CN117054293A - Method for measuring movement path of soil colloid in aeration zone - Google Patents
Method for measuring movement path of soil colloid in aeration zone Download PDFInfo
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- CN117054293A CN117054293A CN202311318227.6A CN202311318227A CN117054293A CN 117054293 A CN117054293 A CN 117054293A CN 202311318227 A CN202311318227 A CN 202311318227A CN 117054293 A CN117054293 A CN 117054293A
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- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000002681 soil colloid Substances 0.000 title claims abstract description 10
- 238000005273 aeration Methods 0.000 title claims description 5
- 239000000084 colloidal system Substances 0.000 claims abstract description 71
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000002689 soil Substances 0.000 claims abstract description 41
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 31
- 239000000700 radioactive tracer Substances 0.000 claims abstract description 23
- 238000012856 packing Methods 0.000 claims abstract description 11
- 239000000276 potassium ferrocyanide Substances 0.000 claims abstract description 9
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005259 measurement Methods 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- 239000011259 mixed solution Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 229960000583 acetic acid Drugs 0.000 claims description 7
- 238000009412 basement excavation Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000012362 glacial acetic acid Substances 0.000 claims description 7
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 238000000691 measurement method Methods 0.000 claims description 5
- 239000001307 helium Substances 0.000 claims description 4
- 229910052734 helium Inorganic materials 0.000 claims description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- 229910052754 neon Inorganic materials 0.000 claims description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 abstract description 5
- 230000001678 irradiating effect Effects 0.000 abstract description 3
- 230000007246 mechanism Effects 0.000 abstract description 2
- 238000013508 migration Methods 0.000 description 11
- 230000005012 migration Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 229910010413 TiO 2 Inorganic materials 0.000 description 7
- 230000027756 respiratory electron transport chain Effects 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000003895 groundwater pollution Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- OCVXZQOKBHXGRU-UHFFFAOYSA-N iodine(1+) Chemical compound [I+] OCVXZQOKBHXGRU-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000007793 ph indicator Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
- G01N2013/003—Diffusion; diffusivity between liquids
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
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- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
The invention provides a method for measuring a movement path of a soil colloid in a gas-covered zone, which comprises the following steps: uniformly injecting a tracer solution containing titanium dioxide colloid into a soil area of the air-packing belt to be detected; after the tracer solution finishes flowing, excavating in the area to form a plurality of longitudinal sections of the soil with the air covering zone, spraying an identification solution containing potassium ferrocyanide on each section formed by excavating, irradiating the section by ultraviolet light, and collecting images of the section after the color of the section changes; and superposing the acquired images of all the sections according to the actual section positions to obtain the motion path. The invention solves the difficult problem of difficult direct measurement in the soil of the gas-covered zone, and has the advantages of clear mechanism, simple operation, high recognition rate and the like.
Description
Technical Field
The invention belongs to the field of a method for measuring soil in a gas-covered zone, and particularly relates to a method for measuring a colloid movement path of soil in a gas-covered zone.
Background
The aeration zone soil is the basis for maintaining agricultural yield and improving the ecological system, and is also the necessary passage for many pollutants to enter the groundwater system. Because the colloid has small particle size, large specific surface area, charge on the surface, unique double-electric-layer structure and rich surface functionsThe organic fertilizer has the characteristics of energy groups and the like, and heavy metals, organic pesticides, organic pollutants, phosphorus, bacteria, microorganisms and the like are adsorbed on the colloid and move along with the colloid, so that the movement of the movable colloid in the soil can accelerate the movement capability of the pollutants to a great extent. Monitoring data in both laboratory and field conditions indicate that colloid migration occurs mainly in the high flow rate region in the soil pores due to both size exclusion and low diffusivity, and that the migration rate of the colloid in the soil is not lower than that of the solute. Some field test results show that the scale of TP easy to move in soil is more than 10 -6 m (macropores) is less than 10 -9 m (colloidal adsorption) two dimensions, and by less than 10 -9 The TP migration flux formed by the m-pathway is significantly over-dimensioned to be greater than 10 -6 Flux formed by the m-pathway. Therefore, the knowledge of the movement path of the colloid in the air-bag soil has important significance for preventing and controlling the groundwater pollution.
The movement speed of the colloid is influenced by various driving factors such as soil adsorption force, pore hydrodynamic force, LVUO acting force, van der Waals force, brownian acting force, acting force generated by electron transfer and the like, and physical and chemical properties of the soil such as water content of the soil, ionic strength, pH value and redox state influence the migration performance of the colloid to a great extent, so that the migration performance of the colloid is influenced, and in addition, the movement of the colloid is influenced by the fluctuation movement of a liquid-water interface in a pore in the air-covered soil. Although iodine (I) - ) Bromine (Br) - ) Such solutes propose methods of generating substances of different colors from the background of soil based on chemical reactions or identifying a solute migration path by pH indicators by changing the pH value of soil, however, in unsaturated zone soil, the mechanical properties of colloids and solutes, and the movement conditions are completely different, the movement paths and processes of solutes and colloids are significantly different, and direct measurement of the movement paths of colloids in air-bag soil is still very difficult.
Disclosure of Invention
The present invention aims to address at least one of the above-mentioned deficiencies of the prior art. For example, one of the purposes of the present invention is to provide a colloid tracing method for electron transfer, and the other purpose of the present invention is to provide a measuring method for a colloid movement path of a soil in a gas-enclosed zone.
In order to achieve the above object, the present invention provides a method for measuring a movement path of a soil colloid in a gas-enclosed belt, the method comprising the steps of:
uniformly injecting a tracer solution containing titanium dioxide colloid into a soil area of the air-packing belt to be detected;
after the tracer solution finishes flowing, a plurality of longitudinal sections of the soil with the air covering zone are excavated in the area, identification solution containing potassium ferrocyanide is sprayed to the section formed by each excavation, then ultraviolet light is utilized to irradiate, and after the color of the section changes, an image of the section is acquired;
and superposing the acquired images of all the sections according to the actual section positions to obtain the motion path.
Optionally, the preparation method of the titanium dioxide colloid comprises the following steps:
glacial acetic acid and butyl titanate are mixed according to the molar ratio of not more than 1:2, after fully mixing the components in proportion, carrying out chemical reaction to generate a mixed solution containing titanium dioxide colloid;
mixing hydrochloric acid solution and the mixed solution containing titanium dioxide colloid according to the volume ratio of 1: completely mixing 10-20; adjusting the pH value of the mixed solution to 5-6;
the pH value of the mixed solution is adjusted to 25-35 o And C, standing for 12-24 hours at constant temperature to obtain the stable transparent nanoscale titanium dioxide colloid.
Optionally, the tracer solution is diluted by titanium dioxide colloid and water, and the proportion is not less than 1: 100.
Alternatively, the recognition solution includes an aqueous potassium ferrocyanide solution having a concentration of not less than 0.1 mol/L.
Optionally, the ultraviolet light wavelength is 270-365 nm.
Alternatively, a short arc mercury uv lamp loaded in a sealed quartz glass cylinder, which is filled with an inert gas, is used as the light source for the uv light.
Alternatively, the inert gas includes helium or neon.
Optionally, the cross-section color change comprises: a partial region of the profile exhibits a deep blue color.
Alternatively, the depth of the longitudinal section is not less than the amount of tracer in mm by 50mm.
Alternatively, the profile number density is not less than 1/10 cm.
Compared with the prior art, the invention has the beneficial effects that at least one of the following contents is included:
1) The invention solves the problems of a measurement mechanism and a measurement technology for directly measuring the loss of a colloid movement path in the soil of the air-packing belt.
2) The method measures the movement path of the soil colloid in the air-packing belt through electronic transfer tracing, is simple to operate and high in recognition rate, and has wide application range because the blue area is different from most of the ground colors.
Drawings
The foregoing and other objects and/or features of the invention will become more apparent from the following description taken in conjunction with the accompanying drawings in which:
fig. 1 shows a schematic diagram of a method for measuring a movement path of a soil colloid in an air-bag belt in an exemplary embodiment 1 of the present invention.
Fig. 2 shows an acquired image of a soil profile of a gas-filled zone formed by excavation in example 1 of the present invention.
Fig. 3 shows an image acquired of a soil profile of the air belt of example 1 of the present invention after spraying an identification solution and uv irradiation.
Reference numerals illustrate:
1-image acquisition device, 2-superimposed multiple profiles.
Detailed Description
Hereinafter, the measuring method of the movement path of the air-bag soil colloid of the present invention will be described in detail with reference to the accompanying drawings and exemplary embodiments.
Example embodiment 1
The present exemplary embodiment provides a measurement method of a movement path of a soil colloid of a gas-filled belt, the measurement method including the steps of:
s01: and uniformly injecting the tracer solution containing the titanium dioxide colloid into the area of the air-packing belt soil to be detected.
In this embodiment, the titanium dioxide colloid is prepared first, specifically comprising the steps of:
glacial acetic acid and butyl titanate Ti (OC 4 H 9 ) 4 According to the molar ratio of glacial acetic acid to butyl titanate not exceeding 1:2, for example 1:1.1, 1:1.5 or 1:1.9, and the like, carrying out chemical reaction to generate a mixed solution containing titanium dioxide colloid, wherein in order to ensure that butyl titanate is fully reacted, glacial acetic acid needs to be excessive;
mixing hydrochloric acid solution and the mixed solution containing titanium dioxide colloid according to the volume ratio of 1: 10-20, for example 1: 11. 1:16 or 1:19, etc.;
adjusting the pH value of the mixed solution to 5-6 to maintain the stability of the colloid;
the mixed solution with the pH value regulated is kept constant for 25-35 in a temperature control box o C is kept stand for 12 to 24 hours, such as 13 hours, 16 hours or 23 hours, etc., to obtain stable and transparent nano-scale titanium dioxide TiO 2 Sol to prepare the tracer colloid.
In this example, potassium ferrocyanide K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 After the concentration is not less than 0.1mol/L, the mixture is fully dissolved and stored in a brown bottle to prepare the identification solution. For example, the concentration of potassium ferrocyanide may be 0.2mol/L, 0.3mol/L, 0.5mol/L, etc., and a lower concentration of the recognition solution may cause insufficient reaction with the colloid.
In this example, a tracer colloid of nano-sized titanium dioxide TiO 2 After the sol is completely diluted in water according to the dilution ratio of not less than 1:100, for example, nano-scale titanium dioxide TiO 2 The ratio of sol to water may be 1:99, 1:95, or 1:80, etc., to ensure that the concentration of titania is not less than the concentration at a 1:100 ratio; the tracer colloid is diluted and then injected into the soil with the air-packing belt along with water flow, the water consumption is tested in the embodiment, namely the diluted colloid consumption can be 20mm, and the area of an experimental area can be1.0m 2 The earth surface adopts a uniform spraying mode, so that water flows uniformly enter the soil of the air-packing belt, and the movement method of the tracer colloid along with the water flows is mainly influenced by the property of the soil of the air-packing belt. The dosage of the titanium dioxide tracing colloid diluent and the area of the test area can be set according to the soil condition.
S02: after the tracer solution finishes flowing, a plurality of longitudinal sections of the soil with the air covering zone are excavated in the area, after each excavation, identification solution containing potassium ferrocyanide is sprayed to the sections, then the sections are irradiated by ultraviolet light, and after the color of the sections changes, images of the sections are acquired.
In this example, after the fully diluted tracer colloid was sprayed in the test area and flowed with water for 12hr, a working area was excavated on one side of the test area along the colloid movement direction to form a soil profile with a gas-over zone, as shown in fig. 1, which is perpendicular to the surface penetration surface of the test area. Spraying identification solvent onto the section, irradiating with ultraviolet light with wavelength of 270-365 nm, such as 271nm, 280nm, 308nm, 350nm or 367nm, wherein the photochemical effect of titanium dioxide tracer colloid on ultraviolet light is most remarkable in the wavelength range, and the titanium dioxide tracer colloid (nanometer TiO) 2 ) Under the electron transfer and photochemical action, the recognition solution is changed in color and appears dark blue, while the areas without colloid movement are not changed in color. And taking a picture of the section by using image acquisition equipment such as a CCD camera after the deep blue area is not changed any more.
In this embodiment, the electron transfer and optical effect is that the titanium dioxide generates electron transfer under the irradiation of ultraviolet light to generate electron holes; the hole has stronger electron capturing capability, and after encountering water molecules, the water molecules are deprived of electrons to form hydroxyl:
(TiO 2 )e + +H 2 O→TiO 2 +•OH+H +
wherein e + Represents electrons, OH is hydroxy, H + Is hydrogen ion. Hydroxy groups and oxygen atoms, all of which are capable of binding part of Fe 2+ Oxidation to Fe 3+ Precipitation, chemical reaction equationThe method comprises the following steps:
K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 +4•OH+4H + →Fe 4 3+ [Fe 2+ (CN 6 )] 3 +4K +
K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 +O 2 +4H + →Fe 4 3+ [Fe 2+ (CN 6 )] 3 +4K + +4H 2 O
fe in soil of the aeration zone 4 3+ [Fe 2+ (CN 6 )] 3 The precipitation is changed in color, and the dark blue of the presentation position can be identified, so that the identification of the nano-scale tracer colloid movement path is realized.
In the embodiment, since the object of measurement is a soil profile, a short arc mercury ultraviolet lamp loaded in a sealed quartz glass cylinder is used as an ultraviolet light source, and inert gas is injected into the cylinder to improve the irradiation area and uniformity of ultraviolet light; the inert gas may be helium or neon.
S03: and superposing the acquired images of all the sections according to the actual section positions to obtain the moving path.
Fig. 1 shows a schematic diagram of the method for measuring the movement path of the soil colloid in the air-bag type belt of the present invention. Wherein 1 in the figure is an image acquisition device, which may include a camera; 2 in the figure represents a plurality of overlapped sections, and a 3-dimensional colloid motion path can be identified after the overlapped sections are overlapped; arrows in the figure indicate the section excavation direction.
In this embodiment, a plurality of longitudinal sections of the soil in the air-packing zone of the working area, such as the sections shown in fig. 1, are excavated in the direction of the colloid movement in the test area. The number density of the sections is not less than 1/10 cm, for example, the distance between the sections may be 9cm, 7cm, 5cm, or the like, and if the distance between the sections is more than 10cm, the error of the superimposed image path increases. The depth of the section excavation is not less than the dosage x 50 of the diluted tracer colloid, the unit is mm, for example, when the dosage of the diluted tracer colloid can be 20mm, the depth of the longitudinal section is not less than 20mm x 50, namely, the depth is not less than 100mm; so as to cover the maximum movement depth of the colloid and avoid the loss of colloid migration information. The horizontal dimension of the section is not smaller than that of the test area, continuous section excavation is carried out along the flowing direction along the surface penetrating plane perpendicular to the test area, so that the colloid movement path is determined in a superposition mode. And (3) irradiating the area of the trace colloid movement of each soil section with ultraviolet light, identifying colloid paths of the section pictures after the deep blue area is not changed, measuring the area with color change layer by layer, namely the migration area of the trace colloid, and superposing all sections according to the actual section positions of the sampling to obtain the movement paths of the trace colloid.
For a better understanding of the above-described exemplary embodiments of the present invention, they are further described below in conjunction with specific examples.
Example 1
Glacial acetic acid and butyl titanate Ti (OC 4 H 9 ) 4 According to the mole ratio of 1:2, adding hydrochloric acid solution with the volume ratio of 1:20 after fully mixing, adjusting the pH value of the mixed solution to 5-6 by glacial acetic acid after fully mixing, and keeping the pH value constant for 30 in a temperature control box o C for 24 hours to obtain stable and transparent nano-scale titanium dioxide (TiO) 2 ) Sol, i.e. tracer colloid.
368.3g of potassium ferrocyanide K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 Dissolving in 1L water, and storing in brown bottle to obtain identification solvent.
The method comprises the steps of tracing a colloid motion path in a gas-wrapping belt by using a tracing colloid, testing in a Wansheng farmland in the glabella city in 2021 month, wherein the experimental gas-wrapping belt soil is clay with a broken structure, the contents of clay particles, powder particles and sand particles are 42.1%,10.7% and 47.2%, after the earth surface is leveled, selecting a rectangular area of 1.0mx1.0m as an experimental area, fully diluting 400mL of nano-scale titanium dioxide sol in 40L of reclaimed water, uniformly injecting the diluted nano-scale titanium dioxide into the experimental area, and enabling the nano-scale titanium dioxide to enter the gas-wrapping belt soil along with water flow.
And (3) identifying a colloid migration path, excavating a working area on one side of a test area after the flow is completed, and excavating along the colloid movement direction to form a soil profile of the air-packing zone, as shown in figure 2. Spraying identification solvent to the profile, adopting a short arc mercury ultraviolet lamp loaded in a sealed quartz glass cylinder as an ultraviolet light source, injecting helium into the cylinder to improve the irradiation area and uniformity of ultraviolet light, and emitting 280nm ultraviolet light to irradiate the profile. Under the irradiation of ultraviolet light, the titanium dioxide generates electron transfer and generates electron holes. The hole has stronger electron capturing capability, and after encountering water molecules, the water molecules are deprived of electrons to form hydroxyl:
(TiO 2 )e + +H 2 O→TiO 2 +•OH+H +
wherein e + Represents electrons, OH is hydroxy, H + Is hydrogen ion. Hydroxy groups and oxygen atoms, all of which are capable of binding part of Fe 2+ Oxidation to Fe 3+ Precipitation, chemical reaction equation is:
K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 +4•OH+4H + →Fe 4 3+ [Fe 2+ (CN 6 )] 3 +4K +
K 4 Fe 4 2+ [Fe 2+ (CN) 6 ] 3 +O 2 +4H + →Fe 4 3+ [Fe 2+ (CN 6 )] 3 +4K + +4H 2 O
the colloid trace colloid movement area, under the electron transfer and photochemical action of colloid, fe 4 3+ [Fe 2+ (CN 6 )] 3 The precipitate will change in color and appear dark blue. After the dark blue region appears unchanged, the CCD camera NikonD90 may be used to photograph the cross section, and the resulting photograph is shown in FIG. 3, where the upper dark region actually appears dark blue, for example, the circled portion of the figure is a portion of the dark region.
The same method is adopted to excavate the next section and identify the colloid path, and the experimental area is 1m 2 Is developed perpendicular to the surface penetration water plane into the test area, each section being spaced 10cm apart,forming 11 sections by excavating; and measuring the color change area layer by layer, namely tracing the migration area of the colloid, and superposing all sections according to the actual section positions of the sampling to obtain the migration path of the colloid.
Although the present invention has been described above with reference to the exemplary embodiments and the accompanying drawings, it should be apparent to those of ordinary skill in the art that various modifications can be made to the above-described embodiments without departing from the spirit and scope of the claims.
Claims (10)
1. The method for measuring the movement path of the soil colloid in the aeration zone is characterized by comprising the following steps of:
uniformly injecting a tracer solution containing titanium dioxide colloid into a soil area of the air-packing belt to be detected;
after the tracer solution finishes flowing, a plurality of longitudinal sections of the soil with the air covering zone are excavated in the area, an identification solution containing potassium ferrocyanide is sprayed to the section formed by each excavation, then ultraviolet light is used for irradiation, and after the color of the section changes, an image of the section is acquired;
and superposing the acquired images of all the sections according to the actual section positions to obtain the motion path.
2. The method for measuring according to claim 1, wherein the method for preparing the titanium dioxide colloid comprises the steps of:
glacial acetic acid and butyl titanate are mixed according to the molar ratio of not more than 1:2, after fully mixing the components in proportion, carrying out chemical reaction to generate a mixed solution containing titanium dioxide colloid;
mixing hydrochloric acid solution and titanium dioxide colloid-containing mixed solution according to a volume ratio of 1: completely mixing 10-20; adjusting the pH value of the mixed solution to 5-6;
the pH value of the mixed solution is adjusted to 25-35 o And C, standing for 12-24 hours at constant temperature to obtain the stable transparent nanoscale titanium dioxide colloid.
3. The method according to claim 1, wherein the tracer solution is a titanium dioxide colloid diluted with water in a ratio of not less than 1: 100.
4. The measurement method according to claim 1, wherein the identification solution comprises an aqueous potassium ferrocyanide solution having a concentration of not less than 0.1 mol/L.
5. The method according to claim 1, wherein the ultraviolet light has a wavelength of 270-365 nm.
6. The method according to claim 1, characterized in that a short-arc mercury ultraviolet lamp loaded in a sealed quartz glass cylinder, into which an inert gas is injected, is used as the light source of the ultraviolet light.
7. The method of measurement according to claim 6, wherein the inert gas comprises helium or neon.
8. The measurement method of claim 1, wherein the cross-section color change comprises: a partial region of the profile exhibits a deep blue color.
9. The method of measuring according to claim 1, wherein the depth of the longitudinal section is not less than the tracer liquid amount x 50 in mm.
10. The measurement method according to claim 1, wherein the number density of cross sections is not less than 1/10 cm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311318227.6A CN117054293B (en) | 2023-10-12 | 2023-10-12 | Method for measuring movement path of soil colloid in aeration zone |
Applications Claiming Priority (1)
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1341452A (en) * | 1970-10-20 | 1973-12-19 | Nasa | Stabilization of pigments |
| US4309480A (en) * | 1980-02-28 | 1982-01-05 | The Mearl Corporation | Iron blue nacreous pigments |
| EP2288879A1 (en) * | 2008-06-04 | 2011-03-02 | G Patel | A monitoring system based on etching of metals |
| KR20180094578A (en) * | 2017-02-16 | 2018-08-24 | 한국원자력연구원 | Adsorbent of radioactive cesium and removal method of radioactive cesium and organic pollutant |
| CN110208262A (en) * | 2018-12-25 | 2019-09-06 | 武汉大学 | A kind of method of colloid distribution of movement in measurement unsaturated soil |
| CN111547938A (en) * | 2020-05-09 | 2020-08-18 | 四川省生态环境科学研究院 | Electrochemical dephosphorization treatment process for wastewater |
| CN112858268A (en) * | 2020-09-18 | 2021-05-28 | 武汉大学 | Soil water and solute migration university measuring method based on chemical imaging-correction analysis |
-
2023
- 2023-10-12 CN CN202311318227.6A patent/CN117054293B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1341452A (en) * | 1970-10-20 | 1973-12-19 | Nasa | Stabilization of pigments |
| US4309480A (en) * | 1980-02-28 | 1982-01-05 | The Mearl Corporation | Iron blue nacreous pigments |
| EP2288879A1 (en) * | 2008-06-04 | 2011-03-02 | G Patel | A monitoring system based on etching of metals |
| KR20180094578A (en) * | 2017-02-16 | 2018-08-24 | 한국원자력연구원 | Adsorbent of radioactive cesium and removal method of radioactive cesium and organic pollutant |
| CN110208262A (en) * | 2018-12-25 | 2019-09-06 | 武汉大学 | A kind of method of colloid distribution of movement in measurement unsaturated soil |
| CN111547938A (en) * | 2020-05-09 | 2020-08-18 | 四川省生态环境科学研究院 | Electrochemical dephosphorization treatment process for wastewater |
| CN112858268A (en) * | 2020-09-18 | 2021-05-28 | 武汉大学 | Soil water and solute migration university measuring method based on chemical imaging-correction analysis |
Non-Patent Citations (9)
| Title |
|---|
| MAO GB 等: "Efficient charge migration in TiO2@PB nanorod arrays with core-shell structure for photoelectrochemical water splitting", 《CRYSTENGCOMM》, vol. 24, no. 14, pages 2567 - 2574 * |
| YANG HM 等: "Hollow flower-like titanium ferrocyanide structure for the highly efficient removal of radioactive cesium from water", 《CHEMICAL ENGINEERING JOURNAL》, vol. 392, pages 1 - 10 * |
| 姜长印 等: "用亚铁氰化钾钛从高放废液中去除铯的研究", 《核化学与放射化学》, no. 02, pages 6 * |
| 庄雨婷: "碳基复合材料和功能化纳米金属颗粒在重金属吸附和检测中的应用研究", 《中国博士学位论文全文数据库工程科技I辑》, no. 01, pages 016 - 300 * |
| 张晓莉 等: "稳定TiO_2水溶胶的制备及其在棉织物上的紫外线屏蔽整理", 《现代纺织技术》, vol. 11, no. 03, pages 1 - 4 * |
| 曾令玺 等: "二氧化钛胶体对棉纱线性能的影响", 《成都纺织高等专科学校学报》, vol. 32, no. 02, pages 29 - 31 * |
| 曾爱香 等: "溶胶-凝胶法制备纳米TiO_2粉体的研究进展", 《材料导报Ａ：综述篇》, vol. 27, no. 10, pages 23 - 28 * |
| 柳强 等: "复合模板合成介孔二氧化钛分子筛及其脱模", 《中国有色金属学报》, no. 05, pages 807 - 812 * |
| 董素芳: "制备纳米二氧化钛凝胶过程中若干因素对凝胶时间的影响", 《山东理工大学学报(自然科学版)》, vol. 19, no. 05, pages 94 - 97 * |
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