CN116269017A - Pocket konjak polysaccharide face towel and preparation method thereof - Google Patents
Pocket konjak polysaccharide face towel and preparation method thereof Download PDFInfo
- Publication number
- CN116269017A CN116269017A CN202310079651.3A CN202310079651A CN116269017A CN 116269017 A CN116269017 A CN 116269017A CN 202310079651 A CN202310079651 A CN 202310079651A CN 116269017 A CN116269017 A CN 116269017A
- Authority
- CN
- China
- Prior art keywords
- konjak
- polysaccharide
- towel
- konjak polysaccharide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002752 Konjac Polymers 0.000 title claims abstract description 171
- 235000010485 konjac Nutrition 0.000 title claims abstract description 170
- 150000004676 glycans Chemical class 0.000 title claims abstract description 130
- 229920001282 polysaccharide Polymers 0.000 title claims abstract description 130
- 239000005017 polysaccharide Substances 0.000 title claims abstract description 130
- 238000002360 preparation method Methods 0.000 title abstract description 15
- 229920000742 Cotton Polymers 0.000 claims abstract description 61
- 239000000843 powder Substances 0.000 claims abstract description 42
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 41
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 34
- 239000000499 gel Substances 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 235000009496 Juglans regia Nutrition 0.000 claims abstract description 24
- 235000020234 walnut Nutrition 0.000 claims abstract description 24
- 239000010420 shell particle Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 17
- 240000007049 Juglans regia Species 0.000 claims abstract 5
- 239000007864 aqueous solution Substances 0.000 claims description 20
- 230000001815 facial effect Effects 0.000 claims description 9
- 238000009964 serging Methods 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 7
- 229920002581 Glucomannan Polymers 0.000 claims description 7
- 229940046240 glucomannan Drugs 0.000 claims description 7
- 239000011324 bead Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 239000003349 gelling agent Substances 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 6
- 238000005057 refrigeration Methods 0.000 claims description 6
- 238000010257 thawing Methods 0.000 claims description 6
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 4
- 239000001639 calcium acetate Substances 0.000 claims description 4
- 229960005147 calcium acetate Drugs 0.000 claims description 4
- 235000011092 calcium acetate Nutrition 0.000 claims description 4
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 244000082204 Phyllostachys viridis Species 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- 241000220317 Rosa Species 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 claims description 3
- 239000001354 calcium citrate Substances 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 claims description 3
- 235000013337 tricalcium citrate Nutrition 0.000 claims description 3
- 244000269722 Thea sinensis Species 0.000 claims description 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 235000009569 green tea Nutrition 0.000 claims description 2
- 239000001771 mentha piperita Substances 0.000 claims description 2
- 235000010204 pine bark Nutrition 0.000 claims description 2
- 229920001202 Inulin Polymers 0.000 claims 1
- 229940029339 inulin Drugs 0.000 claims 1
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 claims 1
- 241000758789 Juglans Species 0.000 description 19
- 239000000243 solution Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000009777 vacuum freeze-drying Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 238000007710 freezing Methods 0.000 description 5
- 230000008014 freezing Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 210000001161 mammalian embryo Anatomy 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000009958 sewing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 244000247812 Amorphophallus rivieri Species 0.000 description 2
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 235000013373 food additive Nutrition 0.000 description 2
- 239000002778 food additive Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 241001278826 Amorphophallus Species 0.000 description 1
- 241000209524 Araceae Species 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- KZNIFHPLKGYRTM-UHFFFAOYSA-N apigenin Chemical compound C1=CC(O)=CC=C1C1=CC(=O)C2=C(O)C=C(O)C=C2O1 KZNIFHPLKGYRTM-UHFFFAOYSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 201000001421 hyperglycemia Diseases 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/02—Towels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Public Health (AREA)
- Cosmetics (AREA)
Abstract
The invention provides pocket type konjak polysaccharide face tissues, which comprise a first konjak polysaccharide towel layer and a second konjak polysaccharide towel layer, wherein an open pocket structure is formed by stitching cotton threads between the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer, an all-cotton spunlaced non-woven fabric is arranged on the inner surface of the pocket structure, and cotton thread hanging ropes are arranged at the outer edge of the pocket structure; the first konjak polysaccharide towel layer is prepared from konjak fine powder, walnut shell particles, gel and cross-linking agent serving as raw materials, and the second konjak polysaccharide towel layer is prepared from konjak fine powder, gel and cross-linking agent serving as raw materials or from konjak fine powder, gel, cross-linking agent and functional auxiliary materials serving as raw materials. The invention also provides a preparation method of the pocket konjak polysaccharide face towel. The invention has the advantages that: can be used for multiple times, is multifunctional, and is not easy to curl and slide.
Description
Technical Field
The invention relates to the technical field of articles for daily use, in particular to pocket konjak polysaccharide face tissues and a preparation method thereof.
Background
Konjak (Amorphophallus Blume), also called konjak (academic name Amorphophallus konjac), is a perennial herb of konjak genus of Araceae family, and is an alkaline plant, and has a planting history of two thousands of years in our country, and is abundant in resources. Konjak is a traditional health food, which is approved as a food additive in japan, the united states, and the european union. Konjak flour has also been approved as a food additive and a food ingredient in china. Konjac tubers have a large amount of glucomannan (KGM) in an amount of about 44 to 64%. The konjak glucomannan is a water-soluble natural high molecular polysaccharide, has good biocompatibility and biodegradability, and has biological activities of resisting tumor, reducing cholesterol, regulating blood fat, resisting hyperglycemia, resisting inflammation, regulating immunity and the like, so that the konjak glucomannan has good application prospect in the biomedical field. Glucomannan has various excellent characteristics, can be used as a gel, a thickener, a stabilizer, an emulsifier, an additive and the like, is widely applied to the fields of food, medicine, printing and dyeing, construction, coating, textile, papermaking and the like, and has great market application value.
At present, konjak towels, konjak wet tissues and konjak face tissues prepared by using food-grade konjak powder as a main raw material are uniform in air holes, white in appearance, soft and smooth in touch feeling after water absorption and rich in elasticity; the base material has the characteristics of moisturizing and softening skin, and is suitable for bathing and massaging facial skin; and the product can be naturally degraded, and the environment is not polluted after being abandoned. However, the product has a single function, and because the product is prepared from plant polysaccharide fibers, the wet surface is smooth, and curling and sliding easily occur in the use process, so that the user experience is affected.
Disclosure of Invention
The invention aims to solve the technical problem of providing pocket konjak polysaccharide face tissues which can be used repeatedly, are multifunctional and are not easy to curl and slide and a preparation method thereof.
The invention adopts the following technical scheme to solve the technical problems:
the pocket type konjak polysaccharide face towel comprises a first konjak polysaccharide towel layer and a second konjak polysaccharide towel layer, wherein an open pocket structure is formed by stitching cotton threads between the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer, an all-cotton spunlaced non-woven fabric is arranged on the inner surface of the pocket structure, and cotton thread hanging ropes are arranged at the outer edge of the pocket structure; the first konjak polysaccharide towel layer is prepared from konjak fine powder, walnut shell particles, gel and cross-linking agent serving as raw materials, and the second konjak polysaccharide towel layer is prepared from konjak fine powder, gel and cross-linking agent serving as raw materials or konjak fine powder, gel, cross-linking agent and functional auxiliary materials serving as raw materials.
As one of the preferable modes of the invention, the raw material of the first konjak polysaccharide towel layer, namely walnut shell particles, is 30-100-mesh spherical bead particles obtained by crushing and polishing walnut shells.
As one preferable mode of the invention, the second konjak polysaccharide towel layer raw material-functional auxiliary material is selected from at least one of bamboo charcoal powder, rose pollen, lavender pollen, pine bark powder, green tea powder, peppermint leaf powder and chamomile powder.
As one preferable mode of the invention, the glucomannan content of the konjak fine powder serving as the raw material in the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer is more than or equal to 90 percent.
In a preferred embodiment of the present invention, the gelling agent, which is a raw material in the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer, is at least one selected from calcium hydroxide, calcium acetate, and calcium citrate.
As one preferable mode of the invention, the raw material-crosslinking agent in the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer is a mixture of sodium trimetaphosphate and disodium hydrogen phosphate according to a mass ratio of 2:1.
As one of the preferable modes of the invention, cotton thread stitching between the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer is performed by adopting pure cotton thread to stitch through a four-needle six-thread serging machine; meanwhile, the all-cotton spunlaced non-woven fabric is prepared from natural pure cotton fibers, and is attached to and embedded with a corresponding konjak polysaccharide towel layer.
The preparation method of the pocket konjak polysaccharide face towel comprises the following steps:
(1) Adding konjak fine powder into a prepared aqueous solution containing a gel agent, a cross-linking agent and walnut shell particles, fully stirring, and then injecting into a die with a bottom provided with all-cotton spunlaced non-woven fabric to form a first primary blank;
(2) Adding konjak fine powder into a prepared aqueous solution containing a gelling agent and a cross-linking agent or containing the gelling agent, the cross-linking agent and functional auxiliary materials, fully stirring, and then injecting into a die with the bottom provided with all-cotton spunlaced non-woven fabric to form a second primary blank;
(3) Standing the first primary blank and the second primary blank for 10-15 hours, respectively carrying out steam bath heat preservation at 70-90 ℃ for 1-3 hours, and then putting the primary blank and the second primary blank into a refrigeration house to be frozen at-25 ℃ for 1-3 days to obtain a first parison and a second parison;
(4) Respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutting die with a specified shape to correspondingly obtain a first konjak polysaccharide towel layer embedded with all-cotton spunlaced non-woven fabrics and a second konjak polysaccharide towel layer embedded with all-cotton spunlaced non-woven fabrics;
(5) Laminating the two products prepared in the step (4); when the film is overlapped, all cotton spunlaced non-woven fabrics of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, and after the completion, the threading and knotting are carried out, and then the drying treatment is carried out, so that the pocket konjak polysaccharide towel required by the target is finally obtained.
In the preferred embodiment of the present invention, in the step (1), the addition amount of the konjak fine powder is 2 to 10% of the aqueous solution, the addition amount of the gel is 0.01 to 0.05% of the aqueous solution, the addition amount of the crosslinking agent is 0.1 to 0.3% of the aqueous solution, and the addition amount of the walnut shell particles is 0.5 to 2.5% of the aqueous solution.
In the preferred embodiment of the present invention, in the step (2), the addition amount of the konjak fine powder is 2 to 10% of the aqueous solution, the addition amount of the gel is 0.01 to 0.05% of the aqueous solution, the addition amount of the crosslinking agent is 0.1 to 0.3% of the aqueous solution, and the addition amount of the functional auxiliary material is 0 to 0.2% of the aqueous solution.
In a preferred embodiment of the present invention, in the step (4), the drying treatment is vacuum freeze drying, wherein the vacuum degree of the vacuum freeze drying is 1.0 to 5.0Pa, the freezing temperature of the vacuum freeze drying is-30 to-50 ℃, and the drying time of the vacuum freeze drying is 6 to 10 hours.
Compared with the prior art, the invention has the advantages that:
(1) The pocket konjak polysaccharide face towel prepared by the invention is formed by sewing towels prepared from plant polysaccharide fibers through cotton threads, and the sewability and the optimal sewing mode of the konjak polysaccharide towels are confirmed through multiple tests so as to ensure the usability of products;
(2) The pocket type konjak polysaccharide face towel prepared by the invention is formed by stitching konjak polysaccharide towels with different functions, one surface of the pocket type konjak polysaccharide face towel has frosted and exfoliating functions (the surface of the first konjak polysaccharide towel layer containing the walnut shell particles) and one surface of the pocket type konjak polysaccharide face towel has functions of moisture preservation, adsorption, antioxidation, wrinkle resistance, whitening or bacteriostasis (the surface of the second konjak polysaccharide towel layer containing functional auxiliary materials), and the pocket type konjak polysaccharide face towel has various functions and is suitable for people with different demands; meanwhile, when the face towel is used, fingers are placed into the pocket openings of the face towel, so that the face towel can be prevented from curling and slipping, the face can be conveniently scrubbed, and the using experience of a user is improved;
(3) The all-cotton spunlaced non-woven fabric adopted by the invention is cellulose polysaccharide from natural sources, has a sugar hydroxyl structure similar to that of konjak polysaccharide, and can be tightly combined with konjak polysaccharide fibers without separation; meanwhile, the all-cotton spunlaced non-woven fabric is used as the lining of the pocket konjak polysaccharide facial tissues, so that the direct contact between fingers and konjak polysaccharide facial tissues in the using process can be effectively avoided, the plant fibers are prevented from being broken or even damaged due to repeated use, the using period is prolonged, and a certain anti-slip effect is achieved;
(4) The raw materials of the product are all green natural substances, and the safety is high.
Drawings
FIG. 1 is a schematic view showing the overall structure of pocket konjak polysaccharide face tissues in examples 1 to 4 at a first view angle;
FIG. 2 is a schematic view showing the overall structure of pocket konjak polysaccharide face tissues in examples 1 to 4 at a second angle of view;
FIG. 3 is a schematic view showing the overall structure of pocket konjak polysaccharide face tissues in examples 1 to 4 at a third angle of view;
FIG. 4 is a schematic front view of pocket konjak polysaccharide face tissues in examples 1 to 4;
FIG. 5 is a schematic rear view of pocket konjak polysaccharide face tissues in examples 1 to 4.
In the figure: 1 is a first konjak polysaccharide towel layer, 2 is a second konjak polysaccharide towel layer, 3 is cotton thread, 4 is an opening, and 5 is a cotton thread hanging rope.
Detailed Description
The following describes in detail the examples of the present invention, which are implemented on the premise of the technical solution of the present invention, and detailed embodiments and specific operation procedures are given, but the scope of protection of the present invention is not limited to the following examples.
Example 1
As shown in fig. 1 to 5, a pocket type konjak polysaccharide face towel of the embodiment includes a first konjak polysaccharide towel layer 1 and a second konjak polysaccharide towel layer 2; the first konjak polysaccharide towel layer 1 and the second konjak polysaccharide towel layer 2 are sewed into a pocket structure with an opening 4 through cotton threads 3, all-cotton spunlaced non-woven fabrics are arranged on the inner surface of the pocket structure, and cotton thread hanging ropes 5 are arranged at the outer edge of the pocket structure.
Wherein, the first konjak polysaccharide towel layer 1 is prepared from konjak fine powder, walnut shell particles, gel and cross-linking agent as raw materials, and the second konjak polysaccharide towel layer 2 is prepared from konjak fine powder, gel and cross-linking agent as raw materials.
Specifically, in this embodiment, the cotton thread 3 between the first konjak polysaccharide towel layer 1 and the second konjak polysaccharide towel layer 2 is sewn, and the pure cotton thread 3 is adopted for sewing by a four-needle six-thread serging machine.
The all-cotton spunlaced non-woven fabric is prepared from natural pure cotton fibers, and is attached to and embedded with a corresponding konjak polysaccharide towel layer.
Meanwhile, in the first konjak polysaccharide towel layer 1 and the second konjak polysaccharide towel layer 2 of the embodiment, the following raw materials are used: the walnut shell particles are 30-mesh spherical bead particles obtained by crushing and polishing walnut shells; the glucomannan content of the konjak refined powder is more than or equal to 90 percent; the gel adopts calcium hydroxide; the cross-linking agent is a mixture of sodium trimetaphosphate and disodium hydrogen phosphate according to a mass ratio of 2:1.
The preparation method of the pocket konjak polysaccharide face tissues comprises the following steps:
(1) 200g of konjak fine powder is added into 10000g of water solution which is prepared in advance and contains 1.0g of gel, 10g of cross-linking agent and 50g of walnut shell particles, and the mixture is fully stirred and then is injected into a die with the bottom provided with all-cotton spunlaced non-woven fabrics, so as to form a first primary blank.
(2) 200g of konjak fine powder is added into 10000g of water solution which is prepared in advance and contains 1.0g of gel and 10g of cross-linking agent, and the mixture is fully stirred and then is injected into a die with the bottom provided with all-cotton spunlaced non-woven fabric, so as to form a second initial blank.
(3) And standing the first primary embryo and the second primary embryo for 10 hours, respectively preserving heat for 1 hour in a steam bath at 70 ℃, and then putting the primary embryo and the second primary embryo into a refrigeration house to be frozen for 1 day at-25 ℃ to obtain a first parison and a second parison.
(4) And respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutter die with a specified shape to correspondingly obtain a first konjak polysaccharide towel layer 1 embedded with the all-cotton spunlaced non-woven fabric and a second konjak polysaccharide towel layer 2 embedded with the all-cotton spunlaced non-woven fabric.
(5) Laminating the two products prepared in the step (4); when the film is overlapped, all cotton spunlaced non-woven fabrics of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, threading and knotting are carried out after the completion of the sewing, then vacuum freeze drying is carried out, the vacuum degree is 1.0Pa, the freezing temperature is minus 30 ℃, the drying time is 6 hours, and finally the pocket konjak polysaccharide towel required by a target is obtained.
Example 2
The pocket konjak polysaccharide face towel of this example is basically the same as example 1 (see fig. 1-5), and is mainly different in raw materials and preparation methods.
Raw materials:
in the first konjak polysaccharide towel layer 1 and the second konjak polysaccharide towel layer 2 of the embodiment, the following raw materials are used: the walnut shell particles are 50-mesh spherical bead particles obtained by crushing and polishing walnut shells; the gel adopts calcium acetate.
The preparation method comprises the following steps:
(1) Adding 600g of konjak fine powder into 10000g of water solution which is prepared in advance and contains 3.0g of gel, 20.1g of cross-linking agent and walnut shell particles, fully stirring, and then injecting into a die with the bottom provided with all-cotton spunlaced non-woven fabric to form a first primary blank.
(2) Adding 600g of konjak fine powder into 10000g of water solution which is prepared in advance and contains 3.0g of gel and 20.1g of cross-linking agent, fully stirring, and then injecting into a mould with the bottom provided with all-cotton spunlaced non-woven fabric to form a second primary blank.
(3) And standing the first primary blank and the second primary blank for 12 hours, respectively preserving heat for 2 hours in a steam bath at 80 ℃, and then putting the primary blank and the second primary blank into a refrigeration house to be frozen for 2 days at-25 ℃ to obtain a first parison and a second parison.
(4) And respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutter die with a specified shape to correspondingly obtain a first konjak polysaccharide towel layer 1 embedded with the all-cotton spunlaced non-woven fabric and a second konjak polysaccharide towel layer 2 embedded with the all-cotton spunlaced non-woven fabric.
(5) Laminating the two products prepared in the step (4); and during film lamination, all-cotton spunlaced non-woven fabric surfaces of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, threading and knotting are carried out after the completion of the steps, then vacuum freeze drying is carried out, the vacuum degree is 3.0Pa, the freezing temperature is minus 40 ℃, the drying time is 8 hours, and finally the pocket konjak polysaccharide towel required by a target is obtained.
Example 3
The pocket konjak polysaccharide face towel of this example is basically the same as example 1 (see fig. 1-5), and is mainly different in raw materials and preparation methods.
Raw materials:
the second konjak polysaccharide towel layer 2 is prepared from konjak fine powder, gel and cross-linking agent; meanwhile, in the embodiment, the walnut shell particles are 50-mesh bead particles obtained by crushing and polishing walnut shells; the functional auxiliary material adopts bamboo charcoal powder; the gel adopts calcium acetate.
The preparation method comprises the following steps:
(1) Adding 600g of konjak fine powder into 10000g of water solution which is prepared in advance and contains 5.0g of gel, 30g of cross-linking agent and 250g of walnut shell particles, fully stirring, and then injecting into a die with the bottom provided with all-cotton spunlaced non-woven fabric to form a first primary blank.
(2) Adding 600g of konjak fine powder into 10000g of water solution which is prepared in advance and contains 5.0g of gel, 30g of cross-linking agent and 10g of functional auxiliary materials, fully stirring, and then injecting into a die with the bottom provided with all-cotton spunlaced non-woven fabric to form a second primary blank.
(3) And standing the first primary blank and the second primary blank for 15 hours, respectively preserving heat for 3 hours in a steam bath at 90 ℃, and then putting the primary blank and the second primary blank into a refrigeration house to be frozen for 3 days at-25 ℃ to obtain a first parison and a second parison.
(4) And respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutter die with a specified shape to correspondingly obtain a first konjak polysaccharide towel layer 1 embedded with the all-cotton spunlaced non-woven fabric and a second konjak polysaccharide towel layer 2 embedded with the all-cotton spunlaced non-woven fabric.
(5) Laminating the two products prepared in the step (4); and during film lamination, all-cotton spunlaced non-woven fabric surfaces of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, threading and knotting are carried out after the completion of the steps, then vacuum freeze drying is carried out, the vacuum degree is 5.0Pa, the freezing temperature is minus 50 ℃, and the drying time is 10 hours, so that the pocket konjak polysaccharide towel required by a target is finally obtained.
Example 4
The pocket konjak polysaccharide face towel of this example is basically the same as example 1 (see fig. 1-5), and is mainly different in raw materials and preparation methods.
Raw materials:
the second konjak polysaccharide towel layer 2 is prepared from konjak fine powder, gel and cross-linking agent; meanwhile, in the embodiment, the walnut shell particles are 100-mesh spherical bead particles obtained by crushing and polishing walnut shells; the functional auxiliary materials adopt rose pollen and lavender pollen mixture (mixing ratio is 1:1); the gel adopts calcium citrate.
The preparation method comprises the following steps:
(1) 1000g of konjak fine powder is added into 10000g of water solution which is prepared in advance and contains 5.0g of gel, 30g of cross-linking agent and 250g of walnut shell particles, and the mixture is fully stirred and then is injected into a die with the bottom provided with all-cotton spunlaced non-woven fabrics, so as to form a first primary blank.
(2) 1000g of konjak fine powder is added into 10000g of water solution which is prepared in advance and contains 5.0g of gel, 30g of cross-linking agent and 20g of functional auxiliary materials, and the mixture is fully stirred and then is injected into a die with the bottom provided with all-cotton spunlaced non-woven fabrics, so as to form a second primary blank.
(3) And standing the first primary blank and the second primary blank for 15 hours, respectively preserving heat for 3 hours in a steam bath at 90 ℃, and then putting the primary blank and the second primary blank into a refrigeration house to be frozen for 3 days at-25 ℃ to obtain a first parison and a second parison.
(4) And respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutter die with a specified shape to correspondingly obtain a first konjak polysaccharide towel layer 1 embedded with the all-cotton spunlaced non-woven fabric and a second konjak polysaccharide towel layer 2 embedded with the all-cotton spunlaced non-woven fabric.
(5) Laminating the two products prepared in the step (4); and during film lamination, all-cotton spunlaced non-woven fabric surfaces of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, threading and knotting are carried out after the completion of the steps, then vacuum freeze drying is carried out, the vacuum degree is 5.0Pa, the freezing temperature is minus 50 ℃, and the drying time is 10 hours, so that the pocket konjak polysaccharide towel required by a target is finally obtained.
Comparative example
The pocket konjak polysaccharide face towel of the comparative example is basically the same as that of example 2 in structure, raw materials and preparation process, and is mainly different in that: the bottom of the die in the step (1) and the step (2) of the preparation process is not provided with all-cotton spunlaced non-woven fabric in advance.
Test examples
The test is used for testing the user use effect of the pocket konjak polysaccharide face tissues prepared by the invention.
The test method comprises the following steps:
60 subjects were selected, aged 25-50 years. The subjects were divided into 3 groups of 20 persons each, and the pocket konjak polysaccharide face tissues prepared by the invention (taking example 2 face tissues) and the pocket konjak polysaccharide face tissues prepared by the comparative example and the commercially available disposable face tissues were used once a day, and the pocket konjak polysaccharide face tissues were hung in a ventilated dry place after being used, and were used for 30 days continuously or were stopped when broken, and were discarded after being used.
Test results: the results are shown in Table 1.
Table 1 user usage statistics test results
From the results in Table 1, it can be seen that: (1) Compared with the traditional disposable face tissues sold on the market, the face tissues are not easy to curl and slide off in the use process, and the user experience is high; (2) Compared with the face towel of the comparative example, the pocket is added with the all-cotton spunlaced non-woven fabric, so that the direct contact between fingers and konjak polysaccharide face towel fibers in the using process can be effectively avoided, the plant fibers are prevented from being broken or even damaged due to repeated use, the using period is prolonged, and a certain anti-slip effect is achieved.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the invention.
Claims (10)
1. The pocket type konjak polysaccharide face towel is characterized by comprising a first konjak polysaccharide towel layer and a second konjak polysaccharide towel layer, wherein an open pocket structure is formed by stitching cotton threads between the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer, an all-cotton spunlaced non-woven fabric is arranged on the inner surface of the pocket structure, and cotton thread hanging ropes are arranged at the outer edge of the pocket structure; the first konjak polysaccharide towel layer is prepared from konjak fine powder, walnut shell particles, gel and cross-linking agent serving as raw materials, and the second konjak polysaccharide towel layer is prepared from konjak fine powder, gel and cross-linking agent serving as raw materials or konjak fine powder, gel, cross-linking agent and functional auxiliary materials serving as raw materials.
2. The pocket type konjak polysaccharide facial towel according to claim 1, wherein the raw material-walnut shell particles in the first konjak polysaccharide towel layer are 30-100 mesh spherical bead particles obtained by crushing and polishing walnut shells.
3. The pocket konjak polysaccharide facial tissue of claim 1, wherein the second konjak polysaccharide towel layer material, the functional adjunct, is selected from at least one of bamboo charcoal powder, rose powder, lavender pollen, pine bark powder, green tea powder, peppermint leaf powder, and inulin.
4. The pocket konjak polysaccharide facial tissue of claim 1, wherein the glucomannan content of the konjak fine flour, a material in the first konjak polysaccharide toweling layer and the second konjak polysaccharide toweling layer, is greater than or equal to 90%.
5. The pocket konjak polysaccharide facial tissue of claim 1, wherein the gelling agent, which is a material of the first konjak polysaccharide toweling layer and the second konjak polysaccharide toweling layer, is at least one selected from the group consisting of calcium hydroxide, calcium acetate, and calcium citrate.
6. The pocket konjak polysaccharide facial tissue of claim 1, wherein the raw material-cross-linking agent in the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer is a mixture of sodium trimetaphosphate and disodium hydrogen phosphate according to a mass ratio of 2:1.
7. The pocket konjak polysaccharide facial tissue of claim 1, wherein the cotton thread between the first konjak polysaccharide towel layer and the second konjak polysaccharide towel layer is sewn by a four-needle six-thread serging machine using pure cotton thread; meanwhile, the all-cotton spunlaced non-woven fabric is prepared from natural pure cotton fibers, and is attached to and embedded with a corresponding konjak polysaccharide towel layer.
8. A method for preparing the pocket konjak polysaccharide face towel according to any one of claims 1 to 7, comprising the steps of:
(1) Adding konjak fine powder into a prepared aqueous solution containing a gel agent, a cross-linking agent and walnut shell particles, fully stirring, and then injecting into a die with a bottom provided with all-cotton spunlaced non-woven fabric to form a first primary blank;
(2) Adding konjak fine powder into a prepared aqueous solution containing a gelling agent and a cross-linking agent or containing the gelling agent, the cross-linking agent and functional auxiliary materials, fully stirring, and then injecting into a die with the bottom provided with all-cotton spunlaced non-woven fabric to form a second primary blank;
(3) Standing the first primary blank and the second primary blank for 10-15 hours, respectively carrying out steam bath heat preservation at 70-90 ℃ for 1-3 hours, and then putting the primary blank and the second primary blank into a refrigeration house to be frozen at-25 ℃ for 1-3 days to obtain a first parison and a second parison;
(4) Respectively thawing, demolding and cleaning the first parison and the second parison, and then cutting by a cutting die to correspondingly obtain a first konjak polysaccharide towel layer embedded with the all-cotton spunlaced non-woven fabric and a second konjak polysaccharide towel layer embedded with the all-cotton spunlaced non-woven fabric;
(5) Laminating the two products prepared in the step (4); when the film is overlapped, all cotton spunlaced non-woven fabrics of two konjak polysaccharide towel layers are contacted, and are sewn by a serging machine, and after the completion, the threading and knotting are carried out, and then the drying treatment is carried out, so that the pocket konjak polysaccharide towel required by the target is finally obtained.
9. The method according to claim 8, wherein in the step (1), the addition amount of konjak fine powder is 2 to 10% of the aqueous solution, the addition amount of the gel is 0.01 to 0.05% of the aqueous solution, the addition amount of the cross-linking agent is 0.1 to 0.3% of the aqueous solution, and the addition amount of the walnut shell particles is 0.5 to 2.5% of the aqueous solution.
10. The method according to claim 8, wherein in the step (2), the addition amount of konjak fine powder is 2 to 10% of the aqueous solution, the addition amount of the gel is 0.01 to 0.05% of the aqueous solution, the addition amount of the crosslinking agent is 0.1 to 0.3% of the aqueous solution, and the addition amount of the functional auxiliary material is 0 to 0.2% of the aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310079651.3A CN116269017A (en) | 2023-01-16 | 2023-01-16 | Pocket konjak polysaccharide face towel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310079651.3A CN116269017A (en) | 2023-01-16 | 2023-01-16 | Pocket konjak polysaccharide face towel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116269017A true CN116269017A (en) | 2023-06-23 |
Family
ID=86778870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310079651.3A Pending CN116269017A (en) | 2023-01-16 | 2023-01-16 | Pocket konjak polysaccharide face towel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116269017A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101011163A (en) * | 2006-12-13 | 2007-08-08 | 董忠蓉 | Villiform edible keep-fit massage towel made of konjak and grain |
| CN101147658A (en) * | 2006-09-20 | 2008-03-26 | 董忠蓉 | Konjak towel with skin-protecting function |
| CN102167846A (en) * | 2011-01-27 | 2011-08-31 | 黄建辉 | Tensile glucomannan sponge and preparation method thereof |
| CN102178484A (en) * | 2011-03-29 | 2011-09-14 | 湖北一致魔芋生物科技有限公司 | Konjak facecloth having washing and massaging functions and preparation method thereof |
| CN205913287U (en) * | 2016-06-06 | 2017-02-01 | 张川平 | Novel clean face towel cover |
| CN206675467U (en) * | 2016-12-16 | 2017-11-28 | 无锡市第二人民医院 | A kind of antibacterial towel |
-
2023
- 2023-01-16 CN CN202310079651.3A patent/CN116269017A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101147658A (en) * | 2006-09-20 | 2008-03-26 | 董忠蓉 | Konjak towel with skin-protecting function |
| CN101011163A (en) * | 2006-12-13 | 2007-08-08 | 董忠蓉 | Villiform edible keep-fit massage towel made of konjak and grain |
| CN102167846A (en) * | 2011-01-27 | 2011-08-31 | 黄建辉 | Tensile glucomannan sponge and preparation method thereof |
| CN102178484A (en) * | 2011-03-29 | 2011-09-14 | 湖北一致魔芋生物科技有限公司 | Konjak facecloth having washing and massaging functions and preparation method thereof |
| CN205913287U (en) * | 2016-06-06 | 2017-02-01 | 张川平 | Novel clean face towel cover |
| CN206675467U (en) * | 2016-12-16 | 2017-11-28 | 无锡市第二人民医院 | A kind of antibacterial towel |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104178834B (en) | A kind of Chinese medicine viscose healthcare face fabric | |
| CN105821549B (en) | A kind of pearl antibacterial yarn with moisture absorption sweat discharging functions and preparation method thereof | |
| CN105795536B (en) | A kind of pearl antibacterial movement brassiere and preparation method thereof | |
| CN102715320A (en) | Mulberry leaf tea and preparation method thereof | |
| CN102178484A (en) | Konjak facecloth having washing and massaging functions and preparation method thereof | |
| CN108260790A (en) | A kind of nourishing albumen powder and preparation method thereof | |
| CN101238896A (en) | High pressure swelling pork skin processing method | |
| CN116269017A (en) | Pocket konjak polysaccharide face towel and preparation method thereof | |
| CN205758204U (en) | A kind of Semen Lini pillow | |
| CN106720413A (en) | A kind of lotus bean curd stick of low sugar step-down | |
| CN103027171A (en) | Composite preserved fruit of water chestnuts and cacti and making method of composite preserved fruit | |
| CN102020711A (en) | Casing smooth muscle collagen preparation method and functional study | |
| CN109233010A (en) | A kind of high-elastic not allergy antibacterial latex of mattress | |
| CN101375830A (en) | Aloe moisture-keeping nutrient skin-care cream and preparation method thereof | |
| CN101965886B (en) | Huai weeping forsythia health tea | |
| CN104546604A (en) | Cosmetic composition for removing cutin | |
| CN206687189U (en) | A kind of spontaneous heating physiological brief | |
| CN101878919A (en) | Ginseng roasted goose and manufacturing method thereof | |
| CN201758783U (en) | Brassiere with loofah sponge pads | |
| Kingsford | Health, Beauty and the Toilet: Letters to Ladies from a Lady Doctor | |
| CN109380851A (en) | A kind of medical hair-washing hat suit of Chinese medicine | |
| CN109350576A (en) | Have effects that the composition of replenishing water and preserving moisture and its application, toner and preparation method thereof | |
| CN103638345A (en) | Medicine used for treating lung Qi deficiency, and preparation method thereof | |
| CN109744563A (en) | A kind of fresh flower steamed stuffed bun and preparation method thereof | |
| CN109054124A (en) | A kind of comfortable latex gasket and women's shoes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |