CN117303944A - Bright and subtotal ceramic rock plate and preparation method thereof - Google Patents
Bright and subtotal ceramic rock plate and preparation method thereof Download PDFInfo
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- CN117303944A CN117303944A CN202311615710.0A CN202311615710A CN117303944A CN 117303944 A CN117303944 A CN 117303944A CN 202311615710 A CN202311615710 A CN 202311615710A CN 117303944 A CN117303944 A CN 117303944A
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- glaze
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- 239000000919 ceramic Substances 0.000 title claims abstract description 65
- 239000011435 rock Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000013461 design Methods 0.000 claims abstract description 10
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical group [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 88
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 56
- 235000012239 silicon dioxide Nutrition 0.000 claims description 46
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 42
- 239000000292 calcium oxide Substances 0.000 claims description 37
- 235000012255 calcium oxide Nutrition 0.000 claims description 37
- 239000000377 silicon dioxide Substances 0.000 claims description 37
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 33
- 229910052810 boron oxide Inorganic materials 0.000 claims description 30
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 30
- 238000005507 spraying Methods 0.000 claims description 25
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 24
- 239000011787 zinc oxide Substances 0.000 claims description 21
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 20
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 20
- 229940116411 terpineol Drugs 0.000 claims description 20
- 239000000395 magnesium oxide Substances 0.000 claims description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 19
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 19
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 18
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 18
- 238000000498 ball milling Methods 0.000 claims description 17
- 239000005995 Aluminium silicate Substances 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 229910052656 albite Inorganic materials 0.000 claims description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims description 14
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 14
- 239000010427 ball clay Substances 0.000 claims description 14
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 239000010459 dolomite Substances 0.000 claims description 14
- 229910000514 dolomite Inorganic materials 0.000 claims description 14
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 14
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000010434 nepheline Substances 0.000 claims description 14
- 229910052664 nepheline Inorganic materials 0.000 claims description 14
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 14
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 14
- 239000010453 quartz Substances 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 12
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 12
- 238000003723 Smelting Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 229910052642 spodumene Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 238000007873 sieving Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- -1 low-temperature frit Chemical compound 0.000 claims description 6
- 230000010354 integration Effects 0.000 claims 1
- 238000010304 firing Methods 0.000 abstract description 7
- 238000005336 cracking Methods 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 5
- 239000006104 solid solution Substances 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 230000005484 gravity Effects 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000007921 spray Substances 0.000 description 6
- 210000003298 dental enamel Anatomy 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- 238000005034 decoration Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000011868 grain product Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000001579 optical reflectometry Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention discloses a ceramic rock plate integrating brightness and a preparation method thereof, and belongs to the technical field of ceramic rock plate preparation. The preparation of the ceramic rock plate comprises the following steps: manufacturing a green body; applying the ground coat on the surface of the green body to prepare a green body A; applying the bright planar glaze on the surface of the green body A to prepare a green body B; uniformly coating the glaze paste on the surface of the green body B to prepare a green body C; the green body C is subjected to color design by an ink jet machine, and matte ink is sprayed on the surface of the green body C to prepare a green body D; placing the green body D in a kiln for firing to obtain a ceramic rock plate, superposing a bright planar glaze and matte ink, wherein the bright and matte ink is different to enable the surface of the rock plate to generate three-dimensional sense and vividness; in the firing process, spodumene forms a solid solution to fill gaps of the glaze layer, water in the inner layer is locked, the viscosity of the inner layer glaze is kept, and the inner layer glaze and the outer layer glaze are tightly combined; in the high-temperature firing, the interface connection of the glaze paste and the inner and outer layers of glaze generates nano-scale composite crystalline phase connection, so that the anti-glaze cracking performance is improved.
Description
Technical Field
The invention relates to the technical field of ceramic rock plate preparation, in particular to a ceramic rock plate integrating brightness and subtotal and a preparation method thereof.
Background
The building ceramic tile is used as a decorative material for beautifying living space and is widely applied to the home decoration industry. The ceramic rock plate is used as a novel building ceramic tile product, and the super-large specification of the ceramic rock plate can bear more abundant texture elements than the traditional ceramic tile, and the ceramic rock plate has the advantages of simple atmosphere with decorative effect, less gaps, avoidance of dirt collection, high construction paving efficiency and the like, so that the occupancy of the ceramic rock plate in the market of high-end household products is continuously increased.
The surface of the ceramic rock plate is divided into a sub-surface (fine sub-surface, coarse sub-surface, texture surface, fire surface, water ripple, golden velvet and the like) and a bright surface, the compact lines and the smooth surface of the matte ceramic rock plate strengthen the compact value, the ceramic is returned to the purest source, the light reflection coefficient is very low, the light pollution is not caused when the ceramic rock plate is used for decoration, the eyeballs of people are not stimulated, the vision is more comfortable, and the ceramic rock plate has a smooth and naive feeling; the polished ceramic rock plate has brighter glossiness, the polished rock plate has a mirror surface effect with brightness higher than 50 degrees, and the polished rock plate, especially white polished continuous grain products, has wider application, high glossiness, smooth surface, strong light reflectivity and the like, is widely applied to the fields of architectural decoration, indoor design and the like, and has brighter and wider overall space due to the mirror surface effect, and can improve the aesthetic feeling and luxury feeling of the space.
The ceramic rock plate with the bright and the semi-integral body is prepared by superposing the matte glaze and the bright glaze, and the novel ceramic rock plate can integrate the advantages of the matte glaze and the bright glaze to a certain extent and has more excellent attractive appearance.
First, the matte glaze generally exhibits a low-tone, natural texture, giving a feeling of simplicity and coarseness. The method can reduce the reflection of light, increase the texture and the texture of the ceramic surface, lead the ceramic surface to show a unique artistic charm, effectively hide some surface defects such as scratches or stains, and lead the whole visual effect to be smoother and consistent; the bright glaze has high luster and reflecting effect, and can make the ceramic surface appear bright and smooth, strengthen the plumpness and brightness of color, make the color vivider and raise the overall ornamental value and light feeling.
The ceramic rock plate with the bright and the semi-integral body, which is prepared by superposing and mixing the matte glaze and the bright glaze, has the texture and the texture of the matte glaze and the bright luster of the bright glaze in the aspect of surface texture, increases the ornamental value and the layering sense, shows more colorful effects, is attractive in aesthetic degree, has unique texture and color effect, and brings more rich and fine visual experience for people.
However, in the firing process, the outer glaze melts relatively early and has certain sinking fluidity, so that the flow between glaze layers is inconsistent, the spacing between the section levels of the glaze layers is increased, the bonding area between the glaze layers is reduced, the bonding force between the glaze layers is weakened, the bonding strength of the whole glaze layers is reduced, and the risk of falling of the glaze layers is increased in the use process, especially under the environmental conditions of external force impact or severe change. After the level spacing is increased, the bonding area between the glaze layers is reduced, the connection points between the glaze layers are reduced, the problems of cracks, deformation or falling off and the like of the glaze layers are caused under the influence of external conditions such as long-term use or temperature change and the like, so that the bonding stability of the glaze layers is reduced, the glaze layers are easy to damage due to the reduction of bonding strength and stability of the glaze layers, the service life of the ceramic rock plate is shortened, the maintenance, repair or replacement of the glaze layers are required more frequently, and the use cost and the workload are increased.
Disclosure of Invention
The invention discloses a ceramic rock plate integrating brightness and a preparation method thereof, and belongs to the technical field of ceramic rock plate preparation. The preparation of the ceramic rock plate comprises the following steps: manufacturing a green body; applying the ground coat on the surface of the green body to prepare a green body A; applying the bright planar glaze on the surface of the green body A to prepare a green body B; uniformly coating the glaze paste on the surface of the green body B to prepare a green body C; performing color design on the green body C by an ink jet machine, and spraying matte ink on the surface of the green body C to obtain a green body D; and (3) placing the green body D in a kiln to fire for 40-60min at 1120-1250 ℃ to obtain the ceramic rock plate.
The invention aims to solve the technical problems: the ceramic rock plate with excellent glaze crack resistance and high beautiful appearance is prepared.
The aim of the invention can be achieved by the following technical scheme:
the preparation method of the ceramic rock plate comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating the glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying matte ink on the surface of the green body C to obtain a green body D;
(6) And (3) placing the green body D in a kiln to fire for 40-60min at 1120-1250 ℃ to obtain the ceramic rock plate.
As a further scheme of the invention, the preparation of the primer comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, stirring uniformly, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze.
As a further scheme of the invention, the mass ratio of the nepheline, the albite, the kaolin, the ball clay, the calcined alumina, the quartz, the barium carbonate, the potassium feldspar, the dolomite, the zinc oxide, the low-temperature frit, the deionized water, the sodium tripolyphosphate and the sodium hydroxymethyl cellulose is 8-13:15-20:5-10:2-5:5-10:10-15:5-10:10-15:5-10:3:15-20:33.2-52.4:0.1245-0.1965:0.2905-0.4585.
As a further aspect of the present invention, the bright planar glaze comprises the following chemical components:
10-11 parts by mass of alumina
50-55 parts by mass of silicon dioxide
14-17 parts by mass of quicklime
4-6 parts by mass of magnesium oxide
5-6 parts by mass of barium oxide
2 to 2.1 parts by mass of sodium oxide
4-5 parts by mass of potassium oxide
0.4-0.5 parts by mass of boron oxide.
As a further scheme of the invention, the matte ink comprises the following raw materials in parts by mass:
10-11 parts by mass of alumina
50-55 parts by mass of silicon dioxide
14-17 parts by mass of quicklime
4-6 parts by mass of magnesium oxide
4-5 parts by mass of potassium oxide
7-7.5 parts by mass of zinc oxide
12-18 parts of spodumene.
As a further scheme of the invention, the preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 1-2 hours, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 2-3 hours, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20-30 minutes to obtain the glaze paste;
wherein the mass ratio of the aluminum oxide to the silicon dioxide to the calcium oxide to the boron oxide to the terpineol is 20-23:18-20:20:20:78-83.
As a further aspect of the present invention, in the step (2), the method of applying the primer to the surface of the green body is spraying; in the step (3), the mode of applying the bright planar glaze to the surface of the blank body A is glazing.
As a further aspect of the present invention, in the step (2), the method of applying the primer to the surface of the green body is spraying; in the step (3), the bright planar glaze is applied to the surface of the blank A in a glaze spraying mode.
As a further scheme of the invention, in the step (2), the mode of applying the primer to the surface of the green body is glazing; in the step (3), the mode of applying the bright planar glaze to the surface of the blank body A is glazing.
The ceramic rock plate with the bright and the dark integrated body is prepared by the preparation method.
The invention has the beneficial effects that:
according to the ceramic rock plate with the integrated brightness and the preparation method, the ceramic rock plate with the integrated brightness and the integrated brightness is prepared by superposing the bright planar glaze and the matte ink, so that the surface of the ceramic rock plate presents a frosting effect, the touch feeling is finer and more comfortable, and the brightness difference enables the surface of the rock plate to generate a stereoscopic effect and a light shadow effect, so that vivid and strong visual impact can be provided for people;
further, in the superposition firing process of the bright plane glaze and the matte ink, spodumene in the matte ink positioned on the outer layer forms a solid solution at high temperature to fill gaps of the glaze layer, water in the inner layer is locked, the viscosity of the glaze in the inner layer is kept, and the glaze in the inner layer is prevented from being cracked;
further, in the firing process, the oxide in the glaze paste permeates and infiltrates into an inner glaze layer formed by the bright plane glaze and an outer glaze layer formed by the matte ink, and the inner glaze layer and the outer glaze layer are tightly connected through the glaze paste.
