CN117208849A - Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof - Google Patents

Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof Download PDF

Info

Publication number
CN117208849A
CN117208849A CN202311206368.9A CN202311206368A CN117208849A CN 117208849 A CN117208849 A CN 117208849A CN 202311206368 A CN202311206368 A CN 202311206368A CN 117208849 A CN117208849 A CN 117208849A
Authority
CN
China
Prior art keywords
adsorption
tower
pressure
tank
hydrogen production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311206368.9A
Other languages
Chinese (zh)
Inventor
张伟
常景彩
石涌
韩新宇
张连海
赵欣茹
王净
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Weihai Institute Of Industrial Technology Shandong University
Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd
Original Assignee
Weihai Institute Of Industrial Technology Shandong University
Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Weihai Institute Of Industrial Technology Shandong University, Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd filed Critical Weihai Institute Of Industrial Technology Shandong University
Priority to CN202311206368.9A priority Critical patent/CN117208849A/en
Publication of CN117208849A publication Critical patent/CN117208849A/en
Pending legal-status Critical Current

Links

Abstract

The invention belongs to the technical field of pressure swing adsorption devices and hydrogen purification, and particularly relates to a multi-tower efficient pressure swing adsorption purification hydrogen production system and a process thereof. Comprising the following steps: the device comprises a first adsorption tower, a second adsorption tower, a third adsorption tower, a fourth adsorption tower, a vacuum pump, a raw material gas buffer tank, a resolved gas buffer tank, a product gas buffer tank, a pressure equalizing tank and a sequential discharge tank; through having changed the route of product gas, and then realized just can carrying out two adsorption towers simultaneously under the condition of only four adsorption towers and adsorb, increase device's throughput, adopt the absorbent regeneration mode that evacuation and washing two modes combined together simultaneously, alleviate current technology only can realize the absorptive current situation of multiple tower simultaneously at not less than six bed pressure swing adsorption, solved the prior art simultaneously and only adopted the vacuum flow to weaken at the regeneration effect of evacuation regeneration terminal stage, the problem that the absorbent regeneration effect is not thorough.

Description

Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof
Technical Field
The invention belongs to the technical field of pressure swing adsorption devices and hydrogen purification, and particularly relates to a multi-tower efficient pressure swing adsorption purification hydrogen production system and a process thereof.
Background
The disclosure of this background section is only intended to increase the understanding of the general background of the invention and is not necessarily to be construed as an admission or any form of suggestion that this information forms the prior art already known to those of ordinary skill in the art.
Hydrogen is one of the most ideal energy sources in the future, and has the advantages of high efficiency, cleanness, no pollution and renewable circulation. The pressure swing adsorption technology is a main technical means for purifying and preparing hydrogen at present, is a novel technology for carrying out gas adsorption and separation in a pressure swing adsorption mode, has important significance for preparing high-purity hydrogen, and has the advantages of simple process flow, high operation flexibility, high reliability, high operation elasticity and high automation degree.
In the existing pressure swing adsorption process, the single adsorption tower is intermittent because the adsorbent needs to be regenerated. Two or more adsorbent beds are used in industry, and adsorption and regeneration of the adsorbent beds are alternately performed. However, since the adsorption tower is in a broadly regenerated state longer than the adsorption state and requires a pressure equalizing operation, the adsorption operation is performed simultaneously with two adsorption towers at some time of the pressure swing adsorption cycle, which occurs only in not less than six bed pressure swing adsorption processes, for example: six-column operation, two-column adsorption, is commonly used in industry, namely: six adsorption towers operate, wherein two adsorption towers are in an adsorption state, and the rest adsorption towers are in a generalized regeneration state.
The production capacity of the device can be increased by feeding multiple towers simultaneously, but the mode of adding multiple adsorption towers is needed, so that the overall equipment cost is increased, meanwhile, multiple pipelines and multiple program control valves are added, the risk of equipment failure is increased, and the later management and maintenance are not facilitated.
Meanwhile, in the actual engineering operation, the problem that the regeneration effect is weakened at the end of vacuumizing is found in the existing pressure swing adsorption process even if a vacuumizing regeneration mode is adopted, so that the adsorbent is not regenerated thoroughly, and the purity of the product gas and the recovery rate of hydrogen are reduced. In addition, if the vacuumizing system fails, the adsorbent regeneration cannot be performed, and the whole pressure swing adsorption device cannot operate.
In summary, the problem that the production capacity of the device needs to be improved is solved by aiming at the high cost of the existing six-tower operation-two-tower adsorption equipment. There is an urgent need to develop a system that can perform simultaneous adsorption of two adsorption towers using only four adsorption towers to increase the throughput of the apparatus.
Disclosure of Invention
In order to solve the problems, the invention provides the multi-tower efficient pressure swing adsorption purification hydrogen production system and the process thereof, which change the path of the product gas, release the product gas to a pressure equalizing tank through a primary pressure equalizing drop part after the adsorption is finished, release the product gas to other adsorption towers through a secondary pressure equalizing drop part, prolong the adsorption time through the two release and the buffering of the pressure equalizing tank, further realize the simultaneous adsorption of two adsorption towers under the condition of only four adsorption towers, increase the production capacity of the device, and simultaneously solve the problems that the prior art only adopts a vacuum flow to weaken the regeneration effect at the end of the vacuumizing regeneration and the regeneration effect of the adsorbent is not thorough by adopting an adsorbent regeneration mode combining vacuumizing and flushing modes.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
in a first aspect of the present invention, there is provided a multi-tower high efficiency pressure swing adsorption purification hydrogen production system comprising: at least four adsorption towers;
the inlet ends of the adsorption towers are respectively connected with an air inlet pipeline and a vacuumizing pipeline, and the outlet ends of the adsorption towers are respectively connected with a pressure equalizing tank and a sequential discharge tank;
two adsorption towers are simultaneously in an adsorption state in each period.
In some embodiments, the pressure equalizing tank performs one pressure equalizing and pressure equalizing on the adsorption tower and one pressure equalizing and pressure equalizing step;
in some embodiments, the hold-down tank holds down and purges the adsorption column.
In some embodiments, the feed gas enters the first adsorption tower, the second adsorption tower, the third adsorption tower, and the fourth adsorption tower from the feed gas buffer tank, respectively.
In some embodiments, further comprising: and after the sequential release, the vacuum pump reversely vacuumizes the impurity gas adsorbed in the adsorption tower, and the impurity gas is discharged as the analysis gas through the analysis gas buffer tank.
In some embodiments, after the evacuation is completed, the adsorption tower is connected to a forward tank, and the gas in the forward tank flows into the adsorption tower from the forward tank, is pumped out by a vacuum pump as purge waste gas, and is discharged through a desorption gas buffer tank.
In some embodiments, after purging, the adsorption tower is disconnected from the forward tank, and the adsorption tower is connected with other adsorption towers to perform secondary pressure equalization.
In some embodiments, after the secondary pressure equalization is finished, the adsorption tower is disconnected from other adsorption towers, and the adsorption tower is connected with the pressure equalization tank to perform primary pressure equalization.
In some embodiments, after the one-time pressure equalization is finished, the connection between the adsorption tower and the pressure equalization tank is disconnected, so that the raw material gas is subjected to final pressure equalization on the adsorption tower through the air inlet pipeline.
In some embodiments, valves are provided on each device and on the piping between each device.
The invention also provides a multi-tower high-efficiency pressure swing adsorption purification hydrogen production process, which adopts the system to produce hydrogen, and comprises the following steps:
the raw material gas passes through a raw material gas buffer tank at normal temperature and then enters adsorption towers, and each adsorption tower is filled with an adsorbent; each adsorption tower sequentially undergoes the procedures of adsorption, pressure equalizing and reducing, sequential discharge, vacuumizing, blowing, pressure equalizing and lifting and final pressure lifting, and two adsorption towers are simultaneously in an adsorption state in each period, and the process is performed circularly to obtain the catalyst;
wherein, the product gas is released to the pressure equalizing tank through the primary pressure equalizing and reducing part, and then is released to other adsorption towers through the secondary pressure equalizing and reducing part.
In some embodiments, the pressure fluctuation of the vacuum pump is controlled between 35 and 50kPaA.
The third aspect of the invention also provides the application of the multi-tower efficient pressure swing adsorption purification hydrogen production system in gas treatment.
The beneficial effects of the invention are that
The invention provides a multi-tower high-efficiency pressure swing adsorption purification hydrogen production system and a process thereof, wherein different process flows are designed by selecting time of steps, so that the production capacity of a device can be improved, the investment is reduced, and the purity of product gas and the recovery rate of hydrogen are improved. In particular, the invention has the advantages that:
1. the invention utilizes the equalizing tank and the sequential discharging tank to simulate the PSA circulation flow of multiple towers in cooperation with the adsorption tower, purifies the hydrogen, greatly reduces the production cost of the multiple towers, simultaneously realizes the simultaneous adsorption of two towers by controlling the switch of the valve to set four-tower process time sequence steps, improves the production capacity of the system, reduces the investment and the operation cost and reduces the equipment failure risk.
2. The adsorbent regeneration process adopts a regeneration mode of combining vacuumizing and purging, and the purging is performed at the middle and later stages of the adsorbent regeneration stage, so that the adsorbent is regenerated more thoroughly, the impurity content is lower, and the adsorbent regeneration effect is better. Even when the vacuum system fails, the reverse discharging and purging processes can be operated, so that the pressure swing adsorption system can still operate stably.
3. The pressure swing adsorption technology adopted by the invention circulates according to the time sequence of adsorption, primary pressure drop equalization, secondary pressure drop equalization, sequential discharge, vacuumizing, purging, secondary pressure rise equalization, primary pressure rise equalization and final pressure rise; and the pressure equalizing tank and the inter-tower pressure equalizing tank are used for realizing three times of pressure reduction, so that the pressure fluctuation range of the system flow is reduced, and the pressure fluctuation and noise of the vacuum pump are smaller.
4. The system and the process can realize gas separation under the conditions of normal temperature and low pressure, and have the characteristics of small device, high production capacity, high product gas purity, high automation degree, low fault risk, low maintenance cost and the like.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention.
FIG. 1 is a schematic diagram of a multi-tower high efficiency pressure swing adsorption purification hydrogen production system and process thereof;
A. a first adsorption tower; B. a second adsorption tower; C. a third adsorption tower; D. a fourth adsorption tower; 1. a raw material gas buffer tank; 2. a product gas buffer tank; 3. analyzing the gas buffer tank; 4. a pressure equalizing tank; 5. c, putting the cans in sequence; 6. and a vacuum pump.
Detailed Description
It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the invention. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
The invention will now be described in further detail with reference to the following specific examples, which should be construed as illustrative rather than limiting.
As shown in fig. 1, the embodiment provides a multi-tower efficient pressure swing adsorption purification hydrogen production system and a process thereof, wherein the system comprises a first adsorption tower a, a second adsorption tower B, a third adsorption tower C, a fourth adsorption tower D, a raw material gas buffer tank 1, a product gas buffer tank 2, a desorption gas buffer tank 3, a pressure equalizing tank 4, a forward discharge tank 5, a vacuum pump 6 and pipelines and valves connected with each other;
the feed gas inlet is connected with the inlet end of the feed gas buffer tank 1, and the outlet ends of the feed gas buffer tank 1 are connected with inlet pipelines at the bottom inlet ends of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D; the bottom inlet ends of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D are respectively connected with a vacuumizing pipeline, and the vacuumizing pipelines are connected with the inlet end of the vacuum pump 6; the outlet end of the vacuum pump 6 is connected with the inlet end of the analysis gas buffer tank 3; the outlet ends of the tops of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D are respectively connected with an outlet pipeline with the inlet end of the product gas buffer tank 2; the outlet ends of the tops of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D are connected with primary pressure equalizing pipelines through inlet ends of a pressure equalizing tank 4; the outlet ends of the tops of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D are respectively connected with a secondary pressure equalizing pipeline; and the outlet ends of the tops of the first adsorption tower A, the second adsorption tower B, the third adsorption tower C and the fourth adsorption tower D are connected with forward pipelines with the inlet ends of forward tanks.
The cycle sequences of the pressure swing adsorption system and the process used in this example are shown in table 1.
TABLE 1 cycle time sequence for four tower high efficiency pressure swing adsorption hydrogen production process
Note that: adsorption A, ED/ER uniform pressure drop/uniform pressure rise, PP forward release, V vacuum, P purging and FR final pressure rise;
as shown in table 1, each column was in a different operating state during each period of the pressure swing adsorption process, and it was ensured that two adsorption columns were simultaneously in an adsorption state during each period. Each adsorption tower carries out the same cycle time sequence, taking tower A as an example, and explaining the pressure swing adsorption process in the section:
(1) Adsorption: and opening a program control valve of an air inlet pipeline of the tower A, allowing raw material gas to enter an adsorption tower A after passing through a raw material gas buffer tank 1, adsorbing impurity gas in the raw material gas by an adsorbent under adsorption pressure, and allowing unadsorbed hydrogen to enter a product gas buffer tank 2 through a product gas pipeline program control valve. When the adsorption front of impurity reaches a certain position of the adsorption tower, the air inlet program control valve is closed, the raw material gas stops being input into the adsorption tower A, and the pressure in the adsorption is kept in the tower.
(2) Pressure drop at one time: after the adsorption step of the A tower is stopped, namely, the A tower is opened and connected with the pressure equalizing tank 4 to be connected with a pipeline program control valve, so that the outlet end of the A tower is communicated with the pressure equalizing tank 4, and the dead space gas in the A tower flows into the pressure equalizing tank 4 from the outlet end of the A tower through the program control valve. At the end of this step, the a column and pressure equalization tank 4 pressures are substantially equalized. (3) secondary pressure equalizing and reducing: after the pressure drop of the tower A is finished, the pipeline program control valve connected with the pressure equalizing tank 4 is closed, the pipeline program control valve connected with the tower D is opened, the outlet end of the tower A is communicated with the outlet end of the tower D which just finishes regeneration, and the dead space gas in the tower A flows into the tower D from the outlet end of the tower A. At the end of this step, the A, D column pressure was substantially equalized.
(4) And (3) forward-put: after the step of secondary pressure equalization and drop of the A tower is stopped, the pipeline program control valve connected with the A tower and the D tower is closed, the pipeline program control valve connected with the A tower and the forward discharge tank 5 is opened, the outlet end of the A tower is communicated with the inlet end of the forward discharge tank 5, and dead air in the A tower flows into the forward discharge tank 5 from the outlet end of the A tower. At the end of this step, the column a and the hold-down tank 5 pressures are substantially equalized.
(5) Vacuumizing: after the sequential putting step of the tower A is finished, the pipeline program control valve connected with the sequential putting tank 5 is closed, the pipeline program control valve connected with the vacuum pump is opened, the vacuum pump 6 is opened, the impurity gas adsorbed in the tower is reversely vacuumized and discharged as the resolved gas through the resolved gas buffer tank 3, and most of the adsorbed impurity gas is desorbed in the process, so that the adsorbent is regenerated to a certain degree.
(6) And (3) purging: after the vacuumizing step is finished, the tower A is opened and connected with the forward tank 5 to connect the pipeline program control valve, so that the outlet end of the tower A is communicated with the inlet end of the forward tank 5, the vacuum pump 6 is kept on, gas in the forward tank flows into the tower A from the outlet end of the forward tank and is pumped out through the vacuum pump as sweeping waste gas, and the sweeping waste gas is discharged out of the system through the analysis gas buffer tank 3. At the end of this step, the regeneration of the a-column is complete.
(7) Secondary pressure equalizing and rising: and closing the pipeline program control valve connected with the forward discharge tank 5, closing the pipeline program control valve connected with the vacuum pump, and opening the pipeline program control valve connected with the tower A and the tower B to ensure that the outlet end of the tower A is communicated with the outlet end of the tower B. And (3) enabling the gas in the tower B to flow into the tower A, equalizing the pressure of the tower A, and enabling the pressure of the tower B to be basically equal to the pressure of the tower A after the step is finished.
(8) And (3) carrying out primary uniform pressure rise: after the A tower completes the secondary pressure equalization boosting process, the A tower is ready for further boosting. And closing the pipeline program control valve connected with the tower A and the tower B, and opening the pipeline program control valve connected with the tower A and the pressure equalizing tank 4 to ensure that the outlet end of the tower A is communicated with the pressure equalizing tank 4. The pressure equalizing tank stores gas flowing in when the pressure of the tower B is equalized once in the previous time sequence, the gas in the pressure equalizing tank 4 enters the tower A to equalize the pressure of the tower A, and the pressure of the pressure equalizing tank 4 is basically equal to the pressure of the tower A after the step is finished.
(9) Final boost: after the tower A undergoes the pressure equalizing step, the pressure in the tower does not reach the working pressure of the adsorption step yet. At this time, the A tower is closed, the pipeline program control valve connected with the equalizing tank 4 is opened, the A tower air inlet pipeline program control valve is opened, and the A tower is finally boosted by the raw material gas until the pressure of the A tower basically reaches the adsorption pressure. The steps of the column a in one cycle are all completed, and the next cycle is started immediately.
Further, the pressure fluctuation of the vacuum pump 6 is controlled to be 35 to 50kPaA.
According to the multi-tower efficient pressure swing adsorption purification hydrogen production system and the process thereof, through designing different process flows of matching four adsorption towers with the pressure equalizing tank and the sequential discharging tank, the simultaneous adsorption of two adsorption towers at any time sequence can be realized, the investment is reduced, and the production capacity of the device can be improved; the adsorbent is regenerated more thoroughly by adopting an adsorbent regeneration mode of combining vacuumizing and purging, so that the purity of the product gas and the hydrogen recovery rate are improved; the device has simple operation process, gentle pressure rise and fall, low noise of the vacuum pump and suitability for industrial production.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. A multi-tower high efficiency pressure swing adsorption purification hydrogen production system, comprising:
at least four adsorption towers;
the inlet ends of the adsorption towers are respectively connected with an air inlet pipeline and a vacuumizing pipeline, and the outlet ends of the adsorption towers are respectively connected with a pressure equalizing tank and a sequential discharge tank;
each adsorption tower sequentially undergoes the procedures of adsorption, pressure equalizing and reducing, sequential discharge, vacuumizing, blowing, pressure equalizing and lifting and final pressure boosting, two adsorption towers are simultaneously in an adsorption state in each period, and secondary pressure equalizing and reducing are carried out among the towers;
the pressure equalizing tank is used for equalizing pressure and rising pressure of the adsorption tower once;
and the forward discharge tank is used for forward discharge and purging of the adsorption tower.
2. The multi-column high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1, wherein the feed gas enters the first adsorption column, the second adsorption column, the third adsorption column, and the fourth adsorption column from the feed gas buffer tank, respectively.
3. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as recited in claim 1, further comprising: and after the sequential release, the vacuum pump reversely vacuumizes the impurity gas adsorbed in the adsorption tower, and the impurity gas is discharged as the analysis gas through the analysis gas buffer tank.
4. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1 wherein after the evacuation is completed, the adsorption tower is connected to a forward tank, the gas in the forward tank flows from the forward tank into the adsorption tower, is pumped out as purge waste gas by a vacuum pump, and is discharged through a desorption gas buffer tank.
5. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1, wherein after purging, the adsorption tower is disconnected from the forward tank, and the adsorption tower is connected with other adsorption towers for secondary pressure equalization.
6. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1, wherein after the secondary pressure equalization is completed, the adsorption tower is disconnected from other adsorption towers, and the adsorption tower is connected with the pressure equalization tank for primary pressure equalization.
7. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1, wherein after one pressure equalization, the adsorption tower is disconnected from the pressure equalization tank, and the feed gas is subjected to final pressure equalization through the air inlet pipe.
8. The multi-tower high efficiency pressure swing adsorption purification hydrogen production system as claimed in claim 1 wherein valves are provided on each device and on the piping between each device.
9. A multi-tower high efficiency pressure swing adsorption purification hydrogen production process employing the system of any one of claims 1-8, comprising:
the raw material gas passes through a raw material gas buffer tank at normal temperature and then enters adsorption towers, and each adsorption tower is filled with an adsorbent; each adsorption tower sequentially undergoes the procedures of adsorption, pressure equalizing and reducing, sequential discharge, vacuumizing, blowing, pressure equalizing and lifting and final pressure lifting, two adsorption towers are simultaneously in an adsorption state in each period, and the process is performed circularly to obtain the catalyst;
wherein, the product gas in the adsorption tower is released to the pressure equalizing tank through the primary pressure equalizing drop part, and then is released to other adsorption towers through the secondary pressure equalizing drop.
10. The multi-tower high efficiency pressure swing adsorption purification hydrogen production process of claim 9, wherein the pressure fluctuation of the vacuum pump is controlled between 35 and 50kPaA.
CN202311206368.9A 2023-09-18 2023-09-18 Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof Pending CN117208849A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311206368.9A CN117208849A (en) 2023-09-18 2023-09-18 Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311206368.9A CN117208849A (en) 2023-09-18 2023-09-18 Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof

Publications (1)

Publication Number Publication Date
CN117208849A true CN117208849A (en) 2023-12-12

Family

ID=89047745

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311206368.9A Pending CN117208849A (en) 2023-09-18 2023-09-18 Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof

Country Status (1)

Country Link
CN (1) CN117208849A (en)

Similar Documents

Publication Publication Date Title
US5411578A (en) Vacuum swing adsorption process with mixed repressurization and provide product depressurization
US20090020014A1 (en) Methods and apparatus for imrpoved control of psa flow variations
US3221476A (en) Adsorption-desorption method
CN111871149B (en) Two-stage pressure swing adsorption system for recovering adsorbed components and application method thereof
CN101301999A (en) Method for collecting oxygen from air
CN111204712A (en) Pressure swing adsorption gas hydrogen separation and purification system and separation and purification method thereof
CN102500190B (en) A kind of cleaning and recovering process for enriched gas source
WO2021207914A1 (en) Method for producing oxygen using pressure swing adsorption technology
CN208829260U (en) Pressure swing adsorption hydrogen production system
CN117208849A (en) Multi-tower efficient pressure swing adsorption purification hydrogen production system and process thereof
CN109276973B (en) Method for separating and purifying hydrogen from refining vent gas
KR20050030957A (en) Method of separating target gas
CN217092804U (en) Pressure swing adsorption hydrogen extraction system in morpholine production process
CN113426245B (en) High-purity gas preparation method based on pressure swing adsorption
CN108793077A (en) Pressure swing adsorption hydrogen production system
JP2004262743A (en) Method and apparatus for concentrating oxygen
CN212492394U (en) Device system for recovering nitrogen in polyethylene device flare gas
CN112919414A (en) Low-pressure flushing regeneration pressure swing adsorption hydrogen purification system and hydrogen purification method
CN116390797A (en) Process and apparatus for producing ultra-high purity hydrogen from low grade hydrogen
CN220609748U (en) Pressure swing adsorption pressure equalizing recovery system
WO2024098997A1 (en) Pressure swing adsorption gas separation method and device for variable-path step-by-step voltage sharing
CN213294685U (en) Efficient VPSA system oxygen system
JP3694343B2 (en) PSA for low concentration oxygen
CN219942316U (en) Three-tower vacuum pressure swing adsorption system
CN215916904U (en) Adsorption system capable of prolonging service life of adsorbent

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination