CN115852275A - Ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and preparation method thereof - Google Patents
Ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and preparation method thereof Download PDFInfo
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- 239000000835 fiber Substances 0.000 title claims abstract description 95
- 229910001148 Al-Li alloy Inorganic materials 0.000 title claims abstract description 75
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 239000001989 lithium alloy Substances 0.000 title claims abstract description 74
- 239000002131 composite material Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims abstract description 8
- 230000032683 aging Effects 0.000 claims abstract description 7
- 238000009941 weaving Methods 0.000 claims abstract description 7
- 238000005266 casting Methods 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims abstract description 5
- 239000011261 inert gas Substances 0.000 claims abstract description 5
- 238000010791 quenching Methods 0.000 claims abstract description 5
- 230000000171 quenching effect Effects 0.000 claims abstract description 5
- 238000003980 solgel method Methods 0.000 claims abstract description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 17
- 239000004917 carbon fiber Substances 0.000 claims description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000011282 treatment Methods 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000009940 knitting Methods 0.000 claims description 2
- 238000003475 lamination Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 239000000956 alloy Substances 0.000 abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 5
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 8
- 238000005245 sintering Methods 0.000 description 6
- WPPDFTBPZNZZRP-UHFFFAOYSA-N aluminum copper Chemical compound [Al].[Cu] WPPDFTBPZNZZRP-UHFFFAOYSA-N 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910000881 Cu alloy Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 239000013585 weight reducing agent Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
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- 239000010703 silicon Substances 0.000 description 2
- 239000011856 silicon-based particle Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000003483 aging Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
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- 230000003472 neutralizing effect Effects 0.000 description 1
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- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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Abstract
The invention discloses an ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material, the volume density of which is less than 2.4g/cm 3 The composite material consists of a reinforced fiber preform, an interface layer and an aluminum-lithium alloy matrix. The preparation method comprises the following steps in sequenceThe method comprises the following steps: weaving a three-dimensional structure fiber prefabricated body, cleaning and drying; (2) Preparing a titanium oxide interface layer on the surface of the fiber by adopting a sol-gel method, wherein the thickness of the interface layer is 0.1-1 mu m; (3) Adopting an extrusion casting method to impregnate an aluminum-lithium alloy matrix in the fiber preform under the protection of inert gas; (4) And quenching and aging the composite material to obtain the fiber reinforced aluminum-lithium alloy composite material. According to the invention, the wettability between the alloy and the fiber is improved through the titanium oxide interface layer, the strength and toughness of the composite material are improved through the weak interface preset between the matrix and the fiber, the composite material integrating the properties of ultra-light weight, high strength, high toughness, damage resistance and the like is obtained, and the requirements in the fields of aerospace and military industry are met.
Description
Technical Field
The invention relates to a composite material and a preparation method thereof, in particular to an ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and a preparation method thereof.
Background
The carbon fiber and the silicon carbide fiber have the excellent performances of light weight, high temperature resistance, corrosion resistance, aging resistance, high strength, high elastic modulus, low thermal expansion coefficient and the like. The fiber reinforced metal matrix composite has high specific strength and specific modulus, and is widely applied in high technical fields with strict requirements on component quality, such as aerospace, war industry, automobile products and the like.
High performance, light weight and high stability have been the goals pursued in material development. Taking an aero-engine as an example, the weight of the aero-engine is reduced, the gas temperature of the aero-engine is increased, and the thrust-weight ratio of the aero-engine can be effectively increased. The blades of the fan section and the compressor section account for the main part of the blades of the aero-engine, and researches show that when the blades of the engine are reduced by 1kg, the corresponding blade casing of the fan is reduced by 1kg, a transmission system is reduced by 1kg, meanwhile, the engine structure and the wing/body structure of the airplane are respectively reduced by 0.5kg, so that the weight reduction of the airplane is very important due to the iteration effect caused by the weight reduction of the fan structure, and the requirement is that the structural quality of the blades of the engine is lower, the aerodynamic stability is better, and the temperature resistance is higher.
Lithium is the lightest metal element in the world and has a density of only 0.534g/cm 3 And the lithium is the only alloying element which can improve the performance and reduce the density, and the lithium is added into the metal aluminum as the alloying element to form the aluminum-lithium alloy. When 1% of lithium is added into the aluminum alloy, the density of the alloy can be reduced by 3%, the elastic modulus can be improved by 5% -6%, and a remarkable aging strengthening effect can be obtained. The aluminum lithium alloy is adopted to replace the traditional 2000 series and 7000 series aluminum alloy materials, so that the weight of the airplane parts can be reduced by 10-20%, the material rigidity is improved by 15-20%, and the aluminum lithium alloy has the advantages of light weight, high elastic modulus, high specific strength, high specific rigidity and the like, and also has high fracture toughness and good corrosion resistance. However, the A1-Li binary alloy has a high anisotropy and plasticityThe toughness level is poor, and the like, so that alloy elements Cu and Mg and trace elements Ag, ce, Y, la, ti, mn, sc, zr and the like are generally required to be added so as to precipitate a strengthening phase and improve the comprehensive mechanical property.
By an extrusion casting method, the aluminum lithium alloy is impregnated into the fiber reinforced composite material, so that the weight of the material can be effectively reduced, and the damage resistance, the temperature resistance, the rigidity, the strength and the designability of the material are improved. When the aluminum lithium alloy is filled, because the wettability of the aluminum lithium alloy and the fiber is poor, an interface reaction can occur in the compounding process, so that the fiber is damaged, and the toughness of the composite material is reduced, a titanium oxide interface layer needs to be prepared on the surface of the fiber preform structure, the titanium oxide stability is good, and the performance of the fiber in a high-temperature aerobic environment can be ensured.
The Chinese patent with the granted publication number of CN104264083B discloses a carbon fiber reinforced aluminum lithium alloy composite material and a preparation method thereof. The composite material is prepared by mixing and sintering pretreated carbon fibers and aluminum-lithium alloy powder, wherein the volume fraction content of the carbon fibers is 1-10%. The preparation method mainly comprises the steps of firing, coarsening, neutralizing treatment, ball milling and mixing and vacuum hot pressing sintering of the carbon fiber. By regulating the volume fraction of the carbon fiber, the density of the aluminum lithium alloy can be reduced, the strength and toughness of the aluminum lithium alloy are improved, and the anisotropy of the aluminum lithium alloy is improved.
The invention discloses a silicon carbide and silicon particle reinforced aluminum-copper based composite material and a preparation method thereof, belonging to the field of particle reinforced metal-based composite materials, and the publication number of the invention is CN 105803293B. The composite material consists of silicon carbide, silicon and aluminum-copper alloy, and the weight percentage of the silicon carbide is as follows: 15-25 wt.%, silicon: 45-50 wt.%, aluminum copper alloy: 25-40 wt.%; the silicon carbide and the silicon particles are uniformly distributed in the aluminum-copper alloy matrix as a reinforcing phase, and the aluminum-copper alloy matrix forms a three-dimensional space net structure.
The national invention patent with the application publication number of CN104213057A discloses a copper-plated carbon fiber reinforced aluminum lithium alloy composite material and a preparation method thereof. The composite material is formed by mixing and sintering copper-plated carbon fiber and aluminum lithium alloy powder, wherein the volume fraction content of the copper-plated carbon fiber is 1-10%. The preparation method mainly comprises copper plating of the carbon fiber, ball milling and mixing and vacuum hot-pressing sintering. By regulating the volume fraction of the copper-plated carbon fiber, the density of the aluminum lithium alloy can be reduced, the strength and toughness of the aluminum lithium alloy are improved, the anisotropy of the aluminum lithium alloy is improved, and the density of the aluminum lithium alloy is reduced by more than 5% compared with the density of the common aluminum lithium alloy under the condition that the mechanical properties of the aluminum lithium alloy are close.
Although the preparation of the fiber reinforced composite material can improve the performance of the material, the wettability and the interface compatibility between the alloy and the fiber are not considered, and a pore defect may occur inside the composite material; the composite material based on the aluminum-lithium alloy is superior to the common aluminum-based composite material in specific rigidity and specific strength, and is superior to the common aluminum-based composite material in mechanical properties such as thermal shock resistance, yield strength, compressive micro-creep resistance and the like; the powder sintering method can avoid or reduce the harmful reaction of aluminum and carbon fiber, but because of the strong activity of the aluminum-lithium alloy, the aluminum-lithium alloy is difficult to avoid oxidation even if strictly protected in the sintering process, and the powder can cause safety problems such as explosion and the like.
Disclosure of Invention
The invention aims to provide an ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and a preparation method thereof.
In order to achieve the aim, the invention provides an ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material with the volume density of less than 2.4g/cm 3 The composite fiber is characterized in that reinforced fibers are woven into a three-dimensional fiber preform in advance, the interface layer uniformly wraps the surface of the fibers, and the aluminum lithium alloy is uniformly impregnated in the fiber preform; the reinforced fiber is one of carbon fiber and silicon carbide fiber; the fiber preform structure is one of 2D lamination, 2.5D weaving and 3D knitting, and the fiber volume fraction is 20-45%; the interface layer is TiO 2 Coating, wherein the thickness of the interface layer is 0.1-1 μm; the composition of the aluminum lithium alloy comprises 2-4% of Li, 1-3.5% of Mg and 1-3% of Al-Li% Cu, 0.1-0.5% Mn, 0.05-0.2% Zr and 0.05-0.35% Zn, the rest is A1.
An ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and a preparation method thereof are characterized by comprising the following steps in sequence:
(1) Weaving fibers into a three-dimensional fiber preform, then ultrasonically cleaning the fiber preform by using absolute ethyl alcohol, and putting the fiber preform into an oven for drying;
(2) Taking tetrabutyl titanate as a precursor, absolute ethyl alcohol as a solvent and hydrochloric acid as a stabilizer, fully stirring for 1-3 h at room temperature, preparing an interface layer on the surface of the fiber preform prepared in the step (1) by adopting a sol-gel method, and then putting the fiber preform into an oven for drying;
(3) Placing the fiber preform prepared in the step (2) into a mold for fixing, preheating at 500-800 ℃, pouring molten aluminum lithium alloy into the mold under the protection of inert gas, simultaneously applying pressure of 4-9 MPa and maintaining the pressure for 10-15 min, immersing the aluminum lithium alloy into the preform, and completing filling of the aluminum lithium alloy by adopting an extrusion casting method to obtain a fiber reinforced aluminum lithium alloy composite material blank;
(4) And (4) carrying out heat treatment on the composite material blank obtained in the step (3), preserving heat for 40-50 min at 500-550 ℃, quenching with hot water, then carrying out artificial aging treatment for 100-120 h at 150-200 ℃, and cooling at room temperature to obtain the fiber reinforced aluminum-lithium alloy composite material.
Compared with the prior materials and technology, the invention has the following beneficial effects: (1) The titanium oxide interface layer obtained by hydrolysis of the good metal-plastic tackifier of tetrabutyl titanate has good stability, and can avoid melt reaction of fibers and aluminum-lithium alloy and ensure the strength of the fibers in a high-temperature aerobic environment; (2) The aluminum lithium alloy is infiltrated into the fiber fabric, so that the characteristics of the aluminum lithium alloy can be fully exerted, the composite material can obtain a good weight reduction effect, and the composite material has high damage resistance, temperature resistance and elastic modulus; (3) The aluminum lithium alloy has obvious age hardening characteristic as an aging-strengthening alloy, and the strength and toughness of the aluminum lithium alloy can be improved by a proper heat treatment process, so that the comprehensive mechanical property of the composite material is improved.
Detailed Description
The invention will now be further described with reference to the examples:
example 1
An ultra-light high-strength fiber-reinforced aluminum-lithium alloy composite material with the volume density less than 2.4g/cm 3 The composite material consists of a reinforced fiber preform, an interface layer and an aluminum lithium alloy matrix, and is characterized in that reinforced fibers are woven into a three-dimensional fiber preform in advance, the interface layer uniformly wraps the surface of the fibers, and the aluminum lithium alloy is uniformly impregnated in the fiber preform; the reinforced fiber is carbon fiber; the fiber preform structure is 3D woven, and the volume fraction of the fiber is 30%; the interface layer is TiO 2 A coating layer, wherein the thickness of the interface layer is 0.3 mu m; the aluminum-lithium alloy comprises the components of 3% of Li, 2% of Mg, 2% of Cu, 0.3% of Mn, 0.05% of Zr and 0.1% of Zn, and the balance of Al.
An ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and a preparation method thereof are characterized by comprising the following steps in sequence:
(1) Weaving carbon fibers into a 3D fiber preform, then ultrasonically cleaning the fiber preform by using absolute ethyl alcohol, and putting the fiber preform into an oven for drying;
(2) Taking tetrabutyl titanate as a precursor, absolute ethyl alcohol as a solvent and hydrochloric acid as a stabilizer, fully stirring at room temperature for 1.5h, preparing an interface layer on the surface of the fiber preform prepared in the step (1) by adopting a sol-gel method, and then putting the fiber preform into an oven for drying;
(3) Placing the three-dimensional carbon fiber preform prepared in the step (2) into a mold for fixing, preheating at 500 ℃, pouring molten aluminum-lithium alloy into the mold under the protection of inert gas, simultaneously applying 6MPa of pressure and maintaining the pressure for 10min, soaking the aluminum-lithium alloy into the preform, and filling the aluminum-lithium alloy by adopting an extrusion casting method to obtain a fiber reinforced aluminum-lithium alloy composite material blank;
(4) And (4) carrying out heat treatment on the composite material blank obtained in the step (3), preserving heat for 40min at 500 ℃, quenching in hot water, then carrying out artificial aging treatment for 109h at 150 ℃, and cooling at room temperature to obtain the fiber reinforced aluminum-lithium alloy composite material.
Example 2
An ultra-light high-strength fiber-reinforced aluminum-lithium alloy composite material with the volume density less than 2.4g/cm 3 The composite material consists of a reinforced fiber preform, an interface layer and an aluminum lithium alloy matrix, and is characterized in that reinforced fibers are woven into a three-dimensional fiber preform in advance, the interface layer uniformly wraps the surface of the fibers, and the aluminum lithium alloy is uniformly impregnated in the fiber preform; the reinforced fiber is silicon carbide fiber; the fiber preform structure is a 2.5D woven fabric, and the fiber volume fraction is 40%; the interface layer is TiO 2 Coating, wherein the thickness of the interface layer is 0.8 mu m; the aluminum-lithium alloy comprises 4% of Li, 3% of Mg, 3% of Cu, 0.5% of Mn, 0.15% of Zr and 0.25% of Zn, and the balance of Al.
An ultra-light high-strength fiber reinforced aluminum-lithium alloy composite material and a preparation method thereof are characterized by comprising the following steps in sequence:
(1) Weaving silicon carbide fibers into a 2.5D fiber preform, then ultrasonically cleaning the fiber preform by absolute ethyl alcohol, and putting the fiber preform into an oven for drying;
(2) Taking tetrabutyl titanate as a precursor, absolute ethyl alcohol as a solvent and hydrochloric acid as a stabilizer, fully stirring for 2 hours at room temperature, preparing an interface layer on the surface of the fiber preform prepared in the step (1) by adopting a sol-gel method, and then putting the fiber preform into an oven for drying;
(3) Placing the silicon carbide fiber preform prepared in the step (2) into a mold for fixing, preheating at 700 ℃, pouring molten aluminum lithium alloy into the mold under the protection of inert gas, applying 5MPa of pressure and maintaining the pressure for 15min, soaking the aluminum lithium alloy into the preform, and filling the aluminum lithium alloy by adopting an extrusion casting method to obtain a fiber reinforced aluminum lithium alloy composite material blank;
(4) And (4) carrying out heat treatment on the composite material blank obtained in the step (3), preserving heat for 50min at 550 ℃, quenching with hot water, then carrying out artificial aging treatment for 112h at 180 ℃, and cooling at room temperature to obtain the fiber reinforced aluminum-lithium alloy composite material.
The above description is only an embodiment of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modifications made by using the design concept should fall within the scope of infringing the protection of the present invention. However, any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention are within the protection scope of the technical solution of the present invention.
Claims (2)
1. An ultra-light high-strength fiber-reinforced aluminum-lithium alloy composite material with the volume density less than 2.4g/cm 3 The composite material consists of a reinforced fiber preform, an interface layer and an aluminum lithium alloy matrix, and is characterized in that reinforced fibers are woven into a three-dimensional fiber preform in advance, the interface layer uniformly wraps the surface of the fibers, and the aluminum lithium alloy is uniformly impregnated in the fiber preform; the reinforced fiber is one of carbon fiber and silicon carbide fiber; the fiber preform structure is one of 2D lamination, 2.5D weaving and 3D knitting, and the fiber volume fraction is 20-45%; the interface layer is TiO 2 Coating, wherein the thickness of the interface layer is 0.1-1 μm; the aluminum-lithium alloy comprises the components of 2-4% of Li, 1-3.5% of Mg, 1-3% of Cu, 0.1-0.5% of Mn, 0.05-0.2% of Zr, 0.05-0.35% of Zn and the balance of Al.
2. The ultra-light high-strength fiber-reinforced aluminum-lithium alloy composite material and the preparation method thereof according to claim 1 are characterized by comprising the following steps in sequence:
(1) Weaving fibers into a three-dimensional fiber preform, then ultrasonically cleaning the fiber preform by using absolute ethyl alcohol, and putting the fiber preform into an oven for drying;
(2) Taking tetrabutyl titanate as a precursor, absolute ethyl alcohol as a solvent and hydrochloric acid as a stabilizer, fully stirring for 1-3 h at room temperature, preparing an interface layer on the surface of the fiber preform prepared in the step (1) by adopting a sol-gel method, and then putting the fiber preform into an oven for drying;
(3) Placing the fiber preform prepared in the step (2) into a mold for fixing, preheating at 500-800 ℃, pouring molten aluminum lithium alloy into the mold under the protection of inert gas, simultaneously applying pressure of 4-9 MPa and maintaining the pressure for 10-15 min, immersing the aluminum lithium alloy into the preform, and completing filling of the aluminum lithium alloy by adopting an extrusion casting method to obtain a fiber reinforced aluminum lithium alloy composite material blank;
(4) And (4) carrying out heat treatment on the composite material blank obtained in the step (3), preserving heat for 40-50 min at 500-550 ℃, quenching in hot water, carrying out artificial aging treatment for 100-120 h at 150-200 ℃, and cooling at room temperature to obtain the fiber reinforced aluminum-lithium alloy composite material.
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