Drawings
The invention is further described below with reference to the accompanying drawings.
FIG. 1 is a schematic view of a ceramic rock plate made in example 1 of a method for making a ceramic rock plate with a bright sub-body according to the present invention;
FIG. 2 is a schematic view of a ceramic rock plate with a bright sub-body and a ceramic rock plate manufactured in example 2 of the manufacturing method;
fig. 3 is a schematic view of a ceramic rock plate with a bright sub-body and a ceramic rock plate manufactured in example 3 of the manufacturing method.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments, and all other embodiments obtained by those skilled in the art without making creative efforts based on the embodiments of the present invention are included in the protection scope of the present invention.
Example 1
The preparation method of the ceramic rock plate integrating the brightness and the sub-integration comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating 50g (300 x 600 plates) of glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying 80g (300 x 600 discs) of matte ink on the surface of the green body C to prepare a green body D;
(6) And (3) placing the green body D in a kiln to fire for 40min at 1120 ℃ to obtain the ceramic rock plate.
Wherein:
the preparation of the ground coat comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, uniformly stirring, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze; the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 8:15:5:2:5:10:5:10:5:3:15:33.2:0.1245:0.2905.
the bright planar glaze comprises the following chemical components:
10 parts by mass of alumina
50 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
Barium oxide 5 parts by mass
Sodium oxide 2 parts by mass
4 parts by mass of potassium oxide
And 0.4 parts by mass of boron oxide.
The matte ink comprises the following raw materials in parts by mass:
10 parts by mass of alumina
50 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
4 parts by mass of potassium oxide
Zinc oxide 7 parts by mass
Spodumene 12 parts by mass.
The preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 1h, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 2h, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain glaze paste; wherein, the mass ratio of the aluminum oxide, the silicon dioxide, the calcium oxide, the boron oxide and the terpineol is 20:18:20:20:78.
the low-temperature frit comprises the following raw materials in parts by mass:
alumina 9.4 parts by mass
46.3 parts by mass of silica
15.3 parts by mass of quicklime
4.3 parts by mass of magnesium oxide
11.2 parts by mass of barium oxide
Sodium oxide 2.2 parts by mass
And 0.4 parts by mass of boron oxide.
In the step (2), the mode of applying the primer to the surface of the green body is glaze spraying, the specific gravity of the primer is 1.55, and the glaze amount of the glaze spraying primer is 80g (300 x 600 plates); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.82, and the glaze amount of the glazing is 70g (300 x 600 plates).
Example 2
The preparation method of the ceramic rock plate integrating the brightness and the sub-integration comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating 55g (300 x 600 plates) of glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying 85g (300 x 600 discs) of matte ink on the surface of the green body C to prepare a green body D;
(6) And (5) placing the green body D in a kiln to fire for 50min at 1140 ℃ to obtain the ceramic rock plate.
Wherein:
the preparation of the ground coat comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, uniformly stirring, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze; the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 10:18:8:4:7:13:8:12:8:3:18:43.7:0.1745:0.3905.
the bright planar glaze comprises the following chemical components:
alumina 10.5 parts by mass
53 parts by mass of silicon dioxide
15 parts by mass of quicklime
5 parts by mass of magnesium oxide
Barium oxide 5.5 parts by mass
Sodium oxide 2.05 parts by mass
4.5 parts by mass of potassium oxide
0.45 parts by mass of boron oxide.
The matte ink comprises the following raw materials in parts by mass:
alumina 10.5 parts by mass
52 parts by mass of silicon dioxide
15 parts by mass of quicklime
5 parts by mass of magnesium oxide
4.5 parts by mass of potassium oxide
Zinc oxide 7.3 parts by mass
15 parts of spodumene.
The preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 1.5 hours, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 2.5 hours, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 25 minutes to obtain the glaze paste; wherein, the mass ratio of the aluminum oxide, the silicon dioxide, the calcium oxide, the boron oxide and the terpineol is 22:19:20:20:80.
the low-temperature frit comprises the following raw materials in parts by mass:
alumina 9.5 parts by mass
46.5 parts by mass of silica
15.5 parts by mass of quicklime
4.4 parts by mass of magnesium oxide
11.4 parts by mass of barium oxide
Sodium oxide 2.25 parts by mass
0.45 parts by mass of boron oxide.
In the step (2), the mode of applying the primer to the surface of the green body is glaze spraying, the specific gravity of the primer is 1.55, and the glaze amount of the glaze spraying primer is 80g (300 x 600 plates); in the step (3), the mode of applying the bright flat glaze to the surface of the green body A is glaze spraying, the specific gravity of the bright flat glaze is 1.52, and the glaze amount of the bright flat glaze sprayed is 60g (300 x 600 plates).
Example 3
The preparation method of the ceramic rock plate integrating the brightness and the sub-integration comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating 60g (300 x 600 discs) of glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying 90g (300 x 600 discs) of matte ink on the surface of the green body C to prepare a green body D;
(6) And (3) placing the green body D in a kiln to fire at 1250 ℃ for 60min, and obtaining the ceramic rock plate.
Wherein:
the preparation of the ground coat comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, uniformly stirring, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze; the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 13:20:10:5:10:15:10:15:10:3:20:52.4:0.1965:0.4585.
the bright planar glaze comprises the following chemical components:
11 parts by mass of alumina
55 parts by mass of silicon dioxide
17 parts by mass of quicklime
Magnesium oxide 6 parts by mass
Barium oxide 6 parts by mass
Sodium oxide 2.1 parts by mass
Potassium oxide 5 parts by mass
And 0.5 parts by mass of boron oxide.
The matte ink comprises the following raw materials in parts by mass:
11 parts by mass of alumina
55 parts by mass of silicon dioxide
17 parts by mass of quicklime
Magnesium oxide 6 parts by mass
Potassium oxide 5 parts by mass
7.5 parts by mass of zinc oxide
Spodumene 18 parts by mass.
The preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 2 hours, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 3 hours, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 30 minutes to obtain the glaze paste; wherein, the mass ratio of the aluminum oxide, the silicon dioxide, the calcium oxide, the boron oxide and the terpineol is 23:20:20:20:83.
the low-temperature frit comprises the following raw materials in parts by mass:
alumina 9.6 parts by mass
46.7 parts by mass of silica
15.7 parts by mass of quicklime
4.5 parts by mass of magnesium oxide
11.6 parts by mass of barium oxide
Sodium oxide 2.3 parts by mass
And 0.5 parts by mass of boron oxide.
In the step (2), the mode of applying the primer on the surface of the green body is that the primer is coated with the glaze, the specific gravity of the primer is 1.85, and the glaze amount of the coated primer is 60g (300 x 600 plates); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.82, and the glaze amount of the glazing is 70g (300 x 600 plates).
Example 4
The difference from example 1 is that in step (2), the pattern of applying the primer to the green body surface is a sprayed primer, the specific gravity of the primer is 1.58, and the amount of the primer sprayed primer is 80g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.85, and the glaze amount of the glazing is 70g (300 x 600 plates).
Example 5
The difference from example 1 is that in step (2), the pattern of applying the primer to the green body surface is a glaze spray, the specific gravity of the primer is 1.60, and the glaze amount of the primer spray is 80g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the green body A is glazing, the specific gravity of the bright flat glaze is 1.87, and the glaze amount of the glazing is 70g (300 x 600 plates).
