CN115744975B - Zirconium tetrachloride apparatus for producing - Google Patents
Zirconium tetrachloride apparatus for producing Download PDFInfo
- Publication number
- CN115744975B CN115744975B CN202211345938.8A CN202211345938A CN115744975B CN 115744975 B CN115744975 B CN 115744975B CN 202211345938 A CN202211345938 A CN 202211345938A CN 115744975 B CN115744975 B CN 115744975B
- Authority
- CN
- China
- Prior art keywords
- outlet
- inlet
- controller
- value
- detector
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 title claims abstract description 36
- 238000000926 separation method Methods 0.000 claims abstract description 60
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 54
- 239000000460 chlorine Substances 0.000 claims abstract description 54
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 39
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 36
- 239000002994 raw material Substances 0.000 claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 230000005540 biological transmission Effects 0.000 claims abstract description 14
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000012265 solid product Substances 0.000 claims description 46
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 11
- 239000006227 byproduct Substances 0.000 claims description 11
- 230000007423 decrease Effects 0.000 claims description 10
- 238000004891 communication Methods 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 7
- 238000007790 scraping Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 238000007599 discharging Methods 0.000 abstract description 10
- 239000007789 gas Substances 0.000 description 36
- 238000000034 method Methods 0.000 description 8
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 6
- 239000002006 petroleum coke Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 229910052845 zircon Inorganic materials 0.000 description 5
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention provides a zirconium tetrachloride production device, which comprises: the feeding assembly comprises a feeding assembly stirrer; a chlorine supply assembly; a chlorination furnace provided with a heater; the filter is provided with a filter element; a first separation tank provided with a cold separator; a gas treatment assembly provided with a reducing agent; the transmission assembly is provided with a conveyor belt; a discharging box; and a controller. According to the embodiment of the invention, the controller is used for controlling the feeding component to mix various raw materials, the chlorine supply component is used for supplying chlorine, the reaction product is obtained through heating reaction in the chlorination furnace by the heater, the reaction product is filtered by the filter element, zirconium tetrachloride is obtained through separation in the first separation box by the cold separator, and the zirconium tetrachloride is transmitted into the discharging box by the conveyor belt, so that the production efficiency in the zirconium tetrachloride production process is improved.
Description
Technical Field
The invention relates to the technical field of automation, in particular to a zirconium tetrachloride production device.
Background
In the zirconium tetrachloride production process, chlorine gas, zircon sand (zirconium silicate) and petroleum coke are required to be used as raw materials for reaction at high temperature. In the related art, production is generally realized by manually inputting raw materials and controlling the operation of each device, and the production mode needs participation of personnel, the personnel needs to determine the progress of the reaction, and long time is spent, so that the production efficiency is lower.
It can be seen that the related art has a problem of low production efficiency in the zirconium tetrachloride production process.
Disclosure of Invention
The embodiment of the invention provides a zirconium tetrachloride production device, which aims to solve the problem of lower production efficiency in the zirconium tetrachloride production process in the prior art.
To achieve the above object, an embodiment of the present invention provides a zirconium tetrachloride production apparatus, including:
the feeding assembly is provided with a first inlet, a first outlet and a stirrer, wherein the first inlet is used for entering various raw materials for producing zirconium tetrachloride, and the stirrer is used for mixing the various raw materials;
A chlorine supply assembly provided with a second outlet for supplying chlorine;
The chlorination furnace is positioned below the level of the feeding assembly and the chlorine supply assembly, and is provided with a second inlet, a third outlet and a heater, wherein the second inlet is communicated with the first outlet, the third inlet is communicated with the second outlet, and the heater is used for heating the raw materials and the chlorine so that the raw materials and the chlorine react to obtain a reaction product;
the filter is provided with a fourth inlet, a fourth outlet and a filter element, the fourth inlet is communicated with the third outlet, the reaction product sequentially passes through the fourth inlet, the filter element and the fourth outlet, and the filter element is used for filtering solid residues in the reaction product;
A first separation tank provided with a fifth inlet, a fifth outlet, a sixth outlet and a cold separator, wherein the fifth inlet is communicated with the fourth outlet, the cold separator is used for cooling the reaction product and separating solid products and gas byproducts in the reaction product, and the solid products comprise zirconium tetrachloride;
A gas treatment assembly provided with a sixth inlet in communication with the fifth outlet and a reductant for treating the gaseous by-products;
a transfer assembly below the level of the first separator tank, the transfer assembly having a seventh inlet in communication with the sixth outlet, a seventh outlet, and a conveyor belt for transferring the solid product;
a discharge bin in communication with the seventh outlet, the discharge bin for storing the solid product;
a controller electrically connected to the first inlet, the second inlet, the third inlet, the fourth inlet, the fifth inlet, the sixth inlet, the seventh inlet, the first outlet, the second outlet, the third outlet, the fourth outlet, the fifth outlet, the sixth outlet, the seventh outlet, the agitator, the heater, and the conveyor belt, respectively;
Before feeding, the controller controls the first inlet to be opened so as to input various raw materials, controls the stirrer to work and controls the first outlet to be closed;
after the mixing of various raw materials is completed, the controller controls the opening of the first outlet, the second inlet and the third inlet, controls the closing of the third outlet and controls the operation of the heater;
After the reaction is completed to obtain the reaction product, the controller controls to close the first outlet, the second inlet, the third inlet, the fifth outlet and the sixth outlet and controls to open the third outlet, the fourth inlet, the fourth outlet and the fifth inlet;
In the case of separating the reaction products, the controller controls the opening of the fifth outlet, the sixth outlet and the sixth inlet, and controls the cold separator to operate;
Upon completion of the separation of the reaction products, the controller controls the sixth outlet and the seventh inlet to be opened, and controls the conveyor belt to operate.
