyceride 10-30ml, Yelkin TTS 20-60g, citric acid 6-10g, sorbyl alcohol 5g, various vitamin A, B, C, D, E and the mineral calcium, zinc, iron, the potassium that contain amino sour 9g/L of Radix Asparagi and arginine 15g/L are a small amount of, Radix Et Caulis Acanthopanacis Senticosi, Radix Panacis Quinquefolii, Fructus Hippophae, each 10-50g decocting and concentrating of Grosvenor Momordica are got juice 10-30ml
6, amino acid products series according to claim 3 comprises the L type amino acid of various single components it is characterized in that amino acid man oral liquid prescription: g/100mL
Arginine 10g aspartic acid 2g herbal medicine: genseng, the tuber of multiflower knotweed, Herba Epimedii, slender acanthopanax, Nandina domestica, each 20-30g water boiling concentration of Radix Rehmanniae Preparata are got juice 10-15ml sorbyl alcohol 0.5g, add a small amount of Sucus Glycyrrhizae, glucose is sweeting agent, 10-15ml.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97105098A CN1089088C (en) | 1996-10-08 | 1997-02-18 | Method for extracting amino acid needed by human body and amino acid products series |
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| CN96119464.2 | 1996-10-08 | ||
| CN96119464 | 1996-10-08 | ||
| CN97105098A CN1089088C (en) | 1996-10-08 | 1997-02-18 | Method for extracting amino acid needed by human body and amino acid products series |
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| Publication Number | Publication Date |
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| CN1173487A true CN1173487A (en) | 1998-02-18 |
| CN1089088C CN1089088C (en) | 2002-08-14 |
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| CN97105098A Expired - Fee Related CN1089088C (en) | 1996-10-08 | 1997-02-18 | Method for extracting amino acid needed by human body and amino acid products series |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103880480A (en) * | 2014-01-15 | 2014-06-25 | 华侨大学 | Special amino-acid organic nutrient fertilizer for tieguanyin tea plants and preparation method thereof |
| CN105105078A (en) * | 2015-09-09 | 2015-12-02 | 陈俊豪 | Delicious scallop juice producing method |
| CN106831465A (en) * | 2016-12-28 | 2017-06-13 | 安徽省虹升生物股份有限公司 | A kind of method by hydrolyzing refinement beta Alanine in gelatine |
| CN106831466A (en) * | 2016-12-28 | 2017-06-13 | 安徽省虹升生物股份有限公司 | A kind of conventional storage method of beta Alanine |
| CN107216265A (en) * | 2017-06-09 | 2017-09-29 | 江苏三宝药业有限公司 | The method that L tyrosine is extracted from hydrolytic liquid of plant protein |
| CN107858174A (en) * | 2017-11-23 | 2018-03-30 | 成都艾伟孚生物科技有限公司 | A kind of special Embryo Culture mineral oil in vitro fertilization and preparation method thereof |
| CN108186429A (en) * | 2017-10-20 | 2018-06-22 | 新疆于田瑰觅生物科技股份有限公司 | A kind of method that amino acid is prepared from rose slag |
| CN112827211A (en) * | 2021-02-07 | 2021-05-25 | 三益创价生物科技(深圳)有限公司 | Method for extracting high-content amino acid from gynura segetum and extract |
-
1997
- 1997-02-18 CN CN97105098A patent/CN1089088C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103880480A (en) * | 2014-01-15 | 2014-06-25 | 华侨大学 | Special amino-acid organic nutrient fertilizer for tieguanyin tea plants and preparation method thereof |
| CN105105078A (en) * | 2015-09-09 | 2015-12-02 | 陈俊豪 | Delicious scallop juice producing method |
| CN106831465A (en) * | 2016-12-28 | 2017-06-13 | 安徽省虹升生物股份有限公司 | A kind of method by hydrolyzing refinement beta Alanine in gelatine |
| CN106831466A (en) * | 2016-12-28 | 2017-06-13 | 安徽省虹升生物股份有限公司 | A kind of conventional storage method of beta Alanine |
| CN106831466B (en) * | 2016-12-28 | 2018-05-22 | 安徽省虹升生物股份有限公司 | A kind of conventional storage method of Beta-alanine |
| CN107216265A (en) * | 2017-06-09 | 2017-09-29 | 江苏三宝药业有限公司 | The method that L tyrosine is extracted from hydrolytic liquid of plant protein |
| CN108186429A (en) * | 2017-10-20 | 2018-06-22 | 新疆于田瑰觅生物科技股份有限公司 | A kind of method that amino acid is prepared from rose slag |
| CN107858174A (en) * | 2017-11-23 | 2018-03-30 | 成都艾伟孚生物科技有限公司 | A kind of special Embryo Culture mineral oil in vitro fertilization and preparation method thereof |
| CN112827211A (en) * | 2021-02-07 | 2021-05-25 | 三益创价生物科技(深圳)有限公司 | Method for extracting high-content amino acid from gynura segetum and extract |
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| Publication number | Publication date |
|---|---|
| CN1089088C (en) | 2002-08-14 |
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