CN1170431A - Silicone compositions - Google Patents

Silicone compositions Download PDF

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Publication number
CN1170431A
CN1170431A CN95196926A CN95196926A CN1170431A CN 1170431 A CN1170431 A CN 1170431A CN 95196926 A CN95196926 A CN 95196926A CN 95196926 A CN95196926 A CN 95196926A CN 1170431 A CN1170431 A CN 1170431A
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oil
acid
composition
acetate
group
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I·A·休斯
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Procter and Gamble Co
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Procter and Gamble Co
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22—Gas releasing
    • A61K2800/222—Effervescent

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Inorganic Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

A bleach composition comprising an inorganic persalt bleaching agent, a lipophile selected from flavorants, perfumes, physiological coolants, antimicrobial agents and mixtures thereof, and an aminoalkylsilicone having an aminoalkylsiloxane content of from about 0.1 % - 2 % on a repeating unit basis. The composition provides improved lipophile and bleach stability.

Description

Polysiloxane composition
Invention field
The present invention relates to contain polysiloxane composition and individual health care product for example, laundry with and various articles for daily use such as the sanitising agent of family expenses, bleaching composition in purposes.Specifically, relate to the lipotropy composition that contains polysiloxane, they are based on flavouring agent, daily use chemicals spices, freshener (coolant) or biocide as lipophile, to on by the surface of its processing (for example tooth, artificial tooth, skin, hair, clothing, tableware, worktable surface etc.), described compositions table reveals better residual, effect and/or effectiveness.In addition, the present invention relates to contain the bleaching composition of polysiloxane, said composition also comprises for example daily use chemicals spices, flavouring agent etc. to bleaching responsive composition, and shows higher stability.
Background of invention
The lipotropy composition, for example flavouring agent, daily use chemicals spices, freshener and antiseptic composition are directly used or are used in the various daily necessities widely, comprising makeup, the oral cavity is used and the artificial tooth composition, bleaching, dishwashing detergent, hard-surface cleaning product and laundry cleaning product etc.A FAQs of lipotropy composition is relevant surperficial affinity (substantivity) or the residual that improves the lipotropy composition.In a lot (if not the overwhelming majority) daily occasions, in order for example to strengthen fragrance or fragrance or to improve antimicrobial effectiveness, people need improve the remained on surface of lipophile.
For example, modern dental hygiene and artificial tooth preparation generally all contain antiplaque agent and/or anticalculus agent, and biocide and flavouring agent.Anti-microbial effect can influence the formation of dental plaque, or this is by reducing the number of bacteria in oral cavity/tooth, perhaps is trapped in bacterium in the film to prevent its further growth and metabolism by killing those.Flavouring agent weakens problem of bad breath by going the peculiar smell effect.Some biocide such as mentha camphor also can be used as antozostomatic.Yet, the effectiveness of biocide depend primarily on they in the oral cavity/denture in the delay situation, especially under the situation that dental plaque forms, they are in residence time on the dental surface or the residence time on artificial tooth.
The exemplary shortcomings of known dental formulations is, has only the short time (tooth be cleaned or the oral cavity is washed by gargling) during this period can allow the biocide in the preparation play a role.This problem has increased the weight of because of the following fact, and promptly the use of dentifrice agent is not frequent: great majority are to use once perhaps secondary every day.Therefore, for most people, between brushing teeth, provide best dental plaque formation condition for a long time.
In many other people and daily application, people need provide the surperficial affinity of reinforcement.For example scouring agent can obtain improvement on the quality by improving the fragrance of daily use chemicals spices in thereby the affinity of fabric face is strengthened the washing back or used.Antimicrobial affinity of strengthening is because can the elimination stink relevant with sweat or other dirt also be very useful.The daily use chemicals spices affinity of strengthening also is very valuable in senior blending makeup.On the other hand, the freshener affinity of reinforcement is very useful in the product of treatment cough/flu.
So people need to develop a kind of lipotropy composition that remained on surface, effect and/or the antimicrobial efficacy of improvement are arranged always.
The lipotropy composition, for example the uses in containing the composition of SYNTHETIC OPTICAL WHITNER such as daily use chemicals spices, flavouring agent also can produce many problems, especially with the SYNTHETIC OPTICAL WHITNER effect after the fragrance that causes or the characteristic or the loss of strength of fragrance.The effectiveness of SYNTHETIC OPTICAL WHITNER also can be adversely affected.So the needs raising contains stability and the validity to the bleaching composition of the component of SYNTHETIC OPTICAL WHITNER sensitivity.
Knownly can in dentifrice composition, add (gathering) siloxanes (silicone), it is said to apply tooth and prevent decayed tooth and painted.For example, GB-A-689,679 disclose a kind of collutory, and it contains organopolysiloxane, adheres to tooth or removes following material from tooth to prevent following material: tar, color spot, dental calculus and food particles.Collutory can contain antiseptic-germicide such as thymol, and flavouring agent and daily use chemicals spices.
US-A-2,806,814 disclose the artificial tooth preparation, and it contains the higher aliphatic acid amides of amino carboxylic acid compounds simultaneously as activeconstituents and polysiloxane compound.This patent points out, proposed to prevent with polysiloxane compound that tar, color spot, dental calculus etc. from adhering to tooth or being convenient to and removed these materials from tooth.It is said that polysiloxane compound can be used as synergist and improves the antibacterial activity of activeconstituents and press down acid activity.It is said that dimethyl polysiloxane is effective especially.Can contain flavouring agent oil and/or mentha camphor.
The quaternary ammonium salt that US-A-3624120 discloses cyclic polysiloxanes is used as cats product, bactericide and anti-caries agent.
So, the invention provides flavouring agent, daily use chemicals spices, freshener, biocide or other lipotropy composition, it has improved surperficial affinity, effect and/or effectiveness.
The present invention also provides a kind of whitener composition, wherein comprises a kind of inorganic persalt SYNTHETIC OPTICAL WHITNER and a kind of lipotropy composition, for example flavouring agent and/or daily use chemicals spices, and also it has the stability of raising.
Summary of the invention
According to a first aspect of the invention, flavouring agent, daily use chemicals spices, freshener, biocide or other lipotropy composition are provided, have wherein contained by the poly-aminoalkyl group siloxanes (aminoalkylsilicone) of a repeated unit basis aminoalkyl group content of siloxane for about 0.1-2%.
The invention still further relates to and will gather aminoalkyl group siloxanes and the lipophile coupling that is selected from flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and composition thereof to improve remained on surface, wherein poly-aminoalkyl group siloxanes is selected from by the poly-aminoalkyl group siloxanes of a repeated unit basis aminoalkyl group content of siloxane for about 0.1-2%.
In another aspect of this invention, bleaching composition is provided, it contains the inorganic persalt SYNTHETIC OPTICAL WHITNER, is selected from the lipophile of flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and composition thereof and is the poly-aminoalkyl group siloxanes of about 0.1-2% by a repeated unit basis aminoalkyl group content of siloxane.
The invention still further relates to the lipophile coupling that will gather aminoalkyl group siloxanes and inorganic persalt SYNTHETIC OPTICAL WHITNER and be selected from flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and composition thereof to improve surperficial affinity, wherein poly-aminoalkyl group siloxanes is selected from by the poly-aminoalkyl group siloxanes of a repeated unit basis aminoalkyl group content of siloxane for about 0.1-2%.
All herein per-cent and ratio all are to calculate by the weight of total composition, unless otherwise indicated.
Therefore, composition of the present invention contains poly-aminoalkyl group siloxanes antiplaque agent and the lipophile that is selected from flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and composition thereof.Other composition of the present invention is then got the form of SYNTHETIC OPTICAL WHITNER and/or detergent composition, wherein comprises poly-aminoalkyl group siloxanes encapsulated stain removing agent and lipophile.
Generally, poly-aminoalkyl group siloxanes is selected from acyclic, hydrophobic poly-aminoalkyl group siloxanes, and its formula comprises two kinds of elementary cells:
1) (R 1) m(R) nSiO (4-m-n)/2, wherein m+n is 1,2 or 3; N is 1,2 or 3; M is 0,1 or 2; With
2) (R 1) a(R 2) bSiO (4-a-b)/2, wherein a+b is 1,2 or 3; And a and b be integer,
Wherein, R 1And R 2Be selected from independently of one another: alkyl and alkenyl, hydroxyl, alkoxyl group and acetoxyl group, for example R of H, about 1-10 carbon atom being replaced arbitrarily by fluorine or cyano group 1And R 2Be selected from methyl, ethyl, phenyl, vinyl, trifluoro propyl and cyano group propyl group independently of one another, and R is
R wherein 3Be about 1-20 the carbon atom that can at random be replaced or be interrupted by Sauerstoffatom, the divalent alkyl of preferably about 3-5 carbon atom, R 4, R 5And R 6Can be identical or different, they are selected from: H, about 1-20 the carbon atom that can be is at random replaced or be interrupted by N and/or O atom, preferably about 1-10 carbon atom, the alkyl of more preferably about 1-4 carbon atom; And X -Be monovalent negatively charged ion such as halogen ion, hydroxide radical and tosylate, by a repeated unit basis, this poly-aminoalkyl group siloxanes contains the 0.1-2% that has an appointment, preferably the unit of about 0.5-2% (1).
In a preferred example, poly-aminoalkyl group siloxanes is XF 49B1989 (amodimethicone).XF 49B1989 is the polydimethylsiloxanepolymer polymer that contains aminoalkyl group.Aminoalkyl group can be positioned on the side chain or one or more end of polydimethylsiloxane chain.Preferably so poly-aminoalkyl group siloxanes, wherein aminoalkyl group part R is selected from: (CH 2) 3NH 2, (CH 2) 3NHCH 2CH 2NH 2, (CH 2) 3N (CH 2CH 2OH) 2, (CH 2) 3NH 3 +X -, and (CH 2) 3N (CH 3) 2(C 18H 37) +X -, especially be selected from (CH 2) 3NH 2(CH 2) 3NHCH 2CH 2NH 2Also preferred molecular-weight average is about 5000 or higher, preferably about 5000-100,000, more preferably about 5000-30,000 poly-aminoalkyl group siloxanes.
Be applicable to that poly-aminoalkyl group silicone compounds of the present invention is known.For example at US-A-2, provided the method for the poly-aminoalkyl group siloxanes of preparation in 930,809.
The example of XF 49B1989 comprises OSI ' s Magnasoft fluid.These polymkeric substance contain and are connected the structural aminoalkyl groups of main polydimethylsiloxane.The unitary typical structure that MagnasoftShi contains aminoalkyl group is
-OSi(Me)C 3H 6NHCH 2CH 2NH 2。
The poly-general amount of aminoalkyl group siloxanes is about 0.01-0.25%, preferably for about 0.1-5%, is more preferably about 0.5-1.5% (weight).
Composition of the present invention preferably also contains lipophilic compound.Generally speaking, be applicable to that lipophilic compound herein is the material of oil sample, they are solvable in poly-aminoalkyl group siloxanes, preferably solubleness in the time of 25 ℃ at least about 1%, preferably at least about 5% (weight).Preferred lipophilic compound is selected from flavouring agent, daily use chemicals spices, physiological cooling agents and Antimicrobe compound.Poly-aminoalkyl group siloxanes is used to improve the affinity of lipophilic compound to handle surface, thereby improves and/or keep the effect and/or the antimicrobial efficacy of flavouring agent, daily use chemicals spices or freshener.
Be applicable to that lipophilic flavouring agent of the present invention comprises that one or more are selected from following flavouring agent component: wintergreen oil, wild marjoram oil (oregano oil), Bay leaves oil, spearmint oil, Oleum Menthae Rotundifoliae, Syzygium aromaticum stem oil, Sha Erweiya oil, sassafras wood oil, lemon oil, mandarin oil, olium anisi, phenyl aldehyde, Semen Armeniacae Amarum oil, camphor, cedar leaves oil, sweet marjoram oil, pamorusa oil, oleum lavendulae, mustard oil, pine tar, Pinus pumilio oil, rosemary oil, thyme oil, Cortex Cinnamomi leaf oil, and their mixture.
Comprise one or more known daily use chemicals flavor compositions at this lipotropy daily use chemicals spices that is suitable for, comprise volatile oil, absolute oil, natural products such as resin, with synthetic daily use chemicals spices components such as hydrocarbon, alcohol, aldehyde, ketone, ether, acid, ester, acetal, ketal, nitriles, comprise saturated and undersaturated compound, aliphatics, carboxylic acid and heterogeneous ring compound.Example at this daily use chemicals spices that is suitable for comprises meraneine, Linalyl acetate, geraniol acetate, acetate dihydromyrcene ester, tirpinyl acetate, verdy acetate, tricyclo decenyl propionate, acetate 2-phenyl chlorocarbonate, jasmal, benzyl salicylate, peruscabin, styroyl acetate, orchidae, the dihydro methyl jasmonate, phenoxyethyl isobutanoate, neryl acetate, acetate trichloromethyl-phenyl methyl esters, vertenex, vanoris, cedryl acetate, the cautious luxuriant ester of acetate Wei, phenylcarbinol, the 2-phenylethyl alcohol, linalool, Tetrahydrolinalool, geraniol, dimethylbenzylcarbinol, dihydromyrcenol, Tetrahydromyrcenol, terpinol, oxymethoxyallylbenzene, Geraniol, the cautious luxuriant alcohol of Wei, different camphyl-the hexalin of 3-, 2-methyl-3-(to tert-butyl-phenyl)-propyl alcohol, 2-methyl-3-(p-isopropyl phenyl)-propyl alcohol, 3-(to tert-butyl-phenyl)-propyl alcohol, vernol, α-n-pentyl phenylacrolein, jasmonal H, 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene formaldehyde, 4-(4-methyl-3-pentenyl)-3-tetrahydrobenzene formaldehyde, 4-acetyl oxygen-3-amyl group-tetrahydropyrans, 2-n-heptyl-cyclopentanone, 3-methyl-2-amyl group-cyclopentanone, n-capric aldehyde, n-dodecane aldehyde, laurine, the phenylacetic aldehyde dimethyl acetal, the phenylacetic aldehyde diethyl acetal, geranonitrile, citronellyl nitrile, cypress ylmethyl ether, the different ketone that comes into leaves, the aubepine nitrile, aubepine, heliotropine, tonka bean camphor, Vanillin, the oxidation phenylbenzene, ionone, irone, different irone, irone, cis-3-hexenol and ester thereof, 1,2-indane Moschus, 1,2,3, the 4-tetralin musk, isochroman Moschus (isochroman musk), macrocyclic ketone, the macrolide Moschus, the undecane dicarboxylic acid vinyl acetate, the aromatic nitro Moschus, and composition thereof.
Be applicable to that lipotropy biocide of the present invention comprises: thymol, mentha camphor, triclosan (triclosan), 4-Sucrets, phenol, eucalyptol, phenylformic acid, benzoyl peroxide, Butyl Chemosept (butyl paraben), nipagin, propylparaben, salicylic amide, and their mixture.
Be applicable to that lipotropy physiological cooling agents of the present invention comprises: carboxylic acid amides (carboxamide), menthane ester and menthane ether, and their mixture.
Be applicable to that menthane ether herein is selected from the kind with following formula:
Figure A9519692600081
Wherein, R 5Be can at random be replaced by hydroxyl, contain within 25 carbon atoms the aliphatic group within 5 carbon atoms preferably, and X is hydrogen or hydroxyl.Such as those kinds that can buy with trade(brand)name Takasago from Takasago InternationalCorporation.A kind of particularly preferred freshener that is used for the present composition is a Takasago 10[3-1-peppermint oxygen the third-1,2-glycol (MPD)].MPD is single glycerol derivative of 1-menthol, and it has excellent refrigerant property.
The most useful carboxylic acid amides of finding is at US-A-4,136,163 (on January 23rd, 1979, authorizing people such as Wason) and US-A-4, the kind described in 230,688 (on October 28th, 1980, the authorizing people such as Rawsell).
The concentration of lipophilic compound is generally about 0.01-10% in the present composition, preferably is to be more preferably about 0.1-3% (weight) by about 0.05-5%.
The present composition can randomly comprise one or more tensio-active agents, and this is good extraordinarily at the lipotropy composition of the present invention that is used for solubilising lipophile and raising effectiveness.Suitable tensio-active agent comprises non-soap anionic, nonionic, positively charged ion, zwitter-ion and both sexes synthetic organic detergent.At Gieske etc., the US-A-4 on September 27th, 1977 has described many these suitable class reagent in 051,234.
Comprise every mole of usefulness about 0.5 C at this tensio-active agent example that is suitable for to about 20 moles of ethylene oxide ethoxylations 6-C 18Alkyl-sulphate and sulfated alkyl ether; Anionic sulphonate comprises C 5-C 20Linear alkyl benzene sulfonate salt, alkyl sulfonic ester salt, C 6-C 22Uncle or secondary alkyl sulfonate, C 6-C 24Alkene sulfonate, the sulfonation poly carboxylic acid, alkyl glycerol sulfonate, the fatty acyl glycerol sulfonate, and composition thereof; The carboxylate anion comprises C 6To C 18The primary, secondary alkyl carboxylate, ethoxy carboxylate and polyethoxye polycarboxylate tensio-active agent, its average degree of ethoxylation is about 0 to about 10; C 5To C 17Sarcosinate, Hamposyl C sodium for example, sodium lauryl sarcosinate (Hamposyl-95 ex W.R.Grace); The condensation product of oxyethane or propylene oxide and lipid acid, Fatty Alcohol(C12-C14 and C12-C18), fatty amide, polyvalent alcohol (Arlacel-60 for example, Span-80), with the condensation product (for example Tergitol) of alkylphenol and with the condensation product (for example Pluronics) of poly(propylene oxide) and polyoxy butylene; US-A-4, the alkyl polysaccharide that discloses in 565,647; Amine oxide, cacodyl oxide base coconut amine (dimethyl cocamine oxide) for example, cacodyl oxide base lauryl amine and oxidation coconut alkyl dimethyl amine (cocoalkyldimethyl amine oxide) are (Aromox); Spheron MD 30/70, for example polysorbate40 and tween 80 (Hercules); Sorbitan monostearate, polyoxyethylene-sorbitan mono-oleate etc.; Cats product, for example cetylpyridinium chloride, cetrimonium bromide, chlorination diisobutyl phenoxy group ethoxyethyl group-dimethyl benzyl ammonium and nitric acid coconut alkyl trimethyl ammonium.
Consider the solubilising of lipophile, good especially at this is nonionogenic tenside.Have following general structure at this a kind of nonionogenic tenside that is suitable for:
R wherein 1Be to have 8 to 22, with the alkyl or alkenyl phenyl group of 10 to 20 carbon atoms of being advisable, m and n represent 0-80 and 2-80 respectively.Usually avoid short-chain alkyl, this is for the consideration to rendeing a service, and because unreacted Fatty Alcohol(C12-C14 and C12-C18) can cause peculiar smell in this class tensio-active agent, causes skin inflammation sometimes.Be appreciated that the mixture that this class tensio-active agent normally has different ethoxylated/propoxylated degree, so m and n represent propoxylation group and ethoxylation group number respectively.Ionic surfactant pack with above-mentioned general type is drawn together the product of mixed alkoxylated, and m wherein and n are between about 2 to 80, and it is about 2 to about 20, about 3 to about 10 better that m is preferably, and it is about 2 to about 60, about 5 to about 50 better that n is preferably.One of this class material is PPG-5-ceteth-20 (Croda Inc provides, and commodity are called Procetyl AWS), and m wherein and n are respectively 5 and 20.Other suitable ionic surfactant pack is drawn together the polyethoxylated tensio-active agent, and ethoxylated alkyl phenols ether for example especially has the octyl group of 8-16EO-and nonyl phenolic ether; The C of ethoxylated fat family 8-C 20Alcohol, they can be line style or side chain, have 8 to 16, are good EO with 9 to 15; And ethoxylated hydrogenated castor oil.
Usually, the ratio of tensio-active agent and daily use chemicals spices, freshener or other oily matter was at about 50: 1 to 1: 10, and about 20: 1 to 1: 2 better, and about 10: 1 to 1: 1 better.
Bleaching composition of the present invention also comprises one or more SYNTHETIC OPTICAL WHITNER, can be randomly and couplings such as organic peroxy acid precursor, effervescent, sequestrant.
SYNTHETIC OPTICAL WHITNER is the inorganic peracid salt form, and can be selected from the known SYNTHETIC OPTICAL WHITNER of knowing that is used in daily bleaching, decontamination, the denture cleanser etc. arbitrarily, for example persulfuric acid basic metal and ammonium salt, one hydration and four hydration perborate, percarbonate (can be as GB-A-1, apply described in 466,799) and superphosphate, and the superoxide of basic metal and alkaline-earth metal.Suitable SYNTHETIC OPTICAL WHITNER example comprises potassium, ammonium, sodium and lithium salts and a hydration and the four hydration perborate of persulfuric acid, trisodium phosphate peroxyhydrate, and the superoxide of magnesium, calcium, strontium, zinc.But, at this wherein persulfuric acid, peroxyboric acid and percarbonic acid an alkali metal salt, especially peroxyboric acid and percarbonic acid an alkali metal salt preferably.
It is about 5% to 70% that SYNTHETIC OPTICAL WHITNER content in bleaching composition of the present invention is generally, and about 10% to 50% is better.
Can also comprise effervescent in the SYNTHETIC OPTICAL WHITNER, it is the solid matter form in example preferably, can accompany by effervesce in water and emits carbonic acid gas or oxygen.Effervescent can be selected from operational pore forming material under acid, neutrality or alkaline pH condition, but be preferably by under acidity or neutral pH effectively the most effective pore forming material with under alkaline pH effectively or the most effective pore forming material mix.Effectively effervescent comprises at least a alkaline carbonate or supercarbonate (sodium bicarbonate for example under acidity or neutral pH, yellow soda ash, sodium sesquicarbonate, salt of wormwood, saleratus or their mixture) with at least a nontoxic, (the tartrate for example of appropriate organic on the physiology, fumaric acid, citric acid, oxysuccinic acid, toxilic acid, glyconic acid, succsinic acid, Whitfield's ointment, hexanodioic acid or thionamic acid, sodium fumarate, sodium acid phosphate or potassium, betaine hydrochloride, or their mixture) mixture of Zu Chenging.Wherein, oxysuccinic acid preferably.Effectively effervescent comprises persalt under alkaline pH, the basic metal of for example aforementioned peroxidation boric acid, peroxyboric acid and alkaline earth salt, persulphate, percarbonate, superphosphate, and their mixture, the mixture of certain alkali-metal perborate (anhydrous, a hydration or four hydrations) and single persulphate for example, for example Caroat that sells of EI du Point de Nemours Co. , this is a kind of 2: 1: 1 mixture of single persulphate, vitriolate of tartar and sal enixum, its active oxygen level is about 4.5%.
Be used for the bleaching composition preferably of denture cleanser, solid matter comprises that a kind of carbonic acid (hydrogen) salt/sour effervescent is right, randomly with perborate/persulphate oxygen effervescent coupling.The coupling of two kinds of effervescent is beneficial to reaching the solvability and the pH condition of the required the best of best cleaning and anti-microbial activity.It is about 5% to 65% that carbonic acid (hydrogen) salt component accounts in total composition usually, is preferably 25% to 55%; It is about 5% to 50%, about 10% to about 30% better that acid constituents accounts in total composition usually.
The present invention can also replenish in SYNTHETIC OPTICAL WHITNER with other component in known this class preparation.A kind of good especially other component is the organic peroxy acid precursor, can generally it be defined as peracid later and form the compound that titre in the test is at least 1.5ml 0.1N Sulfothiorine.
Following substance dissolves in 1000ml distilled water, is prepared testing liquid:
Trisodium phosphate (Na 4PO 2O 7·10H 2O) ????2.5g
Sodium peroxoborate (NaBO 2·H 2O 2·3H 2O), has 10.4% dissolved oxygen ????0.615g
The undecyl benzene sulfonic acid sodium salt ????0.5g
In the time of 60 ℃, in this solution, add a certain amount of activator, dosage is to add the normal activator of a part for each obtainable Sauerstoffatom.
Vigorous stirring adds the mixture behind the activator, and it is maintained 60 ℃.Added back 5 minutes, and got 100ml solution, be pipetted into immediately on the mixture of 250g trash ice and 15ml Glacial acetic acid.Adding potassiumiodide (0.4g) then, is indicator immediately with starch, and the iodine with the titration of 0.1N Sulfothiorine discharges takes off for the first time up to blueness.The milliliter number of used Sulfothiorine is exactly the titre of bleach-activating agent.
The organic peracid precursor normally has one or more compounds that is easy to the carboxyl groups of hydrolysis.Activator is the compound of N-acyl group or O-acyl group class preferably, wherein comprises a R-CO group, and R wherein is hydrocarbon or the substituted hydrocarbon radical group with 1 to 20 carbon atom.Suitable peracid precursors example comprises:
1) structural formula is RCONR 1R 2The acyl group organic amine, RCO wherein is the carboxylic acyl group, R 1Be acyl group, R 2Be an organic group, as US-A-3, described in 117,148.This type of examples for compounds comprises:
A) N, diacetanilide N, and N-acetyl phthalimide;
B) N-acyl group glycolylurea, N for example, N-diacetyl-5,5-T10;
C) Alkylenediamine of many acylations, N for example, N, N ', N '-tetra acetyl ethylene diamine (TAED) and its corresponding hexamethylenediamine (TAHD) derivative, as GB-A-907,356, GB-A-907 is disclosed in 357 and GB-A-907,358;
D) glycoluril of acylations, for example tetra-acetylated glycoluril, as GB-A-1,246,338, GB-A-1 is disclosed in 246,339 and GB-A-1,247,429.
2) the amine sulphonyl of acylations, for example N-methyl-N-benzoyl-Toluidrin and N-phenyl-N-ethanoyl-Toluidrin as GB-A-3, are disclosed in 183,266.
3) GB-A-836,988, GB-A-963, the carboxylicesters that is disclosed in 135 and GB-A-1,147,871.This type of examples for compounds comprises phenylacetate, acetoxyl group benzene sulfonic acid sodium salt, acetate trichloro ethyl ester, sorbitol hexaacetate, fructose pentaacetate, paranitrobenzaldehyde diacetate esters, methylvinyl acetate, ethanoyl N-acetylhydroxylamine and acetylsalicylic acid.Other example is the ester that phenol or fortified phenol and α chloro lower aliphatic carboxylic acid form, the ester of chloracetyl phenol and chloracetyl Whitfield's ointment and so on for example, and as US-A-3,130,165 is described.
4) general formula is the carboxylicesters of AcL, and Ac wherein is the acyl moiety of organic carboxyl acid, and this organic carboxyl acid at random has a C 6-C 20Alkyl or alkenyl part or a C of replacement, straight or branched 6-C 20The aryl that alkyl replaces, L is a leavings group, the pKa of its conjugate acid between 4 to 13, for example phenolsulfonic acid ester or hydroxy benzoate.Better person in this compounds:
A) Ac is R 3-CO, R 3Be the straight or branched alkyl, have 6 to 20 carbon atoms, 6 to 12 is good, and 7 to 9 are better, wherein begin and the longest straight chained alkyl that it is included comprised 5 to 18 carbon atoms from carbonyl carbon, with 5 to 10 be good, R 3Can be randomly by Cl, Br, OCH 3Or OC 2H 5Replace (being preferably in the α position of carbonyl carbon).The example of this type of material comprises 3,5,5-trimethyl acetyl oxygen base benzene sulfonic acid sodium salt, 3,5,5-trimethyl acetyl aminobenzoic acid sodium, 2-ethyl hexanoyl oxygen base benzene sulfonic acid sodium salt, the ninth of the ten Heavenly Stems acyloxy benzene sulfonic acid sodium salt and hot acyloxy benzene sulfonic acid sodium salt, acyloxy wherein is para-orientation preferably;
B) general formula of Ac is R 3(AO) mXA, wherein R 3Be a straight or branched alkyl or alkylaryl, have 6 to 20 carbon atoms at its moieties, with 6 to 15 be good, R 5Can be at random by Cl, Br, OCH 3Or OC 2H 5Replace, AO is oxyethylene group or oxypropylene group, and m is 0 to 100, and X is O, NR 4Or CO-NR 4, and A is CO, CO-CO, R 6-CO, CO-R 6-CO, or CO-NR 4-R 6-CO, R wherein 4Be C 1-C 4Alkyl, R 6Be alkylidene group, alkenylene, arylidene or alkylidene aryl, its alkylidene group or alkenylene partly have 1 to 8 carbon atom.This type of bleach-activating agent comprises that structural formula is R 3(AO) mThe carbonic acid derivatives of OCOL, structural formula are R 3OCO (CH 2) 2The succinic acid derivative of COL, structural formula are R 3OCH 2The oxyacetic acid derivative of COL, structural formula are R 3OCH 2CH 2The hydoxy-propionic acid derivative of COL, structural formula are R 3The oxalic acid derivative of OCOCOL, structural formula are R 3The toxilic acid of OCOCH=CHCOL and fumaric acid derivatives, structural formula are R 3CONR 1(CH 2) 6The acyl amino caproic acid derivative of COL, structural formula is R 3CONR 1CH 2The acylglycine derivatives of COL and structural formula are R 3N (R 1) CO (CH 2) 4The amino of COL-6-carbonyl caproic acid derivative.Wherein, m is good with 0 to 10, and m is 0 o'clock R 3C preferably 6-C 12Alkyl, C 6-C 10Better, m is not 0 o'clock R 3C preferably 9-C 15Alkyl.The definition of leaving group L as above.
5) acyl group cyanurate, for example triacetyl or tri-benzoyl cyanurate, for example United States Patent (USP) 3,332, described in 882.
6) benzoyl oxide or the Tetra hydro Phthalic anhydride that replaces arbitrarily, benzoyl oxide for example, m-chlorobenzoic acid acid anhydride and Tetra hydro Phthalic anhydride.
7) the N-ethanoyl precursor compound of the described lactams of GB-A-855735; especially hexanolactam and Valerolactim class; benzoyl Valerolactim for example; benzoyl caprolactam and their substituted benzoyl analogue, for example chlorine, amino, alkyl, aryl and alkoxy derivative.
In all above-claimed cpds, organic peracid precursor 1 (c) preferably, 4 (a) and 7.
If exist, peroxyacid bleach precursor accounts for the about 0.1% to 10%, 0.5% to 5% better of composition gross weight, and adds with the form of bleach precursor condensation product usually.
Usually contain about by weight 5% to about 40% tackiness agent or flocculation agent at this preferred SYNTHETIC OPTICAL WHITNER condensation product, about 10% to 30% is better.Suitable flocculation agent comprises poly-acetyl-pyrrolidine ketone, and molecular weight is 20,000 to 500; 000 polyoxyethylene, the polyoxyethylene glycol of molecular weight 1000 to 50,000; the Carbowax of molecular weight 4000 to 20,000, nonionogenic tenside; lipid acid, Xylo-Mucine, gelatin; Fatty Alcohol(C12-C14 and C12-C18), phosphoric acid salt, polyphosphate; clay, silico-aluminate and poly-multi-carboxylate.Wherein, preferred especially polyoxyethylene glycol, especially molecular weight about 1,000 to about 30,000,2000 to about 10,000 is better.
Consider from solvability and pH characteristic, preferred bleach precursor condensation product has about by weight 10% to about 75%, be preferably about 20% to about 60% peroxyacid bleach precursor, about 5% to 60%, about 5% to about 50% is good, is more preferably about 10% to about 40% carbonic acid (hydrogen) salt/sour effervescent is right, and about 0% to about 20% peroxide borate, with 5% to about 40%, be preferably about 10% to about 30% flocculation agent.Final bleach precursor grain should have that the average grain of about 500 to 1500 μ m is direct, and about 500 to 1,000 μ m are better, and this solvability and product appearance to the best is very important.And, bleach precursor condensation product content be the composition gross weight about 1% to about 20%, about 5% to 15% is better.
Its form of bleaching composition of the present invention can be lotion, tablet, granular or pulverous.The composition of tablet form can be the single or multiple lift tablet.
Can also replenish in the bleaching composition of the present invention with the component commonly used in other this class preparation, especially previously described tensio-active agent, sequestrant, enzyme, dyestuff, sweeting agent, tablet binder and filler, froth suppressor (for example dimethyl polysiloxane), the suds-stabilizing agent of sucrose fatty acid ester and so on, sanitas, for example lubricant of fine powder of talcum powder, Magnesium Stearate, amorphous silica fume and so on.
Comprise polyvinylpyrrolidone, molecular weight 20,000 to 500 at this tablet binder and filler that is suitable for, 000 polyoxyethylene, the polyoxyethylene glycol of molecular weight about 1000 to about 50,000, about 4000 to 20,000 the Carbowax of molecular weight, nonionogenic tenside, lipid acid, Xylo-Mucine, gelatin, Fatty Alcohol(C12-C14 and C12-C18), clay, polycarboxylate polymkeric substance, yellow soda ash, lime carbonate, calcium hydroxide, magnesium oxide, magnesium basic carbonate, sodium sulfate, protein, ether of cellulose, cellulose ester, polyvinyl alcohol, alginate esters, the vegetation fat with pseudo-colloid characteristic.Wherein, good especially is polyoxyethylene glycol, molecular weight about 1,000 to about 30,000 especially, and about 12,000 to about 30,000 is better.
Sequestrant is by being retained in the stability of helping clean and strengthen SYNTHETIC OPTICAL WHITNER in the solution with metal ions such as calcium, magnesium and heavy metal cations.The example of suitable sequestrant comprises tripoly phosphate sodium STPP, sodium acid phosphate, tetrasodium pyrophosphate, for example nitrilotriacetic acid(NTA) and ethylenediamine tetraacetic acid (EDTA) and salt thereof, quadrol N, the aminopolycanboxylic acid of N '-disuccinic acid (EDDS) and salt thereof and so on, for example polyphosphonic acid salt of hydroxyl ethane di 2 ethylhexyl phosphonic acid, ethylenediamine tetramethylene phosphonic acid, diethylenetriamine pentamethylenophosphonic acid(DTPP) and salt thereof and so on and aminopolyphosphonic acid salt.The selection of sequestrant is very unimportant, but must can be compatible with other composition in the denture cleanser under drying and aqueous solution state.Be preferably, sequestrant accounts for the 0.1% to 60%, 0.5% to 30% better of composition gross weight.But the phosphonic acids sequestrant should account for the about 0.1% to 1%, 0.1% to 0.5% better of composition gross weight.
Example at this enzyme that is suitable for comprises proteolytic enzyme, alkaline enzyme (alkalase), amylase, fungi and bacterium lipolytic enzyme, dextranase (dextranase), mutase (mutanase), dextranase (glucanase), esterase, cellulase, polygalacturonase, Sumylact L and peroxidase etc.US-A-3 has discussed suitable enzyme in 519,570 and US-A-3,533,139.
Following examples have further described and have illustrated the preferred implementation in the scope of the invention.
Example I is to V
Following is the representational false-tooth cleaning plate agent of the present invention.Per-cent calculates by the weight of total tablet.Tablet be by in drift and punch die tabletting machine in about 10 5Punching press particulate state mixture of ingredients is made under the pressure of kPa.
????I ????II ????III ????IV ????V
Oxysuccinic acid ????12 ????10 ????15 ????- ????14
Citric acid ????- ????10 ????- ????15 ????-
Yellow soda ash ????10 ????8 ????10 ????6 ????10
Thionamic acid ????5 ????- ????- ????3 ????3
????PEG?20,000 ????- ????3 ????7 ????8 ????5
????PVP?40,000 ????6 ????3 ????- ????- ????-
Sodium bicarbonate ????23 ????24 ????25 ????23 ????24
The Sodium peroxoborate monohydrate ????15 ????12 ????16 ????30 ????15
Permonosulphuric acid potassium ????15 ????18 ????13 ????- ????14
Fumed silica ????- ????3 ????1 ????1 ????-
Talcum powder ????2 ????- ????- ????- ????-
????EDTA ????- ????- ????1 ????- ????3
????EDTMP 1 ????1 ????- ????- ????1 ????-
Flavouring agent 5 ????2 ????1 ????2 ????1 ????2
The Magnasoft fluid 4 ????1 ????1.5 ????0.5 ????2 ????1
The bleach precursor agglomerate ????9 ????8 ????10 ????12 ????10
The bleach precursor agglomerate ????I ????II ????III ????IV ???V
??TAED 2 ????2 ????- ????4 ????5 ???2.5
??TMHOS 3 ????2 ????3 ????- ????- ???-
Thionamic acid ????2 ????2 ????2 ????2 ???3.5
Sodium bicarbonate ????0.5 ????0.2 ????0.2 ????0.5 ???2
??PEG?6000 ????2.5 ????2 ????2.4 ????2.5 ???1.5
Dyestuff ????- ????0.8 ????1.4 ????2 ???0.5
1. ethylenediamine tetramethylene phosphonic acid
2. tetra acetyl ethylene diamine
3. 3,5,5-trimethyl acetyl oxygen base benzene sulfonic acid sodium salt
4.Magnasoft fluid-provide by OSI
5. pennyroyal flavouring agent
In the above embodiments I to V, the gross weight of tablet is 3 grams; 25 millimeters of diameters.
Example I to the false-tooth cleaning plate agent of V demonstrates better antiplaque, cleaning power and germ resistance, and excellent tack and other physicalies and use properties.
Example VI is to IX
Below be representational daily use chemicals spices, flavouring agent, freshener and antimicrobial composition among the present invention.Per-cent is pressed total restatement of composition.
????VI ????VII ????VIII ????IX
????PPG-5-ceteth-20 ????3.0 ????3.0 ????4.5 ????3.0
The PEG-40 hydrogenated castor oil ????- ????1.8 ????4.5 ????3.0
????Trideceth-12 ????2.0 ????- ????- ????-
????Trideceth-9 ????- ????2.0 ????- ????3.0
Flavouring agent 5 ????2.0 ????- ????- ????3.0
Daily use chemicals spices 6 ????- ????3.0 ????- ????-
The trimethylammonium butyramide ????0.3 ????0.5 ????- ????-
Triclosan ????- ????- ????1.0 ????0.5
The Magnasoft fluid 4 ????1.0 ????1.5 ????5.0 ????1.0
Water Complement to 100%
6. daily use chemicals spices is the complex mixture that is mainly used in each composition of odor effect.
Example VI is to the daily use chemicals spices of IX, and flavouring agent, freshener and/or antimicrobial compositions show surperficial affinity, effect and/or the effectiveness of improvement.

Claims (11)

1. bleaching composition, it is characterized in that, it contains the inorganic persalt SYNTHETIC OPTICAL WHITNER, be selected from down the lipophile of group: flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and their mixture, and by the poly-aminoalkyl group siloxanes of a repeated unit basis aminoalkyl group content of siloxane for about 0.1-2%.
2. composition as claimed in claim 1 is characterized in that, poly-aminoalkyl group siloxanes is acyclic, hydrophobic poly-aminoalkyl group siloxanes, and its formula comprises two kinds of elementary cells:
1) (R 1) m(R) nSiO (4-m-n)/2, wherein m+n is 1,2 or 3; N is 1,2 or 3; M is 0,1 or 2; With
2) (R 1) a(R 2) bSiO (4-a-b)/2, wherein a+b is 1,2 or 3; And a and b be integer,
Wherein, R 1And R 2Be selected from independently of one another: alkyl and alkenyl, hydroxyl, alkoxyl group and the acetoxyl group of H, about 1-10 the carbon atom that can be replaced arbitrarily by fluorine or cyano group, and R is
Figure A9519692600021
R wherein 3Be the divalent alkyl of about 1-20 the carbon atom that can at random be replaced or be interrupted by Sauerstoffatom, R 4, R 5And R 6Can be identical or different, they are selected from: the alkyl of H, about 1-20 carbon atom can be at random being replaced or be interrupted by N and/or O atom; And X -Be monovalent negatively charged ion, by the unit basis of a repeatability, this poly-aminoalkyl group siloxanes contains the 0.1-2% unit (1) of having an appointment.
3. composition as claimed in claim 2 is characterized in that, it is about 5,000 that the molecular weight of this poly-aminoalkyl group siloxanes is at least, and preferably is about 5000-100,000.
4. as the described composition of arbitrary claim among the claim 1-3, it is characterized in that it contains the 0.01-25% that has an appointment, the poly-aminoalkyl group siloxanes of preferably about 0.1-5% (weight).
5. as the described composition of arbitrary claim among the claim 1-4, it is characterized in that the inorganic persalt SYNTHETIC OPTICAL WHITNER contains one or more SYNTHETIC OPTICAL WHITNER that is selected from down group: persulfuric acid an alkali metal salt, peroxyboric acid an alkali metal salt and their mixture.
6. according to the described composition of arbitrary claim among the claim 1-5, flavouring agent comprises one or more and is selected from following flavouring agent component: wintergreen oil, wild marjoram oil, Bay leaves oil, spearmint oil, Oleum Menthae Rotundifoliae, Syzygium aromaticum stem oil, Sha Erweiya oil, sassafras wood oil, lemon oil, mandarin oil, olium anisi, phenyl aldehyde, Semen Armeniacae Amarum oil, camphor, cedar leaves oil, sweet marjoram oil, pamorusa oil, oleum lavendulae, mustard oil, pine tar, Pinus pumilio oil, rosemary oil, thyme oil, Cortex Cinnamomi leaf oil, and their mixture.
7. according to the described composition of arbitrary claim among the claim 1-6, daily use chemicals spices comprises one or more daily use chemicals spices components that is selected from down group: meraneine, Linalyl acetate, geraniol acetate, acetate dihydromyrcene ester, tirpinyl acetate, verdy acetate, tricyclo decenyl propionate, acetate 2-phenyl chlorocarbonate, jasmal, benzyl salicylate, peruscabin, styroyl acetate, orchidae, the dihydro methyl jasmonate, phenoxyethyl isobutanoate, neryl acetate, acetate trichloromethyl-phenyl methyl esters, vertenex, vanoris, cedryl acetate, the cautious luxuriant ester of acetate Wei, phenylcarbinol, the 2-phenylethyl alcohol, linalool, Tetrahydrolinalool, geraniol, dimethylbenzylcarbinol, dihydromyrcenol, Tetrahydromyrcenol, terpinol, oxymethoxyallylbenzene, Geraniol, the cautious luxuriant alcohol of Wei, different camphyl-the hexalin of 3-, 2-methyl-3-(to tert-butyl-phenyl)-propyl alcohol, 2-methyl-3-(p-isopropyl phenyl)-propyl alcohol, 3-(to tert-butyl-phenyl)-propyl alcohol, vernol, α-n-pentyl phenylacrolein, jasmonal H, 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene formaldehyde, 4-(4-methyl-3-pentenyl)-3-tetrahydrobenzene formaldehyde, 4-acetyl oxygen-3-amyl group-tetrahydropyrans, 2-n-heptyl-cyclopentanone, 3-methyl-2-amyl group-cyclopentanone, n-capric aldehyde, n-dodecane aldehyde, laurine, phenylacetic aldehyde dimethyl acetal, the phenylacetic aldehyde diethyl acetal, geranonitrile, citronellyl nitrile, geranonitrile, citronellyl nitrile, cypress ylmethyl ether, the different ketone that comes into leaves, aubepine nitrile, aubepine, heliotropine, tonka bean camphor, Vanillin, the oxidation phenylbenzene, ionone, irone, different irone, irone, cis-3-hexenol and ester thereof, 1,2-indane Moschus, 1,2,3, the 4-tetralin musk, the isochroman Moschus, macrocyclic ketone, macrolide Moschus, undecane dicarboxylic acid vinyl acetate, the aromatic nitro Moschus, and composition thereof.
8. as the described composition of arbitrary claim among the claim 1-7, it is characterized in that, also contain pore forming material.
9. as the described composition of arbitrary claim among the claim 1-8, it is characterized in that, also contain the organic peracid bleach precursor.
10. composition as claimed in claim 9; it is characterized in that the organic peracid bleach precursor is selected from: many alkyl diamines of acidylate especially tetra acetyl ethylene diamine and general formula are the carboxylicesters of AcL; Ac wherein is the acyl moiety of organic carboxyl acid, and this organic carboxyl acid at random has a C 6-C 20Alkyl or alkenyl part or a C of replacement, straight or branched 6-C 20The aryl that alkyl replaces, L is a leavings group, the pKa of its conjugate acid is between 4 to 13.
11. the purposes of poly-aminoalkyl group siloxanes, it is characterized in that, it uses so that better lipophile stability to be provided with inorganic persalt SYNTHETIC OPTICAL WHITNER and lipophile, wherein lipophile is selected from: flavouring agent, daily use chemicals spices, physiological cooling agents, biocide and composition thereof, and poly-aminoalkyl group siloxanes is selected from by the poly-aminoalkyl group siloxanes of a repeated unit basis aminoalkyl group content of siloxane for about 0.1-2%.
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