CN115826121A - Can effectively alleviate visual fatigue's flexible apron of preventing blue light - Google Patents

Can effectively alleviate visual fatigue's flexible apron of preventing blue light Download PDF

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CN115826121A
CN115826121A CN202211461734.0A CN202211461734A CN115826121A CN 115826121 A CN115826121 A CN 115826121A CN 202211461734 A CN202211461734 A CN 202211461734A CN 115826121 A CN115826121 A CN 115826121A
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layer
blue light
parts
flexible
sca
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齐竹竹
郭秋泉
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Jiangsu Chengrui Technology Co ltd
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Jiangsu Chengrui Technology Co ltd
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Abstract

The invention discloses a blue light-proof flexible cover plate capable of effectively relieving visual fatigue, and relates to the technical field of flexible cover plates. This can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit and be connected as a holistic blue light sclerosis layer with flexible basic unit, a side surface of flexible basic unit is provided with the enhancement layer, a side surface of preventing blue light sclerosis layer is provided with the SCA blooming, the interval is provided with the viscose layer between enhancement layer and the SCA blooming, is connected as a whole with preventing blue light sclerosis layer through the viscose layer with flexible basic unit. The transparent polyimide film is used as the flexible base layer, and the polymer formed by reacting the alkoxy isocyanide with the acid reagent is used as the reinforcing layer, so that the transparent polyimide film has high light transmission performance, ultrahigh hardness and bending resistance, the bending resistance times can reach more than 20 ten thousand, and the transparent polyimide film can be used for folding the display screen.

Description

Can effectively alleviate visual fatigue's flexible apron of preventing blue light
Technical Field
The invention relates to the technical field of flexible cover plates, in particular to a blue light-proof flexible cover plate capable of effectively relieving visual fatigue.
Background
With the growth of terminal markets such as mobile phones, computers and liquid crystal televisions and the rapid development of novel application markets such as wearable products and smart homes, nowadays, the shapes of display terminal products are entering a brand new revolution, flexibility becomes the direction of power of various manufacturers, the mobile phones and television screens can be bent and folded and are not dreams any more, and the flexible cover plates become the most critical parts of the mobile phones and the television screens. The flexible cover plate has the characteristics of good light transmission and bending and folding, so that the portability of the electronic product can be greatly improved. The introduction of the people in the industry is that the product is applied to a folding product under the condition of less increase of the volume of the product, the area of a screen can be doubled, and electronic equipment can realize more functions, so that a new man-machine interaction mode is generated.
However, the existing electronic product screens generally have blue light, and the eyes can be damaged when the existing electronic product screens are contacted with the electronic products for a long time. Harmful blue light has extremely high energy and can penetrate through crystalline lens to reach retina, causing atrophy and even death of retinal pigment epithelial cells. The death of light-sensitive cells will lead to a loss of vision or even complete loss, which is irreversible. Blue light can also cause macular degeneration, and the lens in the human eye absorbs part of the blue light, and gradually becomes cloudy and forms cataract. Most of the blue light penetrates through the crystalline lens, especially for children, and the crystalline lens is clear and cannot effectively resist the blue light, so that macular degeneration and cataract are more easily caused.
Disclosure of Invention
Solves the technical problem
Aiming at the defects of the prior art, the invention provides the blue light prevention flexible cover plate capable of effectively relieving visual fatigue, and solves the problem that the existing electronic product screen generally has blue light, and the eye damage can be caused by long-term contact with the electronic product.
Technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, includes flexible basic unit and is connected as a holistic blue light sclerosis layer with flexible basic unit, a side surface of flexible basic unit is provided with the enhancement layer, a side surface of preventing blue light sclerosis layer is provided with the SCA blooming, the interval is provided with the viscose layer between enhancement layer and the SCA blooming, is connected as a whole with preventing blue light sclerosis layer through the viscose layer with flexible basic unit.
Preferably, the flexible base layer is made of a transparent polyimide film, and the thickness of the flexible base layer is 15-120 μm.
Preferably, the reinforcing layer comprises 30-80 parts of silicon-oxygen halide, 45-75 parts of halogenated isocyanide and 0.35-2.5 parts of acid agent by mass, and the thickness of the reinforcing layer is 1-20 μm.
Preferably, the reinforcing layer comprises 45 parts by mass of a silicon oxyhalide, 45 parts by mass of a halogenated isocyanide and 0.75 part by mass of an acid agent, and the thickness of the reinforcing layer is 5 μm.
Preferably, the blue light prevention hardened layer comprises 80-100 parts of polyurethane acrylate resin, 0.01-2 parts of blue light absorbent, 0-30 parts of inorganic silicon dioxide, 0.1-1 part of photoinitiator and 0-0.1 part of perfluoropolyether fingerprint prevention oil by mass, and the thickness of the blue light prevention hardened layer is 1-20 mu m.
Preferably, the blue light prevention hardened layer comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil by mass components, and the thickness of the blue light prevention hardened layer is 10 microns.
Preferably, the SCA optical film comprises 95 to 99 parts of eva resin, 0.5 to 1.5 parts of cross-linking agent, 0.5 to 1.5 parts of coupling agent, 0.2 to 1 part of photoinitiator and 1.5 to 3.5 parts of microcrystalline wax according to mass components, and the thickness of the SCA optical film is 1 to 10 mu m.
Preferably, the SCA optical film 4 comprises, in terms of mass components, 95 parts of eva resin, 0.5 parts of a crosslinking agent, 0.5 parts of a coupling agent, 0.5 parts of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 5 μm.
Preferably, the adhesive layer is OCA optical adhesive, the thickness of the adhesive layer is 1-5 μm, the width of the adhesive layer is 15 μm, and the width of the adhesive layer 5 is 10-20 μm.
The invention also provides a processing technology of the blue-light-proof flexible cover plate capable of effectively relieving visual fatigue, which comprises the following operation steps:
s1: carrying out chemical combination reaction on a proper amount of silicon-oxygen halide and halogenated isocyanide under the argon atmosphere to form alkoxy isocyanide, and carrying out polymerization reaction on the alkoxy isocyanide and an acid reagent under the argon atmosphere to form the polymer;
s2: uniformly coating the polymer obtained in the step S1) on one side surface of the cut flexible base layer, and forming a reinforcing layer on the surface of the flexible base layer after the polymer is cooled and formed;
s3: weighing a proper amount of urethane acrylate resin, a blue light absorber and inorganic silicon dioxide according to the weight, putting the urethane acrylate resin, the blue light absorber and the inorganic silicon dioxide into a homogenizing mixer for stirring, sequentially adding a proper amount of photoinitiator and perfluoropolyether anti-fingerprint oil in the stirring process, and coating the mixture on a template coated with an anti-sticking film for UV curing after uniformly stirring;
s4: curing the reinforced layer in the step 3) to obtain a blue light prevention reinforced layer, taking the blue light prevention reinforced layer down from the anti-sticking film, and then cutting the reinforced layer into a size matched with the flexible base layer;
s5: weighing a proper amount of eva resin, a cross-linking agent, a coupling agent, a photoinitiator and microcrystalline wax, uniformly mixing, introducing the prepared mixture into a double-screw extruder, extruding the mixture at the tail end of the double-screw extruder through a melt pump, filtering and extruding the mixture through a screen, calendering to form a film to obtain an SCA optical film, and covering the SCA optical film on the surface of a blue light prevention reinforcing layer under the condition that the SCA optical film is not cooled;
s6: and (3) sequentially coating an adhesive layer on the surface of the reinforcing layer obtained in the S2), then contacting the blue light prevention reinforcing layer covering the SCA optical film with the adhesive layer, and fixing through normal temperature pressurization to obtain the blue light prevention flexible cover plate.
Advantageous effects
The invention has the following beneficial effects:
1. the blue-light-proof flexible cover plate capable of effectively relieving visual fatigue can effectively block blue light emitted by a display screen and reduce the influence of the blue light on the visual health.
2. This can effectively alleviate visual fatigue's flexible apron of preventing blue light, strengthened the holistic blue light performance of preventing of apron through preventing blue light sclerosis layer, SCA optical film further improves it simultaneously and prevents the blue light effect, leads to the SCA optical film to avoid leading to the problem of preparation process numerous and complicated and influence apron thickness because of coating a plurality of functional layers simultaneously, has greatly improved the productivity, and the cost is reduced has wide market perspective.
Of course, it is not necessary for any product in which the invention is practiced to achieve all of the above-described advantages at the same time.
Drawings
FIG. 1 is a schematic view of the internal cross-sectional structure of the present invention;
FIG. 2 is a graph of light absorption spectra for examples 1-6 of the present invention.
In the figure, 1, a flexible base layer; 2. a reinforcing layer; 3. a blue light-resistant hardened layer; 4. an SCA optical film; 5. an adhesive layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "opening," "upper," "lower," "thickness," "top," "middle," "length," "inner," "peripheral," and the like are used in an orientation or positional relationship that is merely for convenience in describing and simplifying the description, and do not indicate or imply that the referenced component or element must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be considered as limiting the present invention.
Please refer to fig. 1-2:
example 1: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Specifically, the flexible base layer 1 is made of a transparent polyimide film, and the thickness of the flexible base layer 1 is 15 μm.
Further, the reinforcing layer 2 comprises 45 parts by mass of a silicon oxyhalide, 45 parts by mass of a halogenated isocyanide and 0.75 part by mass of an acid agent, and the thickness of the reinforcing layer 2 is 5 μm
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 comprises, by mass, 95 parts of eva resin, 0.5 part of a cross-linking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 5 μm.
Further, the adhesive layer 5 is made of OCA optical adhesive, the thickness of the adhesive layer 5 is 2 μm, and the width of the adhesive layer 5 is 10 μm.
The invention also provides a processing technology of the blue-light-proof flexible cover plate capable of effectively relieving visual fatigue, which comprises the following operation steps:
s1: carrying out chemical combination reaction on a proper amount of silicon-oxygen halide and halogenated isocyanide under the argon atmosphere to form alkoxy isocyanide, and carrying out polymerization reaction on the alkoxy isocyanide and an acid reagent under the argon atmosphere to form a polymer;
s2: uniformly coating the polymer obtained in the step S1) on one side surface of the cut flexible base layer 1, and forming a reinforcing layer 2 on the surface of the flexible base layer 1 after the polymer is cooled and formed;
s3: weighing a proper amount of urethane acrylate resin, a blue light absorber and inorganic silicon dioxide according to the weight, putting the materials into a homogeneous stirrer for stirring, sequentially adding a proper amount of photoinitiator and perfluoropolyether anti-fingerprint oil in the stirring process, and coating the mixture on a template coated with an anti-sticking film for UV curing after uniform stirring;
s4: curing the obtained blue light-proof reinforced layer 2 in the step S3), taking down the blue light-proof reinforced layer 2 from the anti-sticking film, and then cutting the blue light-proof reinforced layer into a size matched with the flexible base layer 1;
s5: weighing a proper amount of eva resin, a cross-linking agent, a coupling agent, a photoinitiator and microcrystalline wax, uniformly mixing, introducing the prepared mixture into a double-screw extruder, extruding the mixture at the tail end of the double-screw extruder through a melt pump, filtering and extruding the mixture through a screen, calendering to form a film to obtain an SCA optical film 4, and covering the SCA optical film 4 on the surface of the blue light prevention reinforcing layer 2 under the condition that the SCA optical film 4 is not cooled;
s6: the surface of the reinforcing layer 2 obtained in S2) is sequentially coated with the viscose layer 5, then the blue light-proof reinforcing layer 2 covering the SCA optical film 4 is contacted with the viscose layer 5 and is fixed by normal temperature pressurization, and the obtained blue light-proof flexible cover plate
Example 2: the embodiment of the invention provides a technical scheme that: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 0.06 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 includes, in terms of mass components, 95 parts of eva resin, 0.5 part of a crosslinking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 5 μm.
Example 2 is the same as example 1 in terms of material and processing steps, except that the blue-light absorber content is different between the two.
Example 3: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 1.5 parts of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 includes, in terms of mass components, 95 parts of eva resin, 0.5 part of a crosslinking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 5 μm.
Example 3 is the same as example 1 and example 2 in material and processing steps, except that the blue light absorber content is different.
Example 4: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 includes, in terms of mass components, 95 parts of eva resin, 0.5 part of a crosslinking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 3 μm.
Example 4 the same materials and processing steps as example 1, except that the thicknesses of the SCA optical films in the two were different.
Example 5: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 includes, in terms of mass components, 95 parts of eva resin, 0.5 part of a crosslinking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 7 μm.
Example 5 was made of the same materials and processed in the same manner as example 1 and example 4, except that the thicknesses of the SCA optical films were different.
Example 6: the embodiment of the invention provides a technical scheme that: the utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, include flexible basic unit 1 and be connected as a holistic blue light sclerosis layer 3 with flexible basic unit 1, a side surface of flexible basic unit 1 is provided with enhancement layer 2, a side surface of preventing blue light sclerosis layer 3 is provided with SCA blooming 4, the interval is provided with viscose layer 5 between enhancement layer 2 and the SCA blooming 4, be connected as a whole with flexible basic unit 1 and prevent blue light sclerosis layer 3 through viscose layer 5.
Further, according to the mass components, the blue light prevention hardened layer 3 comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer 3 is 10 microns.
Further, the SCA optical film 4 includes, in terms of mass components, 95 parts of eva resin, 0.5 part of a crosslinking agent, 0.5 part of a coupling agent, 0.5 part of a photoinitiator, and 1.5 parts of microcrystalline wax, and the SCA optical film 4 has a thickness of 10 μm.
Example 6 is the same as examples 1, 4 and 5 in material and processing steps, except that the thicknesses of the SCA optical films are different.
A commercially available flexible cover plate is selected as a comparative example test object, the blue light-proof flexible cover plate prepared according to the proportion and the preparation method in the embodiments 1-6 is selected as an example test object, and then performance tests are sequentially carried out according to the following test modes:
pencil hardness: the pencil hardness was measured by the method specified in JISK5600-5-4 using a surface measuring instrument (14 FW manufactured by New Toyobo scientific Co., ltd.) and a pencil for measuring pencil hardness (Mitsubishi UNI manufactured by Mitsubishi Pencil Co., ltd.). The measurement load was 750g, the measurement speed was 30mm/min, and the measurement distance was 5mm. The measurement was conducted 5 times, and the hardness of a pencil whose pass number exceeded 4/5 was used as the evaluation result.
Wear resistance: the steel wool is tested with a force of 1kg, a speed of 40 cycles/min, a test stroke of 40mm and a cycle of 2500 circles by using #0000 steel wool, and whether scratches exist in a friction area of the steel wool is observed.
Water contact angle: mu.L of the measurement liquid was dropped on the coating film, and the water contact angle 5 seconds after dropping was measured using an automatic contact angle meter (DM-501, manufactured by Kyowa Kagaku Co., ltd.). The angle is calculated by using a theta/2 method.
Bending test: examples and comparative samples were mounted in a U-tape dynamic folding apparatus (beijing malls precision equipment ltd) having two folding stages that rotated from 180 degrees (i.e., the sample was not bent) to 0 degrees (i.e., the sample is now folded) and were subjected to 100,000 cycles at a test rate of about 6 cycles/minute. The 3mm bend radius is determined by the gap between the two rigid plates in the closed state (0 degrees). No mandrel is used to guide the curvature (i.e., a free-form bend is used). Folding was performed at room temperature.
Table 1 shows the test results of the blue light-proof flexible cover plate prepared in the example of the present invention:
Figure BDA0003955613350000091
Figure BDA0003955613350000101
the transparent polyimide film is used as the flexible base layer, and the polymer formed by reacting the alkoxy isocyanide with the acid reagent is used as the reinforcing layer, so that the transparent polyimide film has high light transmission performance, ultrahigh hardness and bending resistance, the bending resistance times can reach more than 20 ten thousand, and the transparent polyimide film can be used for folding the display screen.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (10)

1. The utility model provides a can effectively alleviate visual fatigue's flexible apron of preventing blue light, includes flexible basic unit (1) and is connected as a whole with flexible basic unit (1) and prevents blue light sclerosis layer (3), its characterized in that: one side surface of flexible basic unit (1) is provided with enhancement layer (2), a side surface of preventing blue light sclerosis layer (3) is provided with SCA blooming (4), the interval is provided with viscose layer (5) between enhancement layer (2) and SCA blooming (4), is connected flexible basic unit (1) and prevent blue light sclerosis layer (3) as a whole through viscose layer (5).
2. The blue light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 1, is characterized in that: the flexible base layer (1) is made of a transparent polyimide film, and the thickness of the flexible base layer (1) is 15-120 mu m.
3. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 1, is characterized in that: according to the mass components, the reinforcing layer (2) comprises 30-80 parts of silicon-oxygen halide, 45-75 parts of halogenated isocyanide and 0.35-2.5 parts of acid agent, and the thickness of the reinforcing layer (2) is 1-20 mu m.
4. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 3, is characterized in that: the reinforcing layer (2) comprises 45 parts of silicon-oxygen halide, 45 parts of halogenated isocyanide and 0.75 part of acid agent by mass, and the thickness of the reinforcing layer (2) is 5 mu m.
5. The blue light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 1, is characterized in that: according to the mass components, the blue light prevention hardened layer (3) comprises 80-100 parts of polyurethane acrylate resin, 0.01-2 parts of blue light absorbent, 0-30 parts of inorganic silicon dioxide, 0.1-1 part of photoinitiator and 0-0.1 part of perfluoropolyether fingerprint oil, and the thickness of the blue light prevention hardened layer (3) is 1-20 mu m.
6. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue according to claim 5, is characterized in that: according to the mass components, the blue light prevention hardened layer (3) comprises 80 parts of polyurethane acrylate resin, 0.05 part of blue light absorbent, 15 parts of inorganic silicon dioxide, 0.5 part of photoinitiator and 0.05 part of perfluoropolyether fingerprint prevention oil, and the thickness of the blue light prevention hardened layer (3) is 10 microns.
7. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 1, is characterized in that: the SCA optical film (4) comprises 95-99 parts of eva resin, 0.5-1.5 parts of cross-linking agent, 0.5-1.5 parts of coupling agent, 0.2-1 part of photoinitiator and 1.5-3.5 parts of microcrystalline wax by mass, and the thickness of the SCA optical film (4) is 1-10 mu m.
8. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 7, is characterized in that: the SCA optical film (4) comprises 95 parts of eva resin, 0.5 part of cross-linking agent, 0.5 part of coupling agent, 0.5 part of photoinitiator and 1.5 parts of microcrystalline wax according to mass components, and the thickness of the SCA optical film (4) is 5 mu m.
9. The blue-light-proof flexible cover plate capable of effectively relieving visual fatigue as claimed in claim 1, is characterized in that: the adhesive layer (5) is made of OCA optical adhesive, the thickness of the adhesive layer (5) is 1-5 mu m, and the width of the adhesive layer (5) is 10-20 mu m.
10. The processing technology of the blue-light-proof flexible cover plate capable of effectively relieving visual fatigue according to the claims 1-9, is characterized in that: the method comprises the following operation steps:
s1: carrying out chemical combination reaction on a proper amount of silicon-oxygen halide and halogenated isocyanide under the argon atmosphere to form alkoxy isocyanide, and carrying out polymerization reaction on the alkoxy isocyanide and an acid reagent under the argon atmosphere to form the polymer;
s2: uniformly coating the polymer obtained in the step S1) on one side surface of the cut flexible base layer (1), and forming a reinforcing layer (2) on the surface of the flexible base layer (1) after the polymer is cooled and formed;
s3: weighing a proper amount of urethane acrylate resin, a blue light absorber and inorganic silicon dioxide according to the weight, putting the urethane acrylate resin, the blue light absorber and the inorganic silicon dioxide into a homogenizing mixer for stirring, sequentially adding a proper amount of photoinitiator and perfluoropolyether anti-fingerprint oil in the stirring process, and coating the mixture on a template coated with an anti-sticking film for UV curing after uniformly stirring;
s4: curing the reinforcing layer (2) for preventing blue light obtained in the step S3), taking down the reinforcing layer (2) for preventing blue light from the anti-sticking film, and then cutting the reinforcing layer into the size matched with the flexible base layer (1);
s5: weighing a proper amount of eva resin, a cross-linking agent, a coupling agent, a photoinitiator and microcrystalline wax, uniformly mixing, introducing the prepared mixture into a double-screw extruder, extruding the mixture at the tail end of the double-screw extruder through a melt pump, filtering and extruding the mixture through a screen, calendering to form a film to obtain an SCA optical film (4), and covering the SCA optical film (4) on the surface of the blue light prevention reinforcing layer (2) under the condition that the SCA optical film (4) is not cooled;
s6: enhancement layer (2) surface that obtains in S2) coats viscose layer (5) in proper order, then will cover preventing blue light enhancement layer (2) and viscose layer (5) contact of SCA blooming (4), fix through the normal atmospheric temperature pressurization, obtain prevent the flexible apron of blue light.
CN202211461734.0A 2022-11-17 2022-11-17 Can effectively alleviate visual fatigue's flexible apron of preventing blue light Withdrawn CN115826121A (en)

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