Example 6
The difference from example 2 is that in step (2), the pattern of applying the primer to the green body surface is a glaze spray, the specific gravity of the primer is 1.58, and the glaze amount of the primer spray is 80g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the green body A is glaze spraying, the specific gravity of the bright flat glaze is 1.55, and the glaze amount of the bright flat glaze sprayed is 60g (300 x 600 plates).
Example 7
The difference from example 2 is that in step (2), the pattern of applying the primer to the green body surface is a glaze spray, the specific gravity of the primer is 1.60, and the glaze amount of the primer spray is 80g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the green body A is glaze spraying, the specific gravity of the bright flat glaze is 1.57, and the glaze amount of the bright flat glaze sprayed is 60g (300 x 600 plates).
Example 8
The difference from example 3 is that in step (2), the pattern of applying the primer to the green body surface is a primer, the specific gravity of the primer is 1.88, and the amount of the primer to be applied is 60g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.85, and the glaze amount of the glazing is 70g (300 x 600 plates).
Example 9
The difference from example 3 is that in step (2), the pattern of applying the primer to the surface of the green body is a pattern of pouring, the specific gravity of the primer is 1.90, and the amount of the primer poured is 60g (300 x 600 discs); in the step (3), the mode of applying the bright flat glaze to the surface of the green body A is glazing, the specific gravity of the bright flat glaze is 1.87, and the glaze amount of the glazing is 70g (300 x 600 plates).
Comparative example 1
The preparation method of the ceramic rock plate integrating the brightness and the sub-integration comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating 50g (300 x 600 plates) of glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying 80g (300 x 600 discs) of matte ink on the surface of the green body C to prepare a green body D;
(6) And (5) placing the green body D in a kiln to fire for 40min at 1120 ℃ to obtain the ceramic rock plate.
Wherein:
the preparation of the ground coat comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, uniformly stirring, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze; the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 8:15:5:2:5:10:5:10:5:3:15:33.2:0.1245:0.2905.
the bright planar glaze comprises the following chemical components:
10 parts by mass of alumina
50 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
Barium oxide 5 parts by mass
Sodium oxide 2 parts by mass
4 parts by mass of potassium oxide
And 0.4 parts by mass of boron oxide.
The matte ink comprises the following raw materials in parts by mass:
16 parts by mass of alumina
56 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
4 parts by mass of potassium oxide
And 7 parts by mass of zinc oxide.
The preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 1h, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 2h, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain glaze paste; wherein, the mass ratio of the aluminum oxide, the silicon dioxide, the calcium oxide, the boron oxide and the terpineol is 20:18:20:20:78.
the low-temperature frit comprises the following raw materials in parts by mass:
alumina 9.4 parts by mass
46.3 parts by mass of silica
15.3 parts by mass of quicklime
4.3 parts by mass of magnesium oxide
11.2 parts by mass of barium oxide
Sodium oxide 2.2 parts by mass
And 0.4 parts by mass of boron oxide.
In the step (2), the mode of applying the primer to the surface of the green body is glaze spraying, the specific gravity of the primer is 1.55, and the glaze amount of the glaze spraying primer is 80g (300 x 600 plates); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.82, and the glaze amount of the glazing is 70g (300 x 600 plates).
Comparative example 2
The preparation method of the ceramic rock plate integrating the brightness and the sub-integration comprises the following steps:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Performing color design on the blank B by an ink jet machine, and spraying 80g (300 x 600 discs) of matte ink on the surface of the blank B to prepare a blank E;
(5) And (5) placing the blank E in a kiln to fire for 40min at 1120 ℃ to obtain the ceramic rock plate.
Wherein:
the preparation of the ground coat comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, uniformly stirring, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze; the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 8:15:5:2:5:10:5:10:5:3:15:33.2:0.1245:0.2905.
the bright planar glaze comprises the following chemical components:
10 parts by mass of alumina
50 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
Barium oxide 5 parts by mass
Sodium oxide 2 parts by mass
4 parts by mass of potassium oxide
And 0.4 parts by mass of boron oxide.
The matte ink comprises the following raw materials in parts by mass:
10 parts by mass of alumina
50 parts by mass of silicon dioxide
14 parts by mass of quicklime
Magnesium oxide 4 parts by mass
4 parts by mass of potassium oxide
Zinc oxide 7 parts by mass
Spodumene 12 parts by mass.
The low-temperature frit comprises the following raw materials in parts by mass:
alumina 9.4 parts by mass
46.3 parts by mass of silica
15.3 parts by mass of quicklime
4.3 parts by mass of magnesium oxide
11.2 parts by mass of barium oxide
Sodium oxide 2.2 parts by mass
And 0.4 parts by mass of boron oxide.
In the step (2), the mode of applying the primer to the surface of the green body is glaze spraying, the specific gravity of the primer is 1.55, and the glaze amount of the glaze spraying primer is 80g (300 x 600 plates); in the step (3), the mode of applying the bright flat glaze to the surface of the blank body A is glazing, the specific gravity of the bright flat glaze is 1.82, and the glaze amount of the glazing is 70g (300 x 600 plates).
Comparative example 3
The difference from example 1 is the preparation of the enamel paste;
the preparation of the glaze paste comprises the following steps: mixing silicon dioxide, calcium oxide and boron oxide, ball milling for 1h, placing in a muffle furnace, smelting for 2h at 1300 ℃, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain the glaze; wherein the mass ratio of the silicon dioxide to the calcium oxide to the boron oxide to the terpineol is 38:20:20:78.
comparative example 4
The difference from example 1 is the preparation of the enamel paste;
the preparation of the glaze paste comprises the following steps: mixing aluminum oxide, calcium oxide and boron oxide, ball milling for 1h, placing in a muffle furnace, smelting for 2h at 1300 ℃, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain the glaze paste; wherein, the mass ratio of the aluminum oxide to the calcium oxide to the boron oxide to the terpineol is 38:20:20:78.
comparative example 5
The difference from example 1 is the preparation of the enamel paste;
the preparation of the glaze paste comprises the following steps: mixing aluminum oxide, silicon dioxide and boron oxide, ball milling for 1h, placing in a muffle furnace, smelting for 2h at 1300 ℃, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain the glaze; wherein the mass ratio of the aluminum oxide to the silicon dioxide to the boron oxide to the terpineol is 40:18:20:78.
comparative example 6
The difference from example 1 is the preparation of the enamel paste;
the preparation of the glaze paste comprises the following steps: mixing aluminum oxide, silicon dioxide and calcium oxide, ball milling for 1h, placing in a muffle furnace, smelting for 2h at 1300 ℃, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20min to obtain the glaze; wherein, the mass ratio of the aluminum oxide to the silicon dioxide to the calcium oxide to the terpineol is 20:18:40:78.
performance testing
The ceramic rock plates produced in examples 1 to 9 and comparative examples 1 to 6 were subjected to the anti-glaze cracking performance test according to GB/T34252-2017, and the test results are shown in Table 1 below.
TABLE 1
As can be seen from table 1, comparative examples 1-2 were prepared on the basis of example 1, wherein comparative example 1 was free of spodumene, resulting in a significant decrease in the anti-glaze cracking properties thereof; comparative example 2 was not applied with Tu You paste, resulting in a significant decrease in the anti-glaze cracking performance, and the anti-glaze cracking performance was worse than comparative example 1; the cracking resistance after firing of comparative examples 3 to 6 was reduced to a different extent than that of example 1 due to the different raw materials during the preparation of the glaze.
The ceramic rock plates prepared in the embodiments 1-3 respectively correspond to the embodiments 1-3, have frosted texture, and give a visual impact to people with brightness difference, and have vividness and three-dimensional effect.
While certain embodiments of the present invention have been described in detail, this disclosure is only for the purpose of illustrating preferred embodiments of the invention and is not to be construed as limiting the scope of the invention. All equivalent changes and modifications within the scope of the present invention are intended to be covered by the present invention.
Claims (10)
1. The preparation method of the ceramic rock plate integrating the brightness and the sub-integration is characterized by comprising the following steps of:
(1) Manufacturing a green body;
(2) Applying the ground coat on the surface of the green body to prepare a green body A;
(3) Applying the bright planar glaze on the surface of the green body A to prepare a green body B;
(4) Uniformly coating the glaze paste on the surface of the green body B to prepare a green body C;
(5) Performing color design on the green body C by an ink jet machine, and spraying matte ink on the surface of the green body C to obtain a green body D;
(6) And (3) placing the green body D in a kiln to fire for 40-60min at 1120-1250 ℃ to obtain the ceramic rock plate.
2. The method for preparing a ceramic rock plate with a bright sub-body according to claim 1, wherein the preparation of the primer comprises the following steps:
mixing nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide and low-temperature frit, stirring uniformly, adding deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose, ball milling, sieving, and removing iron to obtain the ground glaze.
3. The preparation method of the leucinia ceramic rock plate according to claim 2, wherein the mass ratio of nepheline, albite, kaolin, ball clay, calcined alumina, quartz, barium carbonate, potassium feldspar, dolomite, zinc oxide, low-temperature frit, deionized water, sodium tripolyphosphate and sodium hydroxymethyl cellulose is 8-13:15-20:5-10:2-5:5-10:10-15:5-10:10-15:5-10:3:15-20:33.2-52.4:0.1245-0.1965:0.2905-0.4585.
4. The method for preparing a bright sub-integrated ceramic rock plate according to claim 1, wherein the bright planar glaze comprises the following chemical components:
10-11 parts by mass of alumina
50-55 parts by mass of silicon dioxide
14-17 parts by mass of quicklime
4-6 parts by mass of magnesium oxide
5-6 parts by mass of barium oxide
2 to 2.1 parts by mass of sodium oxide
4-5 parts by mass of potassium oxide
0.4-0.5 parts by mass of boron oxide.
5. The preparation method of the bright and matte integrated ceramic rock plate according to claim 1, wherein the matte ink comprises the following raw materials in parts by mass:
10-11 parts by mass of alumina
50-55 parts by mass of silicon dioxide
14-17 parts by mass of quicklime
4-6 parts by mass of magnesium oxide
4-5 parts by mass of potassium oxide
7-7.5 parts by mass of zinc oxide
12-18 parts of spodumene.
6. The method for preparing the ceramic rock plate with the bright and the dark integration according to claim 1, wherein the preparation of the glaze paste comprises the following steps:
mixing and ball milling aluminum oxide, silicon dioxide, calcium oxide and boron oxide for 1-2 hours, placing the mixture in a muffle furnace, smelting the mixture at 1300 ℃ for 2-3 hours, cooling, grinding, adding terpineol, and carrying out ultrasonic vibration for 20-30 minutes to obtain the glaze paste;
wherein the mass ratio of the aluminum oxide to the silicon dioxide to the calcium oxide to the boron oxide to the terpineol is 20-23:18-20:20:20:78-83.
7. The method of claim 1, wherein in step (2), the primer is applied to the green body surface by spraying; in the step (3), the mode of applying the bright planar glaze to the surface of the blank body A is glazing.
8. The method of claim 1, wherein in step (2), the primer is applied to the green body surface by spraying; in the step (3), the bright planar glaze is applied to the surface of the blank A in a glaze spraying mode.
9. The method of claim 1, wherein in step (2), the primer is applied to the green body surface in a pattern of showering; in the step (3), the mode of applying the bright planar glaze to the surface of the blank body A is glazing.
10. A bright sub-body ceramic rock plate made by the method of any one of claims 1-9.
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