CN1163808A - Method for making sintered alloy balls - Google Patents
Method for making sintered alloy balls Download PDFInfo
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- CN1163808A CN1163808A CN 97100450 CN97100450A CN1163808A CN 1163808 A CN1163808 A CN 1163808A CN 97100450 CN97100450 CN 97100450 CN 97100450 A CN97100450 A CN 97100450A CN 1163808 A CN1163808 A CN 1163808A
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Abstract
A method for manufacturing spherical alloy products with metal powder features use of elastic soft ball mould, and includes such technological steps as loading raw material in ball mould by mechanical vibration, isostatic pressing compaction in cold isostatic press, sinter, treating in hot isostatic press, and grinding. its advantages are high productivity and high density and quality of spherical alloy products.
Description
The invention belongs to the method field of making workpiece or goods by metal dust.Mainly be applicable to and make spherical alloy product.
Produce spherical alloy product with powder metallurgy process, its traditional technology is: use hydraulic press or punching machine punching block to be shaped, powder is compacting balling-up base in the ball mould, places the sintering furnace sintering to make spherical artefact the ball base then.Its ball mould normally adopts two hemisphere punching blocks, and sintering also is to carry out " CEMENTED CARBIDE PRODUCTION principle " in the ordinary sinter stove, and Wang Guodong is compiled, metallurgical industry publishing house, in February, 1988, P167～170).Adopting this technology to prepare alloying pellet has the following disadvantages: (1) forming efficiency is low; (2) the ball base behind the two half steel ball contour formings of employing all has protruding endless belt in the middle of it, causes difficulty for fine finishining subsequently; (3) formed thereby ball base density is little, and density unevenness is even.This be because ball mould die wall to due to the frictional resistance of powder, the powder material is when compression aspect moves, pressure constantly incurs loss, and makes that the density of ball base core is minimum; (4) owing to punching block is shaped, thus need to add forming agent, and binder volatilization when sintering, the ball base ftractures easily, and remaining binder can make dirtyization of ball base alloy directly influence the performance of alloying pellet.
The object of the present invention is to provide the not manufacture method of the little and sintered alloy balls that purity is high, performance is good of garden degree of high, the prepared alloying pellet of a kind of production efficiency.
At above-mentioned purpose, the main technical schemes that the present invention adopts: adopt elasticity soft mode and mechanical shaker material charging forming ball base, and on cold isostatic press compacting ball base, carry out sintering (H2 or vacuum-sintering all can) then.Again the ball base is carried out hip treatment according to difference use, performance requirement.
Its concrete technological process is:
The preparation of the soft ball mould of elasticity---mechanical oscillation charging---cold isostatic compaction---corase grind---sintering---hip treatment---finishing.Existing division is as follows:
(1) preparation of the soft ball mould of elasticity
With the polyethylene slip is raw material, is core with the iron ring and the stainless steel ball of suitable size, castable, and the soft ball mould of elasticity is then made in the demoulding after plastifying.The diameter of stainless steel ball is decided according to the big small computer of the finished product alloying pellet of required preparation, and plasticizing process is (150～200 ℃) * (0.5～1 hour).The soft ball mould of the elasticity of institute's castable, each has 30～100 spherical die cavitys (how much quantity decides on ball base size) above the ball mould, spherical die cavity be equidistant one enclose regularly arranged, made soft ball mould softness and have elasticity, the charging door that is used to feed is all left on each top, ball chamber.
(2) dress powder
Get the soft ball mould of a plurality of elasticity, and respectively with there being the metal system garden tube of certain luminosity to fix, then at the upper space of the soft ball mould alloy powder of packing into, each soft ball mould is placed respectively on each garden tube of vibration charger, open vibroswitch, alloy powder can enter in each ball chamber of soft ball mould automatically, treat that powder is full of the ball chamber after, stop vibration, unload the ball mould and charging door is sealed.
(3) compacting of ball mould is shaped
The soft ball mould of the elasticity that is full of powder stock is placed the cold isostatic press compacting of pressurizeing, and moulding pressure is 147～196MPa.The elasticity soft mode is taken out in release after the compacting, the ball base of compacting is deviate from the ball base that obtains suppressing from mould.
(4) sintering
Place hydrogen sintering furnace to carry out sintering the ball base after the demoulding.Its sintering process parameter is 1400～1550 ℃ * 1～1.5nr (the ball base goods on the different sizes of different components is decided).
(5) hip treatment
For eliminating the residual porosity in the sintered alloy ball base, improve the fineness and the material capability of alloying pellet product, place hot isostatic press to handle the alloying pellet base behind the sintering.Hip temperature is 1350～1400 ℃, and transmission medium is a high-purity argon gas, pressure＞98MPa, and the heat-insulation pressure keeping time is 1～1.5nr.With this understanding, can obtain fine and close fully ball base.
(6) finishing
With the alloying pellet behind the sintering grind, finishing, obtain final alloying pellet goods.
Adopt method of the present invention, can prepare various unlike materials, the alloying pellet of different sizes and different purposes, as super-pressure ball valve ball, penetrator etc., and alloying pellet density height, ball matter performance is good, with the sintered carbide ball after the hip treatment is example, can reach V13 through lapped face fineness, the true garden of finished ball degree＜1 μ m.
Compare with traditional powder metallurgy ball making process technology, the present invention has following advantage:
(1) the garden degree is not little to press shape ball base, not garden degree＜5.0%.Be true garden degree height, the ball base is the protruding endless belt as punching block is shaped not, and processing capacity is little during finishing.
(2) the alloying pellet base density height of soft ball mould cold isostatic compaction, and evenly, defectives such as goods flawless, yield rate height.
(3) adopt the charging of vibration charger once can adorn hundreds of, thousands of ball bases, just can finish charging, the production efficiency height in 10 minutes.
(4) adopt cold isostatic compaction, do not need binder such as paraffin, rubber etc., do not come unstuck so the ball base after being shaped need not dewax, can once sintered one-tenth goods, and reduced the possibility of dirtyization of alloy, make alloying pellet protect good purity and performance.
Embodiment
Adopt method of the present invention to prepare three batches of alloying pellets, the alloy composition of three batches of alloying pellets, powder size and desired final finished ball size are as shown in table 1.At first calculate and prepare three batches of soft ball moulds of elasticity that the empty ball of suitable dimension chamber is arranged according to the diameter of goods ball, the ball mould is assemblied in batches on the garden tube of vibration charger, the alloy powder raw material that mixes is placed on the soft mode, and seal, vibration makes powder be full of ball mould cavity then, then take out the ball mould and the sealing that install powder stock and place the cold isostatic press compacting, sintering is carried out in the demoulding again after the compacting, and finishing becomes goods.Isostatic cool pressing pressure and sintering process parameter are as shown in table 2 during compacting.Before sintering, from each batch alloying pellet base optional 30, survey the substance, diameter of its ball and not its result of garden degree list table 3 in, behind the sintering, the ball base has also carried out hip treatment, its parameter has been listed table 2 in.Finished ball is carried out its result of density measure listed table 3 in.
The desired diameter of composition, powder size and goods of table 1 embodiment alloying pellet
| Lot number | Alloying pellet chemical composition (weight %) | Powder size FSSS μ m | Finished ball intended diameter mm |
| ????1 | ?WC?92％?Co?8％ | ????3-4 | ????18 |
| ????2 | ?WC?94％?Co?6％ | ????1-2 | ????5.0 |
| ????3 | ?W95?Ni3.5?Fe1.5 | ????3.5-?4 | ????7.0 |
Table 2 embodiment elasticity soft mode ball chamber diameter, hot and cold isostatic pressing forming parameter
| Lot number | Ball chamber diameter mm | The isostatic cool pressing compacting | Sintering | Hip treatment | ||
| Pressure MPa | Time (branch) | Temperature (℃) | Pressure MPa | Temperature and time ℃ * minute | ||
| ??1 | ??28.0 | ??147～196 | ????60 | ??1400 | ?＞98 | ??1350×90 |
| ??2 | ??9.5 | ??147～196 | ????60 | ??1400 | ?＞98 | ??1350×90 |
| ??3 | ??10.5 | ??196 | ????120 | ??1500 | ?/ | ???/ |
The physical property and the purposes of table 3 embodiment compacting ball base and finished ball
| Lot number | Compacting ball base | Finished ball | |||
| Substance g | Diameter mm | Out-of-roundness % | Density g/cm 3 | Purposes | |
| ????1 | ?54.0～56.5 | ?22.2～23.3 | ????＜1.9 | ??14.8 | The ball mill mixing ball |
| ????2 | ?1.87～1.89 | ?7.3～7.9 | ????＜1.8 | ??15.0 | The septum valve spool |
| ????3 | ?3.4～3.6 | ?8.2～8.6 | ????＜2.0 | ??17.8 | The military project ball |
Claims (2)
1, a kind of manufacture method of sintered alloy balls.Earlier powder is packed in the ball mold, and compacting balling-up base, then the ball base is carried out sintering, last ground finished becomes goods, it is characterized in that:
(1) the ball mold is the soft ball mould of elasticity, is raw material with the polyethylene slip promptly, is core with the iron ring and the stainless steel ball of suitable size, castable, and the soft ball mould of elasticity is then made in the demoulding after plastifying;
(2) adopt the mechanical shaker alloy powder of packing in the soft ball mould of elasticity;
(3) will fill the soft ball mould sealing of the elasticity of full powder material after, place the cold isostatic press compacting of pressurizeing, moulding pressure is 147～196MPa;
(4) place sintering furnace to carry out sintering the alloying pellet base after the demoulding, sintering temperature is 1400～1500 ℃, as when requiring to provide complete fine and close alloying pellet, can pass through hip treatment, pressure＞the 98MPa of high temperature insostatic pressing (HIP), temperature is 1350～1400 ℃, the heat-insulation pressure keeping time is 1～1.5nr.
2, method according to claim 1 is characterized in that having on each ball mould 30～100 spherical die cavitys.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100450A CN1061580C (en) | 1997-02-04 | 1997-02-04 | Method for making sintered alloy balls |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100450A CN1061580C (en) | 1997-02-04 | 1997-02-04 | Method for making sintered alloy balls |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1163808A true CN1163808A (en) | 1997-11-05 |
| CN1061580C CN1061580C (en) | 2001-02-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97100450A Expired - Fee Related CN1061580C (en) | 1997-02-04 | 1997-02-04 | Method for making sintered alloy balls |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1061580C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100387381C (en) * | 2003-07-23 | 2008-05-14 | 上海材料研究所 | Method for producing spheroid by powder stock |
| CN101491832B (en) * | 2008-01-22 | 2010-09-01 | 上海中洲特种合金材料有限公司 | Method for coating cobalt-chromium-tungsten alloy on general steel ball surface |
| CN101817080A (en) * | 2010-04-06 | 2010-09-01 | 四川科力特硬质合金股份有限公司 | Method for manufacturing hard alloy ball |
| CN102271841A (en) * | 2009-01-12 | 2011-12-07 | 米泰克粉末金属股份公司 | Method for the manufacture of a metal part |
| CN103056360A (en) * | 2012-12-29 | 2013-04-24 | 东北大学 | High-performance metal powder forming method |
| CN103495728A (en) * | 2013-10-14 | 2014-01-08 | 自贡长城硬面材料有限公司 | Pressing method of hard alloy balls |
| CN105880605A (en) * | 2016-05-16 | 2016-08-24 | 四川欧曼机械有限公司 | Production process for large-sized hard alloy valve ball with diameter larger than 80mm |
| CN107379216A (en) * | 2017-06-19 | 2017-11-24 | 宁波百诺肯轴承有限公司 | Automobile bearing manufacturing equipment |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4771665A (en) * | 1987-08-28 | 1988-09-20 | Lummus Industries, Inc. | Blade quality monitor |
| CN1033543A (en) * | 1987-12-16 | 1989-06-28 | 中国科学院三环新材料研究开发公司 | Quasi-isostatic pressure method for pressing nd-fe-b magnet |
| CN1050694A (en) * | 1988-12-20 | 1991-04-17 | 苏联科学院宏观动力学结构研究所 | The manufacture method of powdered material goods and equipment used |
| CN1032194C (en) * | 1989-12-26 | 1996-07-03 | 东芝株式会社 | Process for making composite materials, and heat-receiving materials and making method therefor |
-
1997
- 1997-02-04 CN CN97100450A patent/CN1061580C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100387381C (en) * | 2003-07-23 | 2008-05-14 | 上海材料研究所 | Method for producing spheroid by powder stock |
| CN101491832B (en) * | 2008-01-22 | 2010-09-01 | 上海中洲特种合金材料有限公司 | Method for coating cobalt-chromium-tungsten alloy on general steel ball surface |
| CN102271841A (en) * | 2009-01-12 | 2011-12-07 | 米泰克粉末金属股份公司 | Method for the manufacture of a metal part |
| CN102271841B (en) * | 2009-01-12 | 2013-10-16 | 米泰克粉末金属股份公司 | Method for the manufacture of a metal part |
| CN101817080A (en) * | 2010-04-06 | 2010-09-01 | 四川科力特硬质合金股份有限公司 | Method for manufacturing hard alloy ball |
| CN101817080B (en) * | 2010-04-06 | 2012-05-09 | 四川科力特硬质合金股份有限公司 | Method for manufacturing hard alloy ball |
| CN103056360A (en) * | 2012-12-29 | 2013-04-24 | 东北大学 | High-performance metal powder forming method |
| CN103056360B (en) * | 2012-12-29 | 2015-09-09 | 东北大学 | High-performance metal powder forming method |
| CN103495728A (en) * | 2013-10-14 | 2014-01-08 | 自贡长城硬面材料有限公司 | Pressing method of hard alloy balls |
| CN105880605A (en) * | 2016-05-16 | 2016-08-24 | 四川欧曼机械有限公司 | Production process for large-sized hard alloy valve ball with diameter larger than 80mm |
| CN107379216A (en) * | 2017-06-19 | 2017-11-24 | 宁波百诺肯轴承有限公司 | Automobile bearing manufacturing equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1061580C (en) | 2001-02-07 |
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Owner name: ANTAI SCIENCE AND TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: GENERAL RESEARCH INST. OF IRON AND STEEL, MINISTRY OF METALLURGICAL INDUSTRY Effective date: 20070914 |
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Effective date of registration: 20070914 Address after: 100081 No. 76 South College Road, Beijing Patentee after: Antai Science and Technology Co., Ltd. Address before: 100081 No. 76 South College Road, Beijing Patentee before: Iron and Steel Central Research Institute of Ministry of Metallurgical Industry |
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