CN116553911A - Application of clay clinker flint clay in composite sliding nozzle brick outer layer material - Google Patents
Application of clay clinker flint clay in composite sliding nozzle brick outer layer material Download PDFInfo
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- CN116553911A CN116553911A CN202310412614.XA CN202310412614A CN116553911A CN 116553911 A CN116553911 A CN 116553911A CN 202310412614 A CN202310412614 A CN 202310412614A CN 116553911 A CN116553911 A CN 116553911A
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- Prior art keywords
- clay
- outer layer
- sliding nozzle
- nozzle brick
- layer material
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- 239000004927 clay Substances 0.000 title claims abstract description 53
- 239000000463 material Substances 0.000 title claims abstract description 34
- 239000011449 brick Substances 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 28
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 12
- 239000011265 semifinished product Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 230000032683 aging Effects 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- 238000005245 sintering Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000035939 shock Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 239000012856 weighed raw material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/22—Grog products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
- B22D41/28—Plates therefor
- B22D41/30—Manufacturing or repairing thereof
- B22D41/32—Manufacturing or repairing thereof characterised by the materials used therefor
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1315—Non-ceramic binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
- C04B35/6306—Binders based on phosphoric acids or phosphates
- C04B35/6309—Aluminium phosphates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses application of clay clinker flint clay to replace high bauxite chamotte in composite sliding nozzle brick outer layer materials, wherein the composite sliding nozzle brick outer layer materials comprise the following raw materials in percentage by weight: 60-70% of flint clay aggregate, 20-30% of bauxite chamotte powder, 5-10% of soft clay and 4-6% of binding agent aluminum dihydrogen phosphate. According to the invention, the flint clay is used as aggregate to replace high bauxite chamotte aggregate to be used on the composite sliding nozzle brick outer layer material, so that the use requirement can be met, and the production cost of the product is effectively reduced.
Description
Technical Field
The invention belongs to the technical field of sliding nozzle bricks, and particularly relates to application of clay clinker flint clay on an outer layer material of a composite sliding nozzle brick.
Background
The sliding nozzle brick is a control device for molten steel in the casting process of a continuous casting machine and comprises a sliding plate, an upper nozzle brick and a lower nozzle brick. Because the sliding nozzle brick is contacted with high-temperature molten steel in the steel casting operation process, if the heat resistance is poor, the thermal shock resistance is poor, the compression resistance and the fracture resistance are insufficient, the thermal stress can easily cause the sliding nozzle brick to burst, the molten steel seeps along cracks, and serious accidents such as steel running and the like can be caused.
As a refractory material manufacturer, on the premise of ensuring that the use quality of the product is not reduced, the effective cost reduction is a difficult problem faced by the current enterprises.
The nonrenewable bauxite chamotte is used as a necessary main raw material of the composite sliding gate brick outer layer material, so that the purchasing of the bauxite chamotte is more difficult and the price of the bauxite chamotte is more and more expensive. The market price of 85# high bauxite is already more than 2500 yuan/t.
Therefore, searching for low-cost replacement materials of the bauxite chamotte becomes a technical problem to be solved by the existing refractory manufacturers.
The flint clay is an associated accessory product of coal, and has rich reserve and wide sources on the upper layer of a coal bed.
Flint clay is a generic name of hard clay clinker and is formed by sintering raw flint clay at a high temperature of 1250-1350 ℃. The main mineral of the flint clay is kaolinite, a series of physical and chemical changes occur in the high-temperature sintering process, crystal water, structural water and a small amount of organic matters are released, the volume shrinkage is compact, and finally mullite phase, cristobalite phase and a small amount of glass phase are formed, so that the flint clay has good heat resistance, sintering property and thermal shock resistance.
Impurity content in flint clay, especially Na 2 O+K 2 The lower the O content, the higher the refractoriness. And Al is 2 O 3 /3SiO 2 The closer the ratio is to the theoretical value (a/s=0.85), the higher the purity of the flint clay is indicated. The larger the A/S, the higher the refractoriness of the flint clay, and the wider the sintering melting range. The refractoriness of the high-quality flint clay can reach more than 1750 ℃.
The flint clay has wide market supply source, the price of 1650 yuan/t, which is obviously lower than that of the middle-low grade 85# high bauxite chamotte, and the price difference is about 850 yuan/t.
The flint clay has the characteristics of stable volume, good thermal shock resistance, small water absorption and the like after being calcined at high temperature. The water absorption rate of the flint clay with good sintering degree is less than 5 percent, and the volume density is more than 2.55g/cm 3 。
At present, no related record of using clay clinker flint clay to replace high-aluminum bauxite chamotte for producing the sliding nozzle brick is found in a steelmaking system, and no related literature report of using clay clinker flint clay for producing and applying in composite sliding nozzle brick outer materials is found.
Disclosure of Invention
The invention solves the technical problem of providing the application of clay clinker flint clay to replace high bauxite clinker in the outer layer material of the composite sliding nozzle brick.
The invention adopts the following technical scheme for solving the technical problems, and the application of clay clinker flint clay on the composite sliding nozzle brick outer layer material is characterized in that the composite sliding nozzle brick outer layer material consists of the following raw materials in percentage by weight:
further defined, the composite sliding nozzle brick outer layer material consists of the following raw materials in percentage by weight:
the invention relates to a preparation method of a composite sliding nozzle brick outer layer material, which is characterized by comprising the following specific steps:
step S1, mixing materials, namely respectively weighing raw flint clay aggregate, high bauxite chamotte fine powder, soft clay powder and a binding agent aluminum dihydrogen phosphate solution according to a mixing ratio, firstly putting the flint clay aggregate into a wet mill for uniform mixing, then adding the binding agent for clean mixing for 3-5 minutes, adding the high bauxite chamotte fine powder and the soft clay powder, and uniformly mixing in the wet mill;
s2, ageing the materials, namely adding the evenly-kneaded pug into a special container, ageing the materials for at least 8 hours;
s3, molding, namely adding the trapped pug into a mold to perform composite compression molding;
s4, drying, namely drying the pressed semi-finished product;
s5, hooping, namely placing the dried semi-finished product on a hooping platform for hooping;
s6, grinding, namely placing the semi-finished product sleeved with the hoop on a special grinding machine for grinding;
and S7, coating in batches, namely placing the ground semi-finished product on a tooling platform for surface coating, surface coating and drying.
Compared with the prior art, the invention has the following advantages and beneficial effects:
because flint clay has high refractoriness, has the characteristics of stable volume, good thermal shock resistance, small water absorption rate and the like after high-temperature calcination, and because the prepared composite sliding nozzle brick outer layer material is not in direct contact with molten steel, the composite sliding nozzle brick outer layer material can be used as aggregate to replace high-aluminum bauxite clinker aggregate on the sliding nozzle brick outer layer material, the use requirement can be met, and the production cost of products is effectively reduced.
Detailed Description
The specific technical scheme of the invention is described in detail with reference to specific embodiments.
Description of the preferred embodiments
Aggregate index of flint clay clinker adopted
Inspection item | AL2O3 | Fe2O3 | Body density | K2O+Na2O | CaO+MgO | Loss of burning |
Inspection standard | ≥45 | ≤1.6 | ≥2.5 | ≤0.4 | ≤0.6 | ≤0.3 |
The adopted high bauxite chamotte fine powder is of 85# grade with 180 meshes
The adopted soft clay is Guangxi white clay with 180 meshes
The specific gravity of the adopted binding agent aluminum dihydrogen phosphate solution is more than or equal to 1.5g/cm 3
The raw materials (Kg) are respectively weighed according to the following weight proportion:
specification of specification | 1 | 2 | 3 | 4 | |
Flint clay aggregate | 5-0mm | 60 | 70 | 64 | 65 |
Bauxite chamotte fines | 180 mesh | 30 | 20 | 25 | 21 |
Soft clay powder | 180 mesh | 5 | 6 | 5 | 10 |
Binding agent aluminium dihydrogen phosphate solution | 5 | 4 | 6 | 4 |
The preparation method comprises the following steps:
step S1, mixing, namely putting the weighed raw materials including flint clay aggregate, bauxite chamotte fine powder, soft clay powder and a binding agent aluminum dihydrogen phosphate solution into a wet mill for uniform mixing;
s2, ageing the materials, namely adding the evenly-kneaded pug into a special container, ageing the materials for at least 8 hours;
s3, molding, namely adding the trapped pug into a mold to perform composite compression molding;
s4, drying, namely drying the pressed semi-finished product;
s5, hooping, namely placing the dried semi-finished product on a hooping platform for hooping;
s6, grinding, namely placing the semi-finished product sleeved with the hoop on a special grinding machine for grinding;
and S7, coating in batches, namely placing the ground semi-finished product on a tooling platform for surface coating, surface coating and drying.
Typical physical indexes of the composite sliding nozzle brick prepared based on the method and used for production are shown in table 1.
TABLE 1
The composite sliding nozzle brick produced by the composite sliding nozzle brick outer layer material prepared by the embodiment has good effect when 300 sets of composite sliding nozzle bricks are used in a new steel Hua Honggang factory, and experimental data are shown in the following table:
the plate surface crack phenomenon is reduced, the crack degree is light, the diameter expansion is uniform, the plate surface is smooth, no roughening and steel clamping phenomenon occur, the field 3 sliding use requirement can be completely met, and the effect is equivalent to that of a high bauxite aggregate peripheral material product. Particularly, the product is superior to a high bauxite coating material product in the aspect of improving cast hole cracks.
While the basic principles of the invention have been shown and described, there are various changes and modifications to the invention, which fall within the scope of the invention as hereinafter claimed, without departing from the spirit and scope of the invention.
Claims (3)
1. The application of clay clinker flint clay on the composite sliding nozzle brick outer layer material is characterized in that the composite sliding nozzle brick outer layer material is composed of the following raw materials in percentage by weight:
2. the application of flint clay in composite sliding nozzle brick outer layer material according to claim 1, which is characterized in that the composite sliding nozzle brick outer layer material is composed of the following raw materials in percentage by weight:
3. the application of clay clinker flint clay in composite sliding nozzle brick outer layer material according to claim 1 or 2, characterized in that the concrete preparation steps of the composite sliding nozzle brick outer layer material are as follows:
step S1, mixing materials, namely respectively weighing raw flint clay aggregate, high bauxite chamotte fine powder, soft clay powder and a binding agent aluminum dihydrogen phosphate solution according to a mixing ratio, firstly putting the flint clay aggregate into a wet mill for uniform mixing, then adding the binding agent aluminum dihydrogen phosphate solution, carrying out clean mixing for 3-5 minutes, adding the high bauxite chamotte fine powder and the soft clay powder, and carrying out uniform mixing in the wet mill;
s2, ageing the materials, namely adding the evenly-kneaded pug into a special container, ageing the materials for at least 8 hours;
s3, molding, namely adding the trapped pug into a mold to perform composite compression molding;
s4, drying, namely drying the pressed semi-finished product;
s5, hooping, namely placing the dried semi-finished product on a hooping platform for hooping;
s6, grinding, namely placing the semi-finished product sleeved with the hoop on a special grinding machine for grinding;
and S7, coating in batches, namely placing the ground semi-finished product on a tooling platform for surface coating, surface coating and drying.
Priority Applications (1)
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CN202310412614.XA CN116553911A (en) | 2023-04-15 | 2023-04-15 | Application of clay clinker flint clay in composite sliding nozzle brick outer layer material |
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CN202310412614.XA CN116553911A (en) | 2023-04-15 | 2023-04-15 | Application of clay clinker flint clay in composite sliding nozzle brick outer layer material |
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Citations (8)
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---|---|---|---|---|
CN104072175A (en) * | 2014-07-16 | 2014-10-01 | 山国强 | Lint clay brick for cement kiln calciner and preparation method thereof |
CN106116599A (en) * | 2016-06-24 | 2016-11-16 | 武汉科技大学 | One not burnedc lay combines alumino-silicate brick and preparation method thereof |
CN106187236A (en) * | 2016-07-21 | 2016-12-07 | 济源市金峰耐火材料有限公司 | Flint clay composite refractory brick and its preparation method and application |
CN106187248A (en) * | 2016-07-26 | 2016-12-07 | 济源市耐火炉业有限公司 | A kind of MULTILAYER COMPOSITE runner brick and production method thereof |
CN106242594A (en) * | 2016-07-26 | 2016-12-21 | 济源市耐火炉业有限公司 | A kind of clay corundum mullite rock is combined runner brick and production method thereof |
WO2018006885A1 (en) * | 2016-07-04 | 2018-01-11 | 济南圣泉倍进陶瓷过滤器有限公司 | Ceramic powder composition, straight hole ceramic filter and preparation method therefor |
CN108585805A (en) * | 2018-06-21 | 2018-09-28 | 德清凯瑞新材料有限公司 | Packet permanent layer castable and preparation method thereof in one kind |
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-
2023
- 2023-04-15 CN CN202310412614.XA patent/CN116553911A/en active Pending
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CN104072175A (en) * | 2014-07-16 | 2014-10-01 | 山国强 | Lint clay brick for cement kiln calciner and preparation method thereof |
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CN106242594A (en) * | 2016-07-26 | 2016-12-21 | 济源市耐火炉业有限公司 | A kind of clay corundum mullite rock is combined runner brick and production method thereof |
CN108585805A (en) * | 2018-06-21 | 2018-09-28 | 德清凯瑞新材料有限公司 | Packet permanent layer castable and preparation method thereof in one kind |
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Non-Patent Citations (1)
Title |
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中国冶金百科全书总编辑委员会《耐火材料》卷编辑委员会: "《中国冶金百科全书 耐火材料》", vol. 1, 31 October 1997, 冶金工业出版社, pages: 76 * |
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