CN115818955A - Float glass preparation method - Google Patents

Float glass preparation method Download PDF

Info

Publication number
CN115818955A
CN115818955A CN202211406226.2A CN202211406226A CN115818955A CN 115818955 A CN115818955 A CN 115818955A CN 202211406226 A CN202211406226 A CN 202211406226A CN 115818955 A CN115818955 A CN 115818955A
Authority
CN
China
Prior art keywords
glass
molten
percent
oxide
float
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN202211406226.2A
Other languages
Chinese (zh)
Inventor
王柯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Kexin Material Recovery Co ltd
Original Assignee
Nanjing Kexin Material Recovery Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Kexin Material Recovery Co ltd filed Critical Nanjing Kexin Material Recovery Co ltd
Priority to CN202211406226.2A priority Critical patent/CN115818955A/en
Publication of CN115818955A publication Critical patent/CN115818955A/en
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

Abstract

The invention relates to the technical field of glass production, in particular to a method for preparing float glass, which comprises the steps of mixing 65-77% of silicon dioxide, 7-11% of calcium oxide, 3-5% of magnesium oxide, 0.6-1.3% of aluminum oxide, 0.01-0.1% of ferric oxide and 5-12% of cosolvent, and sequentially melting and clarifying to obtain glass liquid; then floating the molten glass on the surface of the molten tin; then processing the molten glass on the tin liquid surface to obtain a glass ribbon; finally, the glass ribbon is sequentially annealed and cut to obtain the float glass, so that the stability of the float glass is improved.

Description

Float glass preparation method
Technical Field
The invention relates to the technical field of glass production, in particular to a float glass preparation method.
Background
Float glass is obtained by floating molten glass on the surface of molten metal and polishing, wherein molten glass is continuously flowed into a melting furnace and filled with protective gas (N) 2 And H 2 ) The tin bath floats on the liquid level of the metallic tin, and the glass of the glass belt with uniform thickness, parallel two surfaces, flatness and polishing is formed by flattening and polishing, which is one of the flat glass. At present, the stability of the float glass is insufficient, so that a float glass preparation method with good stability is needed to be provided.
Disclosure of Invention
The invention aims to provide a method for preparing float glass, which aims to improve the stability of the float glass.
In order to realize the aim, the invention provides a method for preparing float glass, which comprises the following steps:
weighing the following raw materials in percentage by mass: 65 to 77 percent of silicon dioxide, 7 to 11 percent of calcium oxide, 3 to 5 percent of magnesium oxide, 0.6 to 1.3 percent of aluminum oxide, 0.01 to 0.1 percent of ferric oxide and 5 to 12 percent of cosolvent;
mixing the raw materials, and sequentially melting and clarifying to obtain molten glass;
floating the molten glass on the surface of the molten tin;
processing the molten glass on the molten tin surface to obtain a glass ribbon;
the glass ribbon is sequentially annealed and cut to obtain the float glass.
Wherein, the raw materials are weighed according to the following mass percentage: 65 to 77 percent of silicon dioxide, 7 to 11 percent of calcium oxide, 3 to 5 percent of magnesium oxide, 0.6 to 1.3 percent of aluminum oxide, 0.01 to 0.1 percent of ferric oxide and 5 to 12 percent of cosolvent:
the cosolvent is one or a mixture of sodium oxide and potassium oxide.
The method comprises the following steps of mixing the raw materials, sequentially melting and clarifying to obtain molten glass:
mixing the prepared raw materials to obtain a mixture;
heating the mixture at a high temperature of 1300-1400 ℃ to melt the mixture to obtain a solution;
and raising the temperature of the solution to 1400-1550 ℃ to clarify the solution to obtain molten glass.
The method comprises the following specific steps of treating molten glass on a molten tin surface to obtain a glass ribbon:
spreading, flattening and thinning the molten glass on the molten tin surface by adopting an edge roller and a transition roller table;
repeating the above operations for many times to form the molten glass into the glass ribbon with flat upper and lower surfaces.
The method comprises the following steps of sequentially annealing and cutting a glass belt to obtain float glass:
sending the glass belt into an annealing kiln for annealing treatment;
and cutting the annealed glass ribbon according to requirements to obtain the float glass.
Wherein, in the step of sending the glass ribbon into an annealing kiln for annealing treatment:
the temperature after the annealing treatment is 1000-1100 ℃.
The invention relates to a method for preparing float glass, which comprises the steps of mixing 65-77% of silicon dioxide, 7-11% of calcium oxide, 3-5% of magnesium oxide, 0.6-1.3% of aluminum oxide, 0.01-0.1% of ferric oxide and 5-12% of cosolvent, and sequentially melting and clarifying to obtain glass liquid; then floating the molten glass on the surface of the molten tin; then processing the molten glass on the tin liquid surface to obtain a glass ribbon; and finally, sequentially annealing and cutting the glass ribbon to obtain the float glass. Silica is a main oxide forming the float glass, and forms an irregular continuous network with a structural unit of silicon-oxygen tetrahedron, so that a framework of the glass is formed, the viscosity of the float glass is increased, and the thermal stability and the chemical stability of the float glass are improved; the calcium oxide can accelerate the melting and clarification process of the glass, and improve the mechanical strength, hardness and chemical stability of the glass; the magnesium oxide can reduce the high-temperature viscosity of the magic power, so that the crystallization tendency and the crystallization speed of the glass are reduced, and the mechanical strength, the thermal stability and the chemical stability of the glass are improved; the alumina can reduce the crystallization tendency, crystallization speed and expansion coefficient of the glass, and improve the viscosity, surface tension, softening temperature, thermal stability, chemical stability and mechanical strength of the glass; the cosolvent can reduce the melting temperature of the glass, reduce the viscosity of the glass liquid and increase the high-temperature fluidity of the glass liquid, so that the glass liquid can flow on the surface of the tin liquid, and the stability of the float glass is improved.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below.
FIG. 1 is a flow chart of a float glass manufacturing process of the present invention.
Detailed Description
Reference will now be made in detail to the embodiments of the present invention, examples of which are illustrated in the accompanying drawings, and the embodiments described below with reference to the accompanying drawings are exemplary and intended to be illustrative of the present invention and should not be construed as limiting the present invention.
Referring to fig. 1, fig. 1 is a flow chart of a method for manufacturing a float glass according to the present invention, and the present invention provides a method for manufacturing a float glass, which includes the following steps:
s1: weighing the following raw materials in percentage by mass: 65 to 77 percent of silicon dioxide, 7 to 11 percent of calcium oxide, 3 to 5 percent of magnesium oxide, 0.6 to 1.3 percent of aluminum oxide, 0.01 to 0.1 percent of ferric oxide and 5 to 12 percent of cosolvent;
correspondingly weighing raw materials in corresponding mass percentage so as to be convenient for preparing the float glass subsequently.
S2: mixing the raw materials, and sequentially melting and clarifying to obtain molten glass;
silica is a main oxide forming the float glass, and forms an irregular continuous network by a structural unit of silicon-oxygen tetrahedron, so that a framework of the glass is formed, the viscosity of the float glass is increased, and the thermal stability and the chemical stability of the float glass are improved; the calcium oxide can accelerate the melting and clarification process of the glass, and improve the mechanical strength, hardness and chemical stability of the glass; the magnesium oxide can reduce the high-temperature viscosity of the magic power, so that the crystallization tendency and the crystallization speed of the glass are reduced, and the mechanical strength, the thermal stability and the chemical stability of the glass are improved; the alumina can reduce the crystallization tendency, crystallization speed and expansion coefficient of the glass, and improve the viscosity, surface tension, softening temperature, thermal stability, chemical stability and mechanical strength of the glass; the cosolvent is one or a mixture of sodium oxide and potassium oxide, and can reduce the melting temperature of glass, reduce the viscosity of molten glass and increase the high-temperature fluidity of the molten glass so as to facilitate the flow of the molten glass on the surface of the molten tin; iron oxide can affect the optical properties of the glass, rendering the glass yellow-green in color. Mixing the prepared raw materials to obtain a mixture, heating the mixture at the high temperature of 1300-1400 ℃ to melt the mixture to obtain a solution, and raising the temperature of the solution to 1400-1550 ℃ to clarify the solution to obtain the molten glass.
S3: floating the molten glass on the surface of the molten tin;
the molten glass continuously flows into the tin bath through the launder, floats on the surface of the molten tin with high relative density and flows on the surface of the molten tin under the action of self gravity and surface tension.
S4: processing the molten glass on the molten tin surface to obtain a glass ribbon;
and under the action of the pulling force of the edge roller and the transition roller table, spreading, flattening and thinning the molten glass on the molten tin surface, and repeatedly operating for many times to form the molten glass into a glass belt with smooth upper and lower surfaces.
S5: the glass ribbon is sequentially annealed and cut to obtain the float glass.
And (3) conveying the glass belt into an annealing kiln to carry out annealing treatment at the temperature of 1000-1100 ℃, and cutting the annealed glass belt as required to obtain float glass.
The invention relates to a method for preparing float glass, which comprises the steps of mixing raw materials of 65-77% of silicon dioxide, 7-11% of calcium oxide, 3-5% of magnesium oxide, 0.6-1.3% of aluminum oxide, 0.01-0.1% of ferric oxide and 5-12% of cosolvent, and sequentially melting and clarifying the raw materials to obtain glass liquid; then floating the molten glass on the surface of the molten tin; then processing the molten glass on the tin liquid surface to obtain a glass ribbon; and finally, sequentially annealing and cutting the glass ribbon to obtain the float glass. Silica is a main oxide forming the float glass, and forms an irregular continuous network by a structural unit of silicon-oxygen tetrahedron, so that a framework of the glass is formed, the viscosity of the float glass is increased, and the thermal stability and the chemical stability of the float glass are improved; the calcium oxide can accelerate the melting and clarification process of the glass, and improve the mechanical strength, hardness and chemical stability of the glass; the magnesium oxide can reduce the high-temperature viscosity of the magic power, so that the crystallization tendency and the crystallization speed of the glass are reduced, and the mechanical strength, the thermal stability and the chemical stability of the glass are improved; the alumina can reduce the crystallization tendency, crystallization speed and expansion coefficient of the glass, and improve the viscosity, surface tension, softening temperature, thermal stability, chemical stability and mechanical strength of the glass; the cosolvent is one or a mixture of sodium oxide and potassium oxide, and can reduce the melting temperature of glass, reduce the viscosity of molten glass and increase the high-temperature fluidity of the molten glass, so that the molten glass can flow on the surface of molten tin conveniently, and the stability of the float glass is improved.
Example 1
Mixing 65% of silicon dioxide, 11% of calcium oxide, 5% of magnesium oxide, 1.3% of aluminum oxide, 0.1% of ferric oxide and 12% of sodium oxide to obtain a mixture; then heating the mixture at 1300 ℃ to melt the mixture to obtain a solution; then, the temperature of the solution is increased to 1550 ℃ so as to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the molten tin surface by adopting an edge roller and a transition roller table, and repeatedly forming the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 2
Mixing raw materials of 67% of silicon dioxide, 8% of calcium oxide, 3% of magnesium oxide, 1.3% of aluminum oxide, 0.1% of ferric oxide and 11% of sodium oxide to obtain a mixture; then heating the mixture at a high temperature of 1400 ℃ to melt the mixture to obtain a solution; then, the temperature of the solution is increased to 1550 ℃ so as to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 3
Mixing raw materials of 69% of silicon dioxide, 9% of calcium oxide, 5% of magnesium oxide, 0.6% of aluminum oxide, 0.02% of ferric oxide and 6% of sodium oxide to obtain a mixture; then heating the mixture at 1300 ℃ to melt the mixture to obtain a solution; subsequently, the temperature of the solution is raised to 1500 ℃ to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 4
Mixing raw materials of 75% of silicon dioxide, 11% of calcium oxide, 4% of magnesium oxide, 1.1% of aluminum oxide, 0.08% of ferric oxide and 10% of sodium oxide to obtain a mixture; then heating the mixture at 1300 ℃ to melt the mixture to obtain a solution; subsequently, the temperature of the solution is raised to 1450 ℃ so as to clarify the solution to obtain molten glass; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 5
Mixing 65% of silicon dioxide, 7% of calcium oxide, 5% of magnesium oxide, 0.6% of aluminum oxide, 0.05% of ferric oxide and 9% of potassium oxide to obtain a mixture; then heating the mixture at a high temperature of 1400 ℃ to melt the mixture to obtain a solution; then, the temperature of the solution is increased to 1400 ℃ to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 6
Mixing raw materials of 70% of silicon dioxide, 7% of calcium oxide, 4% of magnesium oxide, 0.9% of aluminum oxide, 0.09% of ferric oxide and 10% of potassium oxide to obtain a mixture; then heating the mixture at 1350 ℃ to melt the mixture to obtain a solution; then, the temperature of the solution is increased to 1550 ℃ so as to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the molten tin surface by adopting an edge roller and a transition roller table, and repeatedly forming the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 7
Mixing 76% of silicon dioxide, 11% of calcium oxide, 3% of magnesium oxide, 0.6% of aluminum oxide, 0.01% of ferric oxide and 5% of potassium oxide to obtain a mixture; then heating the mixture at 1300 ℃ to melt the mixture to obtain a solution; subsequently, the temperature of the solution is raised to 1400 ℃ to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally, cutting the annealed glass ribbon according to requirements to obtain the float glass.
Example 8
Mixing 77% of silicon dioxide, 7% of calcium oxide, 3% of magnesium oxide, 0.7% of aluminum oxide, 0.04% of ferric oxide and 6% of potassium oxide to obtain a mixture; then heating the mixture at 1300 ℃ to melt the mixture to obtain a solution; then, the temperature of the solution is increased to 1550 ℃ so as to clarify the solution to obtain glass liquid; then floating the molten glass on the surface of the molten tin; spreading, flattening and thinning the molten glass on the tin liquid surface by adopting an edge roller and a transition roller table, and repeatedly molding the molten glass into a glass belt with flat upper and lower surfaces; then the glass belt is sent into an annealing kiln for annealing treatment; and finally cutting the annealed glass ribbon according to requirements to obtain the float glass.
While the above disclosure describes one or more preferred embodiments of the present invention, it is not intended to limit the scope of the claims to such embodiments, and one skilled in the art will understand that all or a portion of the processes performed in the above embodiments may be practiced without departing from the spirit and scope of the claims.

Claims (6)

1. A method for preparing float glass is characterized by comprising the following steps:
weighing the following raw materials in percentage by mass: 65 to 77 percent of silicon dioxide, 7 to 11 percent of calcium oxide, 3 to 5 percent of magnesium oxide, 0.6 to 1.3 percent of aluminum oxide, 0.01 to 0.1 percent of ferric oxide and 5 to 12 percent of cosolvent;
mixing the raw materials, and sequentially melting and clarifying to obtain molten glass;
floating the molten glass on the surface of the molten tin;
processing the molten glass on the molten tin surface to obtain a glass ribbon;
the glass ribbon is sequentially annealed and cut to obtain the float glass.
2. The float glass process of claim 1,
weighing the following raw materials in percentage by mass: 65 to 77 percent of silicon dioxide, 7 to 11 percent of calcium oxide, 3 to 5 percent of magnesium oxide, 0.6 to 1.3 percent of aluminum oxide, 0.01 to 0.1 percent of ferric oxide and 5 to 12 percent of cosolvent:
the cosolvent is one or a mixture of sodium oxide and potassium oxide.
3. The float glass process of claim 2,
the method comprises the following specific steps of mixing the raw materials, sequentially melting and clarifying to obtain molten glass:
mixing the prepared raw materials to obtain a mixture;
heating the mixture at a high temperature of 1300-1400 ℃ to melt the mixture to obtain a solution;
and raising the temperature of the solution to 1400-1550 ℃ to clarify the solution to obtain molten glass.
4. The float glass process of claim 3,
the method for processing the molten glass on the molten tin surface to obtain the glass ribbon comprises the following specific steps:
spreading, flattening and thinning the molten glass on the molten tin surface by adopting an edge roller and a transition roller table;
repeating the above operations for many times to form the molten glass into the glass ribbon with flat upper and lower surfaces.
5. The float glass process of claim 4,
the method comprises the following specific steps of sequentially annealing and cutting the glass ribbon to obtain the float glass:
sending the glass belt into an annealing kiln for annealing treatment;
and cutting the annealed glass ribbon according to requirements to obtain the float glass.
6. The float glass process of claim 5,
in the step of feeding the glass ribbon into an annealing lehr for annealing treatment:
the temperature after the annealing treatment is 1000-1100 ℃.
CN202211406226.2A 2022-11-10 2022-11-10 Float glass preparation method Withdrawn CN115818955A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211406226.2A CN115818955A (en) 2022-11-10 2022-11-10 Float glass preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211406226.2A CN115818955A (en) 2022-11-10 2022-11-10 Float glass preparation method

Publications (1)

Publication Number Publication Date
CN115818955A true CN115818955A (en) 2023-03-21

Family

ID=85527596

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211406226.2A Withdrawn CN115818955A (en) 2022-11-10 2022-11-10 Float glass preparation method

Country Status (1)

Country Link
CN (1) CN115818955A (en)

Similar Documents

Publication Publication Date Title
TWI555709B (en) Apparatus and method for forming glass sheets
JP6983377B2 (en) Glass
CN113024121B (en) Microcrystalline glass plate production process
TW201245070A (en) Method for producing glass plate
CN109336380B (en) Super white glass and its production method and special equipment
WO2013181925A1 (en) Process for preparing glass with low thermal expansion coefficient and glass product prepared thereby
CN109843817B (en) Glass
US10730786B2 (en) Alkali-free glass and method for producing the same
WO2018116731A1 (en) Glass
JP2016113361A (en) Alkali-free glass
CN105837039B (en) A kind of high intensity float glass production method
CN115818955A (en) Float glass preparation method
CN100339321C (en) Apparatus and method for producing float glass having reduced defect density
CN114656142B (en) Flexible glass and preparation method thereof
CN109111104B (en) Boron-aluminum silicate glass and preparation method thereof
JP2022105215A (en) Glass
CN114920447A (en) Preparation method, forming device and product of borosilicate colored glaze with few bubbles
CN111732336B (en) Composition for glass, aluminosilicate glass, and preparation method and application thereof
CN106007343A (en) Production method capable of improving surface roughness of float glass
CN103449705A (en) Production method of borosilicate flat glass
CN209242934U (en) A kind of special equipment producing ultra-clear glasses
CN117902829A (en) Glass composition, glass plate, and preparation method and application of glass plate
JP6631942B2 (en) Alkali-free glass plate
CN112441740A (en) Preparation method of high-transparency high-strength ultrathin medium-alumina glass
CN103274596A (en) Method for preparing alkali-free glass substrate

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20230321

WW01 Invention patent application withdrawn after publication