CN115590784A - Long-lasting cosmetic composition - Google Patents
Long-lasting cosmetic composition Download PDFInfo
- Publication number
- CN115590784A CN115590784A CN202211212553.4A CN202211212553A CN115590784A CN 115590784 A CN115590784 A CN 115590784A CN 202211212553 A CN202211212553 A CN 202211212553A CN 115590784 A CN115590784 A CN 115590784A
- Authority
- CN
- China
- Prior art keywords
- cosmetic composition
- oil
- cosmetic
- film
- particulate material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000004062 sedimentation Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
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- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 150000003697 vitamin B6 derivatives Chemical class 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 235000001892 vitamin D2 Nutrition 0.000 description 1
- 239000011653 vitamin D2 Substances 0.000 description 1
- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 description 1
- 235000005282 vitamin D3 Nutrition 0.000 description 1
- 239000011647 vitamin D3 Substances 0.000 description 1
- QYSXJUFSXHHAJI-YRZJJWOYSA-N vitamin D3 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-YRZJJWOYSA-N 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 229940021056 vitamin d3 Drugs 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a durable cosmetic composition, which comprises the following components: a film forming agent comprising trimethylsiloxysilicate, a VP/hexadecene copolymer, and dextrin isostearate; liquid oils having emollient effects including isododecane, polyglyceryl-2 triisostearate, isononyl isononanoate, caprylic/capric triglyceride and tri (ethyl hexanoate) triglyceride; a first particulate material comprising silica surface-coated with triethoxycaprylylsiloxane.
Description
Technical Field
The invention relates to the field of daily cosmetics, in particular to a durable cosmetic composition.
Background
The powder cosmetic includes loose powder and powder block formed by pressing plate, such as eye shadow plate, blush, face repairing plate, high-speed compact disc, honey powder, etc. The powder cosmetic is mainly used for absorbing excessive facial grease and reducing facial gloss, can comprehensively adjust skin color, makes makeup more durable, smooth and delicate, and can prevent makeup removal. The powder cosmetic contains pulvis Talci, mica, synthetic fluorophlogopite, silica, toner, etc., and the powder block formed by pressing plate can be compounded with small amount of oil and wax powder as binder.
The prior powder cosmetics have the following technical problems:
1. the particle size of the selected talcum powder is too large, the powder quality is poor, the effect after makeup is not close to skin and powder is floated, and the skin feel is poor;
2. the makeup holding effect is general, a uniform and durable film cannot be formed on the skin surface, the friction resistance is poor, and the color slowly fades and falls off along with the lengthening of the makeup carrying time under the condition of no external force friction;
3. the skin-sticking performance is general, and the powder cosmetic has a limited promotion effect because the main raw material is a particle material, although the skin-sticking performance can be promoted by carrying out surface pretreatment on the particle material and/or matching with a certain proportion of grease;
4. the powder flying problem exists in the process of dipping and making up by using a cosmetic brush, the powder flying can damage the originally clean making up surface, and certain pollution is caused to the environment;
5. the powder cosmetic has a large amount of dust flying in the manufacturing process, powder blocks formed by pressing plates need to be pressed and formed after powder is pulverized, the preparation process is complex and tedious, the production efficiency is low, the production process has certain harm to the health of production workers, and especially has certain risk to the health of lungs and respiratory tracts;
6. the powder cosmetics have a general extending effect, and have the problem of uneven color tinge in the using process.
The term "particulate material" as used herein refers to a particulate material generally used in cosmetics unless otherwise specified, the shape of the particles may be spherical, plate-like, needle-like, etc., the particle size of the particles such as smoke, fine particles, pigment grade, etc., and the particle structure such as porous and non-porous, etc., and the particles are not particularly limited, and for example, examples thereof include inorganic particulate materials (such as alumina, cerium oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic sericite, talc, kaolin, silica, silicon carbide, boron nitride, etc.), luminescent particulate materials (such as bismuth oxychloride, titanium dioxide-coated mica, iron oxide-coated mica titanium, organic pigment-coated mica titanium, titanium dioxide-coated glass powder, and aluminum powder), organic particulate materials (such as nylon, polymethyl methacrylate, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-methacrylic acid copolymer, PET resin, polyethylene, polystyrene, organopolysiloxane elastomer, polymethylsilsesquioxane, polyurethane, wool, crystalline cellulose, and N-acyl lysine), pigment particulate materials (such as organic tar pigments and organic pigment lake pigments), metal particulate materials, composite particulate materials (such as fine particle titanium dioxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, silica containing silica, and silica containing zinc oxide), and 1 or 2 or more of these can be used. These particulate materials may be surface-treated with 1 or 2 or more kinds of fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, surfactants, and the like.
Disclosure of Invention
In view of the technical problems in the prior art, the present invention provides a cosmetic composition which is solvent-based and which contains a particulate material that maintains a high dispersibility in the cosmetic composition for a long period of time.
The oily component in the cosmetic composition provided by the invention is a continuous phase and is an oily type (nonaqueous type) without an aqueous phase, and the cosmetic composition has at least one of the following beneficial effects:
1. the cosmetic composition can form a cosmetic film which is excellent in cosmetic durability and glossy feeling, has no stickiness, has a certain hardness, and is soft without a feeling of burden when applied to the skin surface;
2. the cosmetic composition can form a soft cosmetic film with a certain hardness and strength and easy to stretch when applied on the surface of the skin;
3. the cosmetic composition provides a smooth and ductile feeling of use without stickiness, and excellent skin-friendly feeling and makeup durability, and can form a uniform cosmetic film and exhibit excellent makeup effects;
4. the cosmetic composition provides excellent use feeling which smoothly spreads on the skin, has good gloss feeling, inhibits the fusion of moisture and sebum, and has excellent cosmetic durability;
5. the cosmetic composition has no stickiness, good usability, high adhesion, good gloss, and excellent makeup durability.
In order to achieve the purpose, the invention adopts the following technical scheme: a cosmetic composition comprising the following components (A), (B) and (C):
(A) Film formers including trimethylsiloxysilicate, VP/hexadecene copolymer, and dextrin isostearate;
(B) Liquid oils having emollient effects including isododecane, polyglyceryl-2 triisostearate, isononyl isononanoate, caprylic/capric triglyceride and glycerol tri (ethylhexanoate);
(C) The first particulate material includes silica obtained by surface-coating treatment with triethoxyoctylsiloxane (i.e., silica surface-treated with triethoxyoctylsilane, a bonded structure, in which a crosslinked coating layer is formed on the surface of silica).
In one embodiment, the cosmetic composition further comprises at least one of the following ingredients (E), (F), and (G):
(E) An oil-soluble thickener;
(F) An oil-soluble colorant;
(G) The second particulate material includes disteardimonium hectorite surface-coated with isododecane, synthetic fluorophlogopite surface-coated with triethoxyoctylsiloxane, and methyl alkylated silica.
In one embodiment, from the viewpoint of enhancing the use experience of the cosmetic composition, the cosmetic composition further comprises the following ingredients (H) and (I):
(H) An oil-soluble skin conditioner;
(I) An oil-soluble fragrance.
In the process of developing the technical scheme of the invention, the inventor obtains the following findings:
1. it was found that a film-forming agent comprising a combination of trimethylsiloxysilicate, VP/hexadecene copolymer and dextrin isostearate is excellent in film-forming property, high in adhesion and free from tackiness, and can form a smooth coating film having both hardness and softness, and a cosmetic composition containing the film-forming agent is excellent in cosmetic persistence and glossy feeling, free from tackiness, has a certain hardness and softness, and has followability, and thus a cosmetic film with less burden feeling can be obtained;
2. it has been found that a cosmetic composition obtained by combining the film-forming agent and the liquid oil can form a cosmetic film which is easily spreadable, has an excellent feeling in use, and has a certain hardness, strength and flexibility;
3. it has been found that by combining the film-forming agent, the liquid oil, and the first particulate material, a superior feeling of use that is smooth and spreadable without stickiness can be obtained, while also being superior in a feeling of close contact with the skin and cosmetic persistence, and further, a cosmetic composition that can form a uniform cosmetic film and exhibit an excellent cosmetic effect can be obtained;
4. it has been found that a cosmetic composition obtained by combining the film-forming agent, the liquid oil, the first particulate material, the oil-soluble thickener and the oil-soluble colorant is excellent in the feeling of use that smoothly spreads on the skin and adhesion to the skin, can give a good glossy feel, is free from fusion of moisture and sebum, is not easily removed, can smoothly spread particularly when used for eyelids, is excellent in adhesion, and is easily repeatedly applied, and therefore can draw lines of a desired shape and concentration, is not easily dissolved in tears and sweat, and has a soft cosmetic film that has conformability, and therefore is not easily removed even when the eyelids blink, and is excellent in cosmetic durability;
5. it has been found that a cosmetic composition obtained by combining the film-forming agent, the liquid oil, the first particulate material, the second particulate material, and the oil-soluble thickener is free from stickiness and has good usability, and a cosmetic having excellent gloss feeling, adhesion, and cosmetic durability is obtained;
6. it was found that when a liquid oil comprising a combination of isododecane, polyglyceryl-2 triisostearate, isononyl isononanoate, caprylic/capric triglyceride and tris (ethylhexanoate) triglyceride was used as an oil suspension agent for the first particulate material, the first particulate material exhibited high hydrophobicity and dispersibility without causing sedimentation and aggregation, and the liquid oil was also excellent in adhesion to the skin and in moisturizing properties.
7. It was found that the first particulate material comprising silica obtained by surface-coating treatment with triethoxyoctylsiloxane not only has a uniform particle size distribution, high chemical stability and thermal stability, but also has excellent hydrophobicity, does not release hydrogen gas, does not contain Si — H bonds, has high spreadability, and can provide a dry, silky and soft skin feel. The cosmetic composition contains the first particulate material, which can provide better skin feel and improve the oil control effect (silica has micron-scale sphere-shaped porosity to endow the silica with high oil absorption value) and skin-close effect;
8. the second granular material is found to realize the gain effect equivalent to the beneficial effect of the talcum powder, and simultaneously, the defects of the talcum powder can be avoided, and the beneficial effect which cannot be realized by the talcum powder can be realized. The second particulate material comprising a combination of disteardimonium hectorite, which had been surface-coated with isododecane, synthetic fluorophlogopite, which had been surface-coated with triethoxyoctylsiloxane, and methyl alkylated silica, had good smoothness and excellent skin substantivity, more specifically: disteardimonium hectorite, obtained by surface coating isododecane, can be considered as a suspending agent and a stabilizer; the synthetic fluorophlogopite is coated by triethoxy octyl siloxane, can bring high lubricity and smooth skin feel, has the characteristics of low friction coefficient, static resistance and oxidation resistance, provides silky skin feel and improves skin adhesion; the silica silylate has a porous structure with adsorptive properties and can provide an extending effect. The cosmetic composition comprising both the first particulate material and the second particulate material can provide smooth skin feel, maintain adhesion and improve skin-contact effect, and the second particulate material can improve spreadability of the cosmetic composition and absorb excess oil on the skin, thereby enhancing skin freshness.
Drawings
The figures further illustrate the invention, but the examples in the figures do not constitute any limitation of the invention.
FIG. 1 is a schematic illustration of a cosmetic composition provided in example 1 of the present invention;
FIG. 2 is a schematic illustration of a compliance test;
FIG. 3 is a schematic diagram of a water resistance test;
FIG. 4 is a schematic of a ductility test;
FIG. 5 is a schematic representation of a friction resistance test;
fig. 6 is a schematic view after the rub resistance test.
Detailed Description
It should be understood that the specific embodiments described herein are merely illustrative of the invention and do not limit the invention.
The inventors have conducted intensive studies on existing solvent-based cosmetics including particulate materials, and have obtained the following knowledge:
1. in cosmetics, resin components such as rosin acid-based resins and silicone-based resins are used in order to improve cosmetic durability and to develop a glossy feel. However, although a cosmetic containing a specific organosiloxane resin and a volatile oil can improve the durability of makeup, the softness of a cosmetic film is lost as the amount of the resin added increases, and a feeling of burden is generated during makeup. Furthermore, although a cosmetic using a specific rosin ester compound does not have such a feeling of burden in makeup, the cosmetic film is sticky with an increase in the amount of resin, and thus has a disadvantage that the feeling of use is increased;
2. the combination of a particulate material and a resin component such as a rosin acid resin or a silicone resin in a cosmetic has disadvantages of a hard cosmetic film, lack of flexibility, very strong stickiness, and a feeling of burden;
3. adding wax with low softening point (not more than 80 ℃) and low melting point (not more than 90 ℃) and oil-soluble resin into the cosmetic to form a cosmetic film with certain hardness and strength and flexibility, but the cosmetic film has poor adhesion due to the existence of particle materials; if the amount of wax or oil-soluble resin added is increased, the flexibility of the cosmetic film is impaired;
4. in cosmetics, a dispersant is added to improve the dispersibility of a particulate material, and although the principle is not clear, the addition of a dispersant suitable for a particulate material easily causes removal of makeup, and therefore a sufficient retention effect cannot be obtained;
5. in order to improve the feeling of use, the feeling of adhesion, and the durability of makeup, a highly viscous oil agent such as polybutene is added to the cosmetic. However, the addition of a highly viscous oil agent exerts an adverse effect on the feeling of use such as stickiness or deterioration in spreadability, and a sufficient effect cannot be obtained in the makeup durability. On the other hand, a method of reducing the poor feeling of use by an organosiloxane resin and/or a volatile silicone oil is known, but there is a problem that the close feeling is impaired. Further, there is a method of suppressing stickiness by blending a particulate material, but smooth spreading, uniformity, and makeup durability may be lacking;
6. with conventional cosmetics of this type, tack-free properties, a feeling of close contact with the skin, and makeup durability are basically contradictory properties, and it has been difficult to achieve both properties in the prior art. More specifically, cosmetics of this type, which can be applied smoothly without stickiness, adhere well to an application site, form a uniform and smooth cosmetic film, and exhibit excellent gloss and can be retained for a necessary time, tend to have poor usability such as difficulty in stretching, and are also insufficient in terms of gloss feel.
7. In cosmetics, particulate materials such as inorganic particulate materials, organic particulate materials, pigment particulate materials, and the like are added for the purpose of color cosmetics, touch adjustment, and the like, and these particulate materials can be coated with various surface treatment agents according to the purpose. As one of them, various problems such as aggregation of the particulate material can be solved by improving the wettability and dispersibility to the oil agent, and the particulate material can be subjected to surface treatment for the purpose of improving the long-term storage stability of the cosmetic, and the effects of color cosmetics, ultraviolet absorption, and the like. However, many surface-treating agents having a particle material with good dispersibility in an oil agent have poor adhesion to the skin and have the property of diffusing into a specific oil agent. When a cosmetic containing these components is applied to the skin, the particulate material is continuously dispersed in the oil agent in the cosmetic film, does not adhere to the skin, cannot be absorbed smoothly at all times, and impairs the uniformity of the applied film.
The cosmetic composition provided by the present invention is a liquid oily cosmetic containing a particulate material, and examples thereof include a liquid matte blush, a liquid matte eye shadow, a liquid cosmetic, a liquid shade, and a liquid matte highlight. The cosmetic composition provided by the invention can be used for forming a cosmetic film when being applied, does not generate viscosity, can be uniformly coated under a certain force, is easy to repeatedly apply, can be easily adjusted to a desired film thickness, and can obtain an excellent increment effect.
The present invention provides cosmetic compositions comprising a film former comprising a combination of trimethylsiloxysilicate, VP/hexadecene copolymer, and dextrin isostearate. The trimethylsiloxy silicate has good film forming property, and can improve the durability, the color migration resistance and the excellent water and oil resistance; the VP/hexadecene copolymer has good water-resistant film-forming property, is beneficial to the dispersion of the first particle material, is beneficial to improving the moisture-preserving barrier function, and has good friction resistance; the dextrin isostearate can improve the adhesion of a coating film to skin and quickly form a soft water-resistant film on the surface of the skin. The inventors have found that a combination of soft and hard films, where trimethylsiloxysilicate forms a hard film and VP/hexadecene copolymer and dextrin isostearate forms a soft film, contributes to a better long-lasting effect. The content of the film-forming agent is 15-20wt% based on the mass of the cosmetic composition. The film forming agent in this range can form a uniform and smooth coating film having excellent film forming properties, hardness and flexibility at the same time, has high adhesion and little stickiness, and has excellent adhesion to an object to be coated. When the content of the film-forming agent is less than 15% by weight, a uniform and smooth coating film cannot be formed, and when it exceeds 40% by weight, the tackiness becomes high, and the cosmetic film may give an unpleasant feeling. The cosmetic composition containing the film-forming agent can obtain excellent effects such as excellent cosmetic durability and gloss, no stickiness, certain hardness and flexibility, and less burden, which cannot be obtained by other film-forming resin components.
The cosmetic composition provided by the invention comprises a liquid oil with a skin moistening effect, wherein the liquid oil comprises a combination of isododecane, polyglycerol-2 triisostearate, isononyl isononanoate, caprylic/capric triglyceride and glycerol tri (ethyl hexanoate). The liquid oil can be regarded as a main solvent and an emollient, and can impart long-lasting stability and smooth feeling upon application to the cosmetic composition. The liquid oil has good compatibility with the film-forming agent, and is excellent in remarkably improving the adhesion and hardness of a cosmetic film, and the film-forming agent and the liquid oil can synergistically exhibit the effects of facilitating stretching and softening the cosmetic film, and more specifically, the combination of the film-forming agent and the liquid oil allows the structure to be easily broken by friction during application, thereby providing a feeling of use that facilitates stretching and leaves no burden on the skin, and can complement the brittleness of the cosmetic film formed from the film-forming agent, thereby forming a cosmetic film excellent in hardness and strength. The content of the liquid oil is 40-50wt% based on the mass of the cosmetic composition. Within this range, the ease of spreading and the makeup retention effect are dramatically improved. The liquid oil and the film forming agent are preferably mixed in a mass ratio of 1:1.5-2, excellent makeup retention effect can be obtained. Higher levels of liquid oils with emollient effects in cosmetic compositions result in more cosmetic effects and higher affinity to the skin.
