CN107603468B - Coating liquid for improving water drop angle and surface smoothness of protective film and preparation method thereof - Google Patents
Coating liquid for improving water drop angle and surface smoothness of protective film and preparation method thereof Download PDFInfo
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- CN107603468B CN107603468B CN201710596359.3A CN201710596359A CN107603468B CN 107603468 B CN107603468 B CN 107603468B CN 201710596359 A CN201710596359 A CN 201710596359A CN 107603468 B CN107603468 B CN 107603468B
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Abstract
The invention discloses a coating liquid for improving the water drop angle and the surface smoothness of a protective film, which comprises the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the polymerization degree of 80-100, and 15-17 parts of dimethyl silicone oil B with the polymerization degree of 120-150; 0.005-0.01 parts of alcohol dye solution; the viscosity of the masking liquid is less than 200 cst. The coating liquid is applied to the surface of an optical display screen, has uniform refraction and clear display, and does not influence the use of a display; when the coating liquid is applied to a protective film interface, the contact angle of water drops on the interface is obviously increased, the hydrophobicity of the coating liquid is greatly improved, the applied surface has higher antifouling property, the surface friction coefficient is effectively reduced, the surface smoothness of the coating liquid is improved, and the user experience performance is good; the masking liquid has the advantages of high stability, difficult volatilization, convenient use and simple operation. The invention also provides a preparation method of the masking liquid.
Description
Technical Field
The invention relates to the technical field of antifouling coatings, in particular to a coating liquid for improving the water drop angle and surface smoothness of a protective film and a preparation method thereof.
Background
For transparent optical materials such as glass and plastic compounded on a display screen, the anti-fouling capability is an important consideration index. The anti-fouling ability of such materials is again typically measured by measuring the smoothness of the surface and the angle of the water droplet. The sources of contamination of such materials mainly include moisture, dust, oil stains, fingerprints, and the like. The optical materials are generally prepared into hydrophobic surfaces at present so as to play a role of water resistance and stain resistance. The process for preparing the hydrophobic surface is relatively complex and high in cost, and the prepared hydrophobic surface is poor in durability.
The coating technology is a liquid coating technology which can be used at any time, the requirement on equipment can be greatly reduced, and the application convenience of the coating technology can be suitable for the surfaces of electronic display elements such as mobile phones, flat panels, display screens, vehicle-mounted cameras and the like. In addition to a good hydrophobic capacity, such coating liquids also have to satisfy certain optical properties, i.e. they do not influence the light transmission of glass or plastic.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide a coating liquid which has good optical properties and is convenient to apply and can improve the water drop angle and surface smoothness of a protective film.
The second purpose of the invention is to provide a preparation method of the coating liquid.
One of the purposes of the invention is realized by adopting the following technical scheme:
a coating solution for improving the water drop angle and the surface smoothness of a protective film comprises the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the polymerization degree of 80-100, and 15-17 parts of dimethyl silicone oil B with the polymerization degree of 120-150; 0.005-0.01 parts of alcohol dye solution; the viscosity of the masking liquid is less than 200 cst.
Further, the viscosity range of the dimethyl silicone oil A is 100 +/-10 cst; the viscosity range of the dimethyl silicone oil B is 200 +/-10 cst.
Further, the mass ratio of the dimethyl silicone oil A to the dimethyl silicone oil B is 6: 1.
Further, the concentration of the dye in the alcohol dye solution is 30-40 wt%.
Further, the coating liquid comprises the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the viscosity of 100 cst; 15-17 parts of dimethyl silicone oil B with the viscosity of 200 cst; 0.005-0.01 parts of alcohol dye solution, wherein the concentration of the dye is 30-40 wt%.
Further, the coating liquid comprises the following components in parts by weight: 85 parts of dimethyl silicone oil A with the viscosity of 100 cst; 14 parts of dimethyl silicone oil B with the viscosity of 200 cst; 0.008 parts of an alcohol dye solution, wherein the concentration of the dye is 35 wt%.
Further, the masking liquid also comprises 0.02-0.05 part of essence.
The second purpose of the invention is realized by adopting the following technical scheme:
a method for preparing the above-mentioned coating liquid for improving the water drop angle and surface smoothness of the protective film, comprising:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 100 +/-10 cst;
2) adding the dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 200 +/-10 cst;
3) dropwise adding the solution obtained in the step 2) to the solution obtained in the step 1), and stirring at a constant speed of 800-;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) increasing the stirring speed of the mixed solution treated in the step 4) to 1500-1800r/min, and stirring at constant speed for 6-10 min.
Further, the mixed solution treated in the step 5) is stored in an airtight manner.
Compared with the prior art, the invention has the beneficial effects that:
1) the coating liquid for improving the water drop angle and the surface smoothness of the protective film is applied to the surface of an optical display screen, has uniform refraction and clear display, and does not influence the use of a display;
2) when the coating liquid is applied to the interface of the protective film, the contact angle of water drops on the interface is obviously increased, the hydrophobicity of the coating liquid is greatly improved, and the applied surface has higher antifouling property;
3) the masking liquid provided by the invention has the advantages of high stability, difficult volatilization, convenience in use and simplicity in operation.
Drawings
FIG. 1 is a graph showing the effect of the angle of a water droplet on a material before the application of a non-wiping coating solution;
FIG. 2 is a graph showing the effect of the water drop angle of the wipe coating of example 1;
FIG. 3 is a surface smoothness curve of the protective film with different ratios of dimethicone.
Detailed Description
The present invention will be further described with reference to the accompanying drawings and the detailed description, and it should be noted that any combination of the embodiments or technical features described below can be used to form a new embodiment without conflict.
In the following embodiments, the reagents used are all commercially available, unless otherwise specified. Wherein the general formula of the dimethyl silicone oil A is (C)2H6OSi) n, wherein the range value of n is 80-100, namely the polymerization degree is 80-100; the general formula of the dimethyl silicone oil B is (C)2H6OSi) n, wherein the range of n is 80-100, i.e. the degree of polymerization is 120-150. In the following embodiments, the essences used are also available commercially. For example, Japanese high-sand essence for DAILY use, the product number is as follows: TJ 170312378.
The invention provides a coating liquid for improving the water drop angle and the surface smoothness of a protective film, which comprises the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the polymerization degree of 80-100, and 15-17 parts of dimethyl silicone oil B with the polymerization degree of 120-150; 0.005-0.01 parts of alcohol dye solution; the viscosity of the masking liquid is less than 200 cst.
The viscosity of the dimethyl silicone oil A and the viscosity of the dimethyl silicone oil B in the masking liquid are adjusted by an acid catalyst, the amount of the viscosity of the dimethyl silicone oil A is 100 +/-30 cst, and the acid catalyst is used for adjusting the viscosity of the dimethyl silicone oil A to 200 +/-30 cst;
the coating liquid is prepared by blending two kinds of dimethyl silicone oil with different viscosities into a whole, the viscosity range of the coating liquid is better controllable in the using process, and after the coating liquid is coated on the surface, the surface has lasting and better hydrophobicity.
The invention also provides a method for preparing the coating liquid for improving the water drop angle and the surface smoothness of the protective film, which comprises the following steps:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 100 +/-10 cst;
2) adding the dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 200 +/-10 cst;
3) dropwise adding the solution obtained in the step 2) to the solution obtained in the step 1), and stirring at a constant speed of 800-;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) increasing the stirring speed of the mixed solution treated in the step 4) to 1500-1800r/min, and stirring at constant speed for 6-10 min.
The viscosity of the two dimethyl silicone oils is respectively adjusted to be remixed, so that the obtained coating liquid has better stability and better adhesive force when being attached to the outer surface of a display screen or a film.
Example 1:
a masking liquid for improving the water drop angle and surface smoothness of a protective film comprises 85.5 parts of dimethyl silicone oil A with the viscosity of 100 cst; 14.2 parts of dimethicone B having a viscosity of 200 cst; 0.08 part of alcohol dye solution and 0.24 part of essence, wherein the concentration of the dye in the alcohol dye solution is 35 wt%.
The preparation method of the coating liquid for improving the water drop angle and the surface smoothness of the protective film comprises the following steps:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 95-105 cst;
2) adding dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 195-205 cst;
3) dropwise adding the solution obtained in the step 2) into the step 1), and uniformly stirring at a constant speed of 1000 r/min;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) and (3) increasing the stirring speed of the mixed solution treated in the step 4) to 1500r/min, and stirring at a constant speed for 8 min.
The coating liquid for improving the water drop angle and the surface smoothness of the protective film can improve the water drop angle of the TPU material from 70-80 degrees to 90-102 degrees, and the pair of the coating liquid is shown in figures 1 and 2.
Example 2:
a masking liquid for improving the water drop angle and surface smoothness of a protective film comprises 85.5 parts of dimethyl silicone oil A with the viscosity of 100 cst; 14.2 parts of dimethicone B having a viscosity of 200 cst; 0.06 part of an alcohol dye solution and 0.24 part of essence, wherein the concentration of the dye of the alcohol dye solution is 35 wt%.
The preparation method of the masking liquid comprises the following steps:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 95-105 cst;
2) adding dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 195-205 cst;
3) dropwise adding the solution obtained in the step 2) into the solution obtained in the step 1), and uniformly stirring at a constant speed of 1000r/min to obtain a mixed solution;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) and (3) increasing the stirring speed of the mixed solution treated in the step 4) to 1500r/min, and stirring at a constant speed for 8 min.
Comparative example 1:
a masking liquid comprises 99.7 parts of dimethyl silicone oil A with the viscosity of 100 cst; 0.06 part of an alcohol dye solution and 0.24 part of essence, wherein the concentration of the dye of the alcohol dye solution is 35 wt%.
The preparation method of the masking liquid comprises the following steps:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 95-105 cst;
2) dropwise adding the dye alcohol solution with the formula amount into the solution obtained in the step 1) within 2min for 3 times;
3) and (3) increasing the stirring speed of the mixed solution treated in the step 2) to 1500r/min, and stirring at a constant speed for 8 min.
The coating liquid obtained in comparative example 1 has good processability, but has insufficient smoothness, and does not significantly improve the water drop angle, so that the expected effect cannot be achieved.
Comparative example 2:
a masking liquid comprises 99.7 parts of dimethyl silicone oil B with the viscosity of 200 cst; 0.06 part of an alcohol dye solution and 0.24 part of essence, wherein the concentration of the dye of the alcohol dye solution is 35 wt%.
The preparation method of the masking liquid comprises the following steps:
1) adding dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 195-205 cst;
2) dropwise adding the dye alcohol solution with the formula amount into the solution obtained in the step 1) within 2min for 3 times;
3) and (3) increasing the stirring speed of the mixed solution treated in the step 2) to 1500r/min, and stirring at a constant speed for 8 min.
The coating liquid obtained in comparative example 2 has obviously improved smoothness of the protective film, the water drop angle can reach 90-102 degrees, but the coating liquid has poor optical performance due to the limit of viscosity, and is not beneficial to processing and application.
Proportioning optimization
The proportion of the dimethyl silicone oil A and the dimethyl silicone oil B directly influences the surface smoothness of the protective film after the coating liquid is coated, taking 0.06 part of alcohol dye solution and 0.24 part of essence as an example, the total amount of the dimethyl silicone oil A and the dimethyl silicone oil B is 99.7 parts, wherein the weight ratio of the dimethyl silicone oil A: dimethylsilicone oil B was prepared in a mass ratio of 8:1, 7:1, 6:1, 5:1, 4:1 and 3:1, respectively, to prepare coating solutions for improving the water drop angle and surface smoothness of the protective film, which were measured for surface smoothness and coefficient of friction of the protective film after application, respectively, and the results are shown in fig. 1-3 and table 1.
Wherein the friction coefficient of the coating liquid obtained by each proportion is shown in the following table,
TABLE 1 influence of the Dimethicone A/B mass ratio on the Friction coefficient
Mass ratio of dimethyl silicone oil A to B | 3:1 | 4:1 | 5:1 | 6:1 | 7:1 | 8:1 |
Coefficient of friction | 0.4-0.35 | 0.37-0.34 | 0.35-0.32 | 0.3-0.26 | 0.38-0.35 | 0.42-0.45 |
The mass ratio of the dimethylsilicone oil B to the dimethylsilicone oil A in the coating liquid was plotted on the abscissa and the reciprocal of the surface friction coefficient after application was plotted on the ordinate, as shown in FIG. 3. As can be seen from the graph of FIG. 3, when the B/A mass ratio of the dimethylsilicone oil is 1:5 to 1:7, the smoothness is ideal, wherein 1: the smoothness is highest near 6.
The coefficient of friction is a measure of the smoothness of a surface, and a lower coefficient of friction indicates a smoother surface.
The above embodiments are only preferred embodiments of the present invention, and the protection scope of the present invention is not limited thereby, and any insubstantial changes and substitutions made by those skilled in the art based on the present invention are within the protection scope of the present invention.
Claims (7)
1. The coating liquid for improving the water drop angle and the surface smoothness of the protective film is characterized by being prepared from the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the polymerization degree of 80-100, and 15-17 parts of dimethyl silicone oil B with the polymerization degree of 120-150; 0.005-0.01 parts of alcohol dye solution; the viscosity of the masking liquid is less than 200 cst; the viscosity range of the dimethyl silicone oil A is 100 +/-10 cst; the viscosity range of the dimethyl silicone oil B is 200 +/-10 cst; the mass ratio of the dimethyl silicone oil A to the dimethyl silicone oil B is (5-7): 1;
the concentration of the dye in the alcohol dye solution is 30-40 wt%;
the protective film is an optical material protective film;
the coating liquid for improving the water drop angle and the surface smoothness of the protective film is prepared by the following steps:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 100 +/-10 cst;
2) adding the dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 200 +/-10 cst;
3) dropwise adding the solution obtained in the step 2) to the solution obtained in the step 1), and stirring at a constant speed of 800-;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) increasing the stirring speed of the mixed solution treated in the step 4) to 1500-1800r/min, and stirring at constant speed for 6-10 min.
2. The masking liquid for improving the water drop angle and the surface smoothness of a protective film according to claim 1, wherein the mass ratio of the dimethylsilicone oil a to the dimethylsilicone oil B is 6: 1.
3. The dope for improving the water drop angle and the surface smoothness of the protective film according to claim 1, comprising the following components in parts by weight: 90-100 parts of dimethyl silicone oil A with the viscosity of 100 cst; 15-17 parts of dimethyl silicone oil B with the viscosity of 200 cst; 0.005-0.01 parts of alcohol dye solution, wherein the concentration of the dye is 30-40 wt%.
4. The dope for improving the water drop angle and the surface smoothness of the protective film according to claim 1, comprising the following components in parts by weight: 85 parts of dimethyl silicone oil A with the viscosity of 100 cst; 14 parts of dimethyl silicone oil B with the viscosity of 200 cst; 0.008 parts of an alcohol dye solution, wherein the concentration of the dye is 35 wt%.
5. The masking liquid for improving the water drop angle and the surface smoothness of the protective film according to claim 4, wherein the masking liquid further comprises 0.02 to 0.05 parts of a perfume.
6. A method for producing the dope for improving the water drop angle and the surface smoothness of the protective film according to any one of claims 1 to 5, comprising:
1) adding the dimethyl silicone oil A into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil A is 100 +/-10 cst;
2) adding the dimethyl silicone oil B into a reaction kettle with a stirrer, and adding an acid catalyst to ensure that the viscosity of the dimethyl silicone oil B is 200 +/-10 cst;
3) dropwise adding the solution obtained in the step 2) to the solution obtained in the step 1), and stirring at a constant speed of 800-;
4) dropwise adding the dye alcohol solution with the formula amount into the mixed solution treated in the step 3) within 2min for 3 times;
5) increasing the stirring speed of the mixed solution treated in the step 4) to 1500-1800r/min, and stirring at constant speed for 6-10 min.
7. The method of claim 6, wherein the treated mixture of step 5) is stored in an airtight manner.
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JPS644665A (en) * | 1987-06-28 | 1989-01-09 | Nippon Oils & Fats Co Ltd | Underwater antifouling coating agent |
CN101531865A (en) * | 2009-04-03 | 2009-09-16 | 中国船舶重工集团公司第七二五研究所 | Method for preparing pollution-proof surface material suitably applied in marine environment |
CN101568597A (en) * | 2006-12-25 | 2009-10-28 | 中国涂料株式会社 | Curable composition, antifouling coating composition, antifouling coating film, base with antifouling coating film, and method for preventing fouling on base |
CN103045079A (en) * | 2013-01-17 | 2013-04-17 | 奇瑞汽车股份有限公司 | Hydrophobic modifier for glass, preparation method thereof, hydrophobic glass as well as preparation method thereof |
CN105694711A (en) * | 2015-11-27 | 2016-06-22 | 浙江大学 | Super-smooth self-cleaning coating and preparation method thereof |
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CN106833369A (en) * | 2017-01-05 | 2017-06-13 | 无锡海特新材料研究院有限公司 | A kind of ageing-resistant soil resistance hull coatings material and preparation method thereof |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS644665A (en) * | 1987-06-28 | 1989-01-09 | Nippon Oils & Fats Co Ltd | Underwater antifouling coating agent |
CN101568597A (en) * | 2006-12-25 | 2009-10-28 | 中国涂料株式会社 | Curable composition, antifouling coating composition, antifouling coating film, base with antifouling coating film, and method for preventing fouling on base |
CN101531865A (en) * | 2009-04-03 | 2009-09-16 | 中国船舶重工集团公司第七二五研究所 | Method for preparing pollution-proof surface material suitably applied in marine environment |
CN103045079A (en) * | 2013-01-17 | 2013-04-17 | 奇瑞汽车股份有限公司 | Hydrophobic modifier for glass, preparation method thereof, hydrophobic glass as well as preparation method thereof |
CN105694711A (en) * | 2015-11-27 | 2016-06-22 | 浙江大学 | Super-smooth self-cleaning coating and preparation method thereof |
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