CN116145421B - Method for preparing anti-pilling wool - Google Patents
Method for preparing anti-pilling wool Download PDFInfo
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- CN116145421B CN116145421B CN202211630376.1A CN202211630376A CN116145421B CN 116145421 B CN116145421 B CN 116145421B CN 202211630376 A CN202211630376 A CN 202211630376A CN 116145421 B CN116145421 B CN 116145421B
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- 210000002268 wool Anatomy 0.000 title claims abstract description 200
- 238000000034 method Methods 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 238000005406 washing Methods 0.000 claims abstract description 21
- 230000004048 modification Effects 0.000 claims abstract description 20
- 238000012986 modification Methods 0.000 claims abstract description 20
- 230000009471 action Effects 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- -1 phosphine compound Chemical class 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims abstract description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 23
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 22
- 238000009832 plasma treatment Methods 0.000 claims description 20
- 230000003750 conditioning effect Effects 0.000 claims description 18
- YICAEXQYKBMDNH-UHFFFAOYSA-N 3-[bis(3-hydroxypropyl)phosphanyl]propan-1-ol Chemical compound OCCCP(CCCO)CCCO YICAEXQYKBMDNH-UHFFFAOYSA-N 0.000 claims description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 13
- 150000002191 fatty alcohols Chemical class 0.000 claims description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 13
- 229960000583 acetic acid Drugs 0.000 claims description 11
- 239000012362 glacial acetic acid Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000001678 irradiating effect Effects 0.000 claims description 5
- 239000012495 reaction gas Substances 0.000 claims description 5
- PZIJUXHDLWNNRW-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)phosphanyl]ethanol Chemical compound OCCP(CCO)CCO PZIJUXHDLWNNRW-UHFFFAOYSA-N 0.000 claims description 2
- XVBMSIOVPSSTBM-UHFFFAOYSA-N 4-[bis(3-carboxypropyl)phosphanyl]butanoic acid Chemical compound OC(=O)CCCP(CCCC(O)=O)CCCC(O)=O XVBMSIOVPSSTBM-UHFFFAOYSA-N 0.000 claims description 2
- CRHOVAVWTLRGNY-UHFFFAOYSA-N 5-[bis(4-carboxybutyl)phosphanyl]pentanoic acid Chemical compound OC(=O)CCCCP(CCCCC(O)=O)CCCCC(O)=O CRHOVAVWTLRGNY-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 238000004043 dyeing Methods 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 38
- 230000000694 effects Effects 0.000 abstract description 17
- 238000013461 design Methods 0.000 abstract description 4
- 239000004519 grease Substances 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 13
- 239000004744 fabric Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 7
- 239000004873 Anti Pilling Agent Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 229920013822 aminosilicone Polymers 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000009950 felting Methods 0.000 description 2
- 238000009963 fulling Methods 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C3/00—Treatment of animal material, e.g. chemical scouring of wool
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
- D06B15/10—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by use of centrifugal force
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/001—Treatment with visible light, infrared or ultraviolet, X-rays
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Molecular Biology (AREA)
- Animal Husbandry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
A method of making anti-pilling wool comprising the steps of: s1: placing wool into a dye vat, then sequentially adding water and soaping agent for cleaning, and preserving heat for 20-40min at the temperature of 30-50 ℃ to obtain first treated wool; s2: pretreating the first treated wool to obtain second treated wool; s3: and (3) putting the second treated wool into a dye vat, and then sequentially adding water, an organic phosphine compound, a stabilizer and ferment for biological modification treatment. The method for preparing the anti-pilling wool has reasonable design, firstly adopts the soaping agent to remove impurities such as grease on the wool surface, then hydrolyzes peptide bonds on the surface of wool fibers through the combined action of pretreatment and biological modification treatment, peels off scales on the surface of the wool fibers, has small damage to the wool fibers and better modification effect, and the prepared anti-pilling wool has excellent anti-pilling effect, dimensional stability after washing and appearance stability after washing.
Description
Technical Field
The invention belongs to the technical field of wool, and particularly relates to a method for preparing anti-pilling wool.
Background
Wool is a natural protein fiber with complex structure, and mainly comprises a scale layer, a cortex layer and a medulla layer, wherein cells in each layer are bonded by cell membrane composites among structures of each layer.
The scale layer is formed by overlapping flat scale cells on the surface of the fiber along the direction from the root to the tip of the fiber, and the scale layer only accounts for 10 percent of the total weight of the wool fiber, but the existence of the scale layer has great influence on the chemical and physical properties of the wool fiber. The surface of the outer skin layer of the flake is covered with a layer of tidily and compactly arranged lipoid substance, and the outer skin layer is composed of keratinized protein, so that the wool has good hydrophobicity and chemical inertness, and has the function of protecting the inside of the wool fiber from chemical substances. However, the scale structure and the pseudo-prismatic ridges on the surface of the scale layer enable wool fibers to generate a directional friction effect, the wool fibers gradually move towards the root end under the action of external force due to the existence of the directional friction effect of the scale, so that the fabric gradually contracts tightly, interweaving felting is realized, the directional friction effect also enables the tail ends of the fibers to have a tendency to slide outwards all the time, the tail ends of the slipped fibers cause fuzzing of the wool fabric, the fuzzing and the mutual entanglement of the fuzzing are gradually realized, the felting phenomenon, the itching feeling, the fuzzing and the fuzzing problems in the wearing process are generated, and the like, so that the wearability of wool clothing is limited to a great extent.
In addition, the mass of wool fibers is mostly composed of a leather layer, which is an important part affecting the physical and mechanical properties of wool fibers. The medullary layer has loose structure, is filled with air, and has the characteristics of crisp structure and low strength. The cell membrane complex occupies a small proportion of wool fibers, but can influence the effects of water and chemical agents on wool fibers to a certain extent. .
In recent years, the requirements of consumers on wool fabrics are continuously improved, and higher requirements are put on the performances of wool fabric, such as fuzzing and pilling resistance, fulling property, crease resistance, post-washing flatness and the like. At present, in addition to factors affecting the fulling property and fuzzing and pilling property of fabrics, such as fiber performance, spinning technology, yarn structure and fabric organization structure, in recent years, textile technicians focus on the scale layer of wool fibers, and the effect of reducing the scale layer of the wool fibers from pilling is achieved by adding amino silicone oil or resin anti-pilling agent and increasing lubrication.
For example, chinese patent application No. CN201710510701.3 discloses a wool fabric anti-pilling finishing agent comprising, in parts by weight: 40-50 parts of anti-pilling agent, 10-30 parts of softener, 4-6 parts of amino acid powder, 2-4 parts of tea saponin, 3-5 parts of thickener, 1-3 parts of anti-wrinkle agent, 3-5 parts of polyethylene glycol, 0.1-0.3 part of methyl palmitate, 0.1-0.3 part of defoamer and 80-100 parts of water, wherein the softener comprises amino silicone oil.
For example, chinese patent application No. CN200610086273.8 discloses an anti-pilling process for wool fiber products, wherein the anti-pilling treatment is performed in a treatment bath, the amount of anti-pilling agent is 2-6% by weight of the wool fiber products, the pH of the treatment bath is adjusted to 8.2-8.5, the temperature of the treatment bath is 25-30 ℃, the treatment time is 25-30min, and the anti-pilling agent is an aqueous emulsion containing polyacrylate resin.
However, wool treated with the amino silicone oil or resin and anti-pilling agent of the above prior art is deformed after washing with water many times. Thus, the method is applicable to a variety of applications. There is a need to develop a method for preparing anti-pilling wool which has excellent anti-pilling effect, dimensional stability after washing and appearance stability after washing.
Disclosure of Invention
The invention aims to: in order to overcome the defects, the invention aims to provide the method for preparing the anti-pilling wool, which has reasonable step design, adopts the soaping agent to remove impurities such as grease on the wool surface, then hydrolyzes peptide bonds on the surface of wool fibers through the combined effect of pretreatment and biological modification treatment, peels off scales on the surface of the wool fibers, has small damage to the wool fibers and better modification effect, and the prepared anti-pilling wool has excellent anti-pilling effect, dimensional stability after washing and appearance stability after washing, has great application value and has wide prospect.
The invention aims at realizing the following technical scheme:
a method of making anti-pilling wool comprising the steps of:
s1: placing wool into a dye vat, then sequentially adding water and soaping agent for cleaning, and preserving heat for 20-40min at the temperature of 30-50 ℃ to obtain first treated wool;
s2: pretreating the first treated wool to obtain second treated wool;
s3: placing the second treated wool into a dye vat, sequentially adding water, an organic phosphine compound, a stabilizer and ferment for biological modification treatment, preserving heat for 10-20min at the temperature of 30-50 ℃, and preserving heat for 20-40min after the temperature is raised to 40-60 ℃ at the heating rate of 0.5-1.0 ℃/min to obtain third treated wool;
s4: adding hydrogen peroxide into the dye vat of the third treated wool, and preserving heat for 10-20min at the temperature of 40-60 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the fourth dyeing tank, maintaining at 30-50deg.C for 20-40min, washing for 1-3 times, dehydrating with centrifugal dehydrator, and drying at 60-80deg.C to obtain anti-pilling wool.
The method for preparing the anti-pilling wool is reasonable in step design, firstly, the soaping agent is adopted to remove impurities such as grease on the wool surface, then, through the combined action of pretreatment and biological modification treatment, peptide bonds on the surface of wool fibers are hydrolyzed, scales on the surface of the wool fibers are peeled off, the wool fibers are less damaged, a better modification effect is achieved, finally, the enzyme deactivation effect is achieved through hydrogen peroxide and glacial acetic acid, the anti-pilling wool is prepared after cleaning, and the anti-pilling wool is tested by a GB/T4802.3-2008 roller type pilling method, and the pilling reaches 5 levels after 14400 r. In addition, the anti-pilling wool is tested by FZ/T70009-2021 and GB/T21294-2014, and the dimensional change rate after washing for twenty times and the appearance after washing are qualified.
Wherein the wool can be wool tops or wool products such as wool fabrics.
Further, in the above method for preparing anti-pilling wool, in S1, the mass ratio of wool to water is 1:10-15, the dosage ratio of the neutral soaping agent to the water is 0.5-2.0g/L; the soaping agent is one or a combination of more of fatty alcohol polyoxyethylene ether, AEO-7 and sodium p-methoxy fatty amide benzene sulfonate.
Further, in the above method for preparing anti-pilling wool, in S2, the pretreatment is plasma treatment or ultraviolet irradiation treatment first and then plasma treatment or plasma treatment first and then ultraviolet irradiation treatment.
Further, in the above method for preparing anti-pilling wool, in S2, the plasma treatment includes the following steps: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 60-80 ℃ and then drying for later use; and (3) carrying out pre-conditioning treatment on the first treated wool, then carrying out plasma treatment, wherein the reaction gas of the plasma treatment is air, the action pressure is atmospheric pressure, the action power is 100-200W, and the treatment time is 40-60s.
Further, in the method for preparing anti-pilling wool, the pre-conditioning treatment in S2 is to pre-condition the first treated wool in a constant temperature high-humidity pre-conditioning device for 36-48 hours, wherein the temperature of the constant temperature high-humidity pre-conditioning device is set at 20+/-2 ℃, and the relative humidity is set at 80+/-2%.
Further, in the above method for preparing anti-pilling wool, in S2, the ultraviolet irradiation treatment includes the steps of: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 60-80 ℃ and then drying for later use; placing the first treated wool in an ultraviolet lamp box, wherein the energy density of the ultraviolet lamp box is 10-50mW/cm, and irradiating for 5-20min.
Further, in the method for preparing anti-pilling wool, in the step S3, the organic phosphine compound is one or more of tri (3-hydroxypropyl) phosphine, tri (3-carboxypropyl) phosphine, tri (2-hydroxyethyl) phosphine and tri (4-carboxybutyl) phosphine; the stabilizer is triethanolamine; the mass ratio of the second treated wool to the water is 1:10-15, wherein the mass of the organic phosphine compound is 1-5% of the mass of the second treated wool, the dosage of the stabilizing agent and water is 0.5-1.5g/L, and the mass of the ferment is 0.05-0.1% of the mass of the second treated wool.
Further, in the method for preparing anti-pilling wool, in the step S4, the concentration of the hydrogen peroxide is 20-40wt%, and the dosage of the hydrogen peroxide and water is 0.5-1.5g/L.
Further, in the above method for preparing anti-pilling wool, in the step S5, the amount of the glacial acetic acid and the water is 0.1-0.5g/L.
Compared with the prior art, the invention has the following beneficial effects:
(1) The method for preparing the anti-pilling wool has reasonable step design and simple and controllable process, firstly adopts soaping agent to remove impurities such as grease on the wool surface, then hydrolyzes peptide bonds on the surface of wool fibers through the combined action of pretreatment and biological modification treatment, peels off scales on the surface of the wool fibers, has small damage to the wool fibers and better modification effect, finally plays a role in inactivating enzymes through hydrogen peroxide and glacial acetic acid, and is cleaned to prepare the anti-pilling wool;
(2) According to the method for preparing the anti-pilling wool, the prepared anti-pilling wool has excellent anti-pilling effect, dimensional stability after washing and appearance stability after washing, the anti-pilling effect reaches 5 levels, and the dimensional change rate after washing for twenty times and the appearance after washing are all qualified;
(3) According to the method for preparing anti-pilling wool, pre-conditioning treatment is carried out before plasma treatment, so that the angle between the surface scales of the wool fibers and the surfaces of the fibers can be increased, namely the scale layers can be opened, the probability that high-energy active particle wool impacts the scale structures on the surfaces of the fibers is increased, and the effect of the plasma on the wool fibers is enhanced; plasma treatment is carried out on the first treated wool, physical etching is generated on the surface of the wool, the edges of the scales on the surface of the wool fiber after the plasma treatment are passivated, part of the scales are tilted and have cracks on the surfaces of the scales, and part of scales are peeled off, so that enzymes beneficial to subsequent biological modification treatment are more easily acted on the inner layers of the scales, and the scales of the wool fiber are peeled from inside to outside;
(4) According to the method for preparing the anti-pilling wool, disclosed by the invention, the compact cystine disulfide bond crosslinking with the hydrophobic property on the outer layer of the wool fiber flake can be decomposed and destroyed in the ultraviolet irradiation process, and the nonpolar C-C bond in lipid substances can be increased, so that the contents of hydroxyl groups, N-containing groups and C-O bonds on the surface of the wool can be increased in the irradiation treatment process, the contents of hydrophilic groups and polar groups are increased, the hydrophilic performance of wool fabrics is enhanced, and the permeation and diffusion of enzymes in subsequent biological modification treatment are facilitated.
Detailed Description
In the following, the technical solutions in the examples of the present invention will be clearly and completely described in combination with experimental data in comparative example 1, comparative example 2, example 1, example 2 and example 3, and it is apparent that the described examples are only some examples of the present invention, but not all examples. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to fall within the scope of the invention.
The following comparative examples 1, 2, 3, 4 provide anti-pilling wool and a method for preparing the same.
Wherein wool is treated with a wool top, a fatty alcohol polyoxyethylene ether (from Kunshan chemical Co., ltd.) is used as a soaping agent, tris (3-hydroxypropyl) phosphine (from Japanese Korea Co., ltd.), triethanolamine (from Japanese Korea Co., ltd.) is used as a stabilizer, and ferment (from Japanese Korea Co., ltd.).
Comparative example 1
Comparative example 1 is untreated wool.
Comparative example 2
The preparation method of the anti-pilling wool comprises the following steps:
s1: placing wool tops into a dye vat, then sequentially adding water and fatty alcohol polyoxyethylene ether for cleaning, and preserving heat at 40 ℃ for 30min to obtain first treated wool; the mass ratio of wool to water is 1:10, and the dosage ratio of fatty alcohol polyoxyethylene ether to water is 1g/L;
s2: sequentially adding tri (3-hydroxypropyl) phosphine, triethanolamine and ferment into the dye vat for biological modification treatment, preserving heat for 15min at 40 ℃, then raising the temperature to 50 ℃ at a heating rate of 0.7 ℃/min, and preserving heat for 3min to obtain second treated wool; the mass of the tri (3-hydroxypropyl) phosphine is 3% of the mass of wool; the dosage ratio of triethanolamine to water is 1g/L; the mass of the ferment is 0.09% of the mass of wool;
s3: adding hydrogen peroxide into the dye vat, and preserving heat for 15min at 50 ℃ to obtain third treated wool;
s4: adding glacial acetic acid into the dye vat, preserving heat at 40 ℃ for 30min, washing for 1-3 times, dehydrating by adopting a centrifugal dehydrator, and drying at 70 ℃ to obtain the anti-pilling wool of the comparative example 1.
Example 1
The preparation method of the anti-pilling wool comprises the following steps:
s1: placing wool tops into a dye vat, then sequentially adding water and fatty alcohol polyoxyethylene ether for cleaning, and preserving heat at 40 ℃ for 30min to obtain first treated wool; the mass ratio of wool to water is 1:10, and the dosage ratio of fatty alcohol polyoxyethylene ether to water is 1g/L;
s2: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 70 ℃ and then drying for later use; pre-conditioning the first treated wool in a constant-temperature high-humidity pre-conditioning device for 48 hours, wherein the temperature of the constant-temperature high-humidity pre-conditioning device is set at 20+/-2 ℃ and the relative humidity is set at 80+/-2%, then performing plasma treatment, wherein the reaction gas in the plasma treatment is air, the action pressure is atmospheric pressure, the action power is 150W, and the treatment time is 50s, so as to obtain second treated wool;
s3: placing the second treated wool into a dye vat, sequentially adding water, tri (3-hydroxypropyl) phosphine, triethanolamine and ferment for biological modification treatment, preserving heat at 40 ℃ for 15min, and preserving heat for 3min after the temperature is raised to 50 ℃ at a heating rate of 0.7 ℃/min to obtain third treated wool; the mass ratio of the second treated wool to the water is 1:10, the mass of the tris (3-hydroxypropyl) phosphine is 3% of the mass of the second treated wool; the dosage ratio of triethanolamine to water is 1g/L; the mass of the ferment is 0.09% of the mass of the second treated wool;
s4: adding hydrogen peroxide into the dye vat, and preserving heat for 15min at 50 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the dye vat, preserving heat at 40 ℃ for 30min, washing for 1-3 times, dehydrating by adopting a centrifugal dehydrator, and drying at 70 ℃ to obtain the anti-pilling wool of the embodiment 1.
Example 2
The preparation method of the anti-pilling wool comprises the following steps:
s1: placing wool tops into a dye vat, then sequentially adding water and fatty alcohol polyoxyethylene ether for cleaning, and preserving heat at 40 ℃ for 30min to obtain first treated wool; the mass ratio of wool to water is 1:10, and the dosage ratio of fatty alcohol polyoxyethylene ether to water is 1g/L;
s2: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 70 ℃ and then drying for later use; placing the first treated wool in an ultraviolet lamp box, wherein the energy density of the ultraviolet lamp box is 30mW/cm, and irradiating for 10min to obtain second treated wool;
s3: placing the second treated wool into a dye vat, sequentially adding water, tri (3-hydroxypropyl) phosphine, triethanolamine and ferment for biological modification treatment, preserving heat at 40 ℃ for 15min, and preserving heat for 3min after the temperature is raised to 50 ℃ at a heating rate of 0.7 ℃/min to obtain third treated wool; the mass ratio of the second treated wool to the water is 1:10, the mass of the tris (3-hydroxypropyl) phosphine is 3% of the mass of the second treated wool; the dosage ratio of triethanolamine to water is 1g/L; the mass of the ferment is 0.09% of the mass of the second treated wool;
s4: adding hydrogen peroxide into the dye vat, and preserving heat for 15min at 50 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the dye vat, preserving heat at 40 ℃ for 30min, washing for 1-3 times, dehydrating by adopting a centrifugal dehydrator, and drying at 70 ℃ to obtain the anti-pilling wool of the embodiment 2.
Example 3
The preparation method of the anti-pilling wool comprises the following steps:
s1: placing wool tops into a dye vat, then sequentially adding water and fatty alcohol polyoxyethylene ether for cleaning, and preserving heat at 40 ℃ for 30min to obtain first treated wool; the mass ratio of wool to water is 1:10, and the dosage ratio of fatty alcohol polyoxyethylene ether to water is 1g/L;
s2: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 70 ℃ and then drying for later use; placing the first treated wool in an ultraviolet lamp box, wherein the energy density of the ultraviolet lamp box is 30mW/cm, and irradiating for 10min; taking out, putting the wool into a constant-temperature high-humidity pre-conditioning device for pre-conditioning for 48 hours, wherein the temperature of the constant-temperature high-humidity pre-conditioning device is set at 20+/-2 ℃, the relative humidity is set at 80+/-2%, then carrying out plasma treatment, wherein the reaction gas in the plasma treatment is air, the action pressure is atmospheric pressure, the action power is 150W, and the treatment time is 50s, so that second treated wool is obtained;
s3: placing the second treated wool into a dye vat, sequentially adding water, tri (3-hydroxypropyl) phosphine, triethanolamine and ferment for biological modification treatment, preserving heat at 40 ℃ for 15min, and preserving heat for 3min after the temperature is raised to 50 ℃ at a heating rate of 0.7 ℃/min to obtain third treated wool; the mass ratio of the second treated wool to the water is 1:10, the mass of the tris (3-hydroxypropyl) phosphine is 3% of the mass of the second treated wool; the dosage ratio of triethanolamine to water is 1g/L; the mass of the ferment is 0.09% of the mass of the second treated wool;
s4: adding hydrogen peroxide into the dye vat, and preserving heat for 15min at 50 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the dye vat, preserving heat at 40 ℃ for 30min, washing for 1-3 times, dehydrating by adopting a centrifugal dehydrator, and drying at 70 ℃ to obtain the anti-pilling wool of the embodiment 3.
Example 4
The preparation method of the anti-pilling wool comprises the following steps:
s1: placing wool tops into a dye vat, then sequentially adding water and fatty alcohol polyoxyethylene ether for cleaning, and preserving heat at 40 ℃ for 30min to obtain first treated wool; the mass ratio of wool to water is 1:10, and the dosage ratio of fatty alcohol polyoxyethylene ether to water is 1g/L;
s2: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 70 ℃ and then drying for later use; pre-conditioning for 48 hours in a constant-temperature high-humidity pre-conditioning device, wherein the temperature of the constant-temperature high-humidity pre-conditioning device is set at 20+/-2 ℃, the relative humidity is set at 80+/-2%, then plasma treatment is carried out, the reaction gas in the plasma treatment is air, the action pressure is atmospheric pressure, the action power is 150W, and the treatment time is 50s; placing the wool in an ultraviolet lamp box, wherein the energy density of the ultraviolet lamp box is 30mW/cm, and irradiating for 10min to obtain second treated wool;
s3: placing the second treated wool into a dye vat, sequentially adding water, tri (3-hydroxypropyl) phosphine, triethanolamine and ferment for biological modification treatment, preserving heat at 40 ℃ for 15min, and preserving heat for 3min after the temperature is raised to 50 ℃ at a heating rate of 0.7 ℃/min to obtain third treated wool; the mass ratio of the second treated wool to the water is 1:10, the mass of the tris (3-hydroxypropyl) phosphine is 3% of the mass of the second treated wool; the dosage ratio of triethanolamine to water is 1g/L; the mass of the ferment is 0.09% of the mass of the second treated wool;
s4: adding hydrogen peroxide into the dye vat, and preserving heat for 15min at 50 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the dye vat, preserving heat at 40 ℃ for 30min, washing for 1-3 times, dehydrating by adopting a centrifugal dehydrator, and drying at 70 ℃ to obtain the anti-pilling wool of the example 4.
And (3) effect verification:
the wool obtained in comparative example 1, comparative example 2, example 1, example 2, example 3, example 4 was used as a raw material to prepare 0.3mx0.6 m knitted fabric pieces, and then the knitted fabric pieces obtained in comparative example 1, comparative example 2, example 1, example 2, example 3, example 4 were subjected to performance test according to the following test methods, and the test results are shown in tables 1, 2, 3, 4, 5, and 6.
Table 1 test results of comparative example 1
Table 2 test results of comparative example 2
TABLE 3 test results for example 1
Table 4 test results of example 2
TABLE 5 test results for example 3
TABLE 6 test results for example 4
There are many ways in which the invention may be practiced, and what has been described above is merely a preferred embodiment of the invention. It should be noted that the above examples are only for illustrating the present invention and are not intended to limit the scope of the present invention. It will be apparent to those skilled in the art that modifications may be made without departing from the principles of the invention, and such modifications are intended to be within the scope of the invention.
Claims (8)
1. A method of making anti-pilling wool comprising the steps of:
s1: placing wool into a dye vat, then sequentially adding water and soaping agent for cleaning, and preserving heat for 20-40min at the temperature of 30-50 ℃ to obtain first treated wool;
s2: pretreating the first treated wool to obtain second treated wool; the pretreatment is ultraviolet irradiation treatment and then plasma treatment or plasma treatment and then ultraviolet irradiation treatment;
s3: placing the second treated wool into a dye vat, sequentially adding water, an organic phosphine compound, a stabilizer and ferment for biological modification treatment, preserving heat for 10-20min at the temperature of 30-50 ℃, and preserving heat for 20-40min after the temperature is raised to 40-60 ℃ at the heating rate of 0.5-1.0 ℃/min to obtain third treated wool;
s4: adding hydrogen peroxide into the dye vat of the third treated wool, and preserving heat for 10-20min at the temperature of 40-60 ℃ to obtain fourth treated wool;
s5: adding glacial acetic acid into the fourth dyeing tank, maintaining at 30-50deg.C for 20-40min, washing for 1-3 times, dehydrating with centrifugal dehydrator, and drying at 60-80deg.C to obtain anti-pilling wool.
2. The method for producing anti-pilling wool according to claim 1, wherein in S1, the mass ratio of wool to water is 1:10-15, the dosage ratio of the neutral soaping agent to the water is 0.5-2.0g/L; the soaping agent is one or a combination of more of fatty alcohol polyoxyethylene ether, AEO-7 and sodium p-methoxy fatty amide benzene sulfonate.
3. The method for producing anti-pilling wool according to claim 2, wherein in S2, the plasma treatment comprises the steps of: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 60-80 ℃ and then drying for later use; the first treated wool is subjected to pre-conditioning treatment and then plasma treatment, wherein the reaction gas of the plasma treatment is air, the action pressure is atmospheric pressure, the action power is 100-200W, and the treatment time is 40-60s.
4. A method of preparing anti-pilling wool according to claim 3, wherein the pre-conditioning treatment in S2 is a pre-conditioning of 36-48h of the first treated wool in a constant temperature high-humidity pre-conditioning apparatus having a temperature set at 20±2 ℃ and a relative humidity set at 80±2%.
5. The method for producing anti-pilling wool according to claim 2, wherein in S2, the ultraviolet irradiation treatment comprises the steps of: dehydrating the first treated wool by adopting a centrifugal dehydrator, drying at 60-80 ℃ and then drying for later use; placing the first treated wool in an ultraviolet lamp box, wherein the energy density of the ultraviolet lamp box is 10-50mW/cm, and irradiating for 5-20min.
6. The method for producing anti-pilling wool according to claim 1, wherein in S3, the organic phosphine compound is one or a combination of a plurality of tri (3-hydroxypropyl) phosphine, tri (3-carboxypropyl) phosphine, tri (2-hydroxyethyl) phosphine, tri (4-carboxybutyl) phosphine; the stabilizer is triethanolamine; the mass ratio of the second treated wool to the water is 1:10-15, wherein the mass of the organic phosphine compound is 1-5% of the mass of the second treated wool, the dosage of the stabilizing agent and water is 0.5-1.5g/L, and the mass of the ferment is 0.05-0.1% of the mass of the second treated wool.
7. The method for preparing anti-pilling wool according to claim 1, wherein in the step S4, the concentration of the hydrogen peroxide is 20-40wt%, and the amount of the hydrogen peroxide and water is 0.5-1.5g/L.
8. The method for producing anti-pilling wool according to claim 1, wherein the glacial acetic acid and water is used in an amount of 0.1 to 0.5g/L in S5.
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| CN1170448A (en) * | 1994-12-21 | 1998-01-14 | 诺沃挪第克公司 | Method for enzymatic treatment of wool |
| CN101177915A (en) * | 2007-11-30 | 2008-05-14 | 东华大学 | Plasma and enzyme combined anti-felting method for tidying wool knitted fabric |
| CN105986484A (en) * | 2015-02-13 | 2016-10-05 | 天津滨海东方科技有限公司 | Continuous processing technology for non-shrink treatment of chlorine-free wool top and wool product |
| CN107869045A (en) * | 2017-11-30 | 2018-04-03 | 苏州绣艳天下刺绣工艺有限公司 | A kind of pill resistant finish method of wool fabric |
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- 2022-12-19 CN CN202211630376.1A patent/CN116145421B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170448A (en) * | 1994-12-21 | 1998-01-14 | 诺沃挪第克公司 | Method for enzymatic treatment of wool |
| CN101177915A (en) * | 2007-11-30 | 2008-05-14 | 东华大学 | Plasma and enzyme combined anti-felting method for tidying wool knitted fabric |
| CN105986484A (en) * | 2015-02-13 | 2016-10-05 | 天津滨海东方科技有限公司 | Continuous processing technology for non-shrink treatment of chlorine-free wool top and wool product |
| CN107869045A (en) * | 2017-11-30 | 2018-04-03 | 苏州绣艳天下刺绣工艺有限公司 | A kind of pill resistant finish method of wool fabric |
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Denomination of invention: A method for preparing anti pilling wool Granted publication date: 20231205 Pledgee: Bank of Jiangsu Co.,Ltd. Suzhou Branch Pledgor: JIANGSU DONGZHIHE NEW FIBER TECHNOLOGY Co.,Ltd. Registration number: Y2024980024961 |
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