Optionally, a first weight detector is arranged in the chlorination furnace, and the first weight detector is electrically connected with the controller;
The controller is used for controlling the feeding component to reduce the feeding speed under the condition that the value of the first weight detector is larger than a first set value, and/or controlling the feeding component to increase the feeding speed under the condition that the value of the first weight detector is smaller than the first set value; the first set point is used for representing the weight of raw materials required to be consumed in the production of the chlorination furnace.
Optionally, the third inlet of the chlorination furnace is provided with a first flowmeter, and the first flowmeter is electrically connected with the controller;
The controller is used for controlling the feeding component to increase the feeding speed under the condition that the value of the first flowmeter is increased, and/or controlling the feeding component to decrease the feeding speed under the condition that the value of the first flowmeter is decreased.
Optionally, the sixth inlet of the gas processing assembly is provided with a gas detector, and the gas detector is electrically connected with the controller;
The controller is used for controlling the chlorine gas providing device to reduce the providing speed of the chlorine gas under the condition that the numerical value of the gas detector is larger than a second set value; and/or controlling the chlorine supply device to increase the supply speed of the chlorine in the case that the value of the gas detector is smaller than the second set value; the second set point is used to characterize the process gas velocity set by the gas processing assembly.
Optionally, the reactor further comprises a second separation tank, wherein the second separation tank is provided with an eighth inlet, an eighth outlet and a ninth outlet, the eighth inlet is communicated with the fourth outlet, the eighth outlet is communicated with the sixth inlet, the ninth outlet is communicated with the seventh inlet, and the second separation tank is used for separating solid products and gas byproducts in reaction products;
the controller is electrically connected with the second separation box.
Optionally, a first temperature detector and a first scraper are arranged in the first separation tank, the first scraper is used for scraping the solid product on the inner wall of the first separation tank, and the first temperature detector and the first scraper are electrically connected with the controller;
The controller is used for controlling the first scraper to work under the condition that the numerical value of the first temperature detector is larger than or equal to a third set value; the third set point is used to characterize the temperature value of the solid product separation.
Optionally, a second temperature detector and a second scraper are arranged in the second separation tank, the second scraper is used for scraping the solid product on the inner wall of the second separation tank, and the second temperature detector and the second scraper are electrically connected with the controller;
The controller is used for controlling the second scraper to work under the condition that the value of the second temperature detector is larger than or equal to the third set value
Optionally, a second weight detector and a first level gauge are arranged in the first separation box, and the second weight detector and the first level gauge are electrically connected with the controller;
the controller is used for controlling the sixth outlet and the seventh inlet to be opened when the value of the second weight detector is smaller than or equal to a fourth set value and the value of the first level gauge is larger than or equal to a fifth set value; the fourth set point is used for representing the weight of the solid product after the reaction, and the fifth set point is used for representing the material level of the solid product after the reaction.
Optionally, a third weight detector and a second level gauge are arranged in the second separation box, and the third weight detector and the second level gauge are electrically connected with the controller;
The controller is used for controlling the ninth outlet and the seventh inlet to be opened under the condition that the value of the third weight detector is smaller than or equal to the fourth set value and the value of the second level gauge is smaller than or equal to the fifth set value
Optionally, a fourth weight detector is arranged in the discharging box, and the fourth weight detector is electrically connected with the controller;
The controller is used for controlling the transmission component to reduce the transmission speed under the condition that the value of the fourth weight detector is increased; and/or controlling the transmission component to increase the transmission speed in case the value of the fourth weight detector decreases.
One of the above technical solutions has the following advantages or beneficial effects:
according to the embodiment of the invention, the controller is used for controlling the feeding component to mix various raw materials, the chlorine supply component is used for supplying chlorine, the reaction product is obtained by heating and reacting in the chlorination furnace through the heater, the reaction product is filtered through the filter element, zirconium tetrachloride is obtained by separating in the first separation box through the cold separator, and the zirconium tetrachloride is transmitted into the discharging box through the conveying belt, so that the production efficiency in the zirconium tetrachloride production process is improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are needed in the description of the embodiments of the present invention will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and other drawings may be obtained according to these drawings without inventive effort to a person of ordinary skill in the art.
FIG. 1 is a schematic structural view of a zirconium tetrachloride production device according to an embodiment of the present invention;
FIG. 2 is a schematic structural diagram of a feeding assembly according to an embodiment of the present invention;
FIG. 3 is a schematic view of a partial structure of a chlorination furnace according to an embodiment of the present disclosure;
FIG. 4 is a schematic view of a filter according to an embodiment of the present invention;
FIG. 5 is a schematic view of a partial structure of a first separator tank according to an embodiment of the present invention;
Fig. 6 is a schematic structural view of a transfer assembly and a discharge box according to an embodiment of the present invention.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are some, but not all embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Referring to fig. 1, fig. 1 is a schematic structural diagram of a zirconium tetrachloride production apparatus according to an embodiment of the present invention, as shown in fig. 1, the apparatus includes:
The feeding assembly 10, the feeding assembly 10 is provided with a first inlet, a first outlet and a stirrer 101, the first inlet is used for entering various raw materials for producing zirconium tetrachloride, and the stirrer 101 is used for mixing the various raw materials;
A chlorine supply assembly 20, the chlorine supply assembly 20 being provided with a second outlet, the chlorine supply assembly 20 being adapted to supply chlorine;
The chlorination furnace 30, the chlorination furnace 30 is located below the level of the feeding assembly 10 and the chlorine providing assembly 20, the chlorination furnace 30 is provided with a second inlet, a third outlet and a heater 301, the second inlet is communicated with the first outlet, the third inlet is communicated with the second outlet, and the heater 301 is used for heating various raw materials and chlorine so that the various raw materials and the chlorine react to obtain a reaction product;
the filter 40 is provided with a fourth inlet, a fourth outlet and a filter element 401, the fourth inlet is communicated with the third outlet, reaction products sequentially pass through the fourth inlet, the filter element 401 and the fourth outlet, and the filter element 401 is used for filtering solid residues in the reaction products;
A first separation tank 50, wherein the first separation tank 50 is provided with a fifth inlet, a fifth outlet, a sixth outlet and a cold separator 501, the fifth inlet is communicated with the fourth outlet, the cold separator 501 is used for cooling reaction products, separating solid products and gas byproducts in the reaction products, and the solid products comprise zirconium tetrachloride;
a gas treatment assembly 60, the gas treatment assembly 60 being provided with a sixth inlet and a reducing agent, the sixth inlet being in communication with the fifth outlet, the reducing agent being for treating gaseous byproducts;
A transfer assembly 70, the transfer assembly 70 being located below the level of the first separator tank 50, the transfer assembly 70 being provided with a seventh inlet, a seventh outlet and a conveyor belt, the seventh inlet being in communication with the sixth outlet, the conveyor belt being for transferring the solid product;
the discharging box 80 is communicated with the seventh outlet, and the discharging box 80 is used for storing solid products;
a controller electrically connected to the first inlet, the second inlet, the third inlet, the fourth inlet, the fifth inlet, the sixth inlet, the seventh inlet, the first outlet, the second outlet, the third outlet, the fourth outlet, the fifth outlet, the sixth outlet, the seventh outlet, the agitator 101, the heater 301, and the conveyor belt, respectively;
Before feeding, the controller controls the first inlet to be opened to input various raw materials, controls the stirrer 101 to work and controls the first outlet to be closed;
After the mixing of the multiple raw materials is completed, the controller controls the opening of the first outlet, the second inlet and the third inlet, controls the closing of the third outlet and controls the operation of the heater 301;
after the reaction is completed to obtain a reaction product, the controller controls to close the first outlet, the second inlet, the third inlet, the fifth outlet and the sixth outlet and controls to open the third outlet, the fourth inlet, the fourth outlet and the fifth inlet;
in the case of separating the reaction products, the controller controls the opening of the fifth outlet, the sixth outlet and the sixth inlet, and controls the cold separator 501 to operate;
and when the separation of the reaction products is completed, the controller controls the opening of the sixth outlet and the seventh inlet and controls the operation of the conveyor belt.
The schematic structure of the feeding assembly 10 is shown in fig. 2, the feeding assembly 10 includes a stirrer 101, and a first inlet of the feeding assembly 10 is used for inputting various raw materials including zircon sand, petroleum coke and other raw materials; after the raw materials are put into the mixer 101, zircon sand and petroleum coke are mixed. After mixing is complete, the mixture of zircon sand and petroleum coke enters the chlorination furnace 30 through the first outlet.
Wherein, the bottom of the feeding component 10 is in an inverted triangle structure, and the first outlet is positioned at the bottommost side of the inverted triangle, so that the mixed zircon sand and petroleum coke mixture falls into the chlorination furnace 30 under the action of gravity.
It will be appreciated that the first outlet of the feed assembly 10 and the second inlet of the chlorination furnace 30 may be in communication via a valve or may be transported via a conveyor. The controller may control the rate at which the various materials enter the chlorination furnace 30.
The chlorine supply assembly 20 may be transported by a factory through a pipeline, or may be stored and supplied in the form of a gas tank. Wherein the controller can control the chlorine supply assembly 20 to vary the rate at which chlorine is supplied.
The schematic partial structure of the chlorination furnace 30 is shown in fig. 3, and the chlorination furnace 30 heats various raw materials and chlorine to react to obtain a reaction product, where the reaction product includes zirconium tetrachloride and byproduct silicon tetrachloride. It should be understood that the chlorination furnace 30 also includes unreacted solid residues and gases therein. The controller may control the temperature within the chlorination furnace 30.
The filter 40 is schematically shown in fig. 4, and the reaction products sequentially pass through the fourth inlet, the filter element 401 and the fourth outlet, thereby filtering unreacted solid residues and a part of gas.
As shown in fig. 5, the first separator 50 is partially structured, and the cold separator 501 rapidly cools the reaction product, the zirconium tetrachloride and the byproduct silicon tetrachloride are cooled to solid, while the unreacted gases such as chlorine remain in the non-gaseous state, thereby separating the solid product including zirconium tetrachloride.
Wherein the fifth outlet is for discharging gas and is located at the top end of the first separation tank 50; the sixth outlet is for discharging solid product and is located at the bottom side of the first separator tank 50.
Wherein the controller may control the temperature of the cold separator 501.
The above-described transfer assembly 70 and discharge box 80 are schematically illustrated in fig. 6, wherein the transfer assembly 70 is positioned below the level of the first separator box 50 and transfers the solid product into the discharge box 80 by rotation of the conveyor belt.
It will be appreciated that after the reaction is complete, the controller can control the gas purging of the entire zirconium tetrachloride production plant to achieve a line or assembly of patency.
In this embodiment, the controller controls the feeding assembly 10 to mix various raw materials, the chlorine supply assembly 20 supplies chlorine, the heater 301 heats and reacts in the chlorination furnace 30 to obtain a reaction product, the filter element 401 filters the reaction product, the cold separator 501 separates the reaction product in the first separation tank 50 to obtain zirconium tetrachloride, and the zirconium tetrachloride is transmitted to the discharging tank 80 through the conveyor belt, so that the production efficiency in the zirconium tetrachloride production process is improved.
Optionally, a first weight detector is arranged in the chlorination furnace 30, and the first weight detector is electrically connected with the controller;
The controller is configured to control the feeding assembly 10 to reduce the feeding speed when the value of the first weight detector is greater than the first set value, and/or control the feeding assembly 10 to increase the feeding speed when the value of the first weight detector is less than the first set value; the first set point is used to characterize the weight of raw materials that the chlorination furnace 30 is producing to consume.
The first weight detector may be provided at the bottom side of the chlorination furnace 30.
It should be appreciated that the first weight detector shows the weight of the reacted multiple raw materials in the chlorination furnace 30, and in case that the weight is less than the first set value, it is necessary to increase the feeding speed until the value of the first weight detector is the same as the first set value, avoiding the waste of heat of the heater 301.
For example, the reaction temperature of the heater 301 is 1100 ℃, and 0.5t of various raw materials can be reacted in one chlorination furnace 30 per unit time, at this time, only 0.3t of various raw materials are in the chlorination furnace 30, and at this time, the controller controls to increase the feeding speed, so that the weight in the chlorination furnace 30 reaches 0.5t, and the maximum reaction rate under the temperature condition is reached.
Similarly, in the case where the value of the first weight detector is greater than the first set value, the feeding assembly 10 is controlled to reduce the feeding speed so as to ensure the sufficient reaction of the raw materials.
In this embodiment, by arranging the first weight detector in the chlorination furnace 30, the first weight detector is electrically connected with the controller, and the controller controls the feeding speed based on the numerical value of the first weight detector, so as to realize automatic control of production, improve the production efficiency, and reduce the occurrence of incomplete reaction.
Optionally, the third inlet of the chlorination furnace 30 is provided with a first flowmeter, and the first flowmeter is electrically connected with the controller;
The controller is configured to control the feeding assembly 10 to increase the feeding speed in case the value of the first flow meter increases, and/or control the feeding assembly 10 to decrease the feeding speed in case the value of the first flow meter decreases.
It should be appreciated that the first flow meter is used to count the rate at which chlorine is provided by the chlorine providing device. Since the raw material needs to react with chlorine, the feeding speed is positively related to the supply speed of chlorine.
Illustratively, in the case where the value of the first flow meter is increased, at which time the chlorine supply is increased, it is necessary to control the feeding assembly 10 to increase the feeding speed so as to achieve the complete reaction; in the case of a decrease in the value of the first flow meter, at which time the chlorine available to participate in the reaction in the chlorination furnace 30 is decreased, the feeding assembly 10 needs to be controlled to decrease the feeding speed to achieve the complete reaction.
In this embodiment, by providing the first flowmeter at the third inlet of the chlorination furnace 30, the first flowmeter is electrically connected to the controller, and the controller controls the feeding assembly 10 to increase the feeding speed in the case that the value of the first flowmeter increases, and/or controls the feeding assembly 10 to decrease the feeding speed in the case that the value of the first flowmeter decreases, so as to achieve sufficient reaction in the chlorination furnace 30 and avoid waste of raw materials or chlorine.
Optionally, the sixth inlet of the gas treatment assembly 60 is provided with a gas detector, which is electrically connected to the controller;
the controller is used for controlling the chlorine supply device to reduce the supply speed of the chlorine under the condition that the value of the gas detector is larger than a second set value; and/or, controlling the chlorine supply device to increase the supply speed of the chlorine under the condition that the value of the gas detector is smaller than the second set value; the second set point is used to characterize the process gas velocity set by the gas processing assembly 60.
It should be appreciated that the rate at which the gas treatment assembly 60 treats chlorine is constant, being the second set point. It is necessary to reduce the discharge rate of chlorine when the amount of chlorine is excessive, and the discharge rate of chlorine can be increased when the amount of chlorine is too small.
For example, in the case where the value of the gas detector is greater than the second set value, it is considered that the chlorine gas is discharged more at this time, and the controller is required to control the chlorine gas supply device to reduce the supply speed of the chlorine gas; in the case where the value of the gas detector is smaller than the second set value, it is considered that the chlorine gas discharge is small at this time, and the supply speed of the chlorine gas can be increased by controlling the chlorine gas supply device by the controller.
In this embodiment, by providing a gas detector at the sixth inlet of the gas processing module 60, the gas detector is electrically connected to a controller, and by the controller, in the case where the value of the gas detector is greater than the second set value, the chlorine providing device is controlled to reduce the providing speed of the chlorine; and/or under the condition that the value of the gas detector is smaller than the second set value, controlling the chlorine supply device to increase the supply speed of the chlorine, realizing complete treatment of the chlorine and reducing pollution.
Optionally, the reaction vessel further comprises a second separation vessel 51, the second separation vessel 51 is provided with an eighth inlet, an eighth outlet and a ninth outlet, the eighth inlet is communicated with the fourth outlet, the eighth outlet is communicated with the sixth inlet, the ninth outlet is communicated with the seventh inlet, and the second separation vessel 51 is used for separating solid products and gas byproducts in the reaction products;
The controller is electrically connected to the second separator tank 51.
The function of the second separator tank 51 described above is the same as that of the first separator tank 50 for separating solid products and gaseous products in the reaction products. The second separation tank 51 may be used as a spare separation tank of the first separation tank 50, or may work with the first separation tank 50 at the same time, thereby improving separation efficiency.
Optionally, a first temperature detector and a first scraper 502 are arranged in the first separation tank 50, the first scraper 502 is used for scraping solid products on the inner wall of the first separation tank 50, and the first temperature detector and the first scraper 502 are electrically connected with the controller;
The controller is used for controlling the first scraper 502 to work under the condition that the value of the first temperature detector is larger than or equal to a third set value; the third set point is used to characterize the temperature value of the solid product separation.
Wherein the first temperature detector may be provided at a side surface or a ground surface of the first separation tank 50.
It will be appreciated that during the temperature reduction separation of the solid product and gas in the first separator tank 50 via the cold separator 501, the solid product may adhere to the inner walls of the first separator tank 50, resulting in greater ingress and egress of the final product from the intended product. The first scraper 502 may scrape the solid product on the inner wall of the first separator tank 50, thereby increasing the discharge amount of the solid product.
Wherein the third set point is the temperature at which the cold separator 501 operates, or the temperature at which the solid product condenses.
In this embodiment, by providing the first temperature detector and the first scraper 502 in the first separator 50, the first scraper 502 is controlled to operate when the value of the first temperature detector is greater than or equal to the third set value, thereby increasing the discharge amount of the solid product.
Optionally, a second temperature detector and a second scraper are arranged in the second separation tank 51, the second scraper is used for scraping solid products on the inner wall of the second separation tank 51, and the second temperature detector and the second scraper are electrically connected with the controller;
the controller is used for controlling the second scraper to work under the condition that the value of the second temperature detector is larger than or equal to a third set value
Wherein the second temperature detector may be provided at a side surface or a ground surface of the second separation tank 51.
It should be understood that the second temperature detector and the second scraper are disposed in the second separation tank 51, which has the same effect as the first temperature detector and the first scraper 502 disposed in the first separation tank 50, and will not be described herein.
Optionally, a second weight detector and a first level gauge are arranged in the first separation box 50, and the second weight detector and the first level gauge are electrically connected with the controller;
The controller is used for controlling the opening of the sixth outlet and the seventh inlet under the condition that the value of the second weight detector is smaller than or equal to a fourth set value and the value of the first level gauge is larger than or equal to a fifth set value; the fourth set point is used for representing the weight of the solid product after the reaction, and the fifth set point is used for representing the material level of the solid product after the reaction.
The second weight detector may be disposed at the bottom side of the first separation tank 50, and the first level gauge may be disposed at a side surface of the first separation tank 50.
It will be appreciated that in the case where the solid product of the fourth setpoint is separated in the first separator and the location of the solid product also meets the fifth setpoint, the separation of the solid product from the gas may be considered complete and it is desirable to pass the solid product into the discharge box 80.
In this embodiment, by providing the second weight detector and the first level indicator in the first separator tank 50, the second weight detector and the first level indicator are electrically connected to the controller, so that the controller controls the sixth outlet and the seventh inlet to be opened when the value of the second weight detector is less than or equal to the fourth set value and the value of the first level indicator is greater than or equal to the fifth set value, and the solid product enters the discharge tank 80 through the transmission assembly 70, thereby completing the production process.
Optionally, a third weight detector and a second level gauge are arranged in the second separation box 51, and the third weight detector and the second level gauge are electrically connected with the controller;
the controller is used for controlling the opening of the ninth outlet and the seventh inlet under the condition that the value of the third weight detector is smaller than or equal to a fourth set value and the value of the second level gauge is larger than or equal to a fifth set value
The third weight detector may be disposed at the bottom side of the second separation tank 51, and the second level gauge may be disposed at the side surface of the second separation tank 51.
It should be understood that the function of providing the third weight detector and the second level gauge in the second separator tank 51 is the same as the function of providing the second weight detector and the first level gauge in the first separator tank 50, and will not be described again here.
Optionally, a fourth weight detector is arranged in the discharging box 80 and is electrically connected with the controller;
the controller is configured to control the transmission assembly 70 to reduce the transmission speed in the case that the value of the fourth weight detector increases; and/or, in case the value of the fourth weight detector is reduced, the transmission assembly 70 is controlled to increase the transmission speed.
Wherein the fourth weight detector may be provided at the bottom side of the discharge bin 80.
It should be appreciated that the discharge bin 80 is used to store the solid product or to transfer the solid instructions to a wrapper for packaging. In the case that the value of the fourth weight detector increases, at this time, the remaining storable space in the discharge box 80 becomes small, and it is necessary to control the transfer assembly 70 to reduce the transfer speed; in the case of an increase in the value of the fourth weight detector, the remaining storable space in the tapping tank 80 at this time becomes large, so that the transfer speed of the transfer assembly 70 can be controlled.
It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising one … …" does not exclude the presence of other like elements in a process, method, article, or apparatus that comprises the element.
The embodiments of the present invention have been described above with reference to the accompanying drawings, but the present invention is not limited to the above-described embodiments, which are merely illustrative and not restrictive, and many forms may be made by those having ordinary skill in the art without departing from the spirit of the present invention and the scope of the claims, which are to be protected by the present invention.
Claims (5)
1. A zirconium tetrachloride production device, comprising:
the feeding assembly is provided with a first inlet, a first outlet and a stirrer, wherein the first inlet is used for entering various raw materials for producing zirconium tetrachloride, and the stirrer is used for mixing the various raw materials;
A chlorine supply assembly provided with a second outlet for supplying chlorine;
The chlorination furnace is positioned below the level of the feeding assembly and the chlorine supply assembly, and is provided with a second inlet, a third outlet and a heater, wherein the second inlet is communicated with the first outlet, the third inlet is communicated with the second outlet, and the heater is used for heating the raw materials and the chlorine so that the raw materials and the chlorine react to obtain a reaction product;
the filter is provided with a fourth inlet, a fourth outlet and a filter element, the fourth inlet is communicated with the third outlet, the reaction product sequentially passes through the fourth inlet, the filter element and the fourth outlet, and the filter element is used for filtering solid residues in the reaction product;
A first separation tank provided with a fifth inlet, a fifth outlet, a sixth outlet and a cold separator, wherein the fifth inlet is communicated with the fourth outlet, the cold separator is used for cooling the reaction product and separating solid products and gas byproducts in the reaction product, and the solid products comprise zirconium tetrachloride;
A gas treatment assembly provided with a sixth inlet in communication with the fifth outlet and a reductant for treating the gaseous by-products;
a transfer assembly below the level of the first separator tank, the transfer assembly having a seventh inlet in communication with the sixth outlet, a seventh outlet, and a conveyor belt for transferring the solid product;
a discharge bin in communication with the seventh outlet, the discharge bin for storing the solid product;
a controller electrically connected to the first inlet, the second inlet, the third inlet, the fourth inlet, the fifth inlet, the sixth inlet, the seventh inlet, the first outlet, the second outlet, the third outlet, the fourth outlet, the fifth outlet, the sixth outlet, the seventh outlet, the agitator, the heater, and the conveyor belt, respectively;
Before feeding, the controller controls the first inlet to be opened so as to input various raw materials, controls the stirrer to work and controls the first outlet to be closed;
after the mixing of various raw materials is completed, the controller controls the opening of the first outlet, the second inlet and the third inlet, controls the closing of the third outlet and controls the operation of the heater;
After the reaction is completed to obtain the reaction product, the controller controls to close the first outlet, the second inlet, the third inlet, the fifth outlet and the sixth outlet and controls to open the third outlet, the fourth inlet, the fourth outlet and the fifth inlet;
In the case of separating the reaction products, the controller controls the opening of the fifth outlet, the sixth outlet and the sixth inlet, and controls the cold separator to operate;
upon completion of separation of the reaction products, the controller controls the sixth outlet and the seventh inlet to be opened, controlling the conveyor belt to operate;
a first weight detector is arranged in the chlorination furnace and is electrically connected with the controller;
The controller is used for controlling the feeding component to reduce the feeding speed under the condition that the value of the first weight detector is larger than a first set value, and/or controlling the feeding component to increase the feeding speed under the condition that the value of the first weight detector is smaller than the first set value; the first set value is used for representing the weight of raw materials required to be consumed in the production of the chlorination furnace;
The third inlet of the chlorination furnace is provided with a first flowmeter, and the first flowmeter is electrically connected with the controller;
The controller is used for controlling the feeding assembly to increase the feeding speed under the condition that the value of the first flowmeter is increased, and/or controlling the feeding assembly to decrease the feeding speed under the condition that the value of the first flowmeter is decreased;
The sixth inlet of the gas treatment assembly is provided with a gas detector, and the gas detector is electrically connected with the controller;
The controller is used for controlling the chlorine gas providing device to reduce the providing speed of the chlorine gas under the condition that the numerical value of the gas detector is larger than a second set value; and/or controlling the chlorine supply device to increase the supply speed of the chlorine in the case that the value of the gas detector is smaller than the second set value; the second set point is used for representing the speed of the processing gas set by the gas processing assembly;
The zirconium tetrachloride production device further comprises a second separation box, wherein the second separation box is provided with an eighth inlet, an eighth outlet and a ninth outlet, the eighth inlet is communicated with the fourth outlet, the eighth outlet is communicated with the sixth inlet, the ninth outlet is communicated with the seventh inlet, and the second separation box is used for separating solid products and gas byproducts in reaction products;
the controller is electrically connected with the second separation box;
a first temperature detector and a first scraper are arranged in the first separation box, the first scraper is used for scraping the solid product on the inner wall of the first separation box, and the first temperature detector and the first scraper are electrically connected with the controller;
The controller is used for controlling the first scraper to work under the condition that the numerical value of the first temperature detector is larger than or equal to a third set value; the third set point is used to characterize the temperature value of the solid product separation.
2. The zirconium tetrachloride production device according to claim 1, wherein a second temperature detector and a second scraper are provided in the second separation tank, the second scraper being used for scraping the solid product on the inner wall of the second separation tank, the second temperature detector and the second scraper being electrically connected to the controller;
the controller is used for controlling the second scraper to work under the condition that the value of the second temperature detector is larger than or equal to the third set value.
3. The zirconium tetrachloride production device according to claim 1, wherein a second weight detector and a first level gauge are arranged in the first separation tank, and the second weight detector and the first level gauge are electrically connected with the controller;
the controller is used for controlling the sixth outlet and the seventh inlet to be opened when the value of the second weight detector is smaller than or equal to a fourth set value and the value of the first level gauge is larger than or equal to a fifth set value; the fourth set point is used for representing the weight of the solid product after the reaction, and the fifth set point is used for representing the material level of the solid product after the reaction.
4. The zirconium tetrachloride production device according to claim 3, wherein a third weight detector and a second level gauge are arranged in the second separation tank, and the third weight detector and the second level gauge are electrically connected with the controller;
The controller is used for controlling the opening of the ninth outlet and the seventh inlet under the condition that the value of the third weight detector is smaller than or equal to the fourth set value and the value of the second level gauge is smaller than or equal to the fifth set value.
5. The zirconium tetrachloride production device according to claim 1, wherein a fourth weight detector is provided in the discharge box, the fourth weight detector being electrically connected to the controller;
The controller is used for controlling the transmission component to reduce the transmission speed under the condition that the value of the fourth weight detector is increased; and/or controlling the transmission component to increase the transmission speed in case the value of the fourth weight detector decreases.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211345938.8A CN115744975B (en) | 2022-10-31 | 2022-10-31 | Zirconium tetrachloride apparatus for producing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211345938.8A CN115744975B (en) | 2022-10-31 | 2022-10-31 | Zirconium tetrachloride apparatus for producing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115744975A CN115744975A (en) | 2023-03-07 |
| CN115744975B true CN115744975B (en) | 2024-05-07 |
Family
ID=85354464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211345938.8A Active CN115744975B (en) | 2022-10-31 | 2022-10-31 | Zirconium tetrachloride apparatus for producing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115744975B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102103363A (en) * | 2009-12-22 | 2011-06-22 | 上海吴泾化工有限公司 | Method and device for detecting and controlling acetoacetic ester continuous reaction system on line |
| KR20130076195A (en) * | 2011-12-28 | 2013-07-08 | 주식회사 포스코 | Method for preparing zirconium tetrachloride of high purity and zirconium sponge |
| CN109734129A (en) * | 2019-03-20 | 2019-05-10 | 锦州旭日新材料科技有限公司 | A kind of method that zirconium silicate ball fluidizing chlorination method produces refined zirconium tetrachloride and by-produced tetrachlorosilane |
| CN211636436U (en) * | 2019-11-22 | 2020-10-09 | 三祥新材股份有限公司 | Zirconium tetrachloride fused salt purification melting device |
| CN113880136A (en) * | 2020-07-03 | 2022-01-04 | 新疆硅基新材料创新中心有限公司 | Zirconium tetrachloride and/or silicon tetrachloride, preparation method and preparation device thereof |
| CN215587406U (en) * | 2021-09-17 | 2022-01-21 | 新疆晶硕新材料有限公司 | Scraping device |
| CN115041002A (en) * | 2022-05-09 | 2022-09-13 | 新疆晶硕新材料有限公司 | Method for treating tail gas in zircon sand chlorination production |
-
2022
- 2022-10-31 CN CN202211345938.8A patent/CN115744975B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102103363A (en) * | 2009-12-22 | 2011-06-22 | 上海吴泾化工有限公司 | Method and device for detecting and controlling acetoacetic ester continuous reaction system on line |
| KR20130076195A (en) * | 2011-12-28 | 2013-07-08 | 주식회사 포스코 | Method for preparing zirconium tetrachloride of high purity and zirconium sponge |
| CN109734129A (en) * | 2019-03-20 | 2019-05-10 | 锦州旭日新材料科技有限公司 | A kind of method that zirconium silicate ball fluidizing chlorination method produces refined zirconium tetrachloride and by-produced tetrachlorosilane |
| CN211636436U (en) * | 2019-11-22 | 2020-10-09 | 三祥新材股份有限公司 | Zirconium tetrachloride fused salt purification melting device |
| CN113880136A (en) * | 2020-07-03 | 2022-01-04 | 新疆硅基新材料创新中心有限公司 | Zirconium tetrachloride and/or silicon tetrachloride, preparation method and preparation device thereof |
| CN215587406U (en) * | 2021-09-17 | 2022-01-21 | 新疆晶硕新材料有限公司 | Scraping device |
| CN115041002A (en) * | 2022-05-09 | 2022-09-13 | 新疆晶硕新材料有限公司 | Method for treating tail gas in zircon sand chlorination production |
Non-Patent Citations (1)
| Title |
|---|
| 《合成洗涤剂生产基本知识》编写组.《合成洗涤剂生产基本知识》.轻工业出版社,1986,(第1版),230. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115744975A (en) | 2023-03-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100575323C (en) | The two-step reaction process of dried preparation acetylene and device | |
| EP2449329B1 (en) | Method for controlling a process for burning a lime containing mixture to burnt lime | |
| EP3581266B1 (en) | Continuous reactor | |
| CN104843725B (en) | Process and equipment for producing sodium silicate by using liquid-phase method | |
| CN104496204A (en) | Energy-saving high-performance dry-process calcium hydroxide production line | |
| CN115744975B (en) | Zirconium tetrachloride apparatus for producing | |
| US6190625B1 (en) | Fluidized-bed roasting of molybdenite concentrates | |
| CN110894142A (en) | High-efficient lime slaking dross removal mechanism | |
| CN113292459B (en) | Continuous nitration method of guanidine nitrate | |
| CA1110847A (en) | Automatic calcining kettle | |
| CN204325148U (en) | Energy-saving and high efficient dry method calcium hydroxide production line | |
| CN101439856B (en) | Method and apparatus for preparing high-purity graphite powder | |
| CN112840409B (en) | Method and apparatus for converting uranium hexafluoride to uranium dioxide | |
| CN102653821A (en) | Fluidized bed furnace device for circularly roasting molybdenum concentrates and method for using same | |
| CN212894913U (en) | Continuous production device for extracting rare earth sulfate from electrolytic molten salt slag | |
| CN211170478U (en) | High-efficient lime slaking dross removal mechanism | |
| CN211546341U (en) | Quick lime slaking equipment with dust removal function | |
| CN213375747U (en) | Device for collecting titanium white base material by chlorination process by dry method | |
| CN111893328A (en) | Continuous production device for extracting rare earth sulfate from electrolytic molten salt slag | |
| CN215864604U (en) | High-purity antimony reduction furnace | |
| CN112840410A (en) | Method and installation for converting uranium hexafluoride into uranium dioxide | |
| CN218358628U (en) | Useless transport of danger in bags and slurrying system | |
| CN219341779U (en) | Automatic batching system | |
| CN213416976U (en) | Reaction device for wet metallurgy | |
| CN217341280U (en) | Device for preparing chlorosilane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |