CN116392964A - Dielectrophoresis gas purification unit module and method based on high dielectric material - Google Patents

Dielectrophoresis gas purification unit module and method based on high dielectric material Download PDF

Info

Publication number
CN116392964A
CN116392964A CN202310683701.9A CN202310683701A CN116392964A CN 116392964 A CN116392964 A CN 116392964A CN 202310683701 A CN202310683701 A CN 202310683701A CN 116392964 A CN116392964 A CN 116392964A
Authority
CN
China
Prior art keywords
electrode
dielectrophoretic
high dielectric
shaped
gas purification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202310683701.9A
Other languages
Chinese (zh)
Other versions
CN116392964B (en
Inventor
李旺
张星
李志新
杨名超
马德强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yuanke Qinhuangdao Energy Saving And Environmental Protection Technology Development Co ltd
Original Assignee
Hebei Normal University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Normal University of Science and Technology filed Critical Hebei Normal University of Science and Technology
Priority to CN202310683701.9A priority Critical patent/CN116392964B/en
Publication of CN116392964A publication Critical patent/CN116392964A/en
Application granted granted Critical
Publication of CN116392964B publication Critical patent/CN116392964B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D57/00Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C
    • B01D57/02Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C by electrophoresis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrostatic Separation (AREA)

Abstract

The invention discloses a dielectrophoresis gas purification unit module and a dielectrophoresis gas purification method based on a high dielectric material, and relates to the technical field of energy conservation, environmental protection and separation of solids from fluid and high-voltage electric field separation. The purifying unit module comprises a dielectrophoresis electrode structure and an alternating current power supply, the dielectrophoresis electrode structure comprises an annular barrel-shaped electrode, a central electrode is arranged at the axial position of the annular barrel-shaped electrode, supporting frames are arranged at two ends of the annular barrel-shaped electrode, the central electrode is connected with the annular barrel-shaped electrode through the supporting frames, the annular barrel-shaped electrode, the supporting frames and the central electrode form a cavity structure, and high-dielectric ceramic spheres are filled in the cavity structure; and one pole of the alternating current power supply is connected with the central electrode, and the other pole of the alternating current power supply is connected with the annular barrel-shaped electrode. The dielectrophoresis gas purification unit module provided by the invention has the advantages of simple and stable structure, high purification efficiency, no need of replacing a filter screen, convenience in cleaning, capability of purifying tiny particles and small wind resistance.

Description

一种基于高介电材料的介电电泳气体净化单元模块及方法Dielectrophoretic gas purification unit module and method based on high dielectric material

技术领域technical field

本发明涉及节能环保和从流体中分离固体技术领域,具体而言,涉及一种基于高介电材料的介电电泳气体净化单元模块及方法。The invention relates to the technical field of energy saving and environmental protection and the separation of solids from fluids, in particular to a dielectrophoresis gas purification unit module and method based on high dielectric materials.

背景技术Background technique

为了实现更低浓度粉尘污染物的排放,企业需要性能更好的除尘设备。目前,针对空气中的粉尘颗粒净化的除尘设备有很多种,包括机械除尘器、电除尘器、湿式除尘器和过滤式除尘器,但是以上除尘器主要是对空气中较大的粉尘进行处理,对于微小的颗粒物,特别是可吸入的颗粒物,现有的除尘设备除尘效果不佳,而空气污染中微小粉尘的含量不可忽视,是雾霾形成的重要原因。In order to achieve a lower concentration of dust pollutant emissions, companies need dust removal equipment with better performance. At present, there are many kinds of dust removal equipment for the purification of dust particles in the air, including mechanical dust collectors, electric dust collectors, wet dust collectors and filter dust collectors, but the above dust collectors mainly deal with larger dust in the air. For tiny particles, especially inhalable particles, the existing dust removal equipment is not effective in removing dust, and the content of tiny dust in air pollution cannot be ignored, which is an important reason for the formation of smog.

现有的空气净化技术有:吸附技术、负(正)离子技术、催化技术、光触媒技术、超结构光矿化技术、HEPA高效过滤技术、静电集尘技术等。不论采用哪种技术,多数都存在结构较复杂、制作麻烦费事、成本高、主要部件使用寿命短需要经常更换部件而增加费用开支等问题。例如,一些滤网型过滤除尘技术中,极细小微颗粒有可能漏网,除尘效果不尽理想,而且滤网需要经常更换;静电除尘法,是利用高压直流电场产生使空气中的气体分子电产生大量电子和离子,之后在电场力的作用下向两极移动,在移动过程中碰到气流中的粉尘颗粒使其荷电,荷电颗粒在电场力作用向极板运动,实现固体粒子或液体粒子与气流的分离,这种高压静电除尘技术中涉及的设备复杂、运行时能耗大。Existing air purification technologies include: adsorption technology, negative (positive) ion technology, catalytic technology, photocatalyst technology, superstructure photomineralization technology, HEPA high-efficiency filtration technology, electrostatic dust collection technology, etc. No matter which technology is used, most of them have problems such as complex structure, troublesome production, high cost, short service life of main components, and frequent replacement of components, which increases expenses. For example, in some filter-type filter dust removal technologies, extremely fine particles may slip through the screen, the dust removal effect is not ideal, and the filter screen needs to be replaced frequently; the electrostatic dust removal method uses a high-voltage DC electric field to generate electricity from gas molecules in the air. A large number of electrons and ions move to the poles under the action of the electric field force. During the movement, they encounter dust particles in the airflow to charge them. The charged particles move to the plate under the action of the electric field force to realize solid particles or liquid particles. Separated from the air flow, the equipment involved in this high-voltage electrostatic precipitator technology is complex and consumes a lot of energy during operation.

与目前工业上广泛应用的是管式静电除尘器和板式静电除尘器不同,介电电泳技术除尘具有不同的特点:Different from tubular electrostatic precipitators and plate electrostatic precipitators, which are widely used in industry at present, dielectrophoretic dust removal has different characteristics:

首先,介电电泳技术操纵的是中性颗粒,使其由于介电极化的作用而产生的平移运动;而静电除尘技术中操纵的是电子和离子,使粉尘颗粒负荷后而产生定向移动。First of all, the dielectrophoresis technology manipulates neutral particles to cause translational motion due to the effect of dielectric polarization; while the electrostatic dust removal technology manipulates electrons and ions to make the dust particles move directional after being loaded.

其次,介电电泳技术中颗粒运动方向与电场的方向无关,只与其本身的介电常数和介质的介电常数有关;而静电除尘技术中颗粒运动方向取决于颗粒所带电荷的符号和电场的方向,电场方向反转则运动方向反转。Secondly, the direction of particle movement in dielectrophoresis technology has nothing to do with the direction of the electric field, but only with its own dielectric constant and the dielectric constant of the medium; while in electrostatic dust removal technology, the direction of particle movement depends on the sign of the charge on the particle and the value of the electric field. If the direction of the electric field is reversed, the direction of motion is reversed.

再者,介电电泳技术中需要非均匀电场;而静电除尘技术则需要均匀或非均匀的直流电场。Furthermore, the dielectrophoretic technology requires a non-uniform electric field; while the electrostatic precipitator technology requires a uniform or non-uniform DC electric field.

另外,介电电泳技术中粉尘所受到的吸附力来源于介电电泳力,其介电电泳力的大小正比于颗粒直径的立方和电场梯度的平方;而静电除尘技术中粉尘所受到的静电力的大小正比于颗粒所带电荷的多少,因此除尘效果与粉尘粒子所带的电荷直接相关。In addition, the adsorption force of the dust in the dielectrophoretic technology comes from the dielectrophoretic force, and the size of the dielectrophoretic force is proportional to the cube of the particle diameter and the square of the electric field gradient; The size of the particle is proportional to the amount of charge carried by the particle, so the dust removal effect is directly related to the charge carried by the dust particle.

在现有介电电泳除尘技术中,专利申请号为201410407467.8的专利申请公开了一种介电电泳电极结构,提出了一种介电电泳电极结构,其包括沿第一方向平行或大致平行排布的第一导线群,沿第二方向平行或大致平行排布的第二导线群,第一导线群与第二导线群中的导线外部都具有绝缘层,第一方向与第二方向不平行,第一导线群与第二导线群中的导线交织在一起,第一导线群和第二导线群中的一部分导线连接电源正极,另一部分连接电源负极。另外,此专利技术中采用的介电电泳电极为独立的条状,并通过导线连接在交流电源的对应输出端,需要逐个安装在分离室中并分别通过导线连接对应的输出端,不但费时费力,还可能造成分离室的结构比较松散、接线复杂、容易损坏的问题;除此之外,条状电极还需要逐条制作,工艺成本较高。In the existing dielectrophoretic dust removal technology, the patent application No. 201410407467.8 discloses a dielectrophoretic electrode structure, and proposes a dielectrophoretic electrode structure, which includes parallel or roughly parallel arrangements along the first direction The first wire group, the second wire group arranged in parallel or substantially parallel along the second direction, the wires in the first wire group and the second wire group have an insulating layer on the outside, the first direction is not parallel to the second direction, The wires in the first wire group and the second wire group are intertwined together, some of the wires in the first wire group and the second wire group are connected to the positive pole of the power supply, and the other part is connected to the negative pole of the power supply. In addition, the dielectrophoretic electrodes used in this patented technology are independent strips and are connected to the corresponding output terminals of the AC power supply through wires. They need to be installed in the separation chamber one by one and connected to the corresponding output terminals through wires, which is time-consuming and laborious. , it may also cause problems such as relatively loose structure of the separation chamber, complicated wiring, and easy damage; in addition, strip electrodes need to be fabricated one by one, and the process cost is relatively high.

