CN116710058A - Mascara cosmetics - Google Patents

Mascara cosmetics Download PDF

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Publication number
CN116710058A
CN116710058A CN202280008148.2A CN202280008148A CN116710058A CN 116710058 A CN116710058 A CN 116710058A CN 202280008148 A CN202280008148 A CN 202280008148A CN 116710058 A CN116710058 A CN 116710058A
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China
Prior art keywords
mascara
mass
cosmetic
oil
carbamoyl
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Inventor
中田博子
村冈奈绪美
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Shiseido Co Ltd
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Shiseido Co Ltd
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Publication of CN116710058A publication Critical patent/CN116710058A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

Disclosed is a mascara composition which has excellent handleability without stringiness, and which can make eyelashes look long and has excellent curling effects even without stringiness. [ solution ] A mascara cosmetic comprising: (A) trimethylsilyl carbamoyl amylopectin, (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane and (C) fibers.

Description

Mascara cosmetics
Technical Field
The present invention relates to a mascara cosmetic having no stringiness.
Background
Mascara cosmetics can provide makeup effects such as making eyes stand out, and various raw materials are being studied for various effects such as curling, curling and shaping eyelashes, thickening and lengthening eyelashes, and the like.
For example, patent documents 1 to 4 describe mascara cosmetics that have an effect of making eyelashes look long by blending an oil-soluble resin and a fiber. In addition, patent document 5 describes a water-in-oil type mascara composition containing a small candle resin and a high-polymer polyethylene glycol, and the stringiness effect of the high-polymer polyethylene glycol on eyelashes is maintained by the small candle resin, so that the stringiness effect can be maintained for a long time while maintaining the water-proof effect.
In addition, patent document 6 describes that by combining a silicone-modified polysaccharide compound and an acrylic acid-silicone graft copolymer, good stringiness can be imparted to a cosmetic composition, and curling feel at the time of application to eyelashes can be improved. Further, patent document 7 describes a mascara cosmetic comprising a dextrin fatty acid ester, an organically modified clay mineral, a plurality of fibers having different lengths, an organic siliconized polysaccharide compound, and the like, which is excellent in effect (growth effect) of making eyelashes look long and is excellent in incidental liquid.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open No. 2002-154932
Patent document 2: japanese patent application laid-open No. 2004-300096
Patent document 3: japanese patent No. 4064874
Patent document 4: japanese patent laid-open No. 2020-55804
Patent document 5: japanese patent laid-open No. 2008-231069
Patent document 6: japanese patent laid-open No. 2017-1983
Patent document 7: japanese patent No. 5606671
Disclosure of Invention
Problems to be solved by the invention
In order to make eyelashes look long, it is not enough to fit long fibers only in a mascara cosmetic, and it is also necessary that the fit long fibers adhere reliably to the eyelashes. The organic siliconized polysaccharide compound described in patent document 7 is a compound having an effect of improving adhesion to eyelashes, and when long fibers are blended, adhesion to eyelashes is considered to be improved. However, on the other hand, the organic siliconized polysaccharide compound is a compound having stringiness, and the mascara with stringiness is attractive by making eyelashes look long, and has an effect of making eyes noticeable, while on the other hand, in order to pull out the wires, the periphery is stained when the mascara container is used, and there is a case where it is difficult to apply the lashes, and therefore, as one of the options for purchasing products, a mascara cosmetic having non-stringiness is demanded.
As a result of intensive studies, the present inventors have found that, among organosilicon polysaccharide compounds, particularly useful trimethylsilyl-alkoxysilyl-carbamoyl pullulan is combined with a specific resin, whereby long fibers can be reliably attached to eyelashes despite no stringiness, and have completed the present invention.
That is, the present invention has been made in view of the above circumstances, and an object thereof is to provide a mascara composition which is excellent in handleability due to no stringiness, and which can make eyelashes look long and has an excellent curling effect even though there is no stringiness.
Solution for solving the problem
The mascara cosmetic of the present invention comprises:
(A) Trimethylsilyl carbamoyl amylopectin,
(B) Polymethylsilsesquioxane and/or polypropylsilsesquioxane, and
(C) And (3) fibers.
(A) The trimethylsilyl-oxy-carbamoyl-amylopectin is preferably less than 3% by mass relative to the total amount of the cosmetic.
(A) The total amount of trimethylsilyl carbamoyl amylopectin to be blended with (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane is preferably 0.5 to 15% by mass relative to the total amount of the cosmetic.
(A) The mass ratio of trimethylsilyl carbamoyl amylopectin to (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane is preferably 0.01 to 3.
The fibers (C) preferably have a length of 2 to 4mm and contain 50 mass% or more of fibers having a length of 3mm or more relative to the total amount of the fibers.
The mascara cosmetic of the present invention preferably further comprises (D) trimethylsiloxysilicate.
The amount of the total amount of the coating agent to be blended is preferably 2.5% by mass or more relative to the total amount of the cosmetic.
ADVANTAGEOUS EFFECTS OF INVENTION
The mascara cosmetic of the present invention comprises:
(A) Trimethylsilyl carbamoyl amylopectin,
(B) Polymethylsilsesquioxane and/or polypropylsilsesquioxane, and
(C) The fiber is used as a fiber-optic material,
can be made into cosmetics which have good handleability due to no stringiness, and can make eyelashes look long and have good curling effect even though no stringiness is present.
Detailed Description
The mascara cosmetic of the present invention comprises:
(A) Trimethylsilyl carbamoyl amylopectin,
(B) Polymethylsilsesquioxane and/or polypropylsilsesquioxane, and
(C) And (3) fibers.
The components will be described below. The components may be referred to as "component (a)", component (B) ", and the like.
In the present specification, PEG is abbreviated as polyethylene glycol, and BG is abbreviated as butanediol.
(A) Trimethylsilyl carbamoyl amylopectin
The trimethylsilyl-alkoxysilyl-carbamoyl amylopectin (A) contained in the mascara cosmetic of the present invention can be produced by a known method (for example, japanese patent application laid-open No. 10-29910).
Examples of the commercial products include TSPL-30-ID (trimethylsilyl carbamoyl amylopectin, 30% isododecane solution manufactured by Xinyue chemical industry Co., ltd.), and TSPL-30-D5 (trimethylsilyl carbamoyl amylopectin, 30% decamethyl cyclopentasiloxane solution manufactured by Xinyue chemical industry Co., ltd.).
(A) The blending amount of trimethylsilyl carbamoyl pullulan is preferably less than 0.03 to 3% by mass, more preferably 0.1 to 2.8% by mass, still more preferably 0.15 to 2.4% by mass, relative to the total amount of the cosmetic. (A) When the blending amount of trimethylsilyl-carbamoyl-pullulan is 0.03 mass% or more, the cosmetic can be more easily entangled on eyelashes, and when it is less than 3 mass%, stringiness can be further suppressed, and a mascara cosmetic excellent in handling property can be obtained.
(B) Polymethylsilsesquioxane and/or polypropylsilsesquioxane
The mascara cosmetic of the present invention comprises (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane. (B) Either one of polymethylsilsesquioxane and polypropylsilsesquioxane may be used as the component, or both may be used.
Polymethylsilsesquioxane and polypropylsilsesquioxane have the formula R 1 SiO 1.5 Units and R 2 SiO 0.5 Unit (wherein R 1 、R 2 Represents a substituted or unsubstituted 1-valent hydrocarbon group).
As a commercially available product of polymethylsilsesquioxane, SILFORM FLEXIBLE RESIN (manufactured by Momentive Performance Materials Co.) is mentioned. As a commercially available product of the polysilsesquioxane, DOWSIL TM670 Fluid (Dow Corning Toray Co., ltd., a 50% solution of polypropylene silsesquioxane in cyclopentasiloxane) is exemplified.
(B) The amount of the component(s) to be blended is preferably 0.1 to 12% by mass, more preferably 0.5 to 11% by mass, and still more preferably 0.8 to 10.5% by mass, based on the total amount of the cosmetic. (B) When the amount of the component is 0.1% by mass or more, eyelashes can be made longer (growth effect), and when it is 12% by mass or less, not only fibers can be more cleanly attached, but also a mascara composition which is not sticky after drying and has good makeup holding can be produced.
(A) The total amount of the trimethylsilyl-carbamoyl amylopectin and the component (B) to be blended is preferably 0.5 to 15% by mass, more preferably 1.0 to 13.5% by mass, still more preferably 1.3 to 12.4% by mass, relative to the total amount of the cosmetic. (A) The total amount of the trimethylsilyl-alkoxysilyl-carbamoyl-pullulan and the component (B) is 0.5 mass% or more relative to the total amount of the cosmetics, whereby the cosmetics can be more easily entangled on eyelashes and a more excellent curling effect can be obtained, and the cosmetic can be applied smoothly to the eyelashes and further can be suppressed in stringiness to provide a mascara with excellent handling property by 15 mass% or less.
(A) The mass ratio of trimethylsilyl carbamoyl amylopectin to the component (B) is preferably 0.01 to 3, more preferably 0.05 to 2, and still more preferably 0.1 to 1. (A) When the mass ratio of trimethylsilyl-carbamoyl-amylopectin to component (B) is 0.01 or more, the cosmetic can be more easily entangled on eyelashes and a curl effect can be further improved, and when it is 3 or less, stringiness can be further suppressed and a mascara cosmetic excellent in handling property can be obtained.
(C) Fiber
The fibers used in the mascara composition of the present invention include various fibers known in the art, for example, synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, and semisynthetic fibers such as acetate rayon.
In addition, the fibers can be subjected to further various surface treatments. Examples of the water repellent surface treatment include polymethylhydrosiloxane treatment, silicone resin treatment, silicone rubber treatment, silicone acrylate treatment, silicone treatment such as fluorinated silicone treatment, metal soap treatment such as zinc stearate treatment, silane treatment such as silane coupling agent treatment and alkylsilane treatment, organotitanate treatment, organic aluminate treatment, perfluoroalkyl silane, perfluoroalkyl phosphate salt, fluorine compound treatment such as perfluoropolyether treatment, amino acid treatment such as N-lauroyl-L-lysine treatment, oil treatment such as squalane treatment, acrylic acid treatment such as alkyl acrylate treatment, and the like, and 1 or more of these may be used in combination.
Examples of the hydrophilization surface treatment include agar treatment, deoxyribonucleic acid treatment, lecithin treatment, polyacrylic acid treatment, silica treatment, alumina treatment, and zirconia treatment.
The length of the fibers is preferably in the range of 2 to 4mm, and the fibers having a length of 3mm or more are contained in an amount of 50 mass% or more relative to the total amount of the fibers. By including such fibers, eyelashes can be made to look longer. Since the mascara composition of the present invention contains (a) trimethylsilyloxy-silylcarbamoyl pullulan and (B), it is possible to reliably adhere long fibers to eyelashes, and it is also possible to suppress fiber shedding with time and make eyelashes look longer.
Examples of the fibers used in the present invention include NFCB-10D-2R (nylon fiber 2mm, manufactured by Daidon chemical industry Co., ltd.), NFCB-17D-3R (nylon fiber 3mm, manufactured by Daidon chemical industry Co., ltd.), blackfiber R (3 mm/19T) (manufactured by Daidon chemical industry Co., ltd.), blackfiber R (4 mm/11T) (manufactured by Daidon chemical industry Co., ltd.), and these may be used singly or in combination of at least 2 kinds.
(D) Trimethylsiloxysilicate
The mascara cosmetic of the present invention preferably further comprises (D) trimethylsiloxysilicate. (D) The weight average molecular weight of the trimethylsiloxysilicate is preferably 3000 or more. The weight average molecular weight of 3000 or more can further provide a makeup-retaining effect on eyelashes.
The weight average molecular weight is a polystyrene equivalent based on gel permeation chromatography.
The (D) trimethylsiloxysilicate can be produced by a known method.
Examples of the commercial products include X-21-5250L (made by the chemical industry Co., ltd., 50% polydimethylsiloxane solution), X-21-5616 (made by the chemical industry Co., ltd., 60% isododecane solution), X-21-5249 (made by the chemical industry Co., ltd., 50% decamethylcyclopentasiloxane solution), X-21-5249L (made by the chemical industry Co., ltd., 50% polydimethylsiloxane solution), KF-7312 (made by the chemical industry Co., ltd., 50% decamethylcyclopentasiloxane solution), KF-7312K (made by the chemical industry Co., ltd., 50% polydimethylsiloxane solution), KF-7312T (made by the chemical industry Co., ltd., 60% methylpolytrimethyl siloxane solution), X-21-5595 (made by the chemical industry Co., 60% isododecane solution), KF-9021 (made by the chemical industry Co., ltd., 50% polydimethylsiloxane solution), KF-9021 (made by the chemical industry Co., 50% polydimethylsiloxane solution, KF-7312K (made by the chemical industry Co., ltd., 50% polydimethylsiloxane solution), KF-1600% polydimethylsiloxane solution (made by the chemical industry Co., ltd., 35% polydimethylsiloxane solution), KF-7312L (made by the chemical industry Co., 35% polydimethylsiloxane solution, and the chemical industry Co., 90% polydimethylsiloxane solution, KF-101% by the chemical industry Co., LTD., 100% polydimethylsiloxane solution).
(D) The blending amount of the trimethylsiloxysilicate is preferably 0.1 to 18% by mass, more preferably 0.2 to 15% by mass, still more preferably 0.3 to 12% by mass, relative to the total amount of the cosmetic. (D) The blending amount of trimethylsiloxysilicate is 0.1% by mass or more, whereby the effect of curling eyelashes is more excellent, and 18% by mass or less, whereby eyelashes can be more uniformly coated.
The mascara composition of the present invention may contain, in addition to the component (a) and the component (B) as essential components, the component (D) and a coating agent other than these, and the total amount of the coating agent is preferably 2.5% by mass or more relative to the total amount of the composition. When the amount of the total amount of the coating agent to be blended is 2.5% by mass or more relative to the total amount of the cosmetic, the cosmetic can be more easily entangled on the eyelashes and the eyelashes can be made longer.
In the mascara composition of the present invention, wax, volatile oil, nonvolatile oil, and powder may be used in addition to the essential components. The coating agent may be blended in a form other than the above-mentioned component (A), component (B) and component (D).
Examples of the wax include hydrocarbon waxes such as paraffin wax, ceresin wax, microcrystalline wax, and polyethylene wax, solid oils and fats such as wood wax and hydrogenated castor oil, beeswax, candelilla wax (Candelilla wax), palm wax, cotton wax, montan wax, bran wax, and jojoba wax, and animal and plant waxes such as silicone wax and sucrose fatty acid ester. These waxes may be used in an amount of 1 or 2 or more. Among them, polyethylene wax, microcrystalline wax and sucrose fatty acid ester are particularly preferable.
Examples of the coating agent other than the component (a), the component (B) and the component (D) include silicone resins such as acrylic acid (ester)/polydimethylsiloxane copolymer, dextrin isostearate, fluorine-modified silicone, and acrylic silicone, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, waxes of polyalkyl acetate, dextrin, alkyl cellulose, and cellulose derivatives such as nitrocellulose.
Examples of the volatile oil include cyclic silicones, volatile linear silicones, light isoparaffins, methylene chloride, fluorocarbons, hexane, cyclohexane, ethers, toluene, xylenes, acetone, benzene, terpenes, water, and the like, and among these, cyclic silicones, volatile linear silicones, light isoparaffins are particularly preferable. Examples of the light isoparaffin include ISOPAR H (manufactured by Exxon Mobil corporation).
The amount of volatile oil to be blended is preferably 10 to 60% by mass, particularly preferably 30 to 40% by mass.
Examples of the nonvolatile oil include liquid oils such as avocado oil, camellia seed oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg oil, sesame oil, peach kernel oil, wheat germ oil, camellia oil, castor oil, linseed oil, safflower oil, cotton seed oil, perilla oil, soybean oil, peanut oil, tea seed oil, torreya oil, rice bran oil, paulownia oil, japan tung oil, jojoba oil, germ oil, triglycerin, triisoglyceryl palmitate, hydrogenated polyisobutene, liquid paraffin, squalene, squalane, hydrocarbon oils such as pristane, oleic acid, tall oil, higher alcohols such as isostearic acid, lauryl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol and the like, organosilyl esters such as polydimethylsiloxane, laurate, oleyl ester, decyl oleate, dodecyl myristate, dimethyl myristate, diethyl phthalate, polyoxyethylene fatty acid ester, sucrose fatty acid ester, polyoxyethylene fatty acid ester, and the like.
Further, in order to impart a moisturizing effect or the like to the formulation, the mascara composition of the present invention may contain water, glycerin, propylene glycol, dipropylene glycol, 1, 3-butanediol, polyethylene glycol, 1, 2-hexanediol, hexylene glycol, ethylhexyl glycerin, 1, 3-butanediol, ethanol, methanol, propanol, isopropanol, butanol, and other components blended in usual cosmetics such as an alkaline substance, a perfume, a preservative, a cosmetic agent, and a thickener.
The mascara cosmetic of the present invention is preferably solid, paste or powder, and is liquid in a viscosity range having a degree of stable pigment dispersion.
The formulation of the mascara cosmetic of the present invention is not particularly limited, but is preferably an oily cosmetic.
Examples
The present invention will be described in further detail with reference to examples, but the present invention is not limited to these examples. The amount to be blended in the following examples is represented by mass% unless otherwise specified.
Mascara cosmetics having compositions shown in the following tables 1 to 3 were prepared by a conventional method and evaluated according to the following criteria.
(growth effect)
10 panelists were allowed to use the prepared mascara cosmetics and evaluated according to the following criteria.
< evaluation criterion >
AA:9 or more were evaluated as having an increasing effect
A:7 to 8 persons were evaluated as having an increasing effect
B:6 persons were evaluated as having an increasing effect
C:4 to 5 persons were evaluated as having an increasing effect
D: the following 3 persons were evaluated as having an increasing effect
(operability (presence or absence of stringiness))
10 panelists were allowed to use the prepared mascara cosmetics and evaluated according to the following criteria.
< evaluation criterion >
AA:9 or more were evaluated as good operability
A:7 to 8 persons evaluated good operability
B:6 persons rated good operability
C:4 to 5 persons evaluated good operability
D: the following 3 persons evaluate the operability as good
(curling effect)
10 panelists were allowed to use the prepared mascara cosmetics and evaluated according to the following criteria.
< evaluation criterion >
AA: more than 9 persons were evaluated as having a curling effect
A:7 to 8 persons were evaluated as having a curling effect
B:6 persons rated a curling effect
C:4 to 5 persons were evaluated as having a curling effect
D: the curling effect was evaluated by 3 persons
The product names of the raw materials in the table are as follows.
Polymethylsilsesquioxane: SILFORM FLEXIBLE RESIN (Momentive Performance Materials company)
Polytrimethylsilsesquioxane: DOWSIL TM670 Fluid (Dow Corning Toray Co., ltd. Polypropylene silsesquioxane 50% cyclopentasiloxane solution) trimethylsilyl carbamoyl amylopectin: TSPL-30-ID (30% isododecane solution of trimethylsilyl carbamoyl amylopectin, manufactured by Xinyue chemical industry Co., ltd.)
Trimethylsilyloxy silicate: x-21-5249 (60% isododecane solution, made by Xinyue chemical industry Co., ltd.)
Fiber (4 mm): black fiber R (4 mm/11T) (manufactured by Dadong chemical industry Co., ltd.)
Fiber (3 mm): black fiber R (3 mm/19T) (manufactured by Dadong chemical industry Co., ltd.)
Fiber (2 mm): black fiber R (2 mm/11T) (manufactured by Dadong chemical industry Co., ltd.)
Fiber (2 mm): black fiber R (2 mm/11T) (manufactured by Dadong chemical industry Co., ltd.) [ Table 1]
TABLE 2
TABLE 3
As shown in table 1, examples 1 to 3, in which the fiber length was changed to 2 to 4mm, all obtained a growth effect, a curling effect, and good handleability. In addition, examples 4 to 9 in which the total amount of the components (A) and (B) was changed also gave an increase effect and good handleability. Examples 10 and 11, in which the polypropylene silsesquioxane was blended as the component (B), also gave a good growth effect and good handleability. Table 2 shows an example in which the blending amount of the component (B) (polymethylsilsesquioxane) was changed by changing the blending amount of the component (a) trimethylsilyl carbamoyl amylopectin and the component (D) trimethylsilyloxy silicate while keeping the blending amount at 1 mass%, and in this case, the effect of growth, curling effect, and handleability were also obtained.
Comparative examples 1 to 3 in Table 3 are examples not containing (A) trimethylsilyloxy silylcarbamoyl amylopectin, comparative examples 4 to 8 are examples not containing (B) component, and comparative example 9 is an example not containing fiber, and although they are all good in handleability, no growth effect can be obtained. In addition, comparative examples 10 to 15 are examples in which (a) trimethylsilyloxy silylcarbamoyl pullulan was not contained nor (B) component (examples of oil-in-water type in which a cross-linked polymer of dimethylacrylamide/sodium acryloyldimethyl taurate was blended as a thickener), and in this case, the effect of extension and the handleability were both good, but the curling effect could not be obtained.

Claims (7)

1. A mascara cosmetic comprising:
(A) Trimethylsilyl carbamoyl amylopectin,
(B) Polymethylsilsesquioxane and/or polypropylsilsesquioxane, and
(C) And (3) fibers.
2. The mascara cosmetic according to claim 1, wherein (a) the trimethylsilyloxy silylcarbamoyl amylopectin is less than 3% by mass relative to the total amount of the cosmetic.
3. The mascara cosmetic according to claim 1 or 2, wherein the total blending amount of (a) trimethylsilyloxy carbamoyl amylopectin and (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane is 0.5 to 15 mass% with respect to the total amount of the cosmetic.
4. A mascara cosmetic according to claim 1,2, or 3, wherein the mass ratio of (a) trimethylsilyloxy carbamoyl amylopectin to (B) polymethylsilsesquioxane and/or polypropylsilsesquioxane is 0.01 to 3.
5. The mascara cosmetic according to any one of claims 1 to 4, wherein the length of the (C) fiber is 2 to 4mm, and 50 mass% or more of the fiber having a length of 3mm or more is contained with respect to the total amount of the fibers.
6. The mascara cosmetic according to any one of claims 1 to 5, further comprising (D) trimethylsiloxysilicate.
7. The mascara cosmetic according to any one of claims 1 to 6, wherein the amount of the total amount of the coating agent to the total amount of the cosmetic is 2.5% by mass or more.
CN202280008148.2A 2021-01-14 2022-01-12 Mascara cosmetics Pending CN116710058A (en)

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JP2021004351 2021-01-14
JP2021-004351 2021-01-14
PCT/JP2022/000750 WO2022154013A1 (en) 2021-01-14 2022-01-12 Mascara cosmetic

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JP5777213B2 (en) * 2011-10-04 2015-09-09 株式会社 資生堂 Eyelash cosmetics
JP6024587B2 (en) * 2013-05-13 2016-11-16 信越化学工業株式会社 Oily cosmetics

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