CN117089115A - Environment-friendly durable rubber comprehensive accelerator and rubber composition composed of same - Google Patents
Environment-friendly durable rubber comprehensive accelerator and rubber composition composed of same Download PDFInfo
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- CN117089115A CN117089115A CN202311107518.0A CN202311107518A CN117089115A CN 117089115 A CN117089115 A CN 117089115A CN 202311107518 A CN202311107518 A CN 202311107518A CN 117089115 A CN117089115 A CN 117089115A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 79
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 30
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 28
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 28
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims abstract description 14
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000013922 glutamic acid Nutrition 0.000 claims abstract description 14
- 239000004220 glutamic acid Substances 0.000 claims abstract description 14
- UOJYYXATTMQQNA-UHFFFAOYSA-N Proxan Chemical compound CC(C)OC(S)=S UOJYYXATTMQQNA-UHFFFAOYSA-N 0.000 claims abstract description 13
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 13
- 239000011787 zinc oxide Substances 0.000 claims description 12
- 229920002943 EPDM rubber Polymers 0.000 claims description 11
- 239000005662 Paraffin oil Substances 0.000 claims description 11
- 235000021355 Stearic acid Nutrition 0.000 claims description 11
- 239000006229 carbon black Substances 0.000 claims description 11
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 11
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 11
- 239000008117 stearic acid Substances 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims 3
- 238000004073 vulcanization Methods 0.000 abstract description 21
- 230000006835 compression Effects 0.000 abstract description 7
- 238000007906 compression Methods 0.000 abstract description 7
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 abstract description 7
- 230000000694 effects Effects 0.000 description 7
- 230000032683 aging Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 230000036541 health Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 150000004005 nitrosamines Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000012936 vulcanization activator Substances 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- -1 lanthanum isopropylxanthate Chemical compound 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- CMAUJSNXENPPOF-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-cyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)SC1=NC2=CC=CC=C2S1 CMAUJSNXENPPOF-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 2
- CBWONQBNYZSEKY-UHFFFAOYSA-N 8-propan-2-yl-3,7-dihydropurine-2,6-dione Chemical compound C(C)(C)C1=NC=2NC(NC(C=2N1)=O)=O CBWONQBNYZSEKY-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
Abstract
The invention relates to an environment-friendly durable rubber comprehensive accelerator and a rubber composition formed by the same. The environment-friendly durable rubber comprehensive accelerator consists of the following components in percentage by mass: 30-50% of isopropyl xanthic acid lanthanum, 30-40% of glutamic acid dithiocarbamic acid lanthanum and 20-30% of disulfide-N, N' -dicyclohexyl. The invention has the characteristics of short scorching time, high vulcanization speed, no frosting, no nitrosamine generation, low compression set and the like.
Description
Technical Field
The invention relates to a rubber composition, in particular to an environment-friendly durable rubber comprehensive accelerator and a rubber composition composed of the same.
Background
The frosting phenomenon can be generated in the use or storage process of the rubber product, the yellowing after frosting is obvious, the quality of the rubber product, especially the appearance of the rubber tube, the sealing strip and other products is seriously influenced, and the treatment measure for the phenomenon is to wipe the frosting-proof medicine during the post-treatment at present, so that the rubber product is extremely easy to change color and turn yellow, the repeated repair is needed, and the cost is increased and the profit is reduced. In addition, in the vulcanization molding process of rubber, a vulcanization activator is generally added for improving the vulcanization speed, and the vulcanization activator has the effects of activating a vulcanization system, improving the crosslinking density of vulcanized rubber, improving the ageing resistance of the vulcanized rubber and the like. In the high-temperature vulcanization process of rubber, part of vulcanization accelerator and sulfur carrier can generate secondary amine in the vulcanization process, and stable nitrosamine can be generated with nitrogen oxides in air or additives under certain conditions. Nitrosamines are difficult to remove by washing and soaking. Nitrosamines are strong carcinogens and are released during use, which severely threatens human health. Increasingly, people pay attention to physical health and environmental protection, and more countries and regions strictly limit a rubber product vulcanization system: no nitrosamines are produced during vulcanization. For example, ASTM F1313 of the American society of materials and national Standard SN/T4694-2016. Therefore, the development of a compound vulcanization activator formula system which does not generate nitrosamine, does not spray frost and has high scorching safety meets the market application and use requirements, and is a necessary way for promoting the green and high-quality development of the rubber industry.
Patent application CN201610240020.5 discloses an environment-friendly anti-frosting ethylene propylene rubber compound, wherein an accelerator is prepared by mixing 1 to 1.5 parts by weight, 0.5 to 1 part by weight, 1 to 1.5 parts by weight and 1 to 1.5 parts by weight of accelerator TBzTD-70, accelerator CZ, accelerator ZBEC and accelerator BZ; the vulcanizing agent is DTDC-80, and the dosage is 0.3-0.8 part. In the technical scheme, the accelerators are more in variety and complex in composition; the dosage is more than 3.3 parts; the sulfur vulcanization speed is slower, and the vulcanization time is longer, reaching 15 minutes.
Application number CN201610041853.9, a rubber comprehensive promoter and a preparation method thereof, mainly comprises the following raw materials in parts by weight: 40-75 parts of high-activity zinc oxide, 2-9 parts of post-effect sulfenamide accelerators, 7-15 parts of thiazole accelerators, 10-21 parts of ultra-high speed accelerators and 8-19 parts of high polymer carriers. The sulfenamide accelerator adopted in the technical scheme of the invention, namely N, N-dicyclohexyl-2-benzothiazole sulfenamide, is also called accelerator DZ, and can generate nitrosamine; and the ageing performance is poor, and the hot air ageing is carried out for 72 hours at the temperature of 100 ℃; the change rate of the elongation at break of the sample after aging in the technical scheme is-43%, and the change rate of the elongation at break is large.
Disclosure of Invention
In order to solve the problems, the invention provides the environment-friendly durable type rubber comprehensive accelerator which has the advantages of high vulcanization speed, no frosting, no nitrosamine generation, good ageing resistance, high efficiency of vulcanization promotion, short scorching time, high vulcanization speed, no frosting, no nitrosamine generation, low compression set and the like, and effectively promotes the vulcanization of rubber, shortens the vulcanization time, improves the physical and mechanical properties of vulcanized rubber, ensures that the rubber has better wear resistance and tear resistance, and prolongs the service life.
The technical scheme adopted by the invention is as follows: the technical scheme adopted by the invention is as follows: the environment-friendly durable rubber comprehensive accelerator consists of the following components (the total amount of the comprehensive accelerator is 100 percent, and the contained components are expressed by mass percent): 30-50% of isopropyl xanthic acid lanthanum, 30-40% of glutamic acid dithiocarbamic acid lanthanum, and 20-30% of disulfide-N, N' -biscaprolactam;
preferably, 37-43% of isopropyl xanthic acid lanthanum, 30-40% of glutamic acid dithiocarbamic acid lanthanum, 20-30% of disulfide-N, N' -dicyclohexyl;
preferably, 37-43% of isopropyl xanthic acid lanthanum, 33-37% of glutamic acid dithiocarbamic acid lanthanum, 20-30% of disulfide-N, N' -dicyclohexyl;
preferably, 37-43% of isopropyl xanthic acid lanthanum, 33-37% of glutamic acid dithiocarbamic acid lanthanum, 23-27% of disulfide-N, N' -dicyclohexyl;
the invention also provides a technical scheme as follows: the rubber composition containing the environment-friendly durable rubber comprehensive promoter comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 2-3 parts of environment-friendly durable rubber comprehensive accelerator, 3-7 parts of zinc oxide, 0.5-3 parts of stearic acid, 0.5-2.5 parts of sulfur, 50-120 parts of carbon black and 20-60 parts of paraffin oil;
preferably, 100 parts of ethylene propylene diene monomer rubber, 2.5-3 parts of environment-friendly durable rubber comprehensive accelerator, 4-6 parts of zinc oxide, 1-2 parts of stearic acid, 0.5-2 parts of sulfur, 90-110 parts of carbon black and 45-55 parts of paraffin oil;
preferably, 100 parts of ethylene propylene diene monomer rubber, 2.5-3 parts of environment-friendly durable rubber comprehensive accelerator, 4.5-5.5 parts of zinc oxide, 1-2 parts of stearic acid, 0.75-1.75 parts of sulfur, 95-105 parts of carbon black and 45-55 parts of paraffin oil;
the invention has at least the following beneficial effects:
(1) According to the technical scheme, the lanthanum isopropylxanthate and the lanthanum glutamate dithiocarbamic acid are all rare earth-containing accelerators, so that the activity is high and the vulcanization speed is high; the disulfide-N, N' -dicyclohexyl participates in vulcanization, so that the cross-linking bond formed by the vulcanization system is mainly a monosulfur bond, the heat resistance and the compression deformation resistance are obviously improved, and the vulcanization system is firm and durable. Experiments prove that in the technical scheme of the invention, when vulcanizing at 160 ℃, t10 is less than 50 seconds, and t90 is less than 400 seconds; compression set at 120 ℃ for 24h is less than 40%, and compression set at 100 ℃ for 24h is less than 25%; after the hot air aging at 120 ℃ for 3 days, the tensile strength and the breaking permanent deformation change rate are all less than 30 percent.
(2) The invention fully plays the synergistic reinforcement effect of various accelerators, and the single dosage of the three accelerators is less, thereby greatly reducing the risk of frosting.
(3) The accelerator adopted by the invention does not generate nitrosamine, is environment-friendly and harmless to human health.
(4) The invention has simple formula system, can realize good vulcanization acceleration effect under the condition of less components, and saves raw materials.
(5) The use is simple and convenient. The composition can be added in the mixing process, can be prepared into a mixture in advance, or can be formed into granules together with other polymers and inorganic matters for use, and is convenient to use and environment-friendly.
In order to further illustrate the beneficial effects, a comparison experiment is carried out between the technical scheme of the invention and the prior art, and the result is as follows:
table 1 shows the technical effects of the prior art using accelerators.
TABLE 1
Table 2 shows the technical effects of the embodiments of the present invention compared with the prior art.
TABLE 2
Wherein, the change rate of tensile strength and the elongation at break are measured according to GB/T528; the vulcanization curve is determined according to GB/T16584; compression set was measured according to GB/T7759; the hot air aging properties were determined according to GB/T3512.
As can be seen from the comparison, compared with the conventional nitrosamine-free accelerator in the prior art, the invention has the advantages of smaller performance change after being subjected to the sulfur treatment, heat resistance and excellent compression deformation performance in the proportioning range.
Detailed Description
The invention will be described in further detail below, while exemplary embodiments of the invention are set forth below, it should be understood that the invention may be embodied in various forms and should not be limited to the specific embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.
Example 1, an environmentally friendly durable rubber integrated accelerator, consists of the following components (the total amount of the integrated accelerator is 100%, and the contained components are expressed by mass percent): 30% of isopropyl xanthic acid lanthanum, 40% of glutamic acid dithiocarbamic acid lanthanum, and 30% of N, N' -dicyclohexyl.
Example 2, an environmentally friendly durable rubber integrated accelerator, consists of the following components (the total amount of the integrated accelerator is 100%, and the contained components are expressed by mass percent): 50% of isopropyl xanthic acid lanthanum, 30% of glutamic acid dithiocarbamic acid lanthanum, and 20% of N, N' -dicyclohexyl disulfide.
Example 3, an environmentally friendly durable rubber integrated accelerator, consists of the following components (the total amount of the integrated accelerator is 100%, and the contained components are expressed by mass percent): 40% of isopropyl xanthine acid lanthanum, 35% of glutamic acid dithiocarbamic acid lanthanum and 25% of disulfide-N, N' -dicyclohexyl.
Example 4, an environmentally friendly durable rubber integrated accelerator, consists of the following components (the total amount of the integrated accelerator is 100%, and the contained components are expressed by mass percent): 37% of isopropyl xanthic acid lanthanum, 33% of glutamic acid dithiocarbamic acid lanthanum, and 30% of N, N' -dicyclohexyl disulfide.
Example 5 an environmentally friendly durable rubber integrated accelerator, consisting of the following components (total amount of integrated accelerator is 100%, each component contained in the accelerator is expressed by mass percent): 40% of isopropyl xanthic acid lanthanum, 32% of glutamic acid dithiocarbamic acid lanthanum, and 28% of N, N' -dicyclohexyl disulfide.
Example 6, an environmentally friendly durable rubber integrated accelerator, consists of the following components (the total amount of the integrated accelerator is 100%, and the contained components are expressed by mass percent): 43% of isopropyl xanthic acid lanthanum, 34% of glutamic acid dithiocarbamic acid lanthanum, 23% of disulfide-N, N' -dicyclohexyl.
Example 7 a rubber composition containing the environmentally friendly durable rubber integrated accelerator comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 2 parts of environment-friendly durable rubber comprehensive accelerator, 5 parts of zinc oxide, 1 part of stearic acid, 0.5 part of sulfur, 50 parts of carbon black and 20 parts of paraffin oil.
Example 8A rubber composition containing the environmentally friendly durable rubber integrated accelerator comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 3 parts of environment-friendly durable rubber comprehensive accelerator, 7 parts of zinc oxide, 3 parts of stearic acid, 2.5 parts of sulfur, 100 parts of carbon black and 60 parts of paraffin oil.
Example 9A rubber composition containing the environmentally friendly durable rubber integrated accelerator comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 2.5 parts of environment-friendly durable rubber comprehensive accelerator, 6 parts of zinc oxide, 2 parts of stearic acid, 1.5 parts of sulfur, 80 parts of carbon black and 40 parts of paraffin oil.
Example 10 a rubber composition containing the environmentally friendly durable rubber integrated accelerator comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 3 parts of environment-friendly durable rubber comprehensive accelerator, 5 parts of zinc oxide, 1 part of stearic acid, 0.8 part of sulfur, 100 parts of carbon black and 50 parts of paraffin oil.
Example 11 a rubber composition containing the environmentally friendly durable rubber integrated accelerator comprises the following components (the raw rubber content in the rubber composition is 100 parts by mass, and the other components are expressed in parts by mass relative to the raw rubber): 100 parts of ethylene propylene diene monomer rubber, 3 parts of environment-friendly durable rubber comprehensive accelerator, 5 parts of zinc oxide, 1 part of stearic acid, 1.5 parts of sulfur, 100 parts of carbon black and 50 parts of paraffin oil.
The foregoing description is only a preferred embodiment of the present invention, and the present invention is not limited thereto, but it is to be understood that modifications and equivalents of some of the technical features described in the foregoing embodiments may be made by those skilled in the art, although the present invention has been described in detail with reference to the foregoing embodiments. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. An environment-friendly durable rubber comprehensive accelerator is characterized in that: the composite material consists of the following components in percentage by mass: 30-50% of isopropyl xanthic acid lanthanum, 30-40% of glutamic acid dithiocarbamic acid lanthanum and 20-30% of disulfide-N, N' -dicyclohexyl.
2. The environmentally friendly durable rubber complex accelerator according to claim 1, wherein: the composite material consists of the following components in percentage by mass: 37-43% of isopropyl xanthic acid lanthanum, 30-40% of glutamic acid dithiocarbamic acid lanthanum and 20-30% of disulfide-N, N' -dicyclohexyl.
3. The environmentally friendly durable rubber complex accelerator according to claim 1, wherein: the composite material consists of the following components in percentage by mass: 37-43% of isopropyl xanthic acid lanthanum, 33-37% of glutamic acid dithiocarbamic acid lanthanum, and 20-30% of disulfide-N, N' -dicyclohexyl.
4. A rubber composition comprising the environmentally friendly durable rubber complex accelerator according to any one of claims 1 to 3, characterized in that: comprises the following components in parts by weight: 100 parts of ethylene propylene diene monomer rubber, 2-3 parts of environment-friendly durable rubber comprehensive accelerator, 3-7 parts of zinc oxide, 0.5-3 parts of stearic acid, 0.5-2.5 parts of sulfur, 50-120 parts of carbon black and 20-60 parts of paraffin oil.
5. The rubber composition containing an environmentally friendly durable rubber complex accelerator according to claim 4, wherein: comprises the following components in parts by weight: 100 parts of ethylene propylene diene monomer rubber, 2.5-3 parts of environment-friendly durable rubber comprehensive accelerator, 4-6 parts of zinc oxide, 1-2 parts of stearic acid, 0.5-2 parts of sulfur, 90-110 parts of carbon black and 45-55 parts of paraffin oil.
6. The rubber composition containing an environmentally friendly durable rubber complex accelerator according to claim 4, wherein: comprises the following components in parts by weight: 100 parts of ethylene propylene diene monomer rubber, 2.5-3 parts of environment-friendly durable rubber comprehensive accelerator, 4.5-5.5 parts of zinc oxide, 1-2 parts of stearic acid, 0.75-1.75 parts of sulfur, 95-105 parts of carbon black and 45-55 parts of paraffin oil.
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| CN202311107518.0A CN117089115A (en) | 2023-08-30 | 2023-08-30 | Environment-friendly durable rubber comprehensive accelerator and rubber composition composed of same |
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| CN202311107518.0A CN117089115A (en) | 2023-08-30 | 2023-08-30 | Environment-friendly durable rubber comprehensive accelerator and rubber composition composed of same |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication |