CN115702235A - Composition and use thereof - Google Patents
Composition and use thereof Download PDFInfo
- Publication number
- CN115702235A CN115702235A CN202180044125.2A CN202180044125A CN115702235A CN 115702235 A CN115702235 A CN 115702235A CN 202180044125 A CN202180044125 A CN 202180044125A CN 115702235 A CN115702235 A CN 115702235A
- Authority
- CN
- China
- Prior art keywords
- mass
- isomer
- chloro
- content
- coordinate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 144
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 claims abstract description 142
- 239000000463 material Substances 0.000 claims abstract description 34
- 238000004140 cleaning Methods 0.000 claims abstract description 27
- 239000000443 aerosol Substances 0.000 claims abstract description 26
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- GDPWRLVSJWKGPJ-UHFFFAOYSA-N 1-chloro-2,3,3,3-tetrafluoroprop-1-ene Chemical compound ClC=C(F)C(F)(F)F GDPWRLVSJWKGPJ-UHFFFAOYSA-N 0.000 claims description 52
- 238000010587 phase diagram Methods 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 21
- 229920005989 resin Polymers 0.000 claims description 21
- 229920001971 elastomer Polymers 0.000 claims description 12
- 239000005060 rubber Substances 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 6
- 239000003380 propellant Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 abstract description 19
- 230000000694 effects Effects 0.000 abstract description 14
- 230000002411 adverse Effects 0.000 abstract description 9
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 38
- 239000000314 lubricant Substances 0.000 description 24
- 229910052731 fluorine Inorganic materials 0.000 description 23
- 239000011248 coating agent Substances 0.000 description 22
- 229920001296 polysiloxane Polymers 0.000 description 22
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 20
- 239000011737 fluorine Substances 0.000 description 20
- 239000002904 solvent Substances 0.000 description 19
- 238000011156 evaluation Methods 0.000 description 18
- 238000000576 coating method Methods 0.000 description 16
- 238000009835 boiling Methods 0.000 description 14
- 238000001704 evaporation Methods 0.000 description 14
- 230000008020 evaporation Effects 0.000 description 14
- 150000002894 organic compounds Chemical class 0.000 description 12
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 10
- 239000004519 grease Substances 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 10
- 239000010703 silicon Substances 0.000 description 10
- 229920002545 silicone oil Polymers 0.000 description 10
- 239000000126 substance Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- -1 fluoride ions Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920001955 polyphenylene ether Polymers 0.000 description 5
- LOCOMRPWMOCMPV-UHFFFAOYSA-N 2,3-dichloro-1,1,1,2-tetrafluoropropane Chemical compound FC(F)(F)C(F)(Cl)CCl LOCOMRPWMOCMPV-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 3
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000007033 dehydrochlorination reaction Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- WHPKSWFREPSUCO-UHFFFAOYSA-N 1,2-dichloro-1,2,3,3-tetrafluoropropane Chemical compound FC(F)C(F)(Cl)C(F)Cl WHPKSWFREPSUCO-UHFFFAOYSA-N 0.000 description 2
- KCBWAFJCKVKYHO-UHFFFAOYSA-N 6-(4-cyclopropyl-6-methoxypyrimidin-5-yl)-1-[[4-[1-propan-2-yl-4-(trifluoromethyl)imidazol-2-yl]phenyl]methyl]pyrazolo[3,4-d]pyrimidine Chemical compound C1(CC1)C1=NC=NC(=C1C1=NC=C2C(=N1)N(N=C2)CC1=CC=C(C=C1)C=1N(C=C(N=1)C(F)(F)F)C(C)C)OC KCBWAFJCKVKYHO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 2
- 101150059062 apln gene Proteins 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000010702 perfluoropolyether Substances 0.000 description 2
- 239000003880 polar aprotic solvent Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000011698 potassium fluoride Substances 0.000 description 2
- 235000003270 potassium fluoride Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229940096017 silver fluoride Drugs 0.000 description 2
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- OKIYQFLILPKULA-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane Chemical compound COC(F)(F)C(F)(F)C(F)(F)C(F)(F)F OKIYQFLILPKULA-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- QGYLHZMNVGBXDQ-UHFFFAOYSA-N 1,1-dichloro-2,3,3,3-tetrafluoroprop-1-ene Chemical compound ClC(Cl)=C(F)C(F)(F)F QGYLHZMNVGBXDQ-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- AHFMSNDOYCFEPH-UHFFFAOYSA-N 1,2-difluoroethane Chemical compound FCCF AHFMSNDOYCFEPH-UHFFFAOYSA-N 0.000 description 1
- DFUYAWQUODQGFF-UHFFFAOYSA-N 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane Chemical compound CCOC(F)(F)C(F)(F)C(F)(F)C(F)(F)F DFUYAWQUODQGFF-UHFFFAOYSA-N 0.000 description 1
- SQEGLLMNIBLLNQ-UHFFFAOYSA-N 1-ethoxy-1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propane Chemical compound CCOC(F)(F)C(F)(C(F)(F)F)C(F)(F)F SQEGLLMNIBLLNQ-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- DJXNLVJQMJNEMN-UHFFFAOYSA-N 2-[difluoro(methoxy)methyl]-1,1,1,2,3,3,3-heptafluoropropane Chemical compound COC(F)(F)C(F)(C(F)(F)F)C(F)(F)F DJXNLVJQMJNEMN-UHFFFAOYSA-N 0.000 description 1
- SMCNZLDHTZESTK-UHFFFAOYSA-N 2-chloro-1,1,1,2-tetrafluoropropane Chemical compound CC(F)(Cl)C(F)(F)F SMCNZLDHTZESTK-UHFFFAOYSA-N 0.000 description 1
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 description 1
- ZGOMEYREADWKLC-UHFFFAOYSA-N 3-chloro-1,1,1,3-tetrafluoropropane Chemical compound FC(Cl)CC(F)(F)F ZGOMEYREADWKLC-UHFFFAOYSA-N 0.000 description 1
- KVCQTKNUUQOELD-UHFFFAOYSA-N 4-amino-n-[1-(3-chloro-2-fluoroanilino)-6-methylisoquinolin-5-yl]thieno[3,2-d]pyrimidine-7-carboxamide Chemical compound N=1C=CC2=C(NC(=O)C=3C4=NC=NC(N)=C4SC=3)C(C)=CC=C2C=1NC1=CC=CC(Cl)=C1F KVCQTKNUUQOELD-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003666 anti-fingerprint Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005796 dehydrofluorination reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003444 phase transfer catalyst Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a composition which does not adversely affect the global environment, hardly leaves a liquid residue when used as an aerosol, is excellent in the cleaning property of an object, and has little effect on the material of the object, and use thereof. A composition comprising specified amounts of: 1-chloro-2,3,3,3-the Z isomer of tetrafluoropropene; nonafluorobutoxymethane or nonafluorobutoxyethane; and as an optional ingredient the Z isomer of 1-chloro-3,3,3-trifluoropropene.
Description
Technical Field
The present invention relates to compositions and uses thereof.
Background
Conventionally, as a diluting solvent for a cleaning liquid, a lubricant, or the like for cleaning oil stains and dust, a hydrochlorofluorocarbon (hereinafter, also referred to as HCFC) which is nonflammable, low in toxicity, and excellent in stability has been used. However, HCFCs have an adverse effect on the ozone layer, and therefore, the developed countries are expected to prohibit the production of HCFCs comprehensively in 2020.
As a solvent which does not adversely affect the ozone layer, perfluorocarbon (hereinafter, also referred to as PFC), hydrofluorocarbon (hereinafter, also referred to as HFC), hydrofluoroether (hereinafter, also referred to as HFE), and the like are known. However, since the global warming potential is large, HFC and PFC are the subject substances of the kyoto protocol. Further, oils and fats based on HFC, HFE and PFC have lower solubility than HCFC, and thus have a smaller range of applications in solvent applications.
Patent document 1 proposes a solvent composition which has no adverse effect on the global environment, has little effect on resin materials, has sufficient drying properties, and is excellent in solubility in oils and fats.
Documents of the prior art
Patent document
Patent document 1: japanese patent No. 6699112
Disclosure of Invention
Problems to be solved by the invention
When a cleaning liquid for cleaning oil stains and dust is used as an aerosol together with a propellant, it is required that the liquid is less likely to remain, the cleaning property of an object is excellent, and the influence on the material of the object is small.
The solvent composition described in patent document 1 cannot simultaneously solve the above three problems.
The present invention addresses the problem of providing a composition that does not adversely affect the global environment, is less likely to leave liquid when used as an aerosol, has excellent cleaning properties for objects, and has little effect on the material of objects, and uses thereof.
Means for solving the problems
As a result of intensive studies, the present inventors have found that: the problems can be solved by the following configurations.
[1] A composition, comprising:
1-chloro-2,3,3,3-the Z isomer of tetrafluoropropene (a);
nonafluorobutoxymethane (B); and
as an optional component, 1-chloro-3,3,3-trifluoropropene Z isomer (C),
in a phase diagram of three values of the content (% by mass) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of the nonafluorobutoxymethane (B) and the content (% by mass) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (C) of the nonafluorobutoxymethane (B) and the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of the above-mentioned 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the above-mentioned nonafluorobutoxymethane (B), and the content (mass%) of the above-mentioned 1-chloro-3,3,3-trifluoropropene (C) are mass values of a region enclosed by a line connecting a first coordinate (A, B, C =34.7 mass%, 65.3 mass%, 0.0 mass%), a second coordinate (3534 =74.0 mass%, 26.0 mass%, 0.0 mass%), a third coordinate (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), a fourth coordinate (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (3432 zxft 5362 = 32.5 mass%, 67.6 mass%), and 27.6 mass%) in this order by six straight lines.
[2] The composition according to item [1], wherein in a phase diagram of three values, i.e., a content (mass%) of a Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, a content (mass%) of a Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, a content (mass%) of a nonafluorobutoxymethane (B) and a content (mass%) of a Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, relative to a total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, a content (mass%) of the nonafluorobutoxymethane (B) and a content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of a line connecting a seventh coordinate (A, B, C =29.0 mass%, 66.0 mass%, 5.0 mass%), an eighth coordinate (A, B, C =71.3 mass%, 23.7 mass%, 5.0 mass%), a third coordinate (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), a fourth coordinate (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (343432 zxft 5362 = 5.7 mass%, 27.6 mass%), and 27.6 mass%, in this order, with six straight lines.
[3] The composition according to [1] or [2], wherein in a phase diagram of three values of the content (mass%) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (C) of nonafluorobutoxymethane (B) and 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are coordinates (A, B, C = 12.9%, 67.0%, 20.1%), the tenth coordinates (A, B, C = 16.4%, 65.8%, 17.8%, the eleventh coordinates (A, B, C = 35.4%, 53.0%, 11.6%), the twelfth coordinates (A, B, C = 53.3%, 35.5%, 11.2%), the thirteenth coordinates (A, B, C = 67.1%, 20.1%, 12.8%, the third coordinates (3579 = 53.3%, 35.5%, 35.2%, 35.3%, 35.5%, 27.2%), the thirteenth coordinates (A, B, C = 67.1%, 20.1%, 12.8%, 35.3, 35, 35.3.3, 35, 35.3, 35.5%, 27.7%, 26, 27.6%, 26%, and the sixth coordinates (35, 27.6%).
[4] The composition according to any one of [1] to [3], wherein the composition has a phase diagram showing three values of the content (mass%) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (C) of nonafluorobutoxymethane (B) and 1-chloro-3,3,3-trifluoropropene,
the content (% by mass) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of nonafluorobutoxymethane (B) and the content (% by mass) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values in a region surrounded by a line connecting a fourteenth coordinate (A, B, C =24.2 mass%, 43.1 mass%, 32.7 mass%), a fifteenth coordinate (A, B, C =15.0 mass%, 26.7 mass%, 58.3 mass%), a sixteenth coordinate (A, B, C =5.0 mass%, 35.6 mass%, 59.4 mass%), a seventeenth coordinate (A, B, C =5.0 mass%, 47.0 mass%, 48.0 mass%) in this order by four straight lines.
[5] A composition, comprising:
1-chloro-2,3,3,3-the Z isomer of tetrafluoropropene (a);
nonafluorobutoxyethane (D); and
as an optional component, 1-chloro-3,3,3-trifluoropropene Z isomer (C),
in a phase diagram of three values of the content (% by mass) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of the nonafluorobutoxyethane (D) and the content (% by mass) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (D) of the nonafluorobutoxyethane (D) and the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of a line connecting a first coordinate (A, D, C =34.7 mass%, 65.3 mass%, 0.0 mass%), a second coordinate (A, D, C =86.0 mass%, 14.0 mass%, 0.0 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (343432 zxft 5362 = 0.7 mass%, 27.6 mass%), and 27.6 mass%, in this order, with six straight lines.
[6] The composition according to [5], wherein in a phase diagram having three values of the content (% by mass) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of the nonafluorobutoxyethane (D) and the content (% by mass) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, respectively, with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (D) of the nonafluorobutoxyethane (D) and the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of a line connecting a seventh coordinate (A, D, C =29.0 mass%, 66.0 mass%, 5.0 mass%), an eighth coordinate (A, D, C =82.3 mass%, 12.7 mass%, 5.0 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (343432 zxft 5362 = 5.7 mass%, 27.6 mass%), and 27.6 mass%, in this order, with six straight lines.
[7] The composition according to [5] or [6], wherein in a phase diagram of three values of the content (mass%) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (D) of 1-chloro-3,3,3-trifluoropropene,
the content (% by mass) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of the nonafluorobutoxyethane (D) and the content (% by mass) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are determined by connecting a ninth coordinate (A, D, C = 12.9%, 67.0%, 20.1%, by mass) and a tenth coordinate (A, D, C = 16.4%, 65.8%, 17.8%), an eleventh coordinate (A, D, C = 35.4%, 53.0%, 11.6%), a twelfth coordinate (A, D, C = 53.3%, by mass)%, in this order, by ten straight lines 35.5 mass%, 11.2 mass%), a thirteenth coordinate (A, D, C =69.5 mass%, 17.4 mass%, 13.1 mass%), a fourteenth coordinate (A, D, C =75.6 mass%, 10.5 mass%, 13.9 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (A, D, C =5.0 mass%, 67.6 mass%, 27.4 mass%), and a value within a region surrounded by a connecting line.
[8] The composition according to any one of [5] to [7], wherein the composition has a phase diagram showing three values of the content (mass%) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, and the composition has a high stability,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of mass enclosed by a connecting line connecting a fifteenth coordinate (A, D, C =51.1 mass%, 37.7 mass%, 11.2 mass%), a twelfth coordinate (A, D, C =53.3 mass%, 35.5 mass%, 11.2 mass%), a sixteenth coordinate (A, D, C =66.3 mass%, 20.9 mass%, 12.8 mass%), a seventeenth coordinate (A, D, C =33.2 mass%, 10.5 mass%, 56.3 mass%), an eighteenth coordinate (A, D, C =5.0 mass%, 35.6 mass%, 59.4 mass%), a nineteenth coordinate (3434343432 = 3432.5 mass%, 48.47 mass%).
[9] An aerosol composition comprising the composition according to any one of [1] to [8 ].
[10] The aerosol composition according to [9], comprising at least 1 propellant selected from the group consisting of liquefied gases and compressed gases.
[11] A cleaning method comprising bringing the composition according to any one of [1] to [8] into contact with the surface of an article to remove dirt adhering to the surface of the article.
[12] The washing method according to [11], wherein the material of the article is at least 1 selected from the group consisting of fiber, metal, resin, rubber, glass, and ceramic.
ADVANTAGEOUS EFFECTS OF INVENTION
The composition of the present invention does not adversely affect the global environment, and when used as an aerosol, the composition hardly leaves a liquid, is excellent in the cleaning property of an object, and has little effect on the material of the object.
Drawings
FIG. 1 shows the Z isomer of 1-chloro-2,3,3,3-tetrafluoropropene (hereinafter also referred to as HCFO-1224yd (Z)) as component (A) and nonafluorobutoxymethane (C) as component (B) 4 F 9 OCH 3 The phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the component (A), the content (% by mass) of HFE-449s1 as the component (B), and the content (% by mass) of HCFO-1233zd (Z) as the component (C), namely Z isomer of 1-chloro-3,3,3-trifluoropropene (hereinafter, HCFO-1233zd (Z)) shows the ranges of the three values of the composition 1 of the present invention.
FIG. 2 is a phase diagram showing three values of the content (% by mass) of (A) component HCFO-1224yd (Z), the content (% by mass) of (B) component HFE-449s1 and the content (% by mass) of (C) component HCFO-1233zd (Z) with respect to the total mass of (A) component HCFO-1224yd (Z), (B) component HFE-449s1 and (C) component HCFO-1233zd (Z), and shows suitable ranges of these three values of the composition 1 of the present invention.
FIG. 3 is a phase diagram showing three values of the content (% by mass) of (A) component HCFO-1224yd (Z), the content (% by mass) of (B) component HFE-449s1 and the content (% by mass) of (C) component HCFO-1233zd (Z) with respect to the total mass of (A) component HCFO-1224yd (Z), (B) component HFE-449s1 and (C) component HCFO-1233zd (Z), and shows more suitable ranges of these three values of the composition 1 of the present invention.
FIG. 4 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (A) component, HFE-449s1 (B) component, and HCFO-1233zd (Z) component, the content (% by mass) of HFE-449s1 (B) component, and the content (% by mass) of HCFO-1233zd (Z) component, relative to the total mass of HCFO-1224yd (Z) component (A), HCFO-1233zd (B), and further suitable ranges of these three values of composition 1 of the present invention are shown.
FIG. 5 shows HCFO-1224yd (Z) and (D) as components (A)) Component (C) is nonafluorobutoxyethane 4 F 9 OC 2 H 5 The phase diagram showing three values of the content (mass%) of HCFO-1224yd (Z) as the component (A), the content (mass%) of HFE-569sf2 as the component (D) and the content of HCFO-1233zd (Z) as the component (C) in terms of the total mass of HCFO-1233zd (Z) as the component (A) and HFE-569sf2 as the component (C) shows the ranges of these three values in the composition 2 of the present invention.
FIG. 6 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, and shows suitable ranges of these three values for the composition 2 of the present invention.
FIG. 7 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, and shows more suitable ranges of these three values of composition 2 of the present invention.
FIG. 8 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, and further suitable ranges of these three values of composition 2 of the present invention are shown.
Detailed Description
(composition 1)
A first embodiment of the composition of the invention (hereinafter referred to as composition 1 of the invention) comprises the Z isomer of 1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224 yd (Z)) (a), nonafluorobutoxymethane (HFE-449 s 1) (B), and as an optional component, the Z isomer of 1-chloro-3,3,3-trifluoropropene (HCFO-1233 zd (Z)) (C). Namely, composition 1 of the present invention is a two-component composition comprising (A) component HCFO-1224yd (Z) and (B) component HFE-449s 1; alternatively, the three-component composition comprises HCFO-1224yd (Z) as the component (A), HFE-449s1 as the component (B), and HCFO-1233zd (Z) as the component (C).
(HCFO-1224yd(Z))
HCFO-1224yd(CF 3 CF = CHCl) is an olefin having a double bond between carbon atoms. Therefore, the life in the atmosphere is short, and the ozone destruction coefficient and the global warming potential are small.
It is known that HCFO-1224yd exists as stereoisomers, and that HCFO-1224yd (Z) has a boiling point of 15 ℃ and that the E isomer of HCFO-1224yd (hereinafter also referred to as HCFO-1224yd (E)) has a boiling point of 17 ℃. HCFO-1224yd (Z), HCFO-1224yd (E) and a mixture thereof can be obtained by a known production method (normally, the HCFO-1224yd (Z) ratio is high), and the two can be separated by distillation. Composition 1 of the invention comprises HCFO-1224yd (Z) of these isomers.
By having the above boiling point, HCFO-1224yd (Z) is excellent in volatility.
HCFO-1224yd (Z) has no flash point.
HCFO-1224yd (Z) has low surface tension and viscosity and is easily evaporated at room temperature.
HCFO-1224yd (Z) is excellent in use as a cleaning agent or a coating solvent.
The HCFO-1224yd (Z) is excellent in the cleaning and removing properties of mineral oil, silicone oil, fluorine oil, synthetic oil, mold release agent, dust, etc., and in the coating properties of dissolving a lubricant such as mineral oil, silicone oil, fluorine oil, synthetic oil, etc., and applying it to an object.
Examples of the method for producing HCFO-1224yd include (1) a method of dehydrochlorination of 1,2-dichloro-2,3,3,3-tetrafluoropropane (hereinafter also referred to as HCFC-234 bb); and (2) a method of hydrogen-reducing 1,1-dichloro-2,3,3,3-tetrafluoropropene (hereinafter also referred to as CFO-1214 ya).
Each method will be described in detail below.
(1) Dehydrochlorination of HCFC-234bb
HCFC-234bb is brought into contact with a base dissolved in a solvent, i.e., a base in a solution state, in a liquid phase to conduct dehydrochlorination of HCFC-234 bb. HCFC-234bb can be produced by, for example, reacting 2,3,3,3-tetrafluoropropene (hereinafter also referred to as HFO-1234 yf) with chlorine in a solvent.
(2) Method for reducing CFO-1214ya by hydrogen
CFO-1214ya was reduced to HFO-1234yf by reduction with hydrogen in the presence of a catalyst, and HCFO-1224yd was obtained as an intermediate thereof. In addition, in this reduction reaction, various fluorine-containing compounds are by-produced in addition to HCFO-1224yd. As for CFO-1214ya, the following methods are known: for example, it is produced by dehydrofluorinating 3,3-dichloro-1,1,1,2,2-pentafluoropropane (hereinafter also referred to as HCFC-225 ca) or the like as a raw material with an aqueous alkali solution in the presence of a phase transfer catalyst; or dehydrofluorination by a gas phase reaction in the presence of a catalyst such as chromium, iron, copper, or activated carbon.
(HFE-449s1)
HFE-449s1 means C 4 F 9 OCH 3 The compounds shown. HFE-449s1 has 4 structural isomers, and only 1 of them may be contained in the composition of the present invention, or a mixture of 2 or more of them may be contained in the composition. As HFE-449s1 comprised in the composition of the invention, a mixture of 1-methoxy-2-trifluoromethyl-1,1,2,3,3,3-hexafluoropropane and 1-methoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane is preferred. The mixture may be, for example, novec7100 (manufactured by 3M).
HFE-449s1 has a boiling point of 61 ℃ and forms a vapor of 61 ℃ even when boiled, and therefore is less susceptible to adverse effects even on components that are susceptible to heat, such as rubber components and resin components.
HFE-449s1 does not have a flash point.
HFE-449s1 has low surface tension and viscosity, and is easily evaporated even at room temperature.
The effects of HFE-449s1 on rubber materials and resin materials are small.
HFE-449s1 may be manufactured by known methods.
For example, as described in Japanese patent No. 2908033, CF can be used 3 CF 2 CF 2 C(O)F、CF 3 CF(CF 3 ) C (O) F and C 2 F 5 C(O)CF 3 And mixtures thereof, and anhydrous fluoride ions such as anhydrous alkali metal fluoride (e.g., potassium fluoride or cesium fluoride) or anhydrous silver fluoride, in the presence of a quaternary ammonium compound such as ADOGEN464 available from Aldrich Chemical Company and in an anhydrous polar aprotic solvent.
(HCFO-1233zd(Z))
HCFO-1233zd(CF 3 CH = CHCl) is an olefin having a double bond between carbon atoms, and therefore, has a short life in the atmosphere, a small ozone destruction coefficient, and a small global warming potential.
It is known that HCFO-1233zd exists as stereoisomers, with HCFO-1233zd (Z) having a boiling point of about 40 ℃ and the E isomer of HCFO-1233zd (hereinafter also referred to as HCFO-1233zd (E)) having a boiling point of about 18 ℃. HCFO-1233zd (Z), HCFO-1233zd (E), and mixtures thereof can be obtained by known production methods (normally, the proportion of HCFO-1233zd (Z) is high), and both can be separated by distillation. The composition 1 of the present invention comprises HCFO-1233zd (Z) among these isomers.
The HCFO-1233zd (Z) has excellent volatility due to the boiling point.
HCFO-1233zd (Z) is not easily decomposed in the presence of oxygen although it is olefin, and has high stability.
HCFO-1233zd (Z) has no flash point.
HCFO-1233zd (Z) has low surface tension and viscosity and is easily evaporated at room temperature.
HCFO-1233zd (Z) is excellent in cleaning and removing properties of processing oil, fluorine oil, silicone oil, synthetic oil, mold release agent, dust and the like, and solubility of lubricant such as fluorine oil and silicone oil.
HCFO-1233zd can be made using known methods.
For example, a method of dehydrofluorinating 3-chloro-1,1,1,3-tetrafluoropropane (hereinafter, also referred to as HCFC-244 fa) in the presence of a catalyst is mentioned (jp 2009-263365 a).
FIG. 1 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, the content (% by mass) of HFE-449s1 as the (B) component, and the content (% by mass) of HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-449s1 as the (B) component, and HCFO-1233zd (Z) as the (C) component, and shows the ranges of these three values in the composition 1 of the present invention. In fig. 1, the upper left coordinate is set as the first coordinate, and the second coordinate, the third coordinate, the fourth coordinate, the fifth coordinate, and the sixth coordinate are set counterclockwise from the first coordinate.
In the composition 1 of the present invention, the content of the (a) component, i.e., HCFO-1224yd (Z), the (B) component, i.e., HFE-449s1, and the (C) component, i.e., HCFO-1233zd (Z) is a mass value enclosed by a line connecting the first coordinates (A, B, C =34.7 mass%, 65.3 mass%, 0.0 mass%), the second coordinates (A, B, C =74.0 mass%, 26.0 mass%, 0.0 mass%), the third coordinates (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), the fourth coordinates (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), the fifth coordinates (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), the sixth coordinates (A, B, C =5.0 mass%, 67.6 mass%), 27.6 mass%) of fig. 1 in this order by six straight lines.
In the composition 1 of the present invention, the contents of HCFO-1224yd (Z) as the component (A), HFE-449s1 as the component (B), and HCFO-1233zd (Z) as the component (C) are set to satisfy the above ranges, so that liquid is not easy to remain when the composition is used as an aerosol, the cleaning performance of the object is excellent, and the influence on the resin material is small.
FIG. 2 is a phase diagram showing three values of the content (% by mass) of the (A) component HCFO-1224yd (Z), the content (% by mass) of the (B) component HFE-449s1 and the content (% by mass) of the (C) component HCFO-1233zd (Z) with respect to the total mass of the (A) component HCFO-1224yd (Z), the (B) component HFE-449s1 and the (C) component HCFO-1233zd (Z), and shows suitable ranges of the three values in the composition 1 of the present invention. In fig. 2, the upper left coordinate is set as the seventh coordinate, and the eighth coordinate, the third coordinate, the fourth coordinate, the fifth coordinate, and the sixth coordinate are set counterclockwise from the seventh coordinate.
In the composition 1 of the present invention, if the content of the (a) component, i.e., HCFO-1224yd (Z), the (B) component, i.e., HFE-449s1, and the (C) component, i.e., HCFO-1233zd (Z), is a content of the (a) component, i.e., HCFO-1233zd (Z), in a region surrounded by a line connecting the seventh coordinate (A, B, C =29.0 mass%, 66.0 mass%, 5.0 mass%), the eighth coordinate (A, B, C =71.3 mass%, 23.7 mass%, 5.0 mass%), the third coordinate (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), the fourth coordinate (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), the fifth coordinate (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), the sixth coordinate (A, B, C =5.0 mass%, 67.6 mass%), and the fifth coordinate (HCFO-1233 mass%) of fig. 5 mass%, i.3 mass%, respectively, i.5 mass%, in this sequence, i.3 mass%, in fig. 2, i.3 mass%, i, i.3 mass%, and 5 mass%, respectively. When the content of HCFO-1233zd (Z) as the component (C) is 5.0 mass% or more, the cobutanol value (hereinafter also referred to as KB value) is improved as compared with a two-component composition in which the content ratio of HCFO-1224yd (Z) (mass%) as the component (A) and HFE-449s1 as the component (B) (HCFO-1224 yd (Z):HFE-449 s1 (mass%) in the composition 1 of the present invention is the same level in the examples described later. Therefore, further improvement in the cleaning property of the object can be expected.
FIG. 3 is a phase diagram showing three values of the content (% by mass) of (A) component HCFO-1224yd (Z), the content (% by mass) of (B) component HFE-449s1 and the content (% by mass) of (C) component HCFO-1233zd (Z) with respect to the total mass of (A) component HCFO-1224yd (Z), (B) component HFE-449s1 and (C) component HCFO-1233zd (Z), and shows more suitable ranges of these three values of the composition 1 of the present invention. In fig. 3, the upper left coordinate is set as the ninth coordinate, and the tenth coordinate, the eleventh coordinate, the twelfth coordinate, the thirteenth coordinate, the third coordinate, the fourth coordinate, the fifth coordinate, and the sixth coordinate are set counterclockwise from the ninth coordinate.
In the composition 1 of the present invention, if the content of the (a) component, i.e., HCFO-1224yd (Z), the (B) component, i.e., HFE-449s1, and the (C) component, i.e., HCFO-1233zd (Z), is within a range where the ninth coordinates (A, B, C =12.9 mass%, 67.0 mass%, 20.1 mass%), the tenth coordinates (A, B, C =16.4 mass%, 65.8 mass%, 17.8 mass%), the eleventh coordinates (A, B, C =35.4 mass%, 53.0 mass%, 11.6 mass%), the twelfth coordinates (A, B, C =53.3 mass%, 35.5 mass%, 11.2 mass%), the thirteenth coordinates (A, B, C =67.1 mass%, 20.1 mass%, 12.8 mass%), the third coordinates (A, B, C =44.4 mass%, 0.3 mass%, 1224 3.32 mass%), the thirteenth coordinates (A, B, C zft 3432 =67.1 mass%), the fifth coordinates (428 mass%), the third coordinates (4232, 4232 mass%), the fifth coordinates (4232, 428 mass%), the sixth coordinates (a) of the third coordinates (35.6 mass%), the sixth coordinates, 4232, 428 mass%), the sixth coordinates (i.7.9 mass%), the sixth coordinates) of the composition 1 mass%: HFE-449s1 (% by mass)) is the same degree of the two-component composition, the KB value is improved by more than 10%. Therefore, further improvement in the cleaning property of the object can be expected.
Fig. 4 is a phase diagram showing three values of the content (% by mass) of the (a) component HCFO-1224yd (Z), the content (% by mass) of the (B) component HFE-449s1, and the content (% by mass) of the (C) component HCFO-1233zd (Z), relative to the total mass of the (a) component HCFO-1224yd (Z), the (B) component HFE-449s1, and the (C) component HCFO-1233zd (Z), and further suitable ranges of these three values of the composition 1 of the present invention are shown.
In fig. 4, the upper left coordinate is set as the fourteenth coordinate, and the fifteenth coordinate, the sixteenth coordinate, and the seventeenth coordinate are set counterclockwise from the fourteenth coordinate.
In the composition 1 of the present invention, if the content of HCFO-1224yd (Z) which is the component (a), HFE-449s1 which is the component (B), and HCFO-1233zd (Z) which is the component (C) are values in a region surrounded by connecting lines connecting the fourteenth coordinate (A, B, C =24.2 mass%, 43.1 mass%, 32.7 mass%), the fifteenth coordinate (A, B, C =15.0 mass%, 26.7 mass%, 58.3 mass%), the sixteenth coordinate (A, B, C =5.0 mass%, 35.6 mass%, 59.4 mass%), and the seventeenth coordinate (A, B, C =5.0 mass%, 47.0 mass%, 48.0 mass%) in this order by four straight lines in this order, the ratio of the raffinate, the evaporation rate, the KB value, the material influence evaluation, and the solubility evaluation in various oils are all determined as a.
(composition 2)
The second embodiment of the composition of the present invention (hereinafter referred to as composition 2 of the present invention) comprises HCFO-1224yd (Z) as the component (A), nonafluorobutoxyethane (HFE-569 sf 2) as the component (D), and HCFO-1233zd (Z) as the optional component (C). That is, composition 2 of the present invention is a two-component composition comprising HCFO-1224yd (Z) as component (A) and HFE-569sf2 as component (D); alternatively, the composition is a three-component composition comprising HCFO-1224yd (Z) as the component (A), HFE-569sf2 as the component (D), and HCFO-1233zd (Z) as the component (C).
HCFO-1224yd (Z) and HCFO-1233zd (Z) are as described above and are therefore omitted.
(HFE-569sf2)
HFE-569sf2 means C 4 F 9 OC 2 H 5 The compounds shown. HFE-569sf2 has 4 structural isomers, and HFE-569sf2 contained in the composition of the present invention may be only 1 kind of them, or may be a mixture of 2 or more kinds of them. As HFE-569sf2 comprised in the composition of the invention, preference is given to a mixture of 1-ethoxy-2-trifluoromethyl-1,1,2,3,3,3-hexafluoropropane and 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane. The mixture may be, for example, novec7200 (manufactured by 3M).
HFE-569sf2 has a boiling point of 76 ℃ and forms steam of 76 ℃ even when boiled, and therefore is less susceptible to adverse effects even on members such as rubber members and resin members that are susceptible to heat.
HFE-569sf2 has no flash point.
HFE-569sf2 has low surface tension and viscosity, and is easily evaporated even at room temperature.
The effect of HFE-569sf2 on rubber materials and resin materials is small.
HFE-569sf2 can be produced by known methods.
For example, as described in Japanese patent No. 3068199, CF can be used 3 CF 2 CF 2 C(O)F、CF 3 CF(CF 3 ) C (O) F and C 2 F 5 C(O)CF 3 And mixtures thereof, and anhydrous fluoride ions such as anhydrous alkali metal fluoride (e.g., potassium fluoride or cesium fluoride) or anhydrous silver fluoride, in the presence of a quaternary ammonium compound such as ADOGEN464 available from Aldrich Chemical Company and in an anhydrous polar aprotic solvent.
Fig. 5 is a phase diagram showing three values of the content (% by mass) of the (a) component HCFO-1224yd (Z), the content (% by mass) of the (D) component HFE-569sf2, and the content (% by mass) of the (C) component HCFO-1233zd (Z), relative to the total mass of the (a) component HCFO-1224yd (Z), the (D) component HFE-569sf2, and the (C) component HCFO-1233zd (Z), and shows the ranges of these three values of the composition 2 of the present invention. In fig. 5, the upper left coordinate is set as the first coordinate, and the second coordinate, the third coordinate, the fourth coordinate, the fifth coordinate, and the sixth coordinate are set counterclockwise from the first coordinate.
In the composition 2 of the present invention, the content of the (a) component, i.e., HCFO-1224yd (Z), the (D) component, i.e., HFE-569sf2, and the (C) component, i.e., HCFO-1233zd (Z), is a mass enclosed by a line connecting the first coordinates (A, D, C =34.7 mass%, 65.3 mass%, 0.0 mass%), the second coordinates (A, D, C =86.0 mass%, 14.0 mass%, 0.0 mass%), the third coordinates (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), the fourth coordinates (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), the fifth coordinates (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), the sixth coordinates (A, D, C =5.0 mass%, 67.6 mass%), and 4.27 mass%) in this order by six straight lines.
In the composition 2 of the present invention, the contents of HCFO-1224yd (Z) as the component (A), HFE-569sf2 as the component (D), and HCFO-1233zd (Z) as the component (C) are set to satisfy the above ranges, so that the composition is less likely to leave liquid when used as an aerosol, is excellent in the cleaning property of an object, and has little influence on the material of the object.
FIG. 6 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, and shows suitable ranges of these three values of composition 2 of the present invention. In fig. 6, the upper left coordinate is set as the seventh coordinate, and the second coordinate, the third coordinate, the fourth coordinate, the fifth coordinate, and the sixth coordinate are set counterclockwise from the seventh coordinate.
In the composition 2 of the present invention, if the content of the (a) component, i.e., HCFO-1224yd (Z), the (D) component, i.e., HFE-569sf2, and the (C) component, i.e., HCFO-1233zd (Z), is a value equal to or greater than 5% by mass of the HCFO-1233zd (Z), which is a connecting line connecting the seventh coordinate (A, D, C =29.0 mass%, 66.0 mass%, 5.0 mass%), the eighth coordinate (A, D, C =82.3 mass%, 12.7 mass%, 5.0 mass%), the third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), the fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), the fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), the sixth coordinate (A, D, C =5.0 mass%, 67.6 mass%), and the fifth coordinate (6253 zxft) in this order of fig. 5, the content of the HCFO-1233zd is equal to or greater than 5 mass%. When the content of HCFO-1233zd (Z) as the component (C) is 5.0 mass% or more, the KB value is improved as compared with a two-component composition in which the content ratio of HFE-569sf2 as the components (A), HCFO-1224yd (Z) (mass%) and (D) (HFE-569 sf2 (mass%) in the composition 2 of the present invention is the same in the examples described later. Therefore, further improvement in the cleaning property of the object can be expected.
Fig. 7 is a phase diagram showing three values of the content (% by mass) of the (a) component HCFO-1224yd (Z), the content (% by mass) of the (D) component HFE-569sf2, and the content (% by mass) of the (C) component HCFO-1233zd (Z), relative to the total mass of the (a) component HCFO-1224yd (Z), the (D) component HFE-569sf2, and the (C) component HCFO-1233zd (Z), and shows more suitable ranges of the three values of the composition 2 of the present invention. In fig. 7, the upper left coordinate is set as the ninth coordinate, and the tenth coordinate, the eleventh coordinate, the twelfth coordinate, the thirteenth coordinate, the fourteenth coordinate, the fifteenth coordinate, the sixteenth coordinate, the seventeenth coordinate, and the eighteenth coordinate are set counterclockwise from the ninth coordinate.
In the composition 2 of the present invention, if the contents of the (a) component, i.e., HCFO-1224yd (Z), the (D) component, i.e., HFE-569sf2, and the (C) component, i.e., HCFO-1233zd (Z), are within the ninth coordinates (A, D, C =12.9 mass%, 67.0 mass%, 20.1 mass%), the tenth coordinates (A, D, C =16.4 mass%, 65.8 mass%, 17.8 mass%), the eleventh coordinates (A, D, C =35.4 mass%, 53.0 mass%, 11.6 mass%), the twelfth coordinates (A, D, C =53.3 mass%, 35.5 mass%, 11.2 mass%), the thirteenth coordinates (A, D, C =69.5 mass%, 17.4 mass%, 13.1 mass%), the fourteenth coordinates (5364 zxft 4232 =53.3 mass%, 35.5 mass%, 11.2 mass%), the thirteenth coordinates (4234 zxft 34 =69.5 mass%, 17.4 mass%, 13.1 mass%), the fourteenth coordinates (5364 zxft 3565 mass = 64, 3565 mass%), the fifth coordinates (358 mass = 3265%, 359.9.9 mass%), the fifth coordinates (358 mass%), the fifth coordinates (352 mass% >), the fifth coordinates (359.9.79 mass%), the fifth coordinates, 358 mass% >,55 mass%), the fifth coordinates (358 mass%),55 mass%),55,55,55,55,55 mass%),35,35,55,55,55,55 mass%),35,55%, the content ratio of the component (A) in the composition 2 of the present invention, i.e., HCFO-1224yd (Z), to the component (D) in the composition 2 of the present invention, i.e., HFE-569sf2 (HCFO-1224 yd (Z) (mass%): HFE-569sf2 (% by mass)) to the same extent as in the two-component composition, the KB value is improved by more than 10 percent. Therefore, further improvement in the cleaning property of the object can be expected.
FIG. 8 is a phase diagram showing three values of the content (% by mass) of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, relative to the total mass of HCFO-1224yd (Z) as the (A) component, HFE-569sf2 as the (D) component, and HCFO-1233zd (Z) as the (C) component, and further suitable ranges of these three values of composition 2 of the present invention are shown. In fig. 7, the upper left coordinate is set as the fifteenth coordinate, and the twelfth coordinate, the sixteenth coordinate, the seventeenth coordinate, the eighteenth coordinate, and the nineteenth coordinate are set counterclockwise from the fifteenth coordinate.
In the composition 2 of the present invention, the content of HCFO-1224yd (Z) which is the (a) component, HFE-569sf2 which is the (D) component, and HCFO-1233zd (Z) which is the (C) component, was evaluated in the following evaluation values of the dissolution rate and the evaporation rate of the oil in the examples, and the percentage of the dissolution rate of the oil in the dissolution zone was evaluated in the following examples, and the percentage of the dissolution rate was evaluated in the following examples, in which the fifteenth coordinate (A, D, C =51.1 mass%, 37.7 mass%, 11.2 mass%), the twelfth coordinate (A, D, C =53.3 mass%, 35.5 mass%, 11.2 mass%), the sixteenth coordinate (A, D, C =66.3 mass%, 20.9 mass%, 12.8 mass%), the seventeenth coordinate (A, D, C =33.2 mass%, 10.5 mass%, 56.3 mass%), the eighteenth coordinate (A, D, C =5.0 mass%, 35.6 mass%, 59.4 mass%), the nineteenth coordinate (A, D, C = 430%, 47.0 mass%, 48% and the percentage of the evaporation rate of the oil in fig. 8) in fig. 8 were sequentially connected by six straight lines.
The compositions 1 and 2 of the present invention do not adversely affect the global environment, and when used as an aerosol composition, the compositions are less likely to leave liquid, and are excellent in the cleaning property of objects, and further, have little effect on the materials of objects.
The aerosol composition of the present invention comprises the composition 1 or 2 of the present invention. The aerosol composition of the present invention preferably comprises a propellant, wherein more preferably at least 1 propellant selected from the group consisting of liquefied gases and compressed gases. Examples of the liquefied gas in the aerosol composition include dimethyl ether (DME), liquefied Petroleum Gas (LPG), propane, butane, isobutane, 1,1-difluoroethane (HFC-152 a), 1,1,1,2-tetrafluoroethane (HFC-134 a), 2,3,3,3-tetrafluoropropene (HFO-1234 yf), 1,3,3,3-tetrafluoropropene (HFO-1234 ze), and the like. On the other hand, examples of the compressed gas include nitrogen, carbon dioxide, compressed air, and nitrous oxide.
(cleaning method)
The cleaning method of the present invention is characterized in that the composition 1 or 2 of the present invention is extruded out of the surface of an article to remove dirt adhering to the surface of the article.
As a specific cleaning method, the composition 1 or 2 of the present invention may be brought into contact with the surface of an article. There are no particular restrictions on the method, and for example, manual wiping, dipping, spraying, shaking, ultrasonic cleaning, steam cleaning, or a combination thereof may be used. In the case of using the aerosol composition, the aerosol composition may be sprayed on the surface of the article.
As the material of the article to which the compositions 1 and 2 of the present invention can be applied, at least 1 selected from the group consisting of fibers, metals, resins, rubbers, glasses, and ceramics is preferable, and as the fibers, natural fibers and synthetic fibers can be cited. Further, the article may be formed of a composite material having 2 or more kinds of these materials. Examples of the composite material include a laminate of a metal and a resin. In particular, the compositions 1 and 2 of the present invention can be used for articles containing a rubber material such as Styrene Butadiene Rubber (SBR) or a resin material such as Polycarbonate (PC) resin or polyphenylene ether (PPE) resin which is affected by HCFO-1233zd (Z).
Specific examples of the article include fiber products, medical instruments, electrical equipment, precision machines, optical equipment, vehicles, transportation equipment, and parts thereof. Specific examples of electrical equipment, precision machinery, optical articles, and parts thereof include ICs, capacitors, printed circuit boards, micro motors, relays, bearings, optical lenses, glass substrates, and the like. Specific examples of the vehicle, the transportation equipment, and the components thereof include a vehicle body, a brake component, a suspension, a wheel, and the like. In particular, the composition of the present invention can be used for articles comprising a rubber material such as SBR and a resin material such as PC resin or PPE resin as a material for at least a part of the surface of the article which is in contact with the composition.
In the cleaning method of the present invention, examples of the dirt to be cleaned and removed include carbon, flux, processing oil, release agent, sebum, food oil, and grease such as cosmetics which adhere to various objects to be cleaned, and dust and the like which adhere via these. Examples of the processing oil include cutting oil, quenching oil, rolling oil, lubricating oil, machine oil, press oil, punching oil, drawing oil, assembly oil, drawing oil, and brake fluid. Examples of the cosmetic include nail polish and lipstick. 2 or more of the above-mentioned stains may be attached to various objects to be cleaned. The composition of the present invention is excellent in solubility in these oils, silicone oils, fluorine oils, and the like as compared with conventional solvent compositions such as HFC, HFE, and the like, and therefore is preferably used for cleaning stains containing these oils.
When the compositions 1 and 2 of the present invention are used as aerosol compositions, the compositions are less likely to leave liquid and have little influence on the material of the object, and are excellent in both the evaporation rate evaluation and the KB value evaluation shown in examples described below, and therefore, they can also be used as solvents for forming a coating film of a nonvolatile organic compound from an aerosol (hereinafter, also referred to as coating film forming solvents).
When used as a solvent for forming a coating film, the content of the nonvolatile organic compound is preferably 0.01 to 50% by mass, more preferably 0.05 to 30% by mass, and particularly preferably 0.1 to 20% by mass, based on 100% by mass of the total of the composition 1 or 2 of the present invention and the nonvolatile organic compound. When the content of the nonvolatile organic compound is in the above range, the film thickness of the coating film at the time of coating the nonvolatile organic compound and the thickness of the nonvolatile organic compound coating film after evaporation removal (hereinafter, also referred to as drying) of the solvent for coating film formation can be easily adjusted to appropriate ranges.
The nonvolatile organic compound is a compound having a boiling point higher than that of the solvent for forming the coating film and remaining after the solvent for forming the coating film is evaporated. Specific examples of the nonvolatile organic compound include a lubricant for imparting lubricity to an article, a rust inhibitor for imparting a rust-preventing effect to a metal member, a moisture-repellent coating agent for imparting water repellency to an article, and an antifouling coating agent such as a fingerprint-resistant agent for imparting antifouling property to an article. Among these, from the viewpoint of solubility, it is preferable to use a lubricant as the nonvolatile organic compound.
The lubricant is: when two members are moved in a state where their surfaces are in contact with each other, a preparation is used for reducing friction at the contact surface and preventing heat generation and friction damage. The lubricant may be in any form of liquid (oil), semisolid (grease), or solid.
The lubricant is preferably a mineral oil-based lubricant, a synthetic oil-based lubricant, a fluorine-based lubricant, or a silicone-based lubricant, from the viewpoint of excellent solubility in the coating film forming solvent. The fluorine-based lubricant is a lubricant having a fluorine atom in a molecule. The silicone-based lubricant refers to a lubricant containing silicone. The number of the lubricants may be 1 or 2 or more. The fluorine-based lubricant and the silicone-based lubricant may be used alone or in combination.
Examples of the fluorine-based lubricant include fluorine-based solid lubricants such as fluorine oil, fluorine grease, and polytetrafluoroethylene resin powder. As the fluorine oil, perfluoropolyether and an oligomer of chlorotrifluoroethylene are preferable. Examples of the product name include "Krytox (registered trademark) GPL102" (manufactured by DuPont), "Daifloil #1", "Daifloil #3", "Daifloil # 10", "Daifloil # 20", "Daifloil # 50", "Daifloil # 100" and "Demnum S-65" (manufactured by Dajinindustry Co., ltd.). As the fluorine grease, preferred are: a grease comprising a base oil of a fluorine oil such as perfluoropolyether or an oligomer of chlorotrifluoroethylene, a polytetrafluoroethylene powder and another thickener. Examples thereof include "Krytox (registered trademark) Grease 240AC" (manufactured by DuPont), "Daifloil Grease DG-203", "Demnum L65", "Demnum L100", "Demnum L200" (manufactured by Dajin Co., ltd.), "SUMITEC F936" (manufactured by Daxishi Lubricannsi Co., ltd.), "Molykote (registered trademark) HP-300", "Molykote (registered trademark) HP-500", "Molykote (registered trademark) HP-870", "Molykote (registered trademark) 6169".
Examples of the silicone lubricant include silicone oil and silicone grease. The silicone oil is preferably a dimethylsilicone, methylhydrogensilicone, methylphenylsilicone, cyclic dimethylsilicone, or modified silicone oil having an organic group introduced into a side chain or a terminal. Examples thereof include the product names "CROSS silicone KF-96", "CROSS silicone KF-965", "CROSS silicone KF-968", "CROSS silicone KF-868", "CROSS silicone KF-99", "CROSS silicone KF-50", "CROSS silicone KF-54", "CROSS silicone HIVACF-4", "CROSS silicone HIVACF-5", "CROSS silicone KF-56A", "CROSS silicone KF-995", "CROSS silicone KF-868" and "CROSS silicone KF-859" (the above is manufactured by CROSS chemical industries); "SH200" and "MDX4-4159" (manufactured by Dongli-do-Corning Co., ltd.). As the silicone grease, preferred are: the silicone oil is a base oil, and a thickener such as a metal soap and various additives are added to the base oil. Examples thereof include the product names "CROSS SILICON G-30 series", "CROSS SILICON G-40 series", "CROSS SILICON FG-720 series", "CROSS SILICON G-411", "CROSS SILICON G-501", "CROSS SILICON G-6500", "CROSS SILICON G-330", "CROSS SILICON G-340", "CROSS SILICON G-350", "CROSS SILICON G-630" (manufactured by CROSS CHEMICAL CO., LTD.). "Molykote (registered trademark) SH33L", "Molykote (registered trademark) 41", "Molykote (registered trademark) 44", "Molykote (registered trademark) 822M", "Molykote (registered trademark) 111", "Molykote (registered trademark) high vacuum grease", "Molykote (registered trademark) thermal diffusion mixture" (manufactured by tollgan corporation, above), and the like.
The antirust agent is as follows: a substance for covering the surface of a metal which is easily oxidized and rusted by oxygen in the air, and isolating the surface of the metal from oxygen, thereby preventing the metal material from rusting. Examples of the rust inhibitor include synthetic oils such as mineral oils, polyol esters, polyalkylene glycols, and polyvinyl ethers.
Examples of products of the moisture-proof coating agent include Topas 5013, topas 6013, and Topas 8007 (manufactured by polyclastic corporation); ZEONOR 1020R, ZEONOR R (made by ZEON corporation, japan); APEL 6011T, APEL 8008T (made by Mitsui chemical Co., ltd.); SFE-DP02H, SNF-DP20H (manufactured by Seimi Chemical Co., ltd.). Examples of the products of the antifouling coating agent such as the anti-fingerprint adhesive include Optool DSX, optool DAC (manufactured by Dajin industries, ltd.), FLUOROSURF FG-5000 (manufactured by Fluoro Technology, ltd.), SR-4000A (manufactured by Seimi Chemical Co., ltd.), and the like.
As a substrate for forming a coating film of a nonvolatile organic compound, a substrate made of various materials such as metal, resin, rubber, glass, and ceramics can be used. Further, depending on the solvent for forming the coating film, the coating film of the nonvolatile organic compound can be formed without affecting articles including a rubber material and a resin material.
Specific examples of the substrate on which the coating film of the nonvolatile organic compound is formed include home appliances and office appliances such as carrier parts for CD and DVD in industrial equipment, personal computers and audio equipment, printers, copying equipment and welding equipment, as examples of the fluorine-based lubricant. Examples of the silicone-based lubricant include a syringe, a cylinder, a medical tube member, a metal cutter, a catheter, and the like. Examples of the use of the moisture-proof coating agent and the stain-proofing coating agent include devices used for imparting moisture-proof and stain-proofing properties to plastic materials, rubber materials, metal materials, glass materials, mounting recycled plates, and the like.
Examples
The present invention will be described in detail below with reference to examples. The present invention is not limited to these examples. Examples 15 to 21, 26 to 32, 67 to 70, 72 to 74, 76 to 78, 80 to 83, 86 to 88, 90 to 92, 94 to 97, 99 to 103, 106, 107, 110 to 133, 135, 136, 138 to 170 are examples of the composition of the present invention, and examples 1 to 14, 22 to 25, 33 to 66, 71, 75, 79, 84, 85, 89, 93, 98, 104, 105, 108, 109, 134, 137 are comparative examples.
(preparation of HCFO-1224yd (Z))
An isomer mixture of HCFO-1224yd (E) and HCFO-1224yd (Z) was produced by the method described in International publication No. 2017/110851. The isomer mixture was purified by the method described in International publication No. 2017/146190 to prepare HCFO-1224yd (Z) having a purity of 99.5%.
(preparation of HFE-449s1 or HFE-569sf 2)
Separately, 3M was purchased as HFE-449s1, a HFE-based nonflammable fluorine-based solvent TM NOVEC TM 7100 highly functional liquid (3M JAPAN, japan) is availablePurchase of 3M HFE-569sf2 as a nonflammable fluorine-based solvent of HFE series TM NOVEC TM 7200 high functional liquid (3M JAPAN company, japan).
(preparation of HCFO-1233zd (Z))
HCFO-1233zd (Z) was produced by the method described in Japanese patent application laid-open No. 2013-87066. After production, the resulting product was purified to obtain HCFO-1233zd (Z) with a purity of 99.5%.
(evaluation of ratio of residue based on spray)
HCFO-1224yd (Z), HCFO-1233zd (Z), and HFE-449s1 or HFE-569sf2 were sequentially filled into an aerosol container from the component having a high boiling point so as to have a mass ratio shown in the following table, and then blended. The filling amount was adjusted so that the volume of the liquid phase of the composition became about 80 vol% of the volume of the aerosol container. Thereafter, the pressure in the aerosol container was adjusted to 0.5MPaG by pressurizing with nitrogen and carbon dioxide.
Continuously spraying from the liquid phase in a room at a temperature of 25 ℃. + -. 2 ℃ until the composition filled in the aerosol container is not ejected from the aerosol container. The mass M' of the composition remaining in the aerosol container was measured and calculated from the initial filling mass M according to the following formula 0 The ratio M of the raffinate.
M=M’/M 0 ×100
The ratio of the residual liquid obtained by the above experiment was evaluated according to the following criteria.
Good: the ratio M of the residual liquid is less than 2.0 percent
Poor results: the residual liquid ratio M is more than 2.0 percent
(evaluation of Evaporation Rate)
HCFO-1224yd (Z), HCFO-1233zd (Z), and HFE-449s1 or HFE-569sf2 were sequentially filled into a stainless steel (SUS) -made pressure-resistant container from the components having high boiling points so as to have the mass ratios shown in the following table, and then mixed. The filling amount was adjusted so that the volume of the composition in the liquid phase became about 80 vol% of the volume of the SUS pressure resistant vessel.
The prepared composition was charged into a petri dish having an opening with a diameter of 90mm and a height of 21mm, which was set on a balance, so that the total amount of the composition was 30 g.
The change in mass accompanying the volatilization of the composition in the petri dish was recorded in a room at a temperature of 25 ℃. + -. 2 ℃ and the time from 30g of the initial mass to 0.3g, which is 1 mass% of the initial mass, was defined as the evaporation time T e The evaporation rate V is calculated according to the following formula e 。
V e =(30-0.3)/T e
Regarding the calculated evaporation rate, the evaporation rate V of HCFO-1233zd (Z) is calculated e The evaluation was made with the following criteria, assuming that it was 1.0.
A:1.0 or less
B: more than 1.0 and not more than 1.5
C: over 1.5
(evaluation of KB value)
HCFO-1224yd (Z), HCFO-1233zd (Z), and HFE-449s1 or HFE-569sf2 were charged into a 96cc super glass cylinder (manufactured by Katsubishi Kagaku Kogyo Co., ltd.) in a thermostatic bath set at 25 ℃ in this order from a composition having a high boiling point so as to obtain the mass ratio shown in the following table, and the KB value was determined according to the method described in ASTM: D1133-13.
The obtained KB value was evaluated according to the following criteria.
A:14 or more
B:10 or more and less than 14
C: less than 10
In the present specification, the evaporation rate evaluation and KB value evaluation are used as indexes of the cleanability of the object. When both the evaporation rate evaluation and the KB value evaluation were excellent, the object had excellent cleaning properties.
(evaluation of solubility in various oils)
5g of various oils (brake fluid 2500H-A) manufactured by Fuji chemical research of Kabushiki Kaisha, silicone oil (shin silicone KF-96-50 cs) manufactured by shin-Etsu chemical industry Co., ltd., and fluorine oil (FOMBLIN Y25) manufactured by Solvay Co., ltd., japan) was added to a 96cc super glass cylinder (manufactured by pressure-resistant Nitro industry Co., ltd.) set in a thermostatic bath having a temperature of 25 ℃, and then HCFO-1224yd (Z), HCFO-1233zd (Z), and HFE-449s1 or HFE-569sf2 were sequentially charged from components having high boiling points so as to have a mass ratio shown in the following table, and the total mass was prepared so as to be 45 g. The composition and oils were mixed, and the solution state (solubility) after standing at 25 ℃ for 2 hours was evaluated for solubility according to the following criteria.
A: transparent dissolution
B: pale white turbidity
C: cloudy/biphasic separation
When the solubility was evaluated as B, there was no problem in terms of use, but when the solubility was evaluated as C, it was not usable.
(Material Effect test)
3 test pieces (20 mm. Times.37.5 mm. Times.2 mm in thickness) of a Polycarbonate (PC) resin or a polyphenylene ether (PPE) resin were charged into 96cc super glass cartridges (manufactured by Katsubishi Katsuki Kaishi Co., ltd.), and then HCFO-1224yd (Z), HCFO-1233zd (Z), and HFE-449s1 or HFE-569sf2 were filled in this order from components having high boiling points so as to have a mass ratio shown in the following table, and the total mass was adjusted to 80 g.
Thereafter, the super glass cylinder was left to stand at 25 ℃ for 30 minutes, and then the test piece was taken out to evaluate the appearance according to the following criteria.
A: no change in appearance was observed in the test piece.
B: slight cracking or slight loss of transparency and discoloration were observed in the test pieces.
C: on the surface of the test piece, remarkable cracks, loss of transparency, discoloration, and dissolution were observed.
When the material impact test is evaluated as B, there is no problem in terms of use, but when it is evaluated as C, it cannot be used.
The results are shown in the following table.
[ Table 1]
[ Table 2]
[ Table 3]
[ Table 4]
[ Table 5]
[ Table 6]
The results of the residual liquid tests of examples 15 to 21, 26 to 32, 67 to 70, 72 to 74, 76 to 78, 80 to 83, 86 to 88, 90 to 92, 94 to 97, 99 to 103, 106, 107, 110 to 133, 135, 136, 138 to 170 were good, and the results of the evaporation rate, KB value, evaluation of material influence, and evaluation of solubility in various oils were B or more.
A three-component composition comprising HCFO-1224yd (Z) as a component (A), HFE-449s1 as a component (B), and HCFO-1233zd (Z) as a component (C), wherein the content of HCFO-1233zd (Z) as a component (C) is 5.0 mass% or more, examples 67 to 70, 72 to 74, 76 to 78, 80 to 83, 106 to 107, 110 to 117, and 119 to 133 are similar to the content ratio of HCFO-1224yd (Z) (mass%) to HFE-449s1 (mass%) in a two-component composition, and KB is improved. For example, HCFO-1224yd (Z) (mass%): HFE-449s1 (mass%) was 38.0: example 115 of 57.0 and HCFO-1224yd (Z) (mass%): HFE-449s1 (% by mass)) was 40.0: the KB value is improved compared with example 18, which is 60.0.
A three-component composition comprising HCFO-1224yd (Z) as a component (A), HFE-569sf2 as a component (D), and HCFO-1233zd (Z) as a component (C), wherein the content of HCFO-1233zd (Z) as a component (C) is 5.0 mass% or more, examples 86-88, 90-92, 94-97, 99-103, 135, 136, 138-142, 144-148, 150-153, 155-170 are improved in KB as compared with a two-component composition having the same content ratio (HCFO-1224 yd (Z) (mass%) to HFE-569sf2 (mass%) of HCFO-1224yd (Z) and HFE-569sf 2. For example, HCFO-1224yd (Z) (mass%): HFE-569sf2 is 38.0: example 144 of 57.0 with HCFO-1224yd (Z) (mass%): HFE-569sf2 (% by mass)) was 40.0: in example 143 of 60.0, the KB value is improved.
The contents of HCFO-1224yd (Z), HFE-449s1 and HCFO-1233zd (Z) are values within the region surrounded by nine lines connecting the coordinates of FIG. 3, examples 67-69, 72-74, 76-78, 80-83, 106, 107, 111-114, 116, 117, 120, 121, 128-133, and the KB value is improved by 10% or more compared with the two-component composition in which the content ratio of HCFO-1224yd (Z) (mass%): HFE-449s1 (mass%) to HCFO-1224yd (Z) and HFE-449s1 is the same degree. For example, HCFO-1224yd (Z) (mass%): HFE-449s1 (mass%) 35.4: example 116 of 53.0 and HCFO-1224yd (Z) (mass%): HFE-449s1 (% by mass)) was 40.0: the KB value is improved by 10% in comparison with example 18, which is 60.0.
Examples 86, 90, 91, 94 to 97, 99 to 103, 135, 136, 139 to 142, 145 to 148, 151 to 153, 156, 157, 164 to 170 in which the contents of HCFO-1224yd (Z), HFE-569sf2 and HCFO-1233zd (Z) are values in a region surrounded by ten connecting lines connecting ten coordinates of FIG. 7 by ten straight lines show the same degree of the content ratio of HCFO-1224yd (Z) to HFE-569sf2 (HCFO-1224 yd (Z) (mass%): HFE-569sf2 (mass%)), and the KB value is improved by 10% or more. For example, HCFO-1224yd (Z) (mass%): HFE-569sf2 is 35.4: example 145 of 53.0 compares to HCFO-1224yd (Z) (mass%): HFE-569sf2 (% by mass)) was 40.0: example 143 of 60.0 shows a 10% increase in KB value.
Of examples 67 to 69, 72 to 74, 76 to 78, 80 to 83, 106, 107, 110 to 114, 116, 117, 120, 121, and 128 to 133, examples 72, 73, 107, 112, 113, and 130 to 133 in which the contents of HCFO-1224yd (Z), HFE-449s1, and HCFO-1233zd (Z) are values within a region surrounded by a line connecting four coordinates of FIG. 4 by four straight lines were judged as A for the residual liquid ratio, the evaporation rate, the KB value, the evaluation of the influence of the material, and the evaluation of the solubility in various oils.
Of examples 86, 90, 91, 94 to 97, 99 to 103, 135, 136, 139 to 142, 145 to 148, 151 to 153, 156, 157, 164 to 170, examples 86, 90, 91, 95, 96, 136, 140, 141, 146, 147, 151, 152, 166 to 170 in which the contents of HCFO-1224yd (Z), HFE-569sf2, and HCFO-1233zd (Z) are values within a region surrounded by a line connecting six coordinates of FIG. 8 by six straight lines were all judged as A.
Industrial applicability
The composition of the present invention is useful for use as an aerosol because it does not adversely affect the global environment, does not easily leave liquid when used as an aerosol, has excellent cleaning properties for objects, and has little effect on the material of objects.
The entire contents of the specification, claims, drawings and abstract of japanese patent application No. 2020-117687, published on 7/8/2020, japanese patent application No. 2021-047324, published on 3/22/2021, and japanese patent application No. 2021-100986, published on 6/17/2021 are incorporated herein by reference as the disclosure of the present specification.
Claims (12)
1. A composition, comprising:
1-chloro-2,3,3,3-the Z isomer of tetrafluoropropene (a);
nonafluorobutoxymethane (B); and
as an optional component, 1-chloro-3,3,3-trifluoropropene Z isomer (C),
in a phase diagram of three values of the content (% by mass) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (% by mass) of nonafluorobutoxymethane (B) and the content (% by mass) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene relative to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, Z isomer (B) of nonafluorobutoxymethane (B) and Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of masses enclosed by a connecting line connecting a first coordinate (A, B, C =34.7 mass%, 65.3 mass%, 0.0 mass%), a second coordinate (A, B, C =74.0 mass%, 26.0 mass%, 0.0 mass%), a third coordinate (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), a fourth coordinate (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (343432 zxft 5362 = 0.7 mass%, 27.6 mass%), and 27.6 mass%, in this order, with six straight lines.
2. The composition according to claim 1, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of nonafluorobutoxymethane (B) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxymethane (B) and the Z isomer (mass%) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of masses enclosed by a connecting line connecting a seventh coordinate (A, B, C =29.0 mass%, 66.0 mass%, 5.0 mass%), an eighth coordinate (A, B, C =71.3 mass%, 23.7 mass%, 5.0 mass%), a third coordinate (A, B, C =44.4 mass%, 0.3 mass%, 55.3 mass%), a fourth coordinate (A, B, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, B, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (343432 = 3432.7 mass%, 5.6 mass%), and 27.6 mass%, in this order, with six straight lines.
3. The composition according to claim 1 or 2, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of nonafluorobutoxymethane (B) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxymethane (B) and the Z isomer (mass%) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of coordinates (A, B, C = 12.9%, 67.0%, 20.1%, mass%) sequentially connected by nine straight lines, the ninth coordinates (A, B, C = 16.4%, 65.8%, 17.8%, mass%), the eleventh coordinates (A, B, C = 35.4%, 53.0%, 11.6%, the twelfth coordinates (A, B, C = 53.3%, 35.5%, 11.2%, the thirteenth coordinates (A, B, C = 67.1%, 20.1%, 12.8%, 35.3%, 35.5%, 11.2%), the thirteenth coordinates (A, B, C = 67.1%, 20.1%, 12.8%, 35.3, 35, 35.5%, 27.8%, 27%, 26.6%, 27.6%, 27%, 25, 27.8%, and the sixth coordinates (35, 27.3, 27.8%).
4. The composition according to any one of claims 1 to 3, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxymethane (B) and the Z isomer (mass%) of 1-chloro-3,3,3-trifluoropropene, the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxymethane (B), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values in a region surrounded by a connecting line connecting a fourteenth coordinate (A, B, C =24.2 mass%, 43.1 mass%, 32.7 mass%), a fifteenth coordinate (A, B, C =15.0 mass%, 26.7 mass%, 58.3 mass%), a sixteenth coordinate (A, B, C =5.0 mass%, 35.6 mass%, 59.4 mass%), a seventeenth coordinate (A, B, C =5.0 mass%, 47.0 mass%, 48.0 mass%) in this order by four straight lines.
5. A composition, comprising:
1-chloro-2,3,3,3-the Z isomer of tetrafluoropropene (a);
nonafluorobutoxyethane (D); and
as an optional component, 1-chloro-3,3,3-trifluoropropene Z isomer (C),
in a phase diagram of three values of the content (mass%) of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D) and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of the Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the Z isomer (D) of the nonafluorobutoxyethane (D) and the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are values of the mass of a region enclosed by a connecting line connecting a first coordinate (A, D, C =34.7 mass%, 65.3 mass%, 0.0 mass%), a second coordinate (A, D, C =86.0 mass%, 14.0 mass%, 0.0 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (A, D, C = 320.5.6 mass%), and 27.6 mass%) in this order by six straight lines.
6. The composition according to claim 5, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of nonafluorobutoxyethane (D) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxyethane (D) and the Z isomer (mass%) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of Z isomer (a) of the 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of Z isomer (C) of the 1-chloro-3,3,3-trifluoropropene are values of the masses of the connected lines enclosing a seventh coordinate (A, D, C =29.0 mass%, 66.0 mass%, 5.0 mass%), an eighth coordinate (A, D, C =82.3 mass%, 12.7 mass%, 5.0 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (A, D, C = 3262), 320.5.6 mass%, 67 mass%, 27.6 mass%) by six straight lines.
7. The composition according to claim 5 or 6, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of nonafluorobutoxyethane (D) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxyethane (D) and the Z isomer (mass%) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are determined by connecting a ninth coordinate (A, D, C =12.9 mass%, 67.0 mass%, 20.1 mass%), a tenth coordinate (A, D, C =16.4 mass%, 65.8 mass%, 17.8 mass%), an eleventh coordinate (A, D, C =35.4 mass%, 53.0 mass%, 11.6 mass%), a twelfth coordinate (A, D, C =53.3 mass%, (A, D, C =53.3 mass%) 35.5 mass%, 11.2 mass%), a thirteenth coordinate (A, D, C =69.5 mass%, 17.4 mass%, 13.1 mass%), a fourteenth coordinate (A, D, C =75.6 mass%, 10.5 mass%, 13.9 mass%), a third coordinate (A, D, C =44.8 mass%, 0.1 mass%, 55.1 mass%), a fourth coordinate (A, D, C =25.7 mass%, 10.7 mass%, 63.6 mass%), a fifth coordinate (A, D, C =5.0 mass%, 26.2 mass%, 68.8 mass%), a sixth coordinate (A, D, C =5.0 mass%, 67.6 mass%, 27.4 mass%), and a value within a region surrounded by a connecting line.
8. The composition according to any one of claims 5 to 7, wherein in a phase diagram of three values of the content (mass%) of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D) and the content (mass%) of Z isomer (C) of 1-chloro-3,3,3-trifluoropropene, with respect to the total mass of Z isomer (A) of 1-chloro-2,3,3,3-tetrafluoropropene, the nonafluorobutoxyethane (D) and the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene,
the content (mass%) of the Z isomer (a) of 1-chloro-2,3,3,3-tetrafluoropropene, the content (mass%) of the nonafluorobutoxyethane (D), and the content (mass%) of the Z isomer (C) of 1-chloro-3,3,3-trifluoropropene are mass values of regions surrounded by a connecting line connecting a fifteenth coordinate (A, D, C =51.1 mass%, 37.7 mass%, 11.2 mass%), a twelfth coordinate (A, D, C =53.3 mass%, 35.5 mass%, 11.2 mass%), a sixteenth coordinate (A, D, C =66.3 mass%, 20.9 mass%, 12.8 mass%), a seventeenth coordinate (A, D, C =33.2 mass%, 10.5 mass%, 56.3 mass%), an eighteenth coordinate (A, D, C =5.0 mass%, 35.6 mass%, 59.4 mass%), a nineteenth coordinate (3434343432 = 32.5 mass%, 0.47 mass%).
9. An aerosol composition comprising the composition of any one of claims 1 to 8.
10. The aerosol composition of claim 9, comprising at least 1 propellant selected from the group consisting of liquefied gases and compressed gases.
11. A cleaning method, wherein the composition according to any one of claims 1 to 8 is brought into contact with the surface of an article to remove dirt adhering to the surface of the article.
12. The cleaning method according to claim 11, wherein the material of the article is at least 1 selected from the group consisting of fiber, metal, resin, rubber, glass, and ceramic.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020-117687 | 2020-07-08 | ||
JP2020117687 | 2020-07-08 | ||
JP2021047324 | 2021-03-22 | ||
JP2021-047324 | 2021-03-22 | ||
JP2021-100986 | 2021-06-17 | ||
JP2021100986 | 2021-06-17 | ||
PCT/JP2021/025155 WO2022009801A1 (en) | 2020-07-08 | 2021-07-02 | Composition and use thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN115702235A true CN115702235A (en) | 2023-02-14 |
Family
ID=79552617
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202180044125.2A Pending CN115702235A (en) | 2020-07-08 | 2021-07-02 | Composition and use thereof |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPWO2022009801A1 (en) |
CN (1) | CN115702235A (en) |
WO (1) | WO2022009801A1 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962070A (en) * | 2007-03-29 | 2015-10-07 | 阿科玛股份有限公司 | Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin |
JP2017043742A (en) * | 2015-08-28 | 2017-03-02 | 旭硝子株式会社 | Solvent composition |
CN107641214A (en) * | 2011-12-19 | 2018-01-30 | 霍尼韦尔国际公司 | Composition comprising 1,1,3,3,3 pentafluoropropanes and pentamethylene |
CN108359121A (en) * | 2017-12-14 | 2018-08-03 | 浙江衢化氟化学有限公司 | A kind of azeotropic and Azeotrope-like compositions |
WO2019036049A1 (en) * | 2017-08-18 | 2019-02-21 | The Chemours Company, Fc, Llc | Compositions and uses of z-1-chloro-2,3,3,3-tetrafluoroprop-1-ene |
WO2019123759A1 (en) * | 2017-12-22 | 2019-06-27 | Agc株式会社 | Solvent composition, cleaning method, coating forming composition, method for manufacturing coated substrate, aerosol composition, rinsing composition, method for cleaning member, and device for cleaning member |
-
2021
- 2021-07-02 WO PCT/JP2021/025155 patent/WO2022009801A1/en active Application Filing
- 2021-07-02 JP JP2022535299A patent/JPWO2022009801A1/ja active Pending
- 2021-07-02 CN CN202180044125.2A patent/CN115702235A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962070A (en) * | 2007-03-29 | 2015-10-07 | 阿科玛股份有限公司 | Blowing agent composition of hydrofluoropropene and hydrochlorofluoroolefin |
CN107641214A (en) * | 2011-12-19 | 2018-01-30 | 霍尼韦尔国际公司 | Composition comprising 1,1,3,3,3 pentafluoropropanes and pentamethylene |
JP2017043742A (en) * | 2015-08-28 | 2017-03-02 | 旭硝子株式会社 | Solvent composition |
WO2019036049A1 (en) * | 2017-08-18 | 2019-02-21 | The Chemours Company, Fc, Llc | Compositions and uses of z-1-chloro-2,3,3,3-tetrafluoroprop-1-ene |
CN108359121A (en) * | 2017-12-14 | 2018-08-03 | 浙江衢化氟化学有限公司 | A kind of azeotropic and Azeotrope-like compositions |
WO2019123759A1 (en) * | 2017-12-22 | 2019-06-27 | Agc株式会社 | Solvent composition, cleaning method, coating forming composition, method for manufacturing coated substrate, aerosol composition, rinsing composition, method for cleaning member, and device for cleaning member |
Also Published As
Publication number | Publication date |
---|---|
JPWO2022009801A1 (en) | 2022-01-13 |
WO2022009801A1 (en) | 2022-01-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3778788B1 (en) | Coating film-forming composition | |
CA2996905C (en) | Low flammability solvent composition | |
US20090159850A1 (en) | Solvent Compositions | |
WO2020022474A1 (en) | Azeotrope(-like) composition | |
AU2002227915A1 (en) | Solvent compositions | |
CN113444492B (en) | Solvent composition, aerosol composition, cleaning agent and method for cleaning article | |
JP2022086487A (en) | Fluorine-based solvent composition | |
JP7216302B2 (en) | Detergent composition, cleaning aerosol, method for cleaning contaminated part | |
CN114846129B (en) | Solvent composition and use thereof | |
CN115702235A (en) | Composition and use thereof | |
EP3464227A1 (en) | Methods for producing solvents derived from 1-chloro-3, 3, 3-trifluoro-propene (1233zd) | |
EP4268985A1 (en) | Composition comprising monochlorotrifluoropropene and stabilizer, and its applications | |
US20220073804A1 (en) | Azeotropic composition, azeotrope-like composition, composition, cleaning agent, solvent, and heat transfer medium | |
JP2021105141A (en) | Solvent composition and its use | |
WO2023027188A1 (en) | Solvent composition, cleaning agent, cleaning method, coating film-forming composition, method for producing substrate having coating film, and aerosol | |
JP2021116323A (en) | Azeotrope-like composition and liquid composition | |
CN117693576A (en) | Solvent composition, cleaning method, method for producing article with coating film, aerosol composition, and heat transfer medium | |
JP2023119704A (en) | Cleaner composition and cleaning method | |
JP2023158658A (en) | Solvent composition and applications thereof | |
JP2022016313A (en) | Solvent composition and applications thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |