CN116536972A - High-strength flame-retardant kraft case board for packaging and preparation method thereof - Google Patents
High-strength flame-retardant kraft case board for packaging and preparation method thereof Download PDFInfo
- Publication number
- CN116536972A CN116536972A CN202310622830.7A CN202310622830A CN116536972A CN 116536972 A CN116536972 A CN 116536972A CN 202310622830 A CN202310622830 A CN 202310622830A CN 116536972 A CN116536972 A CN 116536972A
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- Prior art keywords
- retardant
- flame
- board
- paper core
- laminate
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 98
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 239000002655 kraft paper Substances 0.000 title claims abstract description 39
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000123 paper Substances 0.000 claims description 56
- 239000000835 fiber Substances 0.000 claims description 48
- 239000010410 layer Substances 0.000 claims description 29
- 239000002699 waste material Substances 0.000 claims description 21
- 230000030279 gene silencing Effects 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 15
- 239000012792 core layer Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 12
- 230000001681 protective effect Effects 0.000 claims description 10
- 229920000742 Cotton Polymers 0.000 claims description 9
- 229920000877 Melamine resin Polymers 0.000 claims description 7
- 229920000388 Polyphosphate Polymers 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
- 239000003973 paint Substances 0.000 claims description 7
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 7
- 239000001205 polyphosphate Substances 0.000 claims description 7
- 235000011176 polyphosphates Nutrition 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000004537 pulping Methods 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000012141 concentrate Substances 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 description 10
- 239000011120 plywood Substances 0.000 description 8
- 238000005452 bending Methods 0.000 description 6
- 239000011111 cardboard Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000011087 paperboard Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000003139 buffering effect Effects 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000005574 cross-species transmission Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000001743 silencing effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/40—Multi-ply at least one of the sheets being non-planar, e.g. crêped
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a high-strength flame-retardant kraft liner board for packaging and a preparation method thereof, and particularly relates to the field of papermaking.
Description
Technical Field
The invention relates to the field of papermaking, in particular to a high-strength flame-retardant kraft liner board for packaging and a preparation method thereof.
Background
When the common kraft liner board is used, bending conditions often occur, and the gradual deepening of folds can lead to the fracture of the kraft liner board and further affect the use; and the flame retardant effect of the existing kraft liner board is general, and is not ideal under the condition of slightly larger fire.
The Chinese patent publication No. CN211000351U describes a high-strength flame-retardant kraft liner board for packaging, which comprises a core paper layer, the buffer blocks are fixedly arranged on two sides of the core paper layer, the first flame-retardant layer is fixedly bonded on the top side of the buffer blocks, a groove is formed between one side of the first flame-retardant layer opposite to the buffer blocks, the second flame-retardant layer is fixedly bonded on the bottom side of the buffer blocks, the buffer layer is fixedly arranged on the bottom side of the second flame-retardant layer, the adhesive protection layer is fixedly bonded on the top side of the first flame-retardant layer, the high-strength flame-retardant kraft liner board for packaging has the advantages of improving flame retardant property, saving energy and environmental protection, improving economic benefit of the board and saving cost. However, there is no description of a method for obtaining a high-performance flame-retardant kraft liner board by performing specific processing using long fibers and short fibers.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides a high-strength flame-retardant kraft case board for packaging and a preparation method thereof, and the technical problems to be solved by the invention are as follows: when the common kraft liner board is used, bending conditions often occur, and the gradual deepening of folds can lead to the fracture of the kraft liner board and further affect the use; and the flame retardant effect of the existing kraft liner board is general, and is not ideal under the condition of slightly larger fire.
In order to achieve the above purpose, the present invention provides the following technical solutions: the utility model provides a high strength fire-retardant cowhide cardboard for packing, the cowhide cardboard includes refill plywood, fire-retardant plywood and buffering plywood, the both sides bonding of refill plywood has fire-retardant plywood, the outside bonding of fire-retardant plywood has corresponding buffering plywood.
A method for preparing a high-strength flame-retardant kraft liner board for packaging, which is used for preparing the high-strength flame-retardant kraft liner board, and comprises the following steps:
s1: obtaining waste clothes and waste corrugated boards;
s2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4;
s3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry;
s4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry;
s5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers;
s6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a paper core laminate;
s7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate;
s8: three paper core laminates are respectively defined as a side paper core laminate and a middle paper core laminate, a plurality of silencing holes are uniformly drilled in the side paper core laminate, a silencing cotton layer is covered on the side surface of the side paper core laminate, and the two sides of the middle paper core laminate are adhered with the side paper core laminate;
s9: the side surfaces of the side paper core laminates are respectively and correspondingly bonded with a flame-retardant laminate;
s10: the outer side of the flame-retardant laminate is bonded with a protective plate, the protective plate layer is coated with elastic paint, and the protective plate layer coated with the elastic paint is called a buffer laminate.
Preferably, the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1.
Preferably, the thickness of the paper core plate is 3mm.
Preferably, the thickness of the noise reduction cotton layer is 1mm.
Preferably, the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is in the range of 20-50mm.
Preferably, the diameter of the silencing holes is 1.5mm, and the silencing holes are arranged in the side paper core layer board in a wave shape.
The invention has the technical effects and advantages that: compared with the existing kraft paper board, the high-strength flame-retardant kraft paper board has higher strength toughness and flame-retardant effect, and the high-strength flame-retardant kraft paper board can be suitable for more environments through the arranged paper core board with high toughness and the flame-retardant layer board with fireproof capability, and the capability of preventing fine cracking on the outer side of the kraft paper board can be improved through the arrangement of the buffer layer board.
Drawings
FIG. 1 is a schematic view of the structure of a high strength flame retardant kraft liner board for packaging of the invention.
The reference numerals are:
1. a paper core laminate; 101. a middle paper core layer board; 102. side position paper core layer board; 2. flame retardant laminate; 3. and (5) buffering the laminate.
Detailed Description
Example 1
Referring to fig. 1, a high-strength flame-retardant kraft liner board for packaging comprises a paper core layer board 1, flame-retardant layer boards 2 and buffer layer boards 3, wherein the flame-retardant layer boards 2 are bonded to two sides of the paper core layer board 1, and the corresponding buffer layer boards 3 are bonded to the outer sides of the flame-retardant layer boards 2. Compared with the existing kraft paper board, the high-strength flame-retardant kraft paper board has higher strength toughness and flame-retardant effect, and the high-strength flame-retardant kraft paper board can be suitable for more environments through the arranged paper core board 1 with high toughness and the flame-retardant layer board 2 with fireproof capability, and the buffer layer board 3 can improve the capability of preventing fine cracking on the outer side of the kraft paper board.
Example two
Referring to fig. 1, based on the above embodiment, a method for preparing a high-strength flame-retardant kraft liner board for packaging is used for the high-strength flame-retardant kraft liner board described in embodiment one, and the method includes:
s1: obtaining waste clothes and waste corrugated boards; selecting cotton clothes, crushing the cotton clothes to obtain clothes fragments with the area smaller than 300 square millimeters, crushing waste corrugated paper boards to obtain paper board fragments with the area smaller than 300 square millimeters, and determining the size of the crushed waste clothes and the crushed waste corrugated paper boards according to the self-manufacturing requirement by a user during specific operation, wherein the fragments with the larger length-diameter ratio are easier to break out fibers, and the embodiment is not limited.
S2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4; when corrugated container board is as the main raw materials of production cowhide cardboard, can provide enough short fiber and long fiber, the clothes can provide more long fiber, and long fiber and short fiber's combination can prepare the different plywood of function, and a plurality of laminates that have different functions match each other, can improve the whole usability of cowhide cardboard.
S3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry; the clothing chips and corrugated board chips are mixed with alkaline solution and white liquor in a digester of a pulp mill and cooked at high temperature to dissolve lignin and separate into cellulose fibers, and then the fibers are washed, screened and bleached to obtain primary pulp containing fibers with uniform color.
S4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry; the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1. The persulfate initiator and the melamine polyphosphate are mixed with the fiber, so that the flame retardant can be prepared in the fiber solution, and the flame retardant has high nitrogen content, low price, high flame retardant efficiency, excellent electrical performance and mechanical performance, no color change, low smoke and low corrosiveness. Meanwhile, the flame retardant is low in toxicity, safe to a user, good in environmental compatibility and good in thermal stability, so that the flame retardant directly attached to the surface layer of the fiber enables the fiber to have a certain flame retardant effect.
S5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers; the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is 20-50mm.
