CN115627427A - Steel for excavator forging bucket teeth and preparation method thereof - Google Patents

Steel for excavator forging bucket teeth and preparation method thereof Download PDF

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Publication number
CN115627427A
CN115627427A CN202211323712.8A CN202211323712A CN115627427A CN 115627427 A CN115627427 A CN 115627427A CN 202211323712 A CN202211323712 A CN 202211323712A CN 115627427 A CN115627427 A CN 115627427A
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steel
equal
excavator
forging
rolling
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方圆
文辉
李英奎
邓伟
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Nanjing Iron and Steel Co Ltd
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Nanjing Iron and Steel Co Ltd
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Priority to CN202211323712.8A priority Critical patent/CN115627427A/en
Publication of CN115627427A publication Critical patent/CN115627427A/en
Priority to PCT/CN2023/111209 priority patent/WO2024087788A1/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses steel for a forging bucket tooth of an excavator and a preparation method thereof, wherein the steel for the forging bucket tooth of the excavator comprises the following chemical components in percentage by mass: c:0.30-0.37%, si:1.25-1.55%, mn:1.00-1.30%, P: less than or equal to 0.035%, S: less than or equal to 0.035%, cr:1.20-1.50%, al:0.020-0.050%, and the balance of Fe and inevitable impurities; the preparation process comprises converter smelting, LF refining, RH vacuum treatment, continuous casting, heating, rolling and cooling. The invention adopts low-cost alloy elements to carry out component design, adopts the optimal component proportion, and obtains the steel for forging bucket teeth, which has the yield strength of more than or equal to 1500MPa, the tensile strength of more than or equal to 1800MPa, the longitudinal impact absorption power of more than or equal to 45J at 20 ℃, the rolling hardness of 220-240HB and good hardenability.

Description

Steel for excavator forging bucket teeth and preparation method thereof
Technical Field
The invention relates to a steel and a preparation method thereof, in particular to steel for forging bucket teeth of a excavator and a preparation method thereof.
Background
The bucket teeth are easily-worn parts in the working process of the excavator, according to different working scenes, one pair of bucket teeth can be used for 15-45 days in earthwork operation generally, and mine operation can be used for 5-10 days generally, and the failure is mainly that tooth tips are continuously worn until tooth roots are exposed and completely scrapped. A pair of wear-resistant bucket teeth with excellent performance can greatly reduce the replacement and maintenance time and improve the working efficiency, so that the steel for the bucket teeth is required to have good structure uniformity, high hardenability, wear resistance and excellent mechanical property. The design of low cost and high hardenability and the matching of the design with the blanking and water quenching process of downstream users are the key difficulties in the design and production of the steel for forging the bucket teeth.
Disclosure of Invention
The invention aims to: the invention aims to provide steel for forging bucket teeth of excavators, which has excellent mechanical property; the invention also aims to provide a preparation method of the steel for the excavator forging bucket teeth, which adopts the component design and optimized production process of low-cost alloys C, mn, si and Cr to ensure that the steel has good structure uniformity, high hardenability, wear resistance and excellent mechanical properties.
The technical scheme is as follows: the steel for the excavator forging bucket tooth comprises the following chemical components in percentage by mass: c:0.30-0.37%, si:1.25-1.55%, mn:1.00-1.30%, P: less than or equal to 0.035%, S: less than or equal to 0.035%, cr:1.20-1.50%, al:0.020-0.050%, and the balance of Fe and inevitable impurities.
The preparation method of the steel for the excavator forging bucket teeth comprises the following steps:
(1) Smelting in a converter: the main furnace burden is scrap steel and molten iron, lime and magnesite are added in the smelting process to adjust a slag system, silicomanganese, ferrosilicon and ferrochrome are added to coarsely adjust the components, and aluminum blocks are used for deoxidation after tapping;
(2) LF refining: finishing component adjustment, controlling each element in an internal control range, deoxidizing to remove impurities, feeding an aluminum wire, and deoxidizing the slag surface by using silicon carbide in the whole LF process;
(3) RH vacuum treatment: degassing through vacuum treatment to remove impurities, so as to avoid hydrogen embrittlement;
(4) Continuous casting: the bloom continuous casting machine is adopted for production, the casting is fully protected, the secondary oxidation of molten steel is prevented, and the casting is performed at a low superheat degree;
(5) Heating: the method comprises the following steps of (1) feeding a steel billet into a furnace, fully preheating to ensure that the surface temperature of the steel billet is basically consistent with the core temperature, and then heating to over 1200 ℃;
(6) Rolling and cooling: and (3) removing phosphorus from the casting blank after the casting blank is taken out of the heating furnace by adopting high-pressure water, controlling the initial rolling temperature at 1040-1140 ℃, controlling the rolling by adopting a KOCKS unit in the final rolling, slowly cooling the casting blank by adopting a long and large cooling bed after the rolling, covering a heat preservation cover on the cooling bed, shaking the cooling bed at a constant speed to slowly cool the round steel, improving the flatness of the material and releasing stress.
Further, the hydrogen content in the molten steel after the vacuum treatment in the step (3) is less than or equal to 2ppm.
Further, in the continuous casting process in the step (4), the superheat degree of a first furnace of the tundish is controlled to be less than or equal to 40 ℃, the continuous casting furnace is controlled at 10-30 ℃, and the pulling speed is kept at 0.80-0.90m/min.
Further, the heating temperature in the step (5) is specifically that the preheating section is less than or equal to 950 ℃, the first heating section is 1050-1180 ℃, the second heating section is 1200-1290 ℃, the soaking section is 1200-1270 ℃, and the total heating time is more than or equal to 210min.
Further, the controlled phosphorus removal pressure in the step (6) is more than 18MPa; the finishing temperature is 800-870 ℃.
Has the beneficial effects that: compared with the prior art, the invention has the following remarkable advantages: the steel for forging the bucket teeth of the excavator, disclosed by the invention, does not contain high-cost alloy elements such as Mo, ni, ti and W, has the advantage of low cost, and also has excellent performance, the yield strength is more than or equal to 1500MPa, the tensile strength is more than or equal to 1800MPa, the longitudinal impact absorption power at the temperature of 20 ℃ is more than or equal to 45J, and the hardenability is J1.5:54-56HRC, J8: 50-52HRC, J20:48-50HRC, J30:47-49HRC and rolling hardness of 220-240HB.
Detailed Description
The technical solution of the present invention is further illustrated by the following examples.
The production of 5 heats as examples, respectively 1-5, the preparation method is as follows:
(1) Smelting in a converter
The main furnace charge is scrap steel and molten iron, lime, magnesite and the like are added in the smelting process to adjust a slag system, part of silicomanganese, ferrosilicon and ferrochrome are added to coarsely adjust the components, and aluminum blocks are adopted for deoxidation after tapping.
The specific process parameters are as follows:
Figure BDA0003911570290000021
(2) LF refining
And (3) finishing component adjustment, controlling all elements in an internal control range, deoxidizing to remove impurities, feeding an aluminum wire according to the content of 1 (Alt) of the sample to ensure that the (Alt) is more than or equal to 0.040 percent, deoxidizing the slag surface by using silicon carbide in the whole LF process, and feeding the aluminum wire before feeding RH to ensure that the (Alt) reaches 0.035 percent.
The specific process parameters are as follows:
Figure BDA0003911570290000031
(3) RH vacuum treatment
Degassing and removing impurities through vacuum treatment to ensure that the hydrogen content in the molten steel is less than or equal to 2ppm and avoid hydrogen embrittlement.
The specific process parameters are as follows:
vacuum mbar Standing and stirring for a period of time min Vacuum hold time min Hydrogen determination of ppm Exit temperature/. Degree.C
Example 1 0.38 50 15 1.3 1558
Example 2 0.36 33 15 1.2 1560
Example 3 0.38 51 15 1.5 1555
Example 4 0.38 44 15 1.2 1610
Example 5 0.37 37 15 1.5 1625
(4) Continuous casting
The method adopts a 5-machine 5-flow large square billet continuous casting machine for production, fully protects casting, prevents secondary oxidation of molten steel, performs low superheat degree casting, controls the superheat degree of a first furnace of a tundish to be less than or equal to 40 ℃, controls a continuous casting furnace according to 10-30 ℃, keeps the pulling speed constant at 0.85m/min, adopts 380A/2HZ for crystallizer electromagnetic stirring and 520A/6HZ for tail end electromagnetic stirring parameters, and automatically controls the liquid level to keep the fluctuation of the liquid level of the crystallizer within +/-5 mm, so that the waste is judged when the liquid level exceeds the standard.
(5) Heating is carried out
Because the alloy content of the steel is high, the structure stress and the cooling stress of the continuous casting billet are high, and the heating defect is easy to occur. In the aspect of heating process. The steel billet is first preheated to make the surface temperature of the steel billet basically identical to the core temperature, and then heated to over 1200 deg.c. The production of the steel for the bucket teeth is controlled according to the preheating section of less than or equal to 950 ℃, the first heating section of 1100 ℃, the second heating section of 1220 ℃, the soaking section of 1220 ℃ and the total heating time of more than or equal to 210min.
(6) Rolling of
And removing phosphorus from the casting blank after the casting blank is taken out of the heating furnace by adopting high-pressure water, controlling the phosphorus removal pressure to be more than 18MPa, controlling the initial rolling temperature to be 1040-1140 ℃, controlling the rolling by adopting a KOCKS unit in the final rolling, slowly cooling the casting blank by adopting a long and large cooling bed after the rolling, covering a heat preservation cover on the cooling bed, shaking the cooling bed at a constant speed to slowly cool the round steel, improving the straightness of the material and releasing stress.
The specific process parameters are as follows:
Figure BDA0003911570290000041
test result of finished product
(1) Chemical composition
The chemical components and contents of the steel for forging bucket teeth of the excavator in the embodiments 1 to 5 are as follows (%):
C Si Mn P S Cr Al balance of
Example 1 0.35 1.28 1.16 0.011 0.003 1.28 0.027 Fe and impurities
Example 2 0.34 1.25 1.20 0.013 0.004 1.29 0.029 Fe and impurities
Example 3 0.35 1.30 1.18 0.012 0.003 1.25 0.031 Fe and impurities
Example 4 0.33 1.26 1.15 0.013 0.002 1.26 0.024 Fe and impurities
Example 5 0.35 1.25 1.16 0.014 0.005 1.28 0.028 Fe and impurities
(2) Low power
The rolled stock has the following low power (grade):
generally loose Center porosity Center segregation General point segregation Edge point segregation
Example 1 0 0.5 0 Is free of Is composed of
Example 2 0.5 0 0 Is free of Is composed of
Example 3 0 0.5 0.5 Is free of Is composed of
Example 4 0.5 0.5 0.5 Is free of Is free of
Example 5 0.5 1.0 0.5 Is composed of Is free of
(3) Hardness and mechanical properties of rolled stock
The finish rolling temperature and the slow cooling in the cooling bed heat-insulating cover are controlled, and the internal stress of the rolled material is reduced. After the round steel is processed into a blank with the diameter of 25mm, the mechanical properties are obtained by adopting the processes of quenching at 930 +/-15 ℃ and water cooling at 230 +/-10 ℃ and tempering.
Hot rolled hardness HB Tensile strength Rm/MPa Yield strength Rm/MPa Impact energy AKU2/J
Example 1 225 1948 1541 45
Example 2 231 1834 1536 46
Example 3 221 1897 1533 48
Example 4 234 1941 1545 51
Example 5 231 1945 1538 46
(4) Non-metallic inclusions
The non-metallic inclusions were as follows (grade):
a is thin A is coarse B is thin B coarse C fine Coarse fraction of C D is thin D coarse
Example 1 0.5 0.5 0 0 0 0 0 0.5
Example 2 0.5 0 0 0 0 0 0.5 0.5
Example 3 0 0.5 0 0 0 0 0.5 0
Example 4 0 0.5 0 0 0 0 0.5 0.5
Example 5 1.0 0.5 0 0 0 0 0.5 0.5
(5) Hardenability
Hardenability data are as follows (HRC):
J1.5 J8 J15 J20 J30
example 1 55 54 51 50 48
Example 2 55 54 51 50 48
Example 3 56 55 51 51 49
Example 4 54 54 51 50 48
Example 5 55 54 51 50 48
The steel for the bucket teeth produced by the process has the advantages that a user can realize cold shearing and blanking, the production efficiency of the user is improved, the hardness of a bucket tooth product after heat treatment is uniform, the product performance is stable, the wear resistance is good, and the cost advantage is very high.

Claims (7)

1. The steel for the excavator forging bucket tooth is characterized by comprising the following chemical components in percentage by mass: c:0.30-0.37%, si:1.25-1.55%, mn:1.00-1.30%, P: less than or equal to 0.035%, S: less than or equal to 0.035%, cr:1.20-1.50%, al:0.020-0.050%, and the balance of Fe and inevitable impurities.
2. A method of producing the steel for the tooth of the excavator forging bucket according to claim 1, comprising the steps of:
(1) Smelting in a converter: the main furnace burden is scrap steel and molten iron, lime and magnesite are added in the smelting process to adjust a slag system, silicomanganese, ferrosilicon and ferrochrome are added to coarsely adjust the components, and aluminum blocks are used for deoxidation after tapping;
(2) LF refining: finishing component adjustment, controlling each element in an internal control range, deoxidizing to remove impurities, feeding an aluminum wire, and deoxidizing the slag surface by using silicon carbide in the whole LF process;
(3) RH vacuum treatment: degassing through vacuum treatment to remove impurities, so as to avoid hydrogen embrittlement;
(4) Continuous casting: the bloom continuous casting machine is adopted for production, the casting is fully protected, the secondary oxidation of molten steel is prevented, and the casting with low superheat degree is realized;
(5) Heating: the method comprises the following steps of (1) feeding a steel billet into a furnace, fully preheating to ensure that the surface temperature of the steel billet is basically consistent with the core temperature, and then heating to over 1200 ℃;
(6) Rolling and cooling: and (3) removing phosphorus from the casting blank after the casting blank is taken out of the heating furnace by adopting high-pressure water, controlling the initial rolling temperature at 1040-1140 ℃, controlling the rolling of the final rolling by adopting a KOCKS unit, slowly cooling the casting blank by adopting a long and large cooling bed after the rolling, covering a heat preservation cover on the cooling bed, shaking the cooling bed at a constant speed to slowly cool the round steel, improving the flatness of the material and releasing stress.
3. The method for preparing steel for the excavator forging teeth as recited in claim 2, wherein the hydrogen content in the molten steel after the vacuum treatment in the step (3) is not more than 2ppm.
4. The method for preparing the steel for the excavator forging teeth as claimed in claim 2, wherein in the step (4), the superheat degree of a first furnace of the tundish is controlled to be less than or equal to 40 ℃, the continuous casting furnace is controlled at 10-30 ℃, and the pulling speed is kept at 0.80-0.90m/min.
5. The method for preparing the steel for the forging bucket tooth of the excavator according to claim 2, wherein the heating temperature in the step (5) is specifically equal to or less than 950 ℃ in a preheating section, 1050-1180 ℃ in a first heating section, 1200-1290 ℃ in a second heating section, 1200-1270 ℃ in a soaking section, and the total heating time is equal to or more than 210min.
6. The method for preparing the steel for the excavator forging teeth, which is used according to claim 2, is characterized in that the phosphorus removal pressure in the step (6) is controlled to be more than 18MPa.
7. The method for producing a steel for use in forging teeth for excavators according to claim 2, wherein the finish rolling temperature in the step (6) is 800 to 870 ℃.
CN202211323712.8A 2022-10-27 2022-10-27 Steel for excavator forging bucket teeth and preparation method thereof Pending CN115627427A (en)

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PCT/CN2023/111209 WO2024087788A1 (en) 2022-10-27 2023-08-04 Steel for forged bucket teeth of excavator, and preparation method therefor

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WO2024087788A1 (en) * 2022-10-27 2024-05-02 南京钢铁股份有限公司 Steel for forged bucket teeth of excavator, and preparation method therefor

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