CN116716001A - 一种用于海上油田设施设备的防覆冰涂料 - Google Patents
一种用于海上油田设施设备的防覆冰涂料 Download PDFInfo
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- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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Abstract
本发明涉及涂料技术领域,具体涉及一种用于海上油田设施设备的防覆冰涂料。本发明的用于海上油田设施设备的防覆冰涂料,主要由由A组分和B组分组成,A组分由以下质量百分数的原料制成:低表面能树脂20‑50%,着色颜料1‑25%,体质颜料10%‑50%,功能性填料10‑40%,分散助剂0.1‑10%,消泡剂0.05‑2%,流平剂0.05‑2%,防沉助剂0.05‑2%,紫外光吸收剂0.05‑5%,催干剂0.05‑1%,功能性助剂0.05‑10%,溶剂20‑60%;B组分为异氰酸酯类固化剂,A组分与B组分的质量比为6‑10:1。本发明的用于海上油田设施设备的防覆冰涂料,具有优异的低着冰力值、耐候性与防腐蚀性能,可以有效改善冬季海上平台覆冰除去困难的问题。
Description
技术领域
本发明涉及涂料化工技术领域,具体涉及一种防覆冰涂料。
背景技术
海洋平台是开展资源勘探、开采以及运输等活动的载体。然而,在渤海以及往北地区冬季低温多冰,同时海气交换强烈、湿度很大,这种气候环境下形成的覆冰给海洋平台带来了极大的影响。海洋平台上遭受到海水溅淋,甲板上易形成覆冰,同时大气中的过冷液滴在海洋平台的设施设备上形成大量覆冰,覆冰不仅严重影响设施设备的功能,而且冰雪覆冰还会降低平台的结构稳定性、改变结构应力、降低结构可靠性,对平台的日常工作造成危害。同时晶状覆冰还会降低摩擦系数威胁直升机在海洋平台上的起降。
防覆冰是一个世界性的难题,在冰灾多发国如加拿大、美国已成立了专门的研究机构,对解决覆冰问题进行了大量的研究,我国近几年也对解决覆冰开展了大量的研究工作。目前,针对海洋平台的除冰方法按照除冰形式分为主动除冰法和被动除冰法。主动除冰法是指结冰后借助外力除冰,包括机械、盐、电加热、红外线等除冰方法,这些方法需要一定的能源或资源。被动方法是指利用涂层材料本身的属性阻止冰凝结到涂层或降低冰粘附强度,并依靠风力或自身重力就可使冰脱离表面,这些方法几乎不消耗能源。
目前业界公认的解决方案是采用防覆冰涂料最大限度的降低冰在涂料表面的附着力,从而使冰极易脱落和去除。
因此,有必要提供一种可以用于海上油田设施设备的防覆冰涂料。
发明内容
本发明所要解决的技术问题是:提供一种可以用于海上油田设施设备的防覆冰涂料,可以减少冰在涂料表面的附着力,达到防覆冰的效果,且稳定耐用,帮助改善海洋平台上冬季低温覆冰除去困难的问题。
本发明解决其技术问题所采用的技术方案是:一种用于海上油田设施设备的防覆冰涂料,由A组分和B组分组成,A组分和B组分之间的质量比为6-10:1,A组分的质量百分比组成包括:低表面能树脂20-50%,着色颜料1-25%,体质颜料10%-50%,功能性填料10-40%,分散助剂0.1-10%,消泡剂0.05-2%,流平剂0.05-2%,防沉助剂0.05-2%,紫外光吸收剂0.05-5%,催干剂0.05-1%,功能性助剂0.05-10%,溶剂20-60%,B组分为异氰酸酯类固化剂,A组分与B组分的质量比为6-10:1。
上述质量百分数为各原料质量占总原料质量的百分数。
低表面能树脂为四氟乙烯/乙烯基醚共聚物、四氟乙烯/乙烯基酯共聚物、三氟氯乙烯/乙烯基醚共聚物、三氟氯乙烯/乙烯基酯共聚物、有机硅改性氟碳树脂、丙烯酸改性氟碳树脂中的至少一种。漆膜具有较低的表面能,机械性能,耐腐蚀性和耐候性优异。
着色颜料为钛白、炭黑、酞菁蓝、大红粉、中黄、酞菁绿,氧化铬绿中的至少一种。可以构造微纳米表面结构进一步增强漆膜的疏水性能和防粘附性,同时也加强漆膜表面的滑爽性、耐磨性和抗划伤性。
体质填料为滑石粉、云母粉、硫酸钡、高岭土、磷酸锌、多聚磷酸铝、有机膨润土中的至少一种。可以改善漆膜表面外观,片状填料层在漆膜中水平排列并且交叉重叠,产生“迷宫效应”,可以阻缓水分到达基材发生腐蚀,增强防腐性能,片状层填料在漆膜中的水平排列可阻止阻止紫外线的辐射,进一步提高耐候性。
功能性填料为纳米二氧化硅、聚四氟乙烯、纳米碳化硅、纳米氧化铝、石英粉、改性钠离子电解质盐、氧化钙中的至少一种。可以能够提高有机高分子和无机填料的偶联,增强其粘结性,提高漆膜的机械、电气、耐水、抗老化等性能,改善漆膜的疏水性,增加疏冰性能。
分散助剂为BYK-161、BYK-163、EFKA-4010、Solsperse 32500中的至少一种。能够控制和解决絮凝问题,防止研磨时出现的浮色、发花问题,控制纳米材料的絮凝。
消泡剂为EFKA-2022、EFKA-2028、EFKA-2035、EFKA-2040、EFKA-2722、BYK-141、BYK-077、BYK-017中的至少一种。可以控制防覆冰涂料在喷涂、刷涂和辊涂的施工过程中出现的起泡问题,改善施工效果。
流平剂为EFKA-3034、EFKA-3700、EFKA-3886、BYK-300、BYK-331、BBYK-326中的至少一种。
防沉助剂为R-972气相二氧化硅、A-200气相二氧化硅、MT PLUS聚酰胺蜡中的至少一种。
紫外光吸收剂为UVINUL 3035、TINUVINUL 312、TINUVINUL 292、TINUVINUL 1130中的至少一种。
催干剂为二月桂酸二丁基锡、辛酸亚锡中的一种或两种混合物。
功能性助剂为聚二甲基硅氧烷、聚甲基氢硅烷、含羟基官能团的有机硅改性聚丙烯酸酯、氧化硅纳米颗粒分散体、全氟癸基三乙氧基硅烷、3-氨丙基三乙氧基硅烷、丙基三甲氧基硅烷、甲基丙烯酰氧基丙基三甲氧基硅烷中的至少一种。
溶剂为醋酸丁酯、丙二醇甲醚醋酸酯、二甲苯、醋酸乙酯、环己酮中的至少一种。
固化剂为脂肪族异氰酸酯,为HDI三聚体、HDI缩二脲、IPDI三聚体中的至少一种。
本发明的有益效果是:具有较低的着冰力值,剪切位移测试着冰力数值≤30N,人工加速老化后着冰力数值变化不大于15N;具有优异的耐候性,人工加速老化1500h不起泡、不生锈、不脱落、不开裂、不粉化,变色≤2级,失光≤2级;具有优异的防腐蚀性能,1500h耐盐雾试验不起泡、不生锈、不脱落、不开裂,720h耐湿热试验不起泡、不生锈、不脱落、不开裂;具有优异的耐酸碱性,耐5%的H2SO4和5%的NaOH溶液7天不起泡、不生锈、不脱落;具有优异的耐高低温交变特性,-40-80℃交变温度60个周期,漆膜不起泡、不生锈、不开裂、不脱落;具有优异的耐磨性,载荷1000g,1000转磨耗量小于45mg等。
具体实施方式
本发明通过下列成分与实施例进一步加以说明,但非用以限制本发明的范围。
本发明的用于海上油田设备设施的一种防覆冰涂料,由A组分和B组分组成,所述A组分主要由以下质量百分数的原料制成:低表面能树脂20-70%,着色颜料1-50%,体质颜料10%-70%,功能性填料10-40%,分散助剂0.1-10%,消泡剂0.05-2%,流平剂0.05-2%,防沉助剂0.05-2%,紫外光吸收剂0.05-5%,催干剂0.05-1%,功能性助剂0.05-10%,溶剂20-60%,所述B组分为异氰酸酯类固化剂,A组分与B组分的质量比为6-10:1。
上述质量百分数为各原料质量占总原料质量的百分数。
所述低表面能树脂为四氟乙烯/乙烯基醚共聚物、四氟乙烯/乙烯基酯共聚物、三氟氯乙烯/乙烯基醚共聚物、三氟氯乙烯/乙烯基酯共聚物、有机硅改性氟碳树脂、丙烯酸改性氟碳树脂中的至少一种。
所述体质填料为滑石粉、云母粉、硫酸钡、高岭土、磷酸锌、多聚磷酸铝、有机膨润土中的至少一种。
所述功能性填料为纳米二氧化硅、聚四氟乙烯、纳米碳化硅、纳米氧化铝、石英粉、改性钠离子电解质盐、氧化钙中的至少一种。
所述分散助剂为BYK-161、BYK-163、EFKA-4010、Solsperse 32500中的至少一种。
所述消泡剂为EFKA-2022、EFKA-2028、EFKA-2035、EFKA-2040、EFKA-2722、BYK-141、BYK-077、BYK-017中的至少一种。
所述流平剂为EFKA-3034、EFKA-3700、EFKA-3886、BYK-300、BYK-331、BBYK-326中的至少一种。
所述防沉助剂为R-972气相二氧化硅、A-200气相二氧化硅、MT PLUS聚酰胺蜡中的至少一种。
所述紫外光吸收剂为UVINUL 3035、TINUVINUL 312、TINUVINUL 292、TINUVINUL1130中的至少一种。
所述催干剂为二月桂酸二丁基锡、辛酸亚锡中的一种或两种混合物。
所述功能性助剂为聚二甲基硅氧烷、聚甲基氢硅烷、含羟基官能团的有机硅改性聚丙烯酸酯、氧化硅纳米颗粒分散体、全氟癸基三乙氧基硅烷、3-氨丙基三乙氧基硅烷、丙基三甲氧基硅烷、甲基丙烯酰氧基丙基三甲氧基硅烷中的至少一种。
所述溶剂为醋酸丁酯、丙二醇甲醚醋酸酯、二甲苯、醋酸乙酯、环己酮中的至少一种。
所述固化剂为脂肪族异氰酸酯,为HDI三聚体、HDI缩二脲、IPDI三聚体中的至少一种。
实施例及对比例所用原材料除另有说明外均为市售工业用品,可通过商业渠道购得。
本发明还提供了如上述的用于海上油田设备设施的防覆冰涂料的制备方法,具体包括如下步骤:
步骤(1),A组分制备:首先将低表面能树脂、分散助剂、消泡剂和溶剂加入分散罐中,然后以1000~1500转/min分散速度连续分散10~20min,然后加入着色颜料、体质颜料、防沉助剂和功能性填料,以1000~1500转/min连续分散30~40min得到混合体,待分散均匀后将混合体放入砂磨机研磨,研磨至细度为20~30μm,加入流平剂、紫外光吸收剂、催干剂、功能性助剂,然后再次在分散罐中以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分。
步骤(2),B组分制备:将脂肪族异氰酸酯HDI三聚体、HDI缩二脲、IPDI三聚体中的一种直接按重量比称量;或者将脂肪族异氰酸酯HDI三聚体、HDI缩二脲、IPDI三聚体中的二种或三种按一定比例混合,并以1000~1500转/min分散速度连续分散10~20min,使得混合液混合均匀,称量包装即可。
步骤(3),涂料制备:将A组分和B组分按6-10:1比例配制并搅匀。
实施例1
防覆冰涂料包括A组分和B组分,其中A组分的成分按重量如下表:
制备A组分:首先将四氟乙烯/乙烯基醚共聚物树脂、EFKA-4010分散助剂、EFKA-2022消泡助剂、醋酸丁酯、丙二醇甲醚醋酸酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、滑石粉、云母粉、磷酸锌、纳米二氧化硅、聚四氟乙烯、纳米碳化硅、改性钠离子电解质盐、R-972气相二氧化硅,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入EFKA-3700流平助剂、TINUVINUL 292紫外光吸收剂、TINUVINUL 1130紫外光吸收剂、二月桂酸二丁基锡、含羟基官能团的有机硅改性聚丙烯酸脂,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI三聚体;
制备B组分:按重量比称取HDI三聚体作为固化剂;
制备涂层:A组分和B组分之间的质量比为10:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例1涂层技术指标如下表所示:
本实施例的防覆冰涂料产品性能优异,着冰力值达到22N,老化300h后,着冰力值仅上升10N,体现出优异的防覆冰效果。
实施例2
防覆冰涂料包括A组分和B组分,其中A组分的成分按重量如下表:
制备A组分:首先将四氟乙烯/乙烯基酯共聚物树脂、Solsperse 32500分散剂、EFKA-2722消泡助剂、醋酸丁酯、丙二醇甲醚醋酸酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、炭黑、云母粉、高岭土、多聚磷酸铝、纳米氧化铝、聚四氟乙烯、纳米碳化硅、改性钠离子电解质盐、A-200气相二氧化硅,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入BYK-300流平助剂、TINUVINUL 292紫外光吸收剂、TINUVINUL 312紫外光吸收剂、二月桂酸二丁基锡、全氟癸基三乙氧基硅烷、含羟基官能团的有机硅改性聚丙烯酸脂,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI三聚体;
制备B组分:按重量比称取HDI三聚体作为固化剂;
制备涂层:A组分和B组分之间的质量比为10:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例2涂层技术指标如下表所示:
本实施例的防覆冰涂料产品性能优异,着冰力值达到26N,老化300h后,着冰力值仅上升9N,体现出优异的防覆冰效果。
实施例3
防覆冰涂料包括A组分和B组分,其中A组分的成分按重量如下表:
制备A组分:首先将有机硅改性氟碳树脂、BYK-161分散剂、EFKA-2722消泡助剂、醋酸丁酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、炭黑、硫酸钡、云母粉、磷酸锌、纳米二氧化硅、纳米氧化铝、聚四氟乙烯、R-972气相二氧化硅,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入BYK-300流平助剂、TINUVINUL 292紫外光吸收剂、TINUVINUL 312紫外光吸收剂、二月桂酸二丁基锡、全氟癸基三乙氧基硅烷、3-氨丙基三乙氧基硅烷,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI缩二脲;
制备B组分:按重量比称取HDI缩二脲作为固化剂;
制备涂层:A组分和B组分之间的质量比为8:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例3涂层技术指标如下表所示:
本实施例的防覆冰涂料产品性能优异,着冰力值达到29N,老化300h后,着冰力值上升13N,体现出优异的防覆冰效果。
实施例4
防覆冰涂料包括A组分和B组分,其中A组分的成分按重量如下表:
制备A组分:首先将四氟乙烯/乙烯基醚共聚物、丙烯酸改性氟碳树脂、BYK-161分散剂、BYK-077消泡助剂、丙二醇甲醚醋酸酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、云母粉、多聚磷酸铝、纳米碳化硅、纳米氧化铝、聚四氟乙烯、改性钠离子电解质盐、MT PLUS聚酰胺蜡,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入EFKA-4010流平助剂、TINUVINUL 1130紫外光吸收剂、TINUVINUL 312紫外光吸收剂、辛酸亚锡、甲基丙烯酰氧基丙基三甲氧基硅烷、全氟癸基三乙氧基硅烷、含羟基官能团的有机硅改性聚丙烯酸脂,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI三聚体;
制备B组分:按重量比称取HDI三聚体作为固化剂;
制备涂层:A组分和B组分之间的质量比为10:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例4涂层技术指标如下表所示:
本实施例的防覆冰涂料产品性能优异,着冰力值达到28N,老化300h后,着冰力值上升14N,体现出优异的防覆冰效果。
对比例1
防覆冰涂料提供对比例的实施方案,并将涂层性能进行对比,对比例同样有A、B组分组成,其中A组分的成分按重量包括如下表:
制备A组分:首先将羟基丙烯酸树脂、BYK-161分散剂、BYK-077消泡助剂、醋酸丁酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、云母粉、多聚磷酸铝、纳米碳化硅、纳米氧化铝、聚四氟乙烯、改性钠离子电解质盐、MT PLUS聚酰胺蜡,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入EFKA-4010流平助剂、TINUVINUL 1130紫外光吸收剂、TINUVINUL 312紫外光吸收剂、辛酸亚锡、甲基丙烯酰氧基丙基三甲氧基硅烷、全氟癸基三乙氧基硅烷、含羟基官能团的有机硅改性聚丙烯酸脂,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI三聚体;
制备B组分:按重量比称取HDI三聚体作为固化剂;
制备涂层:A组分和B组分之间的质量比为6:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例4涂层技术指标如下表所示:
本对比例与实施例相比,去除了低表面能类树脂,采用的是含羟基的丙烯酸树脂,制备的涂层静态水接触角为85°,滚动角为40°,着冰力42N,老化后着冰力变化值达到35N,要比实施例中的着冰力以及老化后着冰力都要大很多,因此本发明中低表面能树脂在涂层体系中具有重要的作用。
对比例2
防覆冰涂料提供对比例的实施方案,并将涂层性能进行对比,对比例同样有A、B组分组成,其中A组分的成分按重量包括如下表:
制备A组分:首先将四氟乙烯/乙烯基醚共聚物树脂、BYK-161分散剂、BYK-077消泡助剂、醋酸丁酯加入分散罐内,以1000~1500转/min分散速度连续分散10~20min,然后加入钛白粉、云母粉、多聚磷酸铝、纳米碳化硅、纳米氧化铝、聚四氟乙烯、MT PLUS聚酰胺蜡,以1000~1500转/min连续分散20~30min得到混合体,加入砂磨机研磨分散,研磨细度至30-40μm,得到研磨色浆,再在色浆中加入EFKA-4010流平助剂、TINUVINUL 1130紫外光吸收剂、TINUVINUL 312紫外光吸收剂、辛酸亚锡、甲基丙烯酰氧基丙基三甲氧基硅烷、全氟癸基三乙氧基硅烷、含羟基官能团的有机硅改性聚丙烯酸脂,以1000~1500转/min分散速度连续分散15~30min,即得该涂料的A组分;
B组分为脂肪族异氰酸酯,HDI三聚体;
制备B组分:按重量比称取HDI三聚体作为固化剂;
制备涂层:A组分和B组分之间的质量比为8:1,按比例混合A组分B组分,用醋酸丁酯稀释剂将混合液的粘度兑稀到18秒(23±3℃下)。用空气喷涂方法制备防覆冰涂层,涂层测试膜厚在20-60μm之间,实施例4涂层技术指标如下表所示:
本对比例与实施例相比,去除了改性钠离子电解质盐,制备的涂层着冰力48N,老化后着冰力变化值达到33N,要比实施例中的着冰力以及老化后着冰力都要大很多,因此本发明中低表面能树脂在涂层体系中具有重要的作用。
以上述依据本发明的理想实施例为启示,通过上述的说明内容,相关的工作人员完全可以在不偏离本发明的范围内,进行多样的变更以及修改。本项发明的技术范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。
Claims (10)
1.一种用于海上油田设施设备的防覆冰涂料,其特征是:由A组分和B组分组成,所述A组分的质量百分比组成包括:低表面能树脂20-50%,着色颜料1-25%,体质颜料10%-50%,功能性填料10-40%,分散助剂0.1-10%,消泡剂0.05-2%,流平剂0.05-2%,防沉助剂0.05-2%,紫外光吸收剂0.05-5%,催干剂0.05-1%,功能性助剂0.05-10%,溶剂20-60%,所述B组分为异氰酸酯类固化剂,A组分与B组分的质量比为6-10:1。
2.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述低表面能树脂为四氟乙烯/乙烯基醚共聚物、四氟乙烯/乙烯基酯共聚物、三氟氯乙烯/乙烯基醚共聚物、三氟氯乙烯/乙烯基酯共聚物、有机硅改性氟碳树脂、丙烯酸改性氟碳树脂中的至少一种。
3.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述着色颜料为钛白、炭黑、酞菁蓝、大红粉、中黄、酞菁绿,氧化铬绿中的至少一种。
4.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述体质填料为滑石粉、云母粉、硫酸钡、高岭土、磷酸锌、多聚磷酸铝、有机膨润土中的至少一种。
5.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述功能性填料为纳米二氧化硅、聚四氟乙烯、纳米碳化硅、纳米氧化铝、石英粉、改性钠离子电解质盐、氧化钙中的至少一种。
6.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述分散助剂为BYK-161、BYK-163、EFKA-4010、Solsperse 32500中的至少一种。
7.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述消泡剂为EFKA-2022、EFKA-2028、EFKA-2035、EFKA-2040、EFKA-2722、BYK-141、BYK-077、BYK-017中的至少一种。
8.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述流平剂为EFKA-3034、EFKA-3700、EFKA-3886、BYK-300、BYK-331、BBYK-326中的至少一种。
9.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述功能性助剂为聚二甲基硅氧烷、聚甲基氢硅烷、含羟基官能团的有机硅改性聚丙烯酸酯、氧化硅纳米颗粒分散体、全氟癸基三乙氧基硅烷、3-氨丙基三乙氧基硅烷、丙基三甲氧基硅烷、甲基丙烯酰氧基丙基三甲氧基硅烷中的至少一种。
10.根据权利要求1所述一种用于海上油田设施设备的防覆冰涂料,其特征是:所述固化剂为脂肪族异氰酸酯,为HDI三聚体、HDI缩二脲、IPDI三聚体中的至少一种。
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