CN116237363A - Process for producing aluminum foil for high-strength double-light lithium battery in four passes - Google Patents
Process for producing aluminum foil for high-strength double-light lithium battery in four passes Download PDFInfo
- Publication number
- CN116237363A CN116237363A CN202310291554.0A CN202310291554A CN116237363A CN 116237363 A CN116237363 A CN 116237363A CN 202310291554 A CN202310291554 A CN 202310291554A CN 116237363 A CN116237363 A CN 116237363A
- Authority
- CN
- China
- Prior art keywords
- rolling
- pass
- aluminum foil
- passes
- foil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011888 foil Substances 0.000 title claims abstract description 86
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 38
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005096 rolling process Methods 0.000 claims abstract description 98
- 239000000654 additive Substances 0.000 claims abstract description 20
- 239000002199 base oil Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 238000009826 distribution Methods 0.000 claims abstract description 6
- 238000007689 inspection Methods 0.000 claims abstract description 6
- 238000004806 packaging method and process Methods 0.000 claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims description 22
- 239000010731 rolling oil Substances 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 18
- 238000005516 engineering process Methods 0.000 abstract description 5
- 229910001234 light alloy Inorganic materials 0.000 abstract description 2
- 238000009736 wetting Methods 0.000 description 15
- 238000000576 coating method Methods 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 239000010405 anode material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/40—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B15/0007—Cutting or shearing the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/02—Shape or construction of rolls
- B21B27/021—Rolls for sheets or strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/16—Control of thickness, width, diameter or other transverse dimensions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
- B21B37/74—Temperature control, e.g. by cooling or heating the rolls or the product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0239—Lubricating
- B21B45/0242—Lubricants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
- Metal Rolling (AREA)
Abstract
本发明属于轻合金技术领域,涉及一种四道次生产高强度双光锂电池用铝箔的工艺,包括:坯料厚度0.26~0.3mm,硬度状态H18,将微量合金元素铜的含量由0.05~0.1%调整到0.1~0.15%;将坯料按照4个道次工艺分配轧制,其中粗中轧3个道次、精轧1个道次;以厚度0.26㎜的坯料为例,粗轧和中轧安排在同一台轧机经3道次压延轧到0.025mm的厚度铝箔,再以1道次精轧轧至厚0.012mm的双光电池箔,轧制道次分配为:0.26mm→0.115mm→0.055mm→0.025mm→0.012mm,分切、电晕、检验、成品包装。本发明将坯料中铜的含量提高,使用95#基础油配以添加剂W3H,实际板型与目标板型重合度达到95%以上。调节轧辊工艺和高油温,加大箔面油膜的挥发以及电晕,成品表面达因值>32,成材率提升10~15%,综合成材率80%以上。The invention belongs to the field of light alloy technology, and relates to a four-pass process for producing aluminum foil for high-strength dual-light lithium batteries. % is adjusted to 0.1~0.15%; the billet is distributed and rolled according to 4 passes, including 3 passes for rough rolling and 1 pass for finish rolling; taking a billet with a thickness of 0.26mm as an example, rough rolling and Arranged on the same rolling mill to roll the aluminum foil to a thickness of 0.025mm through 3 passes, and then finish rolling to the double photocell foil with a thickness of 0.012mm in 1 pass. The rolling pass distribution is: 0.26mm→0.115mm→0.055mm →0.025mm→0.012mm, slitting, corona, inspection, finished product packaging. The present invention increases the copper content in the billet, uses 95# base oil together with additive W3H, and the coincidence degree of the actual plate shape and the target plate shape reaches more than 95%. Adjust the roll process and high oil temperature, increase the volatilization and corona of the oil film on the foil surface, the surface dyne value of the finished product is > 32, the yield is increased by 10-15%, and the overall yield is over 80%.
Description
技术领域technical field
本发明属于轻合金技术领域,涉及铝箔的生产,尤其涉及一种四道次生产高强度双光锂电池用铝箔的工艺。The invention belongs to the technical field of light alloys and relates to the production of aluminum foil, in particular to a four-pass process for producing aluminum foil for high-strength dual-light lithium batteries.
背景技术Background technique
随着新能源电动汽车的快速发展,核心部件锂电池需求旺盛,作为锂电池正极材料的铝箔,需要具备更高的性能和质量要求。电池箔的各项技术指标要求严格,客户对电池箔的厚度、强度、版型、洁净度等要求达到了极限,生产难度大。国内高强度双光锂电池用铝箔通常要求:厚度15、13、12μm,成品性能抗拉强度≥250N/mm2、延伸率≥3.0%,版型下塌量≤8mm, 表面润湿张力≥32dyn。With the rapid development of new energy electric vehicles, the demand for lithium batteries, the core component, is strong. As the anode material of lithium batteries, aluminum foil needs to have higher performance and quality requirements. The technical indicators of the battery foil are strictly required, and the customer's requirements for the thickness, strength, pattern, and cleanliness of the battery foil have reached the limit, and the production is difficult. Domestic aluminum foil for high-strength dual-light lithium batteries usually requires: thickness 15, 13, 12 μm, finished product performance tensile strength ≥ 250N/mm 2 , elongation ≥ 3.0%, pattern slump ≤ 8mm, surface wetting tension ≥ 32dyn .
目前电池箔制造技术多在普通铝箔轧制的工艺基础上进行优化,大致有:1、增加轧制道次,降低道次压下率,通过多道次加工硬化的手段达到成品的高抗拉强度;2、为提升电池箔表面润湿张力,轧机采用80#和82#基础油同时配合电池箔专用添加剂,分切过程中采用大功率灯箱烘烤和电晕处理。At present, the battery foil manufacturing technology is mostly optimized on the basis of ordinary aluminum foil rolling process, which generally includes: 1. Increase the number of rolling passes, reduce the reduction rate of passes, and achieve high tensile strength of the finished product by means of multi-pass work hardening Strength; 2. In order to improve the surface wetting tension of the battery foil, the rolling mill uses 80# and 82# base oils and special additives for battery foil, and uses high-power light box baking and corona treatment during the cutting process.
存在的问题主要有:The existing problems mainly include:
(1)高强度锂电池箔轧制困难:传统工艺在使用80#或82#基础油时,存在高强度电池箔轧不动或道次加工无法实现的问题,为此大部分厂家采取增加轧制道次和减少坯料厚度来实现,行业内普遍采用5或6个压延道次,坯料厚度≤0.24mm的工艺。这样生产效率大大降低,生产成本随之也大幅增加。(1) Difficulty in rolling high-strength lithium battery foil: When using 80# or 82# base oil in the traditional process, there are problems that the high-strength battery foil cannot be rolled or cannot be processed in one pass. For this reason, most manufacturers adopt additional rolling It is realized by reducing the number of passes and reducing the thickness of the billet. The industry generally adopts a process of 5 or 6 calendering passes, and the thickness of the billet is ≤0.24mm. In this way, the production efficiency is greatly reduced, and the production cost is also greatly increased thereupon.
(2)产品板型平整度不稳定,局部松紧变化现象明显:高端电池箔客户对电池箔的版型要求极高,在离线版型检测仪上需做到在2m的测量间距负载8N/mm2力后,激光扫描箔面最大坍陷≤8mm。板型不平整会影响电池涂碳工艺均匀和一致性,是电池能量密度的关键技术指标。随着行业的发展对锂电池箔的版型精度要求在不断提高,使用80#或82#基础油时,由于运动粘度只有1.75左右,轧制油的耐磨和润滑都不能完全适应轧制需求,致使轧辊热凸不均匀,最终导致箔面版型不良。事实上,电池箔用户对于板型的质量投诉和退货非常多。通过工艺优化和技术创新来不断提高产品的板型质量,是电池箔生产厂家面临的一个重要课题。(2) The flatness of the product plate is unstable, and local tightness changes are obvious: high-end battery foil customers have extremely high requirements on the form of the battery foil, and the off-line form detector needs to achieve a load of 8N/mm at a measuring distance of 2m After 2 forces, the maximum collapse of the laser scanning foil surface is ≤8mm. The uneven plate shape will affect the uniformity and consistency of the carbon coating process of the battery, which is a key technical indicator of the energy density of the battery. With the development of the industry, the requirements for the accuracy of the lithium battery foil pattern are constantly increasing. When using 80# or 82# base oil, since the kinematic viscosity is only about 1.75, the wear resistance and lubrication of the rolling oil cannot fully meet the rolling needs. , resulting in uneven thermal convexity of the roll, which eventually leads to poor foil surface layout. In fact, battery foil users have a lot of quality complaints and returns about the plate type. Continuously improving the shape quality of products through process optimization and technological innovation is an important issue faced by battery foil manufacturers.
(3)表面润湿张力:表面润湿张力不足会严重影响电池箔涂炭质量。润湿张力不达标会在涂炭过程中发生漏涂、脱层等缺陷,这些缺陷会直接导致产品报废,因此箔面检测润湿张力需≥32dyn。(3) Surface wetting tension: Insufficient surface wetting tension will seriously affect the quality of carbon coating on battery foil. If the wetting tension is not up to the standard, defects such as missing coating and delamination will occur during the carbon coating process. These defects will directly lead to the scrapping of the product. Therefore, the wetting tension of the foil surface must be ≥32dyn.
这些问题使得电池箔生产综合成材率低,生产成本较高,锂电池铝箔的生产厂家面临诸多困难。随着新能源汽车迅速崛起,锂电池铝箔需求大幅提升,开发生产高质量适应市场需求的锂电池铝箔势在必行。These problems make the comprehensive yield of battery foil production low, the production cost is high, and the manufacturers of aluminum foil for lithium batteries face many difficulties. With the rapid rise of new energy vehicles, the demand for lithium battery aluminum foil has increased significantly, and it is imperative to develop and produce high-quality lithium battery aluminum foil that meets market demand.
发明内容Contents of the invention
针对现有生产锂电池铝箔存在轧制难度大、生产效率低、生产成本高的问题,本发明的目的是公开一种四道次生产高强度双光锂电池用铝箔的工艺。Aiming at the problems of difficult rolling, low production efficiency and high production cost in the existing production of aluminum foil for lithium batteries, the purpose of the present invention is to disclose a four-pass process for producing aluminum foil for high-strength dual-light lithium batteries.
一种四道次生产高强度双光锂电池用铝箔的工艺,包括如下步骤:A four-pass process for producing aluminum foil for high-strength double-light lithium batteries, comprising the following steps:
坯料厚度0.26~0.3mm,硬度状态H18,将微量合金元素铜的含量由0.05~0.1%调整到0.1~0.15%;The thickness of the billet is 0.26-0.3mm, the hardness state is H18, and the content of trace alloy element copper is adjusted from 0.05-0.1% to 0.1-0.15%;
将坯料按照4个道次工艺分配轧制,其中粗中轧3个道次、精轧1个道次;以厚度0.26㎜的坯料为例,粗轧和中轧安排在同一台轧机经3道次压延轧到0.025mm的厚度铝箔,再以1道次精轧轧至厚0.012mm的双光电池箔,轧制道次分配为:The billet is distributed and rolled according to 4 passes, including 3 passes for rough rolling and 1 pass for finish rolling; taking a billet with a thickness of 0.26mm as an example, rough rolling and intermediate rolling are arranged in the same rolling mill through 3 passes Roll the aluminum foil to a thickness of 0.025mm for the first time, and then finish rolling to the double photocell foil with a thickness of 0.012mm in one pass. The rolling pass distribution is as follows:
0.26mm→0.115mm→0.055mm→0.025mm→0.012mm,0.26mm→0.115mm→0.055mm→0.025mm→0.012mm,
分切、电晕、检验、成品包装,得到锂电池箔成品。Slitting, corona, inspection, and finished product packaging to obtain the finished lithium battery foil.
本发明较优公开例,步骤A中所述坯料的抗拉强度≥195/mm2、性能延伸率≥3.0%,满足坯料在4个道次轧制下成品达到高强度要求。In a preferred disclosed example of the present invention, the tensile strength of the billet in step A is ≥195/mm 2 , and the performance elongation is ≥3.0%, meeting the high-strength requirements of the finished product after the billet is rolled in 4 passes.
进一步的,所述坯料的合金牌号为1100合金。Further, the alloy grade of the blank is 1100 alloy.
本发明较优公开例,步骤B中,各道次所使用的轧辊的参数为:The preferred disclosed example of the present invention, in step B, the parameters of the rolls used in each pass are:
粗轧工作辊粗糙度选择在Ra:0.26~0.28μm之间,凸度选择Cr:0.035mm;The roughness of the rough rolling work roll is selected between Ra: 0.26 ~ 0.28μm, and the convexity is selected as Cr: 0.035mm;
中轧工作辊粗糙度选择在Ra:0.16~0.17μm之间,凸度选择Cr:0.05mm;The roughness of the intermediate rolling work roll is selected between Ra: 0.16 ~ 0.17μm, and the convexity is selected as Cr: 0.05mm;
粗、中轧所用的支撑辊粗糙度Ra:0.60~0.65μm之间,凸度选择Cr:0.04mm;Roughness Ra of backup rolls used in rough and intermediate rolling: between 0.60 and 0.65 μm, crown selection Cr: 0.04 mm;
粗轧道次目标板型曲线值≤13N/mm2、中轧道次目标板型曲线值≤11N/mm2。The target shape curve value of the rough rolling pass is ≤13N/mm 2 , and the target shape curve value of the intermediate rolling pass is ≤11N/mm 2 .
本发明较优公开例中,步骤B中的前3个道次所使用的轧制油为95#基础油配合醇、酯添加剂混合而成,其中添加剂中醇含量质量百分比3~5%,以C12月桂醇为主;酯含量百分比3~5%,以硬酯酸丁酯为主。In the preferred disclosed example of the present invention, the rolling oil used in the first 3 passes in step B is 95# base oil mixed with alcohol and ester additives, wherein the alcohol content in the additives is 3-5% by mass, with C12 lauryl alcohol is the main ingredient; the ester content is 3-5%, mainly butyl stearate.
进一步的,前3个道次轧制时轧制油温控制50~55℃。Further, the rolling oil temperature is controlled at 50-55°C during the first three rolling passes.
本发明较优公开例中,步骤B以中轧所得0.025mm的单张铝箔为例,所使用的精轧工作辊粗糙度为Ra: 0.12~0.13μm,凸度Cr:0.06mm;In the preferred disclosed example of the present invention, step B takes a single aluminum foil of 0.025 mm obtained by intermediate rolling as an example, and the roughness of the work roll used for finishing rolling is Ra: 0.12-0.13 μm, and the crown Cr: 0.06 mm;
精轧机支撑辊粗糙度Ra:0.60~0.65μm,凸度Cr0.04mm;The roughness Ra of the backup roll of the finishing mill: 0.60~0.65μm, the crown Cr0.04mm;
精轧道次目标板型曲线值≤7N/mm2。The target shape curve value of the finishing pass is ≤7N/mm 2 .
本发明较优公开例中,步骤B中第4道次精轧所使用的轧制油为95#基础油配5~7%酯类添加剂W3H,其中添加剂W3H中酯含量占70%,购自石家庄新泰特种油有限公司。轧制时轧制油温控制60~65℃。In the preferred disclosed example of the present invention, the rolling oil used in the fourth pass finish rolling in step B is 95# base oil mixed with 5-7% ester additive W3H, wherein the ester content in additive W3H accounts for 70%, purchased from Shijiazhuang Xintai Special Oil Co., Ltd. During rolling, the rolling oil temperature is controlled at 60-65°C.
本发明较优公开例中,步骤C中所述电晕,属于电池箔表面处理装置,其作用是清理铝箔表面的少量残油和减少箔面油膜厚度,提高表面润湿张力,防止涂炭过程出现漏涂等。采用功率为7~10kW,输出电压25kV的电晕设备进行表面电晕。In the preferred disclosed example of the present invention, the corona described in step C belongs to the battery foil surface treatment device, and its function is to clean up a small amount of residual oil on the surface of the aluminum foil and reduce the thickness of the oil film on the foil surface, increase the surface wetting tension, and prevent the charcoal coating process from occurring Leakage, etc. Corona equipment with a power of 7-10kW and an output voltage of 25kV is used for surface corona.
有益效果Beneficial effect
本发明与常规电池箔生产工艺的区别在于电池坯料中铜的含量增加后使用了粘度2.05的95#基础油配以新型添加剂W3H,轧制油的耐磨强度和润滑性能更强。实现4道次生产的高性能电池箔,实际板型与目标板型重合度达到了95%以上。通过轧辊工艺和高油温调节,加大了箔面油膜的挥发再配合精切的电晕,使得产品表面达因值>32,成材率提升10~15%,综合成材率达到80%以上。同时轧制过程连续稳定,提升了生产效率和产品质量,降低电池箔生产成本,是未来最具潜力的效益增长点,为高质量大批次生产电池箔提供技术支持。The difference between the present invention and the conventional battery foil production process is that 95# base oil with a viscosity of 2.05 and new additive W3H is used after the copper content in the battery blank is increased, and the rolling oil has stronger wear resistance and lubricating performance. The high-performance battery foil produced in 4 passes, the coincidence degree between the actual plate shape and the target plate shape has reached more than 95%. Through the rolling process and high oil temperature adjustment, the volatilization of the oil film on the foil surface is increased, and combined with the fine-cut corona, the surface dyne value of the product is > 32, the yield is increased by 10-15%, and the overall yield reaches more than 80%. At the same time, the rolling process is continuous and stable, which improves production efficiency and product quality, and reduces the production cost of battery foil. It is the most potential profit growth point in the future and provides technical support for high-quality mass production of battery foil.
具体实施方式Detailed ways
下面结合实施例对本技术进行详细说明,以使本领域技术人员更好地理解本技术,但本技术并不局限于以下实施例。The present technology will be described in detail below in conjunction with the embodiments, so that those skilled in the art can better understand the present technology, but the present technology is not limited to the following embodiments.
实施例1Example 1
一种四道次生产高强度双光锂电池用铝箔的工艺,包括如下步骤:A four-pass process for producing aluminum foil for high-strength double-light lithium batteries, comprising the following steps:
步骤一、粗中轧将合金1100H18、厚度0.30×1200㎜的毛料经2道次粗轧、1道次中轧到0.032mm的单张箔,其中坯料抗拉强度实测为195N/mm2,延伸3.0%;Step 1. Rough and intermediate rolling Alloy 1100H18, wool material with a thickness of 0.30×1200㎜ undergoes 2 passes of rough rolling and 1 pass of intermediate rolling to a single foil of 0.032mm. The measured tensile strength of the billet is 195N/mm 2 . 3.0%;
成品质量要求:厚度15μm±3%,抗拉强度≥250N/mm2,延伸率≥3.5%,表面达因值≥32dyn;板型平整,离线板型A级(辊距2m,张力8N/mm2)下塌≤5mm;表面色泽均匀洁净;0.1mm以下针孔数≤10个/m2。Finished product quality requirements: thickness 15μm±3%, tensile strength ≥ 250N/mm 2 , elongation ≥ 3.5%, surface dyne value ≥ 32dyn; plate shape is flat, off-line plate type A grade (roll distance 2m, tension 8N/mm 2 ) Slump ≤ 5mm; the surface color is uniform and clean; the number of pinholes below 0.1mm is ≤ 10/m 2 .
轧制道次分配:0.30mm→0.140mm→0.066mm→0.032mm→0.015mm;Rolling pass distribution: 0.30mm→0.140mm→0.066mm→0.032mm→0.015mm;
步骤一所使用的轧辊参数如下:The used roll parameters of step one are as follows:
粗轧1-2道次采用的工作辊粗糙度Ra: 0.26~0.28μm,工作辊凸度Cr:0.035mm(35‰);Roughness Ra of work rolls used in rough rolling 1-2 pass: 0.26~0.28μm, work roll crown Cr: 0.035mm (35‰);
第3道次中轧工作辊粗糙度Ra:0.16~0.17μm,工作辊凸度Cr:0.03mm(50‰);The work roll roughness Ra of the 3rd intermediate rolling: 0.16~0.17μm, work roll crown Cr: 0.03mm (50‰);
粗中轧所用的支撑辊粗糙度Ra:0.60~0.65μm,支撑辊凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used in rough and medium rolling: 0.60~0.65μm, back-up roll crown Cr: 0.04mm (40‰);
粗轧1、2道次目标板型曲线值13N/mm2;中轧3道次目标板型曲线值11N/mm2.。The target shape curve value of rough rolling 1st and 2nd passes is 13N/mm 2 ; the target shape curve value of intermediate rolling 3rd pass is 11N/mm 2 .
轧制油采用95#基础油配含量3~5%的酯类添加剂和3~5%的醇类添加剂均匀混合作为润滑油。The rolling oil is made of 95# base oil mixed with 3-5% ester additives and 3-5% alcohol additives and evenly mixed as lubricating oil.
生产过程中,粗轧第一道次速度800~850m/min,油温50℃。板型稳定,实际板型与目标板型重合度达到99%,整卷生产无断带,表面质量良好;粗轧第二道次速度1000~1100m/min,油温52℃。板型稳定,实际板型与目标板型重合度达到99%,整卷生产无断带,表面质量良好;中轧第三道次速度1200~1300m/min,油温54℃。板型稳定,实际板型与目标板型重合度达到98%,整卷生产无断带,表面质量良好;During the production process, the speed of the first rough rolling pass is 800-850m/min, and the oil temperature is 50°C. The plate shape is stable, the coincidence degree between the actual plate shape and the target plate shape reaches 99%, the whole coil is produced without broken strips, and the surface quality is good; the speed of the second rough rolling pass is 1000-1100m/min, and the oil temperature is 52°C. The plate shape is stable, the coincidence degree between the actual plate shape and the target plate shape reaches 99%, the whole coil is produced without broken strips, and the surface quality is good; the speed of the third pass of the intermediate rolling is 1200-1300m/min, and the oil temperature is 54°C. The plate shape is stable, the coincidence degree between the actual plate shape and the target plate shape reaches 98%, the whole roll is produced without broken tape, and the surface quality is good;
步骤二、将所获得的0.032mm厚的铝箔在精轧机上进行第4道次轧制,获得0.015mm厚双面光高强度锂电池箔精轧成品;Step 2. Rolling the obtained aluminum foil with a thickness of 0.032 mm in the fourth pass on a finishing mill to obtain a finished product of lithium battery foil with a thickness of 0.015 mm and double-sided light finish rolling;
所用的精轧辊粗糙度为Ra: 0.13~0.135μm,凸度选择Cr:0.06mm(60‰);The roughness of the finishing roll used is Ra: 0.13~0.135μm, and the convexity is Cr: 0.06mm (60‰);
精轧所用的支撑辊粗糙度Ra:0.60~0.65μm,凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used for finishing rolling: 0.60~0.65μm, crown Cr: 0.04mm (40‰);
精轧道次目标板型曲线值设置为7N/mm2;The target shape curve value of the finishing pass is set to 7N/mm 2 ;
轧制油采用95#基础油配5~7% W3H添加剂;The rolling oil is 95# base oil with 5-7% W3H additive;
生产过程中,精轧第4道次速度1000~1200m/min,油温60℃。板型稳定,实际板型与目标板型吻合度达到96%,整卷生产无断带,表面质量良好; 下料实测表面润湿张力上下为32、32dyn,实测厚度15.05μm,抗拉强度为260N/mm2,延伸率4.5%,针孔数<10个/m2,精轧下料检查满足电池箔质量要求。During the production process, the speed of the fourth pass of finish rolling is 1000-1200m/min, and the oil temperature is 60°C. The plate shape is stable, the matching degree between the actual plate shape and the target plate shape reaches 96%, and there is no broken belt in the whole roll production, and the surface quality is good; 260N/mm 2 , elongation 4.5%, number of pinholes < 10/m 2 , the finish rolling blanking inspection meets the battery foil quality requirements.
步骤三、分切、电晕、成品包装。Step 3, cutting, corona, finished product packaging.
上述步骤二所生产的电池箔在分切机分切过程中,板型平整,板面波浪均匀,无肋松、局部松的情况。标准离线板型检测塌边量≤5mm,按行业标准可以达到A级板型,完全满足电池箔板型质量要求.During the slitting process of the above step 2, the battery foil produced by the slitting machine has a flat plate shape, uniform waves on the plate surface, and no loose ribs or partial looseness. The standard off-line plate shape detection has a sag amount of ≤5mm, which can reach the A-level plate shape according to the industry standard, which fully meets the quality requirements of the battery foil plate shape.
分切电晕过程,上下铝箔表面电晕功率参数为8kw/8KW,分切速度120m/min,下料实测上下表面润湿张力34、34dyn,满足电池箔表面润湿张力的需要。During the slitting corona process, the corona power parameters of the upper and lower aluminum foil surfaces are 8kw/8KW, the slitting speed is 120m/min, and the wetting tension of the upper and lower surfaces is 34, 34dyn measured on the blanking, which meets the needs of the surface wetting tension of the battery foil.
实施例2Example 2
一种四道次生产高强度双光锂电池用铝箔的工艺,包括如下步骤:A four-pass process for producing aluminum foil for high-strength double-light lithium batteries, comprising the following steps:
步骤一、粗中轧将合金1100H18、厚度0.27×1200㎜的坯料经2道次粗轧、1道次中轧到0.026mm±3%的单张箔,其中坯料抗拉强度实测为197N/mm2,延伸2.7%;Step 1. Rough and intermediate rolling The billet of alloy 1100H18 and thickness 0.27×1200㎜ undergoes 2 passes of rough rolling and 1 pass of intermediate rolling to a single foil of 0.026mm±3%. The measured tensile strength of the billet is 197N/mm 2 , extended by 2.7%;
成品质量要求:厚度13μm±3%,抗拉强度≥240N/mm2,延伸率≥3.0%,表面达因值≥32dyn;板型平整,离线板型A级(辊距2m,张力8N/mm2)下塌≤5mm;表面色泽均匀洁净;0.1mm以下针孔数≤10个/m2。Finished product quality requirements: thickness 13μm±3%, tensile strength ≥ 240N/mm 2 , elongation ≥ 3.0%, surface dyne value ≥ 32dyn; plate shape flat, off-line plate type A (roll distance 2m, tension 8N/mm 2 ) Slump ≤ 5mm; the surface color is uniform and clean; the number of pinholes below 0.1mm is ≤ 10/m 2 .
轧制道次分配:0.27mm→0.128mm→0.058mm→0.026mm→0.013mm;Rolling pass distribution: 0.27mm→0.128mm→0.058mm→0.026mm→0.013mm;
步骤一所使用的轧辊参数如下:The used roll parameters of step one are as follows:
粗轧1-2道次采用的工作辊粗糙度Ra: 0.26~0.28μm,工作辊凸度Cr:0.035mm(35‰);Roughness Ra of work rolls used in rough rolling 1-2 pass: 0.26~0.28μm, work roll crown Cr: 0.035mm (35‰);
第3道次中轧工作辊粗糙度Ra:0.16~0.17μm,工作辊凸度Cr:0.05mm(50‰);Roughness Ra of work rolls in the third pass: 0.16~0.17μm, work roll crown Cr: 0.05mm (50‰);
粗中轧所用的支撑辊粗糙度Ra:0.60~0.65μm,支撑辊凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used in rough and medium rolling: 0.60~0.65μm, back-up roll crown Cr: 0.04mm (40‰);
粗轧1、2道次目标板型曲线值13N/mm2;中轧3道次目标板型曲线值11N/mm2.。The target shape curve value of rough rolling 1st and 2nd passes is 13N/mm 2 ; the target shape curve value of intermediate rolling 3rd pass is 11N/mm 2 .
轧制油采用95#基础油配含量4~5%的酯类添加剂和3~5%的醇类添加剂均匀混合作为润滑油。The rolling oil is made of 95# base oil mixed with 4-5% ester additives and 3-5% alcohol additives and evenly mixed as lubricating oil.
生产过程中,粗轧第一道次速度800~900m/min,油温50℃。板型稳定,实际板型与目标板型吻合度达到97%,整卷生产无断带,表面质量良好;粗轧第二道次速度1000~1100m/min,油温50℃。板型稳定,实际板型与目标板型吻合度达到98%,整卷生产无断带,表面质量良好;中轧第三道次速度1200~1300m/min,油温53℃。板型稳定,实际板型与目标板型吻合度达到96%,整卷生产无断带,表面质量良好;During the production process, the speed of the first rough rolling pass is 800-900m/min, and the oil temperature is 50°C. The plate shape is stable, the matching degree between the actual plate shape and the target plate shape reaches 97%, there is no broken strip in the whole coil, and the surface quality is good; the speed of the second rough rolling pass is 1000-1100m/min, and the oil temperature is 50°C. The plate shape is stable, the matching degree between the actual plate shape and the target plate shape reaches 98%, the whole coil is produced without broken strips, and the surface quality is good; the speed of the third pass of the intermediate rolling is 1200-1300m/min, and the oil temperature is 53°C. The plate shape is stable, the actual plate shape and the target plate shape match up to 96%, the whole roll is produced without broken tape, and the surface quality is good;
步骤二、将所获得的0.026mm厚的铝箔在精轧机上进行第4道次轧制,获得0.013mm厚双面光高强度锂电池箔精轧成品;Step 2. Rolling the obtained aluminum foil with a thickness of 0.026 mm in the fourth pass on a finishing mill to obtain a finished product of lithium battery foil with a thickness of 0.013 mm and double-sided light finish rolling;
所用的精轧辊粗糙度为Ra: 0.13~0.135μm,凸度选择Cr:0.06mm(60‰);The roughness of the finishing roll used is Ra: 0.13~0.135μm, and the convexity is Cr: 0.06mm (60‰);
精轧所用的支撑辊粗糙度Ra:0.60~0.65μm,凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used for finishing rolling: 0.60~0.65μm, crown Cr: 0.04mm (40‰);
精轧道次目标板型曲线值设置为7N/mm2;The target shape curve value of the finishing pass is set to 7N/mm 2 ;
轧制油采用95#基础油配5~7% W3H添加剂;The rolling oil is 95# base oil with 5-7% W3H additive;
生产过程中,精轧第4道次速度1000~1100m/min,油温63℃。板型稳定,实际板型与目标板型吻合度达到95%,整卷生产无断带,表面质量良好;下料实测表面润湿张力上下为31、32dyn,实测厚度13.1μm,抗拉强度为254N/mm2,延伸率3.5%,针孔数<10个/m2,精轧下料检查满足电池箔质量要求。During the production process, the speed of the fourth pass of finish rolling is 1000-1100m/min, and the oil temperature is 63°C. The plate shape is stable, the actual plate shape and the target plate shape match up to 95%, the whole roll is produced without broken tape, and the surface quality is good; the measured surface wetting tension of blanking is 31, 32dyn, the measured thickness is 13.1μm, and the tensile strength is 254N/mm 2 , elongation 3.5%, number of pinholes <10/m 2 , and the blanking inspection of finish rolling meets the quality requirements of battery foil.
步骤三、分切、电晕、成品包装。Step 3, cutting, corona, finished product packaging.
上述步骤二所生产的电池箔在分切机分切过程中,板型平整,板面波浪均匀,无肋松、局部松的情况。标准离线板型检测塌边量≤5mm,按行业标准可以达到A级板型,完全满足电池箔板型质量要求,During the slitting process of the above step 2, the battery foil produced by the slitting machine has a flat plate shape, uniform waves on the plate surface, and no loose ribs or partial looseness. The standard off-line plate type detection has a sag amount of ≤5mm, which can reach the A-level plate type according to the industry standard, which fully meets the quality requirements of the battery foil plate shape.
分切电晕过程,上下铝箔表面电晕功率参数为8kw/8KW,分切速度110m/min,下料实测上下表面润湿张力33、34dyn,满足电池箔表面润湿张力的需要。During the slitting corona process, the corona power parameters of the upper and lower aluminum foil surfaces are 8kw/8KW, the slitting speed is 110m/min, and the wetting tension of the upper and lower surfaces of the material is measured to be 33, 34dyn, which meets the needs of the surface wetting tension of the battery foil.
实施例3Example 3
一种四道次生产高强度双光锂电池用铝箔的工艺,包括如下步骤: A four-pass process for producing aluminum foil for high-strength double-light lithium batteries, comprising the following steps:
步骤一、粗中轧Step 1. Rough and medium rolling
将合金1100H18、厚度0.26×1200㎜的毛料经2道次粗轧、1道次中轧到0.025mm±3%的单张箔,其中坯料抗拉强度实测为197N/mm2,延伸4.2%;Alloy 1100H18, wool material with a thickness of 0.26×1200㎜ undergoes 2 passes of rough rolling and 1 pass of medium rolling to a single sheet foil of 0.025mm±3%.
成品质量要求:厚度12μm±3%,抗拉强度≥240N/mm2,延伸率≥3.0%,表面达因值≥32dyn;板型平整,离线板型A级(辊距2m,张力8N/mm2)下塌≤8mm;表面色泽均匀洁净;0.1mm以下针孔数≤10个/m2。Finished product quality requirements: thickness 12μm±3%, tensile strength ≥ 240N/mm 2 , elongation ≥ 3.0%, surface dyne value ≥ 32dyn; plate shape flat, off-line plate type A (roll distance 2m, tension 8N/mm 2 ) Slump ≤ 8mm; the surface color is uniform and clean; the number of pinholes below 0.1mm is ≤ 10/m 2 .
轧制道次分配:0.24mm→0.115mm→0.055mm→0.024mm→0.012mm;Rolling pass distribution: 0.24mm→0.115mm→0.055mm→0.024mm→0.012mm;
步骤一所使用的轧辊参数如下:The used roll parameters of step one are as follows:
粗轧1-2道次采用的工作辊粗糙度Ra: 0.26~0.28μm,工作辊凸度Cr:0.035mm(35‰);Roughness Ra of work rolls used in rough rolling 1-2 pass: 0.26~0.28μm, work roll crown Cr: 0.035mm (35‰);
第3道次中轧工作辊粗糙度Ra:0.16~0.17μm,工作辊凸度Cr:0.05mm(50‰);Roughness Ra of work rolls in the third pass: 0.16~0.17μm, work roll crown Cr: 0.05mm (50‰);
粗中轧所用的支撑辊粗糙度Ra:0.6~0.65μm,支撑辊凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used for rough and medium rolling: 0.6~0.65μm, back-up roll crown Cr: 0.04mm (40‰);
粗轧1、2道次目标板型曲线值13N/mm2;中轧3道次目标板型曲线值11N/mm2.。The target shape curve value of rough rolling 1st and 2nd passes is 13N/mm 2 ; the target shape curve value of intermediate rolling 3rd pass is 11N/mm 2 .
轧制油采用95#基础油配含量3~5%的酯类添加剂和3~5%的醇类添加剂均匀混合作为润滑油。The rolling oil is made of 95# base oil mixed with 3-5% ester additives and 3-5% alcohol additives and evenly mixed as lubricating oil.
生产过程中,粗轧第一道次速度800~850m/min,油温53℃。板型稳定,实际板型与目标板型吻合度达到98%,整卷生产无断带,表面质量良好;粗轧第二道次速度1000~1100m/min,油温53℃。板型稳定,实际板型与目标板型吻合度达到98%,整卷生产无断带,表面质量良好; 中轧第三道次速度1200~1300m/min,油温55℃。板型稳定,实际板型与目标板型吻合度达到96%,整卷生产无断带,表面质量良好.During the production process, the speed of the first rough rolling pass is 800-850m/min, and the oil temperature is 53°C. The plate shape is stable, the actual plate shape and the target plate shape match up to 98%, the whole coil is produced without broken strips, and the surface quality is good; the speed of the second rough rolling pass is 1000-1100m/min, and the oil temperature is 53°C. The plate shape is stable, the matching degree between the actual plate shape and the target plate shape reaches 98%, the whole coil is produced without broken strips, and the surface quality is good; the third pass speed of intermediate rolling is 1200-1300m/min, and the oil temperature is 55℃. The plate shape is stable, the actual plate shape and the target plate shape match up to 96%, the whole roll is produced without broken tape, and the surface quality is good.
步骤二、将所获得的0.024mm厚的铝箔在精轧机上进行第4道次轧制,获得0.012mm厚双面光高强度锂电池箔精轧成品;Step 2. Rolling the obtained aluminum foil with a thickness of 0.024 mm in the fourth pass on a finishing mill to obtain a finished product of lithium battery foil with a thickness of 0.012 mm and double-sided light finish rolling;
所用的精轧辊粗糙度为Ra: 0.13~0.135μm,凸度Cr:0.06mm(60‰);The roughness of the finishing roll used is Ra: 0.13~0.135μm, and the crown Cr: 0.06mm (60‰);
精轧所用的支撑辊粗糙度Ra:0.60~0.65μm,凸度Cr:0.04mm(40‰);Roughness Ra of back-up roll used for finishing rolling: 0.60~0.65μm, crown Cr: 0.04mm (40‰);
精轧道次目标板型曲线值设置为7N/mm2;轧制油采用95#基础油配5~7% 的W3H添加剂;The target shape curve value of the finishing pass is set to 7N/mm 2 ; the rolling oil is 95# base oil with 5-7% W3H additive;
生产过程中,精轧第4道次速度1000~1100m/min,油温63℃。板型稳定,实际板型与目标板型吻合度达到95%,整卷生产无断带,表面质量良好;下料实测表面润湿张力上下为30、31dyn,实测厚度12..05μm,抗拉强度为252N/mm2,延伸率3.35%,针孔数<10个/m2,精轧下料检查满足电池箔质量要求。During the production process, the speed of the fourth pass of finish rolling is 1000-1100m/min, and the oil temperature is 63°C. The plate shape is stable, the matching degree between the actual plate shape and the target plate shape reaches 95%, the whole roll is produced without broken tape, and the surface quality is good; the measured surface wetting tension of blanking is 30, 31dyn, the measured thickness is 12..05μm, and the tensile strength The strength is 252N/mm 2 , the elongation is 3.35%, the number of pinholes is less than 10/m 2 , and the blanking inspection of finishing rolling meets the quality requirements of battery foil.
步骤三、分切、电晕、成品包装。Step 3, cutting, corona, finished product packaging.
上述步骤二所生产的电池箔在分切机分切过程中,板型平整,板面波浪均匀,无肋松、局部松的情况。标准离线板型检测塌边量≤5mm,按行业标准可以达到A级板型,完全满足电池箔板型质量要求,During the slitting process of the above step 2, the battery foil produced by the slitting machine has a flat plate shape, uniform waves on the plate surface, and no loose ribs or partial looseness. The standard off-line plate type detection has a sag amount of ≤5mm, which can reach the A-level plate type according to the industry standard, which fully meets the quality requirements of the battery foil plate shape.
分切电晕过程,上下铝箔表面电晕功率参数为8kw/8KW,分切速度100m/min,下料实测上下表面润湿张力32、33dyn,满足电池箔表面润湿张力的需要。During the slitting corona process, the corona power parameters of the upper and lower aluminum foil surfaces are 8kw/8KW, the slitting speed is 100m/min, and the wetting tension of the upper and lower surfaces of the material is measured to be 32, 33dyn, which meets the needs of the surface wetting tension of the battery foil.
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above is only an embodiment of the present invention, and does not limit the patent scope of the present invention. Any equivalent structure or equivalent process transformation made by the description of the present invention, or directly or indirectly used in other related technical fields, shall be the same as The theory is included in the patent protection scope of the present invention.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310291554.0A CN116237363A (en) | 2023-03-23 | 2023-03-23 | Process for producing aluminum foil for high-strength double-light lithium battery in four passes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202310291554.0A CN116237363A (en) | 2023-03-23 | 2023-03-23 | Process for producing aluminum foil for high-strength double-light lithium battery in four passes |
Publications (1)
Publication Number | Publication Date |
---|---|
CN116237363A true CN116237363A (en) | 2023-06-09 |
Family
ID=86627817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202310291554.0A Pending CN116237363A (en) | 2023-03-23 | 2023-03-23 | Process for producing aluminum foil for high-strength double-light lithium battery in four passes |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN116237363A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116851444A (en) * | 2023-07-21 | 2023-10-10 | 陇西西北铝铝箔有限公司 | A method for preparing uniform matte surface battery foil |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107217175A (en) * | 2017-05-08 | 2017-09-29 | 永杰新材料股份有限公司 | A kind of battery high-performance aluminium foil and its production method |
CN110592501A (en) * | 2019-09-05 | 2019-12-20 | 江苏大亚铝业有限公司 | Aluminum foil for lithium battery aluminum plastic film and preparation process thereof |
CN111438187A (en) * | 2020-04-03 | 2020-07-24 | 江苏大亚铝业有限公司 | Production process for preparing aluminum foil for lithium battery by high-hardness roller |
CN112662916A (en) * | 2020-12-30 | 2021-04-16 | 郑州金辉新能源电子材料有限公司 | Aluminum foil for power battery and preparation process thereof |
CN115415318A (en) * | 2022-09-26 | 2022-12-02 | 江苏大亚铝业有限公司 | Process of preparing aluminum foil for lithium battery with large convex support roll |
-
2023
- 2023-03-23 CN CN202310291554.0A patent/CN116237363A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107217175A (en) * | 2017-05-08 | 2017-09-29 | 永杰新材料股份有限公司 | A kind of battery high-performance aluminium foil and its production method |
CN110592501A (en) * | 2019-09-05 | 2019-12-20 | 江苏大亚铝业有限公司 | Aluminum foil for lithium battery aluminum plastic film and preparation process thereof |
CN111438187A (en) * | 2020-04-03 | 2020-07-24 | 江苏大亚铝业有限公司 | Production process for preparing aluminum foil for lithium battery by high-hardness roller |
CN112662916A (en) * | 2020-12-30 | 2021-04-16 | 郑州金辉新能源电子材料有限公司 | Aluminum foil for power battery and preparation process thereof |
CN115415318A (en) * | 2022-09-26 | 2022-12-02 | 江苏大亚铝业有限公司 | Process of preparing aluminum foil for lithium battery with large convex support roll |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116851444A (en) * | 2023-07-21 | 2023-10-10 | 陇西西北铝铝箔有限公司 | A method for preparing uniform matte surface battery foil |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103014452B (en) | 5182 aluminum alloy tab stock substrate and production method thereof | |
CN110238193A (en) | Ultra-thin ultra-wide rolling stainless steel band technique | |
CN113414551B (en) | A kind of preparation method of deformed superalloy wide-width thin strip | |
CN101402167A (en) | Manufacturing method of stainless steel band for flexible thin-film solar cell | |
CN107442570A (en) | A kind of preparation method of micron order titanium foil | |
CN107442576A (en) | A kind of control method of cold-rolled products dimensional accuracy | |
CN102744255A (en) | Process for producing battery aluminium foil | |
CN116237363A (en) | Process for producing aluminum foil for high-strength double-light lithium battery in four passes | |
CN110052497A (en) | A kind of complete roller shape of hot-tandem unit and board-shape control method | |
CN103769431A (en) | Production method for automobile exterior board | |
CN101811142A (en) | Rolling control method of high-strength cold rolled steel strip | |
CN105598167A (en) | Production method of stainless steel composite board | |
CN102688885A (en) | Preparation method for synchronously cold-rolling iron foil by using laminated method | |
CN108273848B (en) | A kind of double dark face aluminium foils and preparation method thereof | |
CN111036676A (en) | Production method of thin strip steel of cold continuous rolling mill | |
CN111346915A (en) | Hot rolling production method of checkered plate and checkered plate | |
CN108704939B (en) | A Rolling Pressure Setting Method Based on Finished Product Roughness Control for Double Skin Passage Units | |
CN101125343A (en) | Comprehensive control method for strip edge thickening in common four-high hot strip continuous rolling mill | |
CN115415318B (en) | Process for preparing aluminum foil for lithium battery using large crown support roller | |
CN104525563A (en) | Alclad casting ingot rolling method | |
CN112122383A (en) | Preparation method of aluminum alloy plate strip for anodic oxidation of roughened surface | |
CN115301739B (en) | Production method for improving cross section shape of hot rolled strip steel | |
CN1709596A (en) | Method for preparing rolled copper foil | |
JP2616181B2 (en) | Method for producing high-gloss titanium foil with excellent moldability | |
CN114535311A (en) | Control method for hot rolling W-shaped section of wide aluminum plate strip |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |