CN115595476A - High-thermal-conductivity aluminum alloy for 5G communication equipment and preparation method thereof - Google Patents

High-thermal-conductivity aluminum alloy for 5G communication equipment and preparation method thereof Download PDF

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CN115595476A
CN115595476A CN202211327075.1A CN202211327075A CN115595476A CN 115595476 A CN115595476 A CN 115595476A CN 202211327075 A CN202211327075 A CN 202211327075A CN 115595476 A CN115595476 A CN 115595476A
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CN115595476B (en
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廖光明
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JIANGXI WANTAI ALUMINUM CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D7/00Casting ingots, e.g. from ferrous metals
    • B22D7/005Casting ingots, e.g. from ferrous metals from non-ferrous metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
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Abstract

A high heat conduction aluminum alloy for 5G communication equipment and a preparation method thereof belong to the technical field of aluminum alloy production, and the aluminum alloy comprises the following components in percentage by weight: 3.0 to 5.0 percent of Si; fe:0.5% -0.7%; zn:0.1% -0.2%; sr:0.025-0.035%; b:0.01 to 0.015 percent; total amount of La and Ce: 0.2 to 0.3 percent; less than or equal to 0.01 percent of other impurities, and the balance of aluminum. The preparation method comprises the following steps: preparing materials, heating and melting, controlling temperature and melting, slagging off and refining, melting and stirring, degassing in a furnace, detecting the content of hydrogen and slag, casting and carrying out two-stage artificial aging. The sampling test proves that the aluminum alloy material provided by the invention has good heat-conducting property.

Description

High-thermal-conductivity aluminum alloy for 5G communication equipment and preparation method thereof
Technical Field
The invention belongs to the technical field of aluminum alloy production, and particularly relates to a high-thermal-conductivity aluminum alloy for 5G communication equipment and a preparation method thereof.
Background
With the progress and rapid development of modern electronic information and manufacturing technology, especially the rapid development of 5G communication products, higher requirements are put forward on the heat dissipation performance of materials, the heat dissipation problem of aluminum alloy structural parts becomes the bottleneck of the development of communication technology, the aluminum alloy materials in the prior art cannot meet the technical application requirements, and a high-heat-conductivity material is urgently needed. The Al-Si alloy has excellent casting performance and heat and electric conductivity. The invention provides a novel Al-Si series die-casting aluminum alloy material which has excellent electric and heat conducting properties through optimization of a material formula and a production process, and has wide market prospects and technical advantages in industries with high requirements on the heat conducting properties of materials, such as the field of new-generation communication technologies.
Disclosure of Invention
The invention provides a high-thermal-conductivity aluminum alloy for 5G communication equipment and a preparation method thereof, which are used for solving the problems in the background art.
The technical problem solved by the invention is realized by adopting the following technical scheme:
a high-thermal-conductivity aluminum alloy for 5G communication equipment comprises the following components in percentage by weight: 3.0 to 5.0 percent of Si; fe:0.5% -0.7%; zn:0.1% -0.2%; sr:0.025-0.035%; b:0.01 to 0.015 percent; total amount of La and Ce: 0.2% -0.3%; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
The preparation method comprises the following steps:
(1) Preparing raw materials according to the proportion for later use;
(2) Heating and melting: firstly, putting an aluminum ingot for remelting into a furnace, heating and smelting, smelting and stirring an aluminum melt, and keeping the temperature for 35-40min;
(3) Controlling temperature and smelting: adding industrial Si, metallic Fe, pure Zn and other raw materials for smelting, and fully stirring a high-temperature melt;
(4) Slagging-off and refining: slagging off ash in the high-temperature aluminum melt, uniformly stirring, performing powder spraying refining twice by adopting a refining agent and high-purity argon dispersion non-chain refining process, slagging off after each refining is finished, and removing scum on the aluminum melt;
(5) Melting and stirring: adding Al-B, al-Sr alloy and La/Ce misch metal, fully stirring aluminum melt, and sampling to analyze chemical components;
(6) Degassing in a furnace: degassing by adopting a high-purity argon dispersion non-chain degassing process, and standing for 25-35min after degassing;
(7) Detecting hydrogen content and slag content: detecting the hydrogen content and the slag content of the aluminum melt by using a decompression solidification device and a K die;
(8) Casting: casting the qualified aluminum melt, performing online degassing and double-layer ceramic filtration in a runner, and automatically stacking ingots after the aluminum alloy is formed;
(9) Two-stage artificial aging: the aluminum alloy artificial aging process is 175 +/-5 ℃, the aging time is 30min, the aluminum alloy is naturally cooled to the normal temperature, then the secondary artificial aging is carried out, the aging process is 150 +/-5 ℃, and the aging time is 30min.
The beneficial effects of the invention are:
according to the invention, by optimizing the proportion of the chemical components of the aluminum alloy, the novel aluminum alloy material with good thermal conductivity is obtained, and the novel aluminum alloy material is particularly suitable for application of structural members with high requirements on thermal conductivity in new technologies such as 5G communication and the like.
Detailed Description
In order to facilitate an understanding of the present invention, a more complete description of the present invention is provided below. The present invention may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Example 1
A high-thermal-conductivity aluminum alloy for 5G communication equipment comprises the following components in percentage by weight: 3.5 percent of Si; fe:0.55 percent; zn:0.15 percent; sr:0.03 percent; b:0.012%; total amount of La and Ce: 0.25 percent; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
The preparation method comprises the following steps:
(1) Preparing raw materials according to the proportion for later use;
(2) Heating and melting: firstly, feeding remelting aluminum ingots into a furnace, heating and smelting, controlling the smelting temperature of an aluminum melt to be 880-890 ℃, stirring the high-temperature aluminum melt for 5-6 minutes, and keeping the temperature for 35-40min;
(3) Controlling temperature and smelting: adding raw materials such as industrial Si, metal Fe, pure Zn and the like for smelting, controlling the smelting temperature of an aluminum melt to be 730-740 ℃, and fully stirring the high-temperature melt;
(4) Slagging-off and refining: slagging off ash in the high-temperature aluminum melt, controlling the temperature of the high-temperature aluminum melt at 730-740 ℃, uniformly stirring, performing powder injection refining twice by adopting a refining agent and high-purity argon dispersion non-chain refining process, refining by using a refining pipe which is 50 porous refining with the inner diameter phi of 5mm, wherein the refining time is 20-30min each time, the injection amount of the refining agent is controlled at 1Kg/min, the pressure is 0.25-0.35MPa, slagging off is performed after each refining is finished, and scum on the aluminum melt is removed;
(5) Melting and stirring: adding Al-B, al-Sr alloy and La/Ce mischmetal, fully stirring aluminum melt, and sampling and analyzing chemical components;
(6) Degassing in a furnace: controlling the temperature of the aluminum melt at 700-720 ℃, degassing by adopting a high-purity argon dispersion non-chain degassing process, wherein a degassing pipe is used for degassing 50 porous pipes with the inner diameter phi of 5mm, the degassing time is 30-40min, the pressure is 0.20-0.45MPa, and standing for 25-35min after degassing;
(7) Detecting hydrogen content and slag content: detecting the hydrogen content and the slag content of the aluminum melt by using a decompression solidification device and a K die, so that the hydrogen content is less than 0.2cc/100gAl, and the slag content is less than or equal to 1/20;
(8) Casting: casting the qualified aluminum melt at the casting temperature of 690-710 ℃, performing online degassing and double-layer ceramic filtration in a runner, and performing automatic ingot stacking after the aluminum alloy is formed;
(9) Two-stage artificial aging: the aluminum alloy artificial aging process is 175 +/-5 ℃, the aging time is 30min, the aluminum alloy is naturally cooled to the normal temperature, and then the second artificial aging process is carried out, wherein the aging process is 150 +/-5 ℃, and the aging time is 30min.
The aluminum alloy produced in the example was sampled and tested for thermal conductivity, and the thermal conductivity was tested according to ASTM E1461-13, ASTM E1269-11 (Reapproved 2018) and GB/T1423-1996 standards. The sample ratio is as follows (chemical composition/%):
Figure DEST_PATH_IMAGE002
the measured thermal conductivity is as follows:
Figure DEST_PATH_IMAGE004
example 2
A high-thermal-conductivity aluminum alloy for 5G communication equipment comprises the following components in percentage by weight: 4.5 percent of Si; fe:0.65 percent; zn:0.15 percent; sr:0.03 percent; b:0.012%; total amount of La and Ce: 0.25 percent; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
The preparation method comprises the following steps:
(1) Preparing raw materials according to the proportion for later use;
(2) Heating and melting: firstly, putting an aluminum ingot for remelting into a furnace, heating and smelting, controlling the smelting temperature of an aluminum melt to be 880-890 ℃, stirring the high-temperature aluminum melt for 5-6 minutes, and keeping the temperature for 35-40 minutes;
(3) Controlling temperature and smelting: adding raw materials such as industrial silicon Si, metal Fe, pure Zn and the like for smelting, controlling the smelting temperature of an aluminum melt to be 730-740 ℃, and fully stirring the high-temperature melt;
(4) Slagging-off and refining: slagging off ash in the high-temperature aluminum melt, controlling the temperature of the high-temperature aluminum melt at 730-740 ℃, uniformly stirring, performing powder injection refining twice by adopting a refining agent and high-purity argon dispersion non-chain refining process, refining by using a refining pipe which is 50 porous refining with the inner diameter phi of 5mm, wherein the refining time is 20-30min each time, the injection amount of the refining agent is controlled at 1Kg/min, the pressure is 0.25-0.35MPa, slagging off is performed after each refining is finished, and scum on the aluminum melt is removed;
(5) Melting and stirring: adding Al-B, al-Sr alloy and La/Ce misch metal, fully stirring aluminum melt, and sampling to analyze chemical components;
(6) Degassing in a furnace: controlling the temperature of the aluminum melt at 700-720 ℃, degassing by adopting a high-purity argon dispersion non-chain degassing process, wherein a degassing pipe is used for degassing 50 porous pipes with the inner diameter phi of 5mm, the degassing time is 30-40min, the pressure is 0.20-0.45MPa, and standing for 25-35min after degassing;
(7) Detecting hydrogen content and slag content: detecting the hydrogen content and the slag content of the aluminum melt by using a decompression solidification device and a K die, so that the hydrogen content is less than 0.2cc/100gAl, and the slag content is less than or equal to 1/20;
(8) Casting: casting the qualified aluminum melt at the casting temperature of 690-710 ℃, performing online degassing and double-layer ceramic filtration in a runner, and performing automatic ingot stacking after the aluminum alloy is formed;
(9) Two-stage artificial aging: the aluminum alloy artificial aging process is 175 +/-5 ℃, the aging time is 30min, the aluminum alloy is naturally cooled to the normal temperature, and then the second artificial aging process is carried out, wherein the aging process is 150 +/-5 ℃, and the aging time is 30min.
The aluminum alloy produced in the example was sampled and tested for thermal conductivity, and the thermal conductivity was tested according to ASTM E1461-13, ASTM E1269-11 (Reapproved 2018) and GB/T1423-1996 standards. The sample proportion is as follows:
the sample ratio is as follows (chemical composition/%):
test piece number Si Fe Zn Sr B Total amount of La and Ce Other impurities singles (maximum)
1 4.56 0.653 0.149 0.031 0.012 0.247 0.0068
2 4.59 0.656 0.151 0.031 0.012 0.245 0.0069
3 4.42 0.652 0.148 0.030 0.012 0.250 0.0067
4 4.45 0.642 0.149 0.030 0.011 0.250 0.0066
5 4.56 0.657 0.150 0.029 0.011 0.249 0.0065
The measured thermal conductivity is as follows:
test piece number Thermal conductivity (W/(m.K))
1 203.1
2 204.5
3 205.3
4 206.4
5 204.7
The embodiment of the invention mainly illustrates the high-thermal-conductivity aluminum alloy for the 5G communication equipment and the preparation method thereof. While only a limited number of embodiments and features have been described, it will be appreciated by those skilled in the art that the invention may be embodied in many other forms without departing from the spirit or scope thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, and various modifications and alternative arrangements may be devised without departing from the spirit and scope of the present invention as defined by the appended claims.

Claims (4)

1. The high-thermal-conductivity aluminum alloy for the 5G communication equipment is characterized in that the aluminum alloy comprises the following components in percentage by weight: 3.0 to 5.0 percent of Si; fe:0.5% -0.7%; zn:0.1 to 0.2 percent; sr:0.025-0.035%; b:0.01-0.015%; total amount of La and Ce: 0.2% -0.3%; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
2. The high-thermal-conductivity aluminum alloy for 5G communication equipment as claimed in claim 1, wherein the aluminum alloy comprises the following components in percentage by weight: 3.5 percent of Si; fe:0.55 percent; zn:0.15 percent; sr:0.03 percent; b:0.012%; total amount of La and Ce: 0.25 percent; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
3. The high-thermal-conductivity aluminum alloy for 5G communication equipment as claimed in claim 1, wherein the aluminum alloy comprises the following components in percentage by weight: 4.5 percent of Si; fe:0.65 percent; zn:0.15 percent; sr:0.03 percent; b:0.012%; total amount of La and Ce: 0.25 percent; less than or equal to 0.01 percent of other impurities, and the balance of aluminum.
4. The preparation method of the high-thermal-conductivity aluminum alloy for 5G communication equipment, according to claim 1, is characterized by comprising the following steps:
(1) Preparing raw materials according to a ratio for later use;
(2) Heating and melting: firstly, feeding remelting aluminum ingots into a furnace, heating and smelting, controlling the smelting temperature of an aluminum melt to be 880-890 ℃, stirring the high-temperature aluminum melt for 5-6 minutes, and keeping the temperature for 35-40min;
(3) Temperature-controlled smelting: adding raw materials such as industrial Si, metallic Fe, pure Zn and the like to smelt, controlling the smelting temperature of an aluminum melt to be 730-740 ℃, and fully stirring the high-temperature melt;
(4) Slagging-off and refining: slagging off ash in the high-temperature aluminum melt, controlling the temperature of the high-temperature aluminum melt at 730-740 ℃, uniformly stirring, performing powder injection refining twice by adopting a refining agent and high-purity argon dispersion non-chain refining process, refining by using a refining pipe which is 50 porous refining with the inner diameter phi of 5mm, wherein the refining time is 20-30min each time, the injection amount of the refining agent is controlled at 1Kg/min, the pressure is 0.25-0.35MPa, slagging off is performed after each refining is finished, and scum on the aluminum melt is removed;
(5) Melting and stirring: adding Al-B, al-Sr alloy and La/Ce misch metal, fully stirring aluminum melt, and sampling to analyze chemical components;
(6) Degassing in a furnace: controlling the temperature of the aluminum melt at 700-720 ℃, degassing by adopting a high-purity argon dispersion non-chain degassing process, wherein a degassing pipe is used for degassing 50 porous pipes with the inner diameter phi of 5mm, the degassing time is 30-40min, the pressure is 0.20-0.45MPa, and standing for 25-35min after degassing;
(7) Detecting hydrogen content and slag content: detecting the hydrogen content and the slag content of the aluminum melt by using a decompression solidification device and a K die, so that the hydrogen content is less than 0.2cc/100gAl, and the slag content is less than or equal to 1/20;
(8) Casting: casting the qualified aluminum melt at the casting temperature of 690-710 ℃, performing online degassing and double-layer ceramic filtration in a runner, and performing automatic ingot stacking after the aluminum alloy is formed;
(9) Two-stage artificial aging: the aluminum alloy artificial aging process is 175 +/-5 ℃, the aging time is 30min, the aluminum alloy is naturally cooled to the normal temperature, and then the second artificial aging process is carried out, wherein the aging process is 150 +/-5 ℃, and the aging time is 30min.
CN202211327075.1A 2022-10-27 2022-10-27 High heat conduction aluminum alloy for 5G communication equipment and preparation method thereof Active CN115595476B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106435294A (en) * 2016-09-24 2017-02-22 清远市顺博铝合金有限公司 Low-cost high-thermal-conductivity aluminum alloy and preparation method thereof
CN110964936A (en) * 2019-12-16 2020-04-07 安徽峰创云通数据科技有限公司 Production process of high-strength corrosion-resistant aluminum alloy for power line hardware
CN111560574A (en) * 2020-06-04 2020-08-21 福建祥鑫股份有限公司 Heat treatment process of high-thermal-conductivity aluminum alloy
CN111636018A (en) * 2020-06-04 2020-09-08 福建祥鑫股份有限公司 High-thermal-conductivity aluminum alloy and casting method thereof
CN113293327A (en) * 2021-05-26 2021-08-24 重庆慧鼎华创信息科技有限公司 High-thermal-conductivity die-casting aluminum alloy and preparation method thereof
US20210292874A1 (en) * 2018-08-24 2021-09-23 Samsung Electronics Co., Ltd. Aluminium alloy for die casting, method for manufacturing same, and die casting method
CN113481395A (en) * 2021-06-28 2021-10-08 华南理工大学 Composite treatment method for improving thermal conductivity of cast Al-Si alloy

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106435294A (en) * 2016-09-24 2017-02-22 清远市顺博铝合金有限公司 Low-cost high-thermal-conductivity aluminum alloy and preparation method thereof
US20210292874A1 (en) * 2018-08-24 2021-09-23 Samsung Electronics Co., Ltd. Aluminium alloy for die casting, method for manufacturing same, and die casting method
CN110964936A (en) * 2019-12-16 2020-04-07 安徽峰创云通数据科技有限公司 Production process of high-strength corrosion-resistant aluminum alloy for power line hardware
CN111560574A (en) * 2020-06-04 2020-08-21 福建祥鑫股份有限公司 Heat treatment process of high-thermal-conductivity aluminum alloy
CN111636018A (en) * 2020-06-04 2020-09-08 福建祥鑫股份有限公司 High-thermal-conductivity aluminum alloy and casting method thereof
CN113293327A (en) * 2021-05-26 2021-08-24 重庆慧鼎华创信息科技有限公司 High-thermal-conductivity die-casting aluminum alloy and preparation method thereof
CN113481395A (en) * 2021-06-28 2021-10-08 华南理工大学 Composite treatment method for improving thermal conductivity of cast Al-Si alloy

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