综上所述,现有除尘技术存在如下至少一个技术问题:In summary, there is at least one technical problem in the existing dust removal technology as follows:

现有净化技术中,高压静电除尘设备复杂、能耗大;In the existing purification technology, the high-voltage electrostatic dust removal equipment is complicated and consumes a lot of energy;

网式过滤法难以对微小颗粒进行过滤,并需要定期更换滤网,存在大量耗材浪费,成本高,不便于清洁的问题;The mesh filter method is difficult to filter tiny particles, and the filter needs to be replaced regularly. There is a lot of waste of consumables, high cost, and inconvenient cleaning;

介电电泳除尘技术中,介电电泳电极结构及制作组装工艺相对复杂,不便于清洁保养。In dielectrophoresis dust removal technology, the structure and assembly process of dielectrophoresis electrodes are relatively complicated, which is not easy to clean and maintain.

发明内容Contents of the invention

本发明的主要目的在于提供一种基于高介电材料的介电电泳气体净化单元模块及方法,以解决背景技术中至少一个技术问题。The main purpose of the present invention is to provide a dielectrophoretic gas purification unit module and method based on high dielectric materials, so as to solve at least one technical problem in the background art.

为了实现上述目的,根据本发明的一个方面,提供了一种基于高介电材料的介电电泳气体净化单元模块,包括:In order to achieve the above object, according to one aspect of the present invention, a dielectrophoretic gas purification unit module based on high dielectric material is provided, including:

介电电泳电极结构,所述介电电泳电极结构包括环形桶状电极,所述环形桶状电极轴线位置设有中心电极,所述环形桶状电极两端设有支撑架,所述中心电极通过支撑架与环形桶状电极相连固定,所述环形桶状电极、支撑架和中心电极形成空腔结构,所述空腔结构内填充高介电陶瓷球体;Dielectrophoretic electrode structure, the dielectrophoretic electrode structure includes a ring-shaped barrel electrode, a center electrode is provided at the axial position of the ring-shaped barrel-shaped electrode, support frames are provided at both ends of the ring-shaped barrel-shaped electrode, and the center electrode passes through The support frame is connected and fixed to the annular barrel-shaped electrode, and the annular barrel-shaped electrode, the support frame and the central electrode form a cavity structure, and the cavity structure is filled with high-dielectric ceramic spheres;

交流电源,所述交流电源的一极与中心电极相连,所述交流电源的另一极与环形桶状电极相连;An AC power supply, one pole of the AC power supply is connected to the center electrode, and the other pole of the AC power supply is connected to the ring-shaped barrel electrode;

所述环形桶状电极的内环直径为10-50mm;The diameter of the inner ring of the annular barrel-shaped electrode is 10-50mm;

所述高介电陶瓷球体的介电常数为23000-34000,直径为2.3-2.8mm;The dielectric constant of the high dielectric ceramic sphere is 23000-34000, and the diameter is 2.3-2.8mm;

所述交流电源的频率为800-5000Hz,交流电源的电压满足中心电极和环形桶状电极之间的电场强度为200-3000V/cm。The frequency of the AC power supply is 800-5000 Hz, and the voltage of the AC power supply satisfies that the electric field strength between the central electrode and the ring-shaped barrel electrode is 200-3000 V/cm.

优选的,所述支撑架采用绝缘的陶瓷或者塑料制成,所述支撑架包括第一支架和第二支架,所述第一支架上具有第一缝隙,所述第二支架上具有第二缝隙,所述第一缝隙和第二缝隙的宽度均小于高介电陶瓷球体的直径,第一支架和第二支架分别封堵在环形桶状电极的两端。支撑架上设置第一缝隙和第二缝隙是为了通风,其中第一缝隙和第二缝隙的宽度小于高介电陶瓷球体的直径,目的是为了防止高介电陶瓷球体从缝隙滚出。Preferably, the support frame is made of insulating ceramic or plastic, the support frame includes a first bracket and a second bracket, the first bracket has a first gap, and the second bracket has a second gap , the widths of the first gap and the second gap are both smaller than the diameter of the high dielectric ceramic sphere, and the first bracket and the second bracket are respectively blocked at both ends of the annular barrel-shaped electrode. The first slit and the second slit are provided on the support frame for ventilation, wherein the width of the first slit and the second slit is smaller than the diameter of the high dielectric ceramic sphere, and the purpose is to prevent the high dielectric ceramic sphere from rolling out of the slit.

优选的,所述环形桶状电极采用金属管结构,所述中心电极采用实心金属棒结构。Preferably, the annular barrel-shaped electrode adopts a metal tube structure, and the central electrode adopts a solid metal rod structure.

优选的,所述介电电泳气体净化单元模块还包括连接板,所述连接板上设置若干个介电电泳电极结构,每个介电电泳电极结构的中心电极分别与交流电源的一极相连,每个介电电泳电极结构的环形桶状电极分别与交流电源的另一极相连。若干个介电电泳电极结构并联形成气体净化模块,即多个介电电泳电极结构安装在一个连接板上形成一个模块,交流电源的两极分别与每个介电电泳电极结构的中心电极与环形桶状电极连接。Preferably, the dielectrophoretic gas purification unit module further includes a connecting plate, on which several dielectrophoretic electrode structures are arranged, and the central electrode of each dielectrophoretic electrode structure is respectively connected to one pole of the AC power supply, The annular barrel-shaped electrode of each dielectrophoretic electrode structure is respectively connected to the other pole of the AC power supply. Several dielectrophoretic electrode structures are connected in parallel to form a gas purification module, that is, multiple dielectrophoretic electrode structures are installed on a connecting plate to form a module, and the two poles of the AC power supply are respectively connected to the center electrode of each dielectrophoretic electrode structure and the ring barrel electrode connection.

优选的,所述支撑架中心位置设有通孔,所述通孔中穿设中心电极。在支撑架中设置通孔的目的是为了穿设和固定中心电极,支撑架通过通孔来支撑和固定中心电极。Preferably, a through hole is provided at the center of the support frame, and a central electrode is passed through the through hole. The purpose of setting the through hole in the support frame is to penetrate and fix the central electrode, and the support frame supports and fixes the central electrode through the through hole.

优选的,所述环形桶状电极上焊接有第一接线端,所述中心电极上焊接有第二接线端,所述第一接线端和第二接线端分别通过电极引线与交流电源相连。优选的,所述交流电源为正弦交流电或者脉冲式交流电,交流电源的频率为800-5000Hz,交流电源的电压满足中心电极和环形桶状电极之间的电场强度为200-3000V/cm(即满足交流电源的电压U与中心电极和环形桶状电极之间距离d的比值为200-3000V/cm)。Preferably, a first terminal is welded on the annular barrel-shaped electrode, a second terminal is welded on the central electrode, and the first terminal and the second terminal are respectively connected to an AC power source through electrode leads. Preferably, the AC power supply is sinusoidal alternating current or pulsed alternating current, the frequency of the AC power supply is 800-5000 Hz, and the voltage of the AC power supply meets the requirement that the electric field strength between the central electrode and the ring-shaped barrel electrode is 200-3000V/cm (that is, satisfying The ratio of the voltage U of the AC power supply to the distance d between the central electrode and the annular barrel electrode is 200-3000V/cm).

优选的,所述连接板上设有若干安装槽,所述安装槽内固定安装介电电泳电极结构。设置安装槽的目的是为了安装固定介电电泳电极结构。安装槽数量根据需要设置的介电电泳电极结构的数量而设置,每个安装槽内插设一个介电电泳电极结构,安装槽与介电电泳电极结构之间可采用过盈配合或者通过螺纹配合连接。Preferably, the connection plate is provided with several installation grooves, and the dielectrophoretic electrode structure is fixedly installed in the installation grooves. The purpose of providing the installation groove is to install and fix the DEP electrode structure. The number of installation slots is set according to the number of DEP electrode structures that need to be installed. A DEP electrode structure is inserted in each installation slot. Interference fit or thread fit can be used between the installation slot and DEP electrode structure connect.

