CN116985368A - High-molecular polymer aeration pipe and preparation method and application thereof - Google Patents

High-molecular polymer aeration pipe and preparation method and application thereof Download PDF

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Publication number
CN116985368A
CN116985368A CN202310857512.9A CN202310857512A CN116985368A CN 116985368 A CN116985368 A CN 116985368A CN 202310857512 A CN202310857512 A CN 202310857512A CN 116985368 A CN116985368 A CN 116985368A
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CN
China
Prior art keywords
aeration pipe
preparation
pipe
molecular polymer
polyethylene
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310857512.9A
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Chinese (zh)
Inventor
姚亮
张强
李鹏
张赛
张冲
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Beijing Zhongshe Water Treatment Co ltd
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Beijing Zhongshe Water Treatment Co ltd
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Publication date
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Priority to CN202310857512.9A priority Critical patent/CN116985368A/en
Publication of CN116985368A publication Critical patent/CN116985368A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The invention belongs to the field of sewage treatment, and particularly relates to a high molecular polymer aeration pipe, and a preparation method and application thereof. The preparation method provided by the invention comprises the following steps: and mixing the hydrophobic plastic raw materials, then melting, blending and extruding, spraying to form fibers, then winding and forming the sprayed fiber filaments on a receiving die, and cooling to obtain the high-molecular polymer aerator pipe. The technical scheme provided by the invention solves the defects that the common rubber material aeration pipe has large resistance loss, the open hole position is easy to tear, and the anchor ear is easy to fall off during installation, and the prepared high polymer aeration pipe has excellent mechanical property, small resistance loss, small micropores, uniform air outlet, convenient installation, and obvious advantages in the aspects of service life, energy conservation, consumption reduction, stable operation and operation cost reduction.

Description

High-molecular polymer aeration pipe and preparation method and application thereof
Technical Field
The invention belongs to the field of sewage treatment, and particularly relates to a high molecular polymer aeration pipe, and a preparation method and application thereof.
Background
The common sewage treatment method often comprises an aerobic biological treatment process, and the process needs to supply oxygen and aerate to the sewage, so that on one hand, the mixed effect is achieved, and on the other hand, the needed oxygen is provided for the growth of microorganisms. At present, an aeration system of an aeration tank is widely used, and an aeration pipe is arranged at the bottom of the tank, namely, purified air is provided by an air blower and is sent to the aeration pipe at the bottom of the biological tank through a pipeline system.
The aeration pipe adopted in the market is usually made of rubber materials such as ethylene propylene diene monomer rubber, silicon rubber and the like, rubber is required to be manufactured into a rubber pipe by means of banburying, mixing, blending, vulcanization, extrusion molding and the like, and then mechanical equipment is adopted to open small holes to meet the aeration requirement in order to enable the rubber product to be more suitable for complex and changeable sewage treatment environments. The inner plastic perforated pipe is fixed through the anchor ear, the fastening safety is not high, the rubber aeration membrane is easy to fall off in the use process, and meanwhile, the rubber aeration membrane is poor in oil resistance, tear resistance and chemical corrosion resistance, easy to age, easy to block, short in service life and inconvenient to maintain and repair.
Disclosure of Invention
In view of the above, the invention aims to provide a high polymer aeration pipe, a preparation method and application thereof, and the high polymer aeration pipe solves the defects that the common rubber material aeration pipe has large resistance loss, the open pore position is easy to tear and the anchor ear is easy to fall off during installation.
The invention provides a preparation method of a high molecular polymer aerator pipe, which comprises the following steps:
and mixing the hydrophobic plastic raw materials, then melting, blending and extruding, spraying to form fibers, then winding and forming the sprayed fiber filaments on a receiving die, and cooling to obtain the high-molecular polymer aerator pipe.
Preferably, the hydrophobic plastic material comprises high density polyethylene, low density polyethylene, polypropylene and polyethylene carbon black masterbatch.
Preferably, the density of the high-density polyethylene is 941-960 kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the high-density polyethylene is 15-25 g/10min.
Preferably, the density of the low-density polyethylene is 910-930 kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the low density polyethylene is 40-60 g/10min.
Preferably, the polypropylene has a density of 890 to 910kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polypropylene is 30-45 g/10min.
Preferably, the density of the polyethylene carbon black masterbatch is 1000-1400 kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polyethylene carbon black masterbatch is 20-35 g/10min; the carbon black content of the polyethylene carbon black masterbatch is 40-60 wt%.
Preferably, the hydrophobic plastic raw materials comprise 40-70% of high-density polyethylene, 10-40% of low-density polyethylene, 10-40% of polypropylene and 1-10% of polyethylene carbon black masterbatch in percentage by mass.
Preferably, the inner diameter of the high polymer aeration pipe is 27-285 mm; the thickness of the high polymer aeration pipe is 5-20 mm; the aperture of the high molecular polymer aerator pipe is 5-80 mu m.
The invention also provides a high polymer aeration pipe prepared by the preparation method according to the technical scheme.
The invention also provides an aeration system, which is provided with the high polymer aeration pipe according to the technical scheme.
Compared with the prior art, the invention provides a high molecular polymer aeration pipe and a preparation method and application thereof. The preparation method provided by the invention comprises the following steps: and (3) melting and blending the hydrophobic plastic raw materials, spraying to form fibers, then rolling and forming the sprayed fiber filaments on a receiving die, and cooling to obtain the high-molecular polymer aerator pipe. The technical scheme provided by the invention solves the defects that the common rubber material aeration pipe has large resistance loss, the open hole position is easy to tear, and the anchor ear is easy to fall off during installation, and the prepared high polymer aeration pipe has excellent mechanical property, small resistance loss, small micropores, uniform air outlet, convenient installation, and obvious advantages in the aspects of service life, energy conservation, consumption reduction, stable operation and operation cost reduction. More specifically, the technical scheme of the invention has the following advantages:
1) The adopted plastic raw materials are all hydrophobic materials, are not easy to scale and adhere to sludge, and have good anti-pollution performance.
2) The aeration pipe is prepared by adopting the modes of blending extrusion, melt spinning and winding forming, and the prepared aeration pipe has higher porosity and uniform aperture, and the aperture range is adjustable; the pore diameter of the aeration pipe is stable and does not change along with the pressure; the aerator pipe has accurate size, high mechanical strength and good ageing resistance; the oxygen-enriched air-conditioning device has the advantages of low energy consumption, good mechanical stability, small and evenly distributed generated bubbles, good oxygenation effect, corrosion resistance, difficult blockage, capability of meeting the requirement of long-term use and the like.
3) The method avoids the poor tear resistance caused by secondary mechanical opening of the rubber aeration pipe, and the formed aeration holes are more uniform and smaller in aperture, thereby being beneficial to dissolution and transfer of oxygen in water and being beneficial to being utilized by microorganisms.
4) The aeration pipe can form an aeration system with common pipe fittings which are easy to obtain in the market, and the cost is low and the popularization is easy.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely, and it is apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The invention provides a preparation method of a high molecular polymer aerator pipe, which comprises the following steps:
and mixing the hydrophobic plastic raw materials, then melting, blending and extruding, spraying to form fibers, then winding and forming the sprayed fiber filaments on a receiving die, and cooling to obtain the high-molecular polymer aerator pipe.
In the preparation method provided by the invention, the hydrophobic plastic raw material preferably comprises high-density polyethylene, low-density polyethylene, polypropylene and polyethylene carbon black masterbatch.
In the preparation method provided by the invention, the density of the high-density polyethylene is preferably 941-960 kg/m 3 Most preferably 954kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the high density polyethylene is preferably 15 to 25g/10min, most preferably 20g/10min.
In the preparation method provided by the invention, the content of the high-density polyethylene in the hydrophobic plastic raw material is preferably 40-70 wt%, and most preferably 55wt%.
In the preparation method provided by the invention, the density of the low-density polyethylene is preferably 910-930 kg/m 3 Most preferably 916kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the low density polyethylene is preferably 40 to 60g/10min, most preferably 50g/10min.
In the preparation method provided by the invention, the content of the low-density polyethylene in the hydrophobic plastic raw material is preferably 10-40 wt%, and most preferably 20wt%.
In the preparation method provided by the invention, the density of the polypropylene is preferably 890-910 kg/m 3 Most preferably 900kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polypropylene is preferably 30 to 45g/10min, most preferably 38g/10min.
In the preparation method provided by the invention, the content of the polypropylene in the hydrophobic plastic raw material is preferably 10-40 wt%, and most preferably 19wt%.
In the preparation method provided by the invention, the density of the polyethylene carbon black masterbatch is preferably 1000-1400 kg/m 3 Most preferably 1200kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polyethylene carbon black masterbatch is preferably 20-35 g/10min, most preferably 27g/10min; the carbon black content of the polyethylene carbon black masterbatch is preferably 40 to 60wt%, most preferably 50wt%.
In the preparation method provided by the invention, the content of the polyethylene carbon black masterbatch in the hydrophobic plastic raw material is preferably 1-10wt%, and most preferably 6wt%.
In the preparation method provided by the invention, after the hydrophobic plastic raw materials are uniformly mixed, the hydrophobic plastic raw materials are preferably fed into a melt blending device in a negative pressure feeding mode, and the melt blending device is preferably an extruder.
In the preparation method provided by the invention, the temperature of the melt blending extrusion is preferably 180-220 ℃, and most preferably 200 ℃.
In the preparation method provided by the invention, the spray forming specifically refers to forming fibers through spray traction. In the invention, the diameter of the fiber and the aperture size of the aerator pipe can be adjusted by adjusting the distance of the jet traction and/or the rotating speed of the receiving die.
In the preparation method provided by the invention, the inner diameter of the high polymer aeration pipe can be selected according to the design requirements of different aeration systems, and the high polymer aeration pipe comprises 27-285 mm, and can be 27mm, 30mm, 35mm, 40mm, 45mm, 50mm, 55mm, 60mm, 65mm, 70mm, 75mm, 80mm, 90mm, 100mm, 120mm, 140mm, 160mm, 180mm, 200mm, 220mm, 240mm, 260mm or 280mm; the thickness of the high polymer aeration pipe is preferably 5-20 mm, specifically can be 5mm, 8mm, 10mm, 12mm, 15mm, 18mm or 20mm, and is most preferably 10mm; the pore diameter of the high molecular polymer aerator pipe is preferably 5 to 80. Mu.m, specifically 5 μm, 10 μm, 15 μm, 20 μm, 25 μm, 30 μm, 35 μm, 40 μm, 45 μm, 50 μm, 55 μm, 60 μm, 65 μm, 70 μm, 75 μm or 80 μm, and most preferably 50 μm.
In the preparation method provided by the invention, the method preferably further comprises the step of cutting the prepared high polymer aeration pipe to obtain the aeration pipe with the required length.
The invention also provides a high polymer aeration pipe prepared by the preparation method according to the technical scheme.
The invention also provides an aeration system, which is provided with the high polymer aeration pipe according to the technical scheme.
The technical scheme provided by the invention solves the defects that the common rubber material aeration pipe has large resistance loss, the open hole position is easy to tear, and the anchor ear is easy to fall off during installation, and the prepared high polymer aeration pipe has excellent mechanical property, small resistance loss, small micropores, uniform air outlet, convenient installation, and obvious advantages in the aspects of service life, energy conservation, consumption reduction, stable operation and operation cost reduction. More specifically, the technical scheme of the invention has the following advantages:
1) The adopted plastic raw materials are all hydrophobic materials, are not easy to scale and adhere to sludge, and have good anti-pollution performance.
2) The aeration pipe is prepared by adopting a melt spinning and winding forming mode, and the prepared aeration pipe has higher porosity and uniform aperture, and the aperture range is adjustable; the pore diameter of the aeration pipe is stable and does not change along with the pressure; the aerator pipe has accurate size, high mechanical strength and good ageing resistance; the oxygen-enriched air-conditioning device has the advantages of low energy consumption, good mechanical stability, small and evenly distributed generated bubbles, good oxygenation effect, corrosion resistance, difficult blockage, capability of meeting the requirement of long-term use and the like.
3) The method avoids the poor tear resistance caused by secondary mechanical opening of the rubber aeration pipe, and the formed aeration holes are more uniform and smaller in aperture, thereby being beneficial to dissolution and transfer of oxygen in water and being beneficial to being utilized by microorganisms.
4) The aeration pipe can form an aeration system with common pipe fittings which are easy to obtain in the market, and the cost is low and the popularization is easy.
For clarity, the following examples are provided in detail.
Example 1
The preparation method of the high molecular polymer aerator pipe comprises the following specific steps:
(1) Preparing materials: 55wt% of high-density polyethylene, 20wt% of low-density polyethylene, 19wt% of polypropylene and 6wt% of polyethylene carbon black masterbatch; wherein the density of the high-density polyethylene is 954kg/m 3 The melt flow rate is 20g/10min; the density of the low-density polyethylene is 916kg/m 3 The melt flow rate is 50g/10min; the density of the polypropylene is 900kg/m 3 The melt flow rate is 38g/10min; the density of the polyethylene carbon black masterbatch is 1200kg/m 3 The melt flow rate was 27g/10min and the carbon black content was 50%.
(2) The raw materials are added into a mixing barrel according to a certain proportion, and are uniformly mixed, then the mixture enters an extruder in a negative pressure feeding mode, is melted and extruded at the temperature of 200 ℃, is formed into fibers through jet traction, is rolled and formed on a receiving die, and is cooled and shaped to obtain the high polymer aeration pipe (the inner diameter R is 65mm, the outer diameter R is 85mm, the thickness W is 10mm, and the aperture is 50 mu m).
(3) Cutting the prepared high polymer aeration pipe by a cutter to obtain the high polymer aeration pipe with the length L of 1000 mm.
(4) The aeration pipe of the high polymer is combined with UPVC and ABS pipes and pipe fittings which are common in the market to be used as an aeration system for sewage treatment; through tests, the oxygen utilization rate of the rubber aerator can reach 25-35%, the bubble diameter is 0.5-2 mm, and the pressure loss is 100-250 mm water column, and the rubber aerator can replace the existing rubber aerator.
The foregoing is merely a preferred embodiment of the present invention and it should be noted that modifications and adaptations to those skilled in the art may be made without departing from the principles of the present invention, which are intended to be comprehended within the scope of the present invention.

Claims (10)

1. The preparation method of the high polymer aeration pipe is characterized by comprising the following steps:
and mixing the hydrophobic plastic raw materials, then melting, blending and extruding, spraying to form fibers, then winding and forming the sprayed fiber filaments on a receiving die, and cooling to obtain the high-molecular polymer aerator pipe.
2. The method of claim 1, wherein the hydrophobic plastic feedstock comprises high density polyethylene, low density polyethylene, polypropylene, and polyethylene carbon black masterbatch.
3. The process according to claim 2, wherein the high-density polyethylene has a density of 941 to 960kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the high-density polyethylene is 15-25 g/10min.
4. The method according to claim 2, wherein the low-density polyethylene has a density of 910 to 930kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the low density polyethylene is 40-60 g/10min.
5. The process according to claim 2, wherein the polypropylene has a density of 890 to 910kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polypropylene is 30-45 g/10min.
6. The method according to claim 2, wherein the polyethylene carbon black masterbatch has a density of 1000 to 1400kg/m 3 The method comprises the steps of carrying out a first treatment on the surface of the The melt flow rate of the polyethylene carbon black masterbatch is 20-35 g/10min; the carbon black content of the polyethylene carbon black masterbatch is 40-60 wt%.
7. The preparation method according to claim 2, wherein the hydrophobic plastic raw materials comprise, in mass percent, 40-70% of high-density polyethylene, 10-40% of low-density polyethylene, 10-40% of polypropylene and 1-10% of polyethylene carbon black masterbatch.
8. The preparation method according to claim 1, wherein the inner diameter of the high molecular polymer aeration pipe is 27-285 mm; the thickness of the high polymer aeration pipe is 5-20 mm; the aperture of the high molecular polymer aerator pipe is 5-80 mu m.
9. A high molecular polymer aeration pipe, characterized in that it is produced by the production method according to any one of claims 1 to 8.
10. An aeration system, characterized in that the aeration system is provided with the high molecular polymer aeration pipe according to claim 9.
CN202310857512.9A 2023-07-13 2023-07-13 High-molecular polymer aeration pipe and preparation method and application thereof Pending CN116985368A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310857512.9A CN116985368A (en) 2023-07-13 2023-07-13 High-molecular polymer aeration pipe and preparation method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310857512.9A CN116985368A (en) 2023-07-13 2023-07-13 High-molecular polymer aeration pipe and preparation method and application thereof

Publications (1)

Publication Number Publication Date
CN116985368A true CN116985368A (en) 2023-11-03

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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