CN115893595A - Control system for electrolyzed water concentration - Google Patents

Control system for electrolyzed water concentration Download PDF

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Publication number
CN115893595A
CN115893595A CN202211385247.0A CN202211385247A CN115893595A CN 115893595 A CN115893595 A CN 115893595A CN 202211385247 A CN202211385247 A CN 202211385247A CN 115893595 A CN115893595 A CN 115893595A
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Prior art keywords
electrolyzed
liquid
water
assembly
sensor
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CN202211385247.0A
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Chinese (zh)
Inventor
张亚州
崔兆辉
毛倩
刘志强
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Suzhou Jiedejia Environmental Technology Co ltd
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Suzhou Jiedejia Environmental Technology Co ltd
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Priority to CN202211385247.0A priority Critical patent/CN115893595A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The embodiment of the invention discloses a control system for the concentration of electrolyzed water, which comprises a first device for inputting water, a second device for inputting liquid to be electrolyzed, a third device for electrolyzing the input water and the liquid to be electrolyzed and a fourth device for pre-storing the electrolyzed liquid, wherein the first device is used for inputting water; the third device is respectively connected with the first device and the second device; the third device is connected with the fourth device; a first sensor is arranged in the fourth device; the first sensor is used for monitoring the component concentration of the electrolyzed liquid so as to control the electrolyzed liquid to enter the water outlet under the condition that the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.

Description

Control system for electrolyzed water concentration
Technical Field
The invention relates to the field of electrolyzed water concentration, in particular to a control system of the electrolyzed water concentration.
Background
In the related art, in order to rapidly obtain slightly acidic electrolyzed water and ensure the quality of the electrolyzed water, a slightly acidic electrolyzed water generator is widely used in the market. The principle of the method is mainly that electrolyte is prepared to a fixed concentration, and subacid electrolyzed water with hypochlorous acid as a main component is generated through a diaphragm-free or diaphragm-type electrolytic tank. Electrolysis of an electrolytic solution containing hydrochloric acid as a main component is considered to cause the following reaction: (surface of anode) 2Cl- → Cl 2 +2e - The chlorine formed will react immediately with water, as shown in formula: cl 2 +H 2 O → HClO + HCl, hypochlorous acid and hydrochloric acid. However, the electrolyte is prepared manually, so that the concentration of the electrolyte is different. Meanwhile, as the equipment faucet is connected to a civil waterway more, the stability of water pressure cannot be guaranteed, and the hypochlorous acid concentration is unstable. No effective solution to this problem is currently available.
Disclosure of Invention
In view of the above, the embodiment of the present invention provides a control system for controlling the concentration of electrolyzed water to solve at least one problem in the prior art.
In order to achieve the above purpose, the technical solution of the embodiment of the present invention is realized as follows:
the embodiment of the invention provides a control system for the concentration of electrolyzed water, which comprises a first device for inputting water, a second device for inputting liquid to be electrolyzed, a third device for electrolyzing the input water and the liquid to be electrolyzed and a fourth device for pre-storing the electrolyzed liquid, wherein the first device is used for inputting water; the third device is respectively connected with the first device and the second device; the third device is connected with the fourth device;
a first sensor is arranged in the fourth device; the first sensor is used for monitoring the component concentration of the electrolyzed liquid so as to control the electrolyzed liquid to enter the water outlet under the condition that the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.
In the above aspect, the first device includes a flow rate assembly and a first switch; the system further comprises a control device; the control device is connected with the first switch; the flow rate assembly is arranged between the water inlet and the first switch; the water inlet is connected with the first switch through a first pipeline;
the flow rate component is used for detecting the flow rate of water in the first pipeline;
the control device is used for controlling the first switch to be in a conducting state under the condition that the flow rate of the water meets a preset use requirement, so that the water in the first pipeline enters the third device; and under the condition that the flow rate of the water does not meet the preset use requirement, controlling the first switch to be in an off state so that the water in the first pipeline cannot enter the third device.
In the above scheme, the first device further comprises a voltage regulating component; the pressure regulating assembly is arranged between the water inlet and the flow velocity assembly;
the pressure regulating assembly is used for regulating the pressure of the water input from the water inlet so as to keep the flow rate of the water unchanged.
In the above solution, the first device further comprises a filter assembly; the filter assembly is arranged between the pressure regulating assembly and the flow velocity assembly;
the filtering component is used for filtering impurities in the input water.
In the above aspect, the second device includes a first container and a first power assembly; the first power assembly is disposed between the first container and the third device; the first container is connected with the third device through a second pipeline;
the first container is used for containing the liquid to be electrolyzed;
the first power assembly is used for controlling the liquid to be electrolyzed in the first container to flow to the third device through the second pipeline.
In the above scheme, the second device further comprises a liquid level assembly, a first controller and a second sensor; the liquid level assembly is arranged on the first container; the second sensor is disposed between the first power assembly and the third device; the first controller is connected with the first power assembly;
the liquid level assembly is used for detecting the volume of the liquid to be electrolyzed in the first container;
the second sensor is used for detecting the flow rate of the liquid to be electrolyzed which is controlled by the first power assembly to flow to the third device through the second pipeline;
the first controller is used for controlling the first power assembly to work under the condition that the capacity meets a second preset requirement and the flow rate of the liquid to be electrolyzed meets a third preset requirement, so that the liquid to be electrolyzed flows to the third device from the first container; and under the condition that the capacity does not meet the second preset requirement and/or the flow rate of the liquid to be electrolyzed does not meet the third preset requirement, controlling the first power assembly to stop working so that the liquid to be electrolyzed in the first container cannot enter the third device.
In the above aspect, the third device comprises an electrolytic cell; an electrode assembly is arranged in the electrolytic cell;
the electrode assembly is used for carrying out chemical reaction on the liquid to be electrolyzed to generate gas;
the electrolytic cell is used for mixing the gas and the input water to generate the electrolyzed liquid.
In the above solution, the third device further comprises a third sensor and a second controller; the third sensor is arranged on the electrolytic cell, and the second controller is arranged on the third sensor;
the third sensor is used for detecting the temperature of the electrolytic bath;
the second controller is used for controlling the electrolytic cell to work under the condition that the temperature is less than or equal to a preset temperature, so that the electrolyzed liquid enters the fourth device; and under the condition that the detected temperature is higher than the preset temperature, controlling the electrolytic bath to stop working so as to prevent the electrolyzed liquid from entering the fourth device.
In the above solution, the fourth device includes a storage component and a second switch; the system further comprises a control device; the control device is connected with the second switch; the second switch is arranged between the water outlet and the storage component; the storage component is connected with the water outlet through a third pipeline;
the storage component is used for storing the electrolyzed liquid;
the control device is used for controlling the second switch to be in a conducting state under the condition that the component concentration meets the first preset requirement, so that the electrolyzed liquid in the third pipeline enters the water outlet; and under the condition that the component concentration does not meet the first preset requirement, controlling the second switch to be in an off state, so that the electrolyzed liquid in the third pipeline cannot enter a water outlet.
In the above solution, the fourth device further comprises a second power assembly and a third controller; the second power assembly is connected with the third device through a fourth pipeline; the third controller is connected with the second power assembly;
and the third controller is used for controlling the second power assembly to work under the condition that the component concentration of the electrolyzed liquid does not meet the first preset requirement, so that the electrolyzed liquid in the storage assembly flows back to the third device through the fourth pipeline for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.
The system for controlling the concentration of the electrolyzed water comprises a first device for inputting water, a second device for inputting liquid to be electrolyzed, a third device for electrolyzing the input water and the liquid to be electrolyzed and a fourth device for pre-storing the electrolyzed liquid, wherein the first device is used for inputting water; the third device is respectively connected with the first device and the second device; the third device is connected with the fourth device; a first sensor is arranged in the fourth device; the first sensor is used for monitoring the component concentration of the electrolyzed liquid so as to control the electrolyzed liquid to enter the water outlet under the condition that the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement. By adopting the technical scheme of the embodiment of the invention, the component concentration of the electrolyzed liquid is detected by the first sensor, the electrolyzed water enters the water outlet under the condition of meeting the first preset requirement, and is electrolyzed again under the condition of not meeting the first preset requirement until the first preset requirement is met, so that the output electrolyzed water meets the requirement, and the condition of inconsistent concentration does not exist.
Drawings
FIG. 1 is a schematic diagram of a configuration of an electrolyzed water concentration control system according to an embodiment of the present invention;
fig. 2 is a schematic diagram of a BP neural network topology according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the following detailed description of specific embodiments of the present invention will be made with reference to the accompanying drawings in the embodiments of the present invention, and the following embodiments are used for illustrating the present invention and are not intended to limit the scope of the present invention.
The embodiment of the invention provides a control system of electrolyzed water concentration, and fig. 1 is a schematic structural diagram of the control system of electrolyzed water concentration provided by the embodiment of the invention; as shown in fig. 1, the system 10 includes: a first device 101 for inputting water, a second device 102 for inputting liquid to be electrolyzed, a third device 103 for electrolyzing the input water and the liquid to be electrolyzed, and a fourth device 104 for pre-storing the electrolyzed liquid; the third device 103 is connected to the first device 101 and the second device 102 respectively; the third device 103 is connected with the fourth device 104;
a first sensor 1041 is arranged in the fourth device 104; the first sensor 1041 is configured to monitor a component concentration of the electrolyzed liquid, so as to control the electrolyzed liquid to enter the water outlet when the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device 103 for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.
In this embodiment, the first device 101 may be any device for inputting water, and is not limited herein. As an example, the first device 101 may be a water intake module. The second device 102 may be any device for inputting a liquid to be electrolyzed, and as an example, the second device 102 may be a liquid inlet module. The third device 103 may be any device for electrolyzing the input water and the liquid to be electrolyzed, and as an example, the third device 103 may be an electrolysis module. The fourth device 104 may be any device for pre-storing the electrolyzed liquid, and as an example, the fourth device 104 may be a liquid storage module.
In this embodiment, the second device 102 is used for inputting a liquid to be electrolyzed, where the liquid to be electrolyzed may be determined according to actual conditions, and is not limited herein. As an example, the liquid to be electrolyzed may be a slightly acidic electrolytic liquid, and specifically, the slightly acidic electrolytic liquid may be an electrolytic liquid containing hydrochloric acid as a main component.
The first sensor 1041 is a sensor for measuring the concentration of the electrolyzed liquid component, and as an example, the first sensor 1041 may be an effective chlorine sensor. The concentration of the electrolyzed liquid is a concentration of a liquid component obtained by a mixed reaction of water and a liquid to be electrolyzed, and the concentration of the electrolyzed liquid may be, for example, a concentration of an effective chlorine in slightly acidic electrolyzed water containing HClO as a main component obtained by a chemical reaction of water and an electrolytic solution containing hydrochloric acid as a main component.
The first predetermined requirement is a range of effective chlorine concentration, which can be determined according to practical situations and is not limited herein, and as an example, the range of effective chlorine concentration can be 40-80ppm.
For convenience of understanding, the slightly acidic electrolyzed water is introduced into the water outlet under the condition that the effective chlorine concentration in the slightly acidic electrolyzed water is 40-80ppm by way of example; and under the condition that the effective chlorine concentration in the slightly acidic electrolyzed water is not between 40 and 80ppm, returning the slightly acidic electrolyzed water which does not meet the requirement to the third device 103 for re-electrolysis until the effective chlorine concentration in the slightly acidic electrolyzed water after re-electrolysis is between 40 and 80ppm.
The system 10 for controlling the concentration of electrolyzed water provided by the embodiment of the invention comprises a first device 101 for inputting water, a second device 102 for inputting liquid to be electrolyzed, a third device 103 for electrolyzing the input water and the liquid to be electrolyzed, and a fourth device 104 for pre-storing the electrolyzed liquid; the third device 103 is connected to the first device 101 and the second device 102 respectively; the third device 103 is connected with the fourth device 104; a first sensor 1041 is arranged in the fourth device 104; the first sensor 1041 is configured to monitor a component concentration of the electrolyzed liquid, so as to control the electrolyzed liquid to enter the water outlet when the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device 103 for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement. By adopting the technical scheme of the embodiment of the invention, the component concentration of the electrolyzed liquid is detected by the first sensor 1041, the electrolyzed water enters the water outlet under the condition of meeting the first preset requirement, and the electrolyzed water meets the requirement without concentration difference under the condition of not meeting the first preset requirement until the first preset requirement is met, so that the output electrolyzed water meets the requirement.
In an alternative embodiment of the present invention, the first device 101 comprises a flow rate assembly 1011 and a first switch 1012; the system 10 further includes a control device; the control device is connected with the first switch 1012; the flow rate assembly 1011 is disposed between the water inlet and the first switch 1012; the water inlet is connected with the first switch 1012 through a first pipeline 11;
the flow rate component 1011 is used for detecting the flow rate of the water in the first pipeline 11;
the control device is used for controlling the first switch 1012 to be in a conducting state under the condition that the flow rate of the water meets a preset use requirement, so that the water in the first pipeline 11 enters the third device 103; in the case that the flow rate of the water does not meet the preset use requirement, the first switch 1012 is controlled to be in an off state, so that the water in the first pipeline 11 cannot enter the third device 103.
It should be noted that the water inlet may be any device for inputting water, and is not limited herein, and the water inlet may be a water tap as an example.
In this embodiment, the flow rate component 1011 is a mechanism for detecting the flow rate of water, and the flow rate component 1011 may be a flow rate meter, for example. The preset usage requirement is a range of a specified water flow speed, which can be determined according to actual conditions, and is not limited herein, and the range of the specified water flow speed is 3-5m/s as an example.
The control device is connected to the first switch 1012, the connection relationship between the control device and the first switch 1012 is not shown in fig. 1, and the control device may be connected to the first switch 1012 by a wireless connection, for example. The first switch 1012 may be turned on or off by a control device, and as an example, the first switch 1012 may be a solenoid valve. As shown in FIG. 1, the first switch 1012 is solenoid A.
For convenience of understanding, in the case where the flow meter detects that the flow rate of the water is between 3 and 5m/s, the electromagnetic valve a is opened to allow the water to enter the third device 103; in case the flow meter detects that the flow rate of the water is not between 3-5m/s, the solenoid valve a is closed and water cannot enter the third device 103.
In an alternative embodiment of the present invention, the first apparatus 101 further comprises a pressure regulating assembly 1013; the pressure regulating assembly 1013 is disposed between the water inlet and the flow rate assembly 1011; the pressure regulating assembly 1013 is configured to regulate the pressure of the water input from the water inlet, so as to keep the flow rate of the water constant.
In this embodiment, the pressure regulating assembly 1013 may be any machine that keeps the flow rate of the input water constant by adjusting the pressure of the input water, and is not limited herein, and as an example, the pressure regulating assembly 1013 may be a pressure reducing valve. For ease of understanding, the pressure relief valve is shown here in communication with the tap to ensure a constant flow rate of water into the cell.
In an alternative embodiment of the present invention, the first device 101 further comprises a filter assembly 1014; the filter assembly 1014 is disposed between the pressure regulation assembly 1013 and the flow rate assembly 1011; the filtering assembly 1014 is used for filtering impurities in the input water.
In this embodiment, the filtering component 1014 may be any component that filters impurities in the input water, i.e., other substances in the water, and is not limited herein. As an example, the filter assembly 1014 can be a filter cartridge and the contaminant can be a metallic contaminant.
In the above embodiment, the first apparatus 101 includes a flow rate assembly 1011, a first switch 1012, a pressure regulating assembly 1013, and a filtering assembly 1014, and as an example, the water inlet module includes a flow rate meter, a solenoid valve a, a pressure reducing valve, and a filter element.
For ease of understanding, the water intake module is illustrated here: the main components comprise a pressure reducing valve, a filter element, a flow rate meter and an electromagnetic valve A. The pressure reducing valve is communicated with the water tap, so that the flow speed of water entering the electrolytic cell is ensured to be constant, and the normal work and the final liquid preparation concentration of the electrolytic cell are ensured. The pressure reducing valve is connected with the filter element, and the whole service life of the electrolytic cell is influenced when the pressure reducing valve enters the electrolytic cell for a long time due to the possibility of various metal impurities in a civil water path, so that the filter element is additionally arranged to ensure the water inlet quality. Flow rate in the water gaging way is measured through the current velocity of flow meter for confirm that current velocity of water flow accords with operation requirement, and make things convenient for the liquid measure statistics of the system liquid measure of predetermineeing in the later stage. After the electromagnetic valve A is opened, the water inlet module continuously supplies water to the electrolytic cell.
In an alternative embodiment of the present invention, the second device 102 comprises a first container 1021 and a first power assembly 1022; the first power assembly 1022 is disposed between the first container 1021 and the third device 103; the first container 1021 is connected with the third device 103 through a second pipeline 12;
the first container 1021 for containing the liquid to be electrolyzed;
the first power assembly 1022 is configured to control the liquid to be electrolyzed in the first container 1021 to flow to the third device 103 through the second pipeline 12.
In this embodiment, the first container 1021 may be any container for containing a liquid to be electrolyzed, and is not limited herein. As an example, the first container 1021 may be a barrel.
The first power assembly 1022 is a mechanism for controlling the flow of the liquid to be electrolyzed to the third device 103. As an example, the first powered assembly 1022 can be a pump, and can be specifically a peristaltic pump, as shown in fig. 1, where the first powered assembly 1022 is a peristaltic pump a.
In an optional embodiment of the present invention, the second apparatus 102 further comprises a fluid level assembly 1023, a first controller 1024, and a second sensor 1025; the liquid level assembly 1023 is arranged on the first container 1021; the second sensor 1025 is disposed between the first power assembly 1022 and the third device 103; the first controller 1024 is connected with the first power assembly 1022;
the liquid level assembly 1023 is used for detecting the volume of the liquid to be electrolyzed in the first container 1021;
the second sensor 1025 is used for detecting the flow rate of the liquid to be electrolyzed which is controlled by the first power assembly 1022 to flow to the third device 103 through the second pipeline 12;
the first controller 1024 is configured to control the first power assembly 1022 to operate to enable the liquid to be electrolyzed to flow from the first container 1021 to the third device 103 when the capacity meets a second preset requirement and the flow rate of the liquid to be electrolyzed meets a third preset requirement; and under the condition that the capacity does not meet the second preset requirement and/or the flow rate of the liquid to be electrolyzed does not meet the third preset requirement, controlling the first power assembly 1022 to stop working, so that the liquid to be electrolyzed in the first container 1021 cannot enter the third device 103.
In this embodiment, the liquid level assembly 1023 may be any mechanism for detecting the volume of the liquid to be electrolyzed in the first container 1021, and is not limited herein. As an example, the liquid level assembly 1023 may be a liquid level meter.
Here, it should be noted that the liquid level assembly 1023 is disposed on the first container 1021, and as an example, a liquid level meter is disposed on the electrolytic tank, and the liquid level meter and the electrolytic tank are connected in a manner as shown in fig. 1, and the liquid level meter is disposed on the side of the electrolytic tank.
The second sensor 1025 is a sensor for detecting the flow rate of the liquid to be electrolyzed entering the third device 103, and is not limited herein. As an example, the second sensor 1025 may be a liquid sensor.
Here, the first controller 1024 is connected to the first power assembly 1022, the connection relationship between the first controller 1024 and the first power assembly 1022 is not shown in fig. 1, and the first controller 1024 can be connected to the first power assembly 1022 through a wireless connection.
The second preset requirement is a set minimum value of the liquid capacity in the first container 1021, the minimum value of the liquid capacity may be determined according to an actual situation, and is not limited herein, and as an example, the minimum value of the liquid capacity may be 1/10 of that of the first container 1021. For ease of understanding, the second predetermined requirement is not met, i.e., less than 1/10 of the electrolyte in the electrolyte tank, i.e., the electrolyte level is low, as exemplified herein.
The third preset requirement is the flow rate of the liquid to be electrolyzed, which can be determined according to actual conditions, and is not limited herein, and the third preset requirement can be 1.6 mL/min-2 mL/min as an example.
In the above embodiment, the second apparatus 102 includes a first container 1021, a first power assembly 1022, a liquid level assembly 1023, and a second sensor 1025, which may be, for example, a liquid inlet module including an electrolyte tank, a peristaltic pump a, a liquid level meter, and a liquid sensor.
For convenience of understanding, the liquid level meter is installed on the side surface of the electrolyte barrel and used for monitoring the electrolyte residual quantity, and if the liquid level is lower, relevant prompting is carried out on an equipment interface. The peristaltic pump A pumps the electrolyte into the electrolytic cell, and the liquid sensor monitors whether the flow rate of the electrolyte meets the requirement.
In an alternative embodiment of the present invention, said third means 103 comprises an electrolytic cell 1031; an electrode assembly 1032 is arranged in the electrolytic bath 1031;
the electrode assembly 1032 is used for carrying out chemical reaction on the liquid to be electrolyzed to generate gas;
the electrolytic cell 1031 is configured to mix the gas and the input water to generate the electrolyzed liquid.
In this embodiment, the electrode assembly 1032 may be any assembly that causes a chemical reaction of a liquid to be electrolyzed to generate a gas, and is not limited herein, and the electrode assembly 1032 may be a multi-layer electrode sheet as an example. For convenience of understanding, the multilayer electrode sheet is exemplified by an electrolytic reaction of an electrolyte solution containing hydrochloric acid as a main component to generate chlorine gas.
The electrolytic cell 1031 is used for mixing gas with water to generate electrolyzed liquid. The electrolyzed liquid is slightly acidic electrolyzed water with HClO as a main component. For convenience of understanding, the chlorine gas produced is mixed with water in the electrolytic bath 1031 to produce slightly acidic electrolyzed water containing HClO as the main component.
In an alternative embodiment of the invention, the third device 103 further comprises a third sensor 1033 and a second controller 1034; the third sensor 1033 is provided on the electrolytic bath 1031, and the second controller 1034 is provided on the third sensor 1033;
the third sensor 1033 for detecting a temperature of the electrolytic bath 1031;
the second controller 1034 is configured to control the operation of the electrolytic bath 1031 to make the electrolyzed liquid enter the fourth device 104 when the temperature is less than or equal to a preset temperature; and controlling the electrolytic bath 1031 to stop working under the condition that the detected temperature is greater than the preset temperature, so that the electrolyzed liquid cannot enter the fourth device 104.
In this embodiment, the third sensor 1033 is a sensor for detecting a temperature of the electrolytic bath 1031. As an example, the third sensor 1033 may be a temperature sensor.
The second controller 1034 is disposed on the third sensor 1033, a connection relationship between the second controller 1034 and the third sensor 1033 is not shown in fig. 1, and the second controller 1034 may be connected to the third sensor 1033 by a wireless connection, for example.
The preset temperature is a maximum value of the operating temperature of the electrolytic cell 1031, the maximum value of the operating temperature of the electrolytic cell 1031 may be determined according to an actual situation, which is not limited herein, and as an example, the maximum value of the operating temperature of the electrolytic cell 1031 may be 50 ℃.
For convenience of understanding, it is exemplified here that the electrolytic cell is operated in a state where the real-time temperature of the electrolytic cell is 50 ℃ or lower, and the electrolyzed liquid is made to enter the fourth device 104; in the case where the real-time temperature of the electrolytic cell is greater than 50 ℃, the electrolytic cell stops operating, so that the electrolyzed liquid cannot enter the fourth device 104.
In the above embodiment, the third device 103 includes the electrolytic bath 1031, the electrode assembly 1032 and the third sensor 1033, and as an example, the electrolytic module includes an electrolytic bath, an electrode sheet and a temperature sensor.
For the convenience of understanding, the electrolyte is exemplified and introduced into the electrolytic bath, and first passes through the multi-layer electrode sheet and undergoes an electrolytic reaction. After chlorine gas is generated, the chlorine gas is mixed with a water path generating tank input by an electromagnetic valve A to prepare subacid electrolyzed water taking HClO as a main component. Meanwhile, the temperature sensor monitors the working temperature of the electrolytic cell, and if the temperature is too high, the liquid preparation is suspended, so that the conditions that the temperature is increased due to long-time electrolysis or other reasons, the electrolysis efficiency is reduced, the concentration of slightly acidic electrolyzed water is reduced and the like are prevented.
In the embodiment, through the mode of in-tank mixing, on one hand, the problem of insufficient electrolysis caused by the fact that the electrolyte enters the electrolytic cell after being mixed with a water channel and is electrolyzed is avoided, on the other hand, the time of full reaction of chlorine and the water channel is effectively prolonged, and the problem of different effective chlorine concentrations of subacid electrolyzed water is effectively avoided.
In an optional embodiment of the present invention, the real-time voltage and current of the third device 103 are further detected, the normal range of the real-time voltage is 10V-11V, the normal range of the current is 2A-3A, and in case of abnormal real-time voltage and current, the operation of the electrolytic cell is stopped, so that the electrolyzed liquid cannot enter the fourth device 104.
In an alternative embodiment of the present invention, the fourth apparatus 104 comprises a storage component 1042 and a second switch 1043; the system 10 further includes a control device; the control device is connected with the second switch 1043; the second switch 1043 is disposed between the water outlet and the storage assembly 1042; the storage assembly 1042 is connected with the water outlet through a third pipeline 13;
the storage component 1042 is used for storing the electrolyzed liquid;
the control device is configured to control the second switch 1043 to be in a conducting state when the component concentration meets a first preset requirement, so that the electrolyzed liquid in the third pipeline 13 enters the water outlet; and under the condition that the component concentration does not meet the first preset requirement, controlling the second switch 1043 to be in an off state, so that the electrolyzed liquid in the third pipeline 13 cannot enter the water outlet.
In this embodiment, the storage unit 1042 may be any container for storing the electrolyzed liquid, and is not limited herein. As one example, the storage component 1042 may be a reservoir. The control device is connected to the second switch 1043, and fig. 1 does not show the connection relationship between the control device and the second switch 1043, and for example, the control device is connected to the second switch 1043 in a wireless connection manner. The second switch 1043 may be turned on or off by a control device, and as an example, the second switch 1043 may be a solenoid valve. As shown in fig. 1, the second switch 1043 is a solenoid valve B.
For convenience of understanding, the electromagnetic valve B is opened to output the slightly acidic electrolyzed water to the water outlet if the effective chlorine concentration meets the requirement in the example; and if the effective chlorine concentration does not meet the requirement, closing the electromagnetic valve B to prevent the outflow of the slightly acidic electrolyzed water which does not meet the requirement.
In the embodiment, the effective chlorine concentration of the subacid electrolyzed water is effectively controlled and ensured by adding the liquid storage module, the chlorine gas leakage caused by insufficient reaction is prevented, and the use efficiency is ensured while the safety is ensured.
In an alternative embodiment of the present invention, the fourth device 104 further comprises a second power assembly 1044 and a third controller 1045; the second power assembly 1044 is connected with the third device 103 through a fourth pipeline 14; the third controller 1045 is connected with the second power assembly 1044;
the third controller 1045 is configured to, when the component concentration of the electrolyzed liquid does not meet the first preset requirement, control the second power assembly 1044 to operate, so that the electrolyzed liquid in the storage assembly 1042 returns to the third device 103 through the fourth pipeline 14 to be electrolyzed again until the component concentration of the electrolyzed liquid meets the first preset requirement.
Here, the third controller 1045 is connected to the second power assembly 1044, the connection relationship between the third controller 1045 and the second power assembly 1044 is not shown in fig. 1, and the third controller 1045 may be connected to the second power assembly 1044 in a wireless connection manner.
In this embodiment, the second power assembly 1044 is a mechanism for controlling the electrolyzed liquid to flow back to the third apparatus 103 for re-electrolysis. As an example, the second power assembly 1044 may be a pump, and may specifically be a peristaltic pump. As shown in fig. 1, the second power assembly 1044 is a peristaltic pump B.
For ease of understanding, the fourth device 104 is illustrated herein as including a first sensor 1041, a storage assembly 1042, a second switch 1043, and a second power assembly 1044, which may be, as an example, a reservoir module including a valid chlorine sensor, a reservoir, a solenoid valve B, and a peristaltic pump B. The slightly acidic electrolyzed water leaves the electrolytic bath and firstly enters the liquid storage bin. The chlorine and the water need to react for a sufficient time, and if the reaction is insufficient, the conditions of low effective chlorine concentration, chlorine leakage and the like of the slightly acidic electrolyzed water are caused, so the chlorine and the water need to be firstly put into a liquid storage bin for full reaction. An effective chlorine sensor is arranged in the liquid storage bin and used for monitoring the effective chlorine concentration of the subacid electrolyzed water in the liquid storage bin in real time.
If the effective chlorine concentration meets the requirement, the electromagnetic valve B is opened, and the subacid electrolyzed water is output to the water outlet.
If the concentration of the effective chlorine is higher, the electromagnetic valve B is closed to prevent the outflow of the slightly acidic electrolyzed water which does not meet the requirement; starting a peristaltic pump B, pumping the high-concentration subacid electrolyzed water in the liquid storage bin, and then refluxing the electrolyzed water into an electrolytic bath for secondary electrolysis; the pumping speed of the peristaltic pump A is reduced, and electrolyte is pumped at a low speed to enter an electrolytic cell for electrolysis so as to reduce the effective chlorine concentration of the prepared subacid electrolyzed water; the electrolytic current and voltage of the electrolytic cell are reduced, and the electrolytic efficiency is reduced, so that the effective chlorine concentration of the prepared subacid electrolyzed water is reduced; and after the effective chlorine concentration measured by the effective chlorine sensor is reduced to a normal range, opening the electromagnetic valve B, and outputting subacid electrolyzed water meeting the requirements to a water outlet.
If the effective chlorine concentration is lower, closing the electromagnetic valve B to prevent the outflow of the slightly acidic electrolyzed water which does not meet the requirement; closing the electromagnetic valve A, and forbidding the water path from flowing in so as to improve the effective chlorine concentration of the prepared subacid electrolyzed water; the pumping speed of the peristaltic pump A is increased, and the electrolyte is highly pumped into the electrolytic bath for electrolysis so as to increase the effective chlorine concentration of the prepared subacid electrolyzed water; the electrolytic current and voltage of the electrolytic cell are improved, and the electrolytic efficiency is improved, so that the effective chlorine concentration of the prepared subacid electrolyzed water is improved; and after the concentration of the effective chlorine measured by the effective chlorine sensor is increased to a normal range, opening the electromagnetic valve B, and outputting the slightly acidic electrolyzed water meeting the requirements to a water outlet.
In the above description, the adjustment of the effective chlorine concentration in the storage tank involves the adjustment of the current and voltage values of the peristaltic pump a, the peristaltic pump B and the electrolytic cell, and all the adjustment adopts a Back Propagation (BP) neural network algorithm to dynamically adjust the current and voltage values of the peristaltic pump a, such as the peristaltic pump B and the electrolytic cell, according to different effective chlorine concentrations and waterway flow rates.
For ease of understanding, the BP neural network is described herein. The BP neural network is an error back-propagation network, adopts a layered structure, has better classification and memory capacity and high operation speed, the topological structure of the BP neural network is shown as figure 2, the figure 2 is a schematic diagram of the BP neural network topological structure provided by the embodiment of the invention, the topological structure is divided into 3 layers, if an input layer and an output layer reach ideal values, the BP neural network is directly output, if the BP neural network exceeds expected values, the BP neural network is back-propagated, and weights of all layers are continuously modified until the output values reach set values.
The BP neural network algorithm is realized by the following specific steps:
1) Setting an initial weight:
initial weights are set for the input layer, the hidden layer and the output layer.
2) Given a sample:
let the input and output of the P-th group of samples be respectively:
Figure BDA0003929433740000141
in the formula, L represents the number of input/output groups.
3) And (3) calculating and outputting:
when the P-th group of samples is input, the node i outputs an expression as follows:
Figure BDA0003929433740000151
in the formula, Q jp The j input of the node i when the p group of samples is input; f is an excitation function, a Sigmoid type is adopted, and the input of the network output layer node can be obtained from an input layer to an output layer through a hidden layer.
4) Calculating an objective function E of the network at the time of sample input p Comprises the following steps:
Figure BDA0003929433740000152
/>
in the formula, y kp (t) is the network output after t times of weight adjustment when the p group of samples are input, and k is the jth node of the output layer.
5) Calculating a total objective function:
each set of objective functions E p Superimposed overall objective function E:
Figure BDA0003929433740000153
6) Calculating deviation:
the total objective function E (t) and the selected desired value E 0 A comparison is made. If E (t) is less than or equal to E 0 Direct output is not calculated any more; if E (t) > E 0 The reverse error propagation calculation continues.
7) Reverse error transfer calculation:
the inverse error transfer is calculated by the gradient descent method. And when the step length is eta, the weight between the neuron j and the neuron i is adjusted as follows:
Figure BDA0003929433740000154
the BP neural network gradually approximates the relation between input and output by using the continuously adjusted reverse error transfer calculation method until a satisfactory fitting relation is found.
In the invention, the values of the peristaltic pump A, the peristaltic pump B and the electrolytic bath current and voltage to be adjusted are calculated by utilizing the BP neural network according to the effective chlorine concentration and the water flow velocity in the liquid storage bin.
In this embodiment, the slightly acidic electrolyzed water generated at the first time is pre-stored, and then the concentration of the effective component is measured by the effective chlorine sensor. If the standard is met, the electromagnetic valve is opened and the water enters the water outlet. If the standard is not met, adjusting the electrolyte amount or refluxing the produced liquid for secondary electrolysis to obtain the subacid electrolyzed water meeting the standard.
In the embodiment, the current and voltage values of the peristaltic pump A, the peristaltic pump B and the electrolytic cell are calculated by applying the BP neural network according to the measured effective chlorine concentration and the water flow velocity, and the dynamic adjustment can be efficiently carried out on the effective chlorine concentration, so that a user can flexibly use electrolyte with various concentrations to adapt to the flow velocity of public water sources in various regions.
In order to understand the embodiment, the embodiment of the invention exemplifies a specific application scenario of the electrolyzed water concentration control system, and the main technology is realized through serial port communication between an operating system and a single chip microcomputer. The single chip microcomputer collects information of each sensor and sends the information to the operating system through the serial port, and the operating system can also send instructions to the single chip microcomputer to operate the sensors through the serial port.
The liquid preparation starting process comprises the following steps:
(1) After a user clicks a liquid preparation button, an operating system firstly sends a command of opening a water inlet valve, a single chip sends the inflow water flow rate to the operating system every about 0.5 second, a program judges whether the inflow water flow rate is in a normal range, a prompt box is not popped up in the normal range to the user, and simultaneously sends a command of stopping the voltage and the current of an electrolytic tank and closing a peristaltic pump, and the flow rate enters a second step normally;
(2) Sending a switch instruction of a peristaltic pump A for opening the electrolyte by a program, monitoring the liquid level of the electrolyte and the flow rate of the peristaltic pump A, stopping the peristaltic pump and popping out a prompt of low liquid level of the electrolyte if the liquid level of the electrolyte is low, stopping the peristaltic pump and popping out a prompt if the flow rate of the peristaltic pump A is not in a normal range, and entering a third step if the flow rate and the liquid level are normal;
(3) Sending a power supply instruction of starting the electrolytic cell by a program, determining the voltage and current of the power supply by the concentration selected by a user, monitoring the real-time temperature of the electrolytic cell, the real-time voltage and current of the electrolytic cell, the effective chlorine of the liquid storage bin and the flow rate of the peristaltic pump B, stopping the power supply of the electrolytic cell, stopping the work of the peristaltic pump and stopping water inflow and popping up an abnormal prompt if the temperature of the electrolytic cell is abnormal or the real-time voltage and current are abnormal;
(4) The program adopts BP neural network algorithm, whether the effective chlorine concentration of the current liquid storage bin is normal is obtained according to the algorithm result, if the effective chlorine concentration is low, the electromagnetic valve B is closed, and the outflow of the slightly acidic electrolyzed water which does not meet the requirement is prevented; closing the electromagnetic valve A, and forbidding the inflow of the waterway so as to improve the effective chlorine concentration of the prepared subacid electrolyzed water; the pumping speed of the peristaltic pump A is increased, and the electrolyte is highly pumped into the electrolytic bath for electrolysis so as to increase the effective chlorine concentration of the prepared subacid electrolyzed water; the electrolytic current and voltage of the electrolytic cell are improved, and the electrolytic efficiency is improved, so that the effective chlorine concentration of the prepared subacid electrolyzed water is improved; after the concentration of the effective chlorine measured by the effective chlorine sensor is increased to a normal range, opening the electromagnetic valve B, and outputting subacid electrolyzed water meeting the requirements to a water outlet;
(5) If the effective chlorine concentration of the liquid storage bin is higher than the concentration value range set by the user according to the algorithm result, the program sends an instruction for starting the peristaltic pump B, high-concentration subacid electrolyzed water in the liquid storage bin is pumped and then flows back to the electrolytic bath for secondary electrolysis; the pumping speed of the peristaltic pump A is reduced, and electrolyte is pumped at a low speed to enter an electrolytic cell for electrolysis so as to reduce the effective chlorine concentration of the prepared subacid electrolyzed water; the electrolytic current and voltage of the electrolytic cell are reduced, and the electrolytic efficiency is reduced, so that the effective chlorine concentration of the prepared subacid electrolyzed water is reduced; after the effective chlorine concentration measured by the effective chlorine sensor is reduced to a normal range, opening the electromagnetic valve B, and outputting slightly acidic electrolyzed water meeting the requirements to a water outlet;
(6) When the liquid preparation reaches the liquid preparation amount set by a user or the liquid preparation time reaches thirty minutes, the program automatically closes the liquid preparation, namely, the electrolytic tank is powered off, then all peristaltic pumps are stopped, and finally the water inlet valve is closed.
The method involved in the system disclosed by the embodiment of the invention can be applied to a processor or realized by the processor. The processor may be an integrated circuit chip having signal processing capabilities. In implementation, the steps of the above method may be performed by integrated logic circuits of hardware in a processor or by instructions in the form of software. The Processor may be a general purpose Processor, a Digital Signal Processor (DSP), or other programmable logic device, discrete gate or transistor logic device, discrete hardware components, etc. The processor may implement or perform the methods, steps, and logic blocks disclosed in embodiments of the present invention. A general purpose processor may be a microprocessor or any conventional processor or the like. The steps of the method disclosed by the embodiment of the invention can be directly implemented by a hardware decoding processor, or can be implemented by combining hardware and software modules in the decoding processor. The software modules may be located in a storage medium that is located in a memory and that is read by a processor to perform the steps of the method described above in connection with its hardware.
In the several embodiments provided in the present application, it should be understood that the disclosed apparatus and method may be implemented in other ways. The above-described device embodiments are merely illustrative, for example, the division of the unit is only a logical functional division, and there may be other division ways in actual implementation, such as: multiple units or components may be combined, or may be integrated into another system, or some features may be omitted, or not implemented. In addition, the coupling, direct coupling or communication connection between the components shown or discussed may be through some interfaces, and the indirect coupling or communication connection between the devices or units may be electrical, mechanical or other forms.
The units described as separate parts may or may not be physically separate, and parts displayed as units may or may not be physical units, may be located in one place, or may be distributed on multiple network units; some or all of the units can be selected according to actual needs to achieve the purpose of the solution of the embodiment.
In addition, all functional units in the embodiments of the present invention may be integrated into one processing unit, or each unit may be separately used as one unit, or two or more units may be integrated into one unit; the integrated unit can be realized in a form of hardware, or in a form of hardware plus a software functional unit.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.

Claims (10)

1. The system for controlling the concentration of the electrolyzed water is characterized by comprising a first device for inputting water, a second device for inputting liquid to be electrolyzed, a third device for electrolyzing the input water and the liquid to be electrolyzed and a fourth device for pre-storing the electrolyzed liquid; the third device is respectively connected with the first device and the second device; the third device is connected with the fourth device;
a first sensor is arranged in the fourth device; the first sensor is used for monitoring the component concentration of the electrolyzed liquid so as to control the electrolyzed liquid to enter the water outlet under the condition that the component concentration meets a first preset requirement; and under the condition that the component concentration does not meet the first preset requirement, controlling the electrolyzed liquid to flow back to the third device for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.
2. The system of claim 1, wherein the first device comprises a flow rate assembly and a first switch; the system further comprises a control device; the control device is connected with the first switch; the flow rate assembly is arranged between the water inlet and the first switch; the water inlet is connected with the first switch through a first pipeline;
the flow rate component is used for detecting the flow rate of water in the first pipeline;
the control device is used for controlling the first switch to be in a conducting state under the condition that the flow rate of the water meets a preset use requirement, so that the water in the first pipeline enters the third device; and under the condition that the flow rate of the water does not meet the preset use requirement, controlling the first switch to be in an off state, so that the water in the first pipeline cannot enter the third device.
3. The system of claim 2, wherein the first device further comprises a pressure regulating assembly; the pressure regulating assembly is arranged between the water inlet and the flow velocity assembly;
and the pressure regulating assembly is used for regulating the pressure of the water input from the water inlet so as to keep the flow rate of the water unchanged.
4. The system of claim 3, wherein the first device further comprises a filter assembly; the filter assembly is arranged between the pressure regulating assembly and the flow velocity assembly;
the filtering component is used for filtering impurities in the input water.
5. The system of claim 1, wherein the second device comprises a first container and a first power assembly; the first power assembly is disposed between the first container and the third device; the first container is connected with the third device through a second pipeline;
the first container is used for containing the liquid to be electrolyzed;
the first power assembly is used for controlling the liquid to be electrolyzed in the first container to flow to the third device through the second pipeline.
6. The system of claim 5, wherein the second device further comprises a fluid level assembly, a first controller, and a second sensor; the liquid level assembly is arranged on the first container; the second sensor is disposed between the first power assembly and the third device; the first controller is connected with the first power assembly;
the liquid level assembly is used for detecting the volume of the liquid to be electrolyzed in the first container;
the second sensor is used for detecting the flow rate of the liquid to be electrolyzed which is controlled by the first power assembly to flow to the third device through the second pipeline;
the first controller is used for controlling the first power assembly to work under the condition that the capacity meets a second preset requirement and the flow rate of the liquid to be electrolyzed meets a third preset requirement, so that the liquid to be electrolyzed flows to the third device from the first container; and under the condition that the capacity does not meet the second preset requirement and/or the flow rate of the liquid to be electrolyzed does not meet the third preset requirement, controlling the first power assembly to stop working, so that the liquid to be electrolyzed in the first container cannot enter the third device.
7. The system of claim 1, wherein the third device comprises an electrolyzer; an electrode assembly is arranged in the electrolytic cell;
the electrode assembly is used for carrying out chemical reaction on the liquid to be electrolyzed to generate gas;
the electrolytic cell is used for mixing the gas and the input water to generate the electrolyzed liquid.
8. The system of claim 7, wherein the third device further comprises a third sensor and a second controller; the third sensor is arranged on the electrolytic cell, and the second controller is arranged on the third sensor;
the third sensor is used for detecting the temperature of the electrolytic bath;
the second controller is used for controlling the electrolytic cell to work under the condition that the temperature is less than or equal to the preset temperature, so that the electrolyzed liquid enters the fourth device; and under the condition that the detected temperature is higher than the preset temperature, controlling the electrolytic bath to stop working so as to prevent the electrolyzed liquid from entering the fourth device.
9. The system of claim 1, wherein the fourth device comprises a storage component and a second switch; the system further comprises a control device; the control device is connected with the second switch; the second switch is arranged between the water outlet and the storage component; the storage assembly is connected with the water outlet through a third pipeline;
the storage component is used for storing the electrolyzed liquid;
the control device is used for controlling the second switch to be in a conducting state under the condition that the component concentration meets the first preset requirement, so that the electrolyzed liquid in the third pipeline enters the water outlet; and under the condition that the component concentration does not meet the first preset requirement, controlling the second switch to be in an off state so as to prevent the electrolyzed liquid in the third pipeline from entering a water outlet.
10. The system of claim 9, wherein the fourth device further comprises a second power assembly and a third controller; the second power assembly is connected with the third device through a fourth pipeline; the third controller is connected with the second power assembly;
and the third controller is used for controlling the second power assembly to work under the condition that the component concentration of the electrolyzed liquid does not meet the first preset requirement, so that the electrolyzed liquid in the storage assembly flows back to the third device through the fourth pipeline for re-electrolysis until the component concentration of the re-electrolyzed liquid meets the first preset requirement.
CN202211385247.0A 2022-11-07 2022-11-07 Control system for electrolyzed water concentration Pending CN115893595A (en)

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