CN116400140A - Piezoelectric coefficient suitable for polymer thick filmd31 Measuring device of (2) - Google Patents

Piezoelectric coefficient suitable for polymer thick filmd31 Measuring device of (2) Download PDF

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CN116400140A
CN116400140A CN202310239397.9A CN202310239397A CN116400140A CN 116400140 A CN116400140 A CN 116400140A CN 202310239397 A CN202310239397 A CN 202310239397A CN 116400140 A CN116400140 A CN 116400140A
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thick film
piezoelectric
clamping block
pressing
clamping
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CN116400140B (en
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解广亚
李峰
郑震宇
廖雪荣
杨旭
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715 Research Institute Of China Shipbuilding Corp
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715 Research Institute Of China Shipbuilding Corp
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R27/00Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
    • G01R27/02Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant
    • G01R27/26Measuring inductance or capacitance; Measuring quality factor, e.g. by using the resonance method; Measuring loss factor; Measuring dielectric constants ; Measuring impedance or related variables
    • G01R27/2688Measuring quality factor or dielectric loss, e.g. loss angle, or power factor
    • G01R27/2694Measuring dielectric loss, e.g. loss angle, loss factor or power factor
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/30Investigating strength properties of solid materials by application of mechanical stress by applying a single impulsive force, e.g. by falling weight
    • G01N3/303Investigating strength properties of solid materials by application of mechanical stress by applying a single impulsive force, e.g. by falling weight generated only by free-falling weight
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R1/00Details of instruments or arrangements of the types included in groups G01R5/00 - G01R13/00 and G01R31/00
    • G01R1/02General constructional details
    • G01R1/04Housings; Supporting members; Arrangements of terminals
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R1/00Details of instruments or arrangements of the types included in groups G01R5/00 - G01R13/00 and G01R31/00
    • G01R1/02General constructional details
    • G01R1/04Housings; Supporting members; Arrangements of terminals
    • G01R1/0408Test fixtures or contact fields; Connectors or connecting adaptors; Test clips; Test sockets
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R19/00Arrangements for measuring currents or voltages or for indicating presence or sign thereof
    • G01R19/12Measuring rate of change
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R27/00Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
    • G01R27/02Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant
    • G01R27/26Measuring inductance or capacitance; Measuring quality factor, e.g. by using the resonance method; Measuring loss factor; Measuring dielectric constants ; Measuring impedance or related variables
    • G01R27/2605Measuring capacitance

Abstract

The invention relates to the field of performance test of piezoelectric materials, in particular to a piezoelectric coefficient suitable for polymer thick filmsd 31 The measuring device comprises an oscilloscope, piezoelectric ceramics, a clamping table, a clamping assembly and a pressing assembly; the clamping assembly comprises an upper clamping block and a lower connecting assembly; the upper clamping block is arranged on the clamping table, the lower connecting component is positioned at the lower side of the upper clamping block, and the upper end of the lower connecting component is connected with the lower end of the upper clamping block through a thick film; the pressing assembly comprises a pressing frame and an active pressing pair; the active pressing pair is arranged at the lower end of the pressing frame; the upper end part of the pressing frame is connected with the lower end part of the lower connecting component through piezoelectric ceramics; the oscillograph, the piezoelectric ceramic and the thick filmThe invention designs the structure by connecting wires, and uses the piezoelectric strain constant of known materials by a comparison methodd 33 Indirectly solving piezoelectric strain coefficient of thick film material to be measuredd 31 The method has the characteristics of low cost, simplicity and convenience in operation, strong repeatability, accurate measurement data and the like.

Description

Piezoelectric coefficient suitable for polymer thick filmd31 Measuring device of (2)
Technical Field
The invention relates to the field of performance test of piezoelectric materials, in particular to a piezoelectric coefficient suitable for a polymer thick filmd 31 Is provided.
Background
The high polymer piezoelectric thick film element has the characteristics of light weight, flexible property, sensitivity, easy matching with water medium and the like, so that the large-area surface element hydrophone developed by adopting the thick film element has the capabilities of vibration resistance, impact resistance, stable acousto-electric performance under high hydrostatic pressure and high wave number noise resistance, can be widely used for replacing the piezoelectric ceramic point element hydrophone, and improves the war technical index of sonar equipment from the source. The polymer piezoelectric thick film is taken as a typical organic high-molecular piezoelectric material and is a core sensitive unit of a face element hydrophone. The receiving sensitivity of the surface element hydrophone in water is mainly equal to the hydrostatic pressure piezoelectric voltage coefficient of the polymer thick film materialg h (g 33 +2g 31 ) Positive correlation, thus accurately obtaining polymer thick filmsg h Has important significance for the performance forecast of the surface element hydrophone.
Due to the piezoelectric voltage coefficient of thick film materialsg 33 (d 3333 ) Andg 31 (d 3133 ) Are obtained by the ratio of the piezoelectric coefficient to the dielectric constant in the corresponding direction. Currently aimed at piezoelectric coefficientd 33 And a dielectric constant epsilon 33 The test method is mature and can obtain accurate piezoelectric voltage coefficientg 33 . Due to piezoelectric coefficient of polymer thick film material in transverse length directiond 31 The absolute value is low, aboutd 33 One third of (3). Current materials for polymer thick filmsd 31 The measurement method of the (B) has large deviation in the test process generally, and thick film materials can not be obtained stably and effectivelyd 31 Is an accurate value of (a). The present invention is based on this backgroundAccording to the performance characteristics of the high polymer material, the designed scheme and the measuring device accurately and stably measure the piezoelectric coefficient of the polymer thick filmd 31 Has certain reference significance.
Disclosure of Invention
The invention provides a measuring device, which ensures that the transverse piezoelectric coefficient of a polymer thick film material is improved by reasonable structural designd 31 ) The measurement of the polymer piezoelectric thick film parameter sensor becomes simpler, more convenient and more reliable so as to meet the application requirement of the performance forecast of the surface element hydrophone on the measurement of the polymer piezoelectric thick film parameter.
In order to achieve the above purpose, the present invention provides the following technical solutions: piezoelectric coefficient suitable for polymer thick filmdThe measuring device comprises an oscilloscope, piezoelectric ceramics, a clamping table, a clamping assembly and a pressing assembly; the clamping assembly comprises an upper clamping block and a lower connecting assembly; the upper clamping block is arranged on the clamping table, the lower connecting component is positioned at the lower side of the upper clamping block, and the upper end of the lower connecting component is connected with the lower end of the upper clamping block through a thick film; the pressing assembly comprises a pressing frame and an active pressing pair; the active pressing pair is arranged at the lower end of the pressing frame; the upper end part of the pressing frame is connected with the lower end part of the lower connecting component through piezoelectric ceramics; the oscillograph is connected with the piezoelectric ceramic and the thick film through leads.
Preferably, the active pressing pair comprises a guide rail line, a small steel ball and a large steel ball; the head end of the guide rail line is connected with the lower end of the pressing frame, and the tail end radially penetrates through the small steel ball and is fixedly connected with the large steel ball; the small steel ball slides relative to the large steel ball on the guide rail line.
Preferably, the lower connecting assembly comprises a lower clamping block and an outer buckle; the lower end of the lower clamping block is detachably connected with the upper end of the outer buckle; the thick film is arranged between the upper clamping block and the lower clamping block.
Preferably, the upper clamping block and the lower clamping block are composed of two symmetrical clamping plates; the two clamping plates are connected through pins and bolts.
Preferably, a first groove is formed in the lower wall of the outer fastener; the upper end part of the pressing frame is provided with a second groove; the outer buckle and the pressing frame form a chain ring structure, and the position of the first groove corresponds to the position of the second groove.
Preferably, a first connecting hole is formed at the lower end of the outer clip; the pressing frame is provided with a second connecting hole; the second connecting hole is positioned on the upper side of the second groove.
Preferably, the size of the piezoelectric ceramic is adapted to the size of the first recess and the size of the second recess.
Preferably, the outer buckle and the pressing frame are made of metal.
Preferably, the guide rail line is nylon wire or PE wire.
Preferably, the clamping table comprises a bottom plate, a supporting rod and an upper cover plate which are sequentially arranged from bottom to top; the upper clamping block is arranged on the upper cover plate; the big steel ball is positioned on the upper side of the bottom plate.
Compared with the prior art, the invention has the beneficial effects that: the measuring device uses the piezoelectric coefficient of known ceramic materiald 33 Solving the piezoelectric coefficient of the thick film material to be measured by a comparison methodd 31 The method has the advantages of simplicity and convenience in operation, strong repeatability, accurate measurement data and the like.
Drawings
FIG. 1 is a schematic diagram of a first embodiment of the present invention;
FIG. 2 is a schematic view of a clamping assembly according to the present invention;
FIG. 3 is a detailed schematic view of the clamping assembly of the present invention;
FIG. 4 is a schematic view of the underside structure of the clamping assembly of the present invention;
fig. 5 is a schematic structural view of the pressing assembly of the present invention.
In the figure: 1, a clamping table, a 101 bottom plate, 102 support rods and 103 upper cover plates;
2 clamping components, 201 upper clamping blocks, 202 lower clamping blocks, 203 outer buckles, 204 bolts, 205 pins, 2031 first grooves and 2032 first connecting holes;
3 a pressing component, 301 a pressing block, 302 a connecting rod, 303 an inner buckle, 304 a guide rail line, 305 a small steel ball, 306 a large steel ball, 3011 a second groove and 3012 a second connecting hole;
4 piezoelectric thick film and 5 piezoelectric ceramics.
Description of the embodiments
The following detailed description of the invention, taken in conjunction with the accompanying drawings, will provide those skilled in the art with a more readily understood understanding of how the invention may be practiced. While the present invention has been described in connection with the preferred embodiments thereof, these embodiments are set forth only and are not intended to limit the scope of the invention.
First embodiment: please refer to fig. 1-5 for a piezoelectric coefficient suitable for polymer thick filmsd 31 Comprising: the clamping device comprises a clamping table 1, a clamping assembly 2 and a pressing assembly 3; specifically, the measuring device is used for measuring the voltage amplitude change of the surfaces of the piezoelectric thick film 4 and the piezoelectric ceramic 5, and solving the piezoelectric coefficient of the thick film material by a comparison methodd 31
The clamping table 1 is composed of a bottom plate 101, a supporting rod 102 and an upper cover plate 103, and is made of 304 stainless steel. The bottom plate 101 has a length of 200mm, a width of 150mm and a thickness of 30mm, and has a screw hole of M16×1.5mm at the upper end for bolting with the upper end of the support bar 102. The supporting rod 102 is a cylinder with the diameter of 30mm and the height of 400mm, and the lower end of the supporting rod is fixedly connected with the bottom plate 101. The length of the upper cover plate 103 is 160mm, the width is 100mm, the height is 20mm, the middle position of the front end part of the upper cover plate is provided with a mounting groove, the mounting groove consists of an upper step and a lower step which are corresponding in position, wherein the depth of the upper step is 50mm, the length of the upper step is 31.5mm, the width of the upper step is 10mm, and the depth of the lower step is 50mm, the length of the lower step is 21.5mm, and the width of the lower step is 10mm.
As shown in fig. 2-4, the clamping assembly 2 comprises an upper clamping block 201, a lower clamping block 202, an outer clamping buckle 203, a plurality of bolts 204 and a plurality of pins 205; the upper clamping block 201 and the lower clamping block 202 are made of 304 # stainless steel materials, and the upper clamping block 201 and the lower clamping block 202 are composed of two symmetrical clamping plates; the clamping plate of the upper clamping block 201 has the length of 50mm, the width of 15.5mm and the height of 30mm, the bottom of the outer side is cut off to have the length of 10mm, the width of 5mm and the thickness of 30mm so as to facilitate the upper clamping block 201 to be installed in the installation groove of the upper cover plate 103; screw holes with the diameter phi of 6.5mm and pin holes with the diameter phi of 5mm are formed in the middle of the two clamping plates of the upper clamping block 201, and when the clamping plate is used, the two clamping plates of the upper clamping block 201 are positioned through the holes by pins, and then the two parts are screwed by bolts;
the clamping plates of the lower clamping block 202 are 20mm in length, 15mm in width and 40mm in thickness, threaded holes of M8 are formed in the middle parts of the two clamping plates 18mm away from the bottom end, and two positioning holes are formed in the upper parts of the two clamping plates; the same as the upper clamping block 201, two clamping plates of the lower clamping block 202 are firstly positioned through holes by pins, and then the two parts are screwed up by bolts; the middle parts of the two clamping plates are respectively provided with a threaded hole M5 at a position 6mm away from the bottom end, and the threaded holes M5 are used for accommodating bolts so as to realize the connection between the lower end of the lower clamping block 202 and the upper end of the outer buckle 203;
in the test, the upper end of the piezoelectric thick film 4 is clamped by the upper clamping block 201, and the lower end is clamped by the lower clamping block 202.
The outer clip 203 is made of 304 stainless steel. The outer buckle 203 is of a U-shaped structure, the length of the outer buckle 203 is 60mm, the width of the outer buckle 203 is 40.5mm, the thickness of the outer buckle is 15mm, and the hollow-out dimension of the inner side of the outer buckle 203 is 50mm, the width of the outer buckle is 30.5mm, and the thickness of the outer buckle is 15mm; the outer clip 203 is provided with a first groove 2031 and a first connection hole 2032; the first groove 2031 is positioned on the upper wall of the lower end part of the outer buckle 203, and the first groove 2031 has the dimensions of 9mm in length, 7mm in width and 2mm in thickness; the first connection hole 2032 is located at a lower wall of the lower end portion of the outer clip 203.
As shown in fig. 5, the pressing assembly 3 includes a pressing frame, a guide rail 304, a small steel ball 305, and a large steel ball 306; the guide rail line 304 radially penetrates through the small steel ball 305, the head end of the guide rail line 304 is fixedly connected with the lower end of the pressing frame, and the tail end of the guide rail line 304 is fixedly connected with the large steel ball 306; the small steel ball 305 can slide up and down on the guide rail line 304; further, the diameter phi of the guide rail line 304 is 0.1mm, and the length is 100mm; the small steel ball 305 and the large steel ball 306 are made of brass alloy materials, the diameter phi of the small steel ball 305 is 8mm, and a round hole with the diameter phi of 1.2mm is formed in the middle of the small steel ball 305 so as to facilitate the small steel ball 305 to slide along the guide track 305; the diameter phi of the large steel ball 306 is 24mm; during testing, steel ball 306 is positioned on the upper side of base plate 101.
In other embodiments, thinner, more flexible and smoother materials such as nylon wire, PE wire, etc. may be used for the rail wire 304.
The pressing frame consists of a pressing block 301, a connecting rod 302 and an inner buckle 303; the inner fastener 303 is supported by a 304 stainless steel material; the connecting rod 302 is made of 304 stainless steel material, and has a diameter phi of 5mm and a length of 50mm;
the inner clip 303 has a U-shaped structure, and the hollow inner side of the inner clip 303 has a length of 50mm, a width of 40mm and a thickness of 15mm, and the hollow inner side has a length of 45mm, a width of 30mm and a thickness of 15mm; two holes with diameter phi of 5mm are formed in the inner buckle 303 at the position 45mm away from the bottom end of the inner buckle and are used for erecting the connecting rod 11 and the pressing block 13, wherein the connecting rod 11 penetrates through the pressing block 13 and the pressing block 13 is positioned between two arms of the inner buckle 303, and the pressing block 301, the connecting rod 302 and the inner buckle 303 form a closed loop structure; a hole with the diameter phi of 1.6mm is formed in the middle of the bottom of the inner buckle 303 so as to facilitate the installation of the guide rail line 304;
the pressing block 301 is made of 304 stainless steel material, and has the length of 15mm, the width of 12mm and the thickness of 30mm; the lower end of the pressing block 301 is provided with a second groove 3011, and the side surface of the pressing block is provided with a second connecting hole 3012; the length of the second groove 3011 is 9mm, the width is 7mm, and the thickness is 2mm; the diameter Φ1.6mm of the second connection hole 3012.
During testing, the pressing frame is sleeved on the outer buckle 203, and forms a chain ring structure with the outer buckle 203, and at the moment, the position of the first groove 2031 corresponds to the position of the second connecting hole 3012 and is used for installing the piezoelectric ceramic 5; in other embodiments, the size of the first recess 2031 and the size of the second connection hole 3012 may be set according to the size of the piezoelectric ceramic 5.
In this example, piezoelectric thick film 4 is a piezoelectric homopolymer [ polyvinylidene fluoride (PVDF) ]]Material or piezoelectric copolymer [ P (VDF-TrFE)]The piezoelectric thick film 4 is prepared from the material, the thickness of the piezoelectric thick film 4 is 0.5mm, the total length of the piezoelectric thick film is 120mm, the length of a coated electrode is 100mm, and the width of the coated electrode is 10mm; the piezoelectric ceramics 5 ared 33 The standard component of the vibrator is prepared from PZT-4 piezoelectric ceramic material, and has the length of 9mm, the width of 7mm and the height of 20mm; in other embodiments, the dimensions of the piezoelectric thick film 4 and the dimensions of the piezoelectric ceramic 5 may be adjusted according to the conditions, depending on the test conditions.
When the measuring device is used, an oscilloscope is required to be arranged; specifically, the first connecting hole 2032 and the second connecting hole 3012 both accommodate wires, and the piezoelectric ceramic 5 is connected with an external oscilloscope through the wires and is used for recording the voltage change of the ceramic surface when impact occurs; for the piezoelectric thick film 4, two electrode surfaces of the piezoelectric thick film 4 are respectively connected with leads, so that the piezoelectric thick film 4 is connected with an external oscilloscope, and the voltage change of the surface of the piezoelectric thick film when impact occurs is recorded.
The working principle of the measuring device is that the impact force generated by the small steel ball falling from a certain height to strike the large steel ball is utilizedFImpact force hereFMainly by knowing capacitance, voltaged 33 The piezoelectric ceramic of the parameters is obtained, the pressure born by the piezoelectric ceramic is equivalent to the tensile force born by the piezoelectric thick film through the force conduction of the rigid structure of the device, and then the piezoelectric coefficient of the thick film material is calculated through measuring the surface capacitance, voltage amplitude and area parameters of the piezoelectric thick film and the piezoelectric ceramicd 31
In the present invention,d 33 the piezoelectric constant is defined as:
Figure SMS_1
here the number of the elements is the number,A 1 is the stress area of the ceramic sample,C 1 a ceramic capacitor.
In the present invention, the piezoelectric coefficientd 31 The definition is as follows:
Figure SMS_2
here the number of the elements is the number,A 2 is the stressed area of the piezoelectric thick film,B 2 the area for the charge generation for the piezoelectric thick film,C 2 is a piezoelectric thick film capacitor.
The measuring device uses the piezoelectric coefficient of known ceramic materiald 33 Solving the piezoelectric coefficient of the thick film material to be measured by a comparison methodd 31 The method has the advantages of simplicity and convenience in operation, strong repeatability, accurate measurement data and the like.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (10)

1. Piezoelectric coefficient suitable for polymer thick filmd 31 The measuring device of (1) comprises an oscilloscope and piezoelectric ceramics, and is characterized in that: the clamping table (1), the clamping assembly (2) and the pressing assembly (3); the clamping assembly (2) comprises an upper clamping block (201) and a lower connecting assembly; the upper clamping block (201) is arranged on the clamping table (1), the lower connecting component is positioned at the lower side of the upper clamping block (201), and the upper end of the lower connecting component is connected with the lower end of the upper clamping block (201) through a thick film; the pressing assembly (3) comprises a pressing frame and an active pressing pair; the active pressing pair is arranged at the lower end of the pressing frame; the upper end part of the pressing frame is connected with the lower end part of the lower connecting component through piezoelectric ceramics; the oscillograph is connected with the piezoelectric ceramic and the thick film through leads.
2. A piezoelectric coefficient suitable for use in polymer thick film according to claim 1d 31 Is characterized in that: the active pressing pair comprises a guide rail line (304), a small steel ball (305) and a large steel ball (306); the head end of the guide rail line (304) is connected with the lower end of the pressing frame, and the tail end radially penetrates through the small steel ball (305) and is fixedly connected with the large steel ball (306); the small steel ball (305) slides on the guide rail line (304) relative to the large steel ball (306).
3. A piezoelectric coefficient suitable for use in polymer thick film according to claim 1d 31 Is characterized in that: the lower connecting component comprises a lower clamping block (202) and an outer clamping buckle (203); the lower end of the lower clamping block (202) is detachably connected with the upper end of the outer buckle (203); the thick film is arranged between an upper clamping block (201) and a lower clamping block (202).
4. A piezoelectric coefficient suitable for use in polymer thick film according to claim 3d 31 Is characterized in that: the upper clamping block (201) and the lower clamping block (202) are composed of two symmetrical clamping plates;the two clamping plates are connected through pins and bolts.
5. A piezoelectric coefficient suitable for use in polymer thick film according to claim 3d 31 Is characterized in that: a first groove (2031) is formed in the lower wall of the outer clamp (203); a second groove (3011) is formed in the upper end part of the pressing frame; the outer buckle (203) and the pressing frame form a chain ring structure, and the position of the first groove (2031) corresponds to the position of the second groove (3011).
6. A piezoelectric coefficient suitable for use in polymer thick film as claimed in claim 5d 31 Is characterized in that: the lower end of the outer clamp buckle (203) is provided with a first connecting hole (2032); the pressing frame is provided with a second connecting hole (3012); the second connection hole (3012) is located at an upper side of the second groove (3011).
7. A piezoelectric coefficient suitable for use in polymer thick film as claimed in claim 5d 31 Is characterized in that: the size of the piezoelectric ceramic is matched with the size of the first groove (2031) and the size of the second groove (3011).
8. A piezoelectric coefficient suitable for use in polymer thick film as claimed in claim 6d 31 Is characterized in that: the outer clamping buckle (203) and the pressing frame are made of metal.
9. A piezoelectric coefficient suitable for use in polymer thick film according to claim 2d 31 Is characterized in that: the guide rail wire (304) is nylon wire or PE wire.
10. A piezoelectric coefficient suitable for use in polymer thick film according to claim 2d 31 Is characterized in that: the clamping table (1) comprises a clamping table body from bottom to topA bottom plate (101), a supporting rod (102) and an upper cover plate (103) which are sequentially arranged on the upper part; the upper clamping block (201) is arranged on the upper cover plate (103); the big steel ball (306) is positioned on the upper side of the bottom plate (101).
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