CN1165490C - Process of treatment for waste smell by using microbe fixed cillium ball, and bio-reactor therefor - Google Patents
Process of treatment for waste smell by using microbe fixed cillium ball, and bio-reactor therefor Download PDFInfo
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- CN1165490C CN1165490C CNB981243355A CN98124335A CN1165490C CN 1165490 C CN1165490 C CN 1165490C CN B981243355 A CNB981243355 A CN B981243355A CN 98124335 A CN98124335 A CN 98124335A CN 1165490 C CN1165490 C CN 1165490C
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- biological decomposition
- malodorant
- mentioned
- reactive tank
- decomposition groove
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Abstract
A process of the treatment for malodorous substances and its apparatus are disclosed. Circular villiform contact filtration materials as microbe carriers treat with high concentration organic malodorous substances. In first step, pH is round neutrality using NaOH and H2SO4. In second step, the substances such as bacteria, mildew or the like treat with NH3, H2S, methanthiol(CH3SH) or the like in the malodorous substances. The invention is characterized in that, cyclic disperser and neutralization agent adding tube are provided between the reaction tank (2) in first step. In second step, there is provided with a biolysis carrier layer, and porous villiform medium and water distributor in the decomposer, in first step of adding caustic soda and sulphuric acid there is provided with a cyclic dispersed-air tube and a dispersing dividing panel, in second step microbial circular villiform contact filtration materials and porous pearlite are added into the decomposer.
Description
Technical field
As shown in Figure 1, the present invention relates to a kind of method of wastewater treatment and device thereof, this method comprises: in fine hair shape contact percolation material, form following puberulus fine hair shape contact percolation material, this material is made by PP and nylon, has good tack, by many hair (fine hair, cilium) form, have circular configuration, above-mentioned puberulus length is in the scope of 3~10mm.
Background technology
As the very high place of malodorant concentration, comprise fecaluria, livestock products, alcohol, castoff, slaughterhouse, in serious occasion, the concentration of organic malodorant can reach more than the 500ppm.When organic malodorant concentration is higher, passing through corruption, under the situation that the existing soil body processing constructional method that adopts soil, gravel etc. is handled malodorant, because the pore that not only can occur in the medium stops up, the phenomenon of carrier layer sealing, and because of the breeding of the property bacterium that is sick of, the density unevenness of malodorant is spared, processing efficiency must reduce like this, and floor space is bigger.
Summary of the invention
Therefore, the object of the present invention is to provide a kind of treatment unit and method, these apparatus and method adopt following circular fine hair shape contact percolation material, according to removing method, organic malodorant of high density and hard-degraded substance are handled, be fixed with bacterium and mould by solidification treatment on this filtering material, even this bacterium and mould still can breed under higher organic concentration condition in a large number, and tack is very strong.
Specifically, the present invention relates to:
1). a kind of deodorizing equipment, it comprises pH reactive tank (2), is positioned at the biological decomposition groove (14) on pH reactive tank top, as the dispersion dividing plate (3) on the border of above-mentioned pH reactive tank (2) and biological decomposition groove (14), it is characterized in that:
Be connected with influx (1), circulation diffuser (11), neutralizing agent input port (10) and mud vent pipe (13) that the stench inflow flows in the bottom of above-mentioned pH reactive tank (2); Be filled with circular fine hair shape contact percolation material (4) and porousness perlite (12) in the above-mentioned biological decomposition groove (14), be provided with bacterial classification supply and the water distributor (5) of bacterium and mould at an upper portion thereof; Topmost at above-mentioned biological decomposition groove (14) becomes to connect the vent pipe (15) that is used for discharging by the treating water of above-mentioned reactive tank (2) and biological decomposition groove (14).
2). above-mentioned 1) deodorizing equipment, wherein be provided with dividing plate (7) on the top of above-mentioned biological decomposition groove (14).
3). a kind of usefulness above-mentioned 1) deodorizing equipment carry out the method that stench is handled, it is characterized in that comprising:
After in above-mentioned pH reactive tank (2), dropping into the stench inflow, regulate pH and under aerobic and anaerobic condition, make the 1st step of bacterium and yeast growth;
To be transported to biological decomposition groove (14) through the stench inflow of the 1st step, supply with bacterial classification, remove malodorous the 2nd step after making bacterium and mold propagates with the fine hair shape contact percolation material (4) of circle and porousness perlite to biological decomposition groove (14).
4). above-mentioned 3) method, wherein the stench inflow of Tou Ruing is acidity or alkaline organic.
5). above-mentioned 4) method, wherein said acidity or alkaline organic are to be selected from NH
3, H
2S or thiomethyl alcohol (CH
3The organism of SH) more than one.
6). above-mentioned 4) method, it is characterized in that to malodorant concentration being that 500ppm, pH are that the stench inflow of 3-8 is handled.
7). above-mentioned 3) or 4) method, it is characterized in that in the 2nd operation, filling the microorganism that is fixed on the carrier, this immobilized microorganism prepares as follows: when existing microorganism is carried out inoculation, will be to the malodorant decomposability of high-enriched organics and difficult degradation good microorganism Bacillus licheniformis, bacillus megaterium, achromobacter class, intermediate thiobacilli, mould, nutrient solution to these bacterial strains under 60 ℃ temperature carries out air seasoning, is fixed in circular being on the contact percolation material that the fine hair shape twines mutually then.
Below the present invention is specifically described.
Description of drawings
Fig. 1 is for adopting the malodorant treating processes figure of circular fine hair shape contact percolation material of the present invention.
Fig. 2 represents in the circular fine hair shape contact percolation material of the present invention, the shorter filtering material of villus length in the scope of 3~10mm.
Fig. 3 represents in the circular fine hair shape contact percolation material of the present invention, through the fine hair filtering material of microbial immobilized processing.
Fig. 4 represents of the present invention, the porousness perlite medium of diameter about 5mm.
The present invention is made of two steps substantially, and the 1st step is: by the input port, utilize the circulation diffuser, acidity and the alkaline malodorant of high concentration neutralized. The 2nd step is: by being attached with the circular fine hair shape contact filtration material of bacterium, mould, remove the NH of high concentration3、H
2S and methyl mercaptan (CH3SH)。
According to this step, by water distributor is set, regulate moisture, bacterium, mould that input inoculum agent or process immobilization are processed have higher activity.
The 3rd step is, when malodorant enters the acidity of high concentration or alkaline organic reactive tank (2) by malodorant inflow entrance (1), by nertralizer input port (10), drop into pH value conditioning agent, the pH value is adjusted in 6~8 the scope, mix by circulation diffuser (11), by the dispersion dividing plate (3) at middle part, the power set such by hair-dryer are sent to the top with the said mixture material.
According to the 2nd step, will put in the malodorant biological treatment decomposer (14) through the fixing circular fine hair shape contact filtration material (4) of processing and inoculum agent, be provided with water distributor (5) on top. In addition, the ∧ shape dividing plate (7) that is provided for making the malodorant through final processing to flow out. In addition, as required, can in the 2nd step, the biological decomposition groove more than 2 be set.
The invention is characterized in: the malodorant in the 1st step flows into reactive tank (2) afterwards, and the inside of the biological decomposition groove (14) that the processing malodorant in the 2nd step is used is filled with circular fine hair shape contact filtration material (4) and porous perlite (12). In the 1st step, reactive tank adopts the reason of circulation diffuser to be: when high-concentration acidic wastewater or the inflow of alkaline malodorant, by stirring and circulation, the pH value is adjusted to 6~8 neutral degree, thereby prevents that malodorant in statu quo flows in the 2nd step. In addition, the interior dispersion dividing plate (3) of reactive tank that is arranged on the 1st step can make its dispersion, and keep stable when the malodorant inflow porous disc of high concentration, increases the treatment effeciency of malodorant.
In addition, in the 2nd step, the reason that is filled with the circular fine hair shape contact filtration material of processing through immobilization in the biological decomposition groove is: in the 1st step, when the pH value is adjusted to neutral malodorant inflow, malodorant is adsorbed on the circular fine hair shape contact filtration material, lure thus bacterium and mold propagates into, with malodorant bigger contact area is arranged, thereby in the short period of time it is processed, and Another reason is: for the variation of the pH value of the malodorant that produces in the 1st step, change with the organic concentration load, the biology that employing is adhered to by filling porous fine hair shape material, is easy to realize that oxygen is towards the transmission on the whole surface of contact filtration material, and malodorant transmits towards the dispersion on this surface, thereby can be with the gas discharge that purified.
Therefore, the objective of the invention is in the biological decomposition groove, arrange fine hair shape contact filtration material, the organic malodorant of high concentration and ammonia are carried out Transformatin, thereby remove malodorant. For high concentration Organic malodorant, generally adopt active carbon adsorption to process and chemical treatment, but in the present invention, malodorant is not carried out Chemical Pretreatment, and in the 1st step, directly inject.
In general, the high concentration malodorant is that the pH value is 3 acid malodorant, even but find that also the present invention also is suitable in the pH of malodorant value in 3~8 scopes, still can process by this treating apparatus, according to the present invention, owing to saved the expense of regulating the necessary chemical reagent of pH value, catalyst neither be essential in addition, and the leaked-in air of employing own has reduced operating expenses and maintenance management expense in the 1st step like this. But, because the pH value acid or alkaline malodorant of high concentration presents lack of uniformity, as adding caustic soda, sulfuric acid, promote it to decompose by the conditioning agent that is fit to, thereby improve the removal efficient of malodorant.
Aspect nitrogen and the sulphur, the 2nd step of adding bacterial classification plays an important role in removing the biological decomposition groove. Adoptable inoculum agent comprises bacillus cereus, hay bacillus, bacillus licheniformis, Thiobacillus pars intermedia etc. When in the 2nd step, injecting bacterium, in fine hair shape filtering material layer, microorganism takes off matter and oxidation, and organic matter is decomposed, and organic nutrient substance, nitrogen compound carry out nitrite acidizing to be processed, there is being Nitrosomas to carry out in the situation of nitrated processing, remove ammonia by nitrobacteria, this is external to have in the situation that hydrogen sulfide exists, and oxidizing bacteria, Thiobacillus and der Pilz that the sulfuration bacterium forms make element sulphur become lead sulfate, thread sulfur bacteria is as autotrophic bacterium, with H2S is as the energy. Promote the breeding of other Beggiatoa, Thiothrix and mould.
Except above-mentioned steps, if in the 1st step, breeding has the mud of bacterium mould to become black, then must discharge the mud of reactive tank inside. Be provided with mud discharging pipe (13) in the bottom of reactive tank.
Perhaps, adopt in the following manner bacterium, the der Pilz of microorganism used in the 2nd step, realize the method for processing in the fine hair filtering material, this mode is: under 60 ℃ temperature microbial strain culture is carried out aeration-drying, realize afterwards the immobilization processing. Obviously, adopt method method, that in reactive tank, drop into bacterial classification of processing as common immobilization, can realize the through engineering approaches processing.
Embodiment
With way of example, the effect of apparatus of the present invention and method is described below, the purpose of embodiment is with way of example effect of the present invention and technical characterictic to be described, so these embodiment do not constitute limiting the scope of the invention.
The 1st embodiment
Adopt malodorant treatment unit of the present invention, in the process that waste water is handled, according to the mode of the 1st step and the 2nd step, the night soil plant in Gyeonggi-do, Korea ア ニ ヤ Application city, inject the fecaluria malodorant that fecaluria is handled the field continuously, it is handled.The composition of this fecaluria malodorant is listed in the table below.
Table 1
NH 3(ppm) | 50~120 |
H 2S(ppm) | 12~30 |
The pH value | 6.5 |
By the 1st step of the present invention (pH reactive tank), the 2nd step (biological decomposition groove) above-mentioned malodorant is handled, but the capacity of single pH reactive tank is 150 liters, the capacity of the 2nd biological decomposition groove is 300 liters, the whole residence time of whole and biological decomposition groove is 24 seconds/day, and gas is 2.5 meters/minute by speed.The area of the fine hair shape contact percolation material of being filled in addition also is 1260 meters
2
Table 2
The malodorant processing efficiency
NH 3(ppm) | N.D |
H 2S(ppm) | N.D (odorless) |
Whole process | 99% |
PH value in table 3 reactive tank and the biological decomposition groove
The 1st step | 7.5 |
The 2nd step | 7.9 |
Table 4
When adopting device of the present invention that malodorant is handled, microorganism can be attached on the fine hair shape contact percolation material in apparatus of the present invention, and the microorganism on it is listed in the table below.
The 1st step | Bacterium: bacillus megaterium Pseudomonas aeruginosa |
The 2nd step | Bacterium: Thiobacillus bacillus Nitroaus species nitrobacteria belongs to mushroom: aspergillus, mucor Pusillus etc. |
In addition, the fixedly inoculum agent that is adopted in the present embodiment comprises bacillus cereus, bacillus licheniformis, bacillus megaterium, achromobacter, Thiobacillus pars intermedia.
The 2nd embodiment
Adopt the 1st step and the 2nd step in the wastewater treatment process of the present invention, the livestock products malodorant below injecting is continuously handled malodorant simultaneously.The composition of the livestock products malodorant of イ チ ヨ Application night soil plant is listed in the table below.
Table 5
NH 3(ppm) | 20 |
H 2S(ppm) | 10 |
The pH value | 7.9 |
When in the 1st step (pH reactive tank) and the 2nd step, dropping into circular fine hair shape contact percolation material, by the 2nd step malodorant is handled, but the capacity of biological decomposition groove is 300 liters.The residence time of biological decomposition groove integral body is 20 seconds/day, and wind speed is 3.0 meters/minute.The area of the fine hair shape contact percolation material of being filled in each biological decomposition groove is 1260 meters
2
Table 6
The malodorant processing efficiency
NH 3(ppm) | N.D |
H 2S(ppm) | 0.02 |
Whole process | 99% |
PH value in table 7 reactive tank and the biological decomposition groove
The 1st step | 7.5 |
The 2nd step | 7.3 |
Table 8
Carrying out malodorant of the present invention when handling, particularly when the livestock products malodorant was handled, the fixation of microbe of handling malodorant attached to being used on the fine hair shape contact percolation material was listed in the table below.
The 1st step | Bacterium: bacillus megaterium Pseudomonas aeruginosa algae: singly connect Trentepohlia, Chrococuis |
The 2nd step | General bacterium: the nitronic acid bacterium such as bacillus megaterium bacillus licheniformis: the single fertile Pseudomonas Nitorcoccus nitrobacteria of nitrosation belongs to nitrococcus sulphation bacterium: Thiobacillus pars intermedia Thiomicrospum pelophila spiral microorganism |
By analyzing foregoing technical scheme of the present invention and effect, adopt wastewater treatment equipment of the present invention and method as can be seen, when handling the organic malodorant of high density, NH
3And H
2Removal effect of organic matter such as S are remarkable, also show in addition and can also remove thiomethyl alcohol (NH
3SH).Its concrete processing efficiency also specifically describes in an embodiment of the present invention.
The implication of each label is as follows among Fig. 1
1. 7. dividing plate biological decomposition groove of influx
2. 10. neutralizing agent input port relief outlet of reactive tank
4. fine hair shape filtering material porousness perlite
5. bacterial classification enters the mouth and water distributor mud discharging pipe
Claims (7)
1. deodorizing equipment, it comprises pH reactive tank (2), is positioned at the biological decomposition groove (14) on pH reactive tank top, as the dispersion dividing plate (3) on the border of above-mentioned pH reactive tank (2) and biological decomposition groove (14), it is characterized in that:
Be connected with influx (1), circulation diffuser (11), neutralizing agent input port (10) and mud vent pipe (13) that the stench inflow flows in the bottom of above-mentioned pH reactive tank (2); Be filled with circular fine hair shape contact percolation material (4) and porousness perlite (12) in the above-mentioned biological decomposition groove (14), be provided with bacterial classification supply and the water distributor (5) of bacterium and mould at an upper portion thereof; Topmost at above-mentioned biological decomposition groove (14) becomes to connect the vent pipe (15) that is used for discharging by the treating water of above-mentioned reactive tank (2) and biological decomposition groove (14).
2. the deodorizing equipment of claim 1 wherein is provided with dividing plate (7) on the top of above-mentioned biological decomposition groove (14).
3. the deodorizing equipment with claim 1 carries out the method that stench is handled, and it is characterized in that comprising:
After in above-mentioned pH reactive tank (2), dropping into the stench inflow, regulate pH and under aerobic conditions, make the 1st step of bacterium and mold propagates;
To be transported to biological decomposition groove (14) through the stench inflow of the 1st step, supply with bacterial classification, remove malodorous the 2nd step after making bacterium and mold propagates with the fine hair shape contact percolation material (4) of circle and porousness perlite to biological decomposition groove (14).
4. the method for claim 3, wherein the stench inflow of Tou Ruing is acidity or alkaline organic.
5. the method for claim 4, wherein said acidity or alkaline organic are to be selected from NH
3, H
2S or thiomethyl alcohol (CH
3The organism of SH) more than one.
6. the method for claim 4 is characterized in that to malodorant concentration being that 500ppm, pH are that the stench inflow of 3-8 is handled.
7. claim 3 or 4 method, it is characterized in that in the 2nd operation, filling the microorganism that is fixed on the carrier, this immobilized microorganism prepares as follows: when existing microorganism is carried out inoculation, will be to the malodorant decomposability of high-enriched organics and difficult degradation good microorganism Bacillus licheniformis, bacillus megaterium, achromobacter class, intermediate thiobacilli, mould, nutrient solution to these bacterial strains under 60 ℃ temperature carries out air seasoning, is fixed in circular being on the contact percolation material that the fine hair shape twines mutually then.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR50921/97 | 1997-10-02 | ||
KR1019970050921A KR100260979B1 (en) | 1997-10-02 | 1997-10-02 | A process of the treatment for waste smell by using microbe fixed cillium ball, and the bio-reactor therefor |
KR50921/1997 | 1997-10-02 |
Publications (2)
Publication Number | Publication Date |
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CN1230525A CN1230525A (en) | 1999-10-06 |
CN1165490C true CN1165490C (en) | 2004-09-08 |
Family
ID=19522179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB981243355A Expired - Fee Related CN1165490C (en) | 1997-10-02 | 1998-10-02 | Process of treatment for waste smell by using microbe fixed cillium ball, and bio-reactor therefor |
Country Status (2)
Country | Link |
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KR (1) | KR100260979B1 (en) |
CN (1) | CN1165490C (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100324727B1 (en) * | 1999-04-15 | 2002-02-28 | 한기백 | Separating apparatus of suspended solid in liquid solution using flexible fiber |
KR100360846B1 (en) * | 1999-11-15 | 2002-11-22 | 주식회사 태백종합환경기술단 | A floating biofilm media for odor control in wastewater treatment process |
KR100471385B1 (en) * | 2002-10-30 | 2005-03-10 | 한국과학기술연구원 | Purification apparatus and process for streamwater using Pearlite attached Polyethylene Net and Bulged Polypropylene media |
NZ555673A (en) * | 2004-11-22 | 2010-12-24 | Nubian Water Systems Pty Ltd | Waste water treatment process system with circulating filter bed and aeration means |
KR100971530B1 (en) * | 2009-09-08 | 2010-07-21 | 삼성엔지니어링 주식회사 | Wastewater treatment apparatus having bioreactor filled with media containing immobilized microbe and method of treating wastewater |
JP4565669B1 (en) * | 2010-04-19 | 2010-10-20 | 三菱重工環境・化学エンジニアリング株式会社 | Air diffuser and diffuser for sludge fluidized bed incinerator |
CN102826647B (en) * | 2012-08-15 | 2014-03-12 | 哈尔滨工业大学宜兴环保研究院 | Aerobic denitrification reactor with mycelium pellet as carrier and method for synchronous operation of nitrification and denitrification |
CN103922485B (en) * | 2014-04-04 | 2016-03-30 | 于美萍 | A kind of sewage deodorizing processing method |
CN103922472B (en) * | 2014-04-14 | 2016-03-02 | 北京工业大学 | The device and method of the denitrogenation of a kind of A/O process strengthening and biological deodorizing |
CN104495879B (en) * | 2015-01-12 | 2016-05-11 | 武汉大学 | A kind of integrated form catalytic oxidation/dephosphorization denitrogenation-isolated by filtration bioreactor |
-
1997
- 1997-10-02 KR KR1019970050921A patent/KR100260979B1/en not_active IP Right Cessation
-
1998
- 1998-10-02 CN CNB981243355A patent/CN1165490C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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CN1230525A (en) | 1999-10-06 |
KR19990030630A (en) | 1999-05-06 |
KR100260979B1 (en) | 2000-07-01 |
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