CN116515549A - Long-life wind power gear oil and preparation method thereof - Google Patents
Long-life wind power gear oil and preparation method thereof Download PDFInfo
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- CN116515549A CN116515549A CN202310479155.7A CN202310479155A CN116515549A CN 116515549 A CN116515549 A CN 116515549A CN 202310479155 A CN202310479155 A CN 202310479155A CN 116515549 A CN116515549 A CN 116515549A
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- 239000012208 gear oil Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000002199 base oil Substances 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000000654 additive Substances 0.000 claims abstract description 29
- 230000000996 additive effect Effects 0.000 claims abstract description 28
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims abstract description 16
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000013556 antirust agent Substances 0.000 claims abstract description 14
- 239000006078 metal deactivator Substances 0.000 claims abstract description 14
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 12
- 239000011733 molybdenum Substances 0.000 claims abstract description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 4
- -1 organo molybdenum Chemical compound 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 11
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- 229920013639 polyalphaolefin Polymers 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229920005862 polyol Polymers 0.000 claims description 7
- 150000004867 thiadiazoles Chemical class 0.000 claims description 7
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 6
- 239000013067 intermediate product Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 238000005299 abrasion Methods 0.000 abstract description 2
- 230000001934 delay Effects 0.000 abstract description 2
- 238000001514 detection method Methods 0.000 description 6
- QAPVYZRWKDXNDK-UHFFFAOYSA-N P,P-Dioctyldiphenylamine Chemical compound C1=CC(CCCCCCCC)=CC=C1NC1=CC=C(CCCCCCCC)C=C1 QAPVYZRWKDXNDK-UHFFFAOYSA-N 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
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- Chemical & Material Sciences (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention belongs to the field of gear oil, and particularly relates to long-life wind power gear oil, which comprises the following raw materials in percentage by mass: 1 to 2 percent of extreme pressure agent, 1 to 3 percent of antiwear agent, 0.1 to 1 percent of antioxidant, 0.1 to 0.5 percent of metal deactivator, 0.2 to 0.8 percent of antirust agent, 0.1 to 0.5 percent of demulsifier, 0.1 to 0.2 percent of defoamer, 0.3 to 0.5 percent of modified nano additive and the balance of base oil. The extreme pressure agent adopts the sulfurized isobutene, the antiwear agent adopts the mixture of the phosphorothioate derivative and the organic molybdenum, and the gear oil has micro pitting corrosion resistance through the mutual coordination of the sulfurized isobutene, the phosphorothioate derivative, the organic molybdenum and the modified nano additive, can be well mutually dissolved and mixed with the fully-synthesized base oil, delays the abrasion of the gear, and prolongs the service life of the gear.
Description
Technical Field
The invention belongs to the field of gear oil, and particularly relates to long-life wind power gear oil and a preparation method thereof.
Background
With the significance of large-scale development of wind power in China, wind power generation is used as a green environment-friendly new energy source, and a powerful support is provided for accelerating energy transformation in China.
After the gear oil is put into operation, the gear oil contacts with air to absorb and combine dissolved oxygen, and under the action of temperature, an electric field and catalysis of metal components, huge shearing force and load are born, so that the oxidation process is greatly accelerated, the viscosity change, the acid value rise, the exceeding standard of metal abrasive particles, the oxidation resistance, the extreme pressure wear resistance reduction and the like of the gear oil are caused, and the gear box faults caused by oil quality degradation occur.
Disclosure of Invention
In order to solve the problems in the background art, the invention provides long-life wind power gear oil, which comprises the following raw materials in percentage by mass:
1 to 2 percent of extreme pressure agent, 1 to 3 percent of antiwear agent, 0.1 to 1 percent of antioxidant, 0.1 to 0.5 percent of metal deactivator, 0.2 to 0.8 percent of antirust agent, 0.1 to 0.5 percent of demulsifier, 0.1 to 0.2 percent of defoamer, 0.3 to 0.5 percent of modified nano additive and the balance of base oil.
Preferably, the extreme pressure agent is sulfurized isobutylene.
Preferably, the antiwear agent is a phosphorothioate derivative, and the organic molybdenum is prepared according to the following formula 1: (0.5-2), wherein the phosphorothioate derivative has the following structural formula:
the structural formula of the organic molybdenum is as follows:
preferably, the antioxidant is 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butylphenol and 4,4' -dioctyl diphenylamine, and the mass ratio is 1: (0.5-2): (0.5-2) and mixing.
Preferably, the metal deactivator is a benzotriazole derivative and a thiadiazole derivative, and the mass ratio of the metal deactivator to the thiadiazole derivative is 1: (1-3) and mixing.
Preferably, the rust inhibitor is alkenyl succinate.
Preferably, the demulsifier is a polyether polymer compound, and the defoamer is methyl silicone oil.
Preferably, the preparation method of the modified nano additive comprises the following steps:
preparing boric acid, bismuth nitrate and hollow nano carbon spheres into aqueous solutions respectively, adding the hollow nano carbon sphere aqueous solution into the boric acid aqueous solution, continuously stirring for 30-50min at 60-70 ℃, adding the bismuth nitrate aqueous solution to obtain a mixed solution, performing hydrothermal reaction at 130-150 ℃ for 10-20h, cooling to 20-30 ℃, filtering, washing and drying to obtain an intermediate product;
mixing the intermediate product with oleic acid according to a mass ratio of 1: (3-5) dispersing in n-butyl alcohol to form a uniform suspension, and then carrying out reflux reaction for 1-3h, and carrying out reduced pressure distillation to obtain the modified nano additive.
Preferably, the base oil is neopentyl polyol (complex) ester base oil and poly alpha olefin base oil PAO40, and the mass ratio is 1: (3-5) mixing.
The invention also provides a preparation method of the long-life wind power gear oil, which comprises the following steps:
s1, heating base oil to 50-60 ℃;
s2, adding the extreme pressure agent, the antiwear agent, the antioxidant, the metal deactivator, the antirust agent, the demulsifier, the defoamer and the modified nano additive into the base oil in the step S1, carrying out heat preservation and stirring for 30-60min, cooling, and filtering to obtain the long-service-life wind power gear oil.
Compared with the prior art, the invention has the beneficial effects that:
1. the extreme pressure agent adopts the sulfurized isobutene, the antiwear agent adopts the mixture of the phosphorothioate derivative and the organic molybdenum, and the gear oil has micro pitting corrosion resistance through the mutual coordination of the sulfurized isobutene, the phosphorothioate derivative, the organic molybdenum and the modified nano additive, can be well mutually dissolved and mixed with the fully-synthesized base oil, delays the abrasion of the gear, and prolongs the service life of the gear.
2. When the wind power gear box works in a field area, the wind power gear box is inevitably contacted with water vapor, and in order to ensure the excellent performance of gear oil, a polyether high molecular compound demulsifier and a methyl silicone oil defoaming agent are added.
3. According to the invention, through reasonably controlling the mass ratio of the poly-neopentyl polyol (complex) base oil and the poly-alpha olefin base oil PAO40, under the synergistic effect of the two base oils, the solubility of various additives in the base oil can be improved, the good shear stability and high viscosity index of the gear oil are ensured, the service life is prolonged, and the viscosity improver is not required to be additionally added, so that the gear oil has good shear stability and high-temperature detergency, and the viscosity of the oil is not obviously changed after repeated heavy-load shearing among gears.
Detailed Description
The raw materials used in the invention are purchased in the market from all sources unless otherwise specified;
wherein the phosphorothioate derivative is purchased from Shanghai Bai Hei Biotech Co., ltd;
organo-molybdenum purchased from Shanghai Michael Biochemical technologies Co., ltd;
t551 benzotriazole derivatives and T571 thiadiazole derivatives are purchased from Nanjing Milan New Material Co., ltd;
the T747 alkenyl succinate and DL32 polyether polymer compound are purchased from Hebei Tuo Lubricant sales limited company;
methyl silicone oil and oleic acid are purchased from the Ala-dine;
the hollow nano carbon sphere is purchased from Allatin with the diameter of 300-800nm;
neopentyl polyol (complex) ester base oil was purchased from atan boao chemical company, inc;
the polyalphaolefin base oil PAO40 is purchased from Shanghai, inc.
Preparation example 1
The preparation method of the modified nano additive comprises the following steps:
60g of boric acid is dissolved in 1000ml of deionized water, 40g of bismuth nitrate is dissolved in 1000ml of deionized water, 40g of hollow nano carbon spheres are dispersed in 1000ml of deionized water, then the hollow nano carbon spheres aqueous solution is added into the boric acid aqueous solution, the stirring is continuously carried out for 30 min at 70 ℃, then the bismuth nitrate aqueous solution is added to obtain a mixed solution, then the hydrothermal reaction is carried out for 10h at 130 ℃, the temperature is cooled to 20-30 ℃, and the intermediate product is obtained after filtration, washing and drying;
mixing the intermediate product with oleic acid according to a mass ratio of 1:3 dispersing in 2000ml of n-butanol to form a uniform suspension, and then carrying out reflux reaction for 1-3h, and carrying out reduced pressure distillation to obtain the modified nano additive.
Example 1
A method for preparing long-life wind power gear oil according to the claims, comprising the following steps:
s1, heating base oil to 55 ℃;
s2, adding the extreme pressure agent, the antiwear agent, the antioxidant, the metal deactivator, the antirust agent, the demulsifier, the defoamer and the modified nano additive into the base oil in the step S1, carrying out heat preservation and stirring for 40 min, cooling, and filtering to obtain the long-service-life wind power gear oil.
In the embodiment, the extreme pressure agent is sulfurized isobutylene, and the addition amount is 1.5%; the antiwear agent is phosphorothioate derivative and organic molybdenum according to the following formula 1:1, and the addition amount of the additive is 2%; the antioxidant is 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butylphenol and 4,4' -dioctyl diphenylamine, and the mass ratio is 1:1:1, wherein the addition amount of the mixture is 0.5%; the metal deactivator is a benzotriazole derivative and a thiadiazole derivative, and the mass ratio is 1:2, wherein the addition amount of the additive is 0.3 percent; the antirust agent is alkenyl succinate, and the addition amount of the antirust agent is 0.5%; the demulsifier is polyether polymer compound, and the addition amount of the demulsifier is 0.3%; the defoaming agent is methyl silicone oil, and the addition amount of the defoaming agent is 0.15%; the modified nano additive is obtained by a preparation example 1, and the addition amount of the modified nano additive is 0.4%; the rest is base oil, wherein the base oil is neopentyl polyol (complex) ester base oil and poly alpha olefin base oil PAO40, and the mass ratio is 1:4, mixing.
Example 2
This example differs from example 1 in that "antiwear agent is a phosphorothioate derivative, organomolybdenum is as follows: 1, the amount of which was 1% ", and the rest was the same as in example 1.
Example 3
This example differs from example 1 in that "antiwear agent is a phosphorothioate derivative, organomolybdenum is as follows: 1, the amount of which was 3% ", and the rest was the same as in example 1.
Example 4
This example differs from example 1 in that "antiwear agent is a phosphorothioate derivative, organomolybdenum is as follows: 0.5 by mass, and the amount thereof was 2% ", and the rest was the same as in example 1.
Example 5
This example differs from example 1 in that "antiwear agent is a phosphorothioate derivative, organomolybdenum is as follows: 2, the amount of which was 2% ", and the rest was the same as in example 1.
Example 6
This example is different from example 1 in that "modified nano additive was obtained by preparation example 1, the addition amount thereof was 0.3%", and the rest was identical to example 1.
Example 7
This example is different from example 1 in that "modified nano additive was obtained by preparation example 1, the addition amount thereof was 0.5%", and the rest was identical to example 1.
Example 8
A method for preparing long-life wind power gear oil according to the claims, comprising the following steps:
s1, heating base oil to 55 ℃;
s2, adding the extreme pressure agent, the antiwear agent, the antioxidant, the metal deactivator, the antirust agent, the demulsifier, the defoamer and the modified nano additive into the base oil in the step S1, carrying out heat preservation and stirring for 40 min, cooling, and filtering to obtain the long-service-life wind power gear oil.
In the embodiment, the extreme pressure agent is sulfurized isobutene, and the addition amount is 1%; the antiwear agent is phosphorothioate derivative and organic molybdenum according to the following formula 1:0.5 mass ratio, and the addition amount is 1 percent; the antioxidant is 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butylphenol and 4,4' -dioctyl diphenylamine, and the mass ratio is 1:0.5:0.5, the addition amount of which is 0.1 percent; the metal deactivator is a benzotriazole derivative and a thiadiazole derivative, and the mass ratio is 1:0.5, the addition amount of which is 0.1 percent; the antirust agent is alkenyl succinate, and the addition amount of the antirust agent is 0.2%; the demulsifier is polyether polymer compound, and the addition amount of the demulsifier is 0.1%; the defoaming agent is methyl silicone oil, and the addition amount of the defoaming agent is 0.1%; the modified nano additive is obtained by a preparation example 1, and the addition amount of the modified nano additive is 0.3%; the rest is base oil, wherein the base oil is neopentyl polyol (complex) ester base oil and poly alpha olefin base oil PAO40, and the mass ratio is 1:3, mixing.
Example 9
A method for preparing long-life wind power gear oil according to the claims, comprising the following steps:
s1, heating base oil to 55 ℃;
s2, adding the extreme pressure agent, the antiwear agent, the antioxidant, the metal deactivator, the antirust agent, the demulsifier, the defoamer and the modified nano additive into the base oil in the step S1, carrying out heat preservation and stirring for 40 min, cooling, and filtering to obtain the long-service-life wind power gear oil.
In the embodiment, the extreme pressure agent is sulfurized isobutylene, and the addition amount is 2%; the antiwear agent is phosphorothioate derivative and organic molybdenum according to the following formula 1:2, wherein the addition amount of the additive is 3%; the antioxidant is 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butylphenol and 4,4' -dioctyl diphenylamine, and the mass ratio is 1:2:2, wherein the addition amount of the mixture is 1%; the metal deactivator is a benzotriazole derivative and a thiadiazole derivative, and the mass ratio is 1:3, mixing, wherein the addition amount is 1%; the antirust agent is alkenyl succinate, and the addition amount of the antirust agent is 0.8%; the demulsifier is polyether polymer compound, and the addition amount of the demulsifier is 0.5%; the defoaming agent is methyl silicone oil, and the addition amount of the defoaming agent is 0.2%; the modified nano additive is obtained by a preparation example 1, and the addition amount of the modified nano additive is 0.5%; the rest is base oil, wherein the base oil is neopentyl polyol (complex) ester base oil and poly alpha olefin base oil PAO40, and the mass ratio is 1:5, mixing.
Results and detection
The detection method comprises the following steps:
40 ℃ viscosity and 100 ℃ viscosity detection: GB/T265-1998 petroleum product kinematic viscosity measurement method and dynamic viscosity calculation method;
pour point detection: GB/T3535-2006 petroleum product pour point determination;
flash point detection: GB/T3536-2008 open cup method for measuring flash point and ignition point of petroleum products;
copper sheet corrosion detection: GB/T5096-2017 copper sheet corrosion test method for petroleum products;
and (3) detecting the grinding spot diameter: SH/T0189-1992 determination of antiwear properties of lubricating oils (four-ball machine method).
The results are shown in tables 1 and 2.
TABLE 1
TABLE 2
As can be seen from tables 1 and 2, the gear oil prepared by the invention is superior to the commercial gear oil in various performances, such as 40 ℃ viscosity, 100 ℃ viscosity, pour point, flash point, mill spot diameter and the like, and the wind power gear oil has high viscosity and excellent micro-pitting resistance, and the modified nano additive is added to further synergistically interact with the extreme pressure agent and the antiwear agent to control the proportion added into the wind power gear oil, so that the micro-pitting resistance of the gear oil is improved.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.
Claims (10)
1. The long-life wind power gear oil is characterized by comprising the following raw materials in percentage by mass:
1 to 2 percent of extreme pressure agent, 1 to 3 percent of antiwear agent, 0.1 to 1 percent of antioxidant, 0.1 to 0.5 percent of metal deactivator, 0.2 to 0.8 percent of antirust agent, 0.1 to 0.5 percent of demulsifier, 0.1 to 0.2 percent of defoamer, 0.3 to 0.5 percent of modified nano additive and the balance of base oil.
2. The long life wind power gear oil of claim 1, wherein said extreme pressure agent is sulfurized isobutylene.
3. The long life wind power gear oil of claim 1, wherein said antiwear agent is a phosphorothioate derivative, organo molybdenum is in accordance with 1: (0.5-2), wherein the phosphorothioate derivative has the following structural formula:
the structural formula of the organic molybdenum is as follows:
4. the long-life wind power gear oil according to claim 1, wherein the antioxidant is 2, 6-di-tert-butyl-p-cresol, 2, 6-di-tert-butylphenol, 4' -dioctyl diphenylamine, and the mass ratio is 1: (0.5-2): (0.5-2) and mixing.
5. The long-life wind power gear oil according to claim 1, wherein the metal deactivator is a benzotriazole derivative and a thiadiazole derivative, and the mass ratio is 1: (1-3) and mixing.
6. The long life wind power gear oil of claim 1, wherein said rust inhibitor is alkenyl succinate.
7. The long-life wind power gear oil according to claim 1, wherein the demulsifier is a polyether polymer compound and the antifoaming agent is methyl silicone oil.
8. The long-life wind power gear oil according to claim 1, wherein the preparation method of the modified nano additive is as follows:
preparing boric acid, bismuth nitrate and hollow nano carbon spheres into aqueous solutions respectively, adding the hollow nano carbon sphere aqueous solution into the boric acid aqueous solution, continuously stirring for 30-50min at 60-70 ℃, adding the bismuth nitrate aqueous solution to obtain a mixed solution, performing hydrothermal reaction at 130-150 ℃ for 10-20h, cooling to 20-30 ℃, filtering, washing and drying to obtain an intermediate product;
mixing the intermediate product with oleic acid according to a mass ratio of 1: (3-5) dispersing in n-butyl alcohol to form a uniform suspension, and then carrying out reflux reaction for 1-3h, and carrying out reduced pressure distillation to obtain the modified nano additive.
9. The long-life wind power gear oil according to claim 1, wherein the base oil is neopentyl polyol (complex) ester base oil and poly alpha olefin base oil PAO40 according to the mass ratio of 1: (3-5) mixing.
10. A method for preparing long life wind power gear oil according to any of claims 1-9, comprising the steps of:
s1, heating base oil to 50-60 ℃;
s2, adding the extreme pressure agent, the antiwear agent, the antioxidant, the metal deactivator, the antirust agent, the demulsifier, the defoamer and the modified nano additive into the base oil in the step S1, carrying out heat preservation and stirring for 30-60min, cooling, and filtering to obtain the long-service-life wind power gear oil.
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JPS62240389A (en) * | 1986-04-09 | 1987-10-21 | Asahi Denka Kogyo Kk | Gear oil composition |
WO1995007964A1 (en) * | 1993-09-13 | 1995-03-23 | Exxon Research And Engineering Company | Lubricant composition containing antiwear additive combination |
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