优选的,所述连接板上设有槽孔,所述槽孔内设有橡胶塞,所述橡胶塞中穿设连接引线,其中槽孔用于插设橡胶塞。橡胶塞用于实现与连接引线之间的紧密接触,进而保证穿设连接引线时的密封性。Preferably, the connecting plate is provided with a slot, and a rubber plug is provided in the slot, and a connection lead wire is passed through the rubber plug, wherein the slot is used for inserting the rubber plug. The rubber plug is used to achieve close contact with the connecting lead, thereby ensuring the sealing when the connecting lead is passed through.

根据本发明的另一方面,提供了一种基于高介电材料的介电电泳气体净化方法,包括:According to another aspect of the present invention, a kind of dielectrophoretic gas purification method based on high dielectric material is provided, comprising:

通过将中心电极和环形桶状电极分别连接到交流电源的两极,并调节交流电源的电压和频率,使得在中心电极与环形桶状电极之间形成非均匀的电场;填充在中心电极和环形桶状电极之间的具有高介电常数的高介电陶瓷球体被高度极化,从而使高介电陶瓷球体表面产生大量感应电荷;中心电极与环形桶状电极之间的电场在高介电陶瓷球体曲面结构的作用下剧烈变化而在高介电陶瓷球之间的间隙区域形成极大的电场梯度,从而有效增强对气体中的粉尘粒子的介电电泳力;粉尘粒子在介电电泳力的作用下,向高介电陶瓷球的外壁移动并被吸附在高介电陶瓷球的表面,从而实现对空气中粉尘粒子高效捕捉。By connecting the center electrode and the ring-shaped barrel electrode to the two poles of the AC power supply, and adjusting the voltage and frequency of the AC power supply, a non-uniform electric field is formed between the center electrode and the ring-shaped barrel electrode; filling in the center electrode and the ring barrel The high-dielectric ceramic sphere with high dielectric constant between the electrodes is highly polarized, so that a large amount of induced charges are generated on the surface of the high-dielectric ceramic sphere; the electric field between the center electrode and the ring-shaped barrel electrode Under the action of the curved surface structure of the sphere, a large electric field gradient is formed in the gap area between the high dielectric ceramic balls, thereby effectively enhancing the dielectrophoretic force on the dust particles in the gas; the dust particles in the dielectrophoretic force Under the action, it moves to the outer wall of the high dielectric ceramic ball and is adsorbed on the surface of the high dielectric ceramic ball, so as to realize the efficient capture of dust particles in the air.

与现有技术相比,本发明具有如下技术效果:Compared with the prior art, the present invention has the following technical effects:

高介电陶瓷球体、中心电极和环形桶状电极、支撑架结构简单、稳定,易于工业化批量生产;High-dielectric ceramic spheres, central electrodes, ring-shaped barrel electrodes, and support frames have simple and stable structures, and are easy to mass-produce in an industrialized manner;

高介电陶瓷球体填充在中心电极与环形电极之间,填充装配时易于操作;当需要对各部件清洗时,可以将高介电陶瓷球体取出进行清洗后再进行填充,不存在耗材的浪费;The high dielectric ceramic sphere is filled between the center electrode and the ring electrode, which is easy to operate during filling and assembly; when it is necessary to clean each part, the high dielectric ceramic sphere can be taken out for cleaning and then filled, and there is no waste of consumables;

高介电陶瓷球体性能稳定,高介电陶瓷球体可以重复使用,且高介电陶瓷球体耐高温,可以对高温气体进行净化;High-dielectric ceramic spheres have stable performance, high-dielectric ceramic spheres can be reused, and high-dielectric ceramic spheres are resistant to high temperatures and can purify high-temperature gases;

空气粉尘净化率高:由于高介电陶瓷球体具有高的介电常数,当处于中心电极与环形桶状电极形成的非均匀电场中时,高介电陶瓷球体被高度极化,从而在高介电陶瓷球体表面产生大量感应电荷。中心电极和环形桶状电极之间的非均匀电场将会在高介电陶瓷球体曲面结构的作用下剧烈变化而在陶瓷球之间的间隙区域形成极大的电场梯度,进而有效增强粉尘粒子所受到的介电电泳力,从而实现对空气中粉尘粒子的高效率捕捉净化;High air dust purification rate: due to the high dielectric constant of the high dielectric ceramic sphere, when it is in the non-uniform electric field formed by the central electrode and the ring-shaped barrel electrode, the high dielectric ceramic sphere is highly polarized, thus A large amount of induced charge is generated on the surface of the electroceramic sphere. The non-uniform electric field between the central electrode and the ring-shaped barrel electrode will change drastically under the action of the curved surface structure of the high-dielectric ceramic sphere, and a large electric field gradient will be formed in the gap area between the ceramic spheres, thereby effectively enhancing the dust particles. Received dielectrophoretic force, so as to achieve high-efficiency capture and purification of dust particles in the air;

另外,中心电极和环形桶状电极之间的高介电陶瓷球体相互堆积会在球体之间自然形成间隙,其间隙隙尺寸为0.5-1.5mm之间,其间隙尺寸远远大于过滤网的缝隙尺寸,因此当对空气进行粉尘净化时,可以明显减小风阻,一方面可以减小风机的功率,从而减小净化器的噪音;另一方面可以加大通风量而提高净化效率。In addition, the stacking of high-dielectric ceramic spheres between the central electrode and the ring-shaped barrel electrode will naturally form a gap between the spheres. The size of the gap is between 0.5-1.5mm, and the size of the gap is much larger than the gap of the filter screen. Size, so when the air is dust purified, the wind resistance can be significantly reduced. On the one hand, the power of the fan can be reduced, thereby reducing the noise of the purifier; on the other hand, the ventilation volume can be increased to improve the purification efficiency.

附图说明Description of drawings

构成本申请的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The accompanying drawings constituting a part of the present application are used to provide a further understanding of the present invention, and the schematic embodiments and descriptions of the present invention are used to explain the present invention, and do not constitute an improper limitation of the present invention. In the attached picture:

图1示出了根据本发明的基于高介电材料的介电电泳气体净化单元模块的结构示意图;Fig. 1 shows the structural representation of the dielectrophoretic gas purification unit module based on high dielectric material according to the present invention;

图2示出了图1中的基于高介电材料的介电电泳气体净化单元模块的主视图;Fig. 2 shows the front view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图3示出了图1中的基于高介电材料的介电电泳气体净化单元模块的左视图;Fig. 3 shows the left side view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图4示出了图1中的基于高介电材料的介电电泳气体净化单元模块的俯视图;Fig. 4 shows the top view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图5示出了图1中的基于高介电材料的介电电泳气体净化单元模块的仰视图;Fig. 5 shows the bottom view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图6示出了图1中的基于高介电材料的介电电泳气体净化单元模块的右视图;Fig. 6 shows the right side view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图7示出了图1中的基于高介电材料的介电电泳气体净化单元模块的高介电陶瓷球体填充视图;Fig. 7 shows the high dielectric ceramic sphere filling view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图8示出了图1中的基于高介电材料的介电电泳气体净化单元模块的组装结构视图;Fig. 8 shows the assembly structure view of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 1;

图9示出了图8中的基于高介电材料的介电电泳气体净化单元模块的组装结构侧视图;Fig. 9 shows a side view of the assembly structure of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 8;

图10示出了图8中的基于高介电材料的介电电泳气体净化单元模块的组装结构主视图;Fig. 10 shows the front view of the assembly structure of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 8;

图11示出了图8中的基于高介电材料的介电电泳气体净化单元模块的组装结构俯视图;Fig. 11 shows the top view of the assembly structure of the dielectrophoretic gas purification unit module based on high dielectric material in Fig. 8;

图12示出了图8中的基于高介电材料的介电电泳气体净化单元模块的组装结构仰视图。FIG. 12 shows a bottom view of the assembly structure of the DEP gas purification unit module based on high dielectric material in FIG. 8 .

其中,上述附图包括以下附图标记:Wherein, the above-mentioned accompanying drawings include the following reference signs:

中心电极1;第一缝隙2;第一支架3;环形桶状电极4;第一接线端5;第二支架6;第二接线端7;第二缝隙8;连接板9;第一结构体10;第二结构体11;第三结构体12;第四结构体13;橡胶塞14;安装槽15;高介电陶瓷球体16。Center electrode 1; first slit 2; first support 3; ring-shaped barrel electrode 4; first terminal 5; second support 6; second terminal 7; second slit 8; connecting plate 9; first structure 10; second structure 11; third structure 12; fourth structure 13; rubber plug 14; installation groove 15;

具体实施方式Detailed ways

需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本发明。It should be noted that, in the case of no conflict, the embodiments in the present application and the features in the embodiments can be combined with each other. The present invention will be described in detail below with reference to the accompanying drawings and examples.

如图1至图7所示,本发明实施例提供了一种基于高介电材料的介电电泳气体净化单元模块,包括介电电泳电极结构和交流电源。所述介电电泳电极结构包括环形桶状电极4,所述环形桶状电极4轴线位置设有中心电极1,所述环形桶状电极4两端设有支撑架,所述中心电极1通过支撑架与环形桶状电极4相连,所述环形桶状电极4、支撑架和中心电极1形成空腔结构,所述空腔结构内填充有高介电陶瓷球体16;所述交流电源的一极与中心电极1相连,所述交流电源的另一极与环形桶状电极4相连。本发明结构设计科学合理,具有介电电泳效果好、结构简单、制作安装容易、除尘效果好、效率高、成本低、清理容易、使用寿命长等特点。介电电泳净化是对粒子进行分离的一种重要方法,可以实现固液分离和固气分离。As shown in FIGS. 1 to 7 , an embodiment of the present invention provides a dielectrophoretic gas purification unit module based on a high dielectric material, including a dielectrophoretic electrode structure and an AC power supply. The dielectrophoretic electrode structure includes a ring-shaped barrel electrode 4, the axis position of the ring-shaped barrel-shaped electrode 4 is provided with a central electrode 1, and two ends of the ring-shaped barrel-shaped electrode 4 are provided with support frames, and the center electrode 1 is supported by The frame is connected with the ring-shaped barrel electrode 4, and the ring-shaped barrel electrode 4, the support frame and the center electrode 1 form a cavity structure, and the cavity structure is filled with high-dielectric ceramic spheres 16; one pole of the AC power supply It is connected with the central electrode 1 , and the other pole of the AC power supply is connected with the ring-shaped barrel electrode 4 . The invention has scientific and reasonable structural design, good dielectrophoresis effect, simple structure, easy manufacture and installation, good dust removal effect, high efficiency, low cost, easy cleaning, long service life and the like. Dielectrophoresis purification is an important method for particle separation, which can realize solid-liquid separation and solid-gas separation.

所述介电电泳电极结构由中心电极1、环形桶状电极4、支撑架、高介电陶瓷球体16组成,其中中心电极1通过位于环形桶状电极4两端的支撑架固定于环形桶状电极4的轴向中心位置,交流电源的两极分别连接中心电极1和环形桶状电极4。The dielectrophoretic electrode structure is composed of a central electrode 1, an annular barrel-shaped electrode 4, a support frame, and a high-dielectric ceramic sphere 16, wherein the central electrode 1 is fixed to the annular barrel-shaped electrode through the support frames at both ends of the annular barrel-shaped electrode 4 4, the two poles of the AC power supply are respectively connected to the center electrode 1 and the annular barrel-shaped electrode 4.

实施例1Example 1

本实施例中,介电电泳电极结构包括环形桶状电极4,环形桶状电极4轴线位置设有中心电极1。环形桶状电极4采用铜管结构,中心电极1采用实心铜棒结构,环形桶状电极4上焊接有第一接线端5,中心电极1上焊接有第二接线端7,第一接线端5和第二接线端7分别通过电极引线与交流电源相连。其中,中心电极1直径为1-3mm,环形桶状电极4的内环直径为10-50mm,高度为20-1000mm。优选的,本实施例中,铜管结构内径30mm,铜管结构长度150mm,中心电极1采用直径为4mm的实心铜棒结构,中心电极1长度为180mm。In this embodiment, the dielectrophoretic electrode structure includes an annular barrel-shaped electrode 4 , and a central electrode 1 is provided at the axial position of the annular barrel-shaped electrode 4 . The annular barrel-shaped electrode 4 adopts a copper tube structure, the center electrode 1 adopts a solid copper rod structure, the annular barrel-shaped electrode 4 is welded with a first terminal 5, the center electrode 1 is welded with a second terminal 7, and the first terminal 5 and the second terminal 7 are respectively connected to an AC power source through electrode leads. Wherein, the diameter of the central electrode 1 is 1-3 mm, the diameter of the inner ring of the annular barrel-shaped electrode 4 is 10-50 mm, and the height is 20-1000 mm. Preferably, in this embodiment, the inner diameter of the copper tube structure is 30 mm, the length of the copper tube structure is 150 mm, the center electrode 1 is a solid copper rod structure with a diameter of 4 mm, and the length of the center electrode 1 is 180 mm.

本实施例中,环形桶状电极4两端设有支撑架,中心电极1通过支撑架与环形桶状电极4相连,支撑架采用绝缘材质,制作成瓶盖形状,可通过螺纹与环形桶状电极4相连;支撑架包括第一支架3和第二支架6,第一支架3上具有第一缝隙2,第二支架6上具有第二缝隙8,所述第一缝隙2和第二缝隙8的形状为条状、孔状中的一种或者组合,第一缝隙2和第二缝隙8的宽度均小于高介电陶瓷球体16的直径,也即满足高介电陶瓷球16不会从第一缝隙2和第二缝隙8通过。优选的,在满足支撑强度要求的前提下,应提高缝隙的面积以增加气体的流通量。在本实施例中,缝隙占支撑架截面面积的85-88%;支撑架中心位置设有通孔,通孔中穿设中心电极1,当中心电极1采用4mm铜棒结构时,通孔直径采用4mm。其中第一支架3和第二支架6分别用于封堵住环形桶状电极4的两端和支撑固定中心电极1,防止高介电陶瓷球体16滚出空腔结构。In this embodiment, a support frame is provided at both ends of the annular barrel-shaped electrode 4, and the center electrode 1 is connected with the annular barrel-shaped electrode 4 through the support frame. The electrodes 4 are connected; the support frame includes a first support 3 and a second support 6, the first support 3 has a first slit 2, the second support 6 has a second slit 8, and the first slit 2 and the second slit 8 The shape is one or a combination of strips and holes, and the widths of the first slit 2 and the second slit 8 are smaller than the diameter of the high-dielectric ceramic ball 16, which means that the high-dielectric ceramic ball 16 will not dislodge from the second slit. The first slot 2 and the second slot 8 pass through. Preferably, on the premise of meeting the requirement of support strength, the area of the gap should be increased to increase the flow rate of gas. In this embodiment, the gap accounts for 85-88% of the cross-sectional area of the support frame; a through hole is provided at the center of the support frame, and the center electrode 1 is pierced in the through hole. When the center electrode 1 adopts a 4mm copper rod structure, the diameter of the through hole 4mm is used. The first bracket 3 and the second bracket 6 are respectively used to block the two ends of the annular barrel-shaped electrode 4 and support and fix the center electrode 1 to prevent the high dielectric ceramic ball 16 from rolling out of the cavity structure.

本实施例中,环形桶状电极4、支撑架和中心电极1形成空腔结构,空腔结构内填充有高介电陶瓷球体16,高介电陶瓷球体16的介电常数大于8000,高介电陶瓷球体16的直径为1-4mm,高介电陶瓷球体16的球形度大于85%,即最小直径与最大直径的比值大于85%。高介电陶瓷球体16是介电电泳的核心结构,当填充到环形桶状电极4、第一支撑架3、第二支撑架6和中心电极1形成空腔结构后,高介电陶瓷球体16之间自然堆积而形成互通的缝隙,其缝隙尺寸可以达到毫米级,气体透过率高,对气体净化时风阻小;另外,高介电陶瓷球体16具有高的介电常数,当处于中心电极1与环形桶状电极4形成的电场时,高介电电陶瓷球体16被高度极化而使得高介电陶瓷球体16表面产生大量感应电荷,原来电场强度在陶瓷球曲面的作用下剧烈变化而在陶瓷球体之间的间隙区域形成极大的电场梯度,电场梯度增强从而增强介电电泳力,进而实现对空气中粉尘粒子的高效率捕捉。优选的,本实施例采用Y和Nb掺杂TiO2所制备的陶瓷粉体为主要原料,经过成型烧结得到本实施例所需的高介电陶瓷球体16,所得高介电陶瓷球体16在1600-3200Hz频率下的介电常数为23000-34000之间,所得高介电陶瓷球体16直径为2.3-2.5mm之间,球形度大于90%。In this embodiment, the ring-shaped barrel-shaped electrode 4, the support frame and the central electrode 1 form a cavity structure, and the cavity structure is filled with high-dielectric ceramic spheres 16. The dielectric constant of the high-dielectric ceramic sphere 16 is greater than 8000, and the high-dielectric ceramic sphere 16 The diameter of the electric ceramic sphere 16 is 1-4 mm, and the sphericity of the high dielectric ceramic sphere 16 is greater than 85%, that is, the ratio of the minimum diameter to the maximum diameter is greater than 85%. The high-dielectric ceramic sphere 16 is the core structure of dielectrophoresis. After filling the ring-shaped barrel electrode 4, the first support frame 3, the second support frame 6 and the center electrode 1 to form a cavity structure, the high-dielectric ceramic sphere 16 The intercommunication gap is formed by natural accumulation between them, the gap size can reach millimeter level, the gas permeability is high, and the wind resistance is small when purifying the gas; in addition, the high dielectric ceramic sphere 16 has a high dielectric constant, when it is in the center electrode 1 and the ring-shaped barrel-shaped electrode 4 form an electric field, the high-dielectric ceramic sphere 16 is highly polarized and a large amount of induced charges are generated on the surface of the high-dielectric ceramic sphere 16, and the original electric field intensity changes drastically under the action of the curved surface of the ceramic ball. A huge electric field gradient is formed in the gap area between the ceramic spheres, and the electric field gradient is enhanced to enhance the dielectrophoretic force, thereby achieving high-efficiency capture of dust particles in the air. Preferably, the ceramic powder prepared by Y and Nb doped TiO 2 is used as the main raw material in this embodiment, and the high dielectric ceramic sphere 16 required by this embodiment is obtained through molding and sintering, and the obtained high dielectric ceramic sphere 16 is obtained at 1600 The dielectric constant at the frequency of -3200Hz is between 23000-34000, the obtained high dielectric ceramic sphere 16 has a diameter between 2.3-2.5mm, and the sphericity is greater than 90%.

本实施例中,交流电源的一极与中心电极1相连,交流电源的另一极与环形桶状电极4相连,交流电源为正弦交流电或者脉冲式交流电。In this embodiment, one pole of the AC power is connected to the central electrode 1 , and the other pole of the AC power is connected to the ring-shaped barrel electrode 4 , and the AC power is sinusoidal or pulsed.

本实施例中介电电泳净化模块的组装步骤为:首先将第二支架6安装在环形桶状电极4的一端,然后将中心电极1插入第二支架6的通孔内,并使中心电极1两端均突出环形桶状电极4的端部,之后将第二支架6朝下使环形桶状电极4垂直固定,高介电陶瓷球体16从第一支架3的一端填入到中心电极1、环形电极和支撑架形成的空腔结构内,直至填满;之后安装第一支架3,使中心电极1穿过第一支架3的通孔,使中心电极1和环形桶状电极4的位置固定;然后在中心电极1上焊接第二接线端7,在环形桶状电极4上焊接第一接线端5;最后通过电极引线将第一接线端5和第二接线端7分别与交流电源相连。在本实施例中,为了避免触电、漏电问题,本实施例中环形桶状电极4和中心电极1突出环形电极4的部分以及电极引线焊点作绝缘处理,以保证电学安全性。The assembly steps of the dielectrophoresis purification module in this embodiment are as follows: first, the second bracket 6 is installed on one end of the annular barrel-shaped electrode 4, and then the center electrode 1 is inserted into the through hole of the second bracket 6, and the center electrode 1 is two Both ends protrude from the end of the ring-shaped barrel-shaped electrode 4, and then the second support 6 is placed downward to make the ring-shaped barrel-shaped electrode 4 vertically fixed, and the high-dielectric ceramic ball 16 is filled into the center electrode 1 and the ring-shaped electrode 1 from one end of the first support 3. In the cavity structure formed by the electrode and the support frame, until it is filled; then the first bracket 3 is installed, so that the center electrode 1 passes through the through hole of the first bracket 3, so that the positions of the center electrode 1 and the ring-shaped barrel electrode 4 are fixed; Then the second terminal 7 is welded on the central electrode 1, and the first terminal 5 is welded on the annular barrel electrode 4; finally, the first terminal 5 and the second terminal 7 are respectively connected to an AC power source through electrode leads. In this embodiment, in order to avoid electric shock and leakage problems, in this embodiment, the part of the annular barrel electrode 4 and the central electrode 1 protruding from the annular electrode 4 and the solder joints of the electrode leads are insulated to ensure electrical safety.

为了检测效果,将上述组装好的介电电泳净化模块放置于通风管中,通风管内壁与桶状电极4边缘缝隙通过胶泥填充;通风管的一侧安装鼓风机,安装鼓风机的一端为进风口,另一端为出风口,然后分别在进风口和出风口侧视粉尘粒子的含量。实验条件:交流电源的波形为正弦交流电或者脉冲式交流电,交流电源的频率为800-5000Hz,交流电源的电压为满足中心电极1与环形桶状电极4的电场强度为200-3000V/cm(即交流电源的电压U与中心电极1和环形桶状电极4之间距离d的比值为200-3000V/cm)。In order to test the effect, the above assembled dielectrophoresis purification module is placed in the ventilation pipe, and the gap between the inner wall of the ventilation pipe and the edge of the barrel electrode 4 is filled with cement; one side of the ventilation pipe is installed with a blower, and the end of the blower is the air inlet. The other end is the air outlet, and then the content of dust particles is observed at the air inlet and the air outlet respectively. Experimental conditions: the waveform of the AC power supply is sinusoidal AC or pulsed AC, the frequency of the AC power is 800-5000Hz, and the voltage of the AC power is such that the electric field strength of the center electrode 1 and the ring-shaped barrel electrode 4 is 200-3000V/cm (ie The ratio of the voltage U of the AC power supply to the distance d between the central electrode 1 and the ring-shaped barrel electrode 4 is 200-3000V/cm).

具体的,本实施例1中的交流电源的输入电压为1500V,环形桶状电极4采用内径为30mm的铜管结构,铜管结构的长度为150mm;中心电极1采用直径为4mm的实心铜棒结构,长度为180mm;支撑架采用绝缘塑料制作成瓶盖形状,内径为30mm,正好可以封盖环形桶状电极4的两端,同时支撑架底面中心打孔4mm的通孔,中心电极1正好可以穿透固定,同时底面开成阵列式开孔网状缝隙结构。在本实施例中,高介电陶瓷陶瓷的的直径为2.3-2.5mm,支撑架的开孔的缝隙最大尺寸为1.8mm。另外,为了说明环形桶状电极4的尺寸对净化效果的影响,选取了直径为60mm的铜管结构作为环形桶状电极4,以作为对比例1;相应地,对比例1采用与实施例1相同的材料及其他相对应的参数制备了配套的中心电极1和支撑架;在进行净化效果测试时,对比例1中交流电源的输入参数与实施例1相同。测试结果如表1。Specifically, the input voltage of the AC power supply in Example 1 is 1500V, and the annular barrel-shaped electrode 4 adopts a copper tube structure with an inner diameter of 30mm, and the length of the copper tube structure is 150mm; the center electrode 1 adopts a solid copper rod with a diameter of 4mm structure, the length is 180mm; the support frame is made of insulating plastic into a bottle cap shape, with an inner diameter of 30mm, which can just cover the two ends of the ring-shaped barrel-shaped electrode 4. At the same time, a 4mm through hole is punched in the center of the bottom surface of the support frame. It can be penetrated and fixed, and at the same time, the bottom surface is opened into an array-type opening mesh structure. In this embodiment, the diameter of the high-dielectric ceramic is 2.3-2.5 mm, and the maximum size of the opening gap of the support frame is 1.8 mm. In addition, in order to illustrate the impact of the size of the ring-shaped barrel-shaped electrode 4 on the purification effect, a copper tube structure with a diameter of 60 mm was selected as the ring-shaped barrel-shaped electrode 4 as Comparative Example 1; The matching central electrode 1 and supporting frame were prepared with the same materials and other corresponding parameters; when performing the purification effect test, the input parameters of the AC power supply in Comparative Example 1 were the same as those in Example 1. The test results are shown in Table 1.

表1实施例1和对比例1测试结果Table 1 embodiment 1 and comparative example 1 test result

Figure SMS_1
Figure SMS_1

由表1可以得出,实施例1对于PM2.5及更大尺寸的PM5.0的净化效果得到100%,对于更小PM0.5的净化率也在99.7%以上,由此可以说明本实施例1的技术方案可以对空气中粉尘粒子达到超净化的效果。另外,从对比例1的结果可以看出,当加大环形桶状电极4的直径尺寸到60mm时,虽然采用相同介电常数等级的高介电陶瓷球体16,但对粉尘的净化效果却显著减弱,例如,对于PM2.5粉尘的净化率仅为62.2%,而对于PM0.5更微小粉尘的净化率则更低,仅为17.4%。由实施例1和对比例1的测试结果表明,要想达到较好的净化效果,对于环形桶状电极的直径需要满足特定的尺寸要求。It can be concluded from Table 1 that the purification effect of Example 1 for PM2.5 and larger PM5.0 is 100%, and the purification rate for smaller PM0.5 is also above 99.7%, which can illustrate this implementation The technical solution of Example 1 can achieve super-purification effect on dust particles in the air. In addition, it can be seen from the results of Comparative Example 1 that when the diameter of the annular barrel-shaped electrode 4 is increased to 60mm, although the high-dielectric ceramic ball 16 of the same dielectric constant level is used, the dust purification effect is remarkable. For example, the purification rate for PM2.5 dust is only 62.2%, while the purification rate for PM0.5 finer dust is even lower, only 17.4%. The test results of Example 1 and Comparative Example 1 show that in order to achieve a better purification effect, the diameter of the ring-shaped barrel-shaped electrode needs to meet specific size requirements.

实施例2、对比例2和对比例3Embodiment 2, comparative example 2 and comparative example 3

为进一步说明本发明技术方案的有益效果,下面将结合实施例2进行说明;同时为证明本发明技术中所述高介电陶瓷球16的直径尺寸以及陶瓷球基体的介电常数在所述介电电泳电极结构净化时起到的关键作用,将结合对比例2(改变高介电陶瓷球的直径尺寸)和对比例3(改变高介电陶瓷球16的介电常数)进行说明。In order to further illustrate the beneficial effects of the technical solution of the present invention, it will be described below in conjunction with Example 2; simultaneously, in order to prove that the diameter size of the high dielectric ceramic ball 16 and the dielectric constant of the ceramic ball matrix in the technology of the present invention are within the range of the dielectric constant The key role played in the purification of the electrophoretic electrode structure will be described in conjunction with Comparative Example 2 (changing the diameter of the high dielectric ceramic ball) and Comparative Example 3 (changing the dielectric constant of the high dielectric ceramic ball 16 ).

在实施例1基础上,实施例2、对比例2和对比例3采用相同的中心电极1和环形桶状电极4尺寸,即环形桶状电极4采用内径为30mm的铜管,铜管的长度为150mm,中心电极1采用直径为4mm的实心铜棒结构,长度为180mm;支撑架采用绝缘塑料制作成瓶盖形状,内径为30mm,正好可以封盖环形铜管电极的两端,同时支撑架中缝隙占支撑架截面面积的85-88%,支撑架中心打孔4mm的通孔。On the basis of Example 1, Embodiment 2, Comparative Example 2 and Comparative Example 3 adopt the same center electrode 1 and annular barrel-shaped electrode 4 sizes, that is, the annular barrel-shaped electrode 4 adopts a copper tube with an inner diameter of 30mm, and the length of the copper tube is The center electrode 1 adopts a solid copper rod structure with a diameter of 4mm and a length of 180mm; the support frame is made of insulating plastic into a bottle cap shape with an inner diameter of 30mm, which can just cover the two ends of the ring-shaped copper tube electrode, while the support frame The middle gap accounts for 85-88% of the cross-sectional area of the support frame, and a 4mm through hole is punched in the center of the support frame.

优选的,实施例2采用纯钙铜钛氧(CaCu3Ti4O12,简记CCTO)陶瓷粉体,制备高介电陶瓷球体16,其直径尺寸为2.5-2.8mm,所得高介电陶瓷球体16基体在1000-3000Hz频率范围的介电常数为24500-27890;对比例2也采用相同CCTO陶瓷粉体制备高介电陶瓷球体16,但高介电陶瓷球体16的直径为4.8-5.0mm;对比例3采用CCTO-15%Al2O3混合粉体制备2.5-2.8mm的高介电陶瓷球体16,所得高介电陶瓷球体16在1000-3000Hz频率范围的介电常数为5500-7630。将以上三种高介电陶瓷球体16体分别装入中心电极1、环形桶状电极4和支撑架围成的空腔结构中,形成介电电泳电极结构,然后将中心电极1和环形电极接通交流电源,调节交流电源原电压为1200-1600V,频率为1300-2800Hz之间。对实施例2、对比例2和对比例3进行净化效果测试时,采用与实施例1相同的测试方法,测试结果如表2。Preferably, in Example 2, pure calcium copper titanium oxide (CaCu 3 Ti 4 O 12 , CCTO for short) ceramic powder is used to prepare high dielectric ceramic spheres 16 with a diameter of 2.5-2.8mm, and the resulting high dielectric ceramic The dielectric constant of the sphere 16 substrate in the frequency range of 1000-3000Hz is 24500-27890; Comparative Example 2 also uses the same CCTO ceramic powder to prepare the high-dielectric ceramic sphere 16, but the diameter of the high-dielectric ceramic sphere 16 is 4.8-5.0mm ; Comparative Example 3 adopts CCTO-15%Al 2 O 3 mixed powder to prepare 2.5-2.8mm high dielectric ceramic sphere 16, the dielectric constant of the gained high dielectric ceramic sphere 16 in the frequency range of 1000-3000Hz is 5500-7630 . Put the above three kinds of high dielectric ceramic spheres 16 into the cavity structure surrounded by the center electrode 1, the ring-shaped barrel electrode 4 and the support frame respectively to form a dielectrophoretic electrode structure, and then connect the center electrode 1 and the ring electrode Through the AC power supply, the original voltage of the AC power supply is adjusted to 1200-1600V, and the frequency is between 1300-2800Hz. When carrying out purification effect test to embodiment 2, comparative example 2 and comparative example 3, adopt the same test method as embodiment 1, test result is shown in table 2.

表2实施例2、对比例2和对比例3测试结果Table 2 embodiment 2, comparative example 2 and comparative example 3 test results

Figure SMS_2
Figure SMS_2

表2结果可知,实施例2中,当高介电陶瓷球体16的采用尺寸为2.5-2.8mm,介电常数为24500-27890时,净化效果显著,对于PM2.5的净化率可以达到100%;而在对比例2中,当高介电陶瓷球体16的尺寸较大时(4.8-5.0mm),净化效果不理想,对PM2.5的净化率为78.6%;另外,从对比例3可知,高介电陶瓷球体16的介电常数较小为5500-7630时,虽然陶瓷球16的直径与实施例2相同,但其对粉尘净化率明显变差,如对于PM2.5的净化率仅为62.2%,对于PM0.5和PM1.0的净化率则更低,仅为21.4%和31.6%。由此,综合实施例2和对比例2的结果可以证明,当高介电陶瓷球16具有较高的介常数(24500-27890之间),高介电陶瓷球16尺寸是影响净化率的重要因素;另外,综合实施例2和对比例3的测试结果可知,当高介电陶瓷球采用合适的直径尺寸时,其陶瓷球基体的介电常数对净化率的影响也是非常重要。从本发明技术方案中实现有益效果的原理可知,高介电陶瓷球16基体的介电常数越高,高介电陶瓷球16在电场中的极化强度就越高,陶瓷球之间的间隙区域所对应的电场梯度就越强,从而提高粉尘所受的介电电泳力而增强净化效果。因此,为达到优质的净化效果,高介电陶瓷球16的介电常数需要达到一定的数值。It can be seen from the results in Table 2 that in Example 2, when the high dielectric ceramic sphere 16 has a size of 2.5-2.8mm and a dielectric constant of 24500-27890, the purification effect is remarkable, and the purification rate for PM2.5 can reach 100%. and in Comparative Example 2, when the size of the high dielectric ceramic sphere 16 was larger (4.8-5.0mm), the purification effect was not ideal, and the purification rate to PM2.5 was 78.6%; in addition, from Comparative Example 3, it can be seen that , when the dielectric constant of the high-dielectric ceramic ball 16 is less than 5500-7630, although the diameter of the ceramic ball 16 is the same as that of Example 2, it obviously deteriorates the dust purification rate, as the purification rate for PM2.5 is only The purification rate for PM0.5 and PM1.0 is even lower, only 21.4% and 31.6%. Thus, the comprehensive results of Example 2 and Comparative Example 2 can prove that when the high dielectric ceramic ball 16 has a higher dielectric constant (between 24500-27890), the size of the high dielectric ceramic ball 16 is an important factor affecting the purification rate. In addition, the comprehensive test results of Example 2 and Comparative Example 3 show that when the high dielectric ceramic ball adopts a suitable diameter size, the dielectric constant of the ceramic ball matrix is also very important to the purification rate. From the principle of realizing the beneficial effect in the technical scheme of the present invention, it can be seen that the higher the dielectric constant of the high dielectric ceramic ball 16 substrate, the higher the polarization intensity of the high dielectric ceramic ball 16 in the electric field, and the gap between the ceramic balls The stronger the electric field gradient corresponding to the area, the stronger the dielectrophoretic force on the dust and enhance the purification effect. Therefore, in order to achieve a high-quality purification effect, the dielectric constant of the high-dielectric ceramic ball 16 needs to reach a certain value.

实施例3Example 3

根据本发明的内容,还提供另一种基于高介电材料的介电电泳气体净化单元模块,下面将结合实施例3进行说明。According to the content of the present invention, another dielectrophoretic gas purification unit module based on high dielectric material is also provided, which will be described in conjunction with Embodiment 3 below.

参照图8-图12,本实施例3中,一种基于高介电材料的介电电泳气体净化单元模块,还包括连接板9,连接板9上设置若干个介电电泳电极结构。本实施例中,采用四个介电电泳电极结构,但不限于四个,分别为第一结构体10、第二结构体11、第三结构体12和第四结构体13。每个介电电泳电极结构的中心电极1分别与交流电源的一极相连,每个介电电泳电极结构的环形桶状电极4分别与交流电源的另一极相连。连接板9上设有若干安装槽15,通过安装槽15内固定安装介电电泳电极结构,其中连接板9上还设有槽孔,槽孔内设有橡胶塞14,橡胶塞14中可穿设连接引线,若干个介电电泳电极结构并联形成气体净化模块,即多个介电电泳电极结构安装在一个连接板9上形成一个模块,交流电源的两极分别与每个介电电泳的中心电极1与环形桶状电极4连接。为检测实施例3中介电电泳气体净化单元模块的净化效果,采用与实施例1和实施例2相同的方法,将所述介电电泳气体净化单元模块放置于管道中,通过风机实现气体的流通,调节交流电源的频率为800-4800Hz,电压为200-2800V,然后分别测试进气口和出气口的粒子含量并计算净化率。检测结果为:PM0.5和PM1.0的净化率为92.4%-99.7%之间;PM2.5的净化为99.9-100%。Referring to Fig. 8-Fig. 12, in this embodiment 3, a dielectrophoretic gas purification unit module based on a high dielectric material further includes a connecting plate 9 on which several dielectrophoretic electrode structures are arranged. In this embodiment, four DEP electrode structures are used, but not limited to four, which are the first structure body 10 , the second structure body 11 , the third structure body 12 and the fourth structure body 13 . The central electrode 1 of each DEP electrode structure is respectively connected to one pole of the AC power supply, and the annular barrel-shaped electrode 4 of each DEP electrode structure is respectively connected to the other pole of the AC power supply. The connecting plate 9 is provided with a number of mounting grooves 15, through which the dielectrophoretic electrode structure is fixedly installed in the mounting grooves 15, wherein the connecting plate 9 is also provided with a slot, and a rubber plug 14 is arranged in the slot, and the rubber plug 14 can be worn Connecting leads are set, and several DEP electrode structures are connected in parallel to form a gas purification module, that is, a plurality of DEP electrode structures are installed on a connecting plate 9 to form a module, and the two poles of the AC power supply are respectively connected to the center electrode of each DEP. 1 is connected to the ring-shaped barrel electrode 4. In order to detect the purification effect of the dielectrophoresis gas purification unit module in Example 3, the same method as in Example 1 and Example 2 is adopted, the dielectrophoresis gas purification unit module is placed in the pipeline, and the gas circulation is realized by a fan , adjust the frequency of the AC power supply to 800-4800Hz, and the voltage to 200-2800V, then test the particle content of the air inlet and air outlet respectively and calculate the purification rate. The test results are: the purification rate of PM0.5 and PM1.0 is between 92.4%-99.7%; the purification rate of PM2.5 is 99.9-100%.

从以上描述中,可以看出,本发明上述的实施例实现了如下技术效果:From the above description, it can be seen that the above-mentioned embodiments of the present invention have achieved the following technical effects:

高介电陶瓷球体16、中心电极1和环形桶状电极4、支撑架结构简单、稳定,易于工业化批量生产;The high dielectric ceramic sphere 16, the central electrode 1, the ring-shaped barrel electrode 4, and the support frame have a simple and stable structure, and are easy to industrialized mass production;

高介电陶瓷球体16填充在中心电极1与环形桶状电极4之间,填充装配时易于操作;当需要对各部件清洗时,可以将高介电陶瓷球体16取出进行清洗后再进行填充,不存在耗材的浪费;The high dielectric ceramic sphere 16 is filled between the center electrode 1 and the ring-shaped barrel electrode 4, which is easy to operate during filling and assembly; when it is necessary to clean each part, the high dielectric ceramic sphere 16 can be taken out for cleaning and then filled. There is no waste of consumables;

高介电陶瓷球体16性能稳定,高介电陶瓷球体16可以重复使用,且高介电陶瓷球体16耐高温,可以在高温下进行气体净化使用;The performance of the high-dielectric ceramic sphere 16 is stable, the high-dielectric ceramic sphere 16 can be reused, and the high-dielectric ceramic sphere 16 is resistant to high temperature, and can be used for gas purification at high temperature;

空气粉尘净化效果好,对PM2.5的净化率可以达到100%;The air dust purification effect is good, and the purification rate of PM2.5 can reach 100%;

净化单元中,高介电陶瓷球体16相互堆积而自然形成缝隙,缝隙尺寸为0.5-1.5mm之间,其缝隙尺寸远远大于过滤网的缝隙尺寸,因此当对空气进行粉尘净化时,可以减小风阻,一方面可以减小风机的功率,从而减小净化器的噪音;另一方面可以加大通风量,而增大净化效率。In the purification unit, the high-dielectric ceramic spheres 16 are piled up to form a gap naturally. The gap size is between 0.5-1.5mm, and the gap size is much larger than the filter screen. Small wind resistance, on the one hand, can reduce the power of the fan, thereby reducing the noise of the purifier; on the other hand, it can increase the ventilation volume, and increase the purification efficiency.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.

Claims (10)

1.一种基于高介电材料的介电电泳气体净化单元模块,其特征在于,包括:1. A dielectrophoretic gas purification unit module based on high dielectric material, characterized in that, comprising: 介电电泳电极结构,所述介电电泳电极结构包括环形桶状电极,所述环形桶状电极轴线位置设有中心电极,所述环形桶状电极两端设有支撑架,所述中心电极通过支撑架与环形桶状电极相连固定,所述环形桶状电极、支撑架和中心电极形成空腔结构,所述空腔结构内填充有高介电陶瓷球体;Dielectrophoretic electrode structure, the dielectrophoretic electrode structure includes a ring-shaped barrel electrode, a center electrode is provided at the axial position of the ring-shaped barrel-shaped electrode, support frames are provided at both ends of the ring-shaped barrel-shaped electrode, and the center electrode passes through The support frame is connected and fixed with the annular barrel-shaped electrode, and the annular barrel-shaped electrode, the support frame and the central electrode form a cavity structure, and the cavity structure is filled with high-dielectric ceramic spheres; 交流电源,所述交流电源的一极与中心电极相连,所述交流电源的另一极与环形桶状电极相连;An AC power supply, one pole of the AC power supply is connected to the center electrode, and the other pole of the AC power supply is connected to the ring-shaped barrel electrode; 所述环形桶状电极的内环直径为10-50mm;The diameter of the inner ring of the annular barrel-shaped electrode is 10-50mm; 所述高介电陶瓷球体的介电常数为23000-34000,直径为2.3-2.8mm;The dielectric constant of the high dielectric ceramic sphere is 23000-34000, and the diameter is 2.3-2.8mm; 所述交流电源的频率为800-5000Hz,交流电源的电压满足中心电极和环形桶状电极之间的电场强度为200-3000V/cm。The frequency of the AC power supply is 800-5000 Hz, and the voltage of the AC power supply satisfies that the electric field strength between the central electrode and the ring-shaped barrel electrode is 200-3000 V/cm. 2.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述支撑架采用绝缘材质,所述支撑架包括第一支架和第二支架,所述第一支架上具有第一缝隙,所述第二支架上具有第二缝隙,所述第一缝隙和第二缝隙的宽度均小于高介电陶瓷球体的直径。2. the dielectrophoretic gas purification unit module based on high dielectric material as claimed in claim 1, is characterized in that, described support frame adopts insulating material, and described support frame comprises a first support and a second support, and described The first bracket has a first gap, and the second bracket has a second gap, and the widths of the first gap and the second gap are both smaller than the diameter of the high dielectric ceramic sphere. 3.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述环形桶状电极采用金属管结构,所述中心电极采用实心金属棒结构。3 . The dielectrophoretic gas purification unit module based on high dielectric material according to claim 1 , wherein the annular barrel-shaped electrode adopts a metal tube structure, and the central electrode adopts a solid metal rod structure. 4 . 4.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,还包括连接板,所述连接板上设置若干个介电电泳电极结构,每个介电电泳电极结构的中心电极分别与交流电源的一极相连,每个介电电泳电极结构的环形桶状电极分别与交流电源的另一极相连。4. the dielectrophoretic gas purification unit module based on high dielectric material as claimed in claim 1, is characterized in that, also comprises connecting plate, and described connecting plate is provided with several dielectrophoretic electrode structures, each dielectric The central electrode of the electrophoretic electrode structure is respectively connected to one pole of the AC power supply, and the annular barrel-shaped electrode of each DEP electrode structure is respectively connected to the other pole of the AC power supply. 5.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述支撑架中心位置设有通孔,所述通孔中穿设中心电极。5 . The dielectrophoretic gas purification unit module based on high dielectric material according to claim 1 , wherein a through hole is provided at the center of the support frame, and a central electrode is penetrated in the through hole. 6 . 6.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述环形桶状电极上焊接有第一接线端,所述中心电极上焊接有第二接线端,所述第一接线端和第二接线端分别通过电极引线与交流电源相连。6. The dielectrophoretic gas purification unit module based on high dielectric material as claimed in claim 1, wherein a first terminal is welded on the annular barrel electrode, and a second terminal is welded on the central electrode. A connection terminal, the first connection terminal and the second connection terminal are respectively connected to an AC power supply through electrode leads. 7.如权利要求1所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述交流电源为正弦交流电或者脉冲式交流电。7 . The dielectrophoretic gas purification unit module based on high dielectric material according to claim 1 , wherein the AC power supply is sinusoidal AC or pulsed AC. 8 . 8.如权利要求4所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述连接板上设有若干安装槽,所述安装槽内固定安装介电电泳电极结构。8. the dielectrophoresis gas purification unit module based on high dielectric material as claimed in claim 4, is characterized in that, described connecting plate is provided with some installation grooves, and the dielectrophoresis electrode structure is fixedly installed in the described installation grooves . 9.如权利要求4所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,所述连接板上设有槽孔,所述槽孔内设有橡胶塞,所述橡胶塞中穿设连接引线。9. The dielectrophoretic gas purification unit module based on high dielectric material as claimed in claim 4, wherein a slot is provided on the connecting plate, a rubber plug is provided in the slot, and the rubber Connecting lead wires are passed through the plug. 10.一种基于高介电材料的介电电泳气体净化方法,基于权利要求1-9任意一项所述的基于高介电材料的介电电泳气体净化单元模块,其特征在于,包括:10. A dielectrophoretic gas purification method based on a high dielectric material, based on the dielectrophoretic gas purification unit module based on a high dielectric material according to any one of claims 1-9, characterized in that it comprises: 将交流电源的两极分别与中心电极和环形桶状电极连接,在中心电极与环形桶状电极之间产生非均匀的电场,填充在中心电极与环形桶状电极之间的具有高介电常数的高介电陶瓷球体被高度极化,高介电陶瓷球体表面产生大量感应电荷,中心电极与环形桶状电极之间的电场在高介电陶瓷球体曲面结构的作用下剧烈变化而使得高介电陶瓷球之间的间隙区域形成极大的电场梯度,增强粉尘粒子受到介电电泳力,粉尘粒子在介电电泳力的作用下向高介电陶瓷球运动并被吸附在高介电陶瓷球的表面实现对空气中粉尘粒子高效捕捉。Connect the two poles of the AC power supply to the center electrode and the ring-shaped barrel electrode respectively, generate a non-uniform electric field between the center electrode and the ring-shaped barrel electrode, and fill the gap between the center electrode and the ring-shaped barrel electrode with a high dielectric constant. The high-dielectric ceramic sphere is highly polarized, and a large amount of induced charges are generated on the surface of the high-dielectric ceramic sphere. The gap area between the ceramic balls forms a huge electric field gradient, which enhances the dielectrophoretic force on the dust particles. Under the action of the dielectrophoretic force, the dust particles move towards the high dielectric ceramic ball and are adsorbed on the The surface achieves efficient capture of dust particles in the air.
CN202310683701.9A 2023-06-09 2023-06-09 Dielectrophoresis gas purification unit module and method based on high dielectric material Active CN116392964B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310683701.9A CN116392964B (en) 2023-06-09 2023-06-09 Dielectrophoresis gas purification unit module and method based on high dielectric material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310683701.9A CN116392964B (en) 2023-06-09 2023-06-09 Dielectrophoresis gas purification unit module and method based on high dielectric material

Publications (2)

Publication Number Publication Date
CN116392964A true CN116392964A (en) 2023-07-07
CN116392964B CN116392964B (en) 2023-08-25

Family

ID=87010970

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310683701.9A Active CN116392964B (en) 2023-06-09 2023-06-09 Dielectrophoresis gas purification unit module and method based on high dielectric material

Country Status (1)

Country Link
CN (1) CN116392964B (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030010637A1 (en) * 2001-06-20 2003-01-16 Cummings Eric B. Continuous flow dielectrophoretic particle concentrator
JP2003260329A (en) * 2002-03-11 2003-09-16 Sharp Corp Radical generating device, substance removing device, and air cleaning device
US20040211669A1 (en) * 2001-06-20 2004-10-28 Cummings Eric B. Dielectrophoresis device and method having non-uniform arrays for manipulating particles
DE102006023069A1 (en) * 2006-05-17 2007-11-22 Johannes Dipl.-Ing. Schedler Non-thermal plasma reactor for cleaning air-borne pollutants, uses bulk material for filling reactor and consisting of dense, non-pours, and/or hydrophobic porous material
CN101239278A (en) * 2008-03-07 2008-08-13 黄立维 Device for cleaning treatment harmful gas and technique thereof
CN104174497A (en) * 2014-08-22 2014-12-03 成都代代吉前瞻科技股份有限公司 High-efficiency dielectrophoresis dust removal unit
CN204933257U (en) * 2015-07-01 2016-01-06 王冰 For separating of dielectrophoresis electrode and the electrod-array of medium endoparticle and droplet
CN107309089A (en) * 2017-07-27 2017-11-03 重庆科技学院 Using the purifier of electrostatic removing impurities
CN206965932U (en) * 2017-07-27 2018-02-06 重庆科技学院 Electrostatic filter with filler particles

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030010637A1 (en) * 2001-06-20 2003-01-16 Cummings Eric B. Continuous flow dielectrophoretic particle concentrator
US20040211669A1 (en) * 2001-06-20 2004-10-28 Cummings Eric B. Dielectrophoresis device and method having non-uniform arrays for manipulating particles
JP2003260329A (en) * 2002-03-11 2003-09-16 Sharp Corp Radical generating device, substance removing device, and air cleaning device
DE102006023069A1 (en) * 2006-05-17 2007-11-22 Johannes Dipl.-Ing. Schedler Non-thermal plasma reactor for cleaning air-borne pollutants, uses bulk material for filling reactor and consisting of dense, non-pours, and/or hydrophobic porous material
CN101239278A (en) * 2008-03-07 2008-08-13 黄立维 Device for cleaning treatment harmful gas and technique thereof
CN104174497A (en) * 2014-08-22 2014-12-03 成都代代吉前瞻科技股份有限公司 High-efficiency dielectrophoresis dust removal unit
CN204933257U (en) * 2015-07-01 2016-01-06 王冰 For separating of dielectrophoresis electrode and the electrod-array of medium endoparticle and droplet
CN107309089A (en) * 2017-07-27 2017-11-03 重庆科技学院 Using the purifier of electrostatic removing impurities
CN206965932U (en) * 2017-07-27 2018-02-06 重庆科技学院 Electrostatic filter with filler particles

Also Published As

Publication number Publication date
CN116392964B (en) 2023-08-25

Similar Documents

Publication Publication Date Title
CN103084036B (en) Electrostatic reinforcing bag type dust collector with reverse electric field
CN104998502A (en) Fine particle purifying equipment
CN105817331A (en) Columnar two-section device for collecting dust through electrostatic adsorption
CN221780837U (en) A new type of air conditioning box purifier and combined air conditioning unit
CN108607688A (en) A kind of fresh air purification device in electrode
CN206474284U (en) A kind of device that electrostatic precipitation is carried out using temperature difference electricity generation device
CN204933696U (en) A kind of composite static electric cleaner
CN105107630A (en) Electrostatic precipitator
CN116392964B (en) Dielectrophoresis gas purification unit module and method based on high dielectric material
CN207204383U (en) Air cleaning facility
CN105546657A (en) Air filter and applicable air cleaning device
CN203140156U (en) Reverse-electric-field electric bag dust remover
CN105327578A (en) Dusty gas purifying method
CN106975351A (en) A kind of air cleaning unit based on electrostatic precipitator technology and photocatalysis technology
CN204911784U (en) Field restraint dust remover
CN105727670A (en) Air filtering method
CN103817004A (en) High gas speed and high efficiency wet-type electrofiltration device for deep treatment of PM2.5
CN204380852U (en) A kind of dust arrester
CN2728627Y (en) Wire purifier
CN203886382U (en) Direct-current high-voltage bipolar electrostatic actuation bag type dust remover
CN116272211B (en) Dielectrophoresis electrode structure, preparation method and gas purification device
CN108465558A (en) A kind of compound dust-collection device based on solar power generation
CN209715413U (en) The tension device of wet electrical dust precipitator discharge electrode lower suspension anti-rock stabilising arrangement
CN205949069U (en) Two segmentation electrostatic absorption dust collecting device of column
CN205701028U (en) A kind of Household Air Purifier using column dielectrophoresis electrode

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CB03 Change of inventor or designer information

Inventor after: Li Wang

Inventor after: Zhang Xing

Inventor after: Li Zhixin

Inventor after: Yan Junliang

Inventor after: Guo Hao

Inventor after: Chen Zhiguo

Inventor after: Xu Shu

Inventor after: Wang Chunhui

Inventor before: Li Wang

Inventor before: Zhang Xing

Inventor before: Li Zhixin

Inventor before: Yang Mingchao

Inventor before: Ma Deqiang

CB03 Change of inventor or designer information
TR01 Transfer of patent right

Effective date of registration: 20240205

Address after: 066000 No. 2, Zushan Road, Qinhuangdao Economic and Technological Development Zone, Hebei Province

Patentee after: YUANKE QINHUANGDAO ENERGY SAVING AND ENVIRONMENTAL PROTECTION TECHNOLOGY DEVELOPMENT Co.,Ltd.

Country or region after: China

Address before: 066099 No. 360, west section of Hebei Street, Haigang District, Qinhuangdao City, Hebei Province

Patentee before: HEBEI NORMAL University OF SCIENCE & TECHNOLOGY

Country or region before: China

TR01 Transfer of patent right