CN116693197A - Matte anti-slip Yi Jiechao wear-resistant diamond glaze, ceramic tile and preparation method thereof - Google Patents
Matte anti-slip Yi Jiechao wear-resistant diamond glaze, ceramic tile and preparation method thereof Download PDFInfo
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- CN116693197A CN116693197A CN202310717932.7A CN202310717932A CN116693197A CN 116693197 A CN116693197 A CN 116693197A CN 202310717932 A CN202310717932 A CN 202310717932A CN 116693197 A CN116693197 A CN 116693197A
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- glaze
- wear
- jiechao
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- 239000010432 diamond Substances 0.000 title claims abstract description 78
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 78
- 239000000919 ceramic Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract description 15
- 239000013078 crystal Substances 0.000 claims abstract description 84
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 67
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 60
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 50
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000010304 firing Methods 0.000 claims abstract description 38
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 23
- 239000004110 Zinc silicate Substances 0.000 claims abstract description 19
- 229910052916 barium silicate Inorganic materials 0.000 claims abstract description 19
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 claims abstract description 19
- 235000019352 zinc silicate Nutrition 0.000 claims abstract description 19
- XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 14
- 230000001681 protective effect Effects 0.000 claims description 43
- 239000000126 substance Substances 0.000 claims description 43
- 239000002002 slurry Substances 0.000 claims description 35
- 239000002994 raw material Substances 0.000 claims description 33
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 16
- 239000004576 sand Substances 0.000 claims description 16
- 229910052845 zircon Inorganic materials 0.000 claims description 16
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000007641 inkjet printing Methods 0.000 claims description 10
- 239000010453 quartz Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 34
- 239000004575 stone Substances 0.000 abstract description 22
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 2
- 230000006870 function Effects 0.000 abstract description 2
- 230000003670 easy-to-clean Effects 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 76
- 239000011734 sodium Substances 0.000 description 45
- 239000000395 magnesium oxide Substances 0.000 description 38
- 239000000203 mixture Substances 0.000 description 20
- 239000002245 particle Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000011521 glass Substances 0.000 description 17
- 238000002156 mixing Methods 0.000 description 12
- 238000000498 ball milling Methods 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 10
- 238000002834 transmittance Methods 0.000 description 10
- 230000003373 anti-fouling effect Effects 0.000 description 8
- 230000006872 improvement Effects 0.000 description 8
- 238000007639 printing Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 238000005245 sintering Methods 0.000 description 7
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 6
- 238000011161 development Methods 0.000 description 6
- 239000010459 dolomite Substances 0.000 description 6
- 229910000514 dolomite Inorganic materials 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 238000007650 screen-printing Methods 0.000 description 6
- 239000000454 talc Substances 0.000 description 6
- 235000012222 talc Nutrition 0.000 description 6
- 229910052623 talc Inorganic materials 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 229910052656 albite Inorganic materials 0.000 description 5
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 229910052863 mullite Inorganic materials 0.000 description 3
- 239000011667 zinc carbonate Substances 0.000 description 3
- 235000004416 zinc carbonate Nutrition 0.000 description 3
- 229910000010 zinc carbonate Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N Oxozirconium Chemical compound [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 230000016776 visual perception Effects 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 1
- 239000010424 alunite Substances 0.000 description 1
- 229910052934 alunite Inorganic materials 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- 229910001422 barium ion Inorganic materials 0.000 description 1
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 description 1
- IYIWLMDFTXXNAA-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane;zirconium(4+) Chemical compound [Zr+4].[Ba+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IYIWLMDFTXXNAA-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 210000004127 vitreous body Anatomy 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- RCFBAMFJCITZIC-UHFFFAOYSA-N zinc;dioxido(oxo)silane;zirconium(4+) Chemical compound [Zn+2].[Zr+4].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O RCFBAMFJCITZIC-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to the field of building ceramic materials, and particularly discloses a matte anti-slip Yi Jiechao wear-resistant diamond glaze, a ceramic tile and a preparation method thereof. Matte anti-slip Yi Jiechao wear-resistant diamond glaze comprises: siO (SiO) 2 57％‑70％，Al 2 O 3 4％‑10％，K 2 O+Na 2 O＝1％‑4％，CaO+MgO+ZnO+BaO＝15％‑35％，ZrO 2 1.5％‑4.5％，Fe 2 O 3 +TiO 2 =0.05% -0.55%, (cao+mgo)/(zno+bao) =1.5-2.5, loi 0.5% -3%; and the obtained glaze layer after firing contains cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains. The invention can improve the hardness of the glaze, the wear resistance and the antiskid and easy-to-clean functions of the glaze,in addition, the decorative effect similar to stone light can be given to the glaze.
Description
Technical Field
The invention relates to the technical field of building ceramic materials, in particular to a matte anti-slip Yi Jiechao wear-resistant diamond glaze, a ceramic tile and a preparation method thereof.
Background
With the improvement of the living standard of people, higher requirements are put on the functionality of the ceramic tile. One of the main decorative requirements is to mimic the decorative effect of natural stone. Natural stone is typically a mixture of heterogeneous crystals, for example marble stone is typically a mixture of calcite (calcium carbonate), serpentine (magnesium-containing silicate), dolomite (calcium magnesium carbonate). Therefore, after marble polishing, some gaps are generated at different crystal joints, so that the gloss presents a gradual, fine and three-dimensional feel, which is called "stone light" in the decoration industry. However, it is difficult for a common tile to produce such a gradual gloss, stereoscopic visual effect, and a solution commonly used in the industry is to use engraving ink to form the stereoscopic effect. For example, chinese patent CN115677220a proposes printing with engraving ink and sinking ink on the base coat, so as to form a recessed texture with a greater depth, thereby introducing a stereoscopic impression and a layering impression. Although recessed textures can be formed by adopting the engraving ink, the engraving ink also causes the later glaze to have certain concave-convex degree, the light scattering is enhanced, and the stone-like light visual perception is difficult to form. To solve this problem, a conventional proposal is to greatly improve the light transmittance of the overglaze, for example, a dry granular glaze with high transparency is adopted in the above patent. However, the dry granular glaze mainly comprises a glass body, which necessarily means that harder crystals (such as mullite and the like) in the overglaze layer are reduced, the glaze hardness is reduced, and the wear resistance is greatly reduced.
On the other hand, with respect to the function of the wear resistance of the ceramic tile, the prior art CN114772933B discloses a nano soft super wear-resistant diamond glaze, ceramic tile and a preparation method thereof, wherein zirconia grains, zirconium silicate grains and zirconium-containing silicate M grains are introduced into the diamond glaze, so that the diamond glaze has the advantages of high hardness, high wear resistance and high transparency. However, when the glaze is used for a brick surface with micro concave-convex, the scattering effect is strong, the transmission effect is weakened, and the visual perception similar to stone light is difficult to be generated by a user.
Disclosure of Invention
The technical problem to be solved by the invention is to provide the matte anti-skid Yi Jiechao wear-resistant diamond glaze which has high hardness, good wear resistance, skid resistance and easy cleaning, and can realize gradual and hierarchical decorative effects similar to stone.
The invention also aims to solve the technical problem of providing the matte anti-slip Yi Jiechao wear-resistant ceramic tile and the preparation method thereof, wherein the ceramic tile has high hardness, good wear resistance and stone-like decorative effect.
In order to achieve the technical effects, the invention provides a matte anti-slip Yi Jiechao wear-resistant diamond glaze, which comprises the following chemical components in percentage by weight:
SiO 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 =0.05% -0.55%, (cao+mgo)/(zno+bao) =1.5-2.5; the loss on ignition is 0.5% -3%;
and cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains coexist in the glaze layer obtained after the matte anti-slip Yi Jiechao wear-resistant diamond glaze is sintered.
As an improvement of the technical proposal, al 2 O 3 /(K 2 O+Na 2 O)＝2-4。
As an improvement of the technical scheme, the matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
60-75 parts of zirconium-containing frit, 0.1-2 parts of zircon sand powder, 0.1-5 parts of zirconia, 8-13 parts of kaolin, 15-22 parts of quartz and 0.1-5 parts of auxiliary agent;
the zirconium-containing frit comprises the following chemical components in percentage by weight: siO (SiO) 2 48％-60％，Al 2 O 3 4％-15％，CaO+MgO+ZnO+BaO＝25％-40％，K 2 O+Na 2 O＝3％-8％，ZrO 2 3.5％-5.5％。
As an improvement of the technical scheme, the grain size of the cristobalite grains is 50-200 nanometers, the grain size of the nano zirconia grains is 100-900 nanometers, the grain size of the zirconium silicate grains is 1-5 micrometers, the grain size of the zirconium-containing barium silicate grains is 1-10 micrometers, and the grain size of the zirconium-containing zinc silicate grains is 1-10 micrometers.
As improvement of the technical scheme, the wear resistance of the glaze layer obtained after the matte anti-skid Yi Jiechao wear-resistant diamond glaze is sintered is more than or equal to 8000 turns, and the Mohs hardness is more than or equal to 7.
Correspondingly, the invention also discloses a matte anti-skid Yi Jiechao wear-resistant ceramic tile which comprises a blank body and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer arranged on the blank body, wherein the matte anti-skid Yi Jiechao wear-resistant diamond glaze layer is made of the matte anti-skid Yi Jiechao wear-resistant diamond glaze.
As an improvement of the technical scheme, a ground coat layer, an ink-jet printing layer, a protective glaze layer, an engraving layer and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer are sequentially arranged on the green body;
wherein the protective glaze layer is made of protective glaze;
the protective glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 50％-60％，Al 2 O 3 11％-18％，K 2 O+Na 2 O=1-3%, cao+mgo+zno+sro+bao=15-30%, loss on ignition 1-5%; wherein SiO is 2 /Al 2 O 3 ＝3.0-3.5。
Correspondingly, the invention also discloses a preparation method of the matte anti-skid Yi Jiechao wear-resistant ceramic tile, which is used for preparing the matte anti-skid Yi Jiechao wear-resistant ceramic tile and comprises the following steps:
(1) Preparing the slurry of the matte anti-slip Yi Jiechao wear-resistant diamond glaze;
(2) Providing a green body, applying the slurry on the green body, drying and firing.
As an improvement of the technical scheme, in the step (2), under-glaze, ink-jet printing, protective glaze, engraving ink and slurry of matte anti-skid Yi Jiechao wear-resistant diamond glaze are sequentially applied to the green body;
wherein the application amount of the ground coat is 200g/m 2 -400g/m 2 The application amount of the glaze slip of the protective glaze is 80g/m 2 -260g/m 2 The application amount of the engraving ink is 20g/m 2 -100g/m 2 The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 200g/m 2 -400g/m 2 。
As an improvement of the technical scheme, in the step (2), the sintering temperature is 1180-1250 ℃, the sintering period is 50-100 minutes, and the heat preservation is carried out for 5-30 minutes at the sintering temperature.
The implementation of the invention has the following beneficial effects:
1. the invention discloses a matte anti-skid Yi Jiechao wear-resistant diamond glaze which comprises the following chemical components in percentage by weight: siO (SiO) 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 =0.05% -0.55%, (cao+mgo)/(zno+bao) =1.5-2.5; the loss on ignition is 0.5% -3%. Based on the chemical components, cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains are commonly formed in the glaze layer obtained after firing, and Al mainly exists in a glass body, so that the light transmission performance of the glaze layer is greatly optimized, the light can still be well transmitted under the condition that a micro concave-convex structure exists, and further the gradual three-dimensional decorative effect similar to stone light is formed. Meanwhile, due to the existence of the crystals, the glaze layer has the advantages of high hardness, high wear resistance, skid resistance and easy cleaning.
2. According to the matte anti-skid Yi Jiechao wear-resistant ceramic tile, a protective glaze layer is arranged after ink-jet printing, and the protective glaze layer is made of protective glaze; the protective glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 50％-60％，Al 2 O 3 11％-18％，K 2 O+Na 2 O=1-3%, cao+mgo+zno+sro+bao=15-30%, loss on ignition 1-5%; wherein SiO is 2 /Al 2 O 3 =3.0-3.5. The protective glaze based on the chemical components can effectively promote the color development of the inkjet printing, and further form better stereoscopic effect after the refined carving ink is applied in the later stage. In addition, the protective glaze layer can be matched with the matte anti-skid Yi Jiechao wear-resistant diamond glaze layer, so that gradual layering sense is optimized, and the decorative effect of stone light is improved.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the following detailed description.
In the conventional stone-like bricks, in order to enhance the decorative effect of stone-like light, a high-light-transmittance overglaze is often used. However, high light transmittance often means that the glass body is increased, the content of crystalline phase is reduced, the hardness of the glaze is greatly reduced, and the wear resistance is greatly reduced. The technical scheme is further deepened on the basis of the applicant's preamble research, and creatively provides the glaze which can keep high light transmittance on the concave-convex structure, high wear resistance and skid resistance and easy cleaning. The specific steps are as follows:
the invention provides a matte anti-slip Yi Jiechao wear-resistant diamond glaze which comprises the following chemical components in percentage by weight: siO (SiO) 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 =0.05% -0.55%, (cao+mgo)/(zno+bao) =1.5-2.5; loss On Ignition (LOI) is 0.5% -3%.
Based on the chemical components, cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains are commonly formed in the glaze layer obtained after firing, and Al mainly exists in a glass body, so that the light transmission performance of the glaze layer is greatly optimized, the light can still be well transmitted under the condition that a micro concave-convex structure exists, and further the gradual three-dimensional decorative effect similar to stone light is formed. Meanwhile, due to the existence of the crystals, the glaze layer has the advantages of high hardness, high wear resistance, skid resistance and easy cleaning.
In particular, the invention controls SiO 2 The content is 57-70 wt%, siO 2 After firing, the glass is mainly in the form of glass body and cristobalite. The invention is realized by introducing a large amount of SiO 2 The content of square quartz crystals in the glaze after firing can be improved, and the light transmittance, especially the light transmittance under the condition of the micro concave-convex structure, is improved.In particular, when SiO 2 When the weight percentage is less than 57%, the precipitation amount of the cristobalite is less, and the light transmittance is poor when the micro concave-convex structure exists, so that the decorative effect of stone light is difficult to endow the glaze; when SiO 2 When the weight percentage is more than 70%, the viscosity of the glass body formed in the firing process is too high, other crystals (such as zirconia, zirconium silicate and the like) are affected to be separated out, and the wear resistance, the skid resistance and the antifouling performance of the glaze are weakened. In addition, excessive SiO 2 The glossiness of the glaze surface is improved, and the effect of matte (glossiness is less than 15) is difficult to achieve.
Wherein, unlike conventional glazes, al in the present invention 2 O 3 Mainly ablated in the vitreous body without forming individual acicular mullite crystals. Acicular mullite crystals reduce the light transmission properties of the glaze in the presence of micro-relief structures. For this purpose, control Al 2 O 3 The content of (C) is 4-10 wt%.
Wherein the invention controls K 2 O+Na 2 O=1 wt% -4wt%, K, na is embedded more into SiO 2 -Al 2 O 3 Among the formed glass bodies, the viscosity of the glass body at high temperature is adjusted, so that good conditions are created for ordered precipitation of each crystal grain, and the wear resistance, the skid resistance and the antifouling performance of the glaze are ensured. Specifically, when K 2 O+Na 2 When O is more than 4wt%, the high temperature viscosity of the glass body is too low, but the cristobalite crystal grains, the nanometer zirconia crystal grains, the zirconium silicate crystal grains, the zirconium-containing barium silicate crystal grains and the zirconium-containing zinc silicate crystal grains can be melted, so that the wear resistance, the skid resistance, the antifouling performance and the light transmittance of the glaze are reduced. When K is 2 O+Na 2 When O is less than 1wt%, the high-temperature viscosity of the glass body is too high, which is not beneficial to grain precipitation; meanwhile, the micro concave-convex structure is further expanded, while the glossiness of the glaze is reduced, and the anti-skid performance is improved; however, the stone light decorative effect disappears, and the antifouling performance is reduced.
The CaO and MgO are main flux components, the moving radius of the flux components in the glass phase is large, the fluxing effect is strong, but the dispersion degree of the glass body containing the CaO and MgO is high, and the flux components are not beneficial to the building of the stone light decorative effect of three-dimensional layering sense. Ba. The Zn has large ionic radius and narrower moving range in the glass body, can increase the gloss of the glaze, improve the refractive index, reduce the dispersion and diffuse reflection, and is beneficial to forming the decorative effect of 'stone light'. Therefore, the invention controls CaO+MgO+ZnO+BaO=15 wt% to 35wt%, and controls (CaO+MgO)/(ZnO+BaO) =1.5 to 2.5; if (CaO+MgO)/(ZnO+BaO) < 1.5, the glossiness of the finished glaze is improved, the matte effect is difficult to achieve, and the stone polishing effect is also lost. If (CaO+MgO)/(ZnO+BaO) > 2.5, the precipitated crystals in the glaze are reduced, so that not only are the wear resistance, the skid resistance and the antifouling property of the glaze reduced, but also the decorative effect of 'stone light' is avoided.
Wherein ZrO 2 Is the main source component of various grains, and the content of the grain is controlled to be 1.5 to 4.5 weight percent.
Wherein Fe is 2 O 3 +TiO 2 Is a main impurity substance whose content is less than 0.8wt% to prevent it from affecting light transmission properties, especially in the presence of micro-relief structures. Preferably, fe is controlled 2 O 3 +TiO 2 0.05wt％-0.55wt％。
Based on the formula, the types of crystals and the sizes of the crystals in the glaze obtained after firing can be well controlled, a reasonable crystal grain and glass body system is constructed, and the wear resistance, the skid resistance, the antifouling performance and the light transmittance of the glaze are improved. Specifically, the grain size of the square quartz crystal grain is 50-1000 nanometers, the grain size of the nanometer zirconia crystal grain is 100-1000 nanometers, the grain size of the zirconium silicate crystal grain is 1-10 micrometers, the grain size of the zirconium-containing barium silicate crystal grain is 1-12 micrometers, and the grain size of the zirconium-containing zinc silicate crystal grain is 1-12 micrometers. By controlling the size of the crystal grains, the crystal grains are uniformly distributed to form a reasonable network frame, so that the reinforcing and toughening effects are effectively exerted, and the wear resistance, the anti-skid performance, the antifouling performance and the matte effect are ensured while the high light transmittance performance is ensured.
Preferably, in one embodiment of the present invention, the matte anti-slip Yi Jiechao wear resistant diamond glaze comprises the following chemical components in weight percent:
SiO 2 60％-68％，Al 2 O 3 4％-8％，K 2 O+Na 2 O＝2％-4％，CaO+MgO+ZnO+BaO＝20％-30％，ZrO 2 3％-4.5％，(CaO+MgO)/(ZnO+BaO)＝1.8-2.5，Fe 2 O 3 +TiO 2 =0.05% -0.2%; the loss on ignition is 1% -3%.
More preferably, in one embodiment of the present invention, the matte anti-slip Yi Jiechao wear resistant diamond glaze comprises the following chemical components in weight percent:
SiO 2 62％-68％，Al 2 O 3 4％-7％，K 2 O+Na 2 O＝2％-4％，CaO+MgO+ZnO+BaO＝20％-28％，ZrO 2 3％-4.5％，(CaO+MgO)/(ZnO+BaO)＝1.8-2.5，Fe 2 O 3 +TiO 2 =0.05% -0.2%; the loss on ignition is 1% -3%.
Wherein, in some embodiments of the invention, al is further controlled 2 O 3 /(K 2 O+Na 2 O) =2-4 (weight ratio). Based on the above control, the performance of the high temperature glass body can be optimized, the precipitation of cristobalite grains, nano zirconia grains, zirconium silicate grains, zirconium-containing barium silicate grains and zirconium-containing zinc silicate grains can be further promoted, and the grain size of each grain can be optimized. So that the stone light effect of the glaze is better, and the wear resistance, the skid resistance and the antifouling performance are stronger. Based on the control, a quick cooling process can be adopted in the cooling process, so that the firing period is greatly shortened, and the ceramic tile yield is improved.
Preferably, in some embodiments of the present invention, the grain size of the cristobalite grains is controlled to be 50-200 nanometers, the grain size of the nano zirconia grains is controlled to be 100-900 nanometers, the grain size of the zirconium silicate grains is controlled to be 1-5 micrometers, the grain size of the zirconium-containing barium silicate grains is controlled to be 1-10 micrometers, and the grain size of the zirconium-containing zinc silicate grains is controlled to be 1-10 micrometers. Based on the control, the cristobalite crystal grains with smaller grain size and the nano zirconia crystal grains are dispersed and distributed in a frame structure formed by the micron-sized zirconium silicate crystal grains, the zirconium-containing barium silicate crystal grains and the zirconium-containing zinc silicate crystal grains, so that the effect of dispersion strengthening is achieved, the wear resistance and the skid resistance are further improved, and meanwhile, the stone light decorative effect is further enhanced due to the dispersion distribution of the cristobalite crystal grains.
The glaze obtained by firing the matte anti-slip Yi Jiechao wear-resistant diamond glaze has wear resistance of more than or equal to 8000 turns, mohs hardness of more than or equal to 7 and glossiness of 8-15.
Preferably, in some embodiments of the present invention, the matte anti-slip Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
60-75 parts of zirconium-containing frit, 0.1-2 parts of zircon sand powder, 0.1-5 parts of zirconia, 8-13 parts of kaolin, 15-22 parts of quartz and 0.1-5 parts of auxiliary agent;
the zirconium-containing frit comprises the following chemical components in percentage by weight: siO (SiO) 2 48％-60％，Al 2 O 3 4％-15％，CaO+MgO+ZnO+BaO＝25％-40％，K 2 O+Na 2 O＝3％-8％，ZrO 2 3.5％-5.5％。
The invention provides three main forms of zirconium, namely a zirconium-containing frit, zircon sand powder and zirconia, wherein the zirconium in the frit is in an ionic state, the zirconium in the zircon sand powder is in a silicon oxygen tetrahedral lattice of zircon crystals, and the zirconium in the zirconia is in a zirconium oxygen face-centered cubic lattice formed by oxygen. Zirconium in the zirconium oxygen face-centered cubic lattice is likely to be converted into monoclinic, tetragonal and cubic systems at any time under the influence of the surrounding environment (each element component and ratio) and the temperature. Zirconium in zircon sand powder is relatively stable, and zirconium in the frit and zirconia is susceptible to form transformation or reaction with surrounding zinc barium ions. And firing to obtain cristobalite with particle size of 50-1000 nm, nano zirconium oxide crystal with particle size of 100-1000 nm, zirconium silicate crystal with particle size of 1-10 microns, barium zirconium silicate crystal with particle size of 1-12 microns, and zinc zirconium silicate crystal with particle size of 1-12 microns.
Further, in some embodiments of the invention, the particle size of the quartz feedstock is controlled to be 10-20 nanometers, and the chemical composition of the zirconia frit is controlled to be: siO (SiO) 2 50％-58％，Al 2 O 3 4％-8％，CaO+MgO+ZnO+BaO＝28％-35％，K 2 O+Na 2 O＝3％-6.00％，ZrO 2 4％-5.5％。Based on the control, the grain size of the cristobalite crystal grains in the finished glaze can be controlled to be 50-200 nanometers, so that gradual layering sense is further optimized.
Among them, the auxiliary agent includes suspending agent and water reducing agent which are common in the art, but is not limited thereto. The suspending agent may be CMC, cellulose ether, for example, but is not limited thereto. The water reducer may be sodium tripolyphosphate or a polycarboxylate water reducer commonly known in the art, but is not limited thereto.
Correspondingly, the invention also discloses a matte anti-skid Yi Jiechao wear-resistant ceramic tile which comprises a blank body and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer arranged on the blank body, wherein the matte anti-skid Yi Jiechao wear-resistant diamond glaze layer is made of matte anti-skid Yi Jiechao wear-resistant diamond glaze. The matte anti-slip Yi Jiechao wear-resistant diamond glaze comprises the following chemical components in percentage by weight:
SiO 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 =0.05% -0.55%, (cao+mgo)/(zno+bao) =1.5-2.5; the loss on ignition is 0.5% -3%. Based on the chemical components, cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains are commonly formed in the glaze layer obtained after firing, and Al mainly exists in a glass body, so that the light transmission performance of the glaze layer is greatly optimized, the light can still be well transmitted under the condition that a micro concave-convex structure exists, and further the gradual three-dimensional decorative effect similar to stone light is formed. Meanwhile, due to the existence of the crystals, the glaze layer has the advantages of high hardness, high wear resistance, skid resistance and easy cleaning.
Preferably, in some embodiments of the invention, the green body is provided with a ground coat layer, an ink-jet printing layer, a protective glaze layer, an engraving layer and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer in sequence. Wherein the protective glaze layer is made of protective glaze; the protective glaze comprises the following chemical components in percentage by weight:
SiO 2 50％-60％，Al 2 O 3 11％-18％，K 2 O+Na 2 o=1-3%, cao+mgo+zno+sro+bao=15-30%, loss on ignition 1-5%; wherein SiO is 2 /Al 2 O 3 ＝3.0-3.5。
It should be noted that, the conventional protective glaze is generally applied by screen printing, and the applied area coincides with the applied area of the subsequent engraving ink. When the technical scheme is adopted, the alignment difficulty of the subsequent screen printing and the preamble ink-jet printing is high, the pattern change is easy to cause, and the decoration effect is poor. According to the invention, the protective glaze layer is integrally applied on the ink-jet printing layer to form the protective glaze layer, and the protective glaze layer not only has a good color development effect, but also ensures that the patterns have stable color development and strong transparent feeling. And the ink can be well matched with the engraving ink of the subsequent engraving layer, the depth of the micro-concave-convex structure is increased, the stereoscopic impression is increased, and the deviation of the decorative effect caused by the non-ideal alignment of the pattern is weakened. In addition, the protective glaze layer can be well matched with the subsequent matte anti-skid Yi Jiechao wear-resistant diamond glaze layer, so that gradual change layering sense is optimized, and the decorative effect of stone light is optimized.
Specifically, siO in the glaze is protected 2 The content of (C) is 50-60 wt%, al 2 O 3 The content of (C) is 11-18 wt%, and SiO is controlled 2 /Al 2 O 3 =3-3.5. When SiO 2 /Al 2 O 3 When the roughness is less than 3, the matching property with the matte anti-skid Yi Jiechao wear-resistant diamond glaze layer on the upper layer is poor, the micro concave-convex structure is easy to change, and the decorative effect of stone light is damaged; in addition, the precipitation of crystals in the upper high-transparency matte super wear-resistant glaze layer can be influenced. When SiO 2 /Al 2 O 3 When the color is more than 3.5, the subsequent engraving ink permeation is not facilitated, and the three-dimensional sense of the pattern is weakened.
Specifically, the K in the glaze is protected 2 O+Na 2 O=1wt% -3wt%, cao+mgo+zno+sro+bao=15wt% -30wt%, based on the protective glaze of the component, the fusion degree of the permeation pattern and the protective glaze in the firing process is optimized, the nature degree of pattern transition is optimized, and the gradual change layering sense is optimized.
Wherein, the ground coat layer is made of ground coat, and the chemical composition of the ground coat in percentage by weight comprises: siO (SiO) 2 60％-65％，Al 2 O 3 12％-20％，CaO+MgO＝8％-15％，K 2 O+Na 2 O＝2.5％-3.5％，ZnO+BaO＝3％-5％，ZrO 2 1% -3% and 3% -5% of loss on ignition.
The engraving layer is made of engraving ink, and is printed on the protective glaze layer by adopting a screen printing process. Specifically, the engraving ink comprises the following raw materials in parts by weight: 40-50 parts of chromophoric frit, 3-10 parts of polyethylene glycol, 15-25 parts of solvent oil, 10-15 parts of cyclohexane, 2-10 parts of waterborne polyurethane and 1-5 parts of sodium cellulose. The chemical composition of the color-developing frit in weight percent comprises:
SiO 2 50％-60％，Al 2 O 3 12％-15％，CaO 3％-10％，MgO 1％-4％，K 2 O3％-8％，Na 2 O 1％-3％，BaO 10％-13％，ZnO 0-5％，P 2 O 5 1% -3% and loss on ignition is 0.5% -3%.
Among them, the dissolved oil is vegetable oil, and exemplary may be soybean oil, but is not limited thereto.
The chemical composition of the primer and the engraving ink in the present invention is not limited to the above examples. The prior art refined carving ink and ground coat are applicable.
Correspondingly, the invention also discloses a preparation method of the matte anti-skid Yi Jiechao wear-resistant ceramic tile, which comprises the following steps:
(1) Preparing slurry of matte anti-slip Yi Jiechao wear-resistant diamond glaze;
wherein, the matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following chemical components in percentage by weight:
SiO 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，
CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 ＝0.05％-0.55％，
(cao+mgo)/(zno+bao) =1.5-2.5; the loss on ignition is 0.5% -3%.
The matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
60-75 parts of zirconium-containing frit, 0.1-2 parts of zircon sand powder, 0.1-5 parts of zirconia, 8-13 parts of kaolin, 15-22 parts of quartz and 0.1-5 parts of auxiliary agent.
The preparation of the slurry is to mix the raw materials for preparing the matte anti-slip Yi Jiechao wear-resistant diamond glaze, and add water to ball mill to obtain the slurry. The slurry has a water content of 37-39wt% and a specific gravity of 1.8-1.85g/cm 3 . Further, the fineness of the slurry is controlled to be less than or equal to 0.2 weight percent after ball milling, so that the subsequent crystallization process is enhanced.
(2) Providing a green body, applying slurry on the green body, drying and firing.
Wherein, the application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 300-500g/m 2 。
Preferably, in one embodiment of the present invention, step (2) includes:
(2.1) providing or preparing a green body;
wherein the green body is a low water absorption ceramic tile green body common in the field, and the water absorption rate of the green body is less than 0.5%. Common raw materials for green bodies include, but are not limited to, kaolin, ball clay (various types of mud), high temperature sand, low temperature sand, medium temperature sand, feldspar, talc, magnesia, alunite, flint clay, and the like.
(2.2) providing or preparing a primer;
wherein, in one embodiment of the invention, the chemical composition of the primer comprises the following components in percentage by weight: siO (SiO) 2 60％-65％，Al 2 O 3 12％-20％，CaO+MgO＝8％-15％，K 2 O+Na 2 O＝2.5％-3.5％，ZnO+BaO＝3％-5％，ZrO 2 1% -3% and 3% -5% of loss on ignition.
The raw materials for preparing the base glaze include, but are not limited to, kaolin, potassium feldspar, albite, dolomite, talc, znO, baO, zircon, zirconia, etc., which are common in the art. Mixing the above raw materials according to chemical composition proportion, adding water, ball milling to obtain the base glaze.
(2.3) providing or preparing an inkjet ink and a cnc ink;
among them, the inkjet ink is an inkjet ink commonly used in the art.
In one embodiment of the invention, the engraving ink comprises the following raw materials in parts by weight: 40-50 parts of chromophoric frit, 3-10 parts of polyethylene glycol, 18-25 parts of solvent oil, 5-15 parts of cyclohexane, 1-10 parts of waterborne polyurethane and 1-5 parts of sodium cellulose. The chemical composition of the color-developing frit in weight percent comprises:
SiO 2 50％-60％，Al 2 O 3 12％-15％，CaO 3％-10％，MgO 1％-4％，K 2 O3％-8％，Na 2 O 1％-3％，BaO 10％-13％，ZnO 0-5％，P 2 O 5 1% -3% and loss on ignition is 0.5% -3%. The ink-jet ink based on the composition can be better matched with the protective glaze and the matte anti-skid Yi Jiechao wear-resistant diamond glaze in the invention, so that the decorative effect of stone light is optimized.
Mixing the above materials uniformly, and grinding to average particle diameter (D50) < 1 μm to obtain refined carving ink.
(2.4) providing or preparing a protective glaze;
wherein, in one embodiment of the invention, the protective glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 50％-60％，Al 2 O 3 11％-18％，K 2 O+Na 2 O=1-3%, cao+mgo+zno+sro+bao=15-30%, loss on ignition 1-5%; wherein SiO is 2 /Al 2 O 3 ＝3.0-3.5。
The raw materials for preparing the protective glaze include, but are not limited to, kaolin, potassium feldspar, albite, dolomite, talc, znO, srO, strontium carbonate, zircon, zirconia, etc., which are common in the art. Mixing the above raw materials according to chemical composition proportion, adding water, ball grinding until the screen residue of 325 mesh sieve is less than 0.5wt%, and obtaining the protective glaze.
(2.5) sequentially applying base glaze on the green body, carrying out ink-jet printing, applying protective glaze, applying engraving ink, and then applying slurry of matte anti-skid Yi Jiechao wear-resistant diamond glaze;
wherein the application amount of the ground coat is 200-400g/m 2 The application amount of the glaze slip of the protective glaze is 80-260g/m 2 The application amount of the engraving ink is 20-100g/m 2 The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 200-400g/m 2 。
(2.5) drying and sintering the green body obtained in the step (2.4) to obtain the finished product.
Wherein the firing temperature is 1180-1230 ℃, the firing period is 50-100 minutes, and the temperature is kept for 5-30 minutes at the firing temperature. According to the invention, through regulating and controlling the chemical components of each glaze, the firing period is quickened, a slow cooling procedure with very low cooling speed is not needed in the cooling process, and the production efficiency of the ceramic tile is greatly improved.
The invention is further illustrated by the following examples:
example 1
The embodiment provides a matte anti-skid Yi Jiechao wear-resistant ceramic tile, which comprises a green body, and a ground coat layer, an engraving layer, a protective glaze layer and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer which are sequentially arranged on the green body.
The preparation method comprises the following steps:
(1) Preparing a green body;
specifically, the raw materials for preparing the green body are mixed and ball-milled to prepare slurry with the water content of 37wt%, the slurry is spray-dried to obtain powder, and then the powder is pressed, molded and dried to obtain the green body.
(2) Applying a primer on the green body;
wherein, the chemical composition of the ground coat in weight percent comprises: siO (SiO) 2 61.2％，Al 2 O 3 13.4％，CaO+MgO＝13.5％，K 2 O+Na 2 O＝2.8％，ZnO+BaO＝3.3％，ZrO 2 2.2% and loss on ignition 3.6%.
The preparation raw materials of the ground glaze comprise the following components in parts by weight: 34 parts of kaolin, 9 parts of potassium feldspar, 5 parts of albite, 36 parts of dolomite, 6 parts of talcum, 4 parts of zinc carbonate, 2 parts of barium carbonate and 4 parts of zircon sand. And (3) mixing and ball milling the raw materials until the screen residue of a 325-mesh screen is 0.1wt%, thus obtaining the ground glaze.
The application amount of the primer is 250g/m 2 。
(3) Printing a decorative pattern on the green body obtained in the step (2);
(4) Screen printing engraving ink on the green body obtained in the step (3);
the engraving ink comprises the following raw materials in parts by weight: 45 parts of color development frit, 6 parts of polyethylene glycol, 23 parts of solvent oil, 14 parts of cyclohexane, 8 parts of waterborne polyurethane and 4 parts of cellulose sodium. The chemical composition of the color-developing frit in weight percent comprises:
SiO 2 53.2％，Al 2 O 3 13.6％，CaO 6.3％，MgO 2.3％，K 2 O 6.4％，Na 2 O 1.2％，BaO 12.8％，ZnO 0.2％，P 2 O 5 1.5% and loss on ignition 2.5%.
And mixing and ball milling the raw materials until the average particle size is 820nm, thus obtaining the refined carving ink.
The printing quantity of the engraving ink is 80g/m 2 。
(5) Applying a slurry of matte anti-slip Yi Jiechao wear-resistant diamond glaze on the green body obtained in the step (4);
wherein, the matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 60.3％，Al 2 O 3 5.5％，K 2 O+Na 2 O＝3.2％，CaO+MgO+ZnO+BaO＝24.4％，ZrO 2 4.4％，Fe 2 O 3 +TiO 2 ＝0.3％，(CaO+MgO)/(ZnO+BaO)＝1.7；Al 2 O 3 /(K 2 O+Na 2 O) =1.72, loss on ignition of 1.9% (excluding CMC).
The matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
67.5 parts of zirconium-containing frit, 1.7 parts of zircon sand powder, 0.8 part of zirconia, 9 parts of kaolin, 18 parts of quartz (with the particle size of 300-900 nanometers) and 3 parts of CMC;
wherein the chemical composition of the zirconium-containing frit comprises: siO (SiO) 2 53.1％，Al 2 O 3 4.1％，CaO+MgO+ZnO+BaO＝34.8％，K 2 O+Na 2 O＝4.5％，ZrO 2 3.5％。
And mixing the raw materials for preparing the matte anti-slip Yi Jiechao wear-resistant diamond glaze, and adding water to carry out ball milling to obtain slurry. The slurry had a water content of 38wt% and a maximum particle diameter of 953 nm and an average particle diameter of 530 nm.
The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 260g/m 2 。
(6) And (5) drying and sintering the green body obtained in the step (5) to obtain the finished product.
Wherein the firing temperature is 1210 ℃, the temperature is kept for 12 minutes at the firing temperature, and the firing period is 74 minutes.
After firing, the glaze layer obtained by firing the matte anti-slip Yi Jiechao wear-resistant diamond glaze contains cristobalite grains, nano zirconia grains, zirconium silicate grains, zirconium-containing barium silicate grains and zirconium-containing zinc silicate grains. Wherein, the grain size of the cristobalite crystal grain is 800-900 nanometers, the grain size of the nanometer zirconia crystal grain is 100-150 nanometers, the grain size of the zirconium silicate crystal grain is 3-5 micrometers, the grain size of the zirconium-containing barium silicate crystal grain is 1-5 micrometers, and the grain size of the zirconium-containing zinc silicate crystal grain is 3-8 micrometers.
Example 2
The embodiment provides a matte anti-skid Yi Jiechao wear-resistant ceramic tile, which comprises a green body, and a ground coat layer, an engraving layer, a protective glaze layer and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer which are sequentially arranged on the green body.
The preparation method comprises the following steps:
(1) Preparing a green body;
specifically, the raw materials for preparing the green body are mixed and ball-milled to prepare slurry with the water content of 37wt%, the slurry is spray-dried to obtain powder, and then the powder is pressed, molded and dried to obtain the green body.
(2) Applying a primer on the green body;
wherein, the chemical composition of the ground coat in weight percent comprises: siO (SiO) 2 61.2％，Al 2 O 3 13.4％，CaO+MgO＝13.5％，K 2 O+Na 2 O＝2.8％，ZnO+BaO＝3.3％，ZrO 2 2.2% and loss on ignition 3.6%.
The preparation raw materials of the ground glaze comprise the following components in parts by weight: 34 parts of kaolin, 9 parts of potassium feldspar, 5 parts of albite, 36 parts of dolomite, 6 parts of talcum, 4 parts of zinc carbonate, 2 parts of barium carbonate and 4 parts of zircon sand. And (3) mixing and ball milling the raw materials until the screen residue of a 325-mesh screen is 0.1wt%, thus obtaining the ground glaze.
The application amount of the primer is 250g/m 2 。
(3) Printing a decorative pattern on the green body obtained in the step (2);
(4) Screen printing engraving ink on the green body obtained in the step (3);
the engraving ink comprises the following raw materials in parts by weight: 45 parts of color development frit, 6 parts of polyethylene glycol, 23 parts of solvent oil, 14 parts of cyclohexane, 8 parts of waterborne polyurethane and 4 parts of cellulose sodium. The chemical composition of the color-developing frit in weight percent comprises:
SiO 2 53.2％，Al 2 O 3 13.6％，CaO 6.3％，MgO 2.3％，K 2 O 6.4％，Na 2 O 1.2％，BaO 12.8％，ZnO 0.2％，P 2 O 5 1.5% and loss on ignition 2.5%.
And mixing and ball milling the raw materials until the average particle size is 820nm, thus obtaining the refined carving ink.
The printing quantity of the engraving ink is 80g/m 2 。
(5) Applying a slurry of matte anti-slip Yi Jiechao wear-resistant diamond glaze on the green body obtained in the step (4);
wherein, the matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 61.9％，Al 2 O 3 7.0％，K 2 O+Na 2 O＝2.9％，CaO+MgO+ZnO+BaO＝22.8％，ZrO 2 3.8％，Fe 2 O 3 +TiO 2 0.1％，(CaO+MgO)/(ZnO+BaO)＝1.7；Al 2 O 3 /(K 2 O+Na 2 O) =2.4, loss on ignition of 1.5% (excluding CMC).
The matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
64.3 parts of zirconium-containing frit, 1.5 parts of zircon sand powder, 0.5 part of zirconia, 10.7 parts of kaolin, 21 parts of quartz (with the particle size of 15-20 nanometers) and 2 parts of CMC;
wherein the chemical composition of the zirconium-containing frit comprises: siO (SiO) 2 53.1％，Al 2 O 3 4.1％，CaO+MgO+ZnO+BaO＝34.8％，K 2 O+Na 2 O＝4.5％，ZrO 2 3.5％。
And mixing the raw materials for preparing the matte anti-slip Yi Jiechao wear-resistant diamond glaze, and adding water to carry out ball milling to obtain slurry. The slurry had a water content of 38wt% and a maximum particle diameter of 953 nm and an average particle diameter of 530 nm.
The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 260g/m 2 。
(6) And (5) drying and sintering the green body obtained in the step (5) to obtain the finished product.
Wherein the firing temperature is 1210 ℃, the temperature is kept for 12 minutes at the firing temperature, and the firing period is 74 minutes.
After firing, the glaze layer obtained by firing the matte anti-slip Yi Jiechao wear-resistant diamond glaze contains cristobalite grains, nano zirconia grains, zirconium silicate grains, zirconium-containing barium silicate grains and zirconium-containing zinc silicate grains. Wherein, the grain size of the cristobalite crystal grain is 80-100 nanometers, the grain size of the nanometer zirconia crystal grain is 100-150 nanometers, the grain size of the zirconium silicate crystal grain is 3-5 micrometers, the grain size of the zirconium-containing barium silicate crystal grain is 1-5 micrometers, and the grain size of the zirconium-containing zinc silicate crystal grain is 2-5 micrometers.
Example 3
The embodiment provides a matte anti-skid Yi Jiechao wear-resistant ceramic tile, which comprises a green body, and a ground coat layer, an engraving layer, a protective glaze layer and a matte anti-skid Yi Jiechao wear-resistant diamond glaze layer which are sequentially arranged on the green body.
The preparation method comprises the following steps:
(1) Preparing a green body;
specifically, the raw materials for preparing the green body are mixed and ball-milled to prepare slurry with the water content of 37wt%, the slurry is spray-dried to obtain powder, and then the powder is pressed, molded and dried to obtain the green body.
(2) Applying a primer on the green body;
wherein, the chemical composition of the ground coat in weight percent comprises: siO (SiO) 2 61.2％，Al 2 O 3 13.4％，CaO+MgO＝13.5％，K 2 O+Na 2 O＝2.8％，ZnO+BaO＝3.3％，ZrO 2 2.2% and loss on ignition 3.6%.
The preparation raw materials of the ground glaze comprise the following components in parts by weight: 34 parts of kaolin, 9 parts of potassium feldspar, 5 parts of albite, 36 parts of dolomite, 6 parts of talcum, 4 parts of zinc carbonate, 2 parts of barium carbonate and 4 parts of zircon sand. And (3) mixing and ball milling the raw materials until the screen residue of a 325-mesh screen is 0.1wt%, thus obtaining the ground glaze.
The application amount of the primer is 250g/m 2 。
(3) Printing a decorative pattern on the green body obtained in the step (2);
(4) Applying a protective glaze to the green body obtained in step (3);
wherein, the protective glaze comprises the following chemical components in percentage by weight:
SiO 2 53.6％，Al 2 O 3 16.1％，K 2 O+Na 2 O＝2.6％，
cao+mgo+zno+bao=23.5%, loss on ignition 4.2%; wherein SiO is 2 /Al 2 O 3 ＝3.3。
The application amount of the glaze slip of the protective glaze is 110g/m 2 ，
(5) Screen printing engraving ink on the green body obtained in the step (4);
the engraving ink comprises the following raw materials in parts by weight: 45 parts of color development frit, 6 parts of polyethylene glycol, 23 parts of solvent oil, 14 parts of cyclohexane, 8 parts of waterborne polyurethane and 4 parts of cellulose sodium. The chemical composition of the color-developing frit in weight percent comprises:
SiO 2 53.2％，Al 2 O 3 13.6％，CaO 6.3％，MgO 2.3％，K 2 O 6.4％，Na 2 O 1.2％，BaO 12.8％，ZnO 0.2％，P 2 O 5 1.5% and loss on ignition 2.5%.
And mixing and ball milling the raw materials until the average particle size is 820nm, thus obtaining the refined carving ink.
The printing quantity of the engraving ink is 80g/m 2 。
(6) Applying a slurry of matte anti-slip Yi Jiechao wear-resistant diamond glaze on the green body obtained in the step (5);
wherein, the matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 61.9％，Al 2 O 3 7.0％，K 2 O+Na 2 O＝2.9％，CaO+MgO+ZnO+BaO＝22.8％，ZrO 2 3.8％，Fe 2 O 3 +TiO 2 0.1％，(CaO+MgO)/(ZnO+BaO)＝1.7；Al 2 O 3 /(K 2 O+Na 2 O) =2.4, loss on ignition of 1.5% (excluding CMC).
The matte anti-skid Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
64.3 parts of zirconium-containing frit, 1.5 parts of zircon sand powder, 0.5 part of zirconia, 10.7 parts of kaolin, 21 parts of quartz (with the particle size of 15-20 nanometers) and 2 parts of CMC;
wherein the chemical composition of the zirconium-containing frit comprises: siO (SiO) 2 53.1％，Al 2 O 3 4.1％，CaO+MgO+ZnO+BaO＝34.8％，K 2 O+Na 2 O＝4.5％，ZrO 2 3.5％。
And mixing the raw materials for preparing the matte anti-slip Yi Jiechao wear-resistant diamond glaze, and adding water to carry out ball milling to obtain slurry. The slurry had a water content of 38wt% and a maximum particle diameter of 953 nm and an average particle diameter of 530 nm.
The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 260g/m 2 。
(7) And (3) drying and sintering the green body obtained in the step (6) to obtain the finished product.
Wherein the firing temperature is 1210 ℃, the temperature is kept for 10 minutes at the firing temperature, and the firing period is 58 minutes.
After firing, the glaze layer obtained by firing the matte anti-slip Yi Jiechao wear-resistant diamond glaze contains cristobalite grains, nano zirconia grains, zirconium silicate grains, zirconium-containing barium silicate grains and zirconium-containing zinc silicate grains. Wherein, the grain size of the cristobalite crystal grain is 50-80 nanometers, the grain size of the nanometer zirconia crystal grain is 100-200 nanometers, the grain size of the zirconium silicate crystal grain is 2-5 micrometers, the grain size of the zirconium-containing barium silicate crystal grain is 2-7 micrometers, and the grain size of the zirconium-containing zinc silicate crystal grain is 2-5 micrometers.
The tiles obtained in examples 1-3 were subjected to technical tests, in particular gloss measurements with reference to GB/T13891, at a test angle of 60 °; the abrasion resistance test is referred to GB/T3810.7, the stain resistance test is referred to GB/T3810.14, the friction coefficient measurement is referred to GB/T4100-2015 appendix M (wet method), the Mohs hardness is measured by a Mohs hardness tester, and the surface effect is visually measured. The specific results are as follows:
while the foregoing is directed to the preferred embodiments of the present invention, it will be appreciated by those skilled in the art that changes and modifications may be made without departing from the principles of the invention, such changes and modifications are also intended to be within the scope of the invention.
Claims (10)
1. The matte anti-skid Yi Jiechao wear-resistant diamond glaze is characterized by comprising the following chemical components in percentage by weight:
SiO 2 57％-70％，Al 2 O 3 4％-10％，K 2 O+Na 2 O＝1％-4％，
CaO+MgO+ZnO+BaO＝15％-35％，ZrO 2 1.5％-4.5％，Fe 2 O 3 +TiO 2 ＝0.05％-0.55％，
(cao+mgo)/(zno+bao) =1.5-2.5; the loss on ignition is 0.5% -3%;
and cristobalite crystal grains, nano zirconia crystal grains, zirconium silicate crystal grains, zirconium-containing barium silicate crystal grains and zirconium-containing zinc silicate crystal grains coexist in the glaze layer obtained after the matte anti-slip Yi Jiechao wear-resistant diamond glaze is sintered.
2. The matte anti-slip Yi Jiechao wear resistant diamond glaze of claim 1, wherein Al 2 O 3 /(K 2 O+Na 2 O)＝2-4。
3. The matte anti-slip Yi Jiechao wear-resistant diamond glaze according to claim 1, wherein the matte anti-slip Yi Jiechao wear-resistant diamond glaze comprises the following raw materials in parts by weight:
60-75 parts of zirconium-containing frit, 0.1-2 parts of zircon sand powder, 0.1-5 parts of zirconia, 8-13 parts of kaolin, 15-22 parts of quartz and 0.1-5 parts of auxiliary agent;
the zirconium-containing frit comprises the following chemical components in percentage by weight: siO (SiO) 2 48％-60％，Al 2 O 3
4％-15％，CaO+MgO+ZnO+BaO＝25％-40％，K 2 O+Na 2 O＝3％-8％，ZrO 2 3.5％-5.5％。
4. The matte anti-slip Yi Jiechao wear-resistant diamond glaze according to claim 1, wherein the grain size of the cristobalite grains is 50-200 nanometers, the grain size of the nano-zirconia grains is 100-900 nanometers, the grain size of the zirconium silicate grains is 1-5 microns, the grain size of the zirconium-containing barium silicate grains is 1-10 microns, and the grain size of the zirconium-containing zinc silicate grains is 1-10 microns.
5. The matte anti-slip Yi Jiechao wear-resistant diamond glaze according to any one of claims 1-4, wherein the wear resistance of the glaze layer obtained after firing of the matte anti-slip Yi Jiechao wear-resistant diamond glaze is greater than or equal to 8000 revolutions and the mohs hardness is greater than or equal to 7.
6. A matte anti-slip Yi Jiechao wear-resistant ceramic tile, which comprises a green body and a matte anti-slip Yi Jiechao wear-resistant diamond glaze layer arranged on the green body, wherein the matte anti-slip Yi Jiechao wear-resistant diamond glaze layer is made of the matte anti-slip Yi Jiechao wear-resistant diamond glaze according to any one of claims 1-5.
7. The matte anti-skid Yi Jiechao wear-resistant ceramic tile according to claim 6, wherein the base glaze layer, the ink-jet printing layer, the protective glaze layer, the engraving layer and the matte anti-skid Yi Jiechao wear-resistant diamond glaze layer are sequentially arranged on the green body;
wherein the protective glaze layer is made of protective glaze;
the protective glaze comprises the following chemical components in percentage by weight: siO (SiO) 2 50％-60％，Al 2 O 3 11％-18％，K 2 O+Na 2 O=1-3%, cao+mgo+zno+sro+bao=15-30%, loss on ignition 1-5%; wherein SiO is 2 /Al 2 O 3 ＝3.0-3.5。
8. A method for preparing a matte anti-slip Yi Jiechao wear resistant tile for preparing the matte anti-slip Yi Jiechao wear resistant tile of claim 6 or 7, comprising:
(1) Preparing a slurry of the matte anti-slip Yi Jiechao wear resistant diamond glaze of any of claims 1-5;
(2) Providing a green body, applying the slurry on the green body, drying and firing.
9. The method for preparing the matte anti-skid Yi Jiechao wear-resistant ceramic tile according to claim 8, wherein in the step (2), under-glaze, ink-jet printing, protective glaze, engraving ink and slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze are sequentially applied to the green body;
wherein the application amount of the ground coat is 200g/m 2 -400g/m 2 The application amount of the glaze slip of the protective glaze is 80g/m 2 -260g/m 2 The application amount of the engraving ink is 20g/m 2 -100g/m 2 The application amount of the slurry of the matte anti-skid Yi Jiechao wear-resistant diamond glaze is 200g/m 2 -400g/m 2 。
10. The method for preparing the matte anti-skid Yi Jiechao wear-resistant ceramic tile according to claim 8, wherein in the step (2), the firing temperature is 1180-1230 ℃, the firing period is 50-100 minutes, and the heat preservation is carried out at the firing temperature for 5-30 minutes.
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| CN116986925A (en) * | 2023-09-27 | 2023-11-03 | 佛山市金舵陶瓷有限公司 | Anti-skid wear-resistant ceramic tile with island-shaped structure and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116986925A (en) * | 2023-09-27 | 2023-11-03 | 佛山市金舵陶瓷有限公司 | Anti-skid wear-resistant ceramic tile with island-shaped structure and preparation method thereof |
| CN116986925B (en) * | 2023-09-27 | 2023-12-15 | 佛山市金舵陶瓷有限公司 | Anti-skid wear-resistant ceramic tile with island-shaped structure and preparation method thereof |
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Application publication date: 20230905 Assignee: Foshan dajiaolu marble tile Co.,Ltd. Assignor: Guangdong dajiaolu New Material Co.,Ltd. Contract record no.: X2024980000565 Denomination of invention: A matte, anti slip, easy to clean, super wear-resistant diamond glaze, ceramic tile and its preparation method License type: Common License Record date: 20240112 |
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Application publication date: 20230905 Assignee: Foshan dajiaolu marble tile Co.,Ltd. Assignor: Guangdong dajiaolu New Material Co.,Ltd. Contract record no.: X2024980000565 Denomination of invention: A matte, anti slip, easy to clean, super wear-resistant diamond glaze, ceramic tile and its preparation method License type: Common License Record date: 20240112 |