CN116731568A - Wear-resistant coating - Google Patents

Wear-resistant coating Download PDF

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Publication number
CN116731568A
CN116731568A CN202310853209.1A CN202310853209A CN116731568A CN 116731568 A CN116731568 A CN 116731568A CN 202310853209 A CN202310853209 A CN 202310853209A CN 116731568 A CN116731568 A CN 116731568A
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CN
China
Prior art keywords
coating
wear
resistant coating
resistance
corrosion resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310853209.1A
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Chinese (zh)
Inventor
周勍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Huichang Saw Industry Co ltd
Original Assignee
Suzhou Huichang Saw Industry Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Huichang Saw Industry Co ltd filed Critical Suzhou Huichang Saw Industry Co ltd
Priority to CN202310853209.1A priority Critical patent/CN116731568A/en
Publication of CN116731568A publication Critical patent/CN116731568A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18Homopolymers or copolymers of tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention is applicable to the technical field of wear-resistant coatings, and provides a wear-resistant coating which is prepared from the following raw materials in percentage by mass: 20% -25% of polytetrafluoroethylene; 5% -10% of phenolic resin; 3% -15% of organic polymer; 10 to 15 percent of molybdenum disulfide. The wear-resistant coating is used for improving corrosion resistance and wear resistance of the coating, an organic polymer and guaranteeing conductivity, durability and thermal stability of the coating, wherein the corrosion resistance effect is further enhanced by molybdenum disulfide and butanol, the high temperature resistance is improved by matching butanol with propylene glycol methyl ether acetate, the risk of cracking and peeling is avoided, the adhesion effect is improved, the fluidity and distribution of the coating are improved, the high temperature resistance and corrosion resistance are further enhanced by mixed hydrocarbon, the strength of the coating is enhanced, the risk of impact damage and stress crack is reduced, and the effects of difficult peeling and separation under repeated impact abrasion are achieved, so that the wear-resistant coating is high in corrosion resistance and meets the use effect under severe environment.

Description

Wear-resistant coating
Technical Field
The invention belongs to the technical field of saw blade coatings, and particularly relates to a wear-resistant coating.
Background
Saw blades are a collective term for thin sheet circular cutters for cutting solid materials, and are widely used in the woodworking and construction industries for cutting and shaping wood, plastic, metal and other materials, and are widely used in various fields, including manufacturing, construction and furniture industries, among which the need for accurate and efficient cutting in these fields has driven the need for saw blades.
The surface of the saw blade needs to be provided with a wear-resistant coating, as it can extend the life of the saw blade and increase the cutting efficiency, for example, in the woodworking industry, where saw blades are used for cutting and shaping hard wood, cork and plywood, which are difficult to cut effectively without a sharp and durable saw blade, the wear-resistant coating can protect the blade from wear, enable it to hold the blade edge, and reduce the need for sharpening and replacement.
The conventional saw blade surface coating is largely classified into a ceramic coating, a diamond coating, a titanium nitride coating and a polymer coating, and is exemplified simply, for example, in a ceramic coating, the ceramic coating has wear resistance, but the type is easily broken and fragile when being subjected to repeated impact or abrasion, and for example, a titanium nitride coating is easily scratched or damaged due to its hardness, and when exposed to severe conditions or hard materials, the coating cannot be kept good, and its service life is affected, so that there is a need for a wear-resistant coating having excellent wear resistance, corrosion resistance, long service life and the like.
Disclosure of Invention
The invention provides a wear-resistant coating, which aims to solve the problems that the existing various coatings cannot bear repeated impact wear or are easily scratched and damaged and cannot resist corrosion.
The invention is realized in such a way that the wear-resistant coating consists of the following raw materials in percentage by mass:
20% -25% of polytetrafluoroethylene;
5% -10% of phenolic resin;
3% -15% of organic polymer;
10% -15% of molybdenum disulfide;
4% -15% of solvent;
5% -10% of mixed hydrocarbon;
5 to 10 percent of butyrolactone.
Preferably, the organic polymer additive is polyamide imide and graphite, wherein the polyamide imide is 7% -15%, and the graphite is 3% -7%.
Preferably, the inorganic compound is molybdenum disulfide, and the compound number of the molybdenum disulfide is Cas1317-33-5.
Preferably, the solvent comprises butanol and propylene glycol methyl ether acetate, wherein the butanol accounts for 4% -5%, and the propylene glycol methyl ether acetate accounts for 8% -15%.
Preferably, the mixed hydrocarbon is C9-10 aromatic hydrocarbon, and the compound number of the C9-10 aromatic hydrocarbon is Cas 64142-95-6.
Preferably, the organic polymer is polyamide polyimide and graphite, the graphite is 3% -7%, and the polyamide polyimide is 7% -15%.
Preferably, the compound number of the butyrolactone is Cas 96-48-0.
Advantageous effects
Compared with the prior art, the invention has the beneficial effects that: according to the wear-resistant coating, the polytetrafluoroethylene and the phenolic resin are used for improving corrosion resistance and wear resistance of the coating, the organic polymer is used for guaranteeing conductivity, durability, thermal stability and wear resistance of the coating, the corrosion resistance effect is further enhanced by molybdenum disulfide and butanol, the high temperature resistance is improved by matching use of butanol and propylene glycol methyl ether acetate, the risk of cracking and peeling is avoided, the adhesion effect is improved, the fluidity and distribution of the coating are improved, the high temperature resistance and corrosion resistance are further enhanced by mixing hydrocarbon, the strength of the coating is enhanced, the risk of impact damage and stress cracking is reduced, and in sum, the effects of difficult peeling and separation under repeated impact wear are achieved, the corrosion resistance is high, the use effect under severe environments is met, and the adhesion effect of the coating to a base material is guaranteed.
Description of the embodiments
The present invention will be described in further detail with reference to the following examples in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
The invention provides a technical scheme that: the wear-resistant coating consists of the following raw materials in percentage by mass: 20-25% of polytetrafluoroethylene and 5-10% of phenolic resin.
Polytetrafluoroethylene is widely used in various fields including coating preparation processes, in which polytetrafluoroethylene is used to enhance lubricity and wear resistance of a coating so that it can withstand high stress conditions occurring when a saw blade cuts a hard material, due to its unique properties including high durability, low friction and excellent lubricity.
Phenolic resins, in turn, are thermosetting resins having high strength, toughness and durability, and are often used in a variety of coating applications because of their ability to adhere well to a variety of surfaces and provide excellent chemical resistance, where they serve to enhance the durability and corrosion resistance of the coating, making them better resistant to harsh environmental conditions and the corrosive action of moisture or other corrosive substances.
Thus, by combining the polytetrafluoroethylene with phenolic resin, the addition to the coating preparation results in 1. Improved lubricity and wear resistance, 2. Increased durability, 3. Improved cutting performance.
Abrasion resistance: the lubricity and wear resistance of the coating may be enhanced to withstand the high stress conditions that occur when cutting hard materials with a saw blade.
Durability: the durability and corrosion resistance of the coating are improved, so that the coating can better bear severe environmental conditions and the corrosion action of other corrosive substances.
Cutting performance: improved lubricity and wear resistance, reduced need for frequent maintenance, and improved cutting performance.
3-15% of organic polymer, wherein the organic polymer additive is polyamide imide and graphite, the polyamide imide is 7-15%, and the graphite is 3-7%.
Organic polymers are polymeric compounds formed by covalent bonding of a number of identical or different monomer molecules. They have many excellent properties such as high strength, high toughness, heat resistance, corrosion resistance, etc., and thus are widely used in various fields including coating preparation processes, and thus mainly serve three functions in the coating preparation process, 1. Improvement of durability, 2. Improvement of wear resistance, 3. Improvement of chemical resistance.
However, in the preparation process of the organic polymer in the present invention, two kinds of the organic polymer are classified into polyamideimide and graphite:
the polyamide imide has the characteristics of high strength, flexibility and heat resistance, so that the polyamide imide is an excellent choice in the preparation of the coating, and mainly plays a role in improving the wear resistance and durability of the coating, so that the polyamide imide can ensure the service effect under severe environment and the service life.
And graphite has high conductivity, high hardness and thermal stability, and when the graphite is applied to the wear-resistant coating, the electrical performance of the coating can be improved by adding the graphite with proper mass percent, and the effect of ensuring heat dissipation is achieved.
Illustrating: in the production process of microelectronic products or precision optical elements, a high-speed dicing machine is needed, wherein the high-speed dicing machine, a main shaft, a flange disc and a saw blade are used as an anode, a workbench is used as a cathode, the saw blade rotating at high speed moves towards the workbench along with the movement of the main shaft, when the saw blade contacts the workbench, the anode and the cathode together with current generation are considered to be the peaks of the saw blade in the vertical direction, the purpose that the workpiece can be cut through and the saw blade can not be cut to the workbench is achieved, and the situation that the cutting saw blade requires higher conductivity in the tool setting process is guaranteed, and the current generation is convenient for subsequent confirmation of the position of the saw blade is guaranteed.
10% -15% of molybdenum disulfide, wherein the inorganic compound is molybdenum disulfide, and the compound number of the molybdenum disulfide is Cas1317-33-5.
Molybdenum disulfide is an inorganic material, which has advantages of high strength, high corrosion resistance, and excellent heat resistance. The molybdenum disulfide is used for enhancing the corrosion resistance and the heat resistance of the coating when the coating is manufactured, so that the coating can bear severe environmental conditions and the durability of the saw blade is improved.
The high-temperature-resistant effect is mainly achieved in a high-temperature environment, such as woodworking or metal cutting, better heat resistance is provided for the coating, and molybdenum disulfide is known to be high in corrosion resistance, so that moisture and other corrosive substances can be effectively blocked, the coating is more comfortable to use in a severe or humid environment, and meanwhile, the coating has a low friction coefficient and hardness, and meets the use requirements under the condition of high stress.
Further, the solvent is 4% -15%, the solvent comprises butanol and propylene glycol methyl ether acetate, the butanol is 4% -5%, and the propylene glycol methyl ether acetate is 8% -15%.
The butanol and the propylene glycol methyl ether acetate are both organic solvents, and have high purity and low toxicity, and when the butanol and the propylene glycol methyl ether acetate are added into the coating, the coating performance can be improved, particularly the fluidity and the distribution of the coating can be improved, the coating is easier to apply, potential defects or flaws are reduced, the service life of the coating is prolonged, the high temperature resistance of the coating is improved, the cracking or peeling risk is reduced, the adhesion performance is improved, the combination with the surface is enhanced, the separation risk is reduced, the coating strength is improved, the impact damage or the stress cracking is reduced, and the characteristics of improving the coating strength are achieved.
Butanol can be added into the wear-resistant coating to serve as a corrosion inhibitor in the invention, so that the corrosion speed is slowed down, the service life of the coating is prolonged, and the performance of the coating is improved, but the high concentration is required to be carefully prepared, so that skin irritation and damage can be caused.
Further, the mixed hydrocarbon is 5-10%, the mixed hydrocarbon is C9-10 aromatic hydrocarbon, and the compound number of the C9-10 aromatic hydrocarbon is Cas 64142-95-6.
C9-10 aromatic hydrocarbons are a class of organic solvents with high boiling points and good solubility properties, and in new coatings, these solvents are used to enhance the high temperature resistance of the coating and reduce the risk of cracking or flaking.
The C9-10 aromatic hydrocarbons may provide several key benefits including 1. Improving the durability of the coating, C9-10 aromatic hydrocarbons may improve the high temperature resistance of the coating, the coating may reduce the risk of cracking or flaking under high temperature and stress conditions, 2. Improving the adhesion of the coating, solvents may improve the adhesion of the coating to the surface, enhance bonding forces, reduce the risk of flaking or separation, 3. Improving the strength of the coating, C9-10 aromatic hydrocarbons may improve the strength of the coating by reducing the risk of impact damage or stress cracking, 4. Improving the corrosion resistance of the coating, C9-10 aromatic hydrocarbons may also improve the corrosion resistance, moisture resistance, and chemical resistance of the coating, increasing its durability in harsh environments or compounds.
The mass percentages of all the raw materials include the minimum percentage mass, the maximum percentage mass and any percentage between the minimum percentage mass and the maximum percentage mass, such as 20% -25% of polytetrafluoroethylene, namely including 20%, 25%, 21%, 22%, 23%, 24% and any percentage between 20% and 25%.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.

Claims (7)

1. A wear resistant coating, characterized by: the material comprises the following raw materials in percentage by mass:
20% -25% of polytetrafluoroethylene;
5% -10% of phenolic resin;
3% -15% of organic polymer;
10% -15% of molybdenum disulfide;
4% -15% of solvent;
5% -10% of mixed hydrocarbon;
5 to 10 percent of butyrolactone.
2. A wear resistant coating as claimed in claim 1, wherein: the organic polymer additive is polyamide imide and graphite, wherein the polyamide imide accounts for 7-15%, and the graphite accounts for 3-7%.
3. A wear resistant coating as claimed in claim 1, wherein: the inorganic compound is molybdenum disulfide, and the compound number of the molybdenum disulfide is Cas1317-33-5.
4. A wear resistant coating as claimed in claim 1, wherein: the solvent comprises 4-5% of butanol and 8-15% of propylene glycol methyl ether acetate.
5. A wear resistant coating as claimed in claim 1, wherein: the mixed hydrocarbon is C9-10 aromatic hydrocarbon, and the compound number of the C9-10 aromatic hydrocarbon is Cas 64142-95-6.
6. A wear resistant coating as claimed in claim 1, wherein: the organic polymer is polyamide polyimide and graphite, wherein the graphite accounts for 3% -7%, and the polyamide polyimide accounts for 7% -15%.
7. A wear resistant coating as claimed in claim 1, wherein: the compound number of the butyrolactone is Cas 96-48-0.
CN202310853209.1A 2023-07-12 2023-07-12 Wear-resistant coating Pending CN116731568A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310853209.1A CN116731568A (en) 2023-07-12 2023-07-12 Wear-resistant coating

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Application Number Priority Date Filing Date Title
CN202310853209.1A CN116731568A (en) 2023-07-12 2023-07-12 Wear-resistant coating

Publications (1)

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CN116731568A true CN116731568A (en) 2023-09-12

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Country Status (1)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1073968A (en) * 1991-12-31 1993-07-07 中国科学院兰州化学物理研究所 Dry-film lubricant
KR20010046935A (en) * 1999-11-16 2001-06-15 김충섭 Composition for anti-corrosive coating primer
CN102816518A (en) * 2012-09-06 2012-12-12 山东滨州渤海活塞股份有限公司 Carbon-carbon composite nano-base wear-resistant coating material
US20200407592A1 (en) * 2017-09-12 2020-12-31 Federal-Mogul Wiesbaden Gmbh Solid film lubricant, method for producing same, sliding element comprising same and use thereof
WO2022046617A1 (en) * 2020-08-24 2022-03-03 Ddp Specialty Electronic Materials Us 9, Llc Antifriction coating composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1073968A (en) * 1991-12-31 1993-07-07 中国科学院兰州化学物理研究所 Dry-film lubricant
KR20010046935A (en) * 1999-11-16 2001-06-15 김충섭 Composition for anti-corrosive coating primer
CN102816518A (en) * 2012-09-06 2012-12-12 山东滨州渤海活塞股份有限公司 Carbon-carbon composite nano-base wear-resistant coating material
US20200407592A1 (en) * 2017-09-12 2020-12-31 Federal-Mogul Wiesbaden Gmbh Solid film lubricant, method for producing same, sliding element comprising same and use thereof
WO2022046617A1 (en) * 2020-08-24 2022-03-03 Ddp Specialty Electronic Materials Us 9, Llc Antifriction coating composition

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