CN1166426C - Dyeable fabrics - Google Patents

Dyeable fabrics Download PDF

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Publication number
CN1166426C
CN1166426C CNB981082106A CN98108210A CN1166426C CN 1166426 C CN1166426 C CN 1166426C CN B981082106 A CNB981082106 A CN B981082106A CN 98108210 A CN98108210 A CN 98108210A CN 1166426 C CN1166426 C CN 1166426C
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CN
China
Prior art keywords
lining
dyeable
filling
toy
toy according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB981082106A
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Chinese (zh)
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CN1235219A (en
Inventor
毛健雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HANGLI INDUSTRY Co Ltd SHANGHAI
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HANGLI INDUSTRY Co Ltd SHANGHAI
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Priority to CNB981082106A priority Critical patent/CN1166426C/en
Publication of CN1235219A publication Critical patent/CN1235219A/en
Application granted granted Critical
Publication of CN1166426C publication Critical patent/CN1166426C/en
Anticipated expiration legal-status Critical
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Abstract

The present invention relates to R1-*-CH2-*-CH2-SO3 <->. In the present invention, fibers contact the alkali solution of an ampholytic surface active agent. After the fibers are pretreated, the dyeing solution of a levelling agent in which a surface active agent almost does not exist is used for attaching dye to the pretreated fibers, or after the fibers contact the dyeing solution of an alkali solution containing the surface active agent, dye is added into the dyeing solution, and consequently, the dye is attached to the fibers in the dyeing solution, wherein a used new surface active agent compound comprises the alkoxylating hydroxyl group sulfo betaine of the formula in which R1 represents hydrocarbyl selected from C12 H15 to C21 H43; R2 and R3 represent poly (alkylene oxide) groups, and both contains three to twenty-one alkylene oxide units.

Description

A kind of dyeable filling toy
Technical field
What the present invention relates to is a kind of filling toy, and specifically, what the present invention relates to is a kind of dyeable filling toy.
Background technology
The kind of the filling toy of selling in the market is a lot, and all have their own characteristics each, the researcher is improving these filling toys always, and more recruiting that the filling toy does liked, simultaneously also give the filling toy with new use, for example: denomination of invention is integrated for the Chinese patent application CN88211327 of " lint hot-water heating toy " will play happy heating, and structure feature is simple.
And for example, denomination of invention discloses a kind of down toy for the Chinese patent application CN93231866 of " inflatable woolen toy ", and its special character is that air bag is housed in cavity, thereby reduces product cost, and toy weight is reduced greatly, made things convenient for transportation, carried, washing and airing etc.
In addition, denomination of invention discloses a kind of downy animal toy head for the Chinese patent application CN94240367 of " downy animal toy head ", it is characterized in that internal layer is provided with the plastic inner lining of animal skull shape, skin is provided with an artificial fur that is printed on the outer table image of animal head, and this utility model third dimension is strong, lifelike image.
The kind of filling toy has been enriched in these improvement.
Summary of the invention
The object of the present invention is to provide a kind of filling toy, described filling toy surface is printed on line image, can tint to the toy surface with watercolor pencil, again tint if think, toy can be put into washing machine or manual the cleaning, toy is faded substantially, tint again then.
Purpose of the present invention can be achieved by the following method,, adopts a kind of lining that can meet requirement of the present invention that is, and is on lining that various line images are printed, makes desirable toy then and gets final product.
To the present invention, for reaching goal of the invention, at first be to choosing fabric, as everyone knows, the lining wide range of general concept, press the preparation method of fabric, can be divided into woven fabric, knitted fabric, water and air injection fabric and adhesive-bonded fabric, to these coloration of textile materials stamps basically based on suitability for industrialized production, the notion of prior art is how dyeing is dyed more firm all the time, therefore, considers how to cooperate follow-up dyeing and printing technology basically when producing lining, and can not go to consider to make dyeing and printing easy, can remove the color that is coated with substantially by simple washing when not required again.
Therefore, the present invention proposes to satisfying a kind of fabric of requirement needs of the present invention, at first, it should satisfy of the present invention tinting, that is,
1, the lining surface should be satisfied smoothly substantially, and to the good result of having tinted of water-soluble dye, tinted and should not influence the effect of tinting because of the lint of fabric face in tinting back;
2, the combination of dyes power used tinting of lining should be more weak, that is, after the drying of tinting, institute's coating colour should have suitable dyefastness, but when washing, should be able to remove color substantially;
3, owing to the present invention seeks to make a kind of filling toy, making in the engineering of toy, just need fabric that suitable intensity is arranged, and, toy in use also requires fabric itself that good intensity is arranged, and intensity described here should comprise the tearing strength and the fracture strength of fabric;
4, when the toy of making used, high-frequency distortion can take place in fabric under toy any kneading in use, therefore required lining should have certain elongation;
5, after preparing lining by above-mentioned requirements, lining is carried out the impression case on request, the impression case can be continuous printing, hour also can cut in batches the back printing, simultaneously the sideline of line image and sewing toy is printed off during printing, carry out then carrying out cutting, and become the toy of tinting of the present invention after technology is made routinely by the sideline of various toys.
In toy of the present invention, the most important thing is to form a kind of brand-new product with such design and in conjunction with existing raw material and technology, design described here is, produce a kind of toy, it can be the filling toy of arbitrary shape, its lining surface be white or other light color, preprinted pattern or hollow literal are arranged then thereon, can allow children coat color according to the imagination of oneself, the color that is coated with forms the color of different style in conjunction with the background color of lining itself and the line image of printing; When needs are tinted again, toy can be put into washing machine or wash by hand, make former basic removing of tinting after the washing, can tint repeatedly after drying.
As aforementioned, if reach purpose of the present invention, except that design, also need used lining is limited, because lining commonly used can not satisfy needs of the present invention simultaneously, for example, cotton, chemical fibre woven fabric commonly used, because existence at the woven face fibre fluff, the poor effect that becomes because of fine hair during feasible tinting, in addition, because the absorption property of cotton fiber is better, when washing, be difficult for primary colors is removed, the toy surface color and polish is deepened; Simultaneously, because the woven fabric sideline comes off easily, just need reserve wideer processing back gauge.
Conventional knitted fabric except the shortcoming of above-mentioned existence, also exists woven design too dark, and influence is coated with chromatic effect more.
A kind of dyeable filling toy of the present invention, described object for appreciation has multiple shape, they are made up of lining and filler, it is characterized in that described lining is a white or light, on the lining of forming toy, be printed on pattern, described lining is that outer surface can be tinted at least, is washing the lining that can fade substantially down with water.
Described lining is a white or light, and described lining outer surface is dyeable.
The described available water miscible dyestuff of tinting is tinted.
Described lining is an outer surface lining level and smooth substantially and low fluffing at least.
Described lining is an outer surface nonwoven level and smooth substantially and low fluffing at least.
Described nonwoven is the nonwoven that the TYVEK14 type spunbonded type hdpe fiber of the level and smooth substantially and low fluffing in surface is made.
The about 6-15 newton of ligulate sample tearing strength (MD and XD) of described lining.
Bar stretching (MD) about 1-2.5 Newton/millimeter of described lining.
Bar stretching (XD) about 1-3 Newton/millimeter of described lining.
The about 25-30% of the elongation of described lining.
The about 38-48 gram of the pivot weight of described lining/square metre.
Described lining is the TYVEK14 of a Du Pont type nonwoven.
Conventional nonwoven, usually also be to glue with short fiber acupuncture, point to form, there is above-mentioned problem equally, in order to reach purpose of the present invention, the present invention limits lining commonly used especially, that is, described lining is a white or light, its at least outer surface can tint, under washing with water, can fade substantially; The outer at least of described lining is level and smooth substantially and low the fluffing; The about 6-15 newton of ligulate sample tearing strength (MD and XD) of this lining; Its (MD) about 1-2.5 Newton/millimeter that stretches; Its (XD) about 1-3 Newton/millimeter that stretches; It extends about 25-30%.
Described lining can be any type of fabric that satisfies above-mentioned requirements, but the nonwoven among the following embodiment of preferred the present invention, because following nonwoven can be near requirement in the product of prior art.
The present invention is according to the abundant characteristics of children's visionary, a kind of dyeable toy is provided, because the dyeable performance that this toy provides other toy not have, make children to design and produce the lovely animal of various clevernesses according to oneself imagination, children can coat various colors with the imagination of oneself, describe the fine piece of writing of oneself, and this toy can also wash, no matter implement with concrete, can think a kind of product of unique creativity from design.
Description of drawings
Be description of drawings below, in conjunction with the accompanying drawings, can clearer understanding technology contents of the present invention, wherein:
Fig. 1 is the schematic perspective view of the toy of tinting of the present invention, and wherein, A and B are respectively the toys after not tinting and tinting;
Fig. 2,3, the 4th is imprinted on schematic diagram on the lining of the present invention with various line images;
Fig. 5 is the production procedure of the preferred TYVEK14 type of the present invention nonwoven, wherein, the 1st, spinneret orifice, the 2nd, roller, the 3rd, sided corona treatment, the 4th, antistatic treatment, the 5th, softening, the 6th, packing/carry and cut;
Fig. 6 is the photo of the preferred TYVEK14 type of the present invention nonwoven fibre structure under 180 times of electronic scanner microscopes.
The specific embodiment
Be the present invention is preferred below, satisfy above-mentioned requirements substantially, be applicable to the embodiment that makes toy of the present invention.
The preferred example of the lining that dyeable toy of the present invention uses is, the commodity that du pont company is produced Tyvek 14 type nonwoven by name, and this nonwoven is solid and durable, and the strength ratio paper is big, and is light when heavy, flexible smooth.
The chromatic effect that is coated with of Tyvek 14 type nonwoven of the present invention outclass that cotton is knitted or imperial goods, can satisfy the purpose of tinting of the present invention.
In fact, Tyvek14 type nonwoven it be a kind of blow the spray hot pressing the high density polyethylene (HDPE) fabric.
Tyvek 14 type nonwoven are that spunbonded type alkene is made with hdpe fiber, production procedure is: high density polyethylene (HDPE) and solvent carry out spinning from spinneret orifice 1, enter roller 2 then and carry out the heat bonding mold pressing, when needing, can carry out sided corona treatment 3, after sided corona treatment, enter antistatic treatment 4, soften 5 at last, and enter packing/carry and cut 6 and form.It has the physical property of balance, combines the characteristics that paper, film and cloth have; The TYVEK14 type forms through continuous process, and in this course, the thin isotropic fiber that reaches the 0.5-10 micron is earlier through spinning, and hot pressing and bonding together then need not adhesive and filler.
TYVEK have the intensity height, in light weight, soft, smoothly, seldom fluffing, opaque, anti-water, chemical resistance, character such as wear-resistant, ageing-resistant.These unique character combine, and make TYVEK become the desirable lining of the toy of tinting of the present invention.
14 types are spot gluing products, have impression, are a kind of pliable and tough matrix as fabric, and have good impressionability energy, 14 types to have high tearing toughness and better surface texturisation.When these materials of processing, can stitch, glue, and in certain limit, carry out ultrasonic wave and sew up and seal.
The preferred lining of the present invention, TYVEK14 type nonwoven can adapt to various requirement of the present invention well, comprise cut, be cut into monolithic, Ma Dui, backfin trace, cross cutting, punching press, bore a hole, tint, heat-sealing, ultrasonic envelope, gluing, sewing etc.
Can be fit to the lining that the present invention uses and be not limited to TYVEK14 type nonwoven, but its performance can reach purpose of the present invention better, be compared as follows with regard to the performance of this lining:
Compare with paper substrate:
The skin-friction force of TYVEK is less.
TYVEK weight is lighter, is generally used for the occasion identical with paper.
TYVEK can elongate 25-30% before fracture, can carry out degree of depth mold pressing and do not break.
The TYVEK hygroscopicity is low, thereby for most of printing ink, coating and adhesive, it needs longer drying time.
TYVEK ten minutes is solid, and weblike material seldom ruptures.When be cut into individual, carry cut, during cross cutting, each silk fiber all must cut off fully; " catenary " can not resemble and disconnect the paper.
The wear resistence of TYVEK is less.Because its natural lubricity is all used the long time when using knife, pressing mold and drift.
Bear deformation ability: temperature raises, and can increase width loss that tension force is caused and the sensitiveness of being out of shape.
Good dimensional stability: under constant temperature, relative humidity is within 0 to 100% scope, and the change in size of sheet material is less than 0.01%.Meet the situation that FDA and USDA require.
Flammable: TYVEK sheet material cleaning, undressed, can or not light toward after-contraction from being heated when running into naked light.14 types are pressed U.S. 16CFR1610 method (the general dress regulation of the flammable textile regulations of clothing) when testing, and are decided to be " 1 grade " (normal flammable).During by the method test of California Fire Department, these types also are decided to be " 1 grade ".
Outstanding pliability: TYVEK has outstanding flexing resistance, when on MIT deflection test machine (U.S. TAPPIT-423 method), testing, and can be easily above 20000 times.
Be difficult for fluffing:, under normal operating position, be difficult for fluffing because TYVEK is synthetic by totally continuous fiber.
In light weight, be about half of paper of condition of equivalent thickness.
Excellent humidity-proof ability: the physical property of TYVEK is not subjected to the influence of water; Under general condition and environment temperature, TYVEK intensity wet and that do equates.
Anti-fungi performance: be embedded in for a long time in the soil, TYVEK undergoes no deterioration.Clean TYVEK also is difficult for mouldy.
The anti-contamination: the resistivity for the muddy water dirt is very high, but lower to the resistivity of fat absorption.14 types can wash and dry-clean.
Temperature range: toughness and flexibility can keep when (73 ℃) at low reaching-100F.When about 245F (118 ℃), TYVEK begins to shrink, and begins fusing when 275F (135 ℃).
Toxicity: the TYVEK of E.I.Du Pont Company's supply, all through carry out the test of skin contact toxicity, the report of not receiving toxic reaction on one's body in animal and human's class.
The present invention is according to the abundant characteristics of children's visionary, a kind of dyeable toy is provided, because the dyeable performance that this toy provides other toy not have, make children to design and produce the lovely animal of various clevernesses according to oneself imagination, children can coat various colors with the imagination of oneself, describe the fine piece of writing of oneself, and this toy can also wash, no matter implement with concrete, can think a kind of product of unique creativity from design.

Claims (11)

1, a kind of dyeable filling toy, described object for appreciation has multiple shape, they are made up of lining and filler, it is characterized in that described lining is a white or light, on the lining of forming toy, be printed on pattern, described lining is that outer surface can be tinted at least, is washing the lining that can fade substantially down with water.
2, dyeable filling toy according to claim 1 is characterized in that the described available water miscible dyestuff of tinting tints.
3, dyeable filling toy according to claim 1 is characterized in that described lining is the lining level and smooth substantially and low fluffing of outer surface at least.
4,, it is characterized in that described lining is the nonwoven level and smooth substantially and low fluffing of outer surface at least according to claim 1 or 3 described dyeable filling toys.
5, dyeable filling toy according to claim 4 is characterized in that described nonwoven is the nonwoven made of TYVEK14 type spunbonded type hdpe fiber of the level and smooth substantially and low fluffing in surface.
6, dyeable filling toy according to claim 1 is characterized in that the ligulate sample tearing strength of described lining is 6-15 newton.
7, dyeable filling toy according to claim 1 is characterized in that the bar stretching MD of described lining is the 1-2.5 Newton/millimeter.
8, dyeable filling toy according to claim 1 is characterized in that the bar stretching XD of described lining is the 1-3 Newton/millimeter.
9, dyeable filling toy according to claim 1 is characterized in that the elongation 25-30% of described lining.
10, dyeable filling toy according to claim 1, the pivot weight that it is characterized in that described lining be 38-48 gram/square metre.
11, dyeable filling toy according to claim 1 is characterized in that described lining is the TYVEK14 of a Du Pont type nonwoven.
CNB981082106A 1998-05-12 1998-05-12 Dyeable fabrics Expired - Lifetime CN1166426C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB981082106A CN1166426C (en) 1998-05-12 1998-05-12 Dyeable fabrics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB981082106A CN1166426C (en) 1998-05-12 1998-05-12 Dyeable fabrics

Publications (2)

Publication Number Publication Date
CN1235219A CN1235219A (en) 1999-11-17
CN1166426C true CN1166426C (en) 2004-09-15

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106894246A (en) * 2017-04-13 2017-06-27 合肥智慧殿投资管理有限公司 A kind of High Temperature Disperse Leveler and its preparation method and application
CN107938391B (en) * 2017-12-01 2020-10-30 山东黄河三角洲纺织科技研究院有限公司 Flax fiber dyeing method

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