CN115946201A - Plamsa-based straw fiber treatment process for artificial board - Google Patents
Plamsa-based straw fiber treatment process for artificial board Download PDFInfo
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- CN115946201A CN115946201A CN202211523207.8A CN202211523207A CN115946201A CN 115946201 A CN115946201 A CN 115946201A CN 202211523207 A CN202211523207 A CN 202211523207A CN 115946201 A CN115946201 A CN 115946201A
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- Prior art keywords
- straw
- plamsa
- treating
- fibers
- artificial board
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- 239000010902 straw Substances 0.000 title claims abstract description 64
- 239000000835 fiber Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 11
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 9
- 238000009832 plasma treatment Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 238000005452 bending Methods 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 7
- IECPWNUMDGFDKC-UHFFFAOYSA-N Fusicsaeure Natural products C12C(O)CC3C(=C(CCC=C(C)C)C(O)=O)C(OC(C)=O)CC3(C)C1(C)CCC1C2(C)CCC(O)C1C IECPWNUMDGFDKC-UHFFFAOYSA-N 0.000 description 4
- IECPWNUMDGFDKC-MZJAQBGESA-N fusidic acid Chemical compound O[C@@H]([C@@H]12)C[C@H]3\C(=C(/CCC=C(C)C)C(O)=O)[C@@H](OC(C)=O)C[C@]3(C)[C@@]2(C)CC[C@@H]2[C@]1(C)CC[C@@H](O)[C@H]2C IECPWNUMDGFDKC-MZJAQBGESA-N 0.000 description 4
- 229960004675 fusidic acid Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a straw fiber treatment process for an artificial board based on Plamsa, which comprises the steps of putting a straw raw material into a Plamsa vacuum plasma treatment instrument; then treating for 1min-5min at low power of 150W-200W to enable the surface of the straw to generate hydroxyl; then treating for 30-60 min at high power of 400-500W to enable carbonyl carboxyl to appear on the surface of the straw; finally, taking out the treated straws for later use; according to the invention, the Plamsa with different powers is adopted to treat the straw fibers, so that the surfaces of the straws are oxidized, the hydroxyl content is increased, the wettability of the surfaces of the straw fibers is increased, the stable structure of a six-membered ring in the chemical structure of the straw fibers is also destroyed, a low molecular compound is formed, more carbonyl groups and carboxyl groups are generated, the bonding and the combination of the straw fibers and the inorganic gel are facilitated, and the inorganic gel straw plate with higher static bending strength and internal bonding force can be produced.
Description
Technical Field
The invention relates to a Plamsa-based straw fiber treatment process for an artificial board, and belongs to the technical field of straw artificial board processing methods.
Background
Compared with wood, the straws of wheat, rice and the like have high sugar content and smooth appearance, the surface horniness layer blocks wetting, diffusion and permeation of glue drops, the existence of the outer layer of the straws has great adverse effect on the bonding property of the artificial straw board, and the mechanical strength and the internal bonding force of the artificial straw board can be reduced.
And a large amount of ions, excited molecules, free radicals and other active particles in the PLASMA PLASMA are used for purely physical impact, atoms on the surface of the straw material or atoms attached to the surface can be knocked off, original pollutants and impurities on the surface of the material are removed, an etching effect is generated, the surface of the material is roughened, a plurality of fine pits and ravines are formed, the specific surface area of the surface of the material is increased, and the wettability of the surface of the material can be improved.
Disclosure of Invention
In view of the above technical problems, the present invention aims to: provides a Plamsa-based straw fiber treatment process for artificial boards.
The technical scheme of the invention is realized as follows: a Plamsa-based straw fiber treatment process for artificial boards comprises the following steps:
(1) putting straw raw materials into a Plamsa vacuum plasma treatment instrument;
(2) treating at low power of 150-200W for 1-5 min to make C2 (hydroxyl) appear on the surface of the straw;
(3) treating at high power of 400-500W for 30-60 min to make C3 (carbonyl) and C4 (carboxyl) appear on the surface of the straw;
(4) taking out the treated straws for later use.
Preferably, after the step (2) is finished, waiting for 1min-5min, and then entering the step (3).
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
according to the method, the straw fibers are treated by using the Plamsa with different powers, and the C spectral peak analysis shows that the oxidation of carbon on the surfaces of the straw fibers depends on the Plamsa treatment power, and the content and the change of functional groups on the surfaces of the straw fibers treated by the Plamsa are different along with the different Plamsa treatment powers; c2 The (hydroxyl) is generally considered to be the characteristic absorption of the hydroxyl, the increase of the content means that the hydroxyl content on the surface of the straw fiber is increased, the wettability of the surface of the straw fiber is inevitably increased, the C2 is obviously increased after being treated for 1min at a lower (200W) power, and the C3 (carbonyl) and the C4 (carboxyl) are sequentially appeared along with the time extension at a high power of 400W, but the C2 (hydroxyl) is sharply reduced.
As the six-membered ring in the chemical structure of the straw fiber is a relatively stable structural unit, tests show that under a high-energy environment, the six-membered ring can be deeply oxidized to form the fusidic acid or be broken to form a low-molecular compound, and the low-molecular compound can also be oxidized to form the fusidic acid, so that the C4 (carboxyl) content is generated after high-power or long-time treatment. In the Plamsa treatment, the surface of the straw is oxidized, the hydroxyl content is increased, the wettability of the surface of the straw fiber is increased, the stable structure of a six-membered ring in the chemical structure of the straw fiber is also damaged, low molecular compounds are formed, more carbonyl groups and carboxyl groups are generated, the bonding and the combination of the straw fiber and the inorganic gel are more facilitated, and the inorganic gel straw plate with higher static bending strength and internal bonding force can be produced.
Detailed Description
In order to make the technical problems solved, technical solutions adopted, and technical effects achieved by the present invention clearer, the technical solutions of the embodiments of the present invention will be described in further detail below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention relates to a Plamsa-based straw fiber treatment process for an artificial board, which comprises the following steps of:
(1) putting the straw raw material into a Plamsa vacuum plasma treatment instrument;
(2) treating at low power of 150W for 1min to make C2 (hydroxyl) appear on the surface of the straw;
(3) treating for 30min under high power of 400W to enable C3 (carbonyl) and C4 (carboxyl) to appear on the surface of the straw;
(4) taking out the treated straws for later use.
Example 2
(1) Putting straw raw materials into a Plamsa vacuum plasma treatment instrument;
(2) treating at low power of 180W for 3min to make C2 (hydroxyl) appear on the surface of the straw, and then waiting for 2min to stabilize the material;
(3) processing for 50min under high power of 450W to enable C3 (carbonyl) and C4 (carboxyl) to appear on the surface of the straw;
(4) taking out the treated straws for later use.
Example 3
(1) Putting the straw raw material into a Plamsa vacuum plasma treatment instrument;
(2) treating at low power of 200W for 4min to make C2 (hydroxyl) appear on the surface of the straw, and then waiting for 3min to stabilize the material;
(3) treating at high power of 500W for 55min to make C3 (carbonyl) and C4 (carboxyl) appear on the surface of the straw;
(4) taking out the treated straws for later use.
In the process, after the straw fiber is treated for 1min under low power, the hydroxyl is obviously increased, carbonyl and carboxyl appear sequentially along with time extension under high power, and as a six-membered ring in the chemical structure of the straw fiber is a relatively stable structural unit, tests show that under a high-energy environment, the six-membered ring can be deeply oxidized to form the fusidic acid or be broken to form a low-molecular compound, and the low-molecular compound can also be oxidized to form the fusidic acid, so that the carboxyl content is generated after the high-power or long-time treatment.
Wherein, the straw can be wheat straw or straw of other plants.
As can be seen from the following table, the artificial board made of the straw fiber treated by the method has more excellent performance, and all indexes of the artificial board are superior to those of the common straw artificial board.
Table 1: performance comparison table for straw artificial board
The above-mentioned embodiments are only for illustrating the technical idea and features of the present invention, and the purpose of the present invention is to enable those skilled in the art to understand the content of the present invention and implement the present invention, and not to limit the protection scope of the present invention by this, and all equivalent changes or modifications made according to the spirit of the present invention should be covered in the protection scope of the present invention.
Claims (2)
1. A Plamsa-based straw fiber treatment process for artificial boards is characterized by comprising the following steps:
(1) putting the straw raw material into a Plamsa vacuum plasma treatment instrument;
(2) treating at low power of 150-200W for 1-5 min to make C2 (hydroxyl) appear on the surface of the straw;
(3) treating at high power of 400-500W for 30-60 min to make C3 (carbonyl) and C4 (carboxyl) appear on the surface of the straw;
(4) taking out the treated straws for later use.
2. The process for treating straw fiber for artificial board based on Plamsa according to claim 1, wherein:
after the step (2) is finished, waiting for 1-5 min, and then entering the step (3).
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CN202211523207.8A CN115946201A (en) | 2022-11-30 | 2022-11-30 | Plamsa-based straw fiber treatment process for artificial board |
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US4824444A (en) * | 1986-04-11 | 1989-04-25 | Applied Membrane Technology, Inc. | Gas permselective composite membrane prepared by plasma polymerization coating techniques |
CN1709664A (en) * | 2005-07-12 | 2005-12-21 | 南京林业大学 | Method for improving glue performance of crop straw and urea resin interface using plasma |
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CN106079012A (en) * | 2016-06-21 | 2016-11-09 | 南京林业大学 | A kind of method utilizing steam dielectric barrier discharge plasma to strengthen agricultural crop straw glue performance |
CN106113208A (en) * | 2016-06-21 | 2016-11-16 | 南京林业大学 | A kind of method utilizing acrylic monomers dielectric barrier discharge plasma to strengthen agricultural crop straw glue performance |
CN114524940A (en) * | 2022-02-22 | 2022-05-24 | 江苏省农业科学院 | Method for modifying surface of wheat straw based on plasma and hyperbranched coupling |
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2022
- 2022-11-30 CN CN202211523207.8A patent/CN115946201A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US4824444A (en) * | 1986-04-11 | 1989-04-25 | Applied Membrane Technology, Inc. | Gas permselective composite membrane prepared by plasma polymerization coating techniques |
US20060185246A1 (en) * | 2005-01-31 | 2006-08-24 | Phoenix Solutions Co. | Integrated whole bale feed plasma pyrolysis gasification of lignocellulosic feed stock |
CN1709664A (en) * | 2005-07-12 | 2005-12-21 | 南京林业大学 | Method for improving glue performance of crop straw and urea resin interface using plasma |
US20110053204A1 (en) * | 2009-09-01 | 2011-03-03 | EcoSphere Energy, LLC. | Use of an adaptive chemically reactive plasma for production of microbial derived materials |
CN106079012A (en) * | 2016-06-21 | 2016-11-09 | 南京林业大学 | A kind of method utilizing steam dielectric barrier discharge plasma to strengthen agricultural crop straw glue performance |
CN106113208A (en) * | 2016-06-21 | 2016-11-16 | 南京林业大学 | A kind of method utilizing acrylic monomers dielectric barrier discharge plasma to strengthen agricultural crop straw glue performance |
CN114524940A (en) * | 2022-02-22 | 2022-05-24 | 江苏省农业科学院 | Method for modifying surface of wheat straw based on plasma and hyperbranched coupling |
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Application publication date: 20230411 |