CN116535072A - Circulating ozone multi-element catalytic oxidation sludge treatment equipment - Google Patents

Circulating ozone multi-element catalytic oxidation sludge treatment equipment Download PDF

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Publication number
CN116535072A
CN116535072A CN202310703471.8A CN202310703471A CN116535072A CN 116535072 A CN116535072 A CN 116535072A CN 202310703471 A CN202310703471 A CN 202310703471A CN 116535072 A CN116535072 A CN 116535072A
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CN
China
Prior art keywords
catalytic oxidation
reaction tower
oxidation reaction
link
pipeline
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Pending
Application number
CN202310703471.8A
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Chinese (zh)
Inventor
黄丽荣
金明哲
武亦文
花敏
常凯
李岚冰
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Yangzhou Sinochem Huayu Environmental Protection Co ltd
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Yangzhou Sinochem Huayu Environmental Protection Co ltd
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Priority to CN202310703471.8A priority Critical patent/CN116535072A/en
Publication of CN116535072A publication Critical patent/CN116535072A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/06Treatment of sludge; Devices therefor by oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/66Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms

Abstract

The circulating ozone multielement catalytic oxidation sludge treatment equipment comprises a cocatalyst storage tank, wherein the cocatalyst storage tank is connected with a cocatalyst dosing pump through a pipeline, the cocatalyst dosing pump is connected with a catalytic oxidation reaction tower through a pipeline, the catalytic oxidation reaction tower is connected with a lifting pump through a pipeline, the lifting pump is connected with a muddy water mixing tank through a pipeline, the upper part of the catalytic oxidation reaction tower is connected with a tail gas collecting pipe, and the tail gas collecting pipe is connected with a biochemical tank; the traditional ozone tail gas is required to be destroyed and decomposed by a tail breaking and destroying device (heating and catalysis), and the incomplete decomposition can also cause environmental pollution.

Description

Circulating ozone multi-element catalytic oxidation sludge treatment equipment
Technical Field
The invention relates to the technical field of sludge treatment devices, in particular to circulating ozone multi-element catalytic oxidation sludge treatment equipment.
Background
With the continuous development of urban process and production activities, wastewater treatment process has become an extremely important part of the environmental protection field. In general, wastewater treatment produces a large amount of sludge, and the environmental and ecological effects of the waste are serious.
At present, an ozone oxidation sludge reduction technology has become a technology means for effectively reducing the amount of sludge generated in the wastewater treatment process, and the ozone oxidation sludge reduction technology is to add ozone gas to oxidatively decompose organic substances in the sludge, so that the generation amount of the sludge is reduced. The ozone oxidation can break double bonds or triple bonds in molecules to degrade the molecules into substances such as organic acid, carbon dioxide and the like, so that the reduction purpose is realized, and compared with the traditional chemical hormone treatment and biological treatment, the ozone oxidation sludge reduction technology has the following advantages: 1. the ozone oxidation reaction speed is high, the usage amount of the reactant is small, and the treatment efficiency is high; 2. the ozone oxidation can directly oxidize and decompose organic substances in the sludge, so that secondary pollution is avoided; 3. the ozone oxidation reaction time is short, and the treatment period can be greatly shortened; 4. ozone oxidation can be applied to various types of organic wastewater, and the treatment effect is stable. Therefore, the ozone oxidation sludge reduction technology has been widely applied to various types of wastewater treatment processes, effectively reduces the generation amount of sludge, and better protects the environment and ecology.
The general technology adopted at present is as follows: 1. biological treatment technology: the organic matters in the sludge are decomposed into inorganic matters by utilizing the metabolism of microorganisms, so that the sludge amount is reduced.
2. Heat treatment technology: the sludge is treated at high temperature, so that the volume and the weight of the sludge are reduced, and simultaneously, organic matters and pathogenic microorganisms in the sludge can be thoroughly destroyed.
3. Chemical treatment technology: organic matters in the sludge are decomposed into gas and liquid by using chemical agents, so that sludge reduction is realized.
4. Mechanical treatment technology: the sludge is compressed, squeezed, concentrated or dried by using manpower or equipment, thereby reducing the volume and weight thereof.
5. Microwave treatment technology: the high-frequency microwave energy is conducted into the sludge particles to heat the sludge particles rapidly, so that sludge drying and reduction are realized.
6. Other techniques: such as an oxidizing agent method, an ultraviolet treatment method, etc., can also be used for sludge reduction.
The above-mentioned techniques have the following general drawbacks: 1. the biological treatment is to build excellent microbial community to accelerate the decomposition and oxidative degradation of sludge in anaerobic or aerobic environment, so as to achieve the purpose of decrement. However, the biological treatment technology needs a large amount of input microorganisms and maintains a constant ecological environment, is also easily influenced by factors such as unstable water quality of inflow water and process operation, and has the defects of high cost and great technical difficulty.
2. The physicochemical treatment mainly separates solid particles in the sludge by methods such as pressure filtration, centrifugation, filtration and the like, reduces the volume of the sludge, but can not realize complete degradation of organic matters, and also requires a large amount of energy and equipment investment, so the cost of the sludge is higher. The incineration treatment is to burn the sludge at high temperature, so that organic matters can be degraded into CO2 and water, the volume of the sludge and secreted pollutants are effectively reduced, but a large amount of energy is required in the process, and harmful gases such as nitrogen oxides, dioxins and the like are easy to generate, so that the environmental impact is large.
3. The desiccation treatment evaporates the water in the sludge by means of evaporation, aeration and the like, so that the volume of the sludge is reduced, but the desiccated sludge becomes hard and is difficult to further treat, and a large amount of sites are required to be occupied for storage.
4. The microwave auxiliary treatment is to increase the degradation rate of sludge by utilizing the heating effect of microwaves, reduce the treatment time and effectively reduce the sludge, but needs a large amount of energy and specialized equipment, and has high cost.
Disclosure of Invention
The invention aims at overcoming the defects of the prior art, and provides circulating ozone multielement catalytic oxidation sludge treatment equipment which comprises a cocatalyst storage tank, wherein the cocatalyst storage tank is connected with a cocatalyst dosing pump through a pipeline, the cocatalyst dosing pump is connected with a catalytic oxidation reaction tower through a pipeline, the catalytic oxidation reaction tower is connected with a lifting pump through a pipeline, the lifting pump is connected with a sludge-water mixing tank through a pipeline, the upper part of the catalytic oxidation reaction tower is connected with a tail gas collecting pipe, the tail gas collecting pipe is connected with a biochemical tank, the biochemical tank is connected with a sludge concentration tank through a supernatant discharge pipe, the sludge concentration tank is connected with a catalytic oxidation reaction tower through a water outlet pipe, and the catalytic oxidation reaction tower is connected with an ozone generator through a gas pipe.
The mud-water mixing tank is internally provided with a stirrer, the top end of the stirrer is connected with a driving motor, and the driving motor is arranged above the mud-water mixing tank.
The catalytic oxidation reaction tower in be equipped with the catalyst filler, just the catalyst filler be equipped with two, the top of catalyst filler be equipped with the water inlet, just the water inlet establish on the outer wall of catalytic oxidation reaction tower, the below of catalyst filler be equipped with gas distribution device, just gas distribution device link to each other with ozone generator through the trachea, one side of catalytic oxidation reaction tower be equipped with the circulating pump, the both ends of circulating pump link to each other with catalytic oxidation reaction tower through the pipeline, just the both ends of circulating pump establish respectively in the top and the below of the catalyst filler of catalytic oxidation reaction tower.
An inlet is arranged on the outer wall of the catalytic oxidation reaction tower.
The biochemical pond in be equipped with the aeration intake pipe, aeration intake pipe be linked together with the tail gas collecting pipe, aeration intake pipe link to each other with the aeration be responsible for, just the aeration be responsible for and encircle biochemical pond setting, the aeration be responsible for on be equipped with the aeration branch pipe, the aeration branch pipe on be equipped with single pore membrane air diffuser, just single pore membrane air diffuser be equipped with more than one.
The beneficial effects of the invention are as follows: the circulating ozone multielement catalytic oxidation sludge treatment equipment is provided, a traditional ozone oxidation sludge reduction process is adopted, a catalyst is not filled in a system, a cocatalyst is added, hydroxyl free radicals are not sufficiently formed in the ozone oxidation residual sludge process, the oxidation efficiency is not high enough, and partial ozone is dissipated and lost; according to the invention, the catalyst and the hydrogen peroxide added outside the system are added as the cocatalyst, so that the generation amount and the reaction rate of hydroxyl radicals are effectively improved, and the sludge degradation rate and the efficiency are improved; the traditional ozone tail gas is subjected to destructive decomposition by a tail breaking device (heating and catalysis), and the incomplete decomposition also causes environmental pollution; the invention fully utilizes the ozone tail gas for recycling, ozone after the sludge mixed liquid is decomposed into oxygen, the oxygen content of the partial gas is high, and the partial gas is collected and guided into a biochemical pool as an air source, so that the oxygen utilization rate can be greatly improved.
Drawings
Fig. 1 is a schematic structural view of the present invention.
FIG. 2 is a schematic diagram of the internal structure of the biochemical tank according to the present invention.
In the figure: 1. the device comprises a cocatalyst storage tank, 2, a cocatalyst dosing pump, 3, a mud-water mixing tank, 4, an ozone generator, 5, a stirrer, 6, a catalytic oxidation reaction tower, 7, a sludge concentration tank, 8, a biochemical tank, 9, a catalyst filler, 10, an inlet, 11, an air distribution device, 12, a water inlet, 13, a water outlet pipe, 14, a tail gas collecting pipe, 15, a circulating pump, 16, a lifting pump, 17, a supernatant liquid discharge pipe, 18, a driving motor, 81, a single-pore membrane air diffuser, 82, an aeration air inlet pipe, 83, an aeration main pipe, 84 and an aeration branch pipe.
Detailed Description
The drawings are for illustrative purposes only and are not to be construed as limiting the present patent; for the purpose of better illustrating the embodiments, certain elements of the drawings may be omitted, enlarged or reduced and do not represent the actual product dimensions; it will be appreciated by those skilled in the art that certain well-known structures in the drawings and descriptions thereof may be omitted.
Example 1, as shown: the utility model provides a circulating ozone multielement catalytic oxidation sludge treatment equipment, includes cocatalyst storage tank 1, cocatalyst storage tank 1 pass through the pipeline and link to each other with cocatalyst charge pump 2, cocatalyst charge pump 2 pass through the pipeline and link to each other with catalytic oxidation reaction tower 6, catalytic oxidation reaction tower 6 pass through the pipeline and link to each other with elevator pump 16, elevator pump 16 pass through the pipeline and link to each other with muddy water mixing tank 3, catalytic oxidation reaction tower 6's top link to each other with tail gas collecting pipe 14, tail gas collecting pipe 14 link to each other with biochemical pond 8, biochemical pond 8 pass through supernatant fluid discharge pipe 17 and link to each other with sludge concentration pond 7, sludge concentration pond 7 pass through outlet pipe 13 and catalytic oxidation reaction tower 6 link to each other with ozone generator 4 through the trachea. The mud-water mixing tank 3 in be equipped with agitator 5, the top of agitator 5 link to each other with driving motor 18, just driving motor 18 establish the top in mud-water mixing tank 3.
Embodiment 2, a circulating ozone multiple catalysis oxidation sludge treatment equipment, catalytic oxidation reaction tower 6 in be equipped with catalyst filler 9, just catalyst filler 9 be equipped with two, catalyst filler 9's top be equipped with water inlet 12, just water inlet 12 establish on catalytic oxidation reaction tower 6's outer wall, catalyst filler 9's below be equipped with gas distribution device 11, and gas distribution device 11 pass through the trachea and link to each other with ozone generator 4, catalytic oxidation reaction tower 6's one side be equipped with circulating pump 15, circulating pump 15's both ends pass through the pipeline and link to each other with catalytic oxidation reaction tower 6, just circulating pump 15's both ends establish respectively in catalytic oxidation reaction tower 6's catalyst filler 9's top and below. An inlet 10 is arranged on the outer wall of the catalytic oxidation reaction tower 6. The biochemical tank 8 in be equipped with aeration intake pipe 82, aeration intake pipe 82 be linked together with tail gas collecting pipe 14, aeration intake pipe 82 link to each other with aeration main pipe 83, just aeration main pipe 83 encircle biochemical tank 8 and set up, aeration main pipe 83 on be equipped with aeration branch pipe 84, aeration branch pipe 84 on be equipped with single pore membrane air diffuser 81, just single pore membrane air diffuser 81 be equipped with more than one.
The invention relates to an integral system which is upper water distribution and lower air intake. The process flow comprises the following steps: the surplus sludge enters the sludge-water mixing tank 3, is uniformly mixed by the stirrer 5 and then is lifted to the catalytic oxidation reactor by the lifting pump 16, meanwhile, the cocatalyst enters the reaction tower for reaction through the pipeline mixer and the water inlet block, the effluent enters the sludge concentration tank 7 to complete sludge concentration, the tail gas enters the biochemical tank 8 through collection, an oxygen source is provided for the biochemical tank 8, and meanwhile, the supernatant after concentration of the sludge concentration tank 7 enters the biochemical tank 8 as a carbon source to supplement the carbon source.
The diameter of the catalytic oxidation reaction tower 6 is 1.2 m, the height is 8.8 m, the thickness of a filler bed is 3.2 m, the filler material is a composite metal catalyst, the particle diameter is 3-5 mm, the catalyst promoter is 27.5% hydrogen peroxide, the catalytic oxidation reaction time of the catalytic oxidation reaction tower 6 is 1 hour, and the treatment capacity per hour is 6-8 cubic meters per hour.
The invention provides circulating ozone multielement catalytic oxidation sludge treatment equipment with a compact structure, and the traditional ozone oxidation sludge reduction process is characterized in that a catalyst is not filled in a system and a cocatalyst is added, so that hydroxyl free radicals are not sufficiently formed in the process of oxidizing excess sludge by ozone, the oxidation efficiency is not high enough, and partial ozone is dissipated and lost. According to the invention, the catalyst and the hydrogen peroxide added outside the system are added as the cocatalyst, so that the generation amount and the reaction rate of hydroxyl radicals are effectively improved, and the sludge degradation rate and the efficiency are improved; the traditional ozone tail gas is required to be destroyed and decomposed by a tail breaking and destroying device (heating and catalysis), and the incomplete decomposition can also cause environmental pollution.
Finally, the foregoing embodiments were chosen and described in detail to provide a better illustration of the teachings of the present invention, and are not intended to be limited to the details shown. Modifications and equivalents of the present invention may occur to those skilled in the art without departing from the spirit and scope of the present invention, and are intended to be covered by the scope of the appended claims.

Claims (5)

1. The utility model provides a circulating ozone multielement catalytic oxidation sludge treatment equipment, includes cocatalyst storage tank, its characterized in that: the catalyst promoter storage tank link to each other through pipeline and catalyst promoter charge pump, catalyst promoter charge pump link to each other with catalytic oxidation reaction tower through the pipeline, catalytic oxidation reaction tower link to each other with the elevator pump through the pipeline, the elevator pump link to each other with muddy water mixing tank through the pipeline, catalytic oxidation reaction tower's top link to each other with the tail gas collecting pipe, the tail gas collecting pipe link to each other with biochemical pond, biochemical pond link to each other with the sludge concentration pond through the supernatant fluid drain pipe, the sludge concentration pond link to each other with catalytic oxidation reaction tower through the outlet pipe, catalytic oxidation reaction tower link to each other with ozone generator through the trachea.
2. The circulating ozone multi-element catalytic oxidation sludge treatment equipment as claimed in claim 1, wherein: the mud-water mixing tank is internally provided with a stirrer, the top end of the stirrer is connected with a driving motor, and the driving motor is arranged above the mud-water mixing tank.
3. The circulating ozone multi-element catalytic oxidation sludge treatment equipment as claimed in claim 1, wherein: the catalytic oxidation reaction tower in be equipped with the catalyst filler, just the catalyst filler be equipped with two, the top of catalyst filler be equipped with the water inlet, just the water inlet establish on the outer wall of catalytic oxidation reaction tower, the below of catalyst filler be equipped with gas distribution device, just gas distribution device link to each other with ozone generator through the trachea, one side of catalytic oxidation reaction tower be equipped with the circulating pump, the both ends of circulating pump link to each other with catalytic oxidation reaction tower through the pipeline, just the both ends of circulating pump establish respectively in the top and the below of the catalyst filler of catalytic oxidation reaction tower.
4. The circulating ozone multi-element catalytic oxidation sludge treatment equipment as claimed in claim 1, wherein: an inlet is arranged on the outer wall of the catalytic oxidation reaction tower.
5. The circulating ozone multi-element catalytic oxidation sludge treatment equipment as claimed in claim 1, wherein: the biochemical pond in be equipped with the aeration intake pipe, aeration intake pipe be linked together with the tail gas collecting pipe, aeration intake pipe link to each other with the aeration be responsible for, just the aeration be responsible for and encircle biochemical pond setting, the aeration be responsible for on be equipped with the aeration branch pipe, the aeration branch pipe on be equipped with single pore membrane air diffuser, just single pore membrane air diffuser be equipped with more than one.
CN202310703471.8A 2023-06-14 2023-06-14 Circulating ozone multi-element catalytic oxidation sludge treatment equipment Pending CN116535072A (en)

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CN202310703471.8A CN116535072A (en) 2023-06-14 2023-06-14 Circulating ozone multi-element catalytic oxidation sludge treatment equipment

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Application Number Priority Date Filing Date Title
CN202310703471.8A CN116535072A (en) 2023-06-14 2023-06-14 Circulating ozone multi-element catalytic oxidation sludge treatment equipment

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000079384A (en) * 1998-06-22 2000-03-21 Jc Engineering Kk Chemical and biological treatment system for waste
CN106007256A (en) * 2016-07-28 2016-10-12 黄霞 Microbubble ozone catalytic oxidation-no-aeration biochemical coupling technology system and application thereof
CN208249970U (en) * 2018-04-13 2018-12-18 大连理工大学环境工程设计研究院有限公司 A kind of novel water vapor circulation ozone catalytic oxidation reaction device
CN212864482U (en) * 2020-07-30 2021-04-02 上海亦泰环保科技有限公司 Ozone catalytic oxidation combines membrane aeration biological reaction effluent treatment plant
CN115159657A (en) * 2022-08-05 2022-10-11 桂润环境科技股份有限公司 Method for treating organic wastewater by catalytic oxidation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000079384A (en) * 1998-06-22 2000-03-21 Jc Engineering Kk Chemical and biological treatment system for waste
CN106007256A (en) * 2016-07-28 2016-10-12 黄霞 Microbubble ozone catalytic oxidation-no-aeration biochemical coupling technology system and application thereof
CN208249970U (en) * 2018-04-13 2018-12-18 大连理工大学环境工程设计研究院有限公司 A kind of novel water vapor circulation ozone catalytic oxidation reaction device
CN212864482U (en) * 2020-07-30 2021-04-02 上海亦泰环保科技有限公司 Ozone catalytic oxidation combines membrane aeration biological reaction effluent treatment plant
CN115159657A (en) * 2022-08-05 2022-10-11 桂润环境科技股份有限公司 Method for treating organic wastewater by catalytic oxidation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
石岩等: "《化工园区废水分类收集与分质预处理技术》", vol. 2022, 天津:天津大学出版社, pages: 83 - 84 *

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