The cosmetic composition provided by the invention comprises a first particulate material, wherein the first particulate material comprises silica obtained by performing surface coating treatment on triethoxyoctylsiloxane. The content of the first particulate material is 20 to 25wt% based on the mass of the cosmetic composition. Within this range, the dispersibility of the first particulate material in the cosmetic composition is improved, and a cosmetic film which is smoothly spreadable, non-tacky, uniform, and excellent in cosmetic durability can be obtained. By using the first particulate material together with the liquid oil, the film former, the stickiness may be reduced. From the viewpoint of more excellent elongation, the average particle diameter (value measured by laser diffraction particle size distribution) of the first particulate material is more preferably 1 to 30 μm. The first particulate material exhibits an excellent, long-lasting and stable dispersion effect in the liquid oil, and thus the cosmetic composition does not require an additional dispersant to avoid a negative effect on the makeup-holding effect.
The content of the trimethylsiloxysilicate is preferably 70 to 80wt% based on the mass of the film forming agent, from the viewpoint that a cosmetic film which is smooth and ductile, has no stickiness, is uniform, and is excellent in cosmetic durability can be obtained. The total content of isododecane, isononyl isononanoate, caprylic/capric triglyceride and tris (ethylhexanoate) glyceride is preferably 40 to 80% by weight based on the mass of the liquid oil, from the viewpoint of obtaining a cosmetic film having a better skin-friendly effect, more contributing to make-up, being more refreshing and having better spreading properties.
In addition to the above-mentioned film-forming agent, liquid oil and first particulate material component, an oil-soluble thickener, an oil-soluble colorant, a second particulate material (including disteardimonium hectorite obtained by surface-coating isododecane, synthetic fluorophlogopite obtained by surface-coating triethoxyoctylsiloxane, and methyl alkylated silica), an oil-soluble skin conditioner, and an oil-soluble fragrance may be blended in the cosmetic composition according to the purpose within a range not affecting the effects of the present invention.
The oil-soluble thickener used in the cosmetic composition provided by the present invention is not particularly limited as long as it can be blended in a usual cosmetic, and examples thereof include ethylene-propylene copolymer, polyethylene wax, ceresin, paraffin wax, fischer-tropsch wax, hydrogenated microcrystalline wax, candelilla wax, carnauba wax, rice bran wax, beeswax, polybutene, polyethylene, and hydrogenated (styrene/isoprene) copolymer, and 1 or 2 or more of them can be used. Among them, from the viewpoint of excellent adhesion and strong film formation against sweat and sebum, it is preferable to use a combination of polyethylene and ceresin, which contributes to enhancing the film-forming property and improving the makeup-holding effect of the cosmetic composition while providing a thickening effect. The amount of the oil-soluble thickener to be blended in the cosmetic composition provided by the present invention is not particularly limited, but is preferably 0.5 to 5% by weight, more preferably 2 to 4% by weight. Within this range, good effects can be obtained from the viewpoint of good adhesion to the skin and good maintenance of makeup.
The oil-soluble colorant used in the cosmetic composition provided by the present invention may be any colorant that is generally used in cosmetics, and may be in the form of a sphere, plate, spindle, needle or the like, in the form of a smoke, fine particle, pigment grade or the like, or in the form of a porous or non-porous, and the particle structure or the like thereof is not particularly limited, and inorganic pigments, organic pigments, luminescent pigments, metals or the like may be used. Specific examples of the particulate material include white inorganic pigments such as titanium dioxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, prussian blue, ultramarine, and red lead, luminescent pigments such as mica titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide-coated mica, titanium dioxide-coated synthetic phlogopite, titanium dioxide-coated bismuth oxychloride, iron oxide mica titanium, prussian blue-treated mica titanium, carmine-treated mica titanium, fish scale foil, titanium dioxide-coated glass powder, and resin-laminated powder, organic pigment particulate materials such as red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, and yellow 401, organic pigment particulate materials such as red 3, red 104, red 106, red 205, yellow 4, yellow 5, green 3, blue 1, zirconium, barium, or aluminum lake, or metal-coated fine particles such as aluminum powder, gold powder, silver powder, titanium dioxide-coated titanium oxide, orange-coated titanium oxide, and zinc sulfate-coated fine silica particles, and composite fine particles containing at least 2 kinds of oxygen-containing mica, and zinc oxide fine particles can be used as required. They may be surface-treated with 1 or 2 or more kinds of fluorine-based compounds, silicone-based compounds, metal soaps, lecithins, hydrogenated lecithins, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, surfactants, and the like. Among them, surface treatment with a fluorine-based compound, a silicone-based compound, or the like is preferably used because it is not easily incorporated even with sweat or sebum. Iron oxides are preferably used based on compatibility with other components, and may be, for example, a combination of CI 77492, CI 77491, CI 77891, CI 77499, and CI 15850. The amount of the oil-soluble coloring agent to be blended in the cosmetic composition provided by the present invention is not particularly limited, but is preferably 5 to 10% by weight, and within this range, satisfactory effects can be obtained from the viewpoint of excellent coloring properties and no compatibility with moisture such as tears and sebum. It has also been unexpectedly found that the combination of the first particulate material and the oil-soluble colorant helps to improve the extensibility of a cosmetic film formed from the cosmetic composition, is easy to make up uniformly, has a natural make-up effect, does not cake or mottle in color, and also enables a longer lasting make-up because the first particulate material can effectively adsorb oil secreted from the skin.
The second particulate material (including disteardimonium hectorite obtained by surface coating isododecane, synthetic fluorophlogopite obtained by surface coating triethoxyoctylsiloxane, and methyl alkylated silica) used in the cosmetic composition according to the present invention and the first particulate material are mixed in a mass ratio of 1:4-7, preferably 1:4.2 to 6.4, the composition can provide excellent effects in terms of usability and feeling of use, in addition to good adhesion to the skin and good cosmetic retention.
In the present invention, both the first particulate material and the second particulate material are subjected to the surface coating treatment, and the method for performing the surface coating treatment on these particulate materials is not particularly limited, and a generally known treatment method can be used. Specifically, there may be mentioned a method of directly mixing with the particulate material (dry treatment method), a method using a solvent such as ethanol, isopropyl alcohol, n-hexane, benzene or toluene (wet method), a gas phase method, a mechanochemical method and the like. The following methods are preferred: the surface-coated particulate material having a more homogeneous texture and an excellent feeling in use can be produced by dissolving the coating material in a volatile hydrocarbon oil such as hexane or isoparaffin, mixing the resulting solution with the particulate material base material, drying the resulting mixture to remove the solvent, and then pulverizing the dried mixture. The pulverization method is also not particularly limited. The coating amount of the first particulate material and the second particulate material is not particularly limited, but is preferably 0.1 to 8wt% in the surface-coating-treated particulate material.
Examples of the oil-soluble skin conditioning agent used in the cosmetic composition provided by the present invention include vitamins, anti-inflammatory agents, crude drugs, and the like, as long as the oil-soluble component is generally used in cosmetics. Examples of the vitamins include vitamin a oils, vitamin a compounds such as retinol, retinol acetate and retinol palmitate, vitamin B2 compounds such as riboflavin, riboflavin butyrate and flavin adenine nucleotide, vitamin B6 compounds such as pyridoxine hydrochloride and pyridoxine dioctanoate, pantothenic acids such as L-ascorbic acid, L-ascorbyl dipalmitate, L-ascorbic acid-2-sodium sulfate and di-potassium phosphate diester of dl- α -tocopherol-L-ascorbic acid, pantothenic acids such as calcium pantothenate, D-panthenol, panthenyl ethyl ether and acetyl panthenyl ethyl ether, vitamin D compounds such as ergocalciferol and cholecalciferol, nicotinic acids such as nicotinic acid, benzyl nicotinate and nicotinamide, vitamin E compounds such as dl- α -phenol, dl- α -tocopherol acetate, dl- α -tocopherol nicotinate and dl- α -tocopherol succinate, vitamin P and biotin. Preferably, the vitamin E group imparts antioxidant properties to the cosmetic composition.
Examples of the oil-soluble fragrance used in the cosmetic composition of the present invention include perfumes.
The cosmetic composition provided by the present invention may further contain an oily component, an oil-soluble surfactant, an oil-soluble ultraviolet absorber, an oil-soluble antioxidant, an oil-soluble fiber, an oil-soluble fading inhibitor, an oil-soluble defoaming agent, an oil-soluble preservative, an oil-soluble perfume, and the like, which are used in general cosmetics, in such an amount that the effects of the present invention are not impaired.
Wherein the oily component is derived from animal oil, vegetable oil, synthetic oil, etc.; regardless of the properties of the solid oil, semisolid oil, liquid oil, volatile oil, etc., hydrocarbons, oils, waxes, hydrogenated oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oil gelling agents, etc., which are generally used in cosmetics, can be used. The inventors have surprisingly found that by incorporating into a cosmetic composition a liquid oil having a viscosity of not less than 2000mPa "s at 25 ℃ (measured using a Brookfield type viscometer) and/or a semisolid oil having a viscosity of not less than 400000 mPa" s at 25 ℃ (measured using a Brookfield type viscometer), in combination with the film-forming agent and the liquid oil in the cosmetic composition, adhesion can be improved and a thick cosmetic film can be formed, resulting in excellent gloss.
[ examples ]
Specific component distribution ratios of the cosmetic compositions provided in examples 1-4 are shown in table 1.
The components shown in table 1 are all commercially available products.
It should be noted that the cosmetic composition provided in example 1 was a liquid matte blush, and the cosmetic composition was in a liquid state with a certain fluidity, as shown in fig. 1.
The cosmetic composition provided in example 2 was a liquid matte eye shadow.
The cosmetic composition provided in example 3 was shaded with liquid.
In addition, the cosmetic composition provided in example 4 was a liquid matte highlight.
TABLE 1
The cosmetic compositions provided in examples 1 to 4 were prepared by the following methods:
step one, heating phase A to 70-80 ℃, stirring and dissolving until the phase A is uniformly dispersed for later use;
grinding the phase B by using a three-roll grinder until the phase B is uniformly dispersed for later use;
and step three, heating the phase C to 95-105 ℃, stirring until the phase C is clear and transparent and has no particles, cooling to 85 ℃, adding the phase A and the phase B, stirring and dispersing uniformly, then continuing cooling, cooling to 75-80 ℃, adding the phase D, homogenizing for 3-5min, then continuing cooling, cooling to 70 ℃, adding the phase E, stirring uniformly, discharging, detecting to be qualified, and filling.
The cosmetic compositions provided in examples 1 to 4 were all liquid type, and thus there was no problem of flying powder during use. Examples 1 to 4 provide cosmetic compositions which are simple in preparation process, free from a large amount of dust flying during the preparation process, and do not require press molding.
The cosmetic compositions provided in examples 1 to 4 were subjected to the following tests.
(viscosity test)
The cosmetic compositions provided in examples 1 to 4 were subjected to a viscosity test, specifically, a viscosity test using a T-B92 rotor at 25 ℃ and 15RPM, and the results are shown in Table 2. Examples 1-4 provide cosmetic compositions having a moderate viscosity without stickiness.
TABLE 2
| Example 1 | Example 2 | Example 3 | Example 4 | |
| Viscosity (Unit: cP) | 11490 | 12986 | 10954 | 11239 |
| Torque (%) | 43.08％ | 48.69％ | 41.07％ | 42.14％ |
The cosmetic compositions provided in examples 1-2 were tested as follows.
(test of fitness)
The cosmetic composition provided in example 1 and blush of the existing powder formulation system were uniformly applied to the inner side of the forearm, respectively, and the make-up effect was observed. As shown in FIG. 2, the cosmetic composition provided in example 1 (corresponding to b in FIG. 2) was more skin-friendly and had a natural makeup effect, and blush (corresponding to a in FIG. 2) had a blooming phenomenon in the conventional powder formulation system.
(Water resistance test)
Referring to a method for testing the waterproof performance in GB/T35889-2018 eyeliner (cream), the existing blush of a powder formula system and the cosmetic composition provided in example 1 are subjected to a waterproof test.
The method specifically comprises the following steps: uniformly coating the test sample on the inner side of the forearm, wherein the coating area is at least 2cm multiplied by 2cm; at room temperature with a relative humidity of less than 75% until the sample is dry; immediately and fully soaking a facial tissue with pure water at room temperature for 5min in a wet manner on the area coated with the sample; and observing whether the white facial tissue is obviously tinged or shed.
The results of the tests are shown in fig. 3, where the cosmetic composition provided in example 1 (corresponding to b in fig. 3) showed no significant halation or flaking, and the blush of the prior powder formulation (corresponding to a in fig. 3) showed significant flaking.
(ductility (degree of halation)
The same amount of the cosmetic composition provided in example 2 and a commercially available liquid matte eye shadow were applied to the inner side of the forearm, and gently opened with the finger-belly. As shown in FIG. 4, the commercial liquid matte eye shadow (corresponding to a in FIG. 4) has obvious color aggregation and agglomeration, while the cosmetic composition provided by example 2 (corresponding to b in FIG. 3) is more likely to be faint and natural, has better ductility, is uniform in color and is less likely to agglomerate and agglomerate.
(Friction resistance test)
As shown in fig. 5, the cosmetic composition provided in example 1 (corresponding to b in fig. 5) and the blush of the existing powder formula system (corresponding to a in fig. 5) were uniformly applied to the inner side of the forearm, left to stand for 30 minutes, and the skin surface to which the sample was applied was rubbed from the outside to the inside with a white facial tissue 3 times, so that as shown in fig. 6, after three rubs, the test area of the cosmetic composition provided in example 1 (corresponding to b in fig. 6) remained relatively intact, and the color of the test area of the blush of the existing powder formula system (corresponding to a in fig. 6) was clearly released.
In one embodiment, the provided cosmetic composition is useful as a makeup cosmetic or the like because it combines a non-sticky and smoothly spreading feeling in use, and excellent skin-friendly feeling and makeup durability, and can form a uniform cosmetic film and exhibit excellent makeup effects.
In one embodiment, the cosmetic composition is excellent in smooth spreadability on the skin, adhesion to the skin, good color development and luster, free from fusion of moisture and sebum, not easy to remove, smooth spreadability particularly when applied to the eyelid, excellent in adhesion, easy to apply repeatedly, capable of drawing a line of a desired shape and concentration, and soft and conformable to the cosmetic film, and thus not easy to remove even when the eyelid blinks, and excellent in makeup durability. Therefore, it is useful as eyeliner or the like.
In one embodiment, a cosmetic composition is provided which has no stickiness and good usability, has excellent adhesion to applicable parts such as lips, can form a smooth and thick cosmetic film to give an excellent glossy feeling, and has a certain hardness and softness and a high follow-up property to give a high cosmetic durability. Therefore, it is useful as a lip cosmetic or the like.
All possible combinations of the technical features of the above embodiments may not be described for the sake of brevity, but should be considered as within the scope of the present disclosure as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is specific and detailed, but not to be understood as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. A long-wearing cosmetic composition comprising the following ingredients:
a film forming agent comprising trimethylsiloxysilicate, a VP/hexadecene copolymer, and dextrin isostearate;
liquid oils having emollient effect including isododecane, polyglyceryl-2 triisostearate, isononyl isononanoate, caprylic/capric triglyceride and tri (ethyl hexanoic) glyceride;
a first particulate material comprising silica surface-coated with triethoxycaprylylsiloxane.
2. The cosmetic composition according to claim 1, wherein the content of the film-forming agent is 15 to 20wt% based on the mass of the cosmetic composition.
3. The cosmetic composition according to claim 2, wherein the content of the liquid oil is 40 to 50wt% based on the mass of the cosmetic composition.
4. The cosmetic composition according to claim 2, wherein the mass ratio of the liquid oil to the film-forming agent is 1:1.5-2.
5. The cosmetic composition according to claim 3, characterized in that the content of the first particulate material is 20 to 25wt% based on the mass of the cosmetic composition.
6. The cosmetic composition of claim 1, further comprising an oil-soluble thickener comprising polyethylene and ceresin.
7. The cosmetic composition of claim 1, further comprising an oil-soluble colorant, the oil-soluble colorant comprising an iron oxide species.
8. The cosmetic composition of claim 1, further comprising a second particulate material comprising disteardimonium hectorite surface-coated with isododecane, synthetic phlogopite surface-coated with triethoxyoctylsiloxane, and methyl alkylated silica.
9. The cosmetic composition of claim 1, further comprising an oil-soluble skin conditioning agent, said oil-soluble skin conditioning agent comprising a vitamin E group.
10. The cosmetic composition of claim 1, further comprising an oil-soluble fragrance.
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| CN202211212553.4A CN115590784B (en) | 2022-09-29 | 2022-09-29 | Permanent cosmetic composition |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113975218A (en) * | 2021-12-09 | 2022-01-28 | 美尚(广州)化妆品股份有限公司 | Base makeup product suitable for oily skin and preparation method thereof |
| CN114340585A (en) * | 2019-08-26 | 2022-04-12 | 信越化学工业株式会社 | Solid cosmetic |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114340585A (en) * | 2019-08-26 | 2022-04-12 | 信越化学工业株式会社 | Solid cosmetic |
| CN113975218A (en) * | 2021-12-09 | 2022-01-28 | 美尚(广州)化妆品股份有限公司 | Base makeup product suitable for oily skin and preparation method thereof |
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| Title |
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| 佚名: "cilo 十色眼影盘", pages 1 - 5, Retrieved from the Internet <URL:https://www.cosdna.com/chs/cosmetic_245d548856.html> * |
| 佚名: "tarte emphasEYES Waterproof Clay Shadow", pages 1 - 2, Retrieved from the Internet <URL:https://www.cosdna.com/chs/cosmetic_60cd158955.html> * |
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