CN116143245A - Electrolytic treatment device and method for high-salt organic wastewater - Google Patents

Electrolytic treatment device and method for high-salt organic wastewater Download PDF

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Publication number
CN116143245A
CN116143245A CN202310204237.0A CN202310204237A CN116143245A CN 116143245 A CN116143245 A CN 116143245A CN 202310204237 A CN202310204237 A CN 202310204237A CN 116143245 A CN116143245 A CN 116143245A
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electrode
turntable
electrolytic
wastewater
rotary table
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CN202310204237.0A
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CN116143245B (en
Inventor
萧大伟
史会剑
陈洪年
谭现锋
吕瑞学
陈浩
赵庆会
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Shandong Lunan Geological Engineering Survey Institute of Second Geological Brigade of Shandong Geological Survey Bureau
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Shandong Lunan Geological Engineering Survey Institute of Second Geological Brigade of Shandong Geological Survey Bureau
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to an electrolytic treatment device and method for high-salt organic wastewater. The electrolytic treatment device comprises a turntable, wherein a motor for driving the turntable to rotate is arranged on the turntable, more than two electrolytic mechanisms are equidistantly arranged on the turntable along the circumferential direction of the turntable, and one group of electrolytic mechanisms is positioned below the turntable and positioned in the wastewater; the electrolysis mechanism comprises a bracket and a guide rod which are arranged on the turntable, an electrode which slides along the length direction of the guide rod is arranged at one end of the guide rod, which is far away from the turntable, and a reset spring which drives the electrode to move is arranged at one end of the electrode, which is far away from the turntable; the invention can automatically replace in the electrolytic process by arranging a plurality of electrolytic mechanisms, thereby reducing the time for replacing the electrodes, further increasing the time for wastewater treatment, improving the efficiency of wastewater treatment, bringing convenience to the replacement work, and ensuring the normal operation of the electrolysis in the electrolytic process by completing the self cleaning of the electrolytic mechanisms.

Description

Electrolytic treatment device and method for high-salt organic wastewater
Technical Field
The invention belongs to the technical field of waste water electrolysis, and particularly relates to an electrolytic treatment device and method for high-salt organic waste water.
Background
The electrolytic water method is a new thought for sewage treatment, and the mechanism of the method is an electrochemical catalytic oxidation process. The method does not need to add an oxidant, has no secondary pollution, mild conditions and wide application range, and has the functions of air floatation, flocculation and sterilization.
However, the key point of the electrolytic method for treating sewage is an oxidation electrode, the selection of electrode materials is critical, and for the sewage treatment, especially for high-salt wastewater, the electrode is required to have good conductivity and corrosion resistance, which leads to the shorter service life of the electrode, thereby leading to the quicker replacement frequency of the electrode, not only affecting the efficiency of wastewater electrolysis, but also bringing trouble to the replacement work.
Disclosure of Invention
The present invention has been made to solve the above-mentioned problems occurring in the prior art, and an object of the present invention is to provide an apparatus and a method for electrolytic treatment of high-salt organic wastewater.
The invention realizes the above purpose through the following technical scheme:
the electrolytic treatment device for the high-salt organic wastewater comprises a turntable, wherein a motor for driving the turntable to rotate is arranged on the turntable, more than two electrolytic mechanisms are equidistantly arranged on the turntable along the circumferential direction of the turntable, and one group of electrolytic mechanisms is positioned below the turntable and positioned in the wastewater;
the electrolysis mechanism comprises a bracket and a guide rod, wherein the bracket and the guide rod are arranged on the turntable, one end of the guide rod, which is far away from the turntable, is provided with an electrode sliding along the length direction of the guide rod, one end of the electrode, which is far away from the turntable, is provided with a reset spring for driving the electrode to move, one end of the reset spring, which is far away from the turntable, is provided with a pressure sensing unit for detecting the weight of the electrode, and the pressure sensing unit is arranged on the bracket;
the turntable is provided with a controller, and the controller is configured to:
the controller receives the weight value of the electrode sent by the pressure sensing unit and compares the weight value with a set reference value, and when the weight value of the electrode is lower than the reference value, the controller controls the motor to start, so that the motor drives the adjacent electrolysis mechanism to be immersed into the wastewater and reach the working position, and then the motor stops working.
Preferably, the electrolysis mechanism further comprises more than two springs arranged on the turntable, the two springs are fixed with a cleaning ring for cleaning the electrode at one end of the turntable, the support is provided with a mounting groove, the mounting groove is internally provided with a spring No. two, the spring No. two is provided with a clamping block with magnetism for controlling the position of the cleaning ring, and the electrode is provided with a magnetic block which is the same with the magnetism of the clamping block and used for changing the position of the clamping block.
Preferably, the support is provided with a collecting ring which corresponds to the cleaning ring and is used for scraping suspended matters on the surface of the electrode, and one side, close to the turntable, of the collecting ring is provided with a collecting groove for collecting the suspended matters.
Preferably, a storage tank for temporarily storing suspended matters is arranged on one side, far away from the turntable, of the cleaning ring, and the storage tank is C-shaped.
Preferably, the guide rod is provided with a hole, and a limiting body for limiting the movement of the electrode is arranged at the hole.
Preferably, the limiting body is sucrose or sodium chloride.
The electrolytic treatment method for the high-salt organic wastewater by adopting any one of the electrolytic treatment devices for the high-salt organic wastewater comprises the following steps:
s1: performing primary filtration on the high-salt organic wastewater to remove large-particle suspended matters in the wastewater;
s2: pumping the wastewater subjected to primary filtration into an electrolytic cell, and erecting an electrolytic treatment device so that one of electrolytic mechanisms of the electrolytic treatment device is positioned in the wastewater;
s3: the electrode is gradually corroded in the use process of the electrolytic treatment device, the electrode is driven by the reset spring to be close to the rotary table, the total weight of the electrode is reduced under the corrosion condition, the pressure sensing unit triggers the controller after the weight of the electrode is measured to be lower than a reference value, the controller controls the motor to start, and the motor drives the rotary table to rotate, so that the adjacent electrolytic mechanism rotates to the working position in the wastewater;
s4: and (3) carrying out secondary filtration on the electrolyzed sewage to remove suspended matters in the sewage, thereby obtaining clarified wastewater.
The invention has the beneficial effects that:
the invention can automatically replace in the electrolytic process by arranging a plurality of electrolytic mechanisms, thereby reducing the time for replacing the electrodes, further increasing the time for wastewater treatment, improving the efficiency of wastewater treatment, bringing convenience to the replacement work, and ensuring the normal operation of the electrolysis in the electrolytic process by completing the self cleaning of the electrolytic mechanisms.
Drawings
FIG. 1 is a schematic view of the overall structure of the present invention;
FIG. 2 is a schematic view of a second view angle structure of the present invention;
FIG. 3 is an enlarged schematic view at A in FIG. 2;
FIG. 4 is a schematic view showing the positional relationship between the bracket and the latch according to the present invention;
FIG. 5 is a schematic illustration of the operational relationship of a purge ring and a collection ring in accordance with the present invention;
FIG. 6 is a schematic view of the positional relationship between the stopper and the guide rod according to the present invention.
In the figure: 1. a turntable; 2. a motor; 3. a bracket; 4. a guide rod; 5. an electrode; 6. a return spring; 7. a pressure sensing unit; 8. a first spring; 9. cleaning the ring; 10. a second spring; 11. a clamping block; 12. a magnetic block; 13. a collection ring; 14. a collection tank; 15. a storage tank; 16. and a limiting body.
Detailed Description
The following detailed description of the present application is provided in conjunction with the accompanying drawings, and it is to be understood that the following detailed description is merely illustrative of the application and is not to be construed as limiting the scope of the application, since numerous insubstantial modifications and adaptations of the application will be to those skilled in the art in light of the foregoing disclosure.
Example 1
As shown in fig. 1-6, an electrolytic treatment device for high-salt organic wastewater comprises a rotary table 1, wherein a motor 2 for driving the rotary table 1 to rotate is arranged on the rotary table 1, more than two electrolytic mechanisms are equidistantly arranged on the rotary table 1 along the circumferential direction of the rotary table 1, and one group of electrolytic mechanisms is positioned below the rotary table 1 and positioned in the wastewater;
the electrolysis mechanism comprises a bracket 3 and a guide rod 4 which are arranged on the turntable 1, an electrode 5 which slides along the length direction of the guide rod 4 is arranged at one end of the guide rod 4, which is far away from the turntable 1, a reset spring 6 which drives the electrode 5 to move is arranged at one end of the electrode 5, which is far away from the turntable 1, a pressure sensing unit 7 which detects the weight of the electrode 5 is arranged at one end of the reset spring 6, which is far away from the turntable 1, and the pressure sensing unit 7 is arranged on the bracket 3;
the turntable 1 is provided with a controller, and the controller is configured to:
the controller receives the weight value of the electrode 5 sent by the pressure sensing unit 7 and compares the weight value with a set reference value, and when the weight value of the electrode 5 is lower than the reference value, the motor 2 is controlled to start, so that the motor 2 drives the adjacent electrolysis mechanism to be immersed into the wastewater and reach the working position, and then the motor 2 stops working.
In the above embodiment, the motor 2 is fixed above the electrolytic cell, and the turntable 1 is rotatably installed above the electrolytic cell, so that the turntable 1 can be normally rotated. In the electrolysis process, the lowest group of electrolysis mechanisms is positioned in the wastewater, and the rest electrolysis mechanisms are positioned above the wastewater. During electrolysis, current is generated at the electrode 5, and the strong current enables toxic and harmful substances to undergo oxidation-reduction reaction, so that pollutants in water are removed, and COD in the wastewater can be effectively reduced by an electrolysis method. In the electrolysis process, the electrode 5 gradually corrodes, so that the weight of the electrode 5 is reduced, the extrusion force applied to the return spring 6 is reduced, the return spring 6 drives the electrode 5 to move upwards, and meanwhile, the weight value of the electrode 5 measured by the pressure sensing unit 7 is reduced. When the electrode 5 corrodes to a certain extent and reaches a set value for replacement, the pressure sensing unit 7 reaches a set value for measurement, at the moment, the pressure sensing unit 7 sends a signal to the controller, and the controller controls the motor 2 to start, so that the motor 2 drives the turntable 1 to rotate, a next group of electrolysis mechanisms can be replaced to enter the wastewater, and the used electrolysis mechanisms rotate to the water until the plurality of electrolysis mechanisms are uniformly replaced after being used.
As a further scheme of the invention, the electrolysis mechanism further comprises more than two first springs 8 arranged on the turntable 1, a cleaning ring 9 for cleaning the electrode 5 is fixed at one end of each first spring 8 far away from the turntable 1, a mounting groove is formed in the bracket 3, a second spring 10 is arranged in the mounting groove, a clamping block 11 with magnetism for controlling the position of the cleaning ring 9 is arranged on the second spring 10, and a magnetic block 12 with the same magnetism as the clamping block 11 and used for changing the position of the clamping block 11 is arranged on the electrode 5.
In the above embodiment, the electrode 5 will corrode during the working process, so that the electrode 5 moves upwards along the guide rod 4, and when the electrode 5 moves to the set position, the repulsive force applied by the magnetic block 12 on the electrode 5 to the clamping block 11 makes the clamping block 11 enter the mounting groove, so that the first spring 8 is in a free state. The first spring 8 drives the cleaning ring 9 to move downwards rapidly, and the surface of the electrode 5 is cleaned in the moving process of the cleaning ring 9. The cleaning ring 9 is in contact with the surface of the electrode 5 through the inner side wall with soft property, and can clean the surface of the electrode 5 under the condition that the diameter of the surface of the electrode 5 is uneven, and the accumulated adhesion objects on the surface of the electrode 5 are scraped off.
As a further scheme of the invention, a collecting ring 13 which corresponds to the cleaning ring 9 and is used for scraping suspended matters on the surface of the electrode 5 is arranged on the support 3, and a collecting groove 14 for collecting the suspended matters is arranged on one side, close to the turntable 1, of the collecting ring 13.
As a further scheme of the invention, a storage tank 15 for temporarily storing suspended matters is arranged on one side of the cleaning ring 9 away from the turntable 1, and the storage tank 15 is C-shaped.
In the above embodiment, when the cleaning ring 9 passes through the electrode 5 and is located at one side of the return spring 6, the cleaning ring 9 contacts with the collecting ring 13 at this time, and the suspended matters collected on the surface of the cleaning ring 9 enter into the collecting groove 14 of the collecting ring 13 to be temporarily stored, so as to avoid the suspended matters from re-entering into the waste water to pollute the waste water. The cleaning ring 9 and the collecting ring 13 can be made of magnetic materials with different magnetic properties, so that the cleaning ring and the collecting ring are tightly attached to each other, and suspended matters are prevented from entering wastewater.
Wherein, clearance ring 9 probably causes the suspended solid to scatter in the removal in-process and gets into waste water, through being provided with stock chest 15, the suspended solid that scrapes from electrode 5 gets into stock chest 15 and temporarily stores, and the C font structure of stock chest 15 can effectively prevent the scatter of suspended solid to reduce the quantity of suspended solid in the waste water.
As a further scheme of the invention, a hole is arranged on the guide rod 4, and a limiting body 16 for limiting the movement of the electrode 5 is arranged at the hole.
As a further aspect of the present invention, the limiting body 16 is sucrose or sodium chloride.
In the above embodiment, the electrode 5 above the wastewater may pull the pressure sensing unit 7 under the action of gravity, so that the pressure sensing unit 7 generates an alarm to send a signal by mistake, although whether the trigger is normal or false can be judged by adjusting the holding time of the pressure measured by the pressure sensing unit 7, and avoiding the occurrence of the problem ensures that the invention can complete the work better. By arranging the limiting body 16 made of sucrose or sodium chloride to be plugged into the hole, the movement of the electrode 5 is blocked, and the electrode 5 which does not enter the wastewater cannot move, so that false alarm is avoided. When the electrolysis mechanism enters the waste water, the limiting body 16 also synchronously enters the water, and the limiting body 16 is made of a material which is easy to dissolve in the water, so that the limiting body 16 is quickly dissolved in the water after entering the waste water, and the electrode 5 is restored to the movable state, thereby ensuring the normal use of the electrode 5 and avoiding the occurrence of false alarm.
The electrolytic treatment method for the high-salt organic wastewater by adopting the electrolytic treatment device for the high-salt organic wastewater is characterized by comprising the following steps of:
s1: performing primary filtration on the high-salt organic wastewater to remove large-particle suspended matters in the wastewater;
s2: pumping the wastewater subjected to primary filtration into an electrolytic cell, and erecting an electrolytic treatment device so that one of electrolytic mechanisms of the electrolytic treatment device is positioned in the wastewater; the electrode 5 is divided into an anode and a cathode, and one end of the electrode 5 which is easily corroded may be provided as the electrolytic processing device in the present invention, or both ends may be provided as the electrolytic processing device in the present invention.
S3: the electrode 5 is gradually corroded in the use process of the electrolytic treatment device, the electrode 5 is driven by the reset spring 6 to be close to the rotary table 1, the total weight of the electrode 5 is reduced under the corrosion condition, the pressure sensing unit 7 triggers the controller after the weight of the electrode 5 is measured to be lower than a reference value, the controller controls the motor 2 to start, and the motor 2 drives the rotary table 1 to rotate, so that the adjacent electrolytic mechanism rotates to a working position in wastewater; during electrolysis, current is generated at the electrode 5, and the strong current enables toxic and harmful substances to undergo oxidation-reduction reaction, so that pollutants in water are removed, and COD in the wastewater can be effectively reduced by an electrolysis method. In the electrolysis process, the electrode 5 gradually corrodes, so that the weight of the electrode 5 is reduced, the extrusion force applied to the return spring 6 is reduced, the return spring 6 drives the electrode 5 to move upwards, and meanwhile, the weight value of the electrode 5 measured by the pressure sensing unit 7 is reduced. When the electrode 5 corrodes to a certain extent and reaches a set value for replacement, the pressure sensing unit 7 reaches a set value for measurement, at the moment, the pressure sensing unit 7 sends a signal to the controller, and the controller controls the motor 2 to start, so that the motor 2 drives the turntable 1 to rotate, a next group of electrolysis mechanisms can be replaced to enter the wastewater, and the used electrolysis mechanisms rotate to the water until the plurality of electrolysis mechanisms are uniformly replaced after being used.
S4: and (3) carrying out secondary filtration on the electrolyzed sewage to remove suspended matters in the sewage, thereby obtaining clarified wastewater.
The foregoing examples illustrate only a few embodiments of the invention and are described in detail herein without thereby limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention.

Claims (7)

1. An electrolytic treatment device for high-salt organic wastewater, which is characterized in that: the device comprises a rotary table (1), wherein a motor (2) for driving the rotary table (1) to rotate is arranged on the rotary table (1), more than two electrolysis mechanisms are equidistantly arranged on the rotary table (1) along the circumferential direction of the rotary table, and one group of electrolysis mechanisms is positioned below the rotary table (1) and positioned in wastewater;
the electrolysis mechanism comprises a support (3) and a guide rod (4) which are arranged on the turntable (1), one end, far away from the turntable (1), of the guide rod (4) is provided with an electrode (5) sliding along the length direction of the guide rod (4), one end, far away from the turntable (1), of the electrode (5) is provided with a reset spring (6) for driving the electrode (5) to move, one end, far away from the turntable (1), of the reset spring (6) is provided with a pressure sensing unit (7) for detecting the weight of the electrode (5), and the pressure sensing unit (7) is arranged on the support (3);
the turntable (1) is provided with a controller, and the controller is configured to:
the controller receives the weight value of the electrode (5) sent by the pressure sensing unit (7) and compares the weight value with a set reference value, and when the weight value of the electrode (5) is lower than the reference value, the motor (2) is controlled to start, so that the motor (2) drives the adjacent electrolysis mechanism to be immersed in the wastewater and reach the working position, and then the motor (2) is stopped.
2. The electrolytic processing device for high-salt organic wastewater according to claim 1, wherein: the electrolysis mechanism further comprises more than two springs (8) arranged on the rotary table (1), two cleaning rings (9) for cleaning the electrodes (5) are fixed at one ends, far away from the rotary table (1), of the springs (8), mounting grooves are formed in the support (3), springs (10) are arranged in the mounting grooves, clamping blocks (11) with magnetism for controlling the positions of the cleaning rings (9) are arranged on the springs (10), and magnetic blocks (12) with the same magnetism as the clamping blocks (11) and used for changing the positions of the clamping blocks (11) are arranged on the electrodes (5).
3. The electrolytic processing device for high-salt organic wastewater according to claim 2, wherein: the support (3) is provided with a collecting ring (13) which corresponds to the cleaning ring (9) and is used for scraping suspended matters on the surface of the electrode (5), and one side, close to the turntable (1), of the collecting ring (13) is provided with a collecting groove (14) for collecting the suspended matters.
4. An electrolytic processing device for high-salt organic wastewater according to claim 3, wherein: one side of the cleaning ring (9) far away from the turntable (1) is provided with a storage tank (15) for temporarily storing suspended matters, and the storage tank (15) is C-shaped.
5. The electrolytic processing device for high-salt organic wastewater according to claim 1, wherein: the guide rod (4) is provided with a hole, and a limiting body (16) for limiting the movement of the electrode (5) is arranged at the hole.
6. The electrolytic processing device for high-salt organic wastewater according to claim 5, wherein: the limiting body (16) is sucrose or sodium chloride.
7. A method for electrolytic treatment of high-salt organic wastewater by using the electrolytic treatment apparatus for high-salt organic wastewater according to any one of claims 1 to 6, comprising the steps of:
s1: performing primary filtration on the high-salt organic wastewater to remove large-particle suspended matters in the wastewater;
s2: pumping the wastewater subjected to primary filtration into an electrolytic cell, and erecting an electrolytic treatment device so that one of electrolytic mechanisms of the electrolytic treatment device is positioned in the wastewater;
s3: in the use process of the electrolytic treatment device, an electrode (5) is gradually corroded, the electrode (5) is driven by a reset spring (6) to approach a rotary table (1), the total weight of the electrode (5) is reduced under the corrosion condition, a pressure sensing unit (7) triggers a controller after the weight of the electrode (5) is measured to be lower than a reference value, the controller controls a motor (2) to start, and the motor (2) drives the rotary table (1) to rotate, so that adjacent electrolytic mechanisms rotate to a working position in waste water;
s4: and (3) carrying out secondary filtration on the electrolyzed sewage to remove suspended matters in the sewage, thereby obtaining clarified wastewater.
CN202310204237.0A 2023-02-28 2023-02-28 Electrolytic treatment device and method for high-salt organic wastewater Active CN116143245B (en)

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CN117303676A (en) * 2023-11-28 2023-12-29 河南省厚朴环保科技有限公司 Electrolytic sewage treatment system capable of automatically replacing electrode

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CN117303676A (en) * 2023-11-28 2023-12-29 河南省厚朴环保科技有限公司 Electrolytic sewage treatment system capable of automatically replacing electrode
CN117303676B (en) * 2023-11-28 2024-02-13 河南省厚朴环保科技有限公司 Electrolytic sewage treatment system capable of automatically replacing electrode

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