CN1171529C - 植物生长调节剂及其制备方法 - Google Patents
植物生长调节剂及其制备方法 Download PDFInfo
- Publication number
- CN1171529C CN1171529C CNB991165586A CN99116558A CN1171529C CN 1171529 C CN1171529 C CN 1171529C CN B991165586 A CNB991165586 A CN B991165586A CN 99116558 A CN99116558 A CN 99116558A CN 1171529 C CN1171529 C CN 1171529C
- Authority
- CN
- China
- Prior art keywords
- plant growth
- growth regulator
- citrate
- present
- preparing process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000005648 plant growth regulator Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title abstract description 4
- 230000008569 process Effects 0.000 title abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 21
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical group CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 18
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 11
- 235000013336 milk Nutrition 0.000 claims description 10
- 239000008267 milk Substances 0.000 claims description 10
- 210000004080 milk Anatomy 0.000 claims description 10
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- 239000001488 sodium phosphate Substances 0.000 claims description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 4
- 239000013638 trimer Substances 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000003750 conditioning effect Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- WIASXBABRUNXHD-UHFFFAOYSA-N C(C)N(CC)C(C)O.C(CCCCC)(=O)O Chemical compound C(C)N(CC)C(C)O.C(CCCCC)(=O)O WIASXBABRUNXHD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 150000005690 diesters Chemical class 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 235000013399 edible fruits Nutrition 0.000 description 6
- ZQPGEEYBLVXLFJ-UHFFFAOYSA-N C(C)O.NNC(NN)=O Chemical compound C(C)O.NNC(NN)=O ZQPGEEYBLVXLFJ-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000006837 decompression Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000446313 Lamella Species 0.000 description 2
- 235000011430 Malus pumila Nutrition 0.000 description 2
- 235000015103 Malus silvestris Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 102000003992 Peroxidases Human genes 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 108040007629 peroxidase activity proteins Proteins 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 229930192334 Auxin Natural products 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- NNJVILVZKWQKPM-UHFFFAOYSA-N Lidocaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=CC=C1C NNJVILVZKWQKPM-UHFFFAOYSA-N 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 108090000913 Nitrate Reductases Proteins 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 235000010208 anthocyanin Nutrition 0.000 description 1
- 229930002877 anthocyanin Natural products 0.000 description 1
- 239000004410 anthocyanin Substances 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000007952 growth promoter Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229960004194 lidocaine Drugs 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cultivation Of Plants (AREA)
Abstract
本发明涉及一种植物生长调节剂，尤其是一种以己酸二乙氨基乙醇酯柠檬酸盐为基本原料的活性植物生长调节剂及其制备方法。所述的己酸二乙氨基乙醇酯柠檬酸盐的分子式为：该植物生长调节剂不仅便于使用，安全系数高而且成本低，增效显著。
Description
本发明涉及一种植物生长调节剂，尤其是一种以己酸二乙氨基乙醇酯柠檬酸盐为主要原料的活性植物生长促进剂及其制备方法。
目前农业中使用较广泛的大都还是国际上六十年代以前研究出来的如生长素类、赤霉素类、细胞分裂素类产品或其复配产品，它们不同程度地存在著作用单一，增产同时可能使品质下降，合成工艺老化、繁杂，原料来源受限制，成本昂贵等不足之处。
本发明的目的是要提供一种植物生长调节剂及其制备方法。该植物生长调节剂不仅便于使用，安全系数高而且成本低，增效显著。
本发明的植物生长调节剂是以己酸二乙氨基乙醇酯柠檬酸盐或者是以己酸二乙氨基乙醇酯柠檬酸盐为基本原料配制的乳粉。
己酸二乙氨基乙醇酯柠檬酸盐的分子式为：
己酸二乙氨基乙醇酯柠檬酸盐的理化性质：
1.形状：白色或微黄色粉状物
2.溶解度：易溶于水、热乙醇，难溶于氯仿，不溶于苯。
3.稳定性：室温下稳定，在酸性条件下(pH＝3-4)较稳定，在碱性溶液中(pH＞8)易水解而失去活性。
4.毒性：经上海医科大学测定，大鼠急性经口LD50＝8632.76-16569.77mg/kg，小鼠急性经口LD50＝7190.1-10196.5mg/kg，属实际无毒农药，对白鼠、兔子眼睛及皮肤无刺激作用，无致癌、致突变和致畸。
己酸二乙氨基乙醇酯柠檬酸盐的制取工艺步骤是：
1.选料：己酸、二乙氨基乙醇、甲苯，它们的重量配比为0.9-1.1∶0.8-1.1∶0.8-1。
2.常压反应：温度为100℃-160℃；时间：6-8h；应收集的水分量与二乙氨基乙醇的重量比为0.8-1.1∶1。
3.减压反应：真空度为0.09-0.1Mpa，先分离甲苯，收集温度为80℃-130℃再收集己二酯。收集温度为130℃-150℃。
4.加酸反应：将己分离出的己二酯按1∶1-2的重量配比拌入柠檬酸进行常压反应，制得粉末状己酸二乙氨基乙醇酯柠檬酸盐。
制取己酸二乙氨基乙醇酯柠檬酸盐的反应式为：
本发明的植物生长调节剂的基本原料系选用己酸、二乙氨基二醇、柠檬酸为原料，反应生成己酸二氨基乙醇酶柠檬酸盐。其中的二乙氨基乙醇，又称N，N-二乙基乙醇胺，具有使植物生长加快，果实着色好的特点。其它因与己酸反应生成的酯化物，在空气中易被氧气氧化，脱水后从开链化合物变为杂环物，将失去其生理活性：并且本身为液体，难于保存，故本发明针对其特性，在工艺中添加柠檬酸与其反应，使其生成呈酸性的粉末状的盐从而能确保调节剂性状稳定，生理活性不变。
下面结合实施例对本发明予以具体叙述：
本发明制取己酸二乙氨基乙醇酯柠檬酸盐的实施例一是：
1.选料：选用100L的反应釜，取己酸22.1kg，二乙氨基乙醇19.88kg，甲苯18kg。
2.将原料放入与大气相通的反应釜内，升温搅拌至收集的水量达到3.06kg，停止搅拌。
3.冷却过滤，对滤液进行减压蒸馏，在真空度为0.1MPa下，分离甲苯与己二酯，收集甲苯的温度为80℃，收集量为18kg，再收集己二酯，温度为138℃，收集量为36.53kg左右。
4.将收集的己二酯按1∶1加入柠檬酸，反应放热后生成粉末状固体，即己酸二氨基乙醇酯柠檬酸盐。
本发明制取己酸二乙氨基乙醇酯柠檬酸盐的实施例二是：
1.选料：选用100L的反应釜，取己酸26.56kg，二乙氨基乙醇24.55kg，甲苯20kg。
2.将原料放入与大气相通的反应釜内，升温搅拌至收集的水量这到3.78kg，停止搅拌。
3.冷却过滤，对滤液进行减压蒸馏，在真空度为0.095Mpa下，分离甲苯与己二酯，收集甲苯的温度为95℃，收集量为20kg，再收集己二酯，温度为145℃，收集量为45.15kg。
4.将制取的己二酯按1∶1加入柠檬酸，反应放热后生成粉末状固体，即己酸二氨基乙醇酯柠檬酸盐。
本发明的植物生长调节剂可复配成可溶性乳粉，各组分的重量比为己酸二乙氨基乙醇酯柠檬酸盐15-30％；三聚磷酸钠5-15％；硫酸铵55-80％。
本发明可溶性乳粉实施例一的配比为：
己酸二乙氨基乙醇脂柠檬酸盐20％
硫酸铵70％
三聚磷酸钠10％
本发明可溶性乳粉实施例二的配比为：
己酸二乙氨基乙醇酯柠檬酸盐25％
硫酸铵70％
三聚磷酸钠5％
本发明的可溶性乳粉具有以下优点：1.使用时操作简单：由于己酸二氨基乙醇酯柠檬酸盐易溶于水，易与其他元素相容，对铜、铁、锌等金属离子有极好的耐受力，故可直接添加到各种粉剂、水剂中，无需再加任何有机溶剂、乳化剂等。2.安全系数高：无毒、无害、无残留，使用浓度安全幅度大，复配过程易于把握。3.成本低：投入产出比可高达1∶30-60以上，便于大规模推广应用。4.增效明显：本发明用己酸二氨基乙醇酯柠檬酸盐复配的可溶性乳粉，主要通过对植物细胞结构及其功能的影响和对其体内核酸、蛋白质、过氧化物酶等影响来有效调节植物的生长发育，从而使各种作物的产量和品质都有相当的提高。具体表现在促进植物幼叶中类襄体片层的分化，增加成叶中基粒数目和基粒片层的垛叠，从而促进光合作用，提高光合速率。同时，提高线粒体数目、H2O2的分解速率和叶绿素含量；显著提高RNA和可溶性蛋白的含量，提高过氧化酶、硝酸还原酶的活性，延缓植株内该酶活性降低速度，提高碳氮代谢，增强植株对水肥的吸收和干物质的积累，调节体内水分平衡，增强植物抗寒、抗旱、抗病能力。
经试验证明：每亩使用本发明可溶性乳粉1-3克(有效成分)，即以20-30ppm浓度喷施2-3次，可使水稻增产10-20％，小麦增产10-30％，玉米增产15-35％，花生、大豆、油菜、棉花、烟叶、茶叶、甜菜等作物增产15-40％，并能提高作物品质。
每亩使用本发明可溶性乳粉2-6克(有效成分)，即以40-50ppm浓度喷施2-3次，可使蔬菜(茄果类、根茎类、瓜豆类、叶类等)增产20-50％以上，并能促进早熟，增强抗逆性；用于果树(苹果、梨、桃、李、葡萄等)能保花护果，提高座果率，增大果实和提高质量，果实大小均匀，着色好，果皮光滑，增加糖份和维生素C等营养成分。
如小白菜：
试验单位：福建省农科院土肥所
试验处理：本发明可溶性乳粉10ppm、20ppm、40ppm溶液分别于播种后第19天和第26天进行叶面喷施肥。
试验结果：
浓度(ppm) 亩产(kg) 亩增产(kg) 增产率(％)
0 650 0 0
10 750 100 15.4
20 843 193 29.7
40 993 343 52.8
如苹果
| 新梢长度 新梢粗度 花芽数 单果重 产量 花青苷 糖 有机酸 | |
| 与对照相比+、-％ | +19.58 +26.23 +3.85 +14.47 +12.3 +45.4 +61.0 -6.04 |
如玉米、高梁、水稻、小麦、大豆
Claims (1)
1、一种植物生长调节剂，其特征在于该调节剂为可溶性乳粉，各组分的重量配比为己酸二乙氨基乙醇酯柠檬酸盐15-30％，三聚磷酸钠5-15％，硫酸铵55-80％。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991165586A CN1171529C (zh) | 1999-07-16 | 1999-07-16 | 植物生长调节剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991165586A CN1171529C (zh) | 1999-07-16 | 1999-07-16 | 植物生长调节剂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1280766A CN1280766A (zh) | 2001-01-24 |
| CN1171529C true CN1171529C (zh) | 2004-10-20 |
Family
ID=5279357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991165586A Expired - Lifetime CN1171529C (zh) | 1999-07-16 | 1999-07-16 | 植物生长调节剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1171529C (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102138560B (zh) * | 2011-01-24 | 2013-08-07 | 广东省农业科学院土壤肥料研究所 | 一种有机营养型抗旱剂配方及其制备方法 |
| CN102524296B (zh) * | 2011-12-31 | 2014-03-05 | 中国农业大学 | 一种植物生长调节剂及其制备方法与应用 |
| CN102701858B (zh) * | 2012-06-15 | 2014-02-05 | 郑州郑氏化工产品有限公司 | 一种水稻控旺抗倒增产的调节剂组合物 |
| CN113045439B (zh) * | 2021-03-25 | 2022-10-18 | 礼研科技(济南)有限公司 | 琥珀酸单-(2-二乙基氨基-乙基)酯及制备方法与应用 |
| CN113072446A (zh) * | 2021-04-19 | 2021-07-06 | 张�林 | 一种植物生长刺激素的制备方法及其应用 |
| CN113105345B (zh) * | 2021-04-19 | 2023-07-07 | 鹤壁全丰生物科技有限公司 | 一种胺鲜酯柠檬酸盐生产工艺 |
| CN114982757A (zh) * | 2022-05-09 | 2022-09-02 | 郑州尼采生物科技有限公司 | 一种酯类或叔胺类植物生长调节剂水剂的制作方法 |
-
1999
- 1999-07-16 CN CNB991165586A patent/CN1171529C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1280766A (zh) | 2001-01-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101870604B (zh) | 一种复合寡糖植物生长促进剂及其制备方法 | |
| KR100866587B1 (ko) | 게르마늄 및 셀레늄 함유 액상비료의 제조방법, 이로부터제조된 액상비료 및 이를 이용한 작물의 재배방법 | |
| CN100546948C (zh) | 植物源抗病型叶面肥及其制备方法 | |
| CN100556863C (zh) | 一种促进农作物生长的营养素 | |
| CN1171529C (zh) | 植物生长调节剂及其制备方法 | |
| CN108164334A (zh) | 一种富硒沙糖桔肥料以及沙糖桔的高产种植法 | |
| CN111011139A (zh) | 一种富硒无公害土豆的种植方法 | |
| CN109220647B (zh) | 高微量元素高酶活水稻的种植方法 | |
| CN111960886A (zh) | 一种复合微生物菌肥及应用 | |
| CN106748213A (zh) | 一种氨基酸水溶肥及其制作方法 | |
| CN104987259A (zh) | 一种香蕉专用肥及其制备方法 | |
| CN115124376A (zh) | 一种复合生物肥料及其制备方法 | |
| CN113121286B (zh) | 富硒液肥和富硒大米的种植方法 | |
| CN112544360B (zh) | 一种蓖麻与剑麻混合种植的综合利用方法 | |
| CN1050971C (zh) | 植物生长杀菌促进剂的制备方法 | |
| CN113929536A (zh) | 一种提高产量的有机茶专用有机肥及其施用方法 | |
| CN113135797A (zh) | 一种人参专用碳基生物菌肥及制备方法 | |
| CN113443946A (zh) | 用于提高黄瓜产量和品质的水溶性肥料及其制备方法 | |
| CN1054966A (zh) | 农作物根外营养喷施肥的组合物和生产工艺 | |
| CN112174749A (zh) | 一种液体土壤调理剂及其制备方法 | |
| CN112674097A (zh) | 一种壳寡糖和s-诱抗素的复配杀菌调节剂及制备方法 | |
| CN111533607A (zh) | 促进番茄保花保果的叶面肥及其制备方法 | |
| CN109928855A (zh) | 一种富含黄腐酸钾型微生物菌剂及其制备方法 | |
| CN111943756B (zh) | 一种柑橘叶面补硒肥及其喷施方法 | |
| CN1063673A (zh) | 多效灵(钒化合物) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| ASS | Succession or assignment of patent right |
Owner name: FUJIAN SUPER HAOLUN PLANT GROWTH PROMOTING AGENT Free format text: FORMER OWNER: WU SHAONING Effective date: 20020111 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20020111 Address after: 350001 room 602, block A, banyan village, Wenquan branch, Fuzhou, Fujian Applicant after: Fujian Chaoda Haolun Plant Growth Agent Co., Ltd. Address before: 350001 room 602, block A, banyan village, Wenquan branch, Fuzhou, Fujian Applicant before: Wu Shaoning |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: CHINA AGROTECH HOLDINGS LIMITED,FUJIAN Free format text: FORMER NAME OR ADDRESS: FUJIAN SUPER HAOLUN PLANT GROWTH PROMOTING AGENT CO., LTD. |
|
| CP03 | Change of name, title or address |
Address after: 350001 Drum Tower, 154 East Lake Road, tower 31, Zhongshan, Fujian Patentee after: China Agrotech Holdings Limited,Fujian Address before: 350001 room 602, block A, banyan village, Wenquan branch, Fuzhou, Fujian Patentee before: Fujian Chaoda Haolun Plant Growth Agent Co., Ltd. |
|
| ASS | Succession or assignment of patent right |
Owner name: SHANXI GUANGDA CHEMICAL CO., LTD. Free format text: FORMER OWNER: CHINA AGROTECH HOLDINGS LIMITED,FUJIAN Effective date: 20140811 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 350001 FUZHOU, FUJIAN PROVINCE TO: 043699 YUNCHENG, SHAANXI PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20140811 Address after: Joe Village 043699 Shanxi city of Yuncheng province Jiang county Jiang Ancient Town oblique Patentee after: Shanxi Guangda Chemical Co., Ltd. Address before: 350001 Drum Tower, 154 East Lake Road, tower 31, Zhongshan, Fujian Patentee before: China Agrotech Holdings Limited,Fujian |
|
| DD01 | Delivery of document by public notice |
Addressee: Wang Fang Document name: Notification that Application Deemed not to be Proposed |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160608 Address after: 043699 Shanxi city of Yuncheng province Jiang County Development Zone Industrial Park No. 18 Patentee after: SHANXI HAOZHIDA BIOLOGICAL SCIENCE & TECHNOLOGY CO., LTD. Address before: Joe Village 043699 Shanxi city of Yuncheng province Jiang county Jiang Ancient Town oblique Patentee before: Shanxi Guangda Chemical Co., Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20041020 |