CN117270086A - Coated lens with mirror image layer - Google Patents
Coated lens with mirror image layer Download PDFInfo
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- CN117270086A CN117270086A CN202311258981.5A CN202311258981A CN117270086A CN 117270086 A CN117270086 A CN 117270086A CN 202311258981 A CN202311258981 A CN 202311258981A CN 117270086 A CN117270086 A CN 117270086A
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- layer
- nickel
- chromium
- mixed material
- material layer
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- 239000000463 material Substances 0.000 claims abstract description 149
- 229910018487 Ni—Cr Inorganic materials 0.000 claims abstract description 43
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims abstract description 43
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 31
- 230000003287 optical effect Effects 0.000 claims abstract description 30
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 15
- 239000011651 chromium Substances 0.000 claims abstract description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 10
- AZCUJQOIQYJWQJ-UHFFFAOYSA-N oxygen(2-) titanium(4+) trihydrate Chemical compound [O-2].[O-2].[Ti+4].O.O.O AZCUJQOIQYJWQJ-UHFFFAOYSA-N 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000010408 film Substances 0.000 abstract description 89
- 239000000758 substrate Substances 0.000 abstract description 14
- 239000012788 optical film Substances 0.000 abstract description 7
- 238000001771 vacuum deposition Methods 0.000 abstract description 2
- 230000003313 weakening effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 115
- 238000010586 diagram Methods 0.000 description 5
- 230000003595 spectral effect Effects 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Eyeglasses (AREA)
Abstract
The invention discloses a coated lens with a mirror image layer, which comprises a lens substrate, wherein a novel film system is arranged on the surface of the lens substrate, the novel film system comprises a multi-layer structure, the middle of the novel film system is a nickel-chromium material mixed material layer, and the mixing ratio of nickel to chromium materials is 2.5-3.5:0.5-1.5; the physical film thickness range of the nickel-chromium material mixed material layer is 100-400 nm; the nickel-chromium material mixed material layers are alternately stacked with the high refractive index material layers and the low refractive index material layers on two sides of the nickel-chromium material mixed material layers. The novel film system can realize high reflection on both sides of the mixed material layer by absorbing the nickel-chromium material mixed material layer, weakening transmitted light and controlling the optical film thickness of the high-low refractive index materials on both sides. The mirror layer is added in the film layer, so that the two sides of the lens substrate respectively reflect the light of different adjustable light domains, the color and the optical performance of the front side and the back side can be respectively adjusted, and the product connotation of the vacuum coating of the spectacle lens is greatly enriched.
Description
Technical Field
The invention relates to the technical field of optical lenses, in particular to a coated lens with a mirror image layer.
Background
Optical films are composed of a thin, layered medium, a class of optical medium materials that propagate a light beam through an interface. The application of optical films began in the 30 s of the 20 th century. Modern optical films are widely used in the optical and optoelectronic technology field for manufacturing various optical instruments.
The optical film is classified into a reflective film, an antireflection film, a filter film, an optical protective film, a polarizing film, a spectroscopic film, and a phase film according to applications. The first 4 are commonly used. Optical reflective films are used to increase specular reflectivity and are commonly used to fabricate reflective, refractive and resonant cavity devices. The optical antireflection film is deposited on the surface of the optical element to reduce surface reflection and increase transmission of the optical system, and is also called an antireflection film. The optical filter film is used for spectrum or other light division, and has various types and complex structure. The optical protective film is deposited on the surface of metal or other soft and easily-corroded materials or films to increase the strength or stability of the optical protective film and improve the optical properties.
The traditional coating layer in the field has the following defects:
1. the single-sided reflection of the coating layer, the natural complementation of the reflecting surface and the penetrating surface, the incapability of adjusting the transmitted light, and the color-changing lens with the single-sided reflection film can interfere the light rays on the two sides of the lens, thereby affecting the color presentation effect on the two sides of the lens.
2. Poor adhesion to the lens substrate, and is easily corroded and shed in some special atmospheres, thereby affecting the service performance.
Disclosure of Invention
The invention aims to provide a coated lens with a mirror image layer, wherein the mirror image layer is arranged in the film layer, so that the two sides of a lens substrate respectively reflect light in different adjustable light domains, and the adhesive force between the film layer and the lens substrate is strong and is not easy to fall off.
To achieve the above object, the solution of the present invention is: a coated lens with a mirror image layer comprises a lens substrate, wherein a novel film system is arranged on the surface of the lens substrate, the novel film system comprises a multi-layer structure, an intermediate layer is a nickel-chromium material mixed material layer, and the mixing ratio of nickel to chromium materials is 2.5-3.5:0.5-1.5; the physical film thickness range of the nickel-chromium material mixed material layer is 100-400 nm;
the nickel-chromium material mixed material layers are alternately stacked with the high refractive index material layers and the low refractive index material layers on two sides of the nickel-chromium material mixed material layers.
Further, L i An ith layer, R, representing one side of the nickel-chromium material mixed material layer i An ith layer on the other side of the nickel-chromium material mixed material layer, and C represents the nickel-chromium material mixed material layer;
the novel film system comprises L 2 +L 1 +C+R 1 +R 2 Which is provided withWherein L is 1 Is a titanium oxide material layer, L 2 Is a silicon oxide material layer, R 1 Is a titanium oxide material layer, R 2 Is a silicon oxide material layer.
Further, the material of the silicon oxide material layer is silicon dioxide, and the material of the titanium oxide material layer is titanium dioxide or titanium pentoxide.
Further, the L 1 The physical film thickness of the layer is 65.4-0 nm, the optical thickness is 1.0-0L 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
Further, the R 1 The physical film thickness of the layer is 65.4-0 nm, the optical thickness is 1.0-0, R 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
After the scheme is adopted, the beneficial effects of the invention are as follows: the novel film system is realized by dielectric materials, selecting high and low refractive indexes to deposit in vacuum and adding a nickel-chromium material mixed material layer in the middle, wherein the mixing ratio of nickel and chromium materials is 2.5-3.5:0.5-1.5; the physical film thickness of the layer is in the range of 100-400 nm.
The novel film system can realize high reflection on both sides of the mixed material layer by absorbing the nickel-chromium material mixed material layer, weakening transmitted light and controlling the optical film thickness of the high-low refractive index materials on both sides. The mirror layer is added in the film layer, so that the two sides of the lens substrate respectively reflect the light of different adjustable light domains, the color and the optical performance of the front side and the back side can be respectively adjusted, and the product connotation of the vacuum coating of the spectacle lens is greatly enriched.
Drawings
FIG. 1 is a schematic view of a layered structure according to an embodiment of the present invention;
FIG. 2 is a schematic diagram of a layered structure according to an embodiment of the present invention (II)
Fig. 3 is a light path diagram of a conventional coated lens when light passes through:
FIG. 4 is a schematic diagram of a light path through which light passes according to an embodiment of the present invention;
FIG. 5 is a graph of a film spectrum according to an embodiment of the present invention;
FIG. 6 is a graph of a two-film spectral plot in accordance with an embodiment of the present invention;
FIG. 7 is a graph of a three film spectral plot according to an embodiment of the present invention;
FIG. 8 is a graph of a four film spectral plot in accordance with an embodiment of the present invention;
FIG. 9 is a graph of a five film spectral plot of an embodiment of the present invention.
Description of the reference numerals:
1. a lens substrate; 2. a C nickel-chromium material mixed material layer; 3. l (L) 1 A titanium oxide material layer; 4. l (L) 2 A silicon oxide material layer; 5. r is R 1 A titanium oxide material layer; 6. r is R 2 Is a silicon oxide material layer; 7. l (L) 3 ；8、L 4 ；9、R 3 ；10、R 4 。
Detailed Description
The invention will be described in detail with reference to the accompanying drawings and specific embodiments.
The invention provides a coated lens with a mirror image layer. As shown in fig. 1 to 9, the novel film system is arranged on the surface of the lens substrate, and the novel film system can be well attached to the surface of the lens substrate, and meanwhile, double-sided high reflection is ensured, so that the two sides of the lens substrate respectively reflect light of different adjustable light domains without interference.
The novel film system comprises a multi-layer structure, wherein the middle of the novel film system is a nickel-chromium material mixed material layer, and the two sides of the mixed material layer can be designed to stack reflection layers with various colors, namely, high-refractive-index material layers and low-refractive-index material layers are alternately stacked. Through the absorption of the middle mixed material layer, the transmitted light is weakened, and the high reflection can be generated on both sides of the mixed material layer by controlling the optical film thickness of the high and low refractive index materials on both sides, the colors and the optical properties on both sides of the mixed material layer can be respectively adjusted, so that the product presents rich colors.
In the nickel-chromium material mixed material layer, the mixing proportion of nickel and chromium materials is 2.5-3.5:0.5-1.5, and the physical film thickness range of the layer is 100-400 nm. The principle of the design of the mixed material layer is as follows:
the nickel (Ni) neutral beam-splitting and absorbing layer has stable physical property in air, and the nickel coating is mainly characterized in that the nickel has strong passivation capability, and the surface can rapidly generate an extremely thin passivation film to isolate the nickel matrix from air, so that the nickel coating can resist the corrosion of atmosphere, alkali and certain acids. Meanwhile, in the simple salt plating solution of nickel, a plating layer with extremely fine crystals can be obtained, and the plating layer has good polishing performance.
The adhesion capability of metal chromium (Cr) is strong. Cr has very good mechanical strength and chemical stability, and also has very good neutrality, and the change of the spectral ratio with wavelength is very small, so that a chromium film is commonly used for a metal film neutral spectroscope. In the visible region, the beam of the chromium film split reflection light is white, and the beam of the transmission light is slightly brown.
Nickel and chromium are mixed in a ratio of 2.5-3.5:0.5-1.5 to form a mixed material layer, and a layer of chromium is added between the lens base material and the nickel, so that the adhesive force between the nickel and the lens base material is improved, and the mechanical stability of an interface is maintained. The film layer can well give consideration to the mechanical property and the optical property of the film layer.
Setting in the scheme L i An ith layer, R, representing one side of the nickel-chromium material mixed material layer i An i-th layer on the other side of the nickel-chromium material mixed material layer is represented, and C represents the nickel-chromium material mixed material layer. Wherein a larger value of i indicates that the layer is further from the nickel chromium material mixed material layer. The novel film system structure is as follows: l (L) N +......L 3 +L 2 +L 1 +C+R 1 +R 2 +R 3 +......R N 。
The method does not limit the number of the high refractive index material layers and the low refractive index material layers on two sides of the nickel-chromium material mixed material layer, and can freely select the corresponding number of the film layers according to production and processing requirements, wherein the film layers contacted with the lens base material are the low refractive index material layers. As shown in fig. 1, two sides of the nickel-chromium material mixed material layer are respectively provided with a high refractive index material layer and a low refractive index material layer; as shown in fig. 2, two high refractive index material layers and two low refractive index material layers are respectively arranged on two sides of the nickel-chromium material mixed material layer, and the film system structure is as follows: l (L) 4 +L 3 +L 2 +L 1 +C+R 1 +R 2 +R 3 +R 4 。
As shown in fig. 1, in one embodiment, the novel film system structure is: l (L) 2 +L 1 +C+R 1 +R 2 The materials of each layer and the physical film thickness parameters are shown in Table 1.
L 1 Is a titanium oxide material layer, the material of the layer adopts titanium dioxide or titanium pentoxide, L 1 The physical film thickness of the layer is 65.4-0 nm, and the optical thickness is 1.0-0.
L 2 Is a silicon oxide material layer made of silicon dioxide, L 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
C is a nickel-chromium material mixed material layer, the material of the C layer is nickel-chromium material mixed material, the mixing ratio of the nickel and the chromium material is 2.5-3.5:0.5-1.5, and the physical film thickness range is 100-400 nm.
R 1 Is a titanium oxide material layer, the material of the layer adopts titanium dioxide or titanium pentoxide, R 1 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 1.0-0.
R 2 Is a silicon oxide material layer, the material of the layer adopts silicon dioxide, R 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
TABLE 1
TABLE 2
Embodiment one:
the parameters of the structure of each layer of the novel film system in this embodiment are shown in table 2, in which the mixing ratio of the nickel-chromium materials in the nickel-chromium material mixed layer is 3:0.8, and the physical film thickness of the layer is designed to be 115nm. As can be seen from the parameters of the film system of the first example of Table 2 and FIG. 4, the transmittance of the film system was 79.0% at a reference wavelength of 550 nm.
Embodiment two:
the structural parameters of each layer of the novel film system in this embodiment are shown in the second example of table 2, wherein the mixing ratio of the nickel-chromium materials in the nickel-chromium material mixed layer is 3:0.8, and the physical film thickness of the layer is designed to be 250nm. As can be seen from the parameters of the film system of the second example in Table 2 and FIG. 5, the transmittance of the film system was 65.3% at a reference wavelength of 550 nm.
Embodiment III:
the structural parameters of each layer of the novel film system in this embodiment are shown in Table 2, in which the mixing ratio of the nickel-chromium materials in the nickel-chromium material mixed layer is 3:0.8, and the physical film thickness of the layer is designed to be 375nm. As can be seen from the parameters of the film system of the second example in Table 2 and FIG. 5, the transmittance of the film system was 47.5% at a reference wavelength of 550 nm.
Embodiment four:
the structural parameters of each layer of the novel film system in this embodiment are shown in table 2, in which the mixing ratio of the nickel-chromium materials in the nickel-chromium material mixed layer is 2.5:1, and the physical film thickness of the layer is designed to be 115nm. As can be seen from the film system parameters of the fourth example of Table 2 and FIG. 5, the transmittance of the film system was 58.6% at a reference wavelength of 550 nm.
Fifth embodiment:
the structural parameters of each layer of the novel film system in this embodiment are shown in table 2, in which the mixing ratio of the nickel-chromium materials in the nickel-chromium material mixed layer is 3:0.5, and the physical film thickness of the layer is designed to be 115nm. As is clear from the film system parameters of the fourth example in Table 2 and FIG. 5, the transmittance of the film system was 77.8% at a reference wavelength of 550 nm.
Fig. 3 and 4 are schematic views of light paths, wherein the broken lines represent weak light rays and the solid lines represent strong light rays.
FIG. 3 is a light path diagram of a conventional coated lens when light passes through the lens, wherein the film is formed by alternately stacking high and low refractive index materials. As can be seen from fig. 3, the existing conventional coating layer reflects on one side, the light passing through the coating layer is the reflected complementary light (without absorbing film system), the light passes through the high-low refractive index film layer of the common non-absorbing film, the transmitted light is still stronger, the light on both sides of the lens substrate can interfere with and affect each other, and further the color rendering effect on both sides of the lens is affected.
Fig. 4 is a light path diagram of the film-coated lens according to the embodiment when light passes through, the novel film system adds mixed material layers in the film layers formed by alternately stacking high-refractive index materials and low-refractive index materials, the adhesion capability of the mixed material layers is strong, the mixed material layers can absorb the light on two sides strongly, the absorption rate can reach 40% -80%, the transmitted light is weakened, the light on two sides of the mixed material layers is further prevented from interfering with each other, and the color and the optical performance of two sides of the lens can be adjusted respectively.
The above embodiments are only preferred embodiments of the present invention, and are not limited to the present invention, and all equivalent changes made according to the design key of the present invention fall within the protection scope of the present invention.
Claims (5)
1. A coated lens having a mirror layer, characterized by: the novel film system comprises a multilayer structure, wherein an intermediate layer is a nickel-chromium material mixed material layer, and the mixing ratio of nickel to chromium materials is 2.5-3.5:0.5-1.5; the physical film thickness range of the nickel-chromium material mixed material layer is 100-400 nm;
the nickel-chromium material mixed material layers are alternately stacked with the high refractive index material layers and the low refractive index material layers on two sides of the nickel-chromium material mixed material layers.
2. A coated lens having a mirror layer as in claim 1, wherein: l (L) i An ith layer, R, representing one side of the nickel-chromium material mixed material layer i An ith layer on the other side of the nickel-chromium material mixed material layer, and C represents the nickel-chromium material mixed material layer;
the novel film system comprises L 2 +L 1 +C+R 1 +R 2 Wherein L is 1 Is a titanium oxide material layer, L 2 Is a silicon oxide material layer, R 1 Is a titanium oxide material layer, R 2 Is a silicon oxide material layer.
3. A coated lens having a mirror layer as claimed in claim 2, wherein: the material of the silicon oxide material layer is silicon dioxide, and the material of the titanium oxide material layer is titanium dioxide or titanium pentoxide.
4. A coated lens having a mirror layer as claimed in claim 2, wherein: the L is 1 The physical film thickness of the layer is 65.4-0 nm, the optical thickness is 1.0-0L 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
5. A coated lens having a mirror layer as claimed in claim 2, wherein: the R is 1 The physical film thickness of the layer is 65.4-0 nm, the optical thickness is 1.0-0, R 2 The physical film thickness of the layer is 0-94.17 nm, and the optical thickness is 0-1.0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311258981.5A CN117270086A (en) | 2023-09-26 | 2023-09-26 | Coated lens with mirror image layer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311258981.5A CN117270086A (en) | 2023-09-26 | 2023-09-26 | Coated lens with mirror image layer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117270086A true CN117270086A (en) | 2023-12-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311258981.5A Pending CN117270086A (en) | 2023-09-26 | 2023-09-26 | Coated lens with mirror image layer |
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| Country | Link |
|---|---|
| CN (1) | CN117270086A (en) |
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2023
- 2023-09-26 CN CN202311258981.5A patent/CN117270086A/en active Pending
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