CN115594871A - Preparation method of full-biodegradable wood-plastic composite light high-strength material - Google Patents
Preparation method of full-biodegradable wood-plastic composite light high-strength material Download PDFInfo
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- CN115594871A CN115594871A CN202211275272.3A CN202211275272A CN115594871A CN 115594871 A CN115594871 A CN 115594871A CN 202211275272 A CN202211275272 A CN 202211275272A CN 115594871 A CN115594871 A CN 115594871A
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- 239000000463 material Substances 0.000 title claims abstract description 40
- 229920001587 Wood-plastic composite Polymers 0.000 title claims abstract description 34
- 239000011155 wood-plastic composite Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 51
- 239000002028 Biomass Substances 0.000 claims abstract description 36
- 239000002023 wood Substances 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 239000002699 waste material Substances 0.000 claims abstract description 22
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- 238000000034 method Methods 0.000 claims abstract description 14
- 239000003960 organic solvent Substances 0.000 claims abstract description 14
- 238000000748 compression moulding Methods 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- 239000010902 straw Substances 0.000 claims description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 7
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- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 7
- 240000008042 Zea mays Species 0.000 claims description 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 7
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 7
- 235000005822 corn Nutrition 0.000 claims description 7
- 241000609240 Ambelania acida Species 0.000 claims description 6
- 239000010905 bagasse Substances 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 238000000643 oven drying Methods 0.000 claims description 6
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 6
- 239000004626 polylactic acid Substances 0.000 claims description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2301/08—Cellulose derivatives
- C08J2301/10—Esters of organic acids
- C08J2301/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2397/00—Characterised by the use of lignin-containing materials
- C08J2397/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2497/00—Characterised by the use of lignin-containing materials
- C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
Abstract
The invention discloses a preparation method of a full-biodegradable wood-plastic composite light high-strength material, which comprises the following steps: (1) Extracting the waste wood biomass powder by using absolute ethyl alcohol for dewaxing pretreatment, and drying for later use; (2) Fully infiltrating an organic solvent and the waste wood biomass powder after pretreatment and drying, adding a biomass-based high polymer material, and stirring until the mixture is fully and uniformly mixed to obtain a mixture; (3) And (3) carrying out compression molding on the mixture, demolding and drying to obtain the fully biodegradable wood-plastic composite light high-strength material. The invention has simple process, low energy consumption, complete degradation, no pollution to the environment, excellent product performance, tensile strength of 10-26MPa and bending strength of 150-300MPa.
Description
Technical Field
The invention belongs to the technical field of wood-plastic composite materials, and particularly relates to a preparation method of a full-biodegradable wood-plastic composite light high-strength plate.
Background
With the increase of population and the rapid development of economy, people have more and more demand on wood and have higher and higher requirements on wood quality. Excessive tree felling and waste of leftover materials aggravate ecological environment damage and resource waste. Wood-plastic composites (WPC) are novel composite materials which are flourishing in recent years at home and abroad, and are green, environment-friendly and environment-friendly novel materials which are produced by using biomass fillers (including Wood flour, rice hulls, bamboo powder, straws and the like) and thermoplastic plastics (including polyethylene, polypropylene, polyvinyl chloride and the like) as main raw materials through processing technologies such as extrusion, mould pressing, injection molding and the like. The wood-plastic composite material can effectively relieve the contradiction between the shortage of wood supply and the increasing social demand, has very important significance for solving the problems of low comprehensive utilization rate of waste biomass materials, ecological environment damage caused by excessive felling and the like, and becomes one of the research hotspots in the field of wood and plastic processing application at present.
The wood-plastic composite material is based on thermoplastic polymers and biomass fillers, has the characteristics of good processing performance, strength performance, adjustability and the like, and is mainly used in industries of building materials, furniture, logistics packaging and the like. However, the wood-plastic composite material is generally prepared by heating, melting and mixing the polymer and the biomass filler and then molding, on one hand, melting and plasticizing need to consume more energy, and on the other hand, the prepared wood-plastic composite material still contains plastic which cannot be biodegraded, and still causes environmental pollution. Therefore, the fully biodegradable wood-plastic composite light high-strength material with excellent performance and strength is obtained by a method with simple research process, energy conservation and environmental friendliness, and has long-term significance for improving the growing environmental problems and improving the supply and demand tension relation of material industry application.
Disclosure of Invention
In order to overcome the defects of the prior art and better solve the problems of low comprehensive utilization rate of waste biomass materials, high energy consumption in the preparation process of the traditional wood-plastic composite, complex process route and incomplete degradation of the wood-plastic composite, the invention provides the preparation method of the fully biodegradable wood-plastic composite light high-strength material, which has the advantages of simple process, energy conservation, environmental friendliness and excellent performance.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
a preparation method of a full-biodegradable wood-plastic composite light high-strength material comprises the following steps:
(1) Extracting the waste wood biomass powder by absolute ethyl alcohol for dewaxing pretreatment, and drying for later use;
(2) Fully infiltrating an organic solvent and the waste wood biomass powder after pretreatment and drying, adding a biomass-based high polymer material, and stirring until the mixture is fully and uniformly mixed to obtain a mixture;
(3) And (3) carrying out compression molding on the mixture, demolding and drying to obtain the fully biodegradable wood-plastic composite light high-strength material.
Further, in the step (1), the waste woody biomass is selected from any one or a combination of two or more of corn stalks, straws, bamboos, reeds, bagasse and wood powder, and the particle size of the powder is less than 60 meshes.
Further, in the step (2), the waste woody biomass powder, the organic solvent and the biomass-based polymer material are calculated according to the following parts by mass:
10 parts by mass of waste wood biomass powder;
15-30 parts by mass of an organic solvent;
8-15 parts of biomass-based high polymer material.
Further, in the step (2), the organic solvent is at least one selected from tetrahydrofuran, chloroform and acetone.
Further, in the step (2), the biomass-based polymer material is at least one selected from polylactic acid and cellulose acetate, and the particle size is less than 150 μm.
Further, in the step (3), the compression molding conditions are as follows: the pressure is 10-20MPa, and the holding time is 60-90s.
Further, in the step (3), the drying process is as follows: drying in the air at 20-40 deg.C and air relative humidity less than 60% for 4-8 hr, and oven drying at 80-100 deg.C for 4-8 hr.
According to the invention, the waste wood biomass powder is fully infiltrated by the organic solvent, and in the process of contacting with the biodegradable biomass-based high polymer material, the molecular chain of the high polymer material is induced to diffuse to the surface and pore structure of the waste wood biomass powder, so that the interface acting force of the waste wood biomass powder and the high polymer material is effectively increased, and the dispersed waste wood biomass powder is further connected by the high polymer material, thereby realizing the preparation of the fully biodegradable wood-plastic composite light high-strength material.
The invention has the following advantages and effects:
(1) Compared with the traditional hot-melting hot-pressing method technical route of firstly melting and compounding, and then adopting the molding processing modes of hot pressing, extrusion, injection and the like, the method only simply stirs and mixes the waste wood biomass powder and the biomass-based high polymer material under the action of the organic solvent, and then molds and dries to obtain the fully biodegradable wood-plastic composite light high-strength material, and has the advantages of simple process, low energy consumption, excellent product performance, 10-26MPa of tensile strength of the product and 150-300MPa of bending strength.
(2) The biomass-based polymer material and the waste wood biomass powder which are used as raw materials are both derived from biomass, so that the biodegradable wood-plastic composite material has the advantage of biodegradability, and compared with the wood-plastic material prepared by compounding traditional petroleum-based plastics and wood powder, the fully biodegradable wood-plastic composite light-weight high-strength material prepared by the method can be completely degraded without causing pollution to the environment.
Drawings
FIG. 1 is a physical diagram and an SEM diagram of the fully biodegradable wood-plastic composite light high-strength material prepared in example 1;
FIG. 2 is a physical diagram and an SEM diagram of the fully biodegradable wood-plastic composite light high-strength material prepared in example 2;
FIG. 3 is a physical diagram and an SEM diagram of the fully biodegradable wood-plastic composite lightweight high-strength material prepared in example 3;
FIG. 4 is a physical diagram and an SEM diagram of the fully biodegradable wood-plastic composite lightweight high-strength material prepared in example 4;
fig. 5 is a physical diagram and an SEM diagram of the fully biodegradable wood-plastic composite lightweight high-strength material prepared in example 5.
Detailed Description
The present invention will be described in further detail with reference to examples, but the embodiments of the present invention are not limited thereto.
Example 1
Cleaning and drying corn straws by using distilled water, crushing the corn straws into powder, sieving the powder by using a 60-mesh sieve, adding the powder into a reaction container, extracting the powder by using absolute ethyl alcohol for 6 hours, dewaxing the powder, and drying the powder in an oven at the temperature of 105 ℃, wherein the powder is marked as corn straw powder; soaking 15 parts by mass of organic solvent acetone and 10 parts by mass of corn straw powder; adding 8 parts by mass of polylactic acid into the soaked corn straw powder, and stirring the mixture in a stirrer in a closed environment until the mixture is uniform; transferring the obtained mixture into a mold, and carrying out compression molding at normal temperature; and (3) demolding the molded wet material, ventilating and drying for 4 hours under the conditions that the temperature is 20 ℃ and the relative humidity is 60%, and then transferring to an oven to dry for 8 hours at the temperature of 80 ℃ to obtain the fully biodegradable wood-plastic composite light high-strength material. The prepared plate has the tensile strength of 10.2MPa and the bending strength of 150.3MPa.
Example 2
Washing bagasse with distilled water, drying, pulverizing into powder, sieving with 100 mesh sieve, adding into a reaction container, extracting with anhydrous ethanol for 6 hr to dewax the powder, and oven drying at 105 deg.C in oven to obtain bagasse powder; soaking 18 parts by mass of organic solvent trichloromethane and 10 parts by mass of bagasse powder; adding 10 parts by mass of polylactic acid into the soaked bagasse powder, and stirring the mixture in a stirrer in a closed environment until the mixture is uniform; transferring the obtained mixture into a mold, and carrying out compression molding at normal temperature; and (3) demolding the formed wet wood, ventilating and shade-drying for 6 hours under the conditions that the temperature is 20 ℃ and the relative humidity is 50%, and then transferring to an oven to dry for 6 hours at 80 ℃ to obtain the fully biodegradable wood-plastic composite light high-strength material. The prepared plate has the tensile strength of 14.5MPa and the bending strength of 196.3MPa.
Example 3
Washing bamboo chips with distilled water, drying, pulverizing into powder, sieving with 120 mesh sieve, adding into a reaction vessel, extracting with anhydrous ethanol for 6 hr to dewax the powder, oven drying at 105 deg.C, and labeling as bamboo powder; soaking 20 parts by mass of organic solvent tetrahydrofuran and 10 parts by mass of bamboo powder; then adding 10 parts by mass of cellulose acetate into the soaked bamboo powder, and stirring the mixture in a stirrer in a closed environment until the mixture is uniform; transferring the obtained mixture into a mold, and carrying out compression molding at normal temperature; and (3) demolding the formed wet wood, ventilating and shade-drying for 4 hours under the conditions that the temperature is 30 ℃ and the relative humidity is 60%, and then transferring to an oven to dry for 8 hours at the temperature of 80 ℃ to obtain the fully biodegradable wood-plastic composite light high-strength material. The prepared plate has the tensile strength of 17.8MPa and the bending strength of 227.0MPa.
Example 4
Washing pine wood chips with distilled water, drying, pulverizing into powder, sieving with 160 mesh sieve, adding into a reaction container, extracting with anhydrous ethanol for 6 hr to dewax the powder, and oven drying at 105 deg.C in oven to obtain pine wood powder; soaking 20 parts by mass of acetone and 10 parts by mass of pine powder; then adding 10 parts by mass of polylactic acid into the soaked pine wood powder, and stirring the mixture in a stirrer in a closed environment until the mixture is uniform; transferring the obtained mixture into a mold, and carrying out compression molding at normal temperature; and (3) demolding the molded wet material, ventilating and drying for 8 hours under the conditions that the temperature is 20 ℃ and the relative humidity is 50%, and then transferring to an oven to dry for 4 hours at 100 ℃ to obtain the fully biodegradable wood-plastic composite light high-strength material. The prepared plate has the tensile strength of 21.6MPa and the bending strength of 265.7MPa.
Example 5
Washing pine wood chips with distilled water, drying, pulverizing into powder, sieving with 200 mesh sieve, adding into a reaction container, extracting with anhydrous ethanol for 6 hr to dewax the powder, and oven drying at 105 deg.C in oven to obtain pine wood powder; soaking 30 parts by mass of tetrahydrofuran and 10 parts by mass of pine wood powder; adding 15 parts by mass of polylactic acid into the soaked pine wood powder, and stirring the mixture in a stirrer in a closed environment until the mixture is uniform; transferring the obtained mixture into a mold, and carrying out compression molding at normal temperature; and (3) demolding the molded wet material, ventilating and drying for 4 hours under the conditions that the temperature is 40 ℃ and the relative humidity is 30%, and then transferring to an oven for drying for 4 hours at 100 ℃ to obtain the fully biodegradable wood-plastic composite light high-strength material. The prepared plate has the tensile strength of 25.4MPa and the bending strength of 298.8MPa.
The films prepared in examples 1 to 5 were subjected to electron microscope scanning using a Zeiss Sigma 300 instrument and mechanical property testing as follows:
bending strength: the flexural strength and flexural modulus of the material were tested by an electronic universal mechanical tester in accordance with ASTM D790 (Standard test method for flexural Properties of unreinforced and reinforced plastics and Electrical insulation materials). A sample of 50X 12.7X 1.5mm was prepared, spanning 25.4mm, at a speed of 2mm/min.
Tensile strength: according to ASTM D638 (test method for tensile Properties of plastics), a dumbbell type specimen was prepared by testing the tensile strength, tensile modulus and elongation at break of the material by an electronic universal mechanical tester, with the selection of type IV, total length 115mm, total width at both ends 19mm, width of the middle narrow portion 6mm, length of the narrow portion 33mm, thickness 3.0mm, gauge length 25mm, and tensile speed 5mm/min.
The mechanical properties test results are shown in table 1.
TABLE 1
Claims (7)
1. A preparation method of a full-biodegradable wood-plastic composite light high-strength material is characterized by comprising the following steps:
(1) Extracting the waste wood biomass powder by absolute ethyl alcohol for dewaxing pretreatment, and drying for later use;
(2) Fully infiltrating an organic solvent and the waste wood biomass powder after pretreatment and drying, adding a biomass-based high polymer material, and stirring until the mixture is fully and uniformly mixed to obtain a mixture;
(3) And (3) compression molding the mixture, demolding and drying to obtain the fully biodegradable wood-plastic composite light high-strength material.
2. The method according to claim 1, wherein in the step (1), the waste woody biomass is selected from any one or a combination of two or more of corn stover, straw, bamboo, reed, bagasse and wood flour, and the particle size of the powder is less than 60 mesh.
3. The preparation method according to claim 1, wherein in the step (2), the waste woody biomass powder, the organic solvent and the biomass-based polymer material are, in parts by mass:
10 parts by mass of waste wood biomass powder;
15-30 parts of an organic solvent;
8-15 parts of biomass-based high polymer material.
4. The method according to claim 1, wherein in the step (2), the organic solvent is at least one selected from the group consisting of tetrahydrofuran, chloroform, and acetone.
5. The method according to claim 1, wherein in the step (2), the biomass-based polymer material is at least one selected from polylactic acid and cellulose acetate, and has a particle size of less than 150 μm.
6. The production method according to claim 1, wherein in the step (3), the press molding conditions are: the pressure is 10-20MPa, and the holding time is 60-90s.
7. The method according to claim 1, wherein in the step (3), the drying process is: drying in the shade for 4-8h at 20-40 deg.C and air relative humidity less than 60%, and oven drying at 80-100 deg.C for 4-8h.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB559468A (en) * | 1942-08-17 | 1944-02-21 | Henry Dreyfus | Constructional materials |
JPH11300711A (en) * | 1998-04-15 | 1999-11-02 | Fudow Co Ltd | Wooden resin molded article and material for it |
CN102120871A (en) * | 2011-03-22 | 2011-07-13 | 暨南大学 | Preparation method of chitosan fiber reinforced polylactic acid composite material |
CN109880331A (en) * | 2019-04-16 | 2019-06-14 | 广西大学 | A kind of preparation method of graphene PLA wood plastic composite |
US20220275201A1 (en) * | 2021-01-29 | 2022-09-01 | Erthos Inc. | Biodegradable polymeric material, biodegradable products and methods of manufacture and use therefor |
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- 2022-10-18 CN CN202211275272.3A patent/CN115594871A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB559468A (en) * | 1942-08-17 | 1944-02-21 | Henry Dreyfus | Constructional materials |
JPH11300711A (en) * | 1998-04-15 | 1999-11-02 | Fudow Co Ltd | Wooden resin molded article and material for it |
CN102120871A (en) * | 2011-03-22 | 2011-07-13 | 暨南大学 | Preparation method of chitosan fiber reinforced polylactic acid composite material |
CN109880331A (en) * | 2019-04-16 | 2019-06-14 | 广西大学 | A kind of preparation method of graphene PLA wood plastic composite |
US20220275201A1 (en) * | 2021-01-29 | 2022-09-01 | Erthos Inc. | Biodegradable polymeric material, biodegradable products and methods of manufacture and use therefor |
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