S6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain the paper core laminate 1; the thickness of the paper core plate 1 is 3mm. Because the flame-retardant long fibers have the flame-retardant function, the flame-retardant effect of the paper core laminate 1 prepared by polymerizing the flame-retardant long fibers is better than that of a common paper core laminate, wherein the common paper core laminate is prepared by directly brushing flame-retardant paint on the outer side of a paper core; the characteristics of the long fibers enable the paper core layer board 1 to have better toughness, and under the same bending moment, the bending resistance of the paper core layer board 1 in the embodiment is better than that of a paper core made of mixed fibers, wherein the mixed fibers comprise long fibers and short fibers, the ratio of the parts of the long fibers to the parts of the short fibers is not the exact ratio, and the bending resistance of the paper core in the same batch is different.
S7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate 2; the gaps among the flame-retardant short fibers are more, and the retained flame retardant is more, so that the flame retardant has better flame-retardant effect.
S8: three paper core laminates 1 are respectively defined as a side paper core laminate 102 and a middle paper core laminate 101, a plurality of silencing holes are uniformly drilled in the side paper core laminate 102, the diameter of each silencing hole is 1.5mm, the silencing holes are arranged in the side paper core laminate 102 in a wave shape, a silencing cotton layer is covered on the side surface of the side paper core laminate, the thickness of the silencing cotton layer is 1mm, and the side paper core laminates 102 are adhered to two sides of the middle paper core laminate 101;
s9: the side surfaces of the side paper core laminates 102 are respectively and correspondingly bonded with the flame-retardant laminate 2; the combined use of the side-position paper core layer board 102 and the middle-position paper core layer board 101 greatly improves the overall toughness and flame retardant capability, and the use of the silencing holes and the silencing cotton enables the side-position paper core layer board 102 and the middle-position paper core layer board 101 to have a certain sound insulation effect, so that even if a noise source is placed in the kraft liner board, a certain silencing effect can be achieved. It can be appreciated that this design can be applied to the side of stereo set for keep apart stereo set shell body and sound production module, make the sound that the stereo set sent can not spill over from the side of shell body as far as possible, if take place to fire, fire-retardant effect can be from the side protection sound production module of shell body to a certain extent avoid burning out.
S10: the outer side of the flame-retardant laminate 2 is bonded with a protective plate, the protective plate is coated with elastic paint, and the protective plate coated with elastic paint is called a buffer laminate 3. The protective plate can be made of a common corrugated paperboard layer, and is coated with an elastic coating, wherein the elastic coating is prepared by taking synthetic resin emulsion as a base material, pigment, filler and auxiliary agent, and after a certain thickness is applied, the dry film thickness is greater than or equal to 150 mu m, and the elastic coating has elastic functional coating for covering tiny cracks generated by bending of a base material, and can further improve the overall toughness of the kraft liner board.
Claims (7)
1. A high strength flame retardant kraft liner board for packaging, characterized in that: the kraft case board comprises a paper core board (1), a flame-retardant board (2) and a buffer board (3), wherein the flame-retardant board (2) is bonded to two sides of the paper core board (1), and the corresponding buffer board (3) is bonded to the outer side of the flame-retardant board (2).
2. A method for preparing a high-strength flame-retardant kraft liner board for packaging, which is used for preparing the high-strength flame-retardant kraft liner board described in claim 1, and is characterized in that: the method comprises the following steps:
s1: obtaining waste clothes and waste corrugated boards;
s2: putting the waste clothes and the waste corrugated boards into a pulping system according to the part ratio of 1:4;
s3, performing S3; the pulping system breaks, bleaches, screens and concentrates the waste clothes and the waste corrugated board to prepare primary slurry;
s4: adding persulfate initiator and melamine polyphosphate into the primary slurry, and stirring to obtain secondary slurry;
s5: stirring the secondary slurry, and screening to obtain flame-retardant long fibers and flame-retardant short fibers;
s6: taking out the flame-retardant long fibers, mixing the flame-retardant long fibers and the papermaking auxiliary agent according to the part ratio of 5:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a paper core layer board (1);
s7: taking out the flame-retardant short fibers, mixing the flame-retardant short fibers and the papermaking auxiliary agent according to the part ratio of 8:1, and carrying out papermaking, squeezing, drying, surface sizing and drying to obtain a flame-retardant laminate (2);
s8: three paper core laminates (1) are taken and respectively defined as a side paper core laminate (102) and a middle paper core laminate (101), a plurality of silencing holes are uniformly drilled in the side paper core laminate (102), a silencing cotton layer is covered on the side surface of the side paper core laminate, and the side paper core laminates (102) are adhered to the two sides of the middle paper core laminate (101);
s9: the side surfaces of the side paper core laminates (102) are respectively and correspondingly bonded with the flame-retardant laminates (2); .
S10: the outer side of the flame-retardant laminate (2) is bonded with a protective plate, the protective plate layer is coated with elastic paint, and the protective plate layer coated with the elastic paint is called a buffer laminate (3).
3. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the ratio of the parts of the primary slurry to the persulfate initiator to the melamine polyphosphate is 10:0.5:1.
4. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the thickness of the paper core layer plate (1) is 3mm.
5. The method for producing a high strength flame retardant kraft liner board for packaging as claimed in claim 4, wherein: the thickness of the noise reduction cotton layer is 1mm.
6. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 2, wherein the method comprises the following steps: the length of the flame-retardant long fiber is more than 50mm, and the length of the flame-retardant short fiber is 20-50mm.
7. The method for preparing the high-strength flame-retardant kraft liner board for packaging according to claim 6, wherein the method comprises the following steps: the diameter of the silencing holes is 1.5mm, and the silencing holes are arranged in the side paper core layer board (102) in a wave-shaped mode.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN202310622830.7A CN116536972A (en) | 2023-05-30 | 2023-05-30 | High-strength flame-retardant kraft case board for packaging and preparation method thereof |
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CN202310622830.7A CN116536972A (en) | 2023-05-30 | 2023-05-30 | High-strength flame-retardant kraft case board for packaging and preparation method thereof |
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CN116536972A true CN116536972A (en) | 2023-08-04 |
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CN202310622830.7A Pending CN116536972A (en) | 2023-05-30 | 2023-05-30 | High-strength flame-retardant kraft case board for packaging and preparation method thereof |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107962826A (en) * | 2017-12-19 | 2018-04-27 | 天津海利成纸制品有限公司 | A kind of fire protection flame retarding corrugated board |
KR20180053082A (en) * | 2016-11-11 | 2018-05-21 | 인천대학교 산학협력단 | Quasi non-flammable composite panel and Method for manufacturing the same |
CN109466123A (en) * | 2018-10-31 | 2019-03-15 | 重庆华怡蜂窝包装制品有限公司 | A kind of high buffer-type packaging boxboard and its manufacturing method |
CN109853282A (en) * | 2019-03-15 | 2019-06-07 | 浙江荣晟环保纸业股份有限公司 | A kind of fire-retardant kraft liner board and preparation method thereof using the preparation of fire-retardant secondary stock |
CN109881527A (en) * | 2019-03-15 | 2019-06-14 | 浙江荣晟环保纸业股份有限公司 | A kind of fire-retardant secondary stock and its preparation method and application |
CN113580674A (en) * | 2021-07-31 | 2021-11-02 | 乐清市赋源包装有限公司 | Environment-friendly corrugated carton and manufacturing method thereof |
-
2023
- 2023-05-30 CN CN202310622830.7A patent/CN116536972A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180053082A (en) * | 2016-11-11 | 2018-05-21 | 인천대학교 산학협력단 | Quasi non-flammable composite panel and Method for manufacturing the same |
CN107962826A (en) * | 2017-12-19 | 2018-04-27 | 天津海利成纸制品有限公司 | A kind of fire protection flame retarding corrugated board |
CN109466123A (en) * | 2018-10-31 | 2019-03-15 | 重庆华怡蜂窝包装制品有限公司 | A kind of high buffer-type packaging boxboard and its manufacturing method |
CN109853282A (en) * | 2019-03-15 | 2019-06-07 | 浙江荣晟环保纸业股份有限公司 | A kind of fire-retardant kraft liner board and preparation method thereof using the preparation of fire-retardant secondary stock |
CN109881527A (en) * | 2019-03-15 | 2019-06-14 | 浙江荣晟环保纸业股份有限公司 | A kind of fire-retardant secondary stock and its preparation method and application |
CN113580674A (en) * | 2021-07-31 | 2021-11-02 | 乐清市赋源包装有限公司 | Environment-friendly corrugated carton and manufacturing method thereof |
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