CN116087845A - A three-dimensional distribution measurement method of electron spin polarizability based on electron paramagnetic resonance - Google Patents
A three-dimensional distribution measurement method of electron spin polarizability based on electron paramagnetic resonance Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及一种基于电子顺磁共振的电子自旋极化率三维分布测量方法,属于光抽运原子极化领域。The invention relates to a method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance, which belongs to the field of optically pumped atomic polarization.
背景技术Background technique
基于光抽运原子极化的原子磁强计、原子陀螺和原子钟等器件的敏感元件是碱金属气室。由于碱金属对抽运光的吸收,其电子自旋极化率存在严重的梯度,对电子自旋与核自旋的相干性造成极大的影响。准确地测量电子极化率的三维分布成为了亟待解决的问题。The sensitive elements of devices such as atomic magnetometers, atomic gyroscopes, and atomic clocks based on optically pumped atomic polarization are alkali metal gas cells. Due to the absorption of pumping light by alkali metals, there is a serious gradient in electron spin polarizability, which greatly affects the coherence between electron spin and nuclear spin. Accurately measuring the three-dimensional distribution of electronic polarizability has become an urgent problem to be solved.
目前大多数的电子极化率三维分布研究为基于Bloch-Diffusion方程的有限元仿真,该仿真结果严重依赖预设参数,不真实的预设参数会产生迥异的仿真结果。有研究采用抽运光的透射率反应纵向极化率分布,但这种方法无法精确测量极化率的横向分布情况。先前电子顺磁共振测量电子自旋极化的研究中,依赖大磁场产生能级劈裂并对原子布局数进行测量,该方案对于高温度、高气压的原子气室存在测量缺陷。At present, most of the studies on the three-dimensional distribution of electronic susceptibility are finite element simulations based on the Bloch-Diffusion equation. The simulation results are heavily dependent on preset parameters, and untrue preset parameters will produce very different simulation results. Some studies use the transmittance of the pumping light to reflect the longitudinal polarizability distribution, but this method cannot accurately measure the lateral distribution of the polarizability. In the previous research on the measurement of electron spin polarization by electron paramagnetic resonance, a large magnetic field was relied on to generate energy level splitting and measure the number of atomic layouts. This scheme has measurement defects for atomic gas chambers with high temperature and high pressure.
发明内容Contents of the invention
本发明解决的问题是:本发明提出了一种基于电子顺磁共振的电子自旋极化率三维分布测量方法,使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分,在x方向施加振荡磁场与电子自旋发生电子顺磁共振,改变纵向匀强磁场的大小,使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的相对极化率大小成正比,通过测量不同空间位置的共振信号反应电子自旋极化率的三维分布,不用施加高斯量级的大磁场使原子能级产生劈裂,有利于测量高温度、大压强下的电子自旋极化率三维分布。The problem solved by the present invention is: the present invention proposes a method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance. To distinguish, apply an oscillating magnetic field in the x direction and electron paramagnetic resonance occurs with the electron spin, change the size of the longitudinal uniform magnetic field, and make the electron spin at different positions from the x axis resonate with the oscillating magnetic field, and the amplitude of the optical rotation angle of the resonance signal It is proportional to the relative polarizability of the resonance point. By measuring the resonance signals at different spatial positions, it reflects the three-dimensional distribution of electron spin polarizability. It does not need to apply a large Gaussian magnetic field to split the atomic energy level, which is conducive to the measurement of high Three-dimensional distribution of electron spin polarizability under temperature and high pressure.
本发明的技术解决方案如下:Technical solution of the present invention is as follows:
基于电子顺磁共振的电子自旋极化率三维分布测量方法,其特征在于,使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分,在x方向施加振荡磁场与电子自旋发生电子顺磁共振,改变纵向匀强磁场的大小,使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的相对极化率大小成正比,通过测量不同空间位置的共振信号反应电子自旋极化率的三维分布。本方法的空间分辨力小于1mm3。The method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance is characterized in that the transverse distribution of electron spin polarizability is distinguished by using a longitudinal uniform magnetic field coil and a longitudinal gradient magnetic field coil, and an oscillating magnetic field is applied in the x direction Electron paramagnetic resonance occurs with the electron spin, changing the size of the longitudinal uniform magnetic field, so that the electron spin at different positions from the x-axis resonates with the oscillating magnetic field, and the amplitude of the resonance signal optical rotation angle and the relative polarizability of the resonance point In direct proportion, the three-dimensional distribution of electron spin polarizability is reflected by measuring the resonance signals at different spatial positions. The spatial resolution of the method is less than 1 mm 3 .
包括以下步骤:Include the following steps:
步骤1,在垂直于探测光方向的z轴方向施加偏置磁场Bz0与梯度磁场Bz梯度,dBz梯度/dx=k,其中k为磁场梯度,总梯度磁场为Bz(x)=Bz0+Bz梯度(x),x轴方向上即探测光方向上分布的电子自旋进动频率为ωspin(x)=γe(Bz0+kx)/q,其中q为电子自旋系综减慢因子,γe为电子自旋系综旋磁比;Step 1, apply the bias magnetic field B z0 and the gradient magnetic field B z gradient in the z-axis direction perpendicular to the direction of the probe light, dB z gradient /dx=k, where k is the magnetic field gradient, and the total gradient magnetic field is B z (x)= B z0 + B z gradient (x), the electron spin precession frequency distributed in the x-axis direction, that is, the detection light direction is ω spin (x) = γ e (B z0 + kx)/q, where q is the electron spin spin ensemble slowing down factor, γ e is the gyromagnetic ratio of electron spin ensemble;
步骤2,测量探测光的透射光强;Step 2, measuring the transmitted light intensity of the probe light;
步骤3,x方向施加振荡磁场与电子自旋产生共振;Step 3, applying an oscillating magnetic field in the x direction to resonate with the electron spin;
步骤4,改变Bz0的磁场强度值,使电子自旋的共振平面沿碱金属气室x方向从一侧移动到另一侧,电子自旋共振点x=(ωq/γe-Bz0)/k,其中ω为x方向振荡磁场的频率,记录各共振点的共振强度,共振强度与电子自旋极化率成正比;Step 4, change the magnetic field strength value of B z0 , so that the resonance plane of the electron spin moves from one side to the other side along the x direction of the alkali metal gas chamber, and the electron spin resonance point x=(ωq/γ e -B z0 ) /k, where ω is the frequency of the oscillating magnetic field in the x direction, and the resonance strength of each resonance point is recorded, and the resonance strength is proportional to the electron spin polarizability;
步骤5,改变探测光在yoz平面上的位置,重复测试透射光强和共振强度;Step 5, changing the position of the probe light on the yoz plane, and repeatedly testing the transmitted light intensity and resonance intensity;
步骤6,各位置的共振强度除以探测光透射光强,得到电子自旋极化率的三维分布。In step 6, the resonance intensity at each position is divided by the transmitted light intensity of the probe light to obtain the three-dimensional distribution of electron spin polarizability.
所述步骤1中偏置磁场为直流匀强磁场。The bias magnetic field in the step 1 is a DC uniform magnetic field.
所述步骤2中包括在采用平衡差分法测量旋光角的过程中,输出信号与旋光角或透射光强成正比,为保证在不同测量位置的旋光角有可比性,首先对探测光的透射光强进行测量,为后期对输出信号做归一化。The step 2 includes that in the process of measuring the optical rotation angle by the balanced difference method, the output signal is proportional to the optical rotation angle or the transmitted light intensity. In order to ensure that the optical rotation angles at different measurement positions are comparable, firstly, the transmitted light of the probe light Strongly measure and normalize the output signal for the later stage.
所述步骤3中施加振荡磁场的振荡频率在γeBz0/q附近,以便于与电子自旋产生共振。The oscillating frequency of the oscillating magnetic field applied in step 3 is around γ e B z0 /q, so as to resonate with electron spins.
所述步骤4中的共振强度由锁相放大器解调输出信号得到。The resonance strength in step 4 is obtained by demodulating the output signal of the lock-in amplifier.
所述步骤2中包括通过下式提取电子自旋系综极化率x轴分量信息<Px>:The step 2 includes extracting the electron spin ensemble polarizability x-axis component information <P x > by the following formula:
其中<Sx>表示探测光探测到的旋光角信号,I为透射光强,a为常值比例系数,l为碱金属气室内部空间在x轴上的宽度。Where <S x > represents the optical rotation angle signal detected by the probe light, I is the transmitted light intensity, a is a constant proportional coefficient, and l is the width of the inner space of the alkali metal gas chamber on the x-axis.
所述透射光强的测量装置包括偏振分光棱镜,所述偏振分光棱镜的输入侧连接穿越碱金属气室的透射光,所述偏振分光棱镜的反射侧通过第一光电探测器连接差分放大器的负向输入端,所述偏振分光棱镜的透射侧连接差分放大器的正向输入端,所述差分放大器的输出端连接数据采集系统。The measuring device of the transmitted light intensity comprises a polarizing beam splitting prism, the input side of the polarizing beam splitting prism is connected to the transmitted light passing through the alkali metal gas chamber, and the reflection side of the polarizing beam splitting prism is connected to the negative side of the differential amplifier through the first photodetector. To the input end, the transmission side of the polarization splitter prism is connected to the positive input end of the differential amplifier, and the output end of the differential amplifier is connected to the data acquisition system.
本发明的技术效果如下:本发明基于电子顺磁共振的电子自旋极化率三维分布测量方法,基于电子自旋在不同的纵向磁场下进动频率不同,故使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分,在x方向施加振荡磁场,其振荡频率应接近电子自旋的拉莫尔进动频率,改变纵向匀强磁场的大小,可以使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的电子自旋极化率大小成正比,以此方法可以测量横向极化率的三维分布。改变探测光在yoz平面入射的位置进行重复测试,可测得原子气室内电子自旋的极化率三维分布情况。本方法可用于光泵磁强计、SERF原子陀螺仪、光抽运原子钟等系统原子蒸气电子自旋极化率三维分布研究。The technical effect of the present invention is as follows: the present invention is based on the electron paramagnetic resonance three-dimensional distribution measurement method of electron spin polarizability, based on the fact that electron spins have different precession frequencies under different longitudinal magnetic fields, so the use of longitudinal uniform magnetic field coils and longitudinal gradient The magnetic field coil distinguishes the lateral distribution of the electron spin polarizability, and applies an oscillating magnetic field in the x direction. The oscillation frequency should be close to the Larmor precession frequency of the electron spin. Changing the size of the longitudinal uniform magnetic field can make the distance x The electron spins at different positions on the axis resonate with the oscillating magnetic field, and the amplitude of the optical rotation angle of the resonance signal is proportional to the electron spin polarizability at the resonance point. This method can measure the three-dimensional distribution of the transverse polarizability. The three-dimensional distribution of the polarizability of the electron spin in the atomic gas chamber can be measured by changing the incident position of the probe light on the yoz plane and repeating the test. This method can be used to study the three-dimensional distribution of spin polarizability of atomic vapor electrons in systems such as optically pumped magnetometers, SERF atomic gyroscopes, and optically pumped atomic clocks.
本发明与现有技术相比的优点在于:使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分,能够测量横向极化率分布。采用磁场调制后的平衡差分的旋光角检测方案,相对于光吸收的检测方案有更高的信噪比。不用施加高斯量级的大磁场使原子能级产生劈裂,可以测量高温度、大压强下的电子自旋极化率三维分布。Compared with the prior art, the present invention has the advantages that the transverse distribution of electron spin polarizability is distinguished by using the longitudinal uniform magnetic field coil and the longitudinal gradient magnetic field coil, and the transverse polarizability distribution can be measured. The optical rotation angle detection scheme using the balanced differential after magnetic field modulation has a higher signal-to-noise ratio than the light absorption detection scheme. The three-dimensional distribution of electron spin polarizability at high temperature and high pressure can be measured without applying a large Gaussian magnetic field to split the atomic energy level.
附图说明Description of drawings
图1是实施本发明基于电子顺磁共振的电子自旋极化率三维分布测量方法的流程示意图。图1中包括步骤1,z方向施加梯度磁场与直流磁场;步骤2,测量探测光的透射光强;步骤3,x方向施加振荡磁场与电子自旋产生共振;步骤4,改变直流匀强磁场的强度,使电子自旋的共振平面沿气室x方向从一侧移动到另一侧,记录各共振点的共振强度;步骤5,改变探测光在yoz平面上的位置,重复测试透射光强和共振强度;步骤6,各位置的共振强度除以探测光透射光强,得到电子自旋极化率的三维分布。Fig. 1 is a schematic flowchart of implementing the method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance according to the present invention. Figure 1 includes step 1, applying a gradient magnetic field and a DC magnetic field in the z direction; step 2, measuring the transmitted light intensity of the probe light; step 3, applying an oscillating magnetic field in the x direction to resonate with the electron spin; step 4, changing the DC uniform magnetic field Intensity, so that the resonance plane of the electron spin moves from one side to the other along the x direction of the gas cell, and record the resonance intensity of each resonance point; step 5, change the position of the probe light on the yoz plane, and repeat the test of the transmitted light intensity and resonance intensity; step 6, dividing the resonance intensity at each position by the transmitted light intensity of the probe light to obtain the three-dimensional distribution of electron spin polarizability.
图2是基于电子顺磁共振的电子自旋极化率三维分布测量装置原理示意图。图2中包括沿x轴的共振磁场,沿z轴的梯度磁场Bz,沿x方向极化率分布,抽运光束和探测光束,在笛卡尔坐标系中,抽运光入射方向与z轴平行,探测光入射方向与x轴平行。图2中包括PBS(polarization beam splitter,偏振分光棱镜),两个PD(Photodetector,光电探测器),差分放大器,和数据采集系统。Fig. 2 is a schematic diagram of the principle of a three-dimensional distribution measurement device for electron spin polarizability based on electron paramagnetic resonance. Figure 2 includes the resonant magnetic field along the x-axis, the gradient magnetic field Bz along the z-axis, the polarizability distribution along the x-direction, the pumping beam and the detection beam. In the Cartesian coordinate system, the incident direction of the pumping light is parallel to the z-axis , the incident direction of the probe light is parallel to the x-axis. Figure 2 includes PBS (polarization beam splitter, polarization beam splitter), two PDs (Photodetector, photodetector), differential amplifier, and data acquisition system.
具体实施方式Detailed ways
下面结合附图(图1-图2)和实施例对本发明进行说明。The present invention will be described below in conjunction with the accompanying drawings (FIG. 1-FIG. 2) and embodiments.
图1是实施本发明基于电子顺磁共振的电子自旋极化率三维分布测量方法的流程示意图。图2是基于电子顺磁共振的电子自旋极化率三维分布测量装置原理示意图。参考图1至图2所示,基于电子顺磁共振的电子自旋极化率三维分布测量方法,使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分,在x方向施加振荡磁场与电子自旋发生电子顺磁共振,改变纵向匀强磁场的大小,使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的相对极化率大小成正比,通过测量不同空间位置的共振信号反应电子自旋极化率的三维分布。空间分辨力小于1mm3。Fig. 1 is a schematic flowchart of implementing the method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance according to the present invention. Fig. 2 is a schematic diagram of the principle of a three-dimensional distribution measurement device for electron spin polarizability based on electron paramagnetic resonance. Referring to Figures 1 to 2, the method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance uses longitudinal uniform magnetic field coils and longitudinal gradient magnetic field coils to distinguish the lateral distribution of electron spin polarizability. When an oscillating magnetic field is applied in the x direction, electron paramagnetic resonance occurs with the electron spin, and the size of the longitudinal uniform magnetic field is changed, so that the electron spin at different positions from the x axis resonates with the oscillating magnetic field, and the amplitude of the optical rotation angle of the resonance signal is related to the resonance point. The relative polarizability is proportional to the size, and the three-dimensional distribution of electron spin polarizability is reflected by measuring the resonance signals at different spatial positions. The spatial resolution is less than 1mm 3 .
包括以下步骤:步骤1,在垂直于探测光方向的z轴方向施加偏置磁场Bz0与梯度磁场Bz梯度,dBz梯度/dx=k,其中k为磁场梯度,总梯度磁场为Bz(x)=Bz0+Bz梯度(x),x轴方向上即探测光方向上分布的电子自旋进动频率为ωspin(x)=γe(Bz0+kx)/q,其中q为电子自旋系综减慢因子,γe为电子自旋系综旋磁比;步骤2,测量探测光的透射光强;步骤3,x方向施加振荡磁场与电子自旋产生共振;步骤4,改变Bz0的磁场强度值,使电子自旋的共振平面沿碱金属气室x方向从一侧移动到另一侧,电子自旋共振点x=(ωq/γe-Bz0)/k,其中ω为x方向振荡磁场的频率,记录各共振点的共振强度,共振强度与电子自旋极化率成正比;步骤5,改变探测光在yoz平面上的位置,重复测试透射光强和共振强度;步骤6,各位置的共振强度除以探测光透射光强,得到电子自旋极化率的三维分布。Including the following steps: Step 1, applying a bias magnetic field B z0 and a gradient magnetic field B z gradient in the z-axis direction perpendicular to the direction of the probe light, dB z gradient /dx=k, where k is the magnetic field gradient, and the total gradient magnetic field is B z (x) = B z0 + B z gradient (x), the electron spin precession frequency distributed in the x-axis direction, that is, the probe light direction is ω spin (x) = γ e (B z0 + kx)/q, where q is the slowing down factor of the electron spin ensemble, and γ e is the gyromagnetic ratio of the electron spin ensemble; step 2, measuring the transmitted light intensity of the probe light; step 3, applying an oscillating magnetic field in the x direction to generate resonance with the electron spin; step 4. Change the magnetic field strength value of B z0 , so that the resonance plane of the electron spin moves from one side to the other side along the x direction of the alkali metal gas chamber, and the electron spin resonance point x=(ωq/γ e -B z0 )/ k, where ω is the frequency of the oscillating magnetic field in the x direction, record the resonance strength of each resonance point, and the resonance strength is proportional to the electron spin polarizability; step 5, change the position of the probe light on the yoz plane, and repeat the test of the transmitted light intensity and resonance intensity; step 6, dividing the resonance intensity at each position by the transmitted light intensity of the probe light to obtain the three-dimensional distribution of electron spin polarizability.
所述步骤1中偏置磁场为直流匀强磁场。所述步骤2中包括在采用平衡差分法测量旋光角的过程中,输出信号与旋光角或透射光强成正比,为保证在不同测量位置的旋光角有可比性,首先对探测光的透射光强进行测量,为后期对输出信号做归一化。所述步骤3中施加振荡磁场的振荡频率在γeBz0/q附近,以便于与电子自旋产生共振。所述步骤4中的共振强度由锁相放大器解调输出信号得到。The bias magnetic field in the step 1 is a DC uniform magnetic field. The step 2 includes that in the process of measuring the optical rotation angle by the balanced difference method, the output signal is proportional to the optical rotation angle or the transmitted light intensity. In order to ensure that the optical rotation angles at different measurement positions are comparable, firstly, the transmitted light of the probe light Strongly measure and normalize the output signal for the later stage. The oscillating frequency of the oscillating magnetic field applied in step 3 is around γ e B z0 /q, so as to resonate with electron spins. The resonance strength in step 4 is obtained by demodulating the output signal of the lock-in amplifier.
所述步骤2中包括通过下式提取电子自旋系综极化率x轴分量信息<Px>:The step 2 includes extracting the electron spin ensemble polarizability x-axis component information <P x > by the following formula:
其中<Sx>表示探测光探测到的旋光角信号,I为透射光强,a为常值比例系数,l为碱金属气室内部空间在x轴上的宽度。所述透射光强的测量装置包括偏振分光棱镜,所述偏振分光棱镜的输入侧连接穿越碱金属气室的透射光,所述偏振分光棱镜的反射侧通过第一光电探测器连接差分放大器的负向输入端,所述偏振分光棱镜的透射侧连接差分放大器的正向输入端,所述差分放大器的输出端连接数据采集系统。Where <S x > represents the optical rotation angle signal detected by the probe light, I is the transmitted light intensity, a is a constant proportional coefficient, and l is the width of the inner space of the alkali metal gas chamber on the x-axis. The measuring device of the transmitted light intensity includes a polarizing beam splitting prism, the input side of the polarizing beam splitting prism is connected to the transmitted light passing through the alkali metal gas chamber, and the reflection side of the polarizing beam splitting prism is connected to the negative side of the differential amplifier through the first photodetector. To the input end, the transmission side of the polarization splitter prism is connected to the positive input end of the differential amplifier, and the output end of the differential amplifier is connected to the data acquisition system.
本发明提出了基于电子顺磁共振的电子自旋极化率三维分布测量方法。使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分。在x方向施加振荡磁场与电子自旋发生电子顺磁共振。改变纵向匀强磁场的大小,使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的相对极化率大小成正比。通过测量不同空间位置的共振信号反应电子自旋极化率的三维分布。The invention proposes a method for measuring the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance. The lateral distribution of electron spin polarizability is differentiated using longitudinal uniform magnetic field coils and longitudinal gradient magnetic field coils. An oscillating magnetic field is applied in the x-direction to undergo electron paramagnetic resonance with electron spins. Changing the size of the longitudinal uniform magnetic field makes the electron spins at different positions away from the x-axis resonate with the oscillating magnetic field, and the amplitude of the optical rotation angle of the resonance signal is proportional to the relative polarizability of the resonance point. The three-dimensional distribution of electron spin polarizability is reflected by measuring resonance signals at different spatial positions.
基于电子顺磁共振的电子自旋极化率三维分布测量原理与坐标系设置如下图2。光抽运原子极化、原子在外磁场下拉莫尔进动的动力学方程可以用下Bloch方程近似描述:The measurement principle and coordinate system setting of the three-dimensional distribution of electron spin polarizability based on electron paramagnetic resonance are shown in Figure 2. The kinetic equations of atomic polarization pumped by light and Larmor precession of atoms in an external magnetic field can be approximately described by the following Bloch equation:
在图2的笛卡尔坐标系中,抽运光方向入射方向与z轴平行,探测光入射方向与x轴平行;t为时间;电子自旋系综极化<P>=<Px,Py,Pz>,其中Px,Py,Pz为电子极化率的三个坐标轴分量;γe是电子自旋系综旋磁比;q为电子自旋系综减慢因子;脉冲激光的抽运率R;外磁场B=<Bx(t),By(t),Bz(t)>及其三轴分量Bx(t),By(t),Bz(t);为了描述原子纵向和横向极化率的弛豫过程,引入电子自旋的纵向弛豫率Γ1、横向弛豫率Γ2。该方程描述了电子自旋系综在光抽运、原子弛豫、磁场中拉莫尔进动下的动力学演化过程。In the Cartesian coordinate system in Figure 2, the incident direction of the pumping light is parallel to the z-axis, and the incident direction of the probe light is parallel to the x-axis; t is time; electron spin ensemble polarization <P>=<P x ,P y , P z >, where P x , P y , P z are the three coordinate axis components of electron polarizability; γ e is the gyromagnetic ratio of electron spin ensemble; q is the slowing down factor of electron spin ensemble; The pumping rate R of the pulsed laser; the external magnetic field B=<B x (t),B y (t),B z (t)> and its three-axis components B x (t),B y (t),B z (t); In order to describe the relaxation process of the longitudinal and transverse polarizability of atoms, the longitudinal relaxation rate Γ 1 and the transverse relaxation rate Γ 2 of the electron spin are introduced. This equation describes the dynamical evolution of the electron spin ensemble under light pumping, atomic relaxation, and Larmor precession in a magnetic field.
其中<P±>=<Px>±<Py>,<B±>(t)=<Bx>(t)±<By>(t)。电子自旋的纵向分量为在系统的x轴施加振荡磁场Bx(t)=B1cos(ωt),B1为振荡磁场幅值,ω为振荡磁场角速率,y轴不施加磁场,即By(t)=0,z轴施加直流磁场Bz(t)=Bz0,带入式(2)可得出系统x向极化率的磁场响应<Px>:Where <P ± >=<P x >±<P y >, <B ± >(t)=<B x >(t)±<B y >(t). The longitudinal component of the electron spin is Apply an oscillating magnetic field on the x-axis of the system B x (t) = B 1 cos(ωt), B 1 is the amplitude of the oscillating magnetic field, ω is the angular rate of the oscillating magnetic field, and no magnetic field is applied on the y-axis, that is, By y (t) = 0 , the z-axis applies a DC magnetic field B z (t) = B z0 , which can be inserted into the formula (2) to obtain the magnetic field response <P x > of the x-direction polarizability of the system:
其中当z轴施加的磁场与x轴施加的振荡磁场Bx(t)=B1cos(ωt)共振时,即γeBz0=ωq,共振信号达到最大值:in When the magnetic field applied on the z-axis resonates with the oscillating magnetic field B x (t)=B 1 cos(ωt) applied on the x-axis, that is, γ e B z0 =ωq, the resonance signal reaches its maximum value:
与核磁共振成像的原理类似,通过在磁场Bz上增加空间梯度,可以得到沿探测激光方向的电子自旋极化空间变化信息,如图2所示。在垂直于探测激光方向的z轴施加偏置磁场Bz0与梯度磁场Bz梯度,磁场梯度为dBz梯度/dx=k,则总梯度磁场为Bz(x)=Bz0+Bz梯度(x)。这样的梯度下,x方向上分布的电子自旋进动频率为ωspin(x)=γe(Bz0+kx)/q。保持梯度磁场不变,设置x方向振荡场的频率为ω。此时电子自旋共振点为x=(ωq/γe-Bz0)/k,扫描Bz0的大小使共振点沿着探测激光从原子气室的一侧移动到另一侧。保持施加的磁场不变,在电子自旋与施加振荡磁场产生共振时,<Px>的振荡强度仅与电子自旋的纵向极化率<Pz>0相关且成正比。探测光是一束x轴平行的线偏振光,采用平衡差分的方法可以提取电子自旋的<Px>分量信息:Similar to the principle of nuclear magnetic resonance imaging, by adding a spatial gradient to the magnetic field Bz , the spatial variation information of electron spin polarization along the direction of the probe laser can be obtained, as shown in Figure 2. Apply a bias magnetic field B z0 and a gradient magnetic field B z gradient on the z axis perpendicular to the direction of the detection laser, the magnetic field gradient is dB z gradient /dx=k, then the total gradient magnetic field is B z (x) = B z0 + B z gradient (x). Under such a gradient, the electron spin precession frequency distributed in the x direction is ω spin (x)=γ e (B z0 +kx)/q. Keep the gradient magnetic field unchanged, and set the frequency of the oscillating field in the x direction as ω. At this time, the electron spin resonance point is x=(ωq/γ e -B z0 )/k, and the size of B z0 is scanned to move the resonance point from one side of the atomic gas cell to the other side along the probe laser. Keeping the applied magnetic field constant, when the electron spin resonates with the applied oscillating magnetic field, the oscillation intensity of <P x > is only related to and proportional to the longitudinal polarizability <P z > 0 of the electron spin. The probe light is a beam of linearly polarized light parallel to the x-axis, and the <P x > component information of the electron spin can be extracted by using the balanced difference method:
其中<Sx>表示探测光探测到的旋光角信号,I为投射光强,a为常值比例系数。采用锁相放大技术提取沿探测光方向各共振点的振荡幅值并除以相对应的透射光强I,即得到电子自旋纵向极化率的相对分布。由于探测束的直径只有几毫米或更小,本方法的空间分辨力小于1mm3。Among them, <S x > represents the optical rotation angle signal detected by the probe light, I is the projected light intensity, and a is a constant proportional coefficient. The phase-locked amplification technique is used to extract the oscillation amplitude of each resonance point along the direction of the probe light and divide it by the corresponding transmitted light intensity I to obtain the relative distribution of the longitudinal polarizability of the electron spin. Since the diameter of the probe beam is only a few millimeters or less, the spatial resolution of the method is less than 1 mm 3 .
本方法需要通过6个步骤实现基于电子顺磁共振的电子自旋极化率三维分布测量。This method requires six steps to realize the three-dimensional distribution measurement of electron spin polarizability based on electron paramagnetic resonance.
步骤一:z方向施加梯度磁场与直流磁场Step 1: Apply a gradient magnetic field and a DC magnetic field in the z direction
在垂直于探测激光方向的z轴施加偏置磁场Bz0与梯度磁场Bz梯度,磁场梯度为dBz梯度/dx=k,则总梯度磁场为Bz(x)=Bz0+Bz梯度(x)。这样的梯度下,x方向上分布的电子自旋进动频率为ωspin(x)=γe(Bz0+kx)/q。Apply a bias magnetic field B z0 and a gradient magnetic field B z gradient on the z axis perpendicular to the direction of the detection laser, the magnetic field gradient is dB z gradient /dx=k, then the total gradient magnetic field is B z (x) = B z0 + B z gradient (x). Under such a gradient, the electron spin precession frequency distributed in the x direction is ω spin (x)=γ e (B z0 +kx)/q.
步骤二:测量探测光的透射光强Step 2: Measure the transmitted light intensity of the probe light
在采用平衡差分法测量旋光角的过程中,输出信号与旋光角、透射光强成正比。为保证在不同测量位置的旋光角有可比性,首先对探测光的透射光强进行测量,为后期对输出信号做归一化。In the process of measuring the optical rotation angle by the balanced difference method, the output signal is proportional to the optical rotation angle and the transmitted light intensity. In order to ensure that the optical rotation angles at different measurement positions are comparable, the transmitted light intensity of the probe light is measured first, and the output signal is normalized in the later stage.
步骤三:x方向施加振荡磁场与电子自旋产生共振Step 3: Apply an oscillating magnetic field in the x direction to resonate with the electron spin
施加的振荡频率应在γeBz0/q附近,以便于与电子自旋产生共振。The applied oscillation frequency should be around γ e B z0 /q in order to resonate with electron spins.
步骤四:改变z轴直流匀强磁场的强度,使电子自旋的共振平面沿气室x方向从一侧移动到另一侧,电子自旋共振点为x=(ωq/γe-Bz0)/k。记录各共振点的共振强度。共振强度与电子自旋极化率成正比,该值可由锁相放大器解调输出信号得到。Step 4: Change the intensity of the z-axis DC uniform magnetic field, so that the resonance plane of the electron spin moves from one side to the other side along the x direction of the gas cell, and the electron spin resonance point is x=(ωq/γ e -B z0 )/k. Record the resonance intensity of each resonance point. The resonance strength is proportional to the electron spin polarizability, which can be obtained by demodulating the output signal of the lock-in amplifier.
步骤五:改变探测光在yoz平面上的位置,重复测试透射光强和共振强度Step 5: Change the position of the probe light on the yoz plane, and repeat the test of the transmitted light intensity and resonance intensity
步骤六:各位置的共振强度除以探测光透射光强,得到电子自旋极化率的三维分布。Step 6: The resonance intensity at each position is divided by the transmitted light intensity of the probe light to obtain the three-dimensional distribution of electron spin polarizability.
使用纵向均匀磁场线圈与纵向梯度磁场线圈对电子自旋极化率的横向分布进行区分。在x方向施加振荡磁场,其振荡频率应接近电子自旋的拉莫尔进动频率。改变纵向匀强磁场的大小,使距离x轴不同位置的电子自旋与振荡磁场发生共振,其共振信号旋光角的振幅与共振点的相对极化率大小成正比。通过测量不同空间位置的共振信号可以反应电子自旋极化率的三维分布。The lateral distribution of electron spin polarizability is differentiated using longitudinal uniform magnetic field coils and longitudinal gradient magnetic field coils. Apply an oscillating magnetic field in the x direction, and its oscillation frequency should be close to the Larmor precession frequency of electron spins. Changing the size of the longitudinal uniform magnetic field makes the electron spins at different positions away from the x-axis resonate with the oscillating magnetic field, and the amplitude of the optical rotation angle of the resonance signal is proportional to the relative polarizability of the resonance point. The three-dimensional distribution of electron spin polarizability can be reflected by measuring the resonance signals at different spatial positions.
本发明说明书中未作详细描述的内容属于本领域专业技术人员公知的现有技术。在此指明,以上叙述有助于本领域技术人员理解本发明创造,但并非限制本发明创造的保护范围。任何没有脱离本发明创造实质内容的对以上叙述的等同替换、修饰改进和/或删繁从简而进行的实施,均落入本发明创造的保护范围。The contents not described in detail in the description of the present invention belong to the prior art known to those skilled in the art. It is pointed out here that the above description is helpful for those skilled in the art to understand the present invention, but does not limit the protection scope of the present invention. Any equivalent replacement, modification and improvement and/or simplified implementation of the above descriptions without departing from the essence of the present invention shall fall within the protection scope of the present invention.
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