CN116536972A - High-strength flame-retardant kraft case board for packaging and preparation method thereof - Google Patents

High-strength flame-retardant kraft case board for packaging and preparation method thereof Download PDF

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Publication number
CN116536972A
CN116536972A CN202310622830.7A CN202310622830A CN116536972A CN 116536972 A CN116536972 A CN 116536972A CN 202310622830 A CN202310622830 A CN 202310622830A CN 116536972 A CN116536972 A CN 116536972A
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CN
China
Prior art keywords
retardant
flame
board
paper core
laminate
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Pending
Application number
CN202310622830.7A
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Chinese (zh)
Inventor
赵志芳
冯荣华
叶青
顾永明
胡荣霞
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Zhejiang Rongsheng Paper Industry Holding Co ltd
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Zhejiang Rongsheng Paper Industry Holding Co ltd
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Priority to CN202310622830.7A priority Critical patent/CN116536972A/en
Publication of CN116536972A publication Critical patent/CN116536972A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • D21H27/40Multi-ply at least one of the sheets being non-planar, e.g. crêped
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

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  • Laminated Bodies (AREA)

Abstract

The invention discloses a high-strength flame-retardant kraft liner board for packaging and a preparation method thereof, and particularly relates to the field of papermaking.

Description

High-strength flame-retardant kraft case board for packaging and preparation method thereof
Technical Field
The invention relates to the field of papermaking, in particular to a high-strength flame-retardant kraft liner board for packaging and a preparation method thereof.
Background
When the common kraft liner board is used, bending conditions often occur, and the gradual deepening of folds can lead to the fracture of the kraft liner board and further affect the use; and the flame retardant effect of the existing kraft liner board is general, and is not ideal under the condition of slightly larger fire.
The Chinese patent publication No. CN211000351U describes a high-strength flame-retardant kraft liner board for packaging, which comprises a core paper layer, the buffer blocks are fixedly arranged on two sides of the core paper layer, the first flame-retardant layer is fixedly bonded on the top side of the buffer blocks, a groove is formed between one side of the first flame-retardant layer opposite to the buffer blocks, the second flame-retardant layer is fixedly bonded on the bottom side of the buffer blocks, the buffer layer is fixedly arranged on the bottom side of the second flame-retardant layer, the adhesive protection layer is fixedly bonded on the top side of the first flame-retardant layer, the high-strength flame-retardant kraft liner board for packaging has the advantages of improving flame retardant property, saving energy and environmental protection, improving economic benefit of the board and saving cost. However, there is no description of a method for obtaining a high-performance flame-retardant kraft liner board by performing specific processing using long fibers and short fibers.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a high-strength flame-retardant kraft case board for packaging and a preparation method thereof, and the technical problems to be solved by the invention are as follows: when the common kraft liner board is used, bending conditions often occur, and the gradual deepening of folds can lead to the fracture of the kraft liner board and further affect the use; and the flame retardant effect of the existing kraft liner board is general, and is not ideal under the condition of slightly larger fire.
In order to achieve the above purpose, the present invention provides the following technical solutions: the utility model provides a high strength fire-retardant cowhide cardboard for packing, the cowhide cardboard includes refill plywood, fire-retardant plywood and buffering plywood, the both sides bonding of refill plywood has fire-retardant plywood, the outside bonding of fire-retardant plywood has corresponding buffering plywood.
A method for preparing a high-strength flame-retardant kraft liner board for packaging, which is used for preparing the high-strength flame-retardant kraft liner board, and comprises the following steps:
s1: obtaining waste clothes and waste corrugated boards;
s2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4;
s3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry;
s4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry;
s5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers;
s6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a paper core laminate;
s7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate;
s8: three paper core laminates are respectively defined as a side paper core laminate and a middle paper core laminate, a plurality of silencing holes are uniformly drilled in the side paper core laminate, a silencing cotton layer is covered on the side surface of the side paper core laminate, and the two sides of the middle paper core laminate are adhered with the side paper core laminate;
s9: the side surfaces of the side paper core laminates are respectively and correspondingly bonded with a flame-retardant laminate;
s10: the outer side of the flame-retardant laminate is bonded with a protective plate, the protective plate layer is coated with elastic paint, and the protective plate layer coated with the elastic paint is called a buffer laminate.
Preferably, the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1.
Preferably, the thickness of the paper core plate is 3mm.
Preferably, the thickness of the noise reduction cotton layer is 1mm.
Preferably, the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is in the range of 20-50mm.
Preferably, the diameter of the silencing holes is 1.5mm, and the silencing holes are arranged in the side paper core layer board in a wave shape.
The invention has the technical effects and advantages that: compared with the existing kraft paper board, the high-strength flame-retardant kraft paper board has higher strength toughness and flame-retardant effect, and the high-strength flame-retardant kraft paper board can be suitable for more environments through the arranged paper core board with high toughness and the flame-retardant layer board with fireproof capability, and the capability of preventing fine cracking on the outer side of the kraft paper board can be improved through the arrangement of the buffer layer board.
Drawings
FIG. 1 is a schematic view of the structure of a high strength flame retardant kraft liner board for packaging of the invention.
The reference numerals are:
1. a paper core laminate; 101. a middle paper core layer board; 102. side position paper core layer board; 2. flame retardant laminate; 3. and (5) buffering the laminate.
Detailed Description
Example 1
Referring to fig. 1, a high-strength flame-retardant kraft liner board for packaging comprises a paper core layer board 1, flame-retardant layer boards 2 and buffer layer boards 3, wherein the flame-retardant layer boards 2 are bonded to two sides of the paper core layer board 1, and the corresponding buffer layer boards 3 are bonded to the outer sides of the flame-retardant layer boards 2. Compared with the existing kraft paper board, the high-strength flame-retardant kraft paper board has higher strength toughness and flame-retardant effect, and the high-strength flame-retardant kraft paper board can be suitable for more environments through the arranged paper core board 1 with high toughness and the flame-retardant layer board 2 with fireproof capability, and the buffer layer board 3 can improve the capability of preventing fine cracking on the outer side of the kraft paper board.
Example two
Referring to fig. 1, based on the above embodiment, a method for preparing a high-strength flame-retardant kraft liner board for packaging is used for the high-strength flame-retardant kraft liner board described in embodiment one, and the method includes:
s1: obtaining waste clothes and waste corrugated boards; selecting cotton clothes, crushing the cotton clothes to obtain clothes fragments with the area smaller than 300 square millimeters, crushing waste corrugated paper boards to obtain paper board fragments with the area smaller than 300 square millimeters, and determining the size of the crushed waste clothes and the crushed waste corrugated paper boards according to the self-manufacturing requirement by a user during specific operation, wherein the fragments with the larger length-diameter ratio are easier to break out fibers, and the embodiment is not limited.
S2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4; when corrugated container board is as the main raw materials of production cowhide cardboard, can provide enough short fiber and long fiber, the clothes can provide more long fiber, and long fiber and short fiber's combination can prepare the different plywood of function, and a plurality of laminates that have different functions match each other, can improve the whole usability of cowhide cardboard.
S3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry; the clothing chips and corrugated board chips are mixed with alkaline solution and white liquor in a digester of a pulp mill and cooked at high temperature to dissolve lignin and separate into cellulose fibers, and then the fibers are washed, screened and bleached to obtain primary pulp containing fibers with uniform color.
S4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry; the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1. The persulfate initiator and the melamine polyphosphate are mixed with the fiber, so that the flame retardant can be prepared in the fiber solution, and the flame retardant has high nitrogen content, low price, high flame retardant efficiency, excellent electrical performance and mechanical performance, no color change, low smoke and low corrosiveness. Meanwhile, the flame retardant is low in toxicity, safe to a user, good in environmental compatibility and good in thermal stability, so that the flame retardant directly attached to the surface layer of the fiber enables the fiber to have a certain flame retardant effect.
S5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers; the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is 20-50mm.
S6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain the paper core laminate 1; the thickness of the paper core plate 1 is 3mm. Because the flame-retardant long fibers have the flame-retardant function, the flame-retardant effect of the paper core laminate 1 prepared by polymerizing the flame-retardant long fibers is better than that of a common paper core laminate, wherein the common paper core laminate is prepared by directly brushing flame-retardant paint on the outer side of a paper core; the characteristics of the long fibers enable the paper core layer board 1 to have better toughness, and under the same bending moment, the bending resistance of the paper core layer board 1 in the embodiment is better than that of a paper core made of mixed fibers, wherein the mixed fibers comprise long fibers and short fibers, the ratio of the parts of the long fibers to the parts of the short fibers is not the exact ratio, and the bending resistance of the paper core in the same batch is different.
S7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate 2; the gaps among the flame-retardant short fibers are more, and the retained flame retardant is more, so that the flame retardant has better flame-retardant effect.
S8: three paper core laminates 1 are respectively defined as a side paper core laminate 102 and a middle paper core laminate 101, a plurality of silencing holes are uniformly drilled in the side paper core laminate 102, the diameter of each silencing hole is 1.5mm, the silencing holes are arranged in the side paper core laminate 102 in a wave shape, a silencing cotton layer is covered on the side surface of the side paper core laminate, the thickness of the silencing cotton layer is 1mm, and the side paper core laminates 102 are adhered to two sides of the middle paper core laminate 101;
s9: the side surfaces of the side paper core laminates 102 are respectively and correspondingly bonded with the flame-retardant laminate 2; the combined use of the side-position paper core layer board 102 and the middle-position paper core layer board 101 greatly improves the overall toughness and flame retardant capability, and the use of the silencing holes and the silencing cotton enables the side-position paper core layer board 102 and the middle-position paper core layer board 101 to have a certain sound insulation effect, so that even if a noise source is placed in the kraft liner board, a certain silencing effect can be achieved. It can be appreciated that this design can be applied to the side of stereo set for keep apart stereo set shell body and sound production module, make the sound that the stereo set sent can not spill over from the side of shell body as far as possible, if take place to fire, fire-retardant effect can be from the side protection sound production module of shell body to a certain extent avoid burning out.
S10: the outer side of the flame-retardant laminate 2 is bonded with a protective plate, the protective plate is coated with elastic paint, and the protective plate coated with elastic paint is called a buffer laminate 3. The protective plate can be made of a common corrugated paperboard layer, and is coated with an elastic coating, wherein the elastic coating is prepared by taking synthetic resin emulsion as a base material, pigment, filler and auxiliary agent, and after a certain thickness is applied, the dry film thickness is greater than or equal to 150 mu m, and the elastic coating has elastic functional coating for covering tiny cracks generated by bending of a base material, and can further improve the overall toughness of the kraft liner board.

Claims (7)

1. A high strength flame retardant kraft liner board for packaging, characterized in that: the kraft case board comprises a paper core board (1), a flame-retardant board (2) and a buffer board (3), wherein the flame-retardant board (2) is bonded to two sides of the paper core board (1), and the corresponding buffer board (3) is bonded to the outer side of the flame-retardant board (2).
2. A method for preparing a high-strength flame-retardant kraft liner board for packaging, which is used for preparing the high-strength flame-retardant kraft liner board described in claim 1, and is characterized in that: the method comprises the following steps:
s1: obtaining waste clothes and waste corrugated boards;
s2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4;
s3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry;
s4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry;
s5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers;
s6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a paper core layer board (1);
s7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate (2);
s8: three paper core laminates (1) are taken and respectively defined as a side paper core laminate (102) and a middle paper core laminate (101), a plurality of silencing holes are uniformly drilled in the side paper core laminate (102), a silencing cotton layer is covered on the side surface of the side paper core laminate, and the side paper core laminates (102) are adhered to the two sides of the middle paper core laminate (101);
s9: the side surfaces of the side paper core laminates (102) are respectively and correspondingly bonded with the flame-retardant laminates (2); .
S10: the outer side of the flame-retardant laminate (2) is bonded with a protective plate, the protective plate layer is coated with elastic paint, and the protective plate layer coated with the elastic paint is called a buffer laminate (3).
3. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1.
4. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the thickness of the paper core layer plate (1) is 3mm.
5. The method for producing a high strength flame retardant kraft liner board for packaging as claimed in claim 4, wherein: the thickness of the noise reduction cotton layer is 1mm.
6. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is 20-50mm.
7. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 6, wherein the method comprises the following steps: the diameter of the silencing holes is 1.5mm, and the silencing holes are arranged in the side paper core layer board (102) in a wave-shaped mode.
CN202310622830.7A 2023-05-30 2023-05-30 High-strength flame-retardant kraft case board for packaging and preparation method thereof Pending CN116536972A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107962826A (en) * 2017-12-19 2018-04-27 天津海利成纸制品有限公司 A kind of fire protection flame retarding corrugated board
KR20180053082A (en) * 2016-11-11 2018-05-21 인천대학교 산학협력단 Quasi non-flammable composite panel and Method for manufacturing the same
CN109466123A (en) * 2018-10-31 2019-03-15 重庆华怡蜂窝包装制品有限公司 A kind of high buffer-type packaging boxboard and its manufacturing method
CN109853282A (en) * 2019-03-15 2019-06-07 浙江荣晟环保纸业股份有限公司 A kind of fire-retardant kraft liner board and preparation method thereof using the preparation of fire-retardant secondary stock
CN109881527A (en) * 2019-03-15 2019-06-14 浙江荣晟环保纸业股份有限公司 A kind of fire-retardant secondary stock and its preparation method and application
CN113580674A (en) * 2021-07-31 2021-11-02 乐清市赋源包装有限公司 Environment-friendly corrugated carton and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180053082A (en) * 2016-11-11 2018-05-21 인천대학교 산학협력단 Quasi non-flammable composite panel and Method for manufacturing the same
CN107962826A (en) * 2017-12-19 2018-04-27 天津海利成纸制品有限公司 A kind of fire protection flame retarding corrugated board
CN109466123A (en) * 2018-10-31 2019-03-15 重庆华怡蜂窝包装制品有限公司 A kind of high buffer-type packaging boxboard and its manufacturing method
CN109853282A (en) * 2019-03-15 2019-06-07 浙江荣晟环保纸业股份有限公司 A kind of fire-retardant kraft liner board and preparation method thereof using the preparation of fire-retardant secondary stock
CN109881527A (en) * 2019-03-15 2019-06-14 浙江荣晟环保纸业股份有限公司 A kind of fire-retardant secondary stock and its preparation method and application
CN113580674A (en) * 2021-07-31 2021-11-02 乐清市赋源包装有限公司 Environment-friendly corrugated carton and manufacturing method thereof

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