CN115785727A - Preparation method and preparation device of mineral wool board inorganic coating - Google Patents

Preparation method and preparation device of mineral wool board inorganic coating Download PDF

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CN115785727A
CN115785727A CN202211701906.7A CN202211701906A CN115785727A CN 115785727 A CN115785727 A CN 115785727A CN 202211701906 A CN202211701906 A CN 202211701906A CN 115785727 A CN115785727 A CN 115785727A
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stirring
aggregate
mineral wool
wool board
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CN115785727B (en
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李伟成
陈燕
胡中源
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Dragon Brand Coating Beijing Co ltd
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Dragon Brand Coating Beijing Co ltd
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Abstract

The invention discloses a preparation method of mineral wool board inorganic coating, which comprises the following steps: adding deionized water, and forming vortex under the stirring state of 500-800 r/min; continuously stirring, and pouring the modified sodium bentonite into a water flow vortex at a constant speed; then adding a dispersant A and an amine catching agent; then adding 50% of defoaming agent; then, sequentially adding titanium dioxide, an ammonia absorbent, an aldehyde removing agent, a dispersant B, mineral fibers and functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry; stirring the water slurry at 80-90 r/min, and dropwise adding the inorganic adhesive and the rest 50% of the defoaming agent to obtain a finished product. Also discloses a preparation device for the preparation method of the mineral wool board inorganic coating. The invention does not add bactericide, improves the dry film vapor permeability of the coating by using the inorganic adhesive, and reduces the generation of mould; the invention solves the problem of unstable components in the paint by low-speed paint mixing treatment, so that the paint film can achieve the best ventilation effect.

Description

Preparation method and preparation device of mineral wool board inorganic coating
Technical Field
The invention relates to the technical field of coatings, in particular to a preparation method and a preparation device of an inorganic coating for a mineral wool board.
Background
Because the mineral wool board has good sound absorption and noise reduction effects, the mineral wool board has the advantages of excellent decorative effect, good heat insulation performance, safety, fire prevention, simple and convenient cutting, easy decoration and the like, and is widely applied to a plurality of place suspended ceilings with sound absorption requirements.
However, in the process of use, the mineral wool board emits gases with pungent odor, such as organic amine, ammonia gas and the like, in the processes of spraying and drying on a production line, and after the mineral wool board is used in a damp and hot area, the interior of the mineral wool board is easily affected with damp and mildewed, and black mildewed spots can appear on the board surface. The unpleasant smell is mainly generated by the decomposition of certain components in the mineral wool board in the high-temperature drying process, and the mildew on the surface of the mineral wool board is mainly generated by bacteria breeding in the water-soluble adhesive in the mineral wool board in a high-temperature and humid environment.
If the problem needs to be solved, the simplest way is to coat paint with the functions of sterilization, odor removal and the like on the surface of the mineral wool board to treat decomposition and mildewing in the board in a targeted manner, but the bactericide has certain toxin, the sterilization effect of the bactericide is weakened along with the prolonging of the use time after the bactericide is used, and the paint containing a large amount of bactericide can influence the environment after being scrapped, so that a large amount of pollution is caused.
Therefore, there is a need for a low-toxicity and harmless coating material to simultaneously solve the problems of easy decomposition of harmful substances and easy mildew in a humid environment occurring in a mineral wool board, and a preparation method is mainly provided for preparing the coating material.
Disclosure of Invention
The invention aims to provide a preparation method and a preparation device of mineral wool board inorganic paint, which aim to solve the technical problem that mineral wool boards are easy to go moldy in a high-temperature and humid state in the prior art.
In order to solve the technical problems, the invention specifically provides the following technical scheme:
the invention provides a preparation method of mineral wool board inorganic coating, which comprises the following steps:
adding deionized water, and forming vortex under the stirring state of 500-800 r/min;
continuously stirring, pouring the modified sodium bentonite into a water flow vortex at a constant speed along the stirring chamber in a trickle mode, and stirring for 3-5min;
then adding a dispersant A and an amine catching agent, and dispersing for 2-3min;
then adding 50% of defoaming agent, and stirring for 2-3min;
then, sequentially adding titanium dioxide, an ammonia absorbent, an aldehyde removing agent, a dispersant B, mineral fibers and functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
stirring the water slurry at 80-90 r/min, dropwise adding the inorganic adhesive and the rest 50% of the defoaming agent, and continuously stirring for 10min to obtain a finished product.
As a preferable scheme of the invention, the mineral wool board inorganic coating at least comprises the following components in percentage by weight: 20.15 to 26.4 percent of water, 0.1 to 0.5 percent of modified sodium bentonite, 0.4 to 0.8 percent of dispersant A, 0.1 to 0.3 percent of dispersant B, 0.1 to 0.3 percent of organic amine catcher, 0.05 to 0.2 percent of defoaming agent, 1 to 10 percent of titanium dioxide, 1 to 2 percent of ammonia absorbent, 2 to 5 percent of aldehyde remover, 5 to 8 percent of mineral fiber, 45 to 60 percent of functional filler and 3 to 8 percent of inorganic adhesive;
wherein the inorganic adhesive is prepared from potassium silicate and modified nano-silicon sol according to a mass ratio of 2:1 are mixed.
As a preferable scheme of the invention, the amine capture agent consists of benzenesulfonic acid acyl chloride and a wetting agent in a mass ratio of 1;
wherein the ammonia absorbent consists of a molecular sieve and organic salts in a mass ratio of 1-3;
the modified sodium bentonite comprises sodium carboxymethylcellulose, soda ash and sodium bentonite in a mass ratio of 1;
wherein the functional filler consists of 8 percent by mass: 62%:30% of mica powder, talcum powder and heavy calcium carbonate;
wherein the mineral fiber consists of carbon fiber and gypsum fiber in a mass ratio of 1.
The invention further provides a preparation device of the mineral wool board inorganic coating, which comprises the following components:
the central stirring tank is provided with a stirring chamber for stirring finished products and a variable frequency stirring shaft arranged in the stirring chamber, and the rotating speed of the variable frequency stirring shaft can be changed along with the change of production steps;
the boundary aggregate component is arranged at the tank opening of the central stirring tank and arranged on the inner wall of the central stirring tank in a surrounding manner, and the boundary aggregate component rotates to discharge materials in the central stirring tank;
the quantitative blanking component is used for quantitatively introducing two or more materials into the boundary aggregate component respectively for mixing;
wherein, the material of formation after mixing is all in the drive of boundary aggregate subassembly is followed in proper order in the rotatory unloading of jar mouth department to the stirring chamber of central agitator tank to mix with the original material of stirring chamber indoor.
As a preferable scheme of the present invention, the quantitative blanking assembly, the boundary aggregate assembly and the stirring chamber are sequentially disposed in the central stirring tank from top to bottom.
As a preferred aspect of the present invention, the boundary aggregate assembly includes an annular rail disposed in the central stirring tank and an aggregate casing moving on the annular rail by a driving group, the aggregate casing is disposed in the central stirring tank, an upper end of the aggregate casing is open, and the quantitative discharging assembly passes through the central stirring tank and communicates with the aggregate casing;
be provided with the mixing chamber in the casing that gathers materials, be provided with the stirring roller in the mixing chamber, the bottom of mixing chamber is provided with the feed opening, the feed opening sets up under the stirring roller, works as when the feed opening is opened, the stirring roller drives material in the mixing chamber is followed feed opening department flows.
As a preferred scheme of the invention, the annular track comprises an outer ring attached to the inner wall of the central stirring tank and an inner ring mounted on the outer ring through a plurality of support rods, the outer ring and the inner ring are of concentric circle structures, and the inner ring is arranged above the stirring chamber in a suspended manner;
a hollow annular structure is arranged between the inner ring and the outer ring, and the hollow annular structure is divided into a plurality of hollow blocks by the supporting rod; the drive assembly drives the aggregate shell to move on the inner ring and the outer ring, and the feed opening is arranged on the inner ring and between the outer rings and is arranged right above the hollow annular structure.
As a preferable scheme of the invention, the driving group is arranged at the front half part of the aggregate shell, and when the aggregate shell slides on the inner ring and the outer ring, one end of the aggregate shell far away from the driving group inclines downwards and is in discontinuous contact with the support rod.
As a preferable scheme of the present invention, a position origin is disposed between the outer ring and the quantitative blanking assembly, a position plate is disposed on the position origin, the position plate is mounted on the support rod, and the height of the position plate is equal to the distance between the support rod and the aggregate casing, when the aggregate casing moves to the position origin, the bottom of the aggregate casing is attached to the upper end of the position plate, and the position plate is used for centering the aggregate casing.
As a preferred scheme of the invention, the quantitative blanking assembly comprises a plurality of conveyor belts arranged on the position origin, each conveyor belt is provided with a plurality of storage grooves, and corresponding materials are placed in the storage grooves;
the storage groove is driven by the conveyor belt to sequentially pass through the position origin and pour materials into the aggregate shell when the storage groove is turned over.
Compared with the prior art, the invention has the following beneficial effects:
1. according to the invention, no bactericide is added, the dry film vapor permeability of the coating is improved by using the inorganic adhesive, and volatile organic amine, inorganic ammonia and water vapor in the mineral wool board can be rapidly discharged out of the board along a paint film channel and are not easy to remain, so that the peculiar smell and mildew risk in the mineral wool board are reduced, and the generation of mildew is reduced;
meanwhile, an amine trapping agent and an ammonia gas absorbent are added into the coating, so that the absorption and trapping of volatile organic amine and inorganic ammonia generated by the decomposition of raw materials in the spraying and high-temperature drying processes of the mineral wool board are realized.
2. According to the invention, the coating is produced by continuously converting the stirring speed of the system, so that the occurrence of reactions such as complexation and the like caused by excessive components in the system is prevented, especially in the low-speed paint mixing treatment, the ultra-low-speed treatment is required to be carried out, the inorganic adhesive is added into the homogeneous water slurry for paint mixing, the permeability of a paint film channel after the coating is formed is improved, and the ventilation effect is improved;
3. the invention also realizes the precise mixing and discharging of the mixed dry material and the mixed wet material through a production device which is ready for use in the prior preparation, improves the precision of powder mixing in the coating, meets the requirements of dispersed discharging and dropwise feeding in the production method by using a distributed discharging mode, and has simple device and convenient use.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It should be apparent that the drawings in the following description are merely exemplary, and that other embodiments can be derived from the drawings provided by those of ordinary skill in the art without inventive effort.
FIG. 1 is a schematic flow chart of the preparation method of the mineral wool board inorganic coating provided by the invention;
FIG. 2 is a schematic structural diagram of a preparation device for mineral wool board inorganic coating provided by the invention;
FIG. 3 is a schematic diagram of the present invention in the process of providing movement of the aggregate housing;
FIG. 4 is a schematic view of the present invention providing a construction with the aggregate shell at the origin of position;
fig. 5 is a schematic diagram of a circular track structure provided by the present invention.
The reference numerals in the drawings denote the following, respectively:
1-a central stirred tank; 2-a stirring chamber; 3-frequency conversion stirring shaft; 4-a boundary aggregate component; 5-quantitative blanking assembly; 6-a position correcting plate;
401-circular track; 402-a drive group; 403-an aggregate shell; 404-a mixing chamber; 405-a stirring roller; 405-a feed opening;
4011-the outer loop; 4012-inner ring; 4013-a support bar;
501, a conveyor belt; 502-storage tank.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
The invention provides an inorganic coating for mineral wool boards, which comprises the following components in parts by weight: 20.15 to 26.4 percent of water, 0.1 to 0.5 percent of modified sodium bentonite, 0.4 to 0.8 percent of dispersant A, 0.1 to 0.3 percent of dispersant B, 0.1 to 0.3 percent of amine catcher, 0.05 to 0.2 percent of defoamer, 1 to 10 percent of titanium dioxide, 1 to 2 percent of ammonia absorbent, 2 to 5 percent of formaldehyde remover, 5 to 8 percent of mineral fiber, 45 to 60 percent of functional filler and 3 to 8 percent of inorganic adhesive.
In order to improve the ventilation effect of the coating, the inorganic adhesive is potassium silicate and modified nano silica sol in a mass ratio of 2:1 are mixed.
The inorganic silicate adhesive is selected from mineral wool coating, so that the vapor permeability of a coating film is improved, when the mineral wool board is finished, residual gas is volatilized in the board due to moisture absorption in a high-temperature and humid area in the south, the gas is quickly volatilized outside the coating, and the gas is volatilized along with flowing air, so that the moisture is prevented from being residual, and the mildew is prevented. Thereby reducing the use of bactericides and reducing the biological pollution to the environment.
Meanwhile, an amine trapping agent and an ammonia gas absorbent are added into the basic formula of the coating, amine gases and ammonia gas volatilized in a coating production line of the mineral wool board and after home decoration are effectively trapped and absorbed, and volatilization of harmful substances in the mineral wool board and generation of unpleasant odor are greatly reduced.
Furthermore, in order to remove volatile organic amine bad smell gas generated by the decomposition of raw materials in the mineral wool board under the high-temperature environment, the amine catching agent consists of benzenesulfonic acid acyl chloride and a wetting agent in a mass ratio of 1. The benzenesulfonic acid acyl chloride is used as an organic amine trapping agent, when the organic amine is generated, the benzenesulfonic acid acyl chloride reacts with the organic amine to generate solid amine, and the solid amine is not easy to volatilize in the air.
In order to increase the dispersibility of the benzenesulfonic acid chloride, the amine scavenger is a liquid material that is more easily dispersed in the coating during production. Meanwhile, in order to improve the dispersity of the benzenesulfonic acid acyl chloride, the wetting agent is any one or more of polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer.
Furthermore, in order to remove volatile inorganic ammonia-type unpleasant odor generated by the decomposition of raw materials in the mineral wool board under the high-temperature environment, the ammonia absorbent consists of a molecular sieve and organic salts in a mass ratio of 1. The molecular sieve is natural zeolite. In order to increase the mildew-proof effect of the coating, one or more of organic salts sodium ethoxide.
In conclusion, the organic amine catching agent and the ammonia absorbent are added into the coating, when the organic amine and the ammonia volatilize to the coating under the high-temperature drying condition, the organic amine and the ammonia absorbent rapidly perform adsorption chemical reaction with the amine catching agent and the ammonia absorbent in the coating to generate solid salt, and simultaneously form a compact three-dimensional network structure with the inorganic adhesive, and the three-dimensional network structure ensures that most volatile gas is absorbed in a coating film to form a paint film component in the spraying and drying process of the mineral wool board coating, and the unpleasant gas discharged to the external environment is very little. In southern high-temperature humid areas, because organic amine salt and inorganic ammonia salt in the paint film are strongly combined with silicon oxygen bonds of the inorganic adhesive, the paint film cannot be decomposed for the second time to generate volatile organic amine and inorganic ammonia.
Furthermore, in order to increase the aldehyde removing performance of the mineral wool, the aldehyde removing agent is an organic salt powder material, and the aldehyde removing agent is added in the formula of the mineral wool coating material, so that a paint film has the aldehyde removing performance.
Wherein, the organic salt is one or more of sodium oxalate and ethylamine chloride salt, and active groups in the sodium oxalate and the ethylamine chloride salt can replace active hydrogen in aldehyde group to enable aldehyde substances to generate non-aldehyde substances.
Further, the modified sodium bentonite comprises sodium carboxymethylcellulose, soda ash and sodium bentonite in a mass ratio of 1. Sometimes, the color difference and the effect of paint films of different plates of the same batch of paint are not ensured, and a plurality of times of examination finds that the paint film inconsistency of the type is caused by serious layering of the paint due to the fact that the paint is diluted to the viscosity suitable for automatic spraying before use and a large amount of water is required to be added, so that the solid content of the paint on different mineral wool plates and even the proportion of each component in the paint are changed, and the paint films of different plates are inconsistent. The method for solving the problem is to select the modified sodium bentonite as the modified sodium bentonite, so that the coating has good anti-settling effect when diluted by adding water, and the components in the coating are uniformly distributed. The modified sodium bentonite contains 5 percent of sodium carboxymethylcellulose, 5 percent of soda ash and 90 percent of sodium bentonite, and the raw materials of the modified sodium bentonite, the soda ash and the modified sodium bentonite are uniformly mixed in advance during preparation.
Preferably, in order to reduce the phenomenon of paint film blooming, the functional filler is composed of mica powder, talcum powder and heavy calcium carbonate in a mass ratio of 4. The mica powder, the talcum powder and the heavy calcium carbonate are matched according to the components, so that the light reflection of each point of the paint film is consistent after the paint film is dried, the blooming of the paint film is reduced, and meanwhile, the functional powder material does not contain free polyvalent metal ions.
Because the lower the gloss of the paint film on the surface layer of the mineral wool board, the less obvious the color difference of the paint film of the unit board or the plurality of boards, in order to further reduce the gloss of the paint film, the particle size distribution of the powder material needs to be strictly controlled, and the test data shows that the particle size distribution of the powder material in the formula of the mineral wool board paint is as follows, the gloss of the paint film is proper, and the paint film is uniform and does not bloom: d10 is between 1.3 and 2.8, D50 is between 12 and 18, and D90 is between 30 and 38.
Secondly, by adding the mica powder and utilizing the lamellar structure, the powder material particles and other component particles in the paint are uniformly, stably and scientifically distributed, so that the powder particles in the paint film are arranged alternately, the water is not densely piled under the condition of fast volatilization, and the gloss of the paint film is effectively reduced. Meanwhile, because the particles in the paint film are uniformly distributed and the scattering effect is consistent, the paint film has consistent gloss and does not generate flowers, and in addition, the mica powder can assist in improving the anti-settling property of the paint system.
Further, in order to improve the sound absorption and noise reduction effects of the mineral wool board, the mineral fibers consist of carbon fibers and gypsum fibers in a mass ratio of 1.
In order to improve the solid content in the coating, so that the coating is closed, the basic surface of the mineral wool board covered by the coating is strong in porous rough performance, the paint film is strong in fullness and good in hand feeling, the viscosity of the coating is low to facilitate spraying construction, and the dispersing agent A is sodium polyacrylate; the dispersant B is powdery sodium phosphate.
The water is one or more of drinking water, purified water or deionized water. Water is an indispensable component in mineral wool board coating, and drinking water is selected as a formula component in order to reduce the cost of raw materials.
Preferably, the defoaming agent is liquid organosilicon material, and in order to prevent the paint film sprayed on the mineral wool board from shrinking, the defoaming agent is selected according to the invention.
Preferably, the titanium dioxide is rutile type, and a certain amount of rutile titanium dioxide is added in the formula in order to improve the covering power of the product.
In summary, the mineral wool board inorganic coating provided by the invention has the following beneficial effects and performances:
1. the volatilization of harmful gases and bad smelling gases is reduced:
1. organic amine catching agents and ammonia absorbents are added into the coating, and the coating and volatile organic amine and ammonia are subjected to adsorption chemical reaction, so that the organic amine and the ammonia are changed into solid salts, and volatile bad smelling gases of the mineral wool coating are removed:
2. the inorganic adhesive forms a compact three-dimensional network structure, most volatile gas is absorbed in the coating film to form a paint film component, volatilization of unpleasant gas is reduced, and organic amine salt and inorganic ammonia salt in the paint film are strongly combined with silicon oxygen bonds of the inorganic adhesive, so that the paint film cannot be decomposed for the second time to generate volatile organic amine and inorganic ammonia.
2. Mildew-proof and antibacterial:
1. the inorganic silicate adhesive is selected from mineral wool coating, so that the coating film has excellent vapor permeability, moisture volatilization is facilitated, and mildew spots are prevented;
2. the inorganic silicate adhesive used has strong alkalinity, and simultaneously has large reaction activity to react with most materials including water, so the mildew-proof and antibacterial properties are extremely excellent, a special mildew preventive and a fungicide are not required to be added, and compared with an organic adhesive coating, the inorganic adhesive coating has good vapor permeability, water vapor in the mineral wool board is quickly volatilized, the time for drying is short, and mildew is not generated in a water-soluble polymer material which is easy to mildew in the mineral wool board because the water vapor in the board is sealed in the inorganic adhesive coating for a long time in a humid environment;
3. the aldehyde removing agent and the ammonia gas absorbent are alkaline, and are effective in mildew prevention and bacteria resistance.
3. Sound absorption performance:
the mineral wool board sound absorption and noise reduction function is improved by adding mineral fibers in the formula.
4. Aldehyde removal performance:
the mineral wool board coating has the aldehyde removal performance mainly by adding the aldehyde removal auxiliary agent in the formula.
5. The decoration effect is good:
1. by adding two dispersants, namely sodium polyacrylate and powdery sodium phosphate, the powdery sodium phosphate dispersant can effectively reduce the viscosity of the coating slurry, improve the solid content under the same viscosity, improve the fullness and dry film covering power of a paint film, and effectively cover the unevenness and porous defects of a substrate, so that the expected paint film effect can be achieved by two-time spraying, and meanwhile, the painting amount of each plate can be reduced to reduce the cost;
2. mineral oil defoaming is added into the paint formula, so that the occurrence of the phenomenon of paint film floating is reduced;
3. by adding the modified sodium bentonite, the layering phenomenon of the paint is reduced, and the color difference and the effect of a paint film are prevented from being caused;
4. the paint film gloss is effectively reduced by strictly controlling the particle size distribution of the powder material and adding the mica powder, and meanwhile, the paint film gloss is consistent and the paint film gloss does not bloom because the particles in the paint film are uniformly distributed and the scattering effect is consistent.
6. And (3) system stabilization:
all components in the formula of the invention do not contain polyvalent metal ions, thereby improving the stability of the system.
The invention mainly discloses a preparation method of mineral wool board inorganic coating, which comprises the following steps:
adding deionized water, and forming vortex under the stirring state of 500-800 r/min;
continuously stirring, pouring the modified sodium bentonite into the water flow vortex at a constant speed along the stirring cavity in a trickle mode, and stirring for 3-5min;
then adding a dispersant A and an amine catching agent, and dispersing for 2-3min;
then adding 50% of defoaming agent, and stirring for 2-3min;
then, sequentially adding titanium dioxide, an ammonia absorbent, an aldehyde removing agent, a dispersant B, mineral fibers and functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
stirring the water slurry at 80-90 r/min, dropwise adding the inorganic adhesive and the rest 50% of the defoaming agent, and continuously stirring for 10min to obtain a finished product.
Mainly, in order to improve the dispersity of the modified sodium bentonite, the modified sodium bentonite is poured into a water flow vortex at a constant speed along a stirring cavity in a trickle mode, so that the pH value of a water system is improved as soon as possible, and excessive stirring is prevented; and the paint mixing is more stable and is not easy to modify by accurately regulating and controlling the stirring speed. According to the above production method, three are provided below as examples.
The present invention will be described in further detail with reference to specific embodiments below:
example 1:
1. calculated on 100kg total product weight: 20.15kg of water, 0.1kg of modified sodium bentonite, 0.8kg of dispersing agent, 0.3kg of dispersing agent, 0.1kg of amine capturing agent, 0.05kg of defoaming agent, 1kg of titanium dioxide, 1kg of ammonia absorbent, 5kg of aldehyde removing agent, 8kg of mineral fiber, 60kg of functional filler and 3.5kg of inorganic adhesive are weighed.
2. Adding 20.15kg of deionized water, and forming vortex under the stirring state of 500-800 revolutions per minute;
3. continuously stirring, pouring 0.1kg of modified sodium bentonite into the water flow vortex at a constant speed along the stirring cavity in a trickle mode, and stirring for 3-5min;
4. then 0.8kg of dispersant A and 0.1kg of amine capture agent are added for dispersing for 2-3min;
5. then adding 0.025kg of defoaming agent, and stirring for 2-3min;
6. then sequentially adding 1kg of titanium dioxide, 1kg of ammonia absorbent, 5kg of aldehyde removing agent, 0.3 g of dispersing agent B, 8kg of mineral fiber and 60kg of functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
7. the slurry was stirred at 80-90 rpm, 3.5kg of the inorganic adhesive and the remaining 0.025kg of the antifoaming agent were added dropwise, and stirring was continued for 10min to obtain example 1.
Example 2:
1. calculated on 100kg total product weight: weighing 22.5kg of water, 0.3kg of modified sodium bentonite, 0.6kg of dispersing agent A0.6kg, 0.2kg of dispersing agent B0.2kg, 0.2kg of amine capture agent, 0.125kg of defoaming agent, 5.5kg of titanium dioxide, 1.5kg of ammonia absorbent, 3.5kg of aldehyde removing agent, 6.5kg of mineral fiber, 50kg of functional filler and 5.5kg of inorganic adhesive;
2. adding 22.5kg of deionized water, and forming vortex under the stirring state of 500-800 r/min;
3. continuously stirring, pouring 0.3kg of modified sodium bentonite into the water flow vortex at a constant speed along the stirring cavity in a trickle mode, and stirring for 3-5min;
4. then 0.6kg of dispersant A and 0.2kg of amine capture agent are added for dispersing for 2-3min;
5. then adding 0.0625kg of defoaming agent, and stirring for 2-3min;
6. then, sequentially adding 5.5kg of titanium dioxide, 1.5kg of ammonia absorbent, 3.5kg of formaldehyde remover, 0.2kg of dispersant B, 6.5kg of mineral fiber and 50kg of functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
7. the slurry was stirred at 80-90 rpm, 5.5kg of inorganic adhesive and the remaining 0.0625kg of defoamer were added dropwise, and stirring was continued for 10min to obtain example 2.
Example 3:
1. calculated on 100kg total product weight: weighing 26.4kg of water, 0.5kg of modified sodium bentonite, 0.4kg of dispersing agent A0.4kg, 0.1kg of dispersing agent B0.3kg of amine capturing agent, 0.3kg of defoaming agent, 10kg of titanium dioxide, 2kg of ammonia absorbent, 2kg of aldehyde removing agent, 5kg of mineral fiber, 45kg of functional filler and 8kg of inorganic adhesive;
2. adding 26.4kg of deionized water, and forming vortex under the stirring state of 500-800 r/min;
3. continuously stirring, pouring 0.5kg of modified sodium bentonite into the water flow vortex at a constant speed along the stirring cavity in a trickle mode, and stirring for 3-5min;
4. then 0.4kg of dispersant A and 0.3kg of amine capture agent are added for dispersing for 2-3min;
5. then adding 0.15kg of defoaming agent, and stirring for 2-3min;
6. then, sequentially adding 10kg of titanium dioxide, 2kg of ammonia absorbent, 2kg of aldehyde removing agent, 0.1kg of dispersing agent B, 5kg of mineral fiber and 45kg of functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
7. the slurry was stirred at 80-90 rpm, 8kg of inorganic adhesive and the remaining 0.15kg of defoamer were added dropwise, and stirring was continued for 10min to obtain example 3.
The performance index of the product of the above examples 1-3 meets the requirement of the internal control index, as shown in table 1.
TABLE 1
Figure BDA0004024258580000111
Figure BDA0004024258580000121
1. Mineral wool board inorganic coating physical property index (execute GB/T9756-2018 synthetic resin emulsion interior wall coating standard)
TABLE 2
Figure BDA0004024258580000122
As is clear from Table 2, examples 1, 2 and 3 all had good brushing properties.
2. Mineral wool board inorganic coating environmental performance index (execute GB18582-2020 Standard of Limited harmful substance in wall coating for building)
TABLE 3
Figure BDA0004024258580000123
Figure BDA0004024258580000131
As is clear from table 3, no harmful substance was detected in any of examples 1, 2 and 3.
3. Mineral wool board inorganic coating antibacterial and mildewproof performance index (executing HG/T3950-2007 Standard of antibacterial coating)
TABLE 4
Figure BDA0004024258580000132
As is clear from table 4, examples 1, 2 and 3 all had strong antibacterial and antifungal properties.
4. Mineral wool board inorganic coating combustion performance index (execute GB8624-2012 'building material and product combustion performance grading' standard)
TABLE 5
Figure BDA0004024258580000141
5. Mineral wool board inorganic coating formaldehyde-removing performance index (execution JC/T1074-2008 "indoor air purification function coating material purification performance" standard)
TABLE 6
Figure BDA0004024258580000142
As can be seen from table 6, examples 1, 2 and 3 all had good formaldehyde-removing performance, and the formaldehyde-removing performance was gradually improved as the amount of the formaldehyde scavenger in the formulation was increased.
In the invention, the paint is produced by continuously converting the stirring speed of the system, the reactions such as complexation and the like caused by excessive components in the system are prevented, particularly, in the low-speed paint mixing treatment, the ultra-low-speed treatment is needed to add the inorganic adhesive into the homogeneous water slurry for paint mixing, so that the permeability of a paint film channel after the film formation of the paint is improved, and the ventilation effect is improved.
In the preparation method, the adopted materials have extremely high requirements on stirring speed and mixing of the materials, the modified sodium bentonite and the functional filler are required to be prepared at present and have very accurate production proportion, in order to achieve the production effect, the modified sodium bentonite is composed of sodium carboxymethylcellulose, soda ash and sodium bentonite with the mass ratio of 1: 62%:30 percent of mica powder, talcum powder and heavy calcium carbonate.
If a large amount of powder is prepared in advance, the dispersion degree of certain powder in the system is low, and the final production effect is influenced during batch production; if the mixing is directly carried out on site in production, corresponding mixing tools are lacked, and the mixing of the powder is very accurate and difficult to control, so that a production device is also needed to improve the existing production device.
As shown in fig. 2 to 5, the present invention also provides a preparation apparatus of an inorganic coating material for a mineral wool board, comprising a central stirring tank 1, a boundary aggregate component 4 disposed on the central stirring tank 1, and a quantitative blanking component 5 disposed on the boundary aggregate component 4.
The central stirring tank 1 is provided with a stirring chamber 2 for stirring finished products and a variable frequency stirring shaft 3 arranged in the stirring chamber 2, the rotating speed of the variable frequency stirring shaft 3 can be changed along with the change of the production steps, and a plurality of quantitative discharging pipes are communicated with the stirring chamber 2 and used for discharging other types of liquid and other materials.
The boundary aggregate component 4 is arranged at the tank opening of the central stirring tank 1 and is arranged on the inner wall of the central stirring tank 1 in a surrounding manner, and the boundary aggregate component 4 rotates and discharges in the central stirring tank 1.
The quantitative blanking component 5 respectively quantitatively introduces two or more materials into the boundary aggregate component 4 for mixing.
Wherein, the material of formation after mixing all is in the rotatory unloading of jar mouth department to stirring chamber 2 of central agitator tank 1 under the drive of boundary aggregate subassembly 4 in proper order to mix with the original material in stirring chamber 2.
The quantitative blanking component 5 can not only mix two or more dry powder materials into the boundary aggregate component 4, but also perform distributed blanking at the boundary of the stirring chamber 2 after mixing uniformly, such as modified sodium bentonite, functional filler and mineral fiber. And the powder materials such as the amine capture agent and the inorganic adhesive and the liquid can be discharged, after the materials are discharged into the boundary aggregate component 4, the materials are uniformly mixed in the boundary aggregate component 4, and after the materials are uniformly mixed, the materials move around the tank opening of the central stirring tank 1, and are gradually discharged into the stirring chamber 2, so that the dispersion degree of the materials in the solution is improved.
And because the inorganic adhesive is subjected to a small amount of dropwise feeding in the paint mixing process, the inorganic adhesive is put into the boundary aggregate component 4 for feeding, so that the requirement of dropwise feeding can be met, other elements for dropwise feeding are not required to be added, and the multipurpose of the boundary aggregate component 4 is realized.
The basic principle of the ammonia absorbent, the modified sodium bentonite, the functional filler, the mineral fiber and the inorganic adhesive are respectively introduced into the boundary aggregate component 4 through the quantitative blanking component 5, the ammonia absorbent, the modified sodium bentonite, the functional filler, the mineral fiber and the inorganic adhesive are mixed and stirred in the boundary aggregate component 4 to form the corresponding ammonia absorbent, the modified sodium bentonite, the functional filler, the mineral fiber and the inorganic adhesive, and the materials directly fall into the stirring chamber from the boundary aggregate component 4 after the mixing is completed. The quantitative blanking assembly 5, the boundary aggregate assembly 4 and the stirring chamber 2 are sequentially arranged in the central stirring tank 1 from top to bottom.
Place carboxymethylcellulose sodium, soda, sodium bentonite respectively according to corresponding parts in ration unloading subassembly 5 soon, through unloading once, the mass ratio is 1.
Specifically, in order to more conveniently realize boundary distributed blanking, the boundary aggregate component 4 comprises an annular rail 401 arranged in the central stirring tank 1 and an aggregate shell 403 moving on the annular rail 401 through a driving group 402, the aggregate shell 403 is arranged in the central stirring tank 1, the upper end of the aggregate shell 403 is open, and the quantitative blanking component 5 is communicated with the aggregate shell 403 through the central stirring tank 1.
Be provided with mixing chamber 404 in the aggregate casing 403, be provided with stirring roller 405 in mixing chamber 404, mixing chamber 404's bottom is provided with feed opening 406, and feed opening 406 sets up under stirring roller 405, and when feed opening 406 was opened, stirring roller 405 drove the material in mixing chamber 404 and flows out from feed opening 406.
When the material needs to be fed, the aggregate shell 403 circularly moves in the stirring chamber 2 along the circular track 401, and when the stirring roll 405 is opened due to the movement, the material enters the feeding port 406 under the driving of the stirring roll 405, and flows into the stirring chamber 2 from the feeding port 406, so that the process of pouring the modified sodium bentonite into the water flow vortex at a constant speed along the stirring chamber in a trickle manner is realized.
In order to prevent that annular track 401 from blockking the unloading of material, annular track 401 includes outer loop 4011 of laminating on 1 inner wall of central agitator tank and installs inner ring 4012 on outer loop 4011 through a plurality of bracing piece 4013, and outer loop 4011 and inner ring 4012 are the concentric circle structure, and the unsettled setting of inner ring 4012 is in the top of stirring cavity 2.
A hollow annular structure is arranged between the inner ring 4012 and the outer ring 4011 and is divided into a plurality of hollow blocks by a support rod 4013; the driving group 402 drives the aggregate housing 403 to move on the inner ring 4012 and the outer ring 4011, and the feed opening 406 is arranged between the inner ring 4012 and the outer ring 4011 and is arranged right above the hollowed-out ring-shaped structure.
In particular, compared with the ordinary blanking, the ordinary blanking mode can only support the complete blanking of dry materials, and in order to simultaneously support the complete blanking of wet materials with certain viscosity from the aggregate housing 403, the driving group 402 is arranged at the front half part of the aggregate housing 403, and when the aggregate housing 403 slides on the inner ring 4012 and the outer ring 4011, one end of the aggregate housing 403 far away from the driving group 402 inclines downwards and is in intermittent contact with the supporting rod 4013.
When the aggregate shell 403 is inclined, the feed opening 406 is arranged at the lowest point of the aggregate shell 403, and when the aggregate shell 403 is struck in the moving process, the vibration occurs, so that the materials in the mixing chamber 404 are shaken out from the feed opening 406, and the materials can be concentrated at the bottom of the mixing chamber 404, thereby facilitating the subsequent blanking.
In order to prevent the quantitative blanking assembly 5 from being in a tilting state during blanking, the aggregate shell 403 is also in a tilting state, blanking is inconvenient, a position origin is arranged between the outer ring 4011 and the quantitative blanking assembly 5, a position plate 6 is arranged on the position origin, the position plate 6 is arranged on the supporting rod 4013, the height of the position plate 6 is equal to the distance between the supporting rod 4013 and the aggregate shell 403, when the aggregate shell 403 moves to the position origin, the bottom of the aggregate shell 403 is attached to the upper end of the position plate 6, the position plate 6 is used for righting the aggregate shell 403, each time the aggregate shell 403 passes through the position origin, the aggregate shell 403 is in a horizontal state, and the aggregate shell 403 finishes feeding at the position origin.
Specifically, the quantitative blanking assembly 5 has the following structure: quantitative unloading subassembly 5 includes that a plurality of sets up the conveyer belt 501 on the position initial point, all is provided with a plurality of storing groove 502 on every conveyer belt 501, has placed corresponding material in the storing groove 502, and storing groove 502 is in proper order through the position initial point under the drive of conveyer belt 501 and pours the material into to the casing 403 that gathers materials when turning over.
If mica powder, talcum powder and heavy calcium carbonate with the mass ratio of 4.
By the preparation method and the preparation device of the inorganic coating for the mineral wool board, the absorption and capture of volatile organic amine and inorganic ammonia generated by the decomposition of raw materials in the board caused by the fact that water in the coating is soaked into the interior of the mineral wool board in the processes of spraying and high-temperature drying can be realized; meanwhile, the inorganic coating has the performances of sound absorption, noise reduction and aldehyde removal, is antibacterial and mildewproof, and well solves the problem of mildew spots on the surface of the mineral wool board in southern areas; the invention solves the problem of unstable components through low-speed paint mixing treatment and distributed blanking, and improves the dispersion degree of the paint under the premise of low system stirring speed, so that the paint achieves the optimal paint film effect.
The above embodiments are only exemplary embodiments of the present application, and are not intended to limit the present application, and the protection scope of the present application is defined by the claims. Various modifications and equivalents may be made by those skilled in the art within the spirit and scope of the present application and such modifications and equivalents should also be considered to be within the scope of the present application.

Claims (10)

1. The preparation method of the mineral wool board inorganic coating is characterized by comprising the following steps:
adding deionized water, and forming vortex under the stirring state of 500-800 r/min;
continuously stirring, pouring the modified sodium bentonite into a water flow vortex at a constant speed along the stirring chamber in a trickle mode, and stirring for 3-5min;
then adding a dispersant A and an amine catching agent, and dispersing for 2-3min;
then adding 50% of defoaming agent, and stirring for 2-3min;
then, sequentially adding titanium dioxide, an ammonia absorbent, an aldehyde removing agent, a dispersant B, mineral fibers and functional filler, and stirring at 1300-1450 revolutions per minute to prepare water slurry;
stirring the water slurry at 80-90 r/min, dropwise adding the inorganic adhesive and the rest 50% of the defoaming agent, and continuously stirring for 10min to obtain a finished product.
2. The method for preparing the mineral wool board inorganic coating according to claim 1, wherein the mineral wool board inorganic coating comprises at least the following components in percentage by weight: 20.15 to 26.4 percent of water, 0.1 to 0.5 percent of modified sodium bentonite, 0.4 to 0.8 percent of dispersant A, 0.1 to 0.3 percent of dispersant B, 0.1 to 0.3 percent of organic amine catcher, 0.05 to 0.2 percent of defoamer, 1 to 10 percent of titanium dioxide, 1 to 2 percent of ammonia absorbent, 2 to 5 percent of formaldehyde remover, 5 to 8 percent of mineral fiber, 45 to 60 percent of functional filler and 3 to 8 percent of inorganic adhesive;
wherein the inorganic adhesive is prepared from potassium silicate and modified nano-silicon sol according to a mass ratio of 2:1 are mixed.
3. The method for preparing the mineral wool board inorganic coating according to the claim 1, characterized in that the amine catching agent consists of benzenesulfonic acid acyl chloride and wetting agent in the mass ratio of 1;
wherein the ammonia absorbent consists of a molecular sieve and organic salts in a mass ratio of 1-3;
the modified sodium bentonite comprises sodium carboxymethylcellulose, soda ash and sodium bentonite in a mass ratio of 1;
wherein the functional filler is prepared from the following components in percentage by mass of 8%:62%:30% of mica powder, talcum powder and heavy calcium carbonate;
wherein the mineral fiber consists of carbon fiber and gypsum fiber in a mass ratio of 1.
4. A device for preparing mineral wool board inorganic coating according to the preparation method of any one of claims 1 to 3, characterized by comprising:
the central stirring tank (1) is provided with a stirring chamber (2) for stirring finished products and a variable frequency stirring shaft (3) arranged in the stirring chamber (2), and the rotating speed of the variable frequency stirring shaft (3) can be changed along with the change of production steps;
the boundary aggregate component (4) is arranged at the tank opening of the central stirring tank (1) and is arranged on the inner wall of the central stirring tank (1) in a surrounding manner, and the boundary aggregate component (4) rotationally feeds materials in the central stirring tank (1);
the quantitative blanking component (5) is used for quantitatively introducing two or more materials into the boundary aggregate component (4) respectively for mixing;
the mixed materials are driven by the boundary aggregate component (4) to sequentially feed from the tank opening of the central stirring tank (1) into the stirring chamber (2) and are mixed with the original materials in the stirring chamber (2).
5. The apparatus for preparing mineral wool board inorganic coating according to claim 4, characterized in that the quantitative blanking assembly (5), the boundary aggregate assembly (4) and the stirring chamber (2) are arranged in the central stirring tank (1) from top to bottom.
6. The preparation device of mineral wool board inorganic coating according to claim 5, characterized in that the boundary aggregate component (4) comprises an annular rail (401) arranged in the central agitator tank (1) and an aggregate shell (403) moved on the annular rail (401) by a drive group (402), the aggregate shell (403) is arranged in the central agitator tank (1), the upper end of the aggregate shell (403) is open, and the quantitative blanking component (5) is communicated with the aggregate shell (403) through the central agitator tank (1);
be provided with mixing chamber (404) in the casing (403) gathers materials, be provided with stirring roller (405) in mixing chamber (404), the bottom of mixing chamber (404) is provided with feed opening (406), feed opening (406) set up stirring roller (405) under, when feed opening (406) are opened, stirring roller (405) drive material in mixing chamber (404) is followed feed opening (406) department flows.
7. The preparation device of inorganic coating of mineral wool board according to claim 6, characterized in that the circular orbit (401) comprises an outer ring (4011) attached to the inner wall of the central mixing tank (1) and an inner ring (4012) mounted on the outer ring (4011) through a plurality of support rods (4013), the outer ring (4011) and the inner ring (4012) are concentric circles, and the inner ring (4012) is suspended above the mixing chamber (2);
a hollow annular structure is arranged between the inner ring (4012) and the outer ring (4011), and the hollow annular structure is divided into a plurality of hollow blocks by the supporting rod (4013); the drive group (402) drives the aggregate shell (403) to move on the inner ring (4012) and the outer ring (4011), and the feed opening (406) is arranged between the inner ring (4012) and the outer ring (4011) and is arranged right above the hollowed-out annular structure.
8. The preparation device of mineral wool board inorganic coating of claim 7, characterized in that the driving group (402) is arranged at the front half part of the aggregate housing (403), and when the aggregate housing (403) slides on the inner ring (4012) and the outer ring (4011), one end of the aggregate housing (403) away from the driving group (402) inclines downwards and is in intermittent contact with the supporting rod (4013).
9. The preparation device of mineral wool board inorganic coating of claim 8, characterized in that a position origin is provided between the outer ring (4011) and the quantitative blanking assembly (5), a position plate (6) is provided on the position origin, the position plate (6) is installed on a support rod (4013) and the height of the position plate (6) is equal to the distance between the support rod (4013) and the aggregate casing (403), when the aggregate casing (403) moves to the position origin, the bottom of the aggregate casing (403) is attached to the upper end of the position plate (6), and the position plate (6) is used for righting the aggregate casing (403).
10. The preparation device of mineral wool board inorganic coating according to claim 9, characterized in that the quantitative blanking assembly (5) comprises a plurality of conveyor belts (501) arranged on the origin of the position, each conveyor belt (501) is provided with a plurality of storage grooves (502), and corresponding materials are placed in the storage grooves (502);
the storage groove (502) is driven by the conveyor belt (501) to sequentially pass through the position origin and pour the materials into the aggregate shell (403) when the materials are turned over.
CN202211701906.7A 2022-12-28 2022-12-28 Preparation method and preparation device of mineral wool board inorganic coating Active CN115785727B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104150822A (en) * 2014-07-22 2014-11-19 中铁隧道集团有限公司 Thixotropic slurry and preparation method thereof
CN104774514A (en) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 Low-volatility organic compound smell removing coating capable of adsorbing and decomposing formaldehyde in air and preparation method thereof
CN111229080A (en) * 2018-11-29 2020-06-05 黎统兵 Automatic change food ration agitated vessel
CN113750651A (en) * 2021-09-26 2021-12-07 杭州巴贝克科技有限公司 Filter material with antibacterial and deodorizing functions and preparation method thereof
CN114702845A (en) * 2022-04-18 2022-07-05 龙牌涂料(北京)有限公司 Interior wall inorganic coating prepared from organic-inorganic composite emulsion and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104150822A (en) * 2014-07-22 2014-11-19 中铁隧道集团有限公司 Thixotropic slurry and preparation method thereof
CN104774514A (en) * 2015-04-29 2015-07-15 富思特新材料科技发展股份有限公司 Low-volatility organic compound smell removing coating capable of adsorbing and decomposing formaldehyde in air and preparation method thereof
CN111229080A (en) * 2018-11-29 2020-06-05 黎统兵 Automatic change food ration agitated vessel
CN113750651A (en) * 2021-09-26 2021-12-07 杭州巴贝克科技有限公司 Filter material with antibacterial and deodorizing functions and preparation method thereof
CN114702845A (en) * 2022-04-18 2022-07-05 龙牌涂料(北京)有限公司 Interior wall inorganic coating prepared from organic-inorganic composite emulsion and preparation method thereof

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