CN116144121A - Shape memory pipeline material with high heat creep resistance and preparation method thereof - Google Patents

Shape memory pipeline material with high heat creep resistance and preparation method thereof Download PDF

Info

Publication number
CN116144121A
CN116144121A CN202310306829.3A CN202310306829A CN116144121A CN 116144121 A CN116144121 A CN 116144121A CN 202310306829 A CN202310306829 A CN 202310306829A CN 116144121 A CN116144121 A CN 116144121A
Authority
CN
China
Prior art keywords
parts
aging agent
temperature
shape memory
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310306829.3A
Other languages
Chinese (zh)
Inventor
贺爱华
王日国
邵华锋
刘晨光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao University of Science and Technology
Original Assignee
Qingdao University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao University of Science and Technology filed Critical Qingdao University of Science and Technology
Priority to CN202310306829.3A priority Critical patent/CN116144121A/en
Publication of CN116144121A publication Critical patent/CN116144121A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/12—Shape memory
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention relates to a high-creep-resistant shape memory pipeline material and a preparation method thereof. The pipeline material consists of 100 parts by weight of polybutene-based resin, 0.1-5 parts by weight of anti-aging agent, 0-15 parts by weight of dye, 0.01-5 parts by weight of initiator and 0.02-10 parts by weight of auxiliary initiator. The pipe material can be prepared by adopting a melt extrusion method, and the pipe after melt extrusion has good oil resistance, high-temperature creep resistance and shape memory function, and can be used for repairing long-distance non-excavation pipelines of cold and hot water pipes and oil delivery pipes.

Description

Shape memory pipeline material with high heat creep resistance and preparation method thereof
Technical Field
The invention relates to the field of new pipeline lining materials, in particular to a high-heat-creep-resistant pipeline lining material with a memory function and a preparation method thereof.
Background
Creep refers to the phenomenon in which a material slowly undergoes plastic deformation under stress as the loading time increases. The high temperature creep refers to the phenomenon that the material slowly generates plastic deformation along with the extension of loading time under the stress that the temperature T is more than or equal to (0.3-0.5) T (T is the melting point and the temperature is T) and is far lower than the yield strength. Most polymeric materials undergo large plastic deformations around (0.3-0.5) times the melting point temperature, severely affecting the dimensional stability of the article.
Chinese patent CN 105175859A, CN 108774377B discloses an inner liner material of a flexible composite pipe, wherein the inner liner material is a polymer-based material, and comprises high-density polyethylene, polyester thermoplastic polyurethane elastomer, ethylene-propylene ternary rubber and the like, has good sealing property, corrosion resistance and high barrier property, and can be used for preparing an inner liner of the flexible composite pipe.
Chinese patent CN 107987416A discloses a shape memory composite material, which comprises 100 parts of PVC resin, 3.0-20 parts of plasticizer, 1.0-5.0 parts of stabilizer, 1.0-3.0 parts of lubricant, 5.0-30 parts of filler and 1.0-15 parts of impact modifier, and the prepared material can recover the original shape at a specific temperature.
At present, no pipeline material has been reported to have high heat creep resistance and shape memory function. .
Disclosure of Invention
In order to solve the defects and the shortcomings of the prior art, the primary aim of the invention is to provide a pipeline material with high heat creep resistance and shape memory function, which can be applied in a high temperature environment of 90-100 ℃.
The invention also aims to provide a pipeline material with good oil resistance.
The invention relates to a shape memory pipeline material with high heat creep resistance and a preparation method thereof, and adopts the following technical scheme:
the pipeline material comprises the following components in parts by weight: 100 parts of polybutenyl resin, 0.1-5 parts of anti-aging agent, 0-15 parts of dye, 0-15 parts of filler, 0.01-5 parts of initiator and 0.02-10 parts of auxiliary initiator.
In the pipeline material, the polybutylene-based resin is high isotactic polybutylene-1 and alloy in a high isotactic polybutylene kettle, wherein the weight ratio of the high isotactic polybutylene-1 to the alloy in the high isotactic polybutylene kettle is 0-100:100-0, wherein the weight average molecular weight of the polybutenyl resin is 50-100 ten thousand.
In the pipe material of the present invention, the antioxidant is one or more selected from the group consisting of antioxidant 1010, antioxidant 264, antioxidant 2264S, antioxidant MB, antioxidant D, antioxidant H, antioxidant RD, antioxidant AW, antioxidant DOD, antioxidant NBC, antioxidant 4010, and antioxidant 4-1-NA.
In the pipeline material, the dye is one or two or more of titanium dioxide, zinc oxide, cadmium red, zinc yellow and carbon black; the filler is one or more selected from titanium dioxide, carbon black, white carbon black, calcium carbonate, magnesium hydroxide, calcium hydroxide, graphene, kaolin, talcum powder and montmorillonite.
In the pipe material of the present invention, the initiator is selected from peroxide initiators: one or more of peroxyketal, dibenzoyl peroxide (BPO), dicumyl peroxide (DCP), di-tert-butyl cumene peroxide, 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide, di (2, 4-dichlorobenzoyl) peroxide, azo-based initiator, diethylenetriamine (DTA), tert-butyl perbenzoate (TPB), methylenebis-o-chloroaniline (MOCA), and silane initiator.
In the pipeline material, the auxiliary initiator is selected from one or more of Triallyl Isocyanurate (TIAC), triallyl cyanurate (TAC), ethylene glycol dimethacrylate (EDMA), divinylbenzene (DVB), trimethylolpropane trimethacrylate (TMPTMA), trimethylolpropane triacrylate (TMPTA), styrene, maleic anhydride, pentaerythritol tetraacrylate, benzoquinone, hydroquinone, 1, 2-polybutadiene and thiourea.
The preparation method of the shape memory pipeline material with high heat creep resistance comprises the following steps:
(1) 100 parts of polybutenyl resin, 0.1-5 parts of anti-aging agent, 0-15 parts of dye, 0-15 parts of filler, 0.01-5 parts of initiator and 0.02-10 parts of auxiliary initiator are mixed by a high-speed mixer at the mixing temperature of 60-120 ℃ and the rotating speed of 500-1500rpm for 2-30 minutes to obtain uniformly dispersed mixed materials;
(2) Adding the mixed material prepared in the step (1) into a screw extruder, wherein the rotation frequency of the screw is 5-15Hz, the temperature of a first area of the screw is 150-210 ℃, the temperature of a second area of the screw is 160-220 ℃, the temperature of a third area of the screw is 150-210 ℃, and the temperature of a die orifice is 160-200 ℃, and preparing a pipe through melt extrusion;
(3) And (3) pulling the pipe led out from the die opening in the step (2), wherein the pulling speed is 2-10rpm, the vacuum sizing pressure is 0.005-0.05MPa, and the sizing temperature is-15-60 ℃, so that the shape memory lining pipe with high heat creep resistance is obtained.
In the preparation method, the adopted screw extruder is a single screw extruder or a double screw extruder, and the length-diameter ratio of the extruder is 30-50:1.
The invention is characterized in that the shape memory pipeline material with high heat creep resistance can be applied to a high-temperature environment with the temperature of 90-100 ℃, and has outstanding high-temperature heat creep resistance and oil resistance; meanwhile, the non-excavation type lining repair method has a shape memory function and is used for non-excavation type lining repair of oilfield pipelines and civil water pipes.
Detailed Description
The following description of the embodiments of the present invention will be further useful for understanding the present invention, and the scope of the claims should be construed as being limited to the appended claims.
Raw materials
Highly isotactic polybutene-1 (PB), melt index 0.65 (190 ℃,2.16 MPa); alloy (PBA) in high isotactic polybutene kettle, melt finger 1.0 (190 ℃,2.16 MPa); PERT, a special material for polyethylene pipes, with a melt index of 0.8 (190 ℃ C., 2.16 MPa); the special material PPR for the polypropylene pipe is melted to be 1.2 (210 ℃,2.16 MPa); other auxiliary agents are all commercial industrial products
Example 1
Weighing 50 parts of PB (Poly (butylene terephthalate)) by weight, 50 parts of PBA (Poly (butylene terephthalate)) by weight, 1.5 parts of anti-aging agent 1010 and dye TiO (titanium dioxide) 2 3 parts of initiator dicumyl peroxide 0.05 parts and auxiliary initiator EDMA 0.10 parts. The weighed materials are added into a high-speed mixer, the rotating speed of the high-speed mixer is 700rpm, the temperature of the high-speed mixer is 110 ℃, the mixing time is 10 minutes, and the materials are discharged after the mixing is finished. The mixed materials are put into a single screw extruder, the temperature of a first area of a screw is 185 ℃, the temperature of a second area of the screw is 190 ℃, the temperature of a third area of the screw is 175 ℃, the temperature of a die orifice is 180 ℃, the rotation frequency of the single screw extruder is 10Hz, the traction speed of a tractor is 5rpm, the vacuum sizing pressure is 0.01MPa, the sizing temperature is 15 ℃, and a pipe with the outer diameter of about 20mm and the wall thickness of about 1mm is extruded.
Example 2
100 parts of PBA, 264 2 parts of anti-aging agent, 330 parts of carbon black N, 0.15 part of initiator azo diisobutyronitrile and 0.3 part of auxiliary initiator triallyl isocyanurate are weighed according to the parts by weight. The weighed materials are added into a high-speed mixer, the rotating speed of the high-speed mixer is 1200rpm, the temperature of the high-speed mixer is 120 ℃, the mixing time is 5 minutes, and the materials are discharged after the mixing is finished. The mixed materials are put into a single screw extruder, the temperature of the first area is 190 ℃, the temperature of the second area is 200 ℃, the temperature of the third area is 190 ℃, the die temperature is 190 ℃, the rotation frequency of the single screw extruder is 7Hz, the traction speed of a tractor is 4rpm, the vacuum sizing pressure is 0.02MPa, the sizing temperature is 25 ℃, and a pipe with the outer diameter of about 20mm and the wall thickness of about 1mm is extruded.
Example 3
30 parts of PB, 70 parts of PBA, 0.5 part of an anti-aging agent 2264, 3 parts of silicon dioxide, 0.2 part of initiator di-tert-butyl isopropyl peroxide and 0.4 part of auxiliary initiator trimethylolpropane trimethacrylate. The weighed materials are added into a high-speed mixer, the rotating speed of the high-speed mixer is 700rpm, the temperature of the high-speed mixer is 110 ℃, the mixing time is 15 minutes, and the materials are discharged after the mixing is finished. The mixed materials are put into a single screw extruder, the temperature of a first area of a screw is 185 ℃, the temperature of a second area of the screw is 190 ℃, the temperature of a third area of the screw is 200 ℃, the temperature of a die orifice is 190 ℃, the rotation frequency of the single screw extruder is 10Hz, the traction speed of a tractor is 5rpm, the vacuum sizing pressure is 0.01MPa, the sizing temperature is-10 ℃, and a pipe with the outer diameter of about 20mm and the wall thickness of about 1mm is extruded.
Comparative example 1
100 parts of PERT (polyethylene glycol terephthalate) is weighed according to parts by weight, 264 parts of an anti-aging agent, 330 parts of carbon black N, 0.15 part of an initiator azodiisobutyronitrile and 0.3 part of auxiliary initiator triallyl isocyanurate. The weighed materials are added into a high-speed mixer, the rotating speed of the high-speed mixer is 1200rpm, the temperature of the high-speed mixer is 120 ℃, the mixing time is 5 minutes, and the materials are discharged after the mixing is finished. The mixed materials are put into a single screw extruder, the temperature of the first area is 190 ℃, the temperature of the second area is 200 ℃, the temperature of the third area is 190 ℃, the die temperature is 190 ℃, the rotation frequency of the single screw extruder is 7Hz, the traction speed of a tractor is 4rpm, the vacuum sizing pressure is 0.02MPa, the sizing temperature is 25 ℃, and a pipe with the outer diameter of about 20mm and the wall thickness of about 1mm is extruded.
Comparative example 2
100 parts of PPR (poly (phenylene vinylene)) is weighed according to parts by weight, 264 parts of an anti-aging agent, 330 parts of dye carbon black N, 0.15 part of an initiator azo-diisobutyronitrile and 0.3 part of auxiliary initiator triallyl isocyanurate. The weighed materials are added into a high-speed mixer, the rotating speed of the high-speed mixer is 1200rpm, the temperature of the high-speed mixer is 120 ℃, the mixing time is 5 minutes, and the materials are discharged after the mixing is finished. The mixed materials are put into a single screw extruder, the temperature of the first area is 190 ℃, the temperature of the second area is 200 ℃, the temperature of the third area is 190 ℃, the die temperature is 190 ℃, the rotation frequency of the single screw extruder is 7Hz, the traction speed of a tractor is 4rpm, the vacuum sizing pressure is 0.02MPa, the sizing temperature is 25 ℃, and a pipe with the outer diameter of about 20mm and the wall thickness of about 1mm is extruded.
The pipes produced in examples 1 to 3 and comparative examples 1 and 2 were tested and the results are shown in Table 1. As can be seen from the data in Table 1, the pipes produced in examples 1-3 have excellent heat-resistant creep properties, and the 70-degree creep deformation is far lower than PPR and is significantly lower than PERT; the tubing of the embodiment has good 65-degree oil resistance, the tensile strength of the tubing after being soaked in 65-degree light oil is not greatly changed, and the oil resistance is obviously better than PERT; the pipe of the embodiment has good shape memory function, and the shape recovery rate after being stimulated at 130-170 ℃ reaches 96%, which is higher than 92% and 90% of PPR and PERT.
Table 1 pipe properties of examples and comparative examples
Figure BDA0004147062390000031
/>

Claims (10)

1. The shape memory pipeline material with high heat creep resistance is characterized by comprising the following components in parts by weight: 100 parts of polybutenyl resin, 0.1-5 parts of anti-aging agent, 0-15 parts of dye, 0-15 parts of filler, 0.01-5 parts of initiator and 0.02-10 parts of auxiliary initiator.
2. The high creep resistant shape memory tubing material of claim 1, wherein the polybutylene based resin is a high isotactic polybutylene-1 and high isotactic polybutylene in-kettle alloy, wherein the weight ratio of the high isotactic polybutylene-1 to the high isotactic polybutylene in-kettle alloy is 0-100:100-0, wherein the weight average molecular weight of the polybutenyl resin is 50-100 ten thousand.
3. The shape memory pipe material of claim 1, wherein the anti-aging agent is selected from one or more of anti-aging agent 1010, anti-aging agent 264, anti-aging agent 2264S, anti-aging agent MB, anti-aging agent D, anti-aging agent H, anti-aging agent RD, anti-aging agent AW, anti-aging agent DOD, anti-aging agent NBC, anti-aging agent 4010, anti-aging agent 4-1-NA, and the like.
4. The shape memory pipeline material with high heat creep resistance according to claim 1, wherein the dye is one or more selected from titanium dioxide, zinc oxide, cadmium red, zinc yellow, carbon black; the filler is one or more selected from titanium dioxide, carbon black, white carbon black, calcium carbonate, magnesium hydroxide, calcium hydroxide, graphene, kaolin, talcum powder and montmorillonite.
5. The high creep resistant shape memory tubing material of claim 1, wherein said initiator is selected from the group consisting of peroxide initiators: one or more of peroxyketal, dibenzoyl BPO, dicumyl peroxide DCP, di-tert-butylperoxycumene, 2, 5-dimethyl-2, 5-di-tert-butylhexane peroxide, bis (2, 4-dichlorobenzoyl) peroxide, azo initiator, diethylenetriamine DTA, tert-butylperbenzoate TPB, methylenebis-o-chloroaniline MOCA, and silane initiator.
6. The shape memory tubing material of claim 1, wherein said co-initiator is selected from one or more of triallyl isocyanurate, TIAC, triallyl cyanurate, EDMA, divinylbenzene, DVB, TMPTMA, TMPTA, styrene, maleic anhydride, pentaerythritol tetraacrylate, benzoquinone, hydroquinone, 1, 2-polybutadiene, thiourea.
7. The preparation method of the shape memory pipeline material with high heat creep resistance is characterized by comprising the following steps:
(1) 100 parts of polybutene-based resin, 0.1-5 parts of anti-aging agent, 0-15 parts of dye, 0-15 parts of filler, 0.01-5 parts of initiator and 0.02-10 parts of auxiliary initiator are mixed by a high-speed mixer, the mixing temperature is 60-120 ℃, the rotating speed is 500-1500r/min, and the mixing time is 2-30 minutes, so as to obtain a uniformly dispersed mixed material;
(2) Adding the mixed material prepared in the step (1) into a screw extruder, wherein the rotation frequency of the screw is 5-15Hz, the temperature of a first area of the screw is 150-210 ℃, the temperature of a second area of the screw is 160-220 ℃, the temperature of a third area of the screw is 150-210 ℃, and the temperature of a die orifice is 160-200 ℃, and preparing a pipe through melt extrusion;
(3) And (3) pulling the pipe led out from the die opening in the step (2), wherein the pulling speed is 2-10rpm, the vacuum sizing pressure is 0.005-0.05MPa, and the sizing temperature is-15-60 ℃, so that the shape memory lining pipe with high heat creep resistance is obtained.
8. The method according to claim 7, wherein the screw extruder is a single screw extruder or a twin screw extruder, and the extruder aspect ratio is 30-50:1.
9. The piping material according to claim 1, wherein said piping material, after melt extrusion, has a shape memory function, changes shape under the effect of external force, and returns to its original shape at a stimulus temperature of 100 to 190 ℃.
10. The pipeline material according to claim 1, wherein the pipeline material is applied to a high-temperature environment of 90-100 ℃ and has outstanding high-temperature heat-resistant creep property and oil resistance; meanwhile, the non-excavation type lining repair method has a shape memory function and is used for non-excavation type lining repair of oilfield pipelines and civil water pipes.
CN202310306829.3A 2023-03-27 2023-03-27 Shape memory pipeline material with high heat creep resistance and preparation method thereof Pending CN116144121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310306829.3A CN116144121A (en) 2023-03-27 2023-03-27 Shape memory pipeline material with high heat creep resistance and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310306829.3A CN116144121A (en) 2023-03-27 2023-03-27 Shape memory pipeline material with high heat creep resistance and preparation method thereof

Publications (1)

Publication Number Publication Date
CN116144121A true CN116144121A (en) 2023-05-23

Family

ID=86350785

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310306829.3A Pending CN116144121A (en) 2023-03-27 2023-03-27 Shape memory pipeline material with high heat creep resistance and preparation method thereof

Country Status (1)

Country Link
CN (1) CN116144121A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001004077A (en) * 1999-06-23 2001-01-09 Hitachi Metals Ltd Polybutylene pipe for panel piping
CN105504552A (en) * 2016-02-03 2016-04-20 山东东方宏业化工有限公司 Polybutylene material for pipes and preparation method of polybutylene material
CN107353518A (en) * 2017-08-10 2017-11-17 青岛科技大学 A kind of composite rubber-plastic material as floor heating pipe joint material and preparation method thereof
CN108047591A (en) * 2017-11-28 2018-05-18 永高股份有限公司 A kind of production method of the quick pipe-repairing of no-dig technique
CN111286128A (en) * 2020-03-26 2020-06-16 青岛科技大学 Quickly-molded polybutylene resin and preparation method thereof
CN111440387A (en) * 2020-03-26 2020-07-24 青岛科技大学 High-rigidity and high-heat-resistance polybutylene alloy material and preparation method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001004077A (en) * 1999-06-23 2001-01-09 Hitachi Metals Ltd Polybutylene pipe for panel piping
CN105504552A (en) * 2016-02-03 2016-04-20 山东东方宏业化工有限公司 Polybutylene material for pipes and preparation method of polybutylene material
CN107353518A (en) * 2017-08-10 2017-11-17 青岛科技大学 A kind of composite rubber-plastic material as floor heating pipe joint material and preparation method thereof
CN108047591A (en) * 2017-11-28 2018-05-18 永高股份有限公司 A kind of production method of the quick pipe-repairing of no-dig technique
CN111286128A (en) * 2020-03-26 2020-06-16 青岛科技大学 Quickly-molded polybutylene resin and preparation method thereof
CN111440387A (en) * 2020-03-26 2020-07-24 青岛科技大学 High-rigidity and high-heat-resistance polybutylene alloy material and preparation method and application thereof

Similar Documents

Publication Publication Date Title
Ronca Polyethylene
CA2372056A1 (en) Highly crystalline eaodm interpolymers
JP6824936B2 (en) Compositions, thermoplastic vulcanized products produced from compositions and products produced from compositions
US20090306246A1 (en) Crosslinked composition comprising a core/shell copolymer, method of obtaining same and uses thereof
EP1546247B1 (en) Rheology-modified thermoplastic elastomer compositions for extruded profiles
CN109422969B (en) High-gas-barrier thermoplastic vulcanized rubber based on EVOH and preparation method thereof
US5728766A (en) Ethylene elastomer compounds having good processability and ageing properties
CN109456563B (en) Special material for UHMWPE alloy compatibilization toughening modified polypropylene corrugated pipe and preparation method thereof
US9890265B2 (en) Modified polyvinyl alcohol resin composition, film, and tire
CN107556577A (en) One kind includes polyethylene rubber and polyacrylic thermoplastic sulfurized rubber
CN109294117B (en) Plum blossom pipe and production process thereof
JPH10507486A (en) Production of thermoplastic elastomer based on polyolefin
CN104672613A (en) High-temperature-resistant thermoplastic elastomer material and preparation method thereof
CN101824180B (en) High elasticity polyolefin hose with radiation crosslinking and preparation method thereof
CN109824996A (en) Antiskid impact-resistant PVC plastic cement race track prefabrication type surface material and preparation method thereof
CN106750860A (en) A kind of high temperature resistant halogen-free flame-retardant thermoplastic elastomer (TPE) and preparation method thereof
CN103881248B (en) A kind of chlorinated polyethylene rubber composition
CN114193881B (en) Polymer pre-laid waterproof coiled material and preparation method thereof
EP0495996B1 (en) Polyethylene resin composition
CN116144121A (en) Shape memory pipeline material with high heat creep resistance and preparation method thereof
US3891725A (en) Vulcanizable chlorinated elastomer composition
CN114933878B (en) Strong plastic-lined metal pipe quick adhesive and preparation method thereof
CN105330983A (en) TPV for high-abrasion-resistance automobile dustproof cover and preparation method thereof
JPH10182896A (en) Blow-moldable dynamically vulcanized alloy
CN115160938A (en) High-strength and high-modulus PVB film and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination