CN1159474A - Process for degreasing viscosity of fed heavy hydrocarbon and equipment improvement - Google Patents
Process for degreasing viscosity of fed heavy hydrocarbon and equipment improvement Download PDFInfo
- Publication number
- CN1159474A CN1159474A CN96121516.XA CN96121516A CN1159474A CN 1159474 A CN1159474 A CN 1159474A CN 96121516 A CN96121516 A CN 96121516A CN 1159474 A CN1159474 A CN 1159474A
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- Prior art keywords
- ager
- gas
- charging
- hydrocarbon
- viscosity
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- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 37
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 37
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000005238 degreasing Methods 0.000 title 1
- 239000007789 gas Substances 0.000 claims abstract description 49
- 238000005194 fractionation Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000011261 inert gas Substances 0.000 claims abstract 2
- 238000002347 injection Methods 0.000 claims description 17
- 239000007924 injection Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 2
- 238000013022 venting Methods 0.000 claims description 2
- 238000005336 cracking Methods 0.000 abstract description 10
- 238000004821 distillation Methods 0.000 description 9
- 239000003915 liquefied petroleum gas Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000000571 coke Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004323 axial length Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/007—Visbreaking
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
- C10G51/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only
- C10G51/023—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only plural serial stages only only thermal cracking steps
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Carbon And Carbon Compounds (AREA)
- Steroid Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
In a process and apparatus for visbreaking a heavy hydrocarbon feedstock in the liquid state, whereby the feedstock is brought to an appropriate temperature to cause cracking of at least part of the hydrocarbons present, and is then introduced into the bottom of a soaker 3 wherein it travels from bottom to top, and is then discharged from the top of said soaker 3 and directed to a fractionation unit, the improvement wherein a preferably inert gas is injected into the hydrocarbon feedstock inside the soaker 3, in the vicinity of the soaker side walls, at least at the bottom of the soaker 3 and the gas is injected upward along the side walls of the soaker 3 and flows from bottom to top along said walls co-currently with the hydrocarbon feedstock.
Description
The present invention relates to being used to reduce the method for viscosity of heavy hydrocarbon charge and the improvement that equipment is carried out.
As everyone knows, reduction viscosity is meant carries out following processing to heavy hydrocarbon charge, place stove to make it be warming up to the cracking temperature of heavy hydrocarbon this liquid feed and subsequently it is imported the ager that does not carry out other heating, its translational speed causes be enough to make weight molecule that desirable cracking takes place its residence time under described temperature becomes lighter molecule.The cracked effect is to reduce the viscosity of processed charging, and wherein the viscosity reduction is meant a kind of method, and viscosity reduction device is meant a kind of use equipment.
The common cylindrical container of ager does not wherein comprise the additional heating device of charging, and cracking is an endothermic process, the ager inlet with export between, the temperature of charging reduces tens of degree.Wherein temperature is about 400-500 ℃ usually, and pressure is about 2-30 * 10
5Pascal.The residence time of charging in ager is about 10-30 minute.Working depth as the function of the residence time and ager temperature is about 20 minutes.
The ager bottom is injected in treated charging, and comprised that the split product of the gaseous product of looking particular case and forming shifts out from the ager top, obtain fractionation through air distillation, underpressure distillation subsequently subsequently.
Treated material can be heavy crude, air distillation residue (being worth because it possesses others, so be of little use), underpressure distillation residue or diasphaltene resin.
After fractionation, become the decompression resistates of hydrocarbon gas and liquified petroleum gas, gasoline, gas oil, overhead product and reduction viscosity process by reducing product that viscosity obtains.
The decompression resistates that reduces the viscosity process is final recyclable product, it should satisfy for can as oil fuel matrix and compatible with other petroleum cuts and possess stability strict demand, this requires the operator to adjust implementation condition, the especially temperature of reduction viscosity process so that meet the standard that sets.
Reduce the subject matter that runs in the viscosity unit and be in technological process, the inner charging of ager is inhomogeneous, especially near the ager sidewall, and the back-mixing and the vortex phenomenon that occur of its bottom particularly.These disturbances are reinforced further along with the gas that forms in the scission reaction process.The residence time of charging changes a lot along with the difference in zone in the same cross section in the ager.Excessive fragmentation may take place in the processed charging of its result's part, and another part cracking deficiency.
Do not locate in order to remedy this deficiency, people advise in ager and on the orthogonal direction of feed flow direction to be converged a plurality of internals that are made of sieve plate being set in EPA007656, opening on these plates can be the circle and/or the seam shape, these perforates preferably account for the 1-30% on plate surface.
On residing plane, the hole that is positioned on the plate and have bubble to pass through, each piece plate all can produce charging blended effect, above-mentioned european patent application are pointed out, has used this class plate of 1-20 piece in ager.
As indicated in EPA0138247, when using this class sieve plate, the stability of split product is still not high when especially forming a large amount of gaseous compounds and a large amount of coke occurring, in practice, and with serious danger of stopping up plate hole.Consequently in order to clean sieve plate and to remove coke, need make the ager long term stop, this has improved production cost.
FRA2528444 provides a kind of method of thermo-cracking hydrocarbon ils, and wherein a kind of fluid such as water vapor tangentially are imported into (see the 6th page, 8-17 is capable) in the ager by pipe.The purpose of this lead-in mode is to make the hydrocarbon charging to rotate.
Yet charging is rotated needs steam with very big traffic flow, this means and has limited the activity space of charging in ager, thereby reduced its residence time, and this is disadvantageous to reducing viscosity.
The objective of the invention is to overcome these defectives, provide a kind of and guarantee that the residence time of charging in ager is more even, reduce the better unique way of stability of the resistates after the viscosity.
The present invention also aims to limit with ager in the whole plant that reduces viscosity in the relevant air-teturning mixed phenomenon of heavy hydrocarbon charge treating processes.
The invention still further relates to and reduce the growing amount that reduces coke in the viscosity method and apparatus.
In fact, the applicant finds, in the time will also flowing the injection ager in the mode of leaning on bottom and sidewall at least such as the gas water vapor or the nitrogen, can obtain higher feedstock conversion, therefore reduce the coke growing amount significantly, and make the vacuum residue stability that reduces viscosity stronger.
Therefore, the object of the present invention is to provide a kind of reduction liquid hydrocarbon heavy feedstocks method of viscosity, wherein this charging is heated to and can makes at least a portion hydrocarbon generation cracked temperature, subsequently charging is imported from bottom to up in the ager so that its direction towards fractionation unit is discharged from the ager top, in the method, to preferably be inert gasses, among near the charging of side-walls importing hydrocarbon at least in the bottom of ager.This method be characterised in that this gas along the sidewall of ager be injected into from bottom to up and along this wall from bottom to up with hydrocarbon charging concurrent flow.
Like this, just the air-teturning mixed phenomenon that has limited the formation in dead band near slaking wall mobile gas (water vapor, nitrogen, hydrogen, refinery gas or other gas) and suppressed to take place from bottom to up in bottom and side-walls, in the ager residence time of the different logistics of hydrocarbon fluid trend towards homogenizing and, approach the mean residence time of charging.
In addition, this gas also produces the stripping effect to the product of charging, helps like this by transform the sepn process of the lighter products (liquefied petroleum gas (LPG), gasoline, gas oil etc.) that obtains in ager.
Except near the sidewall in ager bottom is injected, can also on the different levels line of ager, near sidewall, inject, so that further suppress the formation of air-teturning mixed phenomenon and coke.
According to the present invention, gas injected from bottom to up only to be needed near the ager sidewall gas flow to reach to hang down numerical value, so especially avoided the problem that runs in the above-mentioned FRA2528444 implementation process.
For flow be the 75-200 ton/hour charging, the injecting gas flow be suitably the 0.2-3 ton/hour, with 0.5-2 ton/hour be good.
Preferably, the gas that superheated and pressure surpass ager pressure is injected on different heights along ring, is injected in the ager feeding line in the ager upstream but this gas can be used as cracking feed equally.
The invention still further relates to the equipment of the viscosity of the heavy feedstocks that reduces liquid hydrocarbon, comprising charging being heated to the well heater that makes at least a portion hydrocarbon generation cracked temperature, its underpart has at least one and is preheated the charging intake pipeline and its top has at least one that treated material is disposed to the ager of the outfall pipeline of material fractionation plant, this equipment is characterised in that wherein to contain and injects the device of pending hydrocarbon charging with preferably being inert gasses, the residing position of this injection device make the gas that is injected into can with charging in ager, to being less than the ager bottom, near side wall inner surfaces and, flow with flowing.
The gas inflow device can comprise regularly the injection tube that distributes, is connected and is circular layout with pressurized gas source, and they are in slaking wall internal surface bottom or are in the ager bottom.
This injection device comprises one significantly ringwise equally, is connected and disposes regularly the conduit of the venting hole that distributes with pressurized gas source, and it is to be placed near the ager bottom with the co-axial mode of ager.
This injection device can comprise a pipeline that this gas is imported among the hydrocarbon heavy feedstocks that is in feed heater downstream and ager upstream and is in the feed flow middle part equally.
It is near that a plurality of identical or different devices that gas injected the hydrocarbon charging all can be set on the different heights of ager slaking wall inner surface additional.
Nonrestrictive accompanying drawing has shown one embodiment of the present invention.
This figure is the synoptic diagram that the present invention reduces viscosity equipment.
Provided the part commonly used that reduces the viscosity unit among the figure, that is:
The liquid heavy charging feed line 1 of-a kind of pending hydrocarbon,
-pipeline 1 by wherein and heavy feedstocks is preheated to the stove 2 of the temperature that can guarantee at least a portion hydrocarbon generation cracking,
-cylindrical container, vertical place, dispose the ager 3 that the charging pyrolysis product is disposed to the discharge pipe line 4 of fractionating device from bottom feed and at its top by pipeline 1.
According to the present invention, be arranged on the device that preferably is the gas inject hydrocarbon charging of inertia near the bottom in the ager 3 and near the sidewall. In the accompanying drawings, injection device comprises with the sidewall of ager coaxial, is arranged on ager bottom and is supplied to the ring duct 5 of gas-pressurized by pipeline 6. This conduit 5 includes regularly hole spaced apart, so just can make gas-pressurized flow to the top of ager 3 in the mode with hydrocarbon charging and stream. So just, can limit the volume size in dead band in the ager and the air-teturning mixed phenomenon of charging and occur, avoid simultaneously the formation of coke and guarantee that ager mild or moderate pyrolysis product obtains stripping.
Compare with the described pipeline of 3B with document FRA2528444 and Fig. 3 A thereof, adopt conduit 5 more favourable, reason is that it has avoided reactor is improved thereby can not make operation more complicated.
As mentioned above, in order to make the best results of γ-ray emission, a plurality of similar gas injection apparatus can be set at the varying level of ager.
Can also adopt and arrange regularly, it is inner and the injection pipeline of gas is provided by pressurized gas source to lead to ager by sidewall and/or bottom.
As alternative alternative, can be with the pipeline 1 that preferably is pipeline 7 that the inertia gas-pressurized represents by dotted line among the figure and injects the upstream of the downstream that is in stove 2 and ager 3 and be in the feed flow middle part. Therefore pipeline 1 preferred with a peripheral injection device for example conduit such as ring duct 5 is connected so that the gas of guaranteeing to be contained in the hydrocarbon charging makes progress mobile along the wall of ager 3.
Gases used be in the situation of pressurized steam, should consider the heat and the water yield that therefore are introduced in the ager, the operating condition that consequently needs to regulate ager.
Under similar treatment conditions, the inventive method can access the vacuum residue of the reduction viscosity process that stability is greatly improved.
In fact, we understand, the stability of the residue by adopt reducing the viscosity process is controlled as the reference standard and is fallen low viscous unit, the application of oil so that it acts as a fuel, because if its stability is not higher than certain limit, then fuel oil will produce owing to the deposit that bitum precipitation forms the use problem.
Under the identical condition of working depth, can improve the stability of the residue that reduces the viscosity process by the lighter products of injecting gas stripping cracking. Keeping under the identical condition of stability, can improve the temperature of ager and increase the conversion ratio of charging.
This can be illustrated by following comparative example.
Embodiment 1
This embodiment provides a description the conventional cracking vacuum distilling resistates method of carrying out by reducing viscosity under the condition that does not adopt assist gas.This resistates is characterised in that:
-density: 1.0375
-viscosity (10
-6m
2/, 100 ℃): 3500
-sulphur content (% weight): 3.86
-Kang Laxun carboloy residue (% weight): 19.6
-asphaltene content (% weight): 12.1
-cut point: 520 ℃
The resistates that will reduce pressure is reducing the unitary stove internal heating of viscosity to about 440 ℃, subsequently it is imported the present invention without in the improved reduction viscosity ager, and this ager diameter is 2.5 meters, and axial length is 14 meters.
Service temperature is 425 ℃, and pressure is 8 * 10
5Pa.The charging flow velocity is about 100 tons/hour, and its mean residence time is about 18 minutes.
After leaving ager, in atmospheric distillation tower, fractionation reduces the effluent of viscosity process in vacuum still subsequently.
Following table 1 has provided product and the quantity thereof that obtains after the fractionation.
Under the identical condition of working depth, will the underpressure distillation resistates identical reduce viscosity again and handle with embodiment 1.Charging is placed in about 450 ℃ stove heats, at 430 ℃ and 8 * 10
5The pressure of Pa is this ager of operation down.
According to the present invention, ager is equipped with the pressured steam sparger, and this sparger is that the annular pipe of 30mm constitutes by diameter, possesses the filling orifice of regular distribution, rotates up.This sparger is located at ager bottom and coaxial with sidewall.Superheated vapour is with 11 * 10
5The about pressure of Pa is injected into 0.5 ton/hour flow, and the flow of charging then is 100 tons/hour.The residence time of charging is about 15 minutes.Therefore under the roughly similar condition of working depth, carry out to embodiment 1.
As mentioned above, the effluent that reduces the viscosity process in atmospheric distillation tower, subsequently in vacuum still by fractionation.Resulting result is collected in down in the tabulation 1.
The result shows that the output of gas reduces, and the output of gasoline and liquefied petroleum gas (LPG) (LPQ) slightly increases, and the output of gas oil obviously increases, and the quantity that reduces the vacuum residue (R.S.V.R) in the viscosity process reduces.
The viscosity that reduces the vacuum residue in the viscosity process does not become, but its stability is improved, and sedimental growing amount descends.
Embodiment 3
By the underpressure distillation resistates identical, under condition, reduce viscosity and handle than embodiment 1 and 2 higher working depths with embodiment 1.
In 455 ℃ stove, add thermal residue, subsequently its importing is equipped with in the ager of the water vapor injection ring identical with embodiment 2.Operate this ager down at 434 ℃.The flow of water vapour is all identical with embodiment 2 with pressure condition in the ager.
The feed rate and the residence time in ager thereof are all identical with embodiment 2.
Therefore, can under than embodiment 1 and 2 higher working depth conditions, operate.
Shown in these embodiment, the ager effluent in atmospheric distillation tower, subsequently in vacuum still by fractionation.
The product of gained is listed in the table below in 1.This shows, if the gas volume words identical significantly with embodiment 2, the quantity of gasoline and liquefied petroleum gas (LPG) increases along with the increase of overhead product quantity, and the increase of gas oil quantity is especially obvious, and the quantity that reduces the decompression resistates of viscosity process reduces significantly.
The viscosity of decompression resistates is compared with 2 slightly with embodiment 1 and is risen.Identical among its stability and the embodiment 1, but the condition that reduces the viscosity process but more careless quarter.
Table 1
| The product that obtains after the fractionation (% weight) | Embodiment 1 | | Embodiment 3 |
| Stability-stability of natural gas liquid+LPG gas oil overhead product R.S.V.R. R.S.V.R. *-settling (ppm) **P.S.V.R. viscosity (10 -6m 2/s，100℃) | 0.64 5 12.3 10.9 71.2 + 850 40000 | 0.42 5.3 13.7 10.3 70.2 ++ 500 50000 | 0.44 5.5 14.3 10.8 68.9 + 800 70000 |
*For example measure according to ASTM testing sequence D1661 (ASTM standard, 657-661 page or leaf, 05.01 volume, 1989 editions).
*According to the NFM07063 step measurements, the temperature during filtration is determined according to the viscosity of product, is higher than 100 ℃.Before washing, add washing by the solvent that is suitable for filtration temperature with dodecane.
These results have clearly illustrated gas to inject the advantage that ager is had with the mode of handling charging and stream.
Claims (10)
1。A kind of reduction liquid hydrocarbon heavy feedstocks method of viscosity, wherein this charging is heated to and can makes at least a portion hydrocarbon generation cracked temperature, subsequently charging is imported from bottom to up in the ager 3 so that its direction towards fractionation unit is discharged from ager 3 tops, in the method, to preferably be inert gasses, among near the charging of side-walls importing hydrocarbon at least in the bottom of ager 3.This method be characterised in that this gas along the sidewall of ager 3 be injected into from bottom to up and along this wall from bottom to up with hydrocarbon charging concurrent flow.
2。According to the method for claim 1, it is characterized in that gas is being injected in the ager 33 on the different levels near inside surface of side wall.
3。According to each method in claim 1 and 2, it is characterized in that gas is injected into ager 33 by being set up conglobate injection device.
4。According to the method for claim 1, it is characterized in that gas is injected among the hydrocarbon charging of ager 3 upstreams that are in the feed flow middle part after charging is heated.
5。According to each method among the claim 1-4, it is characterized in that for feed rate in the ager 3 be the 75-200 ton/hour, gas flow be the 0.2-3 ton/hour, with 0.5-2 ton/hour be good.
6。The equipment of the viscosity of the heavy feedstocks of reduction liquid hydrocarbon, comprising charging being heated to the well heater 2 that makes at least a portion hydrocarbon generation cracked temperature, its underpart has at least one and is preheated charging intake pipeline 1 and its top has at least one that treated material is disposed to the ager 3 of the outfall pipeline 4 of material fractionation plant, inject the device 5 of pending hydrocarbon charging with preferably being inert gasses, device 5 is in ager 3 bottoms at least and is near the side wall inner surfaces, it is characterized in that resupinate filling orifice is arranged on the injection device 5, gas is flowed to the top of ager 3.
7。Equipment according to claim 6 is characterized in that, gas injection apparatus can comprise regularly the injection tube that distributes, is connected and is circular layout with pressurized gas source, and they are in ager 3 side wall inner surfaces bottoms or are in ager 3 bottoms.
8。Equipment according to claim 6, it is characterized in that, this gas injection apparatus comprises one significantly ringwise equally, is connected and disposes the conduit 5 of inert gas venting hole with pressurization inertia source of the gas, and it is to be placed near ager 3 bottoms with ager 3 co-axial modes.
9。Equipment according to claim 6 is characterized in that, this gas injection apparatus comprises a pipeline 7 that this gas is imported among the hydrocarbon heavy feedstocks that is in feed heater 2 downstreams and ager 3 upstreams and is in the feed flow middle part.
10。According to each equipment among the claim 6-9, it is characterized in that this equipment comprises a plurality of gas injection apparatus that are set in the ager 3 (3) on different heights.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9514314A FR2741889B1 (en) | 1995-12-04 | 1995-12-04 | IMPROVEMENTS IN PROCESSES AND DEVICES FOR VISCOREDUCING HEAVY HYDROCARBON LOADS |
| FR9514314 | 1995-12-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1159474A true CN1159474A (en) | 1997-09-17 |
| CN1083876C CN1083876C (en) | 2002-05-01 |
Family
ID=9485125
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96121516A Expired - Fee Related CN1083876C (en) | 1995-12-04 | 1996-12-03 | Process for degreasing viscosity of fed heavy hydrocarbon and equipment improvement |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5925236A (en) |
| EP (1) | EP0778331B1 (en) |
| JP (1) | JP3833318B2 (en) |
| CN (1) | CN1083876C (en) |
| AT (1) | ATE185372T1 (en) |
| CA (1) | CA2191913C (en) |
| DE (1) | DE69604557T2 (en) |
| DK (1) | DK0778331T3 (en) |
| ES (1) | ES2137645T3 (en) |
| FR (1) | FR2741889B1 (en) |
| ZA (1) | ZA9610150B (en) |
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| CN110699114A (en) * | 2019-10-23 | 2020-01-17 | 东营联合石化有限责任公司 | Petroleum refining atmospheric and vacuum distillation device with improved water removal method |
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| US6533925B1 (en) | 2000-08-22 | 2003-03-18 | Texaco Development Corporation | Asphalt and resin production to integration of solvent deasphalting and gasification |
| US6964199B2 (en) | 2001-11-02 | 2005-11-15 | Cantocor, Inc. | Methods and compositions for enhanced protein expression and/or growth of cultured cells using co-transcription of a Bcl2 encoding nucleic acid |
| KR101356947B1 (en) * | 2006-03-29 | 2014-02-06 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | Process for producing lower olefins |
| WO2007117919A2 (en) * | 2006-03-29 | 2007-10-18 | Shell Oil Company | Improved process for producing lower olefins from heavy hydrocarbon feedstock utilizing two vapor/liquid separators |
| PT2011850T (en) * | 2006-04-27 | 2016-07-18 | Tapioca-Comércio E Servicos Soc Unipessoal Lda | Method for converting heavy oil into light oil |
| WO2009073436A2 (en) | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
| USD844091S1 (en) | 2016-10-20 | 2019-03-26 | Bravo Company Mfg, Inc. | Firearm handguard |
| US11149219B2 (en) * | 2019-12-19 | 2021-10-19 | Saudi Arabian Oil Company | Enhanced visbreaking process |
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|---|---|---|---|---|
| US1899889A (en) * | 1929-04-25 | 1933-02-28 | Standard Oil Dev Co | Eliminating water hazard in treating oils |
| US2161247A (en) * | 1936-06-12 | 1939-06-06 | Texas Co | Treating hydrocarbon oil |
| US2312719A (en) * | 1938-11-01 | 1943-03-02 | Standard Oil Dev Co | Cracking process |
| CA1137434A (en) * | 1978-07-11 | 1982-12-14 | Mohammed Akbar | Process for the continuous thermal cracking of hydrocarbon oils |
| FI65274C (en) * | 1982-06-14 | 1984-04-10 | Neste Oy | FOERFARANDE FOER TERMISK KRACKNING AV KOLVAETEOLJA |
| GB8323635D0 (en) | 1983-09-02 | 1983-10-05 | Shell Int Research | Continuous thermal cracking of hydrocarbon oils |
| JPS6112789A (en) * | 1984-06-27 | 1986-01-21 | Fuji Standard Res Kk | Method for continuous thermal cracking treatment of heavy oil |
| ZA862711B (en) * | 1985-05-28 | 1987-11-25 | Mobil Oil Corp | Method of supplying heat to high temperature process streams |
| US4836909A (en) * | 1985-11-25 | 1989-06-06 | Research Association For Residual Oil Processing | Process of thermally cracking heavy petroleum oil |
| US4695367A (en) * | 1986-03-24 | 1987-09-22 | The M. W. Kellogg Company | Diesel fuel production |
| US4784744A (en) * | 1987-09-10 | 1988-11-15 | Mobil Oil Corporation | Process for stabilizing intermediates and improving liquid yields and coke quality |
-
1995
- 1995-12-04 FR FR9514314A patent/FR2741889B1/en not_active Expired - Fee Related
-
1996
- 1996-11-15 ES ES96402450T patent/ES2137645T3/en not_active Expired - Lifetime
- 1996-11-15 DK DK96402450T patent/DK0778331T3/en active
- 1996-11-15 AT AT96402450T patent/ATE185372T1/en not_active IP Right Cessation
- 1996-11-15 DE DE69604557T patent/DE69604557T2/en not_active Expired - Fee Related
- 1996-11-15 EP EP96402450A patent/EP0778331B1/en not_active Expired - Lifetime
- 1996-12-03 ZA ZA9610150A patent/ZA9610150B/en unknown
- 1996-12-03 CA CA002191913A patent/CA2191913C/en not_active Expired - Fee Related
- 1996-12-03 CN CN96121516A patent/CN1083876C/en not_active Expired - Fee Related
- 1996-12-04 US US08/760,678 patent/US5925236A/en not_active Expired - Fee Related
- 1996-12-04 JP JP32371296A patent/JP3833318B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103534336A (en) * | 2011-05-13 | 2014-01-22 | 催化蒸馏技术公司 | Method for producing high vcm coke |
| CN103534336B (en) * | 2011-05-13 | 2016-10-19 | 催化蒸馏技术公司 | For the method preparing high VCM coke |
| CN105921079A (en) * | 2016-05-09 | 2016-09-07 | 怀化学院 | Cracking device and method for polysiloxane oligomer containing long-chain fluoroalkyl |
| CN110699114A (en) * | 2019-10-23 | 2020-01-17 | 东营联合石化有限责任公司 | Petroleum refining atmospheric and vacuum distillation device with improved water removal method |
Also Published As
| Publication number | Publication date |
|---|---|
| DK0778331T3 (en) | 2000-02-07 |
| CN1083876C (en) | 2002-05-01 |
| CA2191913A1 (en) | 1997-06-05 |
| JP3833318B2 (en) | 2006-10-11 |
| CA2191913C (en) | 2007-08-21 |
| JPH09183983A (en) | 1997-07-15 |
| US5925236A (en) | 1999-07-20 |
| DE69604557T2 (en) | 2000-03-02 |
| ATE185372T1 (en) | 1999-10-15 |
| ZA9610150B (en) | 1997-06-17 |
| ES2137645T3 (en) | 1999-12-16 |
| EP0778331B1 (en) | 1999-10-06 |
| DE69604557D1 (en) | 1999-11-11 |
| EP0778331A1 (en) | 1997-06-11 |
| FR2741889A1 (en) | 1997-06-06 |
| FR2741889B1 (en) | 1999-01-29 |
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