CN117263759A - Preparation process of space type high-explosion-heat energy storage broken piece - Google Patents
Preparation process of space type high-explosion-heat energy storage broken piece Download PDFInfo
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- CN117263759A CN117263759A CN202210783727.6A CN202210783727A CN117263759A CN 117263759 A CN117263759 A CN 117263759A CN 202210783727 A CN202210783727 A CN 202210783727A CN 117263759 A CN117263759 A CN 117263759A
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- energy storage
- explosion
- type high
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- heat energy
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- 238000004146 energy storage Methods 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000004880 explosion Methods 0.000 claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000005245 sintering Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 9
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 9
- -1 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002861 polymer material Substances 0.000 claims description 6
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims description 5
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 238000011282 treatment Methods 0.000 claims description 4
- 238000005491 wire drawing Methods 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 2
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 230000006378 damage Effects 0.000 abstract description 20
- 229920002313 fluoropolymer Polymers 0.000 abstract description 14
- 239000004811 fluoropolymer Substances 0.000 abstract description 14
- 239000012634 fragment Substances 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 11
- 238000002715 modification method Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 18
- 239000011258 core-shell material Substances 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 229920001973 fluoroelastomer Polymers 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000011149 active material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZRIMDWRLVGDUBW-UHFFFAOYSA-N 5-hydroxy-2-methylpent-2-enoic acid phosphoric acid Chemical compound P(=O)(O)(O)O.OCCC=C(C(=O)O)C ZRIMDWRLVGDUBW-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000007133 aluminothermic reaction Methods 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000011031 large-scale manufacturing process Methods 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011153 ceramic matrix composite Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- 229910052574 oxide ceramic Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/02—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide with an organic non-explosive or an organic non-thermic component
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/102—Metallic powder coated with organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/1003—Use of special medium during sintering, e.g. sintering aid
- B22F3/1007—Atmosphere
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/0041—Shaping the mixture by compression
Abstract
The invention relates to a preparation process of a space type high-heat-explosion energy storage fragment, which is characterized in that the coating of a fluoropolymer material on nano aluminum is more sufficient by a physical modification method on the basis of the fluoropolymer material, and the energy can be released at maximum efficiency. In addition, the high-explosion heat energy storage structural member is three-dimensionally filled on the basis of the active fragments. The energy storage structure is introduced, so that the damage area is greatly increased when the target object is impacted, and the stealth material is greatly damaged. The introduction of the high-heat-explosion material improves the energy release efficiency of the energy storage structural member with the enlarged damage area. The energy storage structural members are three-dimensionally distributed in the broken piece in a double-cone mode, so that the damage angle is more comprehensive, and the damage area is further improved. In summary, a space type high-explosion heat energy storage broken piece plays a very important role in the field of efficient damage.
Description
Technical Field
The invention relates to a preparation process of a space type high-heat-explosion energy storage broken sheet, and belongs to the field of energy-containing materials and active broken sheets.
Background
Fluoropolymer-based active materials are a very important metastable structure. By means of the detonation-like effect, the target is hit, and in addition to kinetic energy penetration, the detonation-like detonation effect also has high-temperature and overpressure effects, so that the target is damaged to a great extent. The energy storage broken piece is a further innovation of the fluoropolymer active material. The energy storage spiral structural member is filled in the broken piece. Under the action of the launching and flying overload forces, the damaged units in the weak constraint state can be subjected to structural damage to release energy storage fragments, and the energy storage fragments have excellent damage effects on thin shell structures such as thin aluminum plates, fiber reinforced resins, aluminum oxide ceramics, glass ceramics, quartz ceramics, ceramic matrix composite materials and the like.
In recent years, a series of fluoropolymer-based active fragments have been developed by research and development teams, beginning at the university of Beijing. The fluoropolymer matrix active material has excellent comprehensive performance and is widely focused by scientific researchers. So far, there have been team initiated studies of energy storage fragmentation. On the basis of single energy storage broken pieces, the damage power of the broken pieces is further enlarged, and the method is a significant subject.
Disclosure of Invention
The invention aims to further improve the damage capability of the current active fragment, and belongs to the field of special damage technology research.
The preparation of the energy storage structural member introduces substances such as ferric oxide, copper oxide and the like on the basis of the original basic formula, so that the energy storage structural member has a larger bursting effect during penetration and destruction. The core-shell type nano aluminum/fluoropolymer energetic material is adopted, and the preparation steps can be generally summarized into surface functionalization, liquid fluororubber coating and a large amount of polytetrafluoroethylene coating. Polytetrafluoroethylene is hardly dissolved at normal temperature and normal pressure, and fluororubber can be dissolved in organic acetone at normal temperature and normal pressure. The method provides a good idea for us, and the polytetrafluoroethylene and the aluminum particle are well mixed and coated through the transition of the fluororubber. And the space type high-explosion-heat energy storage broken piece is obtained through filling, press fitting, sintering and other processes.
Advantageous effects
1. A preparation process of a space type high-explosion heat energy storage broken sheet is characterized by having both high explosion heat effect and large damage area damage effect. Is characterized in that the adopted material is a fluoropolymer-based active material, has high activity, low sensitivity and high safety performance, and can meet various processing requirements of people. The nano aluminum/fluorine polymer material with the core-shell structure is obtained by a physical coating method, and the operation is simple and easy to implement.
2. In the formula of the energy storage material, a high-heat explosion synergistic agent with a certain proportion is introduced, so that the damage capability of a single energy storage structural member is improved. The inside of the broken piece is spatially filled in the broken piece in a three-dimensional mode with a double-cone structure, so that the damage effect is greatly improved.
Drawings
FIG. 1 is a schematic diagram of an energy storage structure of the present invention;
FIG. 2 core-shell mechanism nanoaluminum morphology;
FIG. 3 is a schematic diagram of an energy storage fragment of the present invention;
FIG. 4 is a photograph of the composite damage effect of a spatial high-heat-burst energy-storage fragment prepared by the invention, impacting a LY12 aluminum plate with a thickness of 2mm at an initial speed of 1000 m/s;
Detailed Description
The invention will be further described with reference to specific examples and figures.
Example 1
A preparation method of a space type high-explosion heat energy storage broken sheet comprises the following specific steps:
the specific formula of the raw materials is as follows,
c=0.08%, mn=2.00%, p=0.035%, s=0.015%, si=0.75%, cr=18.00%, ni=8.00%, n=0.10%, fe=41.02%, feo=30%. FeO is used as a high-explosion heat type synergist, so that a severe aluminothermic reaction occurs when a broken piece impacts a target, and a spiral piece inside the broken piece also has a certain degree of energy release effect. The final energy storage structural member not only plays a certain role in structure, but also has the effect of high-energy damage. The energy storage structural member is molded by adopting a general steel wire machining process, and raw materials are subjected to operations such as drying, coating treatment, heat treatment, wire drawing and the like, so that the spiral telescopic member is obtained.
(1) Preparation of core-shell structured nano aluminum/fluoropolymer material
The nano aluminum fluoride polymer material is obtained by adopting a method of coating aluminum particles with liquid fluorine polymer. Compared with a chemical coating method, the physical coating method is simple to operate and high in feasibility, and can realize large-scale production. Phosphoric acid 2-hydroxyethyl methacrylic acid (PAM) was added to cyclohexanone and the reaction was maintained under nitrogen atmosphere with stirring for 2 hours. Fluororubber was dispersed in the solution and stirred for 2h. Then dispersing the metal powder into the solution to finally obtain the slurry. Extruding and granulating the obtained slurry by a 2mm granulator, and drying the obtained granules at a drying temperature of 6 ℃ to obtain the fluoropolymer coated nano aluminum particles.
(2) Preparation of energy storage broken pieces
And adding the uniformly mixed granules and polytetrafluoroethylene powder into a special forming die according to a calculated mass ratio, and then reasonably assembling an energy storage structural member for pre-pressing. The telescopic spiral structural member is split-packed into a mould according to a head-to-head structure, and is pressed. The pressure is 30MPa, the pressurizing speed is 30N/s, the pressure maintaining time is 5min, the pressure releasing speed is 30N/s, and the energy storage fragments distributed in space are obtained after pressure releasing. Sintering is needed subsequently, the formed test piece after demolding is placed in a sintering furnace for sintering, argon atmosphere is used in the sintering process, the sintering temperature is 360 ℃, the sintering time is 2 hours, the temperature is kept at 327 ℃ for 2 hours, the temperature rising and reducing rates are 1 ℃/min, and the process is carried out along with furnace cooling, so that the preparation process of the space type high-explosion heat energy storage broken piece is obtained.
Example 2
A preparation method of a space type high-explosion heat energy storage broken sheet comprises the following specific steps:
the specific formula of the raw materials is as follows,
c=0.08%, mn=2.00%, p=0.035%, s=0.015%, si=0.75%, cr=18.00%, ni=8.00%, n=0.10%, fe= 36.02%, feo=35%. FeO is used as a high-explosion heat type synergist, so that a severe aluminothermic reaction occurs when a broken piece impacts a target, and a spiral piece inside the broken piece also has a certain degree of energy release effect. The final energy storage structural member not only plays a certain role in structure, but also has the effect of high-energy damage. The energy storage structural member is molded by adopting a general steel wire machining process, and raw materials are subjected to operations such as drying, coating treatment, heat treatment, wire drawing and the like, so that the spiral telescopic member is obtained.
(1) Preparation of core-shell structured nano aluminum/fluoropolymer material
The nano aluminum fluoride polymer material is obtained by adopting a method of coating aluminum particles with liquid fluorine polymer. Compared with a chemical coating method, the physical coating method is simple to operate and high in feasibility, and can realize large-scale production. Phosphoric acid 2-hydroxyethyl methacrylic acid (PAM) was added to cyclohexanone and the reaction was maintained under nitrogen atmosphere with stirring for 2 hours. Fluororubber was dispersed in the solution and stirred for 2h. The metal powder is then dispersed into the solution, eventually yielding a slurry. Extruding and granulating the obtained slurry by a 2mm granulator, and drying the obtained granules at a drying temperature of 6 ℃ to obtain the fluoropolymer coated nano aluminum particles.
(2) Preparation of energy storage broken pieces
Mixing powder: the mass ratio of each component is as follows: nano aluminum particles/polytetrafluoroethylene=30/70, namely, weighing 30g of aluminum powder and 70g of polytetrafluoroethylene powder, drying, placing in an omnibearing planetary ball mill, mixing for 2 hours at the rotating speed of 200rpm/min, and uniformly mixing;
and (3) mould pressing: adding the uniformly mixed powder into a special forming die according to the calculated mass for pre-pressing, wherein the pressure is 30MPa, the pressurizing rate is 30N/s, the pressure maintaining time is 5min, the pressure releasing rate is 30N/s, and demoulding is carried out after pressure releasing to obtain a preliminary energy storage broken piece;
sintering: and (3) placing the obtained energy storage broken piece in a sintering furnace for sintering, wherein argon atmosphere is used in the sintering process, the sintering temperature is 360 ℃, the sintering time is 2h, the temperature is kept for 2h in the cooling process at 327 ℃, the heating and cooling rates are 1 ℃/min, and the energy storage broken piece is cooled along with the furnace, so that the space three-dimensional packed high-explosion heat energy storage broken piece is obtained.
Example 3
A preparation method of a space type high-explosion heat energy storage broken sheet comprises the following specific steps:
the specific formula of the raw materials is as follows,
c=0.08%, mn=2.00%, p=0.035%, s=0.015%, si=0.75%, cr=18.00%, ni=8.00%, n=0.10%, fe= 31.02%, feo=40%. FeO is used as a high-explosion heat type synergist, so that a severe aluminothermic reaction occurs when a broken piece impacts a target, and a spiral piece inside the broken piece also has a certain degree of energy release effect. The final energy storage structural member not only plays a certain role in structure, but also has the effect of high-energy damage. The energy storage structural member is molded by adopting a general steel wire machining process, and raw materials are subjected to operations such as drying, coating treatment, heat treatment, wire drawing and the like, so that the spiral telescopic member is obtained.
(1) Preparation of core-shell structured nano aluminum/fluoropolymer material
The nano aluminum fluoride polymer material is obtained by adopting a method of coating aluminum particles with liquid fluorine polymer. Compared with a chemical coating method, the physical coating method is simple to operate and high in feasibility, and can realize large-scale production. Phosphoric acid 2-hydroxyethyl methacrylic acid (PAM) was added to cyclohexanone and the reaction was maintained under nitrogen atmosphere with stirring for 2 hours. Fluororubber was dispersed in the solution and stirred for 2h. The metal powder is then dispersed into the solution, eventually yielding a slurry. Extruding and granulating the obtained slurry by a 2mm granulator, and drying the obtained granules at a drying temperature of 6 ℃ to obtain the fluoropolymer coated nano aluminum particles.
(2) Preparation of energy storage broken pieces
And adding the uniformly mixed granules and polytetrafluoroethylene powder into a special forming die according to a calculated mass ratio, and then reasonably assembling an energy storage structural member for pre-pressing. The telescopic spiral structural member is split-packed into a mould according to a head-to-head structure, and is pressed. The pressure is 30MPa, the pressurizing speed is 30N/s, the pressure maintaining time is 5min, the pressure releasing speed is 30N/s, and the energy storage fragments distributed in space are obtained after pressure releasing. Sintering is needed subsequently, the formed test piece after demolding is placed in a sintering furnace for sintering, argon atmosphere is used in the sintering process, the sintering temperature is 360 ℃, the sintering time is 2 hours, the temperature is kept at 327 ℃ for 2 hours, the temperature rising and reducing rates are 1 ℃/min, and the process is carried out along with furnace cooling, so that the preparation process of the space type high-explosion heat energy storage broken piece is obtained.
And (3) the obtained energy storage broken piece is impacted on a LY12 aluminum plate with the thickness of 2mm at the initial speed of 1100m/s, so as to obtain a damage effect action diagram. The optimal working effect is the scheme of example 2. The density of the energy storage fragments prepared in this example was 4.558g/cm3. The active energetic structural member exhibits plasticity, and has a yield strength of 22.582MPa at quasi-static state, a reaction threshold of 4500/s, and a yield strength of 50.055MPa at 6500/s strain rate.
Claims (3)
1. A preparation process of a space type high-explosion heat energy storage broken piece is characterized by comprising the following steps of: the method comprises the following specific steps:
step one: the spiral telescopic component is obtained by reasonably proportioning the elements C, mn, P, S, si, cr, ni, N, fe, feO and the like, and performing operations such as drying, coating treatment, heat treatment, wire drawing and the like on raw materials.
Step two: the nano aluminum fluoride polymer material is obtained by adopting a method of coating aluminum particles with liquid fluorine polymer.
Step three: the evenly mixed granules and polytetrafluoroethylene powder are added into a special forming die according to the calculated mass ratio, and then the energy storage structural member is reasonably assembled for pre-pressing and sintering, so that the space type high-explosion-heat energy storage broken piece is obtained.
2. The process for preparing the space type high-explosion heat energy storage broken sheet according to claim 1, which is characterized by comprising the following steps: step one, preparing the spiral type telescopic member.
3. The process for preparing the space type high-explosion heat energy storage broken sheet according to claim 1, which is characterized by comprising the following steps: the nano aluminum fluoride polymer material is obtained by adopting a method of coating aluminum particles with liquid fluorine polymer. And filling the energy storage structural member into a forming die, filling the granules and polytetrafluoroethylene, and performing compression forming and sintering to obtain the space type high-explosion heat energy storage broken sheet.
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