CN115945062A - Waste gas treatment method and system in process of producing clethodim emulsifiable concentrate - Google Patents
Waste gas treatment method and system in process of producing clethodim emulsifiable concentrate Download PDFInfo
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- CN115945062A CN115945062A CN202310087736.6A CN202310087736A CN115945062A CN 115945062 A CN115945062 A CN 115945062A CN 202310087736 A CN202310087736 A CN 202310087736A CN 115945062 A CN115945062 A CN 115945062A
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- waste gas
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- clethodim
- gas treatment
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- 239000002912 waste gas Substances 0.000 title claims abstract description 125
- 239000005497 Clethodim Substances 0.000 title claims abstract description 79
- SILSDTWXNBZOGF-JWGBMQLESA-N clethodim Chemical compound CCSC(C)CC1CC(O)=C(C(CC)=NOC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-JWGBMQLESA-N 0.000 title claims abstract description 79
- 238000000034 method Methods 0.000 title claims abstract description 70
- 239000004495 emulsifiable concentrate Substances 0.000 title claims abstract description 35
- 239000007789 gas Substances 0.000 claims abstract description 99
- 239000002253 acid Substances 0.000 claims abstract description 34
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 26
- 231100000719 pollutant Toxicity 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims abstract description 22
- 239000002245 particle Substances 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 59
- 238000001179 sorption measurement Methods 0.000 claims description 34
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 21
- 230000003197 catalytic effect Effects 0.000 claims description 20
- 230000001954 sterilising effect Effects 0.000 claims description 14
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 238000009434 installation Methods 0.000 claims description 8
- 230000001678 irradiating effect Effects 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 238000004659 sterilization and disinfection Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 150000002927 oxygen compounds Chemical class 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical class [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000007320 Avena fatua Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 235000005373 Uvularia sessilifolia Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Treating Waste Gases (AREA)
Abstract
The invention relates to the technical field of waste gas treatment, in particular to a waste gas treatment method and a waste gas treatment system in a clethodim emulsifiable concentrate production process, wherein a nitrogen oxide-containing compound gas treatment module is adopted to treat nitrogen oxides in waste gas generated in the clethodim emulsifiable concentrate production process; treating acid gas in waste gas in the process of producing clethodim emulsifiable solution by using an acid gas treatment module; treating the particle pollutant gas in the waste gas in the process of producing clethodim emulsifiable solution by using a particle pollutant treatment module; the malodorous gas treatment module is adopted to treat malodorous gas in waste gas generated in the production process of clethodim emulsifiable concentrate, so that harmful gas generated in the production process of clethodim is solved.
Description
Technical Field
The invention relates to the technical field of waste gas treatment, in particular to a waste gas treatment method and system in a clethodim emulsifiable concentrate production process.
Background
The clethodim is a herbicide, has excellent selectivity, is suitable for broad-leaved fields to prevent wild oats and grassy weeds, can be quickly absorbed by the grassy weeds after being applied, is conducted to the stems and meristems of the weeds, can inhibit the activity of the meristems, and destroys cell division, so that the weeds die.
However, clethodim can generate a large amount of harmful gas in the production process, and if the clethodim is directly discharged into the air, the atmospheric pollution can be caused and the physical health of people can be harmed, so that the waste gas treatment method and the waste gas treatment system in the production process of clethodim emulsifiable solution are provided.
Disclosure of Invention
The invention aims to provide a waste gas treatment method and a waste gas treatment system in the production process of clethodim emulsifiable concentrate, so as to treat harmful gases generated in the production process of clethodim.
In order to achieve the above object, the present invention provides a waste gas treatment system in a process of producing clethodim emulsifiable concentrate, comprising:
the nitrogen-oxygen compound-containing gas treatment module is used for treating nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable concentrate;
the acid gas treatment module is used for treating acid gas in waste gas in the process of producing clethodim emulsifiable solution;
the particle pollutant treatment module is used for treating particle pollutant gas in waste gas in the process of producing clethodim emulsifiable concentrate;
the malodorous gas treatment module is used for treating malodorous gas in waste gas in the process of producing clethodim emulsifiable concentrate;
and the pipeline module is used for communicating the nitrogen-oxygen compound-containing gas treatment module, the acid gas treatment module, the particle pollutant treatment module and the malodorous gas treatment module.
Wherein, the nitrogen-oxygen compound-containing gas treatment module specifically comprises:
the catalytic unit is used for catalyzing nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable solution by using a catalyst;
the heating unit is used for heating the catalytic unit;
and the catalytic box body unit is used for installing the catalytic unit and the heating unit.
Wherein, the particle pollutant processing module specifically comprises:
the activated carbon adsorption unit is used for adsorbing particle pollutant gas in waste gas generated in the process of producing clethodim emulsifiable concentrate;
the activated carbon adsorption installation unit is used for dismounting and replacing the activated carbon adsorption unit;
and the activated carbon adsorption box body unit is used for installing the activated carbon adsorption installation unit.
Wherein, the foul gas processing module specifically includes:
the light oxygen lamp unit is used for irradiating waste gas generated in the process of producing clethodim emulsifiable solution so as to degrade molecular chains of organic and inorganic high-molecular malodorous waste gas compounds in the waste gas generated in the process of producing the clethodim emulsifiable solution into low-molecular compounds;
and the light oxygen lamp box body unit is used for installing the light oxygen lamp unit.
Wherein the acid gas treatment module specifically comprises:
the spraying unit is used for treating acid gas in waste gas generated in the process of producing clethodim emulsifiable solution;
a sterilization unit for sterilizing the waste gas generated in the process of producing clethodim emulsifiable concentrate
And the acid gas treatment box body unit is used for installing the spraying unit and the sterilization unit.
The invention also provides a waste gas treatment method for the waste gas treatment system in the process of producing clethodim emulsifiable solution, which specifically comprises the following steps:
introducing waste gas generated in the process of producing clethodim emulsifiable solution into a catalytic box body unit, and carrying out catalyst oxidation on oxynitride in the waste gas through a catalytic unit;
introducing the waste gas into an activated carbon adsorption box body unit, and adsorbing the granular pollutant gas in the waste gas through the activated carbon adsorption unit;
then introducing the waste gas into a photo-oxygen lamp box body unit, and irradiating the waste gas through the photo-oxygen lamp unit so as to degrade malodorous waste gas compounds in the waste gas;
and finally, introducing the waste gas into an acid gas treatment box body unit, and treating the acid gas in the waste gas sequentially through a spraying unit and a sterilizing unit so as to solve the problem of harmful gas generated in the production process of clethodim.
According to the method and the system for treating the waste gas generated in the process of producing clethodim emulsifiable solution, a nitrogen-oxygen compound containing gas treatment module is adopted to treat nitrogen-oxygen compounds in the waste gas generated in the process of producing the clethodim emulsifiable solution; treating acid gas in waste gas in the process of producing clethodim emulsifiable solution by using an acid gas treatment module; treating the particle pollutant gas in the waste gas in the process of producing clethodim emulsifiable solution by using a particle pollutant treatment module; the malodorous gas treatment module is adopted to treat malodorous gas in waste gas generated in the production process of clethodim emulsifiable concentrate, so that harmful gas generated in the production process of clethodim is solved.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
FIG. 1 is a block diagram of an exhaust treatment system of the present invention in the production of clethodim emulsifiable concentrate.
Fig. 2 is a flow diagram of an exhaust gas treatment process of the exhaust gas treatment system for use in the process of producing clethodim emulsifiable concentrate of the present invention.
Detailed Description
Reference will now be made in detail to the embodiments of the present invention, examples of which are illustrated in the accompanying drawings, and the embodiments described below with reference to the accompanying drawings are exemplary and intended to be illustrative of the present invention and should not be construed as limiting the present invention.
Referring to fig. 1, fig. 1 is a block diagram of an exhaust gas treatment system in a process for producing clethodim emulsifiable concentrate according to the present invention. The invention provides a waste gas treatment system in a clethodim emulsifiable concentrate production process, which comprises the following steps:
the nitrogen-oxygen compound-containing gas treatment module is used for treating nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable concentrate; the nitrogen-oxygen compound-containing gas treatment module specifically comprises a catalysis unit, a heating unit and a catalysis box body unit, wherein the catalysis unit is used for carrying out catalyst catalysis on nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable solution; the heating unit is used for heating the catalytic unit; the catalytic box body unit is used for installing the catalytic unit and the heating unit. By the effect of the catalyst, nitrogen oxides in the exhaust gas are oxidized into carbon dioxide and water at a high temperature, so that the exhaust gas is purified.
The acid gas treatment module is used for treating acid gas in waste gas in the process of producing clethodim emulsifiable solution; the acid gas treatment module specifically comprises a spraying unit, a sterilization unit and an acid gas treatment box body unit, wherein the spraying unit is used for treating acid gas in waste gas generated in the process of producing clethodim emulsifiable solution; the sterilization unit is used for sterilizing waste gas generated in the process of producing clethodim emulsifiable solution; the acid gas treatment box body unit is used for installing the spraying unit and the sterilization unit. The unit that sprays can spout alkaline liquid in waste gas for acid gas in the waste gas and alkaline liquid carry out the neutralization, thereby get rid of the acid material in the waste gas, set up ultraviolet lamp in the unit of disinfecting simultaneously and can carry out germicidal treatment to waste gas.
The particle pollutant treatment module is used for treating particle pollutant gas in waste gas in the process of producing clethodim emulsifiable concentrate; the particle pollutant treatment module specifically comprises an activated carbon adsorption unit, an activated carbon adsorption installation unit and an activated carbon adsorption box body unit, wherein the activated carbon adsorption unit is used for adsorbing particle pollutant gas in waste gas generated in the process of producing clethodim emulsifiable solution; the activated carbon adsorption installation unit is used for disassembling, assembling and replacing the activated carbon adsorption unit; the activated carbon adsorption box body unit is used for installing the activated carbon adsorption installation unit. The active carbon adsorption unit can adsorb the granule in the waste gas to carry out purification treatment to waste gas, use at the active carbon adsorption unit simultaneously after of a specified duration, can lead to the effect to reduce after the active carbon adsorption saturation in the active carbon adsorption unit, accessible active carbon adsorption installation unit changes the active carbon adsorption unit, thereby keeps the adsorption effect of active carbon adsorption unit.
The malodorous gas treatment module is used for treating malodorous gas in waste gas in the process of producing clethodim emulsifiable concentrate; the malodorous gas treatment module specifically comprises a photo-oxygen lamp unit and a photo-oxygen lamp box body unit, wherein the photo-oxygen lamp unit is used for irradiating waste gas generated in the production process of clethodim missible oil so as to degrade molecular chains of organic and inorganic high-molecular malodorous waste gas compounds in the waste gas generated in the production process of clethodim missible oil into low-molecular compounds; the light oxygen lamp box body unit is used for installing the light oxygen lamp unit. The light oxygen lamp unit is internally provided with a unique high-energy light oxygen lamp beam for irradiating the waste gas, thereby converting the molecular structure of the malodorous gas in the waste gas, degrading the molecular chain of organic or inorganic polymer malodorous waste gas into low molecular compounds under the irradiation of the beam, and purifying the waste gas.
And the pipeline module is used for communicating the nitrogen-oxygen compound-containing gas treatment module, the acidic gas treatment module, the particle pollutant treatment module and the malodorous gas treatment module. The pipeline module is used for connecting the modules, and the connecting sequence among the nitrogen-oxygen compound-containing gas treatment module, the acidic gas treatment module, the particle pollutant treatment module and the malodorous gas treatment module can be replaced.
Referring to fig. 2, fig. 2 is a flow chart illustrating an exhaust gas treatment method of an exhaust gas treatment system for a process of producing clethodim emulsifiable concentrate according to the present invention. The invention also provides a waste gas treatment method for the waste gas treatment system in the process of producing clethodim emulsifiable concentrate, which specifically comprises the following steps of:
s1: introducing waste gas generated in the process of producing clethodim emulsifiable solution into a catalytic box body unit, and carrying out catalyst oxidation on oxynitride in the waste gas through a catalytic unit;
s2: introducing the waste gas into an activated carbon adsorption box body unit, and adsorbing the granular pollutant gas in the waste gas through the activated carbon adsorption unit;
s3: then introducing the waste gas into a photo-oxygen lamp box body unit, and irradiating the waste gas through the photo-oxygen lamp unit so as to degrade malodorous waste gas compounds in the waste gas;
s4: and finally, introducing the waste gas into an acid gas treatment box body unit, and treating the acid gas in the waste gas sequentially through a spraying unit and a sterilizing unit so as to solve the problem of harmful gas generated in the production process of clethodim.
In the embodiment, waste gas generated in the process of producing clethodim emulsifiable solution is introduced into the catalytic box body unit, and nitrogen oxides in the waste gas are subjected to catalytic oxidation through the catalytic unit so as to remove nitrogen oxides in the waste gas; introducing the waste gas into an activated carbon adsorption box body unit, and adsorbing the granular pollutant gas in the waste gas through the activated carbon adsorption unit to remove granular substances in the waste gas; then introducing the waste gas into a photo-oxygen lamp box body unit, and irradiating the waste gas through the photo-oxygen lamp unit to degrade malodorous waste gas compounds in the waste gas so as to remove malodorous gas in the waste gas; and finally, introducing the waste gas into an acid gas treatment box body unit, and treating the acid gas in the waste gas sequentially through a spraying unit and a sterilizing unit to remove the acid gas in the waste gas, so that harmful gas generated in the production process of clethodim is eliminated.
According to the method and the system for treating the waste gas generated in the process of producing clethodim emulsifiable solution, a nitrogen-oxygen compound containing gas treatment module is adopted to treat nitrogen-oxygen compounds in the waste gas generated in the process of producing the clethodim emulsifiable solution; treating acid gas in waste gas in the process of producing clethodim emulsifiable solution by using an acid gas treatment module; treating the particle pollutant gas in the waste gas in the process of producing clethodim emulsifiable solution by using a particle pollutant treatment module; the malodorous gas treatment module is adopted to treat malodorous gas in waste gas generated in the production process of clethodim emulsifiable concentrate, so that harmful gas generated in the production process of clethodim is solved.
While the above disclosure describes one or more preferred embodiments of the present invention, it should be understood that there is no intent to limit the scope of the claims, and it is intended that all or a portion of the process flow of the above embodiments be practiced and equivalents thereof within the scope of the claims.
Claims (6)
1. The utility model provides a waste gas treatment system in production clethodim milk oil process which characterized in that includes:
the nitrogen-oxygen compound-containing gas treatment module is used for treating nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable concentrate;
the acid gas treatment module is used for treating acid gas in waste gas in the process of producing clethodim emulsifiable concentrate;
the particle pollutant treatment module is used for treating particle pollutant gas in waste gas in the process of producing clethodim emulsifiable concentrate;
the malodorous gas treatment module is used for treating malodorous gas in waste gas in the process of producing clethodim emulsifiable concentrate;
and the pipeline module is used for communicating the nitrogen-oxygen compound-containing gas treatment module, the acidic gas treatment module, the particle pollutant treatment module and the malodorous gas treatment module.
2. The waste gas treatment system device in the process of producing clethodim emulsifiable concentrate according to claim 1,
the nitrogen and oxygen compound-containing gas treatment module specifically comprises:
the catalytic unit is used for catalyzing nitrogen oxides in waste gas generated in the process of producing clethodim emulsifiable solution by using a catalyst;
the heating unit is used for heating the catalytic unit;
and the catalytic box body unit is used for installing the catalytic unit and the heating unit.
3. The waste gas treatment system in the process of producing clethodim emulsifiable concentrate according to claim 2,
the particle pollutant treating module specifically comprises:
the activated carbon adsorption unit is used for adsorbing particle pollutant gas in waste gas generated in the process of producing clethodim emulsifiable concentrate;
the activated carbon adsorption installation unit is used for dismounting and replacing the activated carbon adsorption unit;
and the activated carbon adsorption box body unit is used for installing the activated carbon adsorption installation unit.
4. The waste gas treatment system in the process of producing clethodim emulsifiable concentrate according to claim 3,
the malodorous gas treatment module specifically comprises:
the light oxygen lamp unit is used for irradiating waste gas generated in the process of producing clethodim emulsifiable solution so as to degrade molecular chains of organic and inorganic high-molecular malodorous waste gas compounds in the waste gas generated in the process of producing the clethodim emulsifiable solution into low-molecular compounds;
and the light oxygen lamp box body unit is used for installing the light oxygen lamp unit.
5. The waste gas treatment system in the process of producing clethodim emulsifiable concentrate according to claim 4,
the acid gas treatment module specifically comprises:
the spraying unit is used for treating acid gas in waste gas generated in the process of producing clethodim emulsifiable solution;
a sterilization unit for sterilizing the waste gas generated in the process of producing clethodim emulsifiable concentrate
And the acid gas treatment box body unit is used for installing the spraying unit and the sterilization unit.
6. The waste gas treatment method for the waste gas treatment system in the process of producing clethodim emulsifiable concentrate according to claim 5, is characterized by comprising the following steps:
introducing waste gas generated in the process of producing clethodim emulsifiable solution into a catalytic box body unit, and carrying out catalyst oxidation on oxynitride in the waste gas through a catalytic unit;
then the waste gas is introduced into an activated carbon adsorption box body unit, and the granular pollutant gas in the waste gas is adsorbed through the activated carbon adsorption unit;
then introducing the waste gas into a photo-oxygen lamp box body unit, and irradiating the waste gas through the photo-oxygen lamp unit so as to degrade malodorous waste gas compounds in the waste gas;
and finally, introducing the waste gas into an acid gas treatment box body unit, and treating the acid gas in the waste gas sequentially through a spraying unit and a sterilizing unit so as to solve the problem of harmful gas generated in the production process of clethodim.
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