CN117143676A - Silk laundry detergent with effects of preventing silk fading/color cross and softening - Google Patents
Silk laundry detergent with effects of preventing silk fading/color cross and softening Download PDFInfo
- Publication number
- CN117143676A CN117143676A CN202311120500.4A CN202311120500A CN117143676A CN 117143676 A CN117143676 A CN 117143676A CN 202311120500 A CN202311120500 A CN 202311120500A CN 117143676 A CN117143676 A CN 117143676A
- Authority
- CN
- China
- Prior art keywords
- silk
- laundry detergent
- cross
- fading
- softening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 230000000694 effects Effects 0.000 title claims abstract description 43
- 238000005562 fading Methods 0.000 title claims abstract description 37
- -1 alkyl glycosides Chemical class 0.000 claims abstract description 66
- 238000002360 preparation method Methods 0.000 claims abstract description 35
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 32
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 30
- 108010022355 Fibroins Proteins 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 29
- 150000001413 amino acids Chemical class 0.000 claims abstract description 25
- 239000000872 buffer Substances 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- 239000006260 foam Substances 0.000 claims abstract description 22
- 229930182470 glycoside Natural products 0.000 claims abstract description 22
- 239000003755 preservative agent Substances 0.000 claims abstract description 22
- 240000003377 Shepherdia canadensis Species 0.000 claims abstract description 18
- 235000018324 Shepherdia canadensis Nutrition 0.000 claims abstract description 18
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 16
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940046009 vitamin E Drugs 0.000 claims abstract description 16
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 16
- 239000011709 vitamin E Substances 0.000 claims abstract description 16
- 239000011780 sodium chloride Substances 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 238000003756 stirring Methods 0.000 claims description 26
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 23
- 108090000790 Enzymes Proteins 0.000 claims description 22
- 102000004190 Enzymes Human genes 0.000 claims description 22
- 229940088598 enzyme Drugs 0.000 claims description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 230000002335 preservative effect Effects 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 19
- 229910021641 deionized water Inorganic materials 0.000 claims description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 19
- 229930195729 fatty acid Natural products 0.000 claims description 19
- 239000000194 fatty acid Substances 0.000 claims description 19
- 229910052710 silicon Inorganic materials 0.000 claims description 19
- 239000010703 silicon Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 16
- 239000003094 microcapsule Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 238000005070 sampling Methods 0.000 claims description 14
- 239000011265 semifinished product Substances 0.000 claims description 14
- 239000000975 dye Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 230000002265 prevention Effects 0.000 claims description 8
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 7
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 7
- 239000004382 Amylase Substances 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 229940106157 cellulase Drugs 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- RGUVUPQQFXCJFC-UHFFFAOYSA-N n-hydroxyoctanamide Chemical compound CCCCCCCC(=O)NO RGUVUPQQFXCJFC-UHFFFAOYSA-N 0.000 claims description 7
- 229940069338 potassium sorbate Drugs 0.000 claims description 7
- 235000010241 potassium sorbate Nutrition 0.000 claims description 7
- 239000004302 potassium sorbate Substances 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 239000001509 sodium citrate Substances 0.000 claims description 7
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 7
- 229940088594 vitamin Drugs 0.000 claims description 7
- 229930003231 vitamin Natural products 0.000 claims description 7
- 235000013343 vitamin Nutrition 0.000 claims description 7
- 239000011782 vitamin Substances 0.000 claims description 7
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 102000008186 Collagen Human genes 0.000 claims description 2
- 108010035532 Collagen Proteins 0.000 claims description 2
- 108010077895 Sarcosine Proteins 0.000 claims description 2
- KTYVHLCLTPLSGC-UHFFFAOYSA-N amino propanoate Chemical compound CCC(=O)ON KTYVHLCLTPLSGC-UHFFFAOYSA-N 0.000 claims description 2
- 229920001436 collagen Polymers 0.000 claims description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 2
- 229940065859 sodium cocoyl glycinate Drugs 0.000 claims description 2
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 claims description 2
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 14
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000003431 cross linking reagent Substances 0.000 abstract description 5
- 229940079919 digestives enzyme preparation Drugs 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 20
- 238000012360 testing method Methods 0.000 description 10
- 239000000835 fiber Substances 0.000 description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229940045845 sodium myristate Drugs 0.000 description 5
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical group [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 5
- 230000003020 moisturizing effect Effects 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- FWBHETKCLVMNFS-UHFFFAOYSA-N 4',6-Diamino-2-phenylindol Chemical compound C1=CC(C(=N)N)=CC=C1C1=CC2=CC=C(C(N)=N)C=C2N1 FWBHETKCLVMNFS-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002996 emotional effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Abstract
The invention discloses a silk liquid laundry detergent with effects of preventing silk fading/color cross and softening, which comprises the following raw materials: amino acid surfactants, alkyl glycosides, foam control agents, soapberry extract, chelating buffers, polymethylsiloxane/hydrolyzed fibroin, anti-cross-linking agents, microencapsulated vitamin E, preservatives, enzyme preparations, and sodium chloride; the invention also discloses a preparation method of the silk laundry detergent with the effects of preventing silk fading/color cross and softening. The liquid laundry detergent prepared by the invention not only can effectively remove stubborn stains, but also can effectively prevent fading/cross color among clothes, can keep the flexibility of real silk clothes after washing, and has good affinity to skin.
Description
Technical Field
The invention belongs to the technical field of laundry detergent, and relates to a real silk laundry detergent with effects of preventing real silk from fading/cross color and softening.
Background
With the continuous improvement of living standard, consumers are more and more favored for high-end real silk clothes, which often have higher value or price, but the existing silk and wool laundry detergent only emphasizes the cleaning effect, so that problems such as decolorization, color cross, fiber hardening and the like can be generated on the real silk clothes under most application conditions, and property loss and emotional value loss are caused. Therefore, the preparation of the laundry detergent which is friendly to real silk fabrics, can avoid the phenomena of fading and cross color of the fabrics in the common washing process and ensures the softness of clothes at the same time becomes a technical problem to be solved in the field.
Disclosure of Invention
The invention aims to provide the real silk laundry detergent with the effects of preventing real silk from fading/color mixing and softening, the prepared laundry detergent not only can effectively remove stubborn stains, but also can effectively prevent fading and color mixing among clothes, can keep the flexibility of the real silk clothes after washing, and has good affinity to skin.
The aim of the invention can be achieved by the following technical scheme:
the real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: 25% -45% of amino acid surfactant; 10% -30% of alkyl glycoside; 0.5 to 1.5 percent of foam control agent; soapberry extract 0.5-2.2%; 2% -3% of chelating buffer; 3% -4% of polymethyl siloxane/hydrolyzed fibroin; 1% -3% of anti-stringing agent; microcapsule vitamin E0.8-1.2%; 0.2 to 1.4 percent of preservative; enzyme preparation 0.2% -1%; sodium chloride 0.2-1.5%; the balance of deionized water.
In a preferred embodiment of the present invention, the amino acid surfactant is any one of sodium cocoyl amino propionate, sodium cocoyl collagen amino acid, sodium cocoyl sarcosinate, sodium cocoyl glutamate, and sodium cocoyl glycinate.
As a preferable technical scheme of the invention, the carbon chain length of the alkyl glycoside is C8-C14.
As a preferable technical scheme of the invention, the foam control agent consists of fatty acid salt with carbon chain length of C12-C18 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:1.2-1:2.
As a preferable technical scheme of the invention, the chelating buffer consists of citric acid and sodium citrate with the mass ratio of 1.5:1.7-1:1.5.
As a preferable technical scheme of the invention, the preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
As a preferable technical scheme of the invention, the enzyme preparation consists of amylase and cellulase in a mass ratio of 1:3-1:5.
As a preferable technical scheme of the invention, the anti-cross-linking agent is a vinyl pyrrolidone/vinyl imidazole copolymer.
As a preferable technical scheme of the invention, the preparation method of the vinyl pyrrolidone/vinyl imidazole copolymer comprises the following steps:
s1: sequentially adding 10-16 parts by weight of vinyl pyrrolidone, 5-8 parts by weight of vinyl imidazole, 0.2-1 part by weight of ethanol with the concentration of 10% -15% and 15-20 parts by weight of deionized water into a stirrer, introducing nitrogen, stirring at the rotating speed of 200-220 r/min for 1-1.5 hours, and heating to 70 ℃ to obtain a reaction solution G1;
s2: adding azodiisobutyronitrile into the reaction solution G1, keeping the temperature at 70 ℃ for 10-12 hours, then heating to 75-80 ℃ for continuous reaction for 2-4 hours, and cooling the reaction solution to room temperature after the reaction is finished to obtain a reaction solution G2;
s3: evaporating the reaction solution G2 to remove impurities, and drying in a vacuum drying oven at 45-55 ℃ until the weight is constant to obtain the vinyl pyrrolidone/vinyl imidazole copolymer.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight percentage of each raw material;
a2: adding alkyl glycoside, foam control agent, anti-cross dye, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 500-850 r/min; stirring for 10-15 min at 60-70 ℃;
a3: when the temperature of the stirrer in a1 is reduced to 35-45 ℃, sequentially adding an amino acid surfactant, a chelating buffer, a microcapsule vitamin E, an enzyme preparation and a soapberry extract into the stirrer, increasing the rotating speed to 1100-1500 r/min, and stirring for 0.5-1 h;
a4: when the temperature of the stirrer in a2 is reduced to 25-35 ℃, adding polymethylsiloxane/hydrolyzed fibroin, stirring for 1-1.5 h at the rotating speed of 1100-1500 r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
The invention has the beneficial effects that:
(1) The amino acid surfactant, the chelating buffer, the microcapsule vitamin E, the enzyme preparation, the soapberry extract and the like added in the silk liquid laundry detergent with the effects of preventing silk fading/color cross and softening form a composite surface active system together, so that various stains such as dirt and the like can be effectively removed.
(2) The silk laundry detergent with the effects of preventing silk fading/color cross and softening has a core anti-cross dyeing system which is mainly composed of vinyl pyrrolidone/vinyl imidazole copolymer, has good dispersibility, can be effectively compatible with a plurality of organic and inorganic materials, can prevent redeposition of dispersed suspended particles (such as stains, fibers and the like) and can disperse dye or color agent in the washing liquid; meanwhile, the dye can form a compound with dye or a color agent, and the dye molecules are coated to prevent the dye molecules from contacting with other clothes and from being permeated and dyed, so that the effect of preventing real silk from fading/cross color is achieved.
(3) The silk laundry detergent with the effects of preventing silk fading/color cross and softening is mild and has no stimulation, and the added polymethylsiloxane/hydrolyzed fibroin, the microcapsule vitamin E and the soapberry extract have the effects of synergistically repairing small-scale damage of silk fibers and obviously improving the ductility and the surface smoothness of the silk fibers; meanwhile, the moisturizing and nourishing silk fiber has good moisturizing effects, deep-layer nourishing silk fiber, and a layer of glossy protective film is formed on the surface, so that smoothness, moisturizing degree and overall gloss are improved.
Detailed Description
In order to further describe the technical means and effects adopted by the present invention for achieving the intended purpose, the following detailed description is given below with reference to the embodiments, structures, features and effects according to the present invention.
Example 1
The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: 25% of an amino acid surfactant; 15% of alkyl glycoside; 1% of foam control agent; 1% of soapberry extract; 2.5% of chelating buffer; polymethylsiloxane/hydrolyzed fibroin 3%; 2% of anti-stringing agent; microcapsule vitamin E1%; 0.8% of preservative; enzyme preparation 0.5%; sodium chloride 1%; the balance of deionized water.
The amino acid surfactant is sodium cocoamidopropionate.
The alkyl glycoside has a carbon chain length of C12.
The foam control agent consists of fatty acid salt with carbon chain length of C14 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:1.5, the fatty acid salt is sodium myristate, and the organic silicon is methyl silicone oil.
The chelating buffer consists of citric acid and sodium citrate in a mass ratio of 5:6.
The polymethyl siloxane/hydrolyzed fibroin refers to that amino groups in hydrolyzed fibroin react with a quaternizing agent through quaternization reaction to be converted into a quaternary ammonium salt structure, and further, the hydrolyzed fibroin with the quaternary ammonium salt structure and the polymethyl siloxane are subjected to copolymerization reaction to form the polymethyl siloxane/hydrolyzed fibroin, and a source manufacturer is Chongqing kang's American biotechnology limited company.
The preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
The enzyme preparation consists of amylase and cellulase in a mass ratio of 1:3.
The source manufacturer of the microcapsule vitamin E is Wuhan mountain technology Co.
The anti-cross-linking agent is a vinyl pyrrolidone/vinyl imidazole copolymer.
The preparation method of the vinyl pyrrolidone/vinyl imidazole copolymer comprises the following steps:
s1: sequentially adding 12 parts by weight of vinyl pyrrolidone, 5 parts by weight of vinyl imidazole, 0.5 part by weight of ethanol with the concentration of 15% and 20 parts by weight of deionized water into a stirrer, introducing nitrogen, stirring at the rotating speed of 220r/min for 1.5 hours, and heating to 70 ℃ to obtain a reaction solution G1;
s2: adding azodiisobutyronitrile into the reaction solution G1, keeping the temperature at 70 ℃ for 10 hours, then heating to 80 ℃ for continuous reaction for 2 hours, and cooling the reaction solution to room temperature after the reaction is finished to obtain a reaction solution G2;
s3: evaporating the reaction solution G2 to remove impurities, and drying in a vacuum drying oven at 50 ℃ until the weight is constant to obtain the vinyl pyrrolidone/vinyl imidazole copolymer.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight percentage of each raw material;
a2: adding alkyl glycoside, foam control agent, anti-cross dye, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 650r/min; stirring for 15min at 70deg.C;
a3: when the temperature of the stirrer in a1 is reduced to 40 ℃, sequentially adding an amino acid surfactant, a chelating buffer, microencapsulated vitamin E, an enzyme preparation and soapberry extract into the stirrer, and stirring for 1h at a rotating speed of 1200 r/min;
a4: when the temperature of the stirrer in a2 is reduced to 30 ℃, adding the polymethylsiloxane/hydrolyzed fibroin, stirring for 1.5h at the rotating speed of 1200r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Example 2
The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: amino acid surfactant 45%; alkyl glycoside 30%; 1.5% of foam control agent; 2.2% of soapberry extract; chelating buffer 2%; polymethylsiloxane/hydrolyzed fibroin 4%; 2% of anti-stringing agent; microcapsule vitamin E1%; 0.8% of preservative; enzyme preparation 0.5%; 1.5% of sodium chloride; the balance of deionized water.
The amino acid surfactant is sodium cocoamidopropionate.
The alkyl glycoside has a carbon chain length of C12.
The foam control agent consists of fatty acid salt with carbon chain length of C14 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:2, the fatty acid salt is sodium myristate, and the organic silicon is methyl silicone oil.
The chelating buffer consists of citric acid and sodium citrate in a mass ratio of 1:1.5.
The polymethylsiloxane/hydrolyzed fibroin source manufacturer is Chongqing kang Mei Bio-technology Co., ltd.
The preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
The enzyme preparation consists of amylase and cellulase in a mass ratio of 1:4.
The source manufacturer of the microcapsule vitamin E is Wuhan mountain technology Co.
The anti-cross-linking agent is a vinyl pyrrolidone/vinyl imidazole copolymer.
The preparation method of the vinyl pyrrolidone/vinyl imidazole copolymer comprises the following steps:
s1: sequentially adding 16 parts by weight of vinyl pyrrolidone, 8 parts by weight of vinyl imidazole, 1 part by weight of ethanol with the concentration of 15% and 20 parts by weight of deionized water into a stirrer, introducing nitrogen, stirring at the rotating speed of 220r/min for 1.5h, and heating to 70 ℃ to obtain a reaction solution G1;
s2: adding azodiisobutyronitrile into the reaction solution G1, keeping the temperature at 70 ℃ for 10 hours, then heating to 80 ℃ for continuous reaction for 2 hours, and cooling the reaction solution to room temperature after the reaction is finished to obtain a reaction solution G2;
s3: evaporating the reaction solution G2 to remove impurities, and drying in a vacuum drying oven at 55 ℃ until the weight is constant to obtain the vinyl pyrrolidone/vinyl imidazole copolymer.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight parts of the raw materials;
a2: adding alkyl glycoside, foam control agent, anti-cross dye, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 650r/min; stirring for 15min at 70deg.C;
a3: when the temperature of the stirrer in a1 is reduced to 45 ℃, sequentially adding an amino acid surfactant, a chelating buffer, microencapsulated vitamin E, an enzyme preparation and soapberry extract into the stirrer, increasing the rotating speed to 11000r/min, and stirring for 1h;
a4: when the temperature of the stirrer in a2 is reduced to 35 ℃, adding the polymethylsiloxane/hydrolyzed fibroin, stirring for 1.5h at the rotating speed of 1500r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Example 3
The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: amino acid surfactant 30%; 25% of alkyl glycoside; 1% of foam control agent; soapberry extract 2%; chelating buffer 3%; polymethylsiloxane/hydrolyzed fibroin 4%; 3% of anti-stringing agent; microcapsule vitamin E1%; 1% of preservative; enzyme preparation 0.8%; sodium chloride 1%; the balance of deionized water.
The amino acid surfactant is sodium cocoamidopropionate.
The alkyl glycoside has a carbon chain length of C12.
The foam control agent consists of fatty acid salt with carbon chain length of C14 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:2, the fatty acid salt is sodium myristate, and the organic silicon is methyl silicone oil.
The chelating buffer consists of citric acid and sodium citrate in a mass ratio of 1:1.5.
The polymethylsiloxane/hydrolyzed fibroin source manufacturer is Chongqing kang Mei Bio-technology Co., ltd.
The preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
The enzyme preparation consists of amylase and cellulase in a mass ratio of 1:3.
The source manufacturer of the microcapsule vitamin E is Wuhan mountain technology Co.
The anti-cross-linking agent is a vinyl pyrrolidone/vinyl imidazole copolymer.
The preparation method of the vinyl pyrrolidone/vinyl imidazole copolymer comprises the following steps:
s1: sequentially adding 14 parts by weight of vinyl pyrrolidone, 6 parts by weight of vinyl imidazole, 0.5 part by weight of ethanol with the concentration of 15% and 20 parts by weight of deionized water into a stirrer, introducing nitrogen, stirring at the rotating speed of 220r/min for 1h, and heating to 70 ℃ to obtain a reaction solution G1;
s2: adding azodiisobutyronitrile into the reaction solution G1, keeping the temperature at 70 ℃ for 10 hours, then heating to 80 ℃ for continuous reaction for 2 hours, and cooling the reaction solution to room temperature after the reaction is finished to obtain a reaction solution G2;
s3: evaporating the reaction solution G2 to remove impurities, and drying in a vacuum drying oven at 50 ℃ until the weight is constant to obtain the vinyl pyrrolidone/vinyl imidazole copolymer.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight parts of the raw materials;
a2: adding alkyl glycoside, foam control agent, anti-cross dye, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 650r/min; stirring for 12min at 70deg.C;
a3: when the temperature of the stirrer in a1 is reduced to 40 ℃, sequentially adding an amino acid surfactant, a chelating buffer, microencapsulated vitamin E, an enzyme preparation and soapberry extract into the stirrer, and stirring for 1h at a rotating speed of 1200 r/min;
a4: when the temperature of the stirrer in a2 is reduced to 35 ℃, adding the polymethylsiloxane/hydrolyzed fibroin, stirring for 1.5h at the rotating speed of 1200r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Comparative example 1
The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: amino acid surfactant 45%; alkyl glycoside 30%; 1.5% of foam control agent; 2.2% of soapberry extract; chelating buffer 2%; polymethylsiloxane/hydrolyzed fibroin 4%; vinyl pyrrolidone 2%; microcapsule vitamin E1%; 0.8% of preservative; enzyme preparation 0.5%; 1.5% of sodium chloride; the balance of deionized water.
The amino acid surfactant is sodium cocoamidopropionate.
The alkyl glycoside has a carbon chain length of C12.
The foam control agent consists of fatty acid salt with carbon chain length of C14 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:2, the fatty acid salt is sodium myristate, and the organic silicon is methyl silicone oil.
The chelating buffer consists of citric acid and sodium citrate in a mass ratio of 1:1.5.
The polymethylsiloxane/hydrolyzed fibroin source manufacturer is Chongqing kang Mei Bio-technology Co., ltd.
The preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
The enzyme preparation consists of amylase and cellulase in a mass ratio of 1:4.
The source manufacturer of the microcapsule vitamin E is Wuhan mountain technology Co.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight parts of the raw materials;
a2: adding alkyl glycoside, foam control agent, vinyl pyrrolidone, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 650r/min; stirring for 15min at 70deg.C;
a3: when the temperature of the stirrer in a1 is reduced to 45 ℃, sequentially adding an amino acid surfactant, a chelating buffer, microencapsulated vitamin E, an enzyme preparation and soapberry extract into the stirrer, increasing the rotating speed to 11000r/min, and stirring for 1h;
a4: when the temperature of the stirrer in a2 is reduced to 35 ℃, adding the polymethylsiloxane/hydrolyzed fibroin, stirring for 1.5h at the rotating speed of 1500r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Comparative example 2
The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: amino acid surfactant 45%; alkyl glycoside 30%; 1.5% of foam control agent; 2.2% of soapberry extract; chelating buffer 2%; polymethylsiloxane/hydrolyzed fibroin 4%; vinyl imidazole 2%; microcapsule vitamin E1%; 0.8% of preservative; enzyme preparation 0.5%; 1.5% of sodium chloride; the balance of deionized water.
The amino acid surfactant is sodium cocoamidopropionate.
The alkyl glycoside has a carbon chain length of C12.
The foam control agent consists of fatty acid salt with carbon chain length of C14 and organic silicon, wherein the mass ratio of the fatty acid salt to the organic silicon is 1:2, the fatty acid salt is sodium myristate, and the organic silicon is methyl silicone oil.
The chelating buffer consists of citric acid and sodium citrate in a mass ratio of 1:1.5.
The polymethylsiloxane/hydrolyzed fibroin source manufacturer is Chongqing kang Mei Bio-technology Co., ltd.
The preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
The enzyme preparation consists of amylase and cellulase in a mass ratio of 1:4.
The source manufacturer of the microcapsule vitamin E is Wuhan mountain technology Co.
A preparation method of a silk laundry detergent with effects of preventing silk fading/color cross and softening comprises the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight parts of the raw materials;
a2: adding alkyl glycoside, foam control agent, vinyl imidazole, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 650r/min; stirring for 15min at 70deg.C;
a3: when the temperature of the stirrer in a1 is reduced to 45 ℃, sequentially adding an amino acid surfactant, a chelating buffer, microencapsulated vitamin E, an enzyme preparation and soapberry extract into the stirrer, increasing the rotating speed to 11000r/min, and stirring for 1h;
a4: when the temperature of the stirrer in a2 is reduced to 35 ℃, adding the polymethylsiloxane/hydrolyzed fibroin, stirring for 1.5h at the rotating speed of 1500r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Comparative example 3
On the basis of example 2, the polymethylsiloxane/hydrolyzed fibroin was replaced with an equal mass of hydrolyzed fibroin.
Comparative example 4
On the basis of example 2, the polymethylsiloxane/hydrolyzed fibroin was replaced with an equal mass of polymethylsiloxane.
Comparative example 5
On the basis of example 2, the polymethylsiloxane/hydrolyzed fibroin was replaced with an equal mass of microencapsulated vitamin E.
Comparative example 6
On the basis of example 2, the polymethylsiloxane/hydrolyzed fibroin was replaced with soapberry extract of equal quality.
Performance test:
1. fade/cross color Performance test
Test materials: silk laundry detergent with silk fading/color cross prevention and softening effects obtained in examples 1-3 and comparative examples 1-2, colored silk (6 x 6 cm), white silk (6 x 6 cm).
The test method comprises the following steps: 1 g of silk liquid laundry detergent with the effects of preventing silk from fading/color cross and softening, which are obtained in examples 1-3 and comparative examples 1-2, are respectively weighed, 1L of tap water is added into a vertical washing machine to be uniformly dissolved, 2 pieces of colored silk are added into each washing machine, 2 pieces of white silk are added into each washing machine, and the washing is carried out for 30 minutes at 25 ℃. The colored silk is formed by dyeing white silk with two dyes, namely commercial direct blue and red. And measuring the color difference value of the colored silk and the white silk before washing, rinsing the colored silk and the white silk twice after washing, naturally airing the colored silk and the white silk after washing, and testing the color difference value of the colored silk and the white silk. The smaller the white real silk color difference value is, the better the color cross prevention performance is, the smaller the colored real silk difference value is, and the better the color fixation effect is.
Test results: the test results are shown in Table 1:
table 1 test of test results of anti-fade/cross-color properties of laundry liquids
| Group of | White real silk color difference value | Blue silk color difference value | Red silk difference |
| Example 1 | 0.98 | 0.54 | 0.63 |
| Example 2 | 1.08 | 0.59 | 0.57 |
| Example 3 | 0.95 | 0.48 | 0.52 |
| Comparative example 1 | 2.31 | 0.99 | 1.09 |
| Comparative example 2 | 2.49 | 0.91 | 1.13 |
As can be seen from Table 1, the laundry detergent of examples 1 to 3 of the present invention has a smaller difference in colored silk than the laundry detergent of comparative examples 1 to 2, and has good anti-fading and color-fixing effects; the overall effect of the color difference values of the white silk in the examples 1-3 is better than that of the laundry detergent in the comparative examples 1-2, and the color cross prevention effect is also good.
2. Compliance testing
Test materials: 7 parts of commercial silk with the same pattern, and silk liquid laundry detergent with the effects of preventing silk from fading/color cross and softening, which are obtained in examples 1-3 and comparative examples 3-6.
The test method comprises the following steps: 7 parts of commercial real silk are selected, 1 part of real silk laundry detergent with the effects of preventing real silk from fading/cross color and softening, which are obtained in examples 1-3 and comparative examples 3-6, is respectively weighed, 1 gram of each part is added into a vertical washing machine, 1 liter of tap water is added for uniform dissolution, washing is carried out for 30min at 25 ℃, and the hand feeling of the comparative real silk is dried after the washing is finished respectively.
And (3) scoring and evaluating 1-10 parts of real silk by 30 persons, taking an average value and summarizing the results.
Test results: as shown in table 2.
TABLE 2 results of compliance test
| Group of | Average value of softness and smoothness of silk |
| Example 1 | 9.7 |
| Example 2 | 9.6 |
| Example 3 | 9.8 |
| Comparative example 3 | 9.0 |
| Comparative example 4 | 8.9 |
| Comparative example 5 | 8.3 |
| Comparative example 6 | 8.4 |
From the data in Table 2, it is clear that the laundry detergents prepared in examples 1 to 3 and comparative examples 3 to 6 have good softening effect.
The present invention is not limited to the above embodiments, but is capable of modification and variation in detail, and other modifications and variations can be made by those skilled in the art without departing from the scope of the present invention.
Claims (10)
1. The real silk laundry detergent with the effects of preventing real silk fading/color cross and softening is characterized by comprising the following raw materials in percentage by weight: 25% -45% of amino acid surfactant; 10% -30% of alkyl glycoside; 0.5 to 1.5 percent of foam control agent; soapberry extract 0.5-2.2%; 2% -3% of chelating buffer; 3% -4% of polymethyl siloxane/hydrolyzed fibroin; 1% -3% of anti-stringing agent; microcapsule vitamin E0.8-1.2%; 0.2 to 1.4 percent of preservative; enzyme preparation 0.2% -1%; sodium chloride 0.2-1.5%; the balance of deionized water.
2. The silk laundry detergent with silk fading/color cross-over prevention and softening effects according to claim 1, wherein the amino acid surfactant is any one of sodium cocoyl amino propionate, sodium cocoyl collagen amino acid, sodium cocoyl sarcosinate, sodium cocoyl glutamate and sodium cocoyl glycinate.
3. The silk laundry detergent of claim 1, wherein the alkyl glycoside has a carbon chain length of C8 to C14.
4. The real silk laundry detergent with effects of preventing real silk fading/color cross and softening according to claim 1, wherein the foam control agent consists of fatty acid salt with carbon chain length of C12-C18 and organic silicon, and the mass ratio of the fatty acid salt to the organic silicon is 1:1.2-1:2.
5. The real silk laundry detergent with effects of preventing real silk fading/cross color and softening according to claim 1, wherein the chelating buffer consists of citric acid and sodium citrate in a mass ratio of 1.5:1.7-1:1.5.
6. The silk laundry detergent with silk fading/cross-color prevention and softening effects according to claim 1, wherein the preservative consists of potassium sorbate and octanoyl hydroxamic acid in a mass ratio of 1:1.
7. The silk laundry detergent with silk fading/cross-color prevention and softening effects according to claim 1, wherein the enzyme preparation consists of amylase and cellulase in a mass ratio of 1:3-1:5.
8. The silk laundry detergent of claim 1, wherein the anti-cross dye is a vinyl pyrrolidone/vinyl imidazole copolymer.
9. The silk laundry detergent with silk fading/cross-color prevention and softening effects according to claim 8, wherein the preparation method of the vinyl pyrrolidone/vinyl imidazole copolymer is as follows:
s1: sequentially adding 10-16 parts by weight of vinyl pyrrolidone, 5-8 parts by weight of vinyl imidazole, 0.2-1 part by weight of ethanol with the concentration of 10% -15% and 15-20 parts by weight of deionized water into a stirrer, introducing nitrogen, stirring at the rotating speed of 200-220 r/min for 1-1.5 hours, and heating to 70 ℃ to obtain a reaction solution G1;
s2: adding azodiisobutyronitrile into the reaction solution G1, keeping the temperature at 70 ℃ for 10-12 hours, then heating to 75-80 ℃ for continuous reaction for 2-4 hours, and cooling the reaction solution to room temperature after the reaction is finished to obtain a reaction solution G2;
s3: evaporating the reaction solution G2 to remove impurities, and drying in a vacuum drying oven at 45-55 ℃ until the weight is constant to obtain the vinyl pyrrolidone/vinyl imidazole copolymer.
10. A method for preparing a silk laundry detergent with silk fade/cross-color prevention and softening effects according to any one of claims 1 to 9, comprising the following steps:
a1: weighing raw materials according to the raw materials of the real silk laundry detergent and the weight percentage of each raw material;
a2: adding alkyl glycoside, foam control agent, anti-cross dye, preservative, sodium chloride and deionized water into a stirrer, wherein the rotating speed is 500-850 r/min; stirring for 10-15 min at 60-70 ℃;
a3: when the temperature of the stirrer in a1 is reduced to 35-45 ℃, sequentially adding an amino acid surfactant, a chelating buffer, a microcapsule vitamin E, an enzyme preparation and a soapberry extract into the stirrer, increasing the rotating speed to 1100-1500 r/min, and stirring for 0.5-1 h;
a4: when the temperature of the stirrer in a2 is reduced to 25-35 ℃, adding polymethylsiloxane/hydrolyzed fibroin, stirring for 1-1.5 h at the rotating speed of 1100-1500 r/min to obtain a semi-finished product;
a5: and (3) sampling and detecting the semi-finished product, filtering, aging, sampling and detecting the finished product, and filling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311120500.4A CN117143676A (en) | 2023-09-01 | 2023-09-01 | Silk laundry detergent with effects of preventing silk fading/color cross and softening |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311120500.4A CN117143676A (en) | 2023-09-01 | 2023-09-01 | Silk laundry detergent with effects of preventing silk fading/color cross and softening |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117143676A true CN117143676A (en) | 2023-12-01 |
Family
ID=88900262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311120500.4A Pending CN117143676A (en) | 2023-09-01 | 2023-09-01 | Silk laundry detergent with effects of preventing silk fading/color cross and softening |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117143676A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5243028A (en) * | 1990-06-27 | 1993-09-07 | Siltech Corporation | Silicone protein polymers |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| JP2001348484A (en) * | 2000-06-07 | 2001-12-18 | Marusho:Kk | Fiber processing composition and fiber processing method |
| WO2008112200A1 (en) * | 2007-03-13 | 2008-09-18 | Carson Product Development, Inc. | Cationic protein and silicone polymers |
| CN102965222A (en) * | 2012-12-04 | 2013-03-13 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN108084441A (en) * | 2017-12-27 | 2018-05-29 | 上海隽潮生物科技有限公司 | A kind of siloxanes-hydrolysis oat oligopeptides copolymer and preparation method and application |
| CN109957470A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | A kind of natural amino acid surfactant concentrated type infant liquid laundry detergent and preparation method thereof |
| CN111944622A (en) * | 2020-08-25 | 2020-11-17 | 武汉和康宜生物环保有限公司 | Concentrated laundry detergent and preparation method thereof |
| CN115216371A (en) * | 2022-05-20 | 2022-10-21 | 广州摩亚方舟贸易有限公司 | Multifunctional laundry detergent and preparation method thereof |
-
2023
- 2023-09-01 CN CN202311120500.4A patent/CN117143676A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5243028A (en) * | 1990-06-27 | 1993-09-07 | Siltech Corporation | Silicone protein polymers |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| JP2001348484A (en) * | 2000-06-07 | 2001-12-18 | Marusho:Kk | Fiber processing composition and fiber processing method |
| WO2008112200A1 (en) * | 2007-03-13 | 2008-09-18 | Carson Product Development, Inc. | Cationic protein and silicone polymers |
| CN102965222A (en) * | 2012-12-04 | 2013-03-13 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN109957470A (en) * | 2017-12-26 | 2019-07-02 | 北京绿伞化学股份有限公司 | A kind of natural amino acid surfactant concentrated type infant liquid laundry detergent and preparation method thereof |
| CN108084441A (en) * | 2017-12-27 | 2018-05-29 | 上海隽潮生物科技有限公司 | A kind of siloxanes-hydrolysis oat oligopeptides copolymer and preparation method and application |
| CN111944622A (en) * | 2020-08-25 | 2020-11-17 | 武汉和康宜生物环保有限公司 | Concentrated laundry detergent and preparation method thereof |
| CN115216371A (en) * | 2022-05-20 | 2022-10-21 | 广州摩亚方舟贸易有限公司 | Multifunctional laundry detergent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张森林等: "乙烯基吡咯烷酮/乙烯基咪唑聚合物的制备及其防沾染性", 日用化学工业, 6 July 2023 (2023-07-06), pages 658 - 664 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69631610T2 (en) | Process for simultaneous desizing and stone washing of colored denim | |
| DE69632910T2 (en) | CELLULASES CONTAINING DETERGENT | |
| CN103451972B (en) | Low-temperature dyeing auxiliary and application thereof | |
| CN101215790B (en) | Dyeing and finishing method for cotton/milk protein blended spinning Raschel fabric | |
| CN103233377B (en) | Jeans prevent the preparation method returning staining agent | |
| JP3128136B2 (en) | Method for forming a stonewashed appearance of wet-processed fabric | |
| CN102392374A (en) | Anti-back-staining agent used in jeans enzyme washing | |
| CN110512444A (en) | A kind of dyeing for cotton | |
| CN109355952A (en) | A kind of dyeing of cotton | |
| CN106245371A (en) | A kind of chitin sodium chloride acid stain levelling agent | |
| JP2001518572A (en) | Treatment of cellulose fabric with cellulase | |
| CN110863373B (en) | Active digital printing thickener composition and preparation method thereof | |
| CN110230197B (en) | Method for low-salt dyeing modification of protein fiber reactive dye | |
| DE69737964T2 (en) | Improved cellulase compound for the treatment of cellulosic textiles | |
| CN105714584A (en) | Dyeing technology of polyester-viscose modal fabric | |
| CN113136731A (en) | Cotton fabric printing and dyeing process | |
| CN117143676A (en) | Silk laundry detergent with effects of preventing silk fading/color cross and softening | |
| CN108396576A (en) | A kind of processing method improving dacron print penetration | |
| CN112575587B (en) | Dyeing and finishing process of cotton fabric | |
| CN112048400B (en) | Acidic cellulase complex and preparation method thereof | |
| CN104894848A (en) | Rabbit hair fiber processing method | |
| KR101591041B1 (en) | Dyeing method of denim by cpb | |
| CN101139802A (en) | Low-ratio wool (less than 20 percent) fibre mixed fabrics homochromy dyeing and finishing technique and application | |
| CN104862978B (en) | The degumming of silk-cotton interwoven silk and whitening process | |
| CN114016311B (en) | Dyeing process of cotton knitted fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |