CN117039190A

CN117039190A - Battery monomer, battery and power consumption device

Info

Publication number: CN117039190A
Application number: CN202311034238.1A
Authority: CN
Inventors: 张茜
Original assignee: Shanghai Lanjun New Energy Technology Co Ltd
Current assignee: Shanghai Lanjun New Energy Technology Co Ltd
Priority date: 2023-08-16
Filing date: 2023-08-16
Publication date: 2023-11-10

Abstract

The application relates to a battery cell, which comprises a shell, a battery cell positioned in a containing cavity of the shell and a porous elastic layer arranged between the shell and the battery cell. Excess electrolyte can be injected into the accommodating cavity in the process of assembling the battery cells, and the excess electrolyte can be absorbed by the porous elastic layer. During the charge-discharge cycle, the cell expands and presses the porous elastic layer, thereby releasing the absorbed electrolyte into the receiving cavity by the porous elastic layer to compensate for the consumption of the electrolyte. The more the number of cycles, the greater the expansion of the cell, the more significantly the porous elastic layer is extruded, and the more electrolyte is released. And when the ratio of H/Q/S is more than or equal to 1.5 and more than or equal to 0.2, the electrolyte in the porous elastic layer is almost just released and completed at the end of the cycle of the battery cell, so that the optimal cycle effect can be realized. Therefore, the battery cell described above can improve cycle life. In addition, the application also relates to a battery and an electric device.

Description

Battery monomer, battery and power consumption device

Technical Field

The application relates to the technical field of new energy, in particular to a battery monomer, a battery and an electric device.

Background

With the continuous development of new energy automobiles, the performance requirements on power batteries are also higher and higher. In order to improve the conductivity of the battery, reduce the internal resistance and improve the output power, silicon is generally doped at the negative electrode of the battery core so as to form a layer of compact silicide film on the surface of the negative electrode, thereby effectively preventing the negative electrode from continuing to be silicided.

However, the silicon particles expand during the battery charge and discharge cycles, causing lithium ion deintercalation. The lithium ions after deintercalation need to form new interfaces and consume the electrolyte continuously. Therefore, as the number of cycles of the battery increases, the electrolyte may be insufficient to cause a sudden decrease in cycle, i.e., cycle skip.

Disclosure of Invention

Based on this, it is necessary to provide a battery cell that improves cycle life in view of the above-described problems.

A battery cell comprises a shell, an electric core and a porous elastic layer; the shell is provided with an accommodating cavity, the battery cell is accommodated in the accommodating cavity, and the porous elastic layer is arranged between the shell and the battery cell; the porous elastic layer is internally provided with pores, so that the porous elastic layer can absorb electrolyte in the accommodating cavity and release the absorbed electrolyte into the accommodating cavity when being extruded;

wherein (H.Q)/S is more than or equal to 1.5 and more than or equal to 0.2, H is the thickness of the porous elastic layer, Q is the porosity of the porous elastic layer, and S is the silicon content in the negative electrode of the battery cell.

In one embodiment, 0.05 mm.ltoreq.H.ltoreq.1 mm, 20%.ltoreq.Q.ltoreq.78%, 3%.ltoreq.S.ltoreq.50%.

In one embodiment, the porous elastomeric layer is attached to an inner wall of the housing.

In one embodiment, the housing is hollow and cylindrical, and the porous elastic layer is attached to the inner wall of the cylindrical surface of the housing.

In one embodiment, a diffusion channel is formed on one side of the porous elastic layer facing the battery cell, and electrolyte released by the porous elastic layer can diffuse on the surface of the porous elastic layer along the diffusion channel.

In one embodiment, the porous elastic layer is provided with a whole surface structure, the surface of the porous elastic layer is rugged and forms peaks and valleys, and the valleys form the diffusion flow channel.

In one embodiment, the porous elastic layer is provided with a hollow structure, and the hollow area of the porous elastic layer forms the diffusion channel.

In one embodiment, the porous elastic layer includes a plurality of bar-shaped coatings disposed at intervals, and bar-shaped gaps between the plurality of bar-shaped coatings form the diffusion flow channels.

In one embodiment, the porous elastic layer includes a plurality of spiral coatings disposed at intervals from each other, and spiral gaps between the plurality of spiral coatings form the diffusion flow channels.

In one embodiment, the porous elastic layer comprises a plurality of bulk coatings distributed in scattered points, and gaps among the bulk coatings form the diffusion flow channels.

In one embodiment, the hole is one or a combination of several of a round hole, a strip-shaped through hole and a curve-shaped through hole.

According to the battery cell, excessive electrolyte can be injected into the accommodating cavity in the process of assembling the battery cell, and the excessive electrolyte can be absorbed by the porous elastic layer. During the charge-discharge cycle, the cell expands and presses the porous elastic layer, thereby releasing the absorbed electrolyte into the receiving cavity by the porous elastic layer to compensate for the consumption of the electrolyte. The more the number of cycles, the greater the expansion of the cell, the more significantly the porous elastic layer is extruded, and the more electrolyte is released. And when the ratio of H/Q/S is more than or equal to 1.5 and more than or equal to 0.2, the electrolyte in the porous elastic layer is almost just released and completed at the end of the cycle of the battery cell, so that the optimal cycle effect can be realized. Therefore, the battery cell described above can improve cycle life.

In addition, the application also provides a battery and an electric device.

A battery comprising a plurality of cells as in any of the above preferred embodiments.

An electrical device comprising a battery cell as described in any of the above preferred embodiments or a battery as described in the above preferred embodiments.

Drawings

In order to more clearly illustrate the embodiments of the application or the technical solutions in the prior art, the drawings that are required in the embodiments or the description of the prior art will be briefly described, it being obvious that the drawings in the following description are only some embodiments of the application, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.

FIG. 1 is a schematic view of a battery cell according to a preferred embodiment of the present application;

FIG. 2 is a cross-sectional view of the battery cell shown in FIG. 1 taken along line A-A;

FIG. 3 is a schematic view of the battery cell of FIG. 2 with the cell omitted and the housing and porous elastic layer;

FIG. 4 is an enlarged partial schematic view of the wall of the housing shown in FIG. 3;

FIG. 5 is a schematic view of a battery cell with the cell back casing and porous elastic layer omitted in another embodiment;

FIG. 6 is a schematic view of a battery cell with the cell back casing and porous elastic layer omitted in another embodiment;

FIG. 7 is a schematic view of a battery cell with the cell back casing and porous elastic layer omitted in another embodiment;

fig. 8 is a schematic diagram of a battery cell with the cell back case and the porous elastic layer omitted in another embodiment.

Detailed Description

In order that the above objects, features and advantages of the application will be readily understood, a more particular description of the application will be rendered by reference to the appended drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present application. The present application may be embodied in many other forms than described herein and similarly modified by those skilled in the art without departing from the spirit of the application, whereby the application is not limited to the specific embodiments disclosed below.

In the description of the present application, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings are merely for convenience in describing the present application and simplifying the description, and do not indicate or imply that the device or element being referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the present application.

Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include at least one such feature. In the description of the present application, the meaning of "plurality" means at least two, for example, two, three, etc., unless specifically defined otherwise.

In the present application, unless explicitly specified and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; either directly or indirectly, through intermediaries, or both, may be in communication with each other or in interaction with each other, unless expressly defined otherwise. The specific meaning of the above terms in the present application can be understood by those of ordinary skill in the art according to the specific circumstances.

In the present application, unless expressly stated or limited otherwise, a first feature "up" or "down" a second feature may be the first and second features in direct contact, or the first and second features in indirect contact via an intervening medium. Moreover, a first feature being "above," "over" and "on" a second feature may be a first feature being directly above or obliquely above the second feature, or simply indicating that the first feature is level higher than the second feature. The first feature being "under", "below" and "beneath" the second feature may be the first feature being directly under or obliquely below the second feature, or simply indicating that the first feature is less level than the second feature.

It will be understood that when an element is referred to as being "fixed" or "disposed" on another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical," "horizontal," "upper," "lower," "left," "right," and the like are used herein for illustrative purposes only and are not meant to be the only embodiment.

The application discloses an electric device, a battery and a battery cell. The electric device can be a vehicle, a mobile phone, portable equipment, a notebook computer, a ship, a spacecraft, an electric toy, an electric tool, energy storage equipment, recreation equipment, an elevator, lifting equipment and the like. The vehicle can be a fuel oil vehicle, a fuel gas vehicle or a new energy vehicle, and the new energy vehicle can be a pure electric vehicle, a hybrid electric vehicle or a range-extended vehicle; spacecraft including airplanes, rockets, space planes, spacecraft, and the like; the electric toy includes fixed or mobile electric toys, such as a game machine, an electric car toy, an electric ship toy, or an electric plane toy, etc.; power tools include metal cutting power tools, grinding power tools, assembly power tools, and railroad power tools, such as electric drills, electric grinders, electric wrenches, electric screwdrivers, electric hammers, impact drills, concrete vibrators, electric planers, and the like; the energy storage device can be an energy storage wall, a base station energy storage, a container energy storage and the like; the amusement device may be a carousel, a stair jump machine, or the like. The present application does not particularly limit the above-described power consumption device.

For new energy automobiles, the battery can be used as a driving power source to replace fossil fuel to provide driving power.

The battery may be a battery pack or a battery module. When the battery is a battery pack, the battery pack specifically includes a Battery Management System (BMS) and a plurality of the battery cells. The battery management system is used for controlling and monitoring the working states of the battery monomers. In addition, a plurality of battery cells can be connected in series and/or in parallel and form a battery module together with a module management system, and then the battery modules are electrically connected in series, in parallel or in a mode of mixing the series and the parallel and form a battery pack together with the battery management system.

The battery pack or the battery module can be arranged on a supporting structure such as a box body, a frame and a bracket, and the battery cells can be electrically connected through a confluence part. The battery cell may be a lithium ion battery, a sodium ion battery or a magnesium ion battery, and its external contour may be a cylinder, a flat body, a cuboid or other shapes, but is not limited thereto. In this embodiment, the battery cell is a lithium ion cylindrical battery.

Referring to fig. 1, 2 and 3, a battery cell 10 according to a preferred embodiment of the application includes a housing 100, a cell 200 and a porous elastic layer 300.

The housing 100 may be formed of aluminum, stainless steel, or the like, and has a housing cavity (not shown) formed therein for housing the battery cell 200, electrolyte, and other components. Furthermore, at least one end of the housing 100 is provided with an opening through which the battery cell 200 can be fitted into the housing 100. The outer contour of the case 100 determines the outer contour of the battery cell 10. Since the battery cell 10 in the present embodiment is a cylindrical battery, the case 100 has a cylindrical shape. Obviously, the case 100 may also have a cubic shape when applied to other types of batteries, such as prismatic batteries.

The battery cell 200 is accommodated in the accommodation chamber of the housing 100, and is a core component of the battery cell 10. The battery cell 200 may be formed by stacking or winding a positive electrode sheet, a negative electrode sheet, and a separator having an insulating function between the negative electrode sheet and the positive electrode sheet. In order to adapt to the shape of the housing 100, the battery cell 200 in this embodiment is also cylindrical, and may be wound into a cylindrical shape by winding.

The negative electrode of the cell 200 is doped with silicon, i.e. the negative electrode sheet is doped with a silicon material, which may be pure silicon, silicon carbon or silicon oxygen. The surface of the negative electrode plate doped with silicon can form a layer of compact silicide film, so that the negative electrode plate can be effectively prevented from being continuously silicided, the conductivity of the battery cell 200 is improved, the internal resistance is reduced, and the output power is improved. The expansion rate of silicon is larger, and silicon particles doped in the negative plate can expand in the process of charge-discharge cycle. Preferably, in the embodiment, the silicon content in the negative plate of the battery cell 200 is denoted as S, and S is 3% or more and 50% or less, wherein S refers to mass percent.

The porous elastic layer 300 is disposed between the housing 100 and the battery cell 200. The porous elastic layer 300 may be attached to the inner wall of the case 100, may be attached to the outer circumference of the battery cell 200, and may be detachably mounted between the case 100 and the porous elastic layer 300. In particular, in the present embodiment, the porous elastic layer 300 is attached to the inner wall of the case 100. The porous elastic layer 300 has a small thickness and soft texture, and the housing 100 can provide support to the porous elastic layer 300 attached to the inner wall to maintain the shape stability of the porous elastic layer 300, thereby facilitating assembly.

More specifically, the housing 100 in the present embodiment has a hollow cylindrical shape, and the porous elastic layer 300 is attached to the inner wall of the cylindrical surface of the housing 100. In this way, the porous elastic layer 300 has a larger area and can be disposed around the cell 200. Obviously, in other embodiments, the porous elastic layer 300 may be attached to the bottom surface or the top surface of the housing 100.

The porous elastic layer 300 is formed of a polymer material, and may be specifically at least one of polyurethane elastomer rubber, polydimethylsiloxane, and ultra-high molecular polyethylene. The porous elastic layer 300 is formed at an inside thereof with pores (not shown), which may be one or a combination of several of circular holes, bar-shaped through holes, and curved through holes. Specifically, in the present embodiment, the porous elastic layer 300 is molded from SEBS (linear triblock copolymer) having high porosity. The SEBS and the liquid oil are fully dissolved by high-temperature melting, and are cooled to form colloid, and then the oil dissolved in the SEBS is washed to remove, so that the porous structure with pores in the SEBS can be obtained.

The pores inside the porous elastic layer 300 enable the porous elastic layer 300 to absorb electrolyte in the receiving chamber and release the absorbed electrolyte into the receiving chamber when pressed. During the assembly of the battery cell 10, an excessive amount of electrolyte may be injected into the receiving cavity of the case 100, and the excessive electrolyte may be absorbed by the porous elastic layer 300. Typically, the amount of injected fluid is greater than about 20% compared to the same type of cell without the porous elastic layer 300.

During the charge-discharge cycle, the silicon particles in the negative electrode sheet expand, thereby causing the cell 200 to expand and compress the porous elastic layer 300. The porous elastic layer 300 releases the absorbed electrolyte to the receiving cavity after being pressed by the battery cell 200 to compensate for the consumption of the electrolyte. Further, as the number of cycles increases, the swelling amount of the cell 200 increases, and the porous elastic layer 300 is significantly compressed, so that the electrolyte is released more. That is, the porous elastic layer 300 can gradually release the electrolyte along with the increase of the cycle times, so as to continuously supplement the electrolyte in the accommodating cavity, thereby improving the cycle life of the battery cell 10.

In addition, the porous elastic layer 300 may also serve as a buffer. When the battery cell 200 expands, the porous elastic layer 300 can absorb the expansion force of the battery cell 200, so that uneven stress release of the pole piece caused by hard extrusion of the battery cell 200 and the shell 100 is avoided, the interface of the pole piece can be optimized, the crushing phenomenon of silicon particles is delayed, and the cycle characteristics of the battery cell 10 are improved.

The thickness of the porous elastic layer 300 is denoted as H, the porosity is denoted as Q, and h×q indicates the ability of the porous elastic layer 300 to absorb and store electrolyte, and the larger the value of h×q is, the stronger the ability of the porous elastic layer 300 to absorb and store electrolyte is.

In this example, 0.05 mm.ltoreq.H.ltoreq.1 mm. When H is less than 0.05mm, the thickness of the porous elastic layer 300 is too small to play a role in buffering and absorbing excessive electrolyte; when H is greater than 1mm, the porous elastic layer 300 has an excessively large thickness, and occupies a large space in the case 100, thereby causing the space of the battery cell 200 to be compressed, so that the size of the battery cell 200 needs to be reduced, and thus, the energy density of the battery cell 10 is finally reduced.

In this example, 20% or less and 78% or less of Q. The greater the porosity of the porous elastic layer 300, the greater its ability to absorb and store electrolyte. When the porosity of the porous elastic layer 300 is less than 20%, insufficient absorption and storage of the electrolyte by the porous elastic layer 300 may result in release of no electrolyte at a later stage or lower than required amount per administration at a earlier stage of release. However, excessive porosity may cause instability of the support structure of the porous elastic layer 300. When the porosity of the porous elastic layer 300 is greater than 78%, the electrolyte is easily excessively released, resulting in an insufficient supply of the electrolyte at the end of the cycle of the battery cell 10.

Further, the thickness H, the porosity Q, and the silicon content S in the negative electrode of the cell 200 of the porous elastic layer 300 also satisfy the relationship of 1.5 (h×q)/S being equal to or greater than 0.2. The greater the silicon content S value in the negative electrode sheet of the cell 200, the greater the amount of electrolyte required during cycling, and thus the greater the ability of the porous elastic layer 300 to absorb and store electrolyte is required. When 1.5 (H.Q)/S.gtoreq.0.2 is satisfied, the electrolyte stored in the porous elastic layer 300 is almost just released at the end of the cycle of the cell 200, so that the electrolyte is not wasted, the shortage of the electrolyte is not generated, and the optimal cycle effect can be realized.

Referring to fig. 4, in the present embodiment, a diffusion channel 301 is formed on a side of the porous elastic layer 300 facing the battery cell 200, and the electrolyte released from the porous elastic layer 300 can diffuse along the diffusion channel 301 on the surface of the porous elastic layer 300.

The diffusion flow path 301 may be a groove formed on the surface of the porous elastic layer 300, or may be a groove penetrating the porous elastic layer 300 in the thickness direction. After the electrolyte released by the porous elastic layer 300 enters the diffusion flow channel 301, the electrolyte can flow along the diffusion flow channel 301, so that the electrolyte can uniformly enter all the positions of the accommodating cavity, and the cell 200 is uniformly infiltrated. In this way, the electrolyte supplied into the housing chamber by the porous elastic layer 300 can be prevented from being accumulated in a certain region and being lost in other regions.

Further, in the present embodiment, the porous elastic layer 300 is configured as a whole structure, the surface of the porous elastic layer 300 is rugged and forms peaks and valleys, and the valleys constitute the diffusion flow channel 301.

Specifically, the inner wall of the case 100 may be continuously coated or plated to obtain the porous elastic layer 300 of the whole structure. The porous elastic layer 300 with the whole structure is not broken in the middle, so that the structure strength is higher, and the supporting and buffering effects are better. Moreover, the electrolyte is more strongly absorbed and stored under the same thickness, so that the thickness of the porous elastic layer 300 can be reduced on the premise of meeting the release requirement of the electrolyte, which is beneficial to improving the energy density of the battery cell 100.

The peaks and valleys of the high and low relief can form a wave pattern structure on the surface of the porous elastic layer 300, and the concave areas of the wave patterns, that is, the areas where the valleys are located, form the diffusion flow channels 301. The diffusion flow channel 301 with the wavy structure can make the diffusion of the released electrolyte more uniform, and has the best effect of improving circulation.

In addition, in other embodiments, the porous elastic layer 300 is configured as a hollowed structure, and the hollowed area of the porous elastic layer 300 forms the diffusion channel 301. That is, the porous elastic layer 300 is formed by discontinuous coating or plating, and the porous elastic layer 300 includes a coated area and an uncoated area (hollowed-out area). The hollowed-out region can also provide a buffer region for the porous elastic layer 300 while constituting the diffusion channel 301. When the porous elastic layer 300 is compressed by extrusion deformation, the coating area can extend to the hollow area of the side surface, so that the housing 100 is prevented from bearing too much.

As shown in fig. 5, in one embodiment, the porous elastic layer 300 includes a plurality of bar-shaped coating layers 310 disposed at intervals from each other, and bar-shaped gaps between the plurality of bar-shaped coating layers 310 constitute diffusion channels 301. The porous elastic layer 300 composed of the plurality of bar-shaped coating layers 310 is conveniently molded. Further, since the diffusion flow path 301 is elongated and extends in the up-down direction, the flow and diffusion of the electrolyte in the up-down direction are facilitated.

In another embodiment, as shown in fig. 6, the porous elastic layer 300 includes a plurality of spiral coatings 320 disposed at intervals from each other, and spiral gaps between the plurality of spiral coatings 320 constitute diffusion channels 301. Since the diffusion flow path 301 is spiral and rises spirally around the central axis of the case 100, the electrolyte flowing along the diffusion flow path 301 can be diffused in both the lateral and longitudinal directions, and the diffusion effect of the electrolyte is excellent.

In another embodiment, as shown in fig. 7 and 8, the porous elastic layer 300 includes a plurality of bulk coatings 330 distributed in scattered points, and gaps between the bulk coatings 330 form diffusion channels 301.

Specifically, the block-shaped coating 330 may be in a regular shape such as a rectangle or a triangle, or may be in an irregular shape, and the plurality of block-shaped coatings 330 may be regularly arranged or may be randomly distributed. At this time, the diffusion flow channels 301 are distributed more uniformly, so that the electrolyte is diffused more uniformly along the diffusion flow channels 301. Moreover, the block coating 330 is more uniformly distributed between the housing 100 and the battery cell 200, so that the electrolyte can be uniformly released into the accommodating cavity.

In the battery cell 100, an excessive amount of electrolyte may be injected into the receiving chamber during the assembly process of the battery cell 10, and the excessive electrolyte may be absorbed by the porous elastic layer 300. During the charge-discharge cycle, the cell 200 expands and presses the porous elastic layer 300, so that the porous elastic layer 300 releases the absorbed electrolyte into the receiving cavity to compensate for the consumption of the electrolyte. The more cycles, the greater the expansion of the cell 200, the more significantly the porous elastic layer 300 is compressed, and the more electrolyte is released. Moreover, when 1.5 (h×q)/S is equal to or greater than 0.2, the electrolyte in the porous elastic layer 300 is almost just released at the end of the cycle of the cell 200, and thus an optimal cycle effect can be achieved. Therefore, the battery cell 10 described above can improve the cycle life.

The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.

The above examples illustrate only a few embodiments of the application, which are described in detail and are not to be construed as limiting the scope of the application. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the application, which are all within the scope of the application. Accordingly, the scope of protection of the present application is to be determined by the appended claims.

Claims

1. A battery cell is characterized by comprising a shell, an electric core and a porous elastic layer; the shell is provided with an accommodating cavity, the battery cell is accommodated in the accommodating cavity, and the porous elastic layer is arranged between the shell and the battery cell; the porous elastic layer is internally provided with pores, so that the porous elastic layer can absorb electrolyte in the accommodating cavity and release the absorbed electrolyte into the accommodating cavity when being extruded;

2. The battery cell of claim 1, wherein 0.05 mm.ltoreq.H.ltoreq.1 mm, 20%.ltoreq.Q.ltoreq.78%, 3%.ltoreq.S.ltoreq.50%.

3. The battery cell of claim 1, wherein the porous elastic layer is attached to an inner wall of the housing.

4. The battery cell of claim 3, wherein the housing has a hollow cylindrical shape, and the porous elastic layer is attached to an inner wall of the cylindrical surface of the housing.

5. The battery cell according to claim 1, wherein a diffusion flow channel is formed on a side of the porous elastic layer facing the electric core, and the electrolyte released from the porous elastic layer can diffuse along the diffusion flow channel on the surface of the porous elastic layer.

6. The battery cell according to claim 5, wherein the porous elastic layer is provided in a whole-surface structure, the surface of the porous elastic layer is rugged and forms peaks and valleys, and the valleys constitute the diffusion flow channel.

7. The housing assembly of claim 5, wherein the porous elastic layer is configured as a hollowed out structure, and the hollowed out area of the porous elastic layer forms the diffusion channel.

8. The housing assembly of claim 7, wherein said porous elastomeric layer comprises a plurality of bar-shaped coatings disposed in spaced relation to one another, and wherein a plurality of bar-shaped gaps between said bar-shaped coatings form said diffusion flow channels.

9. The housing assembly of claim 7, wherein the porous elastomeric layer comprises a plurality of spiral coatings disposed in spaced relation to one another, and wherein spiral gaps between the plurality of spiral coatings form the diffusion flow path.

10. The housing assembly of claim 7, wherein the porous elastomeric layer comprises a plurality of bulk coatings distributed in discrete points, and wherein gaps between the plurality of bulk coatings form the diffusion flow channels.

11. The housing assembly of claim 1, wherein the aperture is one or a combination of a circular hole, a bar-shaped through hole, and a curved through hole.

12. A battery comprising a plurality of cells according to any one of claims 1 to 11.

13. An electrical device comprising a battery cell according to any one of claims 1 to 11 or a battery according to claim 12.