CN117206544B - Laser selective melting forming method for Zn-Cu-Mn-Mg alloy porous structure - Google Patents
Laser selective melting forming method for Zn-Cu-Mn-Mg alloy porous structure Download PDFInfo
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- 238000002844 melting Methods 0.000 title claims abstract description 79
- 230000008018 melting Effects 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 40
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 20
- 239000000956 alloy Substances 0.000 claims abstract description 109
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 106
- 239000000843 powder Substances 0.000 claims abstract description 74
- 238000003892 spreading Methods 0.000 claims abstract description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 20
- 230000007797 corrosion Effects 0.000 claims description 16
- 238000005260 corrosion Methods 0.000 claims description 16
- 229910052786 argon Inorganic materials 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- 210000001124 body fluid Anatomy 0.000 claims description 9
- 239000010839 body fluid Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 238000000889 atomisation Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 4
- 238000007788 roughening Methods 0.000 claims description 4
- 230000003746 surface roughness Effects 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000011701 zinc Substances 0.000 description 18
- 210000000988 bone and bone Anatomy 0.000 description 16
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 7
- 239000007943 implant Substances 0.000 description 6
- 238000012216 screening Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 1
- 206010061363 Skeletal injury Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
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Abstract
The application discloses a laser selective melting forming method for a Zn-Cu-Mn-Mg alloy porous structure, relates to the technical field of alloy additive manufacturing, and aims to solve the technical problem that a Zn-Cu-Mn-Mg porous alloy is difficult to form when being prepared by the existing method. The Zn-Cu-Mn-Mg alloy porous structure laser selective melting forming method comprises the following steps: preparing Zn-Cu-Mn-Mg powder; acquiring a laser selective melting parameter based on a target structural parameter of the Zn-Cu-Mn-Mg target porous alloy; the laser selective melting parameters are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the strip interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle range is 60-120 degrees and 240-300 degrees; and printing to obtain the Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters. The method has higher forming performance when preparing Zn-Cu-Mn-Mg porous alloy.
Description
Technical Field
The application relates to the technical field of alloy additive manufacturing, in particular to a Zn-Cu-Mn-Mg alloy porous structure laser selective melting forming method.
Background
The Zn-Cu-Mn-Mg alloy material has the characteristics of good biocompatibility, no toxicity and degradability, so that the Zn-Cu-Mn-Mg alloy material is widely applied to various fields, in particular to a porous alloy structure. Therefore, the Zn-Cu-Mn-Mg porous alloy material is prepared by adopting laser selective melting forming, but the existing laser selective melting forming method is easy to be influenced by metal vapor and has low forming efficiency due to large difference of melting points of elements in alloy components in the preparation process.
Disclosure of Invention
The main purpose of the application is to provide a laser selective melting forming method for Zn-Cu-Mn-Mg alloy porous structure, which aims at solving the technical problem that the Zn-Cu-Mn-Mg porous alloy is difficult to form when the Zn-Cu-Mn-Mg porous alloy is prepared by the existing method.
In order to solve the above technical problems, the embodiments of the present application provide: a laser selective melting forming method for a Zn-Cu-Mn-Mg alloy porous structure comprises the following steps:
preparing Zn-Cu-Mn-Mg powder; wherein the Zn-Cu-Mn-Mg powder comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%;
acquiring a laser selective melting parameter based on a target structural parameter of the Zn-Cu-Mn-Mg target porous alloy; the laser selective melting parameters are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the strip interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle range is 60-120 degrees and 240-300 degrees;
and printing to obtain the Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters.
As some optional embodiments, before the target structural parameter of the Zn-Cu-Mn-Mg-based target porous alloy is obtained, the method further comprises:
dividing the Zn-Cu-Mn-Mg porous alloy into a plurality of unit grid structures; wherein each cell grid structure consists of a plurality of rods;
the target structural parameter of the Zn-Cu-Mn-Mg porous alloy is set to be that the diameter of the rod is 0.20-0.5 mm, the rod diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is 0-120 degrees.
As some alternative embodiments, the Zn-Cu-Mn-Mg porous alloy is composed of a plurality of cell lattice structures, each of which is composed of a plurality of rods; the diameter of the rod is 0.20-0.5 mm, the diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is 0-120 degrees.
As some alternative embodiments, the printing to obtain Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters includes:
obtaining a model file of a Zn-Cu-Mn-Mg target porous alloy model;
obtaining laser selective melting parameters based on a model file of the Zn-Cu-Mn-Mg target porous alloy model;
slicing the Zn-Cu-Mn-Mg target porous alloy model based on the laser selective melting parameters to obtain slice files;
and (3) introducing the slice file into laser selective melting forming equipment, and starting printing to obtain the Zn-Cu-Mn-Mg porous alloy.
As some alternative embodiments, the slice file is introduced into a laser selective melt forming device to start printing, so as to obtain the Zn-Cu-Mn-Mg porous alloy, which comprises:
introducing the slice file into laser selective melting forming equipment, paving powder, heating a substrate, introducing argon for protection, and starting printing to obtain Zn-Cu-Mn-Mg porous alloy; wherein the surface roughness of the substrate is Ra1.6μm-Ra3.2μm.
As some optional embodiments, during the printing process, the purity of argon in a printing chamber of the laser selective melting forming device is 99.999%, the oxygen content in the chamber is lower than 100ppm, the pressure in the chamber is 0 mbar-20 mbar, and the dedusting air quantity is 17-21 m 3 /h。
As some alternative embodiments, the substrate is subjected to surface roughening treatment before heating, the roughness value after the surface roughening treatment is ra1.6-ra3.2 μm, and the substrate heating temperature is 80 ℃.
As some alternative embodiments, the preparing Zn-Cu-Mn-Mg powder includes:
obtaining Zn-Cu-Mn-Mg first alloy powder based on a rotating electrode atomization method;
and carrying out vacuum drying treatment on the Zn-Cu-Mn-Mg first alloy powder to obtain Zn-Cu-Mn-Mg second alloy powder.
As some alternative embodiments, the drying temperature of the vacuum drying treatment is 70-90 ℃, the drying time is 6-8 h, and the vacuum pressure is-0.8 bar to-1.0 bar.
As some alternative embodiments, the structural elastic modulus of the Zn-Cu-Mn-Mg porous alloy is 10 GPa-18 GPa, and the human body fluid corrosion rate is 0.21 mm/year-0.28 mm/year in 30 days.
Compared with the prior art, the Zn-Cu-Mn-Mg porous alloy disclosed by the embodiment of the application comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%; the Zn-Cu-Mn-Mg porous alloy has the advantages of good biocompatibility, degradability and innocuity, so that the porous structure characteristic of the Zn-Cu-Mn-Mg porous alloy can be used for promoting the adhesion of bone tissues, but the porous structure is difficult to manufacture by adopting a conventional machining method, so that the Zn-Cu-Mn-Mg porous alloy is obtained after the Zn-Cu-Mn-Mg porous alloy is mixed by the mass percentage components; and performing laser selective melting forming on the Zn-Cu-Mn-Mg powder serving as printing powder to obtain the printing powder; however, because the melting point of Zn is low, metal vapor is easy to form and adhere to the laser lens, the printing is affected, and the melting point of Cu, mn, mg, zn is very different, so that vaporization of low-melting-point elements or unfused of high-melting-point elements are easy to cause, and printing failure is caused; the present application therefore further defines the parameters of selective laser melting, namely: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg. By the method, the printing efficiency of the porous alloy can be improved, and then the unsupported Zn-Cu-Mn-Mg porous alloy structure with ideal performance requirements is obtained.
Drawings
FIG. 1 is a schematic flow chart of a laser selective melt forming method of a Zn-Cu-Mn-Mg target porous alloy according to an embodiment of the application;
FIG. 2 is a schematic diagram of a target structure of a Zn-Cu-Mn-Mg target porous alloy according to an embodiment of the present application.
Detailed Description
It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the present application.
The fracture or bone injury caused by accidents, aging and the like can be treated by surgical implantation of the metal splint, but after the bone heals, the metal exists in a human body, and the metal splint needs to be taken out, so that secondary injury is caused, and the ideal bone implant has the characteristics of good biocompatibility, degradability, enough mechanical strength, elastic modulus close to the bone of the human body, customizable appearance profile and the like.
The Zn-Cu-Mn-Mg porous alloy has the advantages of good biocompatibility, degradability and innocuity, and the degradation speed of pure zinc is relatively slow, and the addition of Cu and Mg can reduce the degradation speed of the pure Zn, the mechanical property of the pure Zn is poorer, the addition of Mn can improve the mechanical property of the pure Zn, and simultaneously Zn, cu, mg, mn and the like are microelements required by human bodies, and the proper Zn, cu, mg, mn can be attracted by the human bodies and is harmless to the human bodies. Therefore, the porous structure characteristics of the Zn-Cu-Mn-Mg porous alloy can be utilized for promoting the adhesion of bone tissues, but the porous structure is difficult to manufacture by adopting a conventional machining method, so that Zn-Cu-Mn-Mg powder is obtained after the Zn-Cu-Mn-Mg porous alloy is mixed by preset mass percentage components; and performing laser selective melting forming on the Zn-Cu-Mn-Mg powder serving as printing powder to obtain the printing powder.
The selective laser melting forming is to make metal powder spread layer by layer through selective laser melting forming layer by layer, and can make metal product with complex grid according to designed three-dimensional model, especially making product difficult to make by mechanical processing, such as porous structure. However, since Zn has a low melting point, metal vapor is easily formed and attached to a laser lens, which affects printing, and Cu, mn, mg, zn has a very different melting point, vaporization of low melting point elements or unfused of high melting point elements are easily caused, which results in printing failure. The printing density is improved by optimizing the printing parameters such as laser power, scanning speed, scanning interval, path offset, jump angle and the like, so that the defects of cracks, air holes and the like caused by large alloy melting point difference during printing are overcome.
The present application therefore further defines the parameters of selective laser melting, namely: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg. By the method, the printing efficiency of the porous alloy can be improved, and then the unsupported Zn-Cu-Mn-Mg porous alloy structure with ideal performance requirements is obtained.
In order to solve the above technical problems, embodiments of the present application provide: the Zn-Cu-Mn-Mg porous alloy comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%; the method realizes the adjustment of the corrosion rate of the alloy by adjusting the flying proportion of the alloy, so that the corrosion rate is moderate, namely the excessive fast or slow corrosion is avoided; if the corrosion is too fast, bones are not grown well after the implantation into a human body, and the stent is corroded too early to lose mechanical support, the risk of inflammation in the human body exists for a long time due to the too slow corrosion.
The Zn-Cu-Mn-Mg porous alloy is obtained by mixing the components in percentage by mass; and performing laser selective melting forming on the Zn-Cu-Mn-Mg powder serving as printing powder to obtain the printing powder; the parameters of the selective laser melting are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg.
Through the parameter regulation and control, the method can solve the problem that printing and forming are difficult due to the influence of metal vapor or large difference of element melting points in alloy components in the printing process of Zn-Cu-Mn-Mg porous alloy in the prior art.
In practical application, in order to better meet application requirements, such as application as a bone graft, the Zn-Cu-Mn-Mg porous alloy is composed of a plurality of unit grid structures, and each unit grid structure is composed of a plurality of rods; the diameter of the rod is 0.20-0.5 mm, the diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is 0-120 degrees. And when the Zn-Cu-Mn-Mg porous alloy is applied as a bone graft, the structural elastic modulus and the human body fluid corrosion rate of the bone graft are required to be limited, so that the in-vivo supporting performance requirement and the in-vivo degradation performance requirement of the bone graft are better completed, therefore, the structural elastic modulus of the Zn-Cu-Mn-Mg porous alloy is 10 GPa-18 GPa, and the human body fluid corrosion rate is 0.21 mm/year-0.28 mm/year in 30 days. It should be noted that, the elastic modulus of zinc and zinc alloy is higher, and the porous structure design can reduce the elastic modulus of zinc alloy bone implant.
In practical application, the Zn-Cu-Mn-Mg porous alloy is mixed by the components in percentage by mass to obtain Zn-Cu-Mn-Mg powder; and performing laser selective melting forming on the Zn-Cu-Mn-Mg powder serving as printing powder to obtain the printing powder.
Specifically, as shown in fig. 1, the embodiment of the application provides a laser selective melting forming method for a Zn-Cu-Mn-Mg alloy porous structure, which comprises the following steps:
s10, preparing Zn-Cu-Mn-Mg powder; wherein the Zn-Cu-Mn-Mg powder comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%.
The preparation of Zn-Cu-Mn-Mg powder comprises the following steps: obtaining Zn-Cu-Mn-Mg first alloy powder based on a rotating electrode atomization method; carrying out vacuum drying treatment on the Zn-Cu-Mn-Mg first alloy powder to obtain Zn-Cu-Mn-Mg second alloy powder; and in the vacuum drying treatment, the drying temperature is 70-90 ℃, the drying time is 6-8 h, and the vacuum pressure is-0.8 bar to-1.0 bar.
Specifically, in order to improve the printing forming quality, before the Zn-Cu-Mn-Mg first alloy powder is subjected to vacuum drying treatment, the Zn-Cu-Mn-Mg first alloy powder may be subjected to powder screening treatment based on a preset powder screening standard, so as to obtain a printing powder with a more uniform particle size.
S20, obtaining a laser selective melting parameter based on a target structural parameter of a Zn-Cu-Mn-Mg target porous alloy; the laser selective melting parameters are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg.
The Zn-Cu-Mn-Mg target porous alloy is a target structure formed by printing, the size, shape and pore size of the porous structure rod can be set by using a 3-matic software module, and the target structure of the Zn-Cu-Mn-Mg target porous alloy is shown in figure 2. Specifically, before the target structural parameters of the Zn-Cu-Mn-Mg-based target porous alloy are obtained, the method further comprises the steps of: dividing the Zn-Cu-Mn-Mg porous alloy into a plurality of unit grid structures; wherein each cell grid structure consists of a plurality of rods; the target structural parameter of the Zn-Cu-Mn-Mg porous alloy is set to be that the diameter of the rod is 0.20-0.5 mm, the rod diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is 0-120 degrees.
Based on the target structural parameters of the Zn-Cu-Mn-Mg target porous alloy, the obtained laser selective melting parameters are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg.
And step S30, printing to obtain the Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters.
In practical application, the printing to obtain Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters comprises the following steps: obtaining a model file of a Zn-Cu-Mn-Mg target porous alloy model; obtaining laser selective melting parameters based on a model file of the Zn-Cu-Mn-Mg target porous alloy model; slicing the Zn-Cu-Mn-Mg target porous alloy model based on the laser selective melting parameters to obtain slice files; and (3) introducing the slice file into laser selective melting forming equipment, and starting printing to obtain the Zn-Cu-Mn-Mg porous alloy.
In practical application, the step of introducing the slice file into a laser selective melting forming device to start printing to obtain the Zn-Cu-Mn-Mg porous alloy comprises the following steps: introducing the slice file into laser selective melting forming equipment, paving powder, heating a substrate, introducing argon for protection, and starting printing to obtain Zn-Cu-Mn-Mg porous alloy; wherein the surface roughness of the substrate is Ra1.6μm-Ra3.2μm.
In the actual printing process, the purity of argon in a printing cavity of the laser selective melting forming equipment is 99.999 percent, the oxygen content in the cavity is lower than 100ppm, the pressure in the cavity is 0 mbar-20 mbar, and the dedusting air quantity is 17-21 m 3 /h。
After the practical application is finished, the cavity door can be opened again when the temperature in the cavity is reduced to the room temperature, the clean powder is taken out, the clean powder is vibrated firstly, then the air is blown, and the substrate is removed by wire cutting, so that the porous printing piece is obtained. The porous printing piece is Zn-Cu-Mn-Mg porous alloy, which consists of a plurality of unit grid structures, wherein each unit grid structure consists of a plurality of rods; the diameter of the rod is 0.20-0.5 mm, the diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is 0-120 degrees.
Compared with the prior art, the Zn-Cu-Mn-Mg porous alloy disclosed by the embodiment of the application comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%; the Zn-Cu-Mn-Mg porous alloy has the advantages of good biocompatibility, degradability and innocuity, so that the porous structure characteristic of the Zn-Cu-Mn-Mg porous alloy can be used for promoting the adhesion of bone tissues, but the porous structure is difficult to manufacture by adopting a conventional machining method, so that the Zn-Cu-Mn-Mg porous alloy is obtained after the Zn-Cu-Mn-Mg porous alloy is mixed by the mass percentage components; and performing laser selective melting forming on the Zn-Cu-Mn-Mg powder serving as printing powder to obtain the printing powder; however, because the melting point of Zn is low, metal vapor is easy to form and adhere to the laser lens, the printing is affected, and the melting point of Cu, mn, mg, zn is very different, so that vaporization of low-melting-point elements or unfused of high-melting-point elements are easy to cause, and printing failure is caused; the present application therefore further defines the parameters of selective laser melting, namely: the thickness of the powder spreading layer is 20-30 mu m, the diameter of the light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the stripe interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle ranges from 60 DEG to 120 DEG and from 240 DEG to 300 deg. By the method, the printing efficiency of the porous alloy can be improved, and then the unsupported Zn-Cu-Mn-Mg porous alloy structure with ideal performance requirements is obtained.
In order to facilitate understanding of the technical solutions described in the present application by those skilled in the art, the following more detailed description of the technical solutions described in the present application is provided in connection with specific embodiments:
example 1
(1) The Zn-Cu-Mn-Mg alloy powder is prepared by a rotary electrode atomization method and consists of the following components: cu 1%, mn2%, mg2%, and Zn in balance, with the total mass percentage being 100%; screening powder before printing, and vacuum drying at 80deg.C for 6 hr under vacuum pressure of-1.0 bar.
(2) The method comprises the steps of carrying out parameterization design by using a 3-matrix software module, designing a single unit structure, wherein the diameter of a rod is 0.20mm, the maximum span of the diameter of the rod is less than 4mm, clamping angles between the rod and the rod are 0-120 DEG porous model files, guiding the files into magics software for position placement, adopting self-supporting, and setting printing parameters as follows: the thickness of the powder spreading layer is 20 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 95W, the scanning speed is 860mm/s, the scanning interval is 0.06mm, the stripe interval is-0.06 mm, the path offset is 0.03mm, the jump angle is selected and applied, the jump angle range is 60-120 degrees, and the jump angle is 240-300 degrees, and then slicing is carried out, so that a slice file is formed.
(3) Introducing the slice file obtained in the step (2) into laser selective melting forming equipment, mounting a substrate with roughness of Ra1.6-Ra3.2 mu m, mounting a scraper, paving powder, setting the heating temperature of the substrate to 80 ℃, introducing argon with purity of 99.999% to protect a cavity, wherein the oxygen content in the cavity is lower than 100ppm, the pressure in the cavity is 0-20 mbar, and the dust removal air quantity is 19 m 3 H, starting printing;
(4) After printing is finished, the printing equipment is closed, the cavity door is opened when the temperature in the cavity is reduced to room temperature, the printing piece is subjected to powder cleaning treatment after being taken out, firstly, the powder cleaning is vibrated, then the powder cleaning is carried out through flow channel blowing, and the substrate is removed through linear cutting, so that the printing piece, namely the Zn-Cu-Mn-Mg porous alloy, is obtained.
The Zn-Cu-Mn-Mg porous alloy subjected to laser selective melting and forming in this example was subjected to elastic modulus test and human body fluid corrosion rate simulation test for 30 days by using the same sample batch, and the test results are shown in Table 1.
Example 2
(1) The Zn-Cu-Mn-Mg alloy powder is prepared by a rotary electrode atomization method and consists of the following components: cu 2%, mn1%, mg1%, and Zn in balance, with the total mass percentage being 100%; screening powder before printing, and vacuum drying at 80deg.C for 8 hr under vacuum pressure of-1.0 bar.
(2) The method comprises the steps of carrying out parameterization design by using a 3-matrix software module, designing a single unit structure, wherein the diameter of a rod is 0.30mm, the maximum span of the diameter of the rod is less than 4mm, clamping angles between the rod and the rod are 0-120 DEG porous model files, guiding the files into magics software for position placement, adopting self-supporting, and setting printing parameters as follows: the thickness of the powder spreading layer is 30 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 120W, the scanning speed is 1050mm/s, the scanning interval is 0.08mm, the stripe interval is-0.06 mm, the path offset is 0.04mm, the jump angle is selected and applied, the jump angle range is 60-120 degrees, and the jump angle is 240-300 degrees, and then slicing is carried out, so that a slice file is formed.
(3) Introducing the slice file obtained in the step (2) into laser selective melting forming equipment, mounting a substrate with roughness of Ra1.6-Ra3.2 mu m, mounting a scraper, paving powder, setting the heating temperature of the substrate to 80 ℃, introducing argon with purity of 99.999% to protect a cavity, wherein the oxygen content in the cavity is lower than 100ppm, the pressure in the cavity is 0-20 mbar, and the dust removal air quantity is 21 m 3 H, starting printing;
(4) After printing is finished, the printing equipment is closed, the cavity door is opened when the temperature in the cavity is reduced to room temperature, the printing piece is subjected to powder cleaning treatment after being taken out, firstly, the powder cleaning is vibrated, then the powder cleaning is carried out through flow channel blowing, and the substrate is removed through linear cutting, so that the printing piece, namely the Zn-Cu-Mn-Mg porous alloy, is obtained.
The Zn-Cu-Mn-Mg porous alloy subjected to laser selective melting and forming in this example was subjected to elastic modulus test and human body fluid corrosion rate simulation test for 30 days by using the same sample batch, and the test results are shown in Table 1.
Example 3
(1) The Zn-Cu-Mn-Mg alloy powder is prepared by a rotary electrode atomization method and consists of the following components: cu 2%, mn2%, mg2%, and Zn in balance, with the total mass percentage being 100%; screening powder before printing, and vacuum drying at 80deg.C for 6 hr under vacuum pressure of-0.8 bar.
(2) The method comprises the steps of carrying out parameterization design by using a 3-matrix software module, designing a single unit structure, wherein the diameter of a rod is 0.50mm, the maximum span of the diameter of the rod is less than 4mm, clamping angles between the rod and the rod are 0-120 DEG porous model files, guiding the files into magics software for position placement, adopting self-supporting, and setting printing parameters as follows: the thickness of the powder spreading layer is 20 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 96W, the scanning speed is 9600mm/s, the scanning interval is 0.08mm, the stripe interval is-0.06 mm, the path offset is 0.04mm, the jump angle is selected and applied, the jump angle range is 60-120 degrees, and the jump angle is 240-300 degrees, and then slicing is carried out, so that a slice file is formed.
(3) Introducing the slice file obtained in the step (2) into laser selective melting forming equipment, mounting a substrate with roughness of Ra1.6-Ra3.2 mu m, mounting a scraper, paving powder, setting the heating temperature of the substrate to 80 ℃, introducing argon with purity of 99.999% to protect a cavity, wherein the oxygen content in the cavity is lower than 100ppm, the pressure in the cavity is 0-20 mbar, and the dust removal air quantity is 20m 3 H, starting printing;
(4) After printing is finished, the printing equipment is closed, the cavity door is opened when the temperature in the cavity is reduced to room temperature, the printing piece is cleaned after being taken out, the cleaning is vibrated firstly, then the cleaning is blown through a runner, and the substrate is removed through linear cutting, so that the printing piece, namely the Zn-Cu-Mn-Mg porous alloy, is obtained.
The Zn-Cu-Mn-Mg porous alloy subjected to laser selective melting and forming in this example was subjected to elastic modulus test and human body fluid corrosion rate simulation test for 30 days by using the same sample batch, and the test results are shown in Table 1.
Table 1:
it can be seen that the Zn-Cu-Mn-Mg porous alloy structure obtained by the method of the embodiment of the application has the elastic modulus of 11-18 GPa and the corrosion rate of body fluid of a human body of 0.21-0.28mm/year in 30 days, and can meet the requirements of the degradable metal-based bone implant product on the strength and the corrosion rate of the bone implant.
In summary, compared with the prior art, the method for laser selective fusion forming of the Zn-Cu-Mn-Mg porous alloy structure solves the problems that metal vapor is influenced and printing forming is difficult due to large difference of element melting points in alloy components in the laser selective fusion forming process of the Zn-Cu-Mn-Mg porous alloy structure, the unsupported Zn-Cu-Mn-Mg porous alloy structure is obtained, the elastic modulus of the structure is 10-18 GPa, the elastic modulus of the structure is close to that of a human bone, the corrosion rate of body fluid of a human body is 0.21-0.28mm/year after 30 days, and the requirements of the degradable metal porous implant product on the strength and the corrosion rate of the bone implant can be met.
The foregoing description is only of the preferred embodiments of the present application, and is not intended to limit the scope of the claims, and all equivalent structures or equivalent processes using the descriptions and drawings of the present application, or direct or indirect application in other related technical fields are included in the scope of the claims of the present application.
Claims (7)
1. A selective laser melting forming method for a Zn-Cu-Mn-Mg alloy porous structure is characterized by comprising the following steps:
preparing Zn-Cu-Mn-Mg powder; wherein the Zn-Cu-Mn-Mg powder comprises the following components in percentage by mass: 1-2% of Cu, 1-2% of Mn, 1-2% of Mg and the balance of Zn, wherein the total mass percentage is 100%;
dividing a Zn-Cu-Mn-Mg target porous alloy model into a plurality of unit grid structures; wherein each cell grid structure consists of a plurality of rods; setting the target structural parameters of the Zn-Cu-Mn-Mg target porous alloy model to be that the diameter of the rod is 0.20-0.5 mm, the rod diameter span of the rod is 1-4 mm, and the included angle between the rod and the adjacent rod is more than 0 degrees and less than 120 degrees;
acquiring a laser selective melting parameter based on a target structural parameter of the Zn-Cu-Mn-Mg target porous alloy; the laser selective melting parameters are as follows: the thickness of the powder spreading layer is 20-30 mu m, the diameter of a light spot is 50 mu m, the outline is cancelled, only the inner surface is opened, the laser power is 90-120W, the scanning speed is 850-1050 mm/s, the scanning interval is 0.06-0.08 mm, the strip interval is-0.06 mm, the path offset is 0.03-0.04 mm, the jump angle is selected, and the jump angle range is 60-120 degrees and 240-300 degrees;
printing to obtain Zn-Cu-Mn-Mg porous alloy based on the laser selective melting parameters; the structural elastic modulus of the Zn-Cu-Mn-Mg porous alloy is 10 GPa-18 GPa, and the corrosion rate of human body fluid is 0.21 mm/year-0.28 mm/year in 30 days; argon purity in a printing cavity of the laser selective melting forming equipment is 99.999%, oxygen content in the cavity is lower than 100ppm, pressure in the cavity is 0 mbar-20 mbar, and dust removal air quantity is 17-21 m 3 /h。
2. The method for selective laser melting forming of a Zn-Cu-Mn-Mg alloy porous structure according to claim 1, wherein said printing to obtain a Zn-Cu-Mn-Mg porous alloy based on said selective laser melting parameters comprises:
obtaining a model file of a Zn-Cu-Mn-Mg target porous alloy model;
obtaining laser selective melting parameters based on a model file of the Zn-Cu-Mn-Mg target porous alloy model;
slicing the Zn-Cu-Mn-Mg target porous alloy model based on the laser selective melting parameters to obtain slice files;
and (3) introducing the slice file into laser selective melting forming equipment, and starting printing to obtain the Zn-Cu-Mn-Mg porous alloy.
3. The method for selective laser melting and forming of a Zn-Cu-Mn-Mg alloy porous structure according to claim 2, wherein the step of introducing the slice file into a selective laser melting and forming device and starting printing to obtain the Zn-Cu-Mn-Mg porous alloy comprises the following steps:
introducing the slice file into laser selective melting forming equipment, paving powder, heating a substrate, introducing argon for protection, and starting printing to obtain Zn-Cu-Mn-Mg porous alloy; wherein the surface roughness of the substrate is Ra1.6μm-Ra3.2μm.
4. The selective laser melting forming method of a Zn-Cu-Mn-Mg alloy porous structure according to claim 3, wherein during printing, the purity of argon in a printing chamber of the selective laser melting forming device is 99.999%, the oxygen content in the chamber is lower than 100ppm, the pressure in the chamber is 0 mbar-20 mbar, and the dedusting air quantity is 17-21 m 3 /h。
5. The method for selective laser melting and forming a porous structure of a Zn-Cu-Mn-Mg alloy according to claim 3, wherein the substrate is subjected to surface roughening treatment before heating, and the roughness value after the surface roughening treatment is Ra1.6-Ra3.2 μm, and the heating temperature of the substrate is 80 ℃.
6. The method for laser selective melt forming of a Zn-Cu-Mn-Mg alloy porous structure according to claim 1, wherein said preparing Zn-Cu-Mn-Mg powder comprises:
obtaining Zn-Cu-Mn-Mg first alloy powder based on a rotating electrode atomization method;
and carrying out vacuum drying treatment on the Zn-Cu-Mn-Mg first alloy powder to obtain Zn-Cu-Mn-Mg second alloy powder.
7. The selective laser melting forming method of the Zn-Cu-Mn-Mg alloy porous structure according to claim 1, wherein the drying temperature of the vacuum drying treatment is 70-90 ℃, the drying time is 6-8 h, and the vacuum pressure is-0.8 bar to-1.